Nitrogen Containing Organic Solvent Compound (e.g., Acetonitrile, Etc.) Patents (Class 429/339)
  • Patent number: 11962032
    Abstract: An assembly for supplying power to an aircraft is disclosed having at least one battery housed in a respective housing, each housing comprising a wall in which a through-opening is arranged, and an exhaust device including a discharge duct connecting each housing opening to a common discharge port, a valve mounted on each opening. Each valve includes a membrane arranged so as to seal the opening closed and having a surface of pressure application towards the inside of the housing and a surface of pressure application towards the outside of the housing. The surface of pressure application towards the outside of the housing is larger than the surface of pressure application towards the inside of the housing, so that the membrane bursts at a bursting pressure inside the housing that is lower than a bursting pressure reached outside the housing.
    Type: Grant
    Filed: July 27, 2021
    Date of Patent: April 16, 2024
    Assignee: AIRBUS DEFENCE AND SPACE SAS
    Inventors: Julien Bergery, Dimitry Loubere
  • Patent number: 11929503
    Abstract: Provided is a positive electrode for a secondary battery in which carbon nanotubes are used, of which an initial resistance is small, and that suppresses an increase in resistance when charging and discharging are repeated. The positive electrode for a secondary battery disclosed herein includes a positive-electrode current collector and a positive-electrode active material layer provided on the positive-electrode current collector. The positive-electrode active material layer contains a positive-electrode active material and carbon nanotubes, and substantially does not contain a resin binder. The positive-electrode active material layer includes a layer-like region that is in contact with the positive-electrode current collector, and a region other than the layer-like region. Both of the layer-like region and the region other than the layer-like region contain carbon nanotubes.
    Type: Grant
    Filed: August 12, 2021
    Date of Patent: March 12, 2024
    Assignee: PRIME PLANET ENERGY & SOLUTIONS, INC.
    Inventor: Yuji Yamamoto
  • Patent number: 11837715
    Abstract: The present disclosure provides a composite wherein NaCl nanoparticles are uniformly dispersed on reduced graphene oxide (rGO), a positive electrode active material including the same, a sodium secondary battery including the same, and a method for preparing the same. The positive electrode active material according to the present disclosure has a structure wherein NaCl nanoparticles are uniformly dispersed on rGO in a one-step process through chemical self-assembly. Therefore, the positive electrode active material according to the present disclosure exhibits superior electrochemical properties with high capacity because the small NaCl particles are dispersed uniformly and is economically favorable because the preparation process is simple.
    Type: Grant
    Filed: February 18, 2021
    Date of Patent: December 5, 2023
    Assignee: Korea Institute of Science and Technology
    Inventors: Kyung Yoon Chung, Ha Kyung Roh, Moeez Iqra, Eun Seong Kim, Hun-Gi Jung, Won Young Chang
  • Patent number: 11830978
    Abstract: An electrolyte additive for a lithium secondary battery, an electrolyte, and a lithium secondary battery, the additive including a compound represented by Formula 1 below:
    Type: Grant
    Filed: May 29, 2020
    Date of Patent: November 28, 2023
    Assignee: SAMSUNG SDI CO., LTD.
    Inventors: Myungheui Woo, Pavel Shatunov, Olga Tsay, Younghye Kang, Aeran Kim, Hyejin Park, Jeongmin Shin, Duckjae You, Taejin Lee, Harim Lee, Jinhyeok Lim, Wonseok Cho, Hyunbong Choi
  • Patent number: 11784347
    Abstract: The present invention relates to an electrolyte for a rechargeable lithium, battery and a rechargeable lithium battery including same, wherein the electrolyte for a rechargeable lithium battery may comprise: a non-aqueous organic solvent, a lithium salt, a first additive containing a compound represented by chemical formula 1, and a second additive containing a magnesium salt.
    Type: Grant
    Filed: February 12, 2019
    Date of Patent: October 10, 2023
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Soojin Kim, Sangjae Park, Yongbeom Lee, Jeongdoo Yi
  • Patent number: 11777142
    Abstract: A gelable system is formed by mixing lithium salts and small-molecule ether compounds such as cyclic ether compounds or straight-chain ether compounds, optionally added with inorganic nanoparticles, additives, other solvents and/or electrolytes; a gel system or solid system is formed by interaction between them (such as the formation of new complexes or self-assembly, etc.), and by ring-opening polymerization or polycondensation of the small-molecule cyclic ether compounds, or by addition-fragmentation chain transfer polymerization of the small-molecule straight-chain ether compounds, etc. The gel system or solid system not only has better safety in use than common gel systems or solid systems, but also better adjustability of strength. The strength of the formed gel can be improved from the source by changing composition and type of raw materials. The improvement in the strength enables the gel system to be expanded into the solid system, thereby further extending the application range of the gel system.
    Type: Grant
    Filed: November 26, 2019
    Date of Patent: October 3, 2023
    Assignee: BEIJING NORMAL UNIVERSITY
    Inventors: Lin Li, Fengquan Liu, Jianjun Zhou, Lu Wang
  • Patent number: 11777081
    Abstract: The present invention provides a multilayer assembly comprising a metallic layer that is at least partially coated with a hybrid inorganic/organic composition, a method for its preparation and an electrochemical cell comprising said multilayer assembly.
    Type: Grant
    Filed: February 14, 2017
    Date of Patent: October 3, 2023
    Assignee: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
    Inventors: Christine Hamon, Libero Damen, Julio A. Abusleme, Riccardo Pieri
  • Patent number: 11764402
    Abstract: The present invention relates to an electrolytic solution for a lithium secondary battery, and a lithium secondary battery including the same. The lithium secondary battery according to the present invention employs the electrolytic solution for a lithium secondary battery, containing a difluorophosphite compound, according to the present invention, and thus has improved characteristics.
    Type: Grant
    Filed: February 12, 2019
    Date of Patent: September 19, 2023
    Assignee: SK On Co., Ltd.
    Inventors: Inhaeng Cho, Dai In Park, Jinhaek Yang
  • Patent number: 11757135
    Abstract: The present invention relates to an electrolytic solution for a lithium secondary battery, and a lithium secondary battery comprising the same. The lithium secondary battery according to the present invention employs the electrolytic solution for a lithium secondary battery, containing a difluorophosphite compound, according to the present invention, and thus has improved characteristics.
    Type: Grant
    Filed: November 8, 2021
    Date of Patent: September 12, 2023
    Assignee: SK On Co., Ltd.
    Inventors: Inhaeng Cho, Dai In Park, Jinhaek Yang
  • Patent number: 11742513
    Abstract: A separator for lithium-sulfur batteries and a lithium-sulfur battery including the same. The separator for lithium-sulfur batteries includes a separator substrate, a first coating layer formed on at least one surface of the separator substrate, and a second coating layer formed on the first coating layer. The first coating layer includes a polydopamine, and the second coating layer includes a lithium-substituted water-soluble polymer. Also a method for preparing the separator.
    Type: Grant
    Filed: October 23, 2018
    Date of Patent: August 29, 2023
    Assignee: LG ENERGY SOLUTION, LTD.
    Inventors: Sunjin Kim, Dongseok Shin, Doo Kyung Yang
  • Patent number: 11688853
    Abstract: An alkali-ion battery is provided that includes an anhydrous alkaline salt as an active cathode material, where the alkaline salt may be, for example, a lithium sulfate salt, sodium sulfate salt or potassium sulfate salt, as the active cathode material. In some such batteries, the inter-conversion of sulfate to persulfate occurs during charging and discharging of the battery, respectively.
    Type: Grant
    Filed: January 13, 2021
    Date of Patent: June 27, 2023
    Assignee: NRGTEK, Inc.
    Inventors: Subramanian Iyer, Ramesh Palanisamy
  • Patent number: 11677097
    Abstract: A solid electrolyte including a compound represented by Formula 1 or 3, the compound having a glass transition temperature of ?30° C. or less, and a glass or glass-ceramic structure, AQX—Ga1?zMz1(F1?kClk)3?3zZ3z1??Formula 1 wherein, in Formula 1, Q is Li or a combination of Li and Na, K, or a combination thereof, M is a trivalent cation, or a combination thereof, X is a halogen other than F, pseudohalogen, OH, or a combination thereof, Z is a monovalent anion, or a combination thereof, 1<A<5, 0?z?1, 0?z1?1, and 0?k<1, AQX-aMz1Z3z1-bGa1?z(F1?kClk)3?3z??Formula 3 wherein, in Formula 3, Q is Li or a combination of Li and Na, K, or a combination thereof; M is a trivalent cation, or a combination thereof, X is a halogen other than F, pseudohalogen, OH, or a combination thereof, Z is a monovalent anion, or a combination thereof, 0<a?1, 0<b?1, 0<a+b, a+b=4?A, 1<A<5, 0?z<1, 0?z1?1, and 0?k<1.
    Type: Grant
    Filed: June 1, 2021
    Date of Patent: June 13, 2023
    Assignee: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Sungkyun Jung, Hyeokjo Gwon, Gabin Yoon, Jusik Kim
  • Patent number: 11664536
    Abstract: Electrolytes for lithium ion batteries with carbon-based, silicon-based, or carbon- and silicon-based anodes include a lithium salt; a nonaqueous solvent comprising at least one of the following components: (i) an ester, (ii) a sulfur-containing solvent, (iii) a phosphorus-containing solvent, (iv) an ether, (v) a nitrile, or any combination thereof, wherein the lithium salt is soluble in the solvent; a diluent comprising a fluoroalkyl ether, a fluorinated orthoformate, a fluorinated carbonate, a fluorinated borate, or a combination thereof, wherein the lithium salt has a solubility in the diluent at least 10 times less than a solubility of the lithium salt in the solvent; and an additive having a different composition than the lithium salt, a different composition than the solvent, and a different composition than the diluent.
    Type: Grant
    Filed: January 8, 2021
    Date of Patent: May 30, 2023
    Assignee: Battelle Memorial Institute
    Inventors: Wu Xu, Ji-Guang Zhang, Hao Jia, Xianhui Zhang, Xia Cao, Sujong Chae, Ran Yi, Qiuyan Li, Won-Jin Kwak, Xiaolin Li
  • Patent number: 11652239
    Abstract: Electrolytes and electrolyte additives for energy storage devices comprising dihydrofuranone based compounds are disclosed. The energy storage device comprises a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, an electrolyte comprising at least two electrolyte co-solvents, wherein at least one electrolyte co-solvent comprises a dihydrofuranone based compound.
    Type: Grant
    Filed: May 23, 2022
    Date of Patent: May 16, 2023
    Assignee: Enevate Corporation
    Inventors: Hong Zhao, Liwen Ji, Heidi Anderson, Benjamin Yong Park
  • Patent number: 11646448
    Abstract: The electrolyte for a lithium secondary battery includes: a lithium salt; a solvent; and a functional additive, wherein the functional additive includes 1,2-bis(maleimido)ethane, represented by the following formula 1:
    Type: Grant
    Filed: June 7, 2021
    Date of Patent: May 9, 2023
    Assignees: Hyundai Motor Company, Kia Corporation, UNIST (Ulsan National Insitute of Science and Technology)
    Inventors: Yoon Sung Lee, Seung Min Oh, Ji Eun Lee, Sung Ho Ban, Ik Kyu Kim, Ko Eun Kim, Sang Kyu Kwak, Nam Soon Choi, Woo Gyum Kim, Hyeon Gyu Moon, Sung You Hong, Dae Yeon Hwang
  • Patent number: 11621437
    Abstract: An electrolyte, including a fluorine-containing phosphate ester and a carboxylate ester, wherein the fluorine-containing phosphate ester is represented by Formula 1: R1, R2 and R3 are each independently selected from hydrogen, a C1-C10 alkyl group, C1-C10 alkoxy group, C1-C10 haloalkyl group, C1-C10 haloalkoxy group, C1-C10 phosphate ester group, or C1-C10 mono- or multiple-carbonate ester group, wherein at least one of R1, R2 and R3 comprises a fluorine atom. The weight ratio of the fluorine-containing phosphate ester to the carboxylate ester is 0.001-0.5.
    Type: Grant
    Filed: February 14, 2020
    Date of Patent: April 4, 2023
    Assignee: NINGDE AMPEREX TECHNOLOGY LIMITED
    Inventors: Jianyu Liu, Jianming Zheng, Qian Wen, Wenqiang Li
  • Patent number: 11596926
    Abstract: Disclosed is a method for preparing a ternary alloy catalyst with polydopamine coating and a ternary alloy catalyst prepared thereby. The method for preparing a ternary alloy catalyst according to the present disclosure may provide a ternary alloy catalyst with increased resistance to carbon monoxide (CO) poisoning in which polydopamine is utilized as a coating material for a ternary alloy catalyst having a core-shell structure containing platinum to suppress the growth of particles during subsequent high-temperature heat treatment, and nickel (Ni), which is a transition metal, is diffused inside to form a core, thereby effectively preventing elution of nickel under an acidic condition.
    Type: Grant
    Filed: August 24, 2021
    Date of Patent: March 7, 2023
    Assignee: UIF (University Industry Foundation), Yonsei University
    Inventors: Han Sung Kim, Ho Jin Lee
  • Patent number: 11484867
    Abstract: An electrocatalyst comprises a crumpled transition metal dichalcogenide support loaded with catalytic metal nanoparticles through spontaneous reduction reactions. The support can be prepared by hydrothermal conversion of 2D nanosheets to 3D hierarchically crumpled sheets. As an example, using crumpled MoS2 as a support, highly tunable Ru loadings were obtained using the electrostatic interaction between MoS2 and RuCl3 in solution. Control over Ru loading was leveraged to produce Ru—MoS2 electrocatalysts that demonstrate different nitrogen reduction reaction activities, and which show varying resistance to electrochemical sintering and deactivation. Further, these high surface area materials can be utilized for many applications, including electrocatalysts, supercapacitors, and batteries.
    Type: Grant
    Filed: November 10, 2020
    Date of Patent: November 1, 2022
    Assignee: National Technology & Engineering Solutions of Sandia, LLC
    Inventors: Stephen Percival, James Eujin Park, Ivana Gonzales, Stanley Shihyao Chou
  • Patent number: 11482729
    Abstract: Some embodiments include an electrolyte composition for a battery using sodium ions as electrochemical vector, to the use of such an electrolyte composition as non-aqueous liquid electrolyte in a sodium-ion battery and to a sodium-ion battery comprising such a non-aqueous liquid electrolyte. In some embodiments, the amount of (oxalato)borate ranges from 0.05 to 10 wt. %, relative to the total weight of the electrolyte composition.
    Type: Grant
    Filed: October 11, 2018
    Date of Patent: October 25, 2022
    Assignees: Centre national de la recherche scientifique, College de france, Sorbonne Universite
    Inventors: Guochun Yan, Jean-Marie Tarascon
  • Patent number: 11335901
    Abstract: Provided are a negative active material for a lithium secondary battery, a manufacturing method thereof, and a lithium secondary battery including the same, and the present invention may provide a negative active material for a lithium secondary battery including a secondary particle in which a plurality of silicon nanoparticles are aggregated; and a plurality of metal particles distributed in pores in the secondary particle, a manufacturing method thereof, and a lithium secondary battery including the same.
    Type: Grant
    Filed: June 9, 2015
    Date of Patent: May 17, 2022
    Assignee: UNIST(ULSAN NATIONAL INSTITUTE OF SCIENCE AND TECHNOLOGY)
    Inventors: Jaephil Cho, Min-Seong Ko, Sujong Chae
  • Patent number: 11316195
    Abstract: Energy storage materials, and specifically, an electrolyte and an electrochemical device, where the electrolyte includes an additive A and an additive B, the additive A is selected from multi-cyano six-membered N-heterocyclic compounds represented by Formula I-1, Formula I-2 and Formula I-3, and combinations thereof, and the additive B is at least one sulfonate compound. The electrochemical device includes the above electrolyte. The electrolyte can effectively passivate surface activity of the positive electrode material, inhibit oxidation of the electrolyte, and effectively reduce gas production of the battery, meanwhile the electrolyte can be adsorbed on catalytically active sites of the graphite surface to form a stable SEI film, thereby effectively reducing side reactions. The electrochemical device using the electrolyte has good high temperature and high voltage cycle performance and storage performance.
    Type: Grant
    Filed: July 18, 2017
    Date of Patent: April 26, 2022
    Assignee: CONTEMPORARY AMPEREX TECHNOLOGY CO., LIMITED
    Inventors: Zijun Xu, Chunhua Hu, Tiancheng Yi, Yingjie Zhan, Chengdu Liang
  • Patent number: 11239459
    Abstract: A composite electrode for use in an all-solid-state electrochemical cell that cycles lithium ions is provided. The composite electrode comprises a solid-state electroactive material that undergoes volumetric expansion and contraction during cycling of the electrochemical cell and a solid-state electrolyte. The solid-state electroactive material is in the form of a plurality of particles and each particle has a plurality of internal pores formed therewithin. Each particle has an average porosity ranging from about 10% to about 75%, and the composite electrode has an interparticle porosity between the solid-state electroactive material and solid-state electrolyte particles ranging from about 5% to about 40%.
    Type: Grant
    Filed: October 18, 2018
    Date of Patent: February 1, 2022
    Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLC
    Inventors: Thomas A. Yersak, Mei Cai
  • Patent number: 11050090
    Abstract: The present invention relates to a liquid electrolyte formulation for a lithium metal secondary battery comprising: a conductive lithium salt which is selected from the group consisting of LiTFSI, LiFSI, LiCl, LiF, LiCN, LiC2N3, LiN3, LiNO2, LiNO3, LiBF4, LiPF6, LiAsF6, LiSbF6, and LiAlCl4 a first ionic liquid having the formula (CATION)FSI, wherein CATION is selected from the group consisting of alkyl pyrollidinium and alkyl piperidinium, a second ionic liquid as anti-corrosion agent, said second ionic liquid having the formula (CATION)(ANION) where (CATION) is defined as above and (ANION) is an anion comprising at least one nitrile functionality. The present invention relates also to a process for preparing such liquid electrolyte formulation and a lithium metal secondary battery comprising said liquid electrolyte formulation.
    Type: Grant
    Filed: September 27, 2018
    Date of Patent: June 29, 2021
    Assignee: Belenos Clean Power Holding AG
    Inventor: Yoann Mettan
  • Patent number: 10998574
    Abstract: This invention provides a non-aqueous electrolyte magnesium secondary battery comprising a positive electrode, a negative electrode, a separator, and a non-aqueous electrolyte, the non-aqueous electrolyte comprising [N(SO2CF3)2]? as an anion, and Mg2+ and/or an organic onium cation as a cation.
    Type: Grant
    Filed: October 8, 2015
    Date of Patent: May 4, 2021
    Assignee: NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY
    Inventors: Keigo Kubota, Kenichi Teramoto, Rie Ooyabu, Hajime Matsumoto
  • Patent number: 10847839
    Abstract: An electrochemical cell includes a cathode active material, lithium metal, a separator, and an electrolyte comprising a lithium salt, an organic aprotic solvent and a fluorinated sulfone represented by Formula II:
    Type: Grant
    Filed: August 1, 2018
    Date of Patent: November 24, 2020
    Assignee: UCHICAGO ARGONNE, LLC
    Inventors: Chi Cheung Su, Khalil Amine, Meinan He
  • Patent number: 10826121
    Abstract: The present disclosure provides an electrolyte and a secondary battery. The electrolyte comprises: a non-aqueous organic solvent; an electrolyte salt dissolved in the non-aqueous organic solvent; and an additive dissolved in the non-aqueous organic solvent. The additive comprises a first additive, the first additive is selected from boron phosphate represented by formula 1. When the electrolyte of the present disclosure is applied in the secondary battery, the performances of the secondary battery under high temperature environment can be effectively improved.
    Type: Grant
    Filed: February 7, 2018
    Date of Patent: November 3, 2020
    Assignee: CONTEMPORARY AMPEREX TECHNOLOGY CO., LIMITED
    Inventors: Feng Ju, Shaowei Feng, Changlong Han, Xiaochong Zhou, Ming Zhang
  • Patent number: 10797304
    Abstract: An all-solid-state secondary battery includes a positive electrode having a positive electrode active material layer, a negative electrode having a negative electrode active material layer, and a solid electrolyte layer between the positive and negative electrode active material layers. The solid electrolyte layer has a thickness of 2 to 20 ?m. The solid electrolyte layer includes a binder containing a particulate polymer having an average particle diameter of 0.1 to 1 ?m.
    Type: Grant
    Filed: February 3, 2016
    Date of Patent: October 6, 2020
    Assignee: ZEON CORPORATION
    Inventor: Kouichirou Maeda
  • Patent number: 10756394
    Abstract: The purpose of the present invention is to provide a nonaqueous electrolyte that contains acetonitrile having an excellent balance between viscosity and the dielectric constant and a fluorine-containing inorganic lithium salt, wherein the generation of complex cations comprising a transition metal and acetonitrile is suppressed, excellent load characteristics are exhibited, and increases in internal resistance upon repeated charge/discharge cycles are suppressed; a further purpose of the present invention is to provide a nonaqueous secondary battery. The present invention relates to a nonaqueous electrolyte which contains: a nonaqueous solvent comprising acetonitrile; a fluorine-containing inorganic lithium salt; and a specific nitrogenous cyclic compound typified by benzotriazole.
    Type: Grant
    Filed: March 30, 2016
    Date of Patent: August 25, 2020
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventors: Naoki Matsuoka, Akira Yoshino, Yutaka Natsume, Mitsuhiro Kishimi, Hirokazu Kamine
  • Patent number: 10727529
    Abstract: Lithium ion batteries containing fine, non-aggregated silicon particles have high initial voltage and exhibit good charge retention over large numbers of charge/discharge cycles when used with an electrolyte containing one or more amines, under conditions that silicon contained in the anode is only partially lithiated such that the ratio of Li:Si is less than or equal to 2.2:1.
    Type: Grant
    Filed: August 2, 2016
    Date of Patent: July 28, 2020
    Assignee: WACKER CHEMIE AG
    Inventors: Stefan Haufe, Daniel Braeunling
  • Patent number: 10541445
    Abstract: The present invention relates to an additive for a non-aqueous electrolyte solution including a compound represented by Formula 1 below, a non-aqueous electrolyte solution for a lithium secondary battery including the same, and a lithium secondary battery including the non-aqueous electrolyte solution. NC—(R)n—CN??[Formula 1] (in Formula 1, R is a cycloalkylene group having 3 to 6 carbon atoms in which at least one cyano group (—CN) is substituted or unsubstituted, a haloalkylene group having 2 to 5 carbon atoms in which at least one cyano group (—CN) is substituted or unsubstituted, or an alkylene group having 2 to 5 carbon atoms in which at least one cyano group (—CN) is substituted, and n is an integer of 1 to 5.
    Type: Grant
    Filed: October 24, 2016
    Date of Patent: January 21, 2020
    Assignee: LG Chem, Ltd.
    Inventors: Sung Hoon Yu, Yoo Sun Kang, Kyung Mi Lee
  • Patent number: 10411251
    Abstract: A novel lithium battery cathode, a lithium ion battery using the same and processes and preparation thereof are disclosed. The battery cathode is formed by force spinning. Fiber spinning allows for the formation of core-shell materials using material chemistries that would be incompatible with prior spinning techniques. A fiber spinning apparatus for forming a coated fiber and a method of forming a coated fiber are also disclosed.
    Type: Grant
    Filed: May 7, 2012
    Date of Patent: September 10, 2019
    Assignees: National Technology & Engineering Solutions of Sandia, LLC, The Board of Regents of the University of Texas System
    Inventors: Nelson S. Bell, Nancy A. Missert, Karen Lozano, Yatinkumar N. Rane
  • Patent number: 10199688
    Abstract: A one-step method to prepare a magnesium electrolyte salt is provided. According to the method, the magnesium electrolyte is obtained by reacting a Grignard reagent and a fluorinated aryl borane. In addition, formation of monomeric or dimeric magnesium ion is determined by the choice of the Grignard reagent. The magnesium electrolyte may be non-chlorinated and non-corrosive. A magnesium battery containing the magnesium electrolyte is also provided.
    Type: Grant
    Filed: December 22, 2015
    Date of Patent: February 5, 2019
    Assignee: Toyota Motor Engineering & Manufacturing North America, Inc.
    Inventors: Claudiu B. Bucur, John Muldoon
  • Patent number: 10115959
    Abstract: A method of manufacturing a non-aqueous liquid electrolyte secondary battery is to manufacture a non-aqueous liquid electrolyte secondary battery including a positive electrode mixture layer containing a lithium-containing transition metal oxide as a positive electrode active material. The manufacturing method includes: mixing the positive electrode active material and an aromatic nitrile compound such that a mass ratio of the aromatic nitrile compound to the positive electrode active material is not less than 0.1% by mass and not more than 4% by mass, to prepare a mixture; mixing the mixture, a conductive material, a binder, and a solvent to prepare a granular body; and disposing the granular body on a surface of a positive electrode collector to form at least a part of the positive electrode mixture layer.
    Type: Grant
    Filed: August 22, 2016
    Date of Patent: October 30, 2018
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Hideyuki Saka, Yukihiro Okada
  • Patent number: 10056651
    Abstract: The present invention provides a molten sodium secondary cell. In some cases, the secondary cell includes a sodium metal negative electrode, a positive electrode compartment that includes a positive electrode disposed in a molten positive electrolyte comprising Na—FSA (sodium-bis(fluorosulonyl)amide), and a sodium ion conductive electrolyte membrane that separates the negative electrode from the positive electrolyte. One disclosed example of electrolyte membrane material includes, without limitation, a NaSICON-type membrane. The positive electrode includes a sodium intercalation electrode. Non-limiting examples of the sodium intercalation electrode include NaxMnO2, NaxCrO2, NaxNiO, and NaxFey(PO4)z. The cell is functional at an operating temperature between about 100° C. and about 150° C., and preferably between about 110° C. and about 130° C.
    Type: Grant
    Filed: March 11, 2014
    Date of Patent: August 21, 2018
    Assignee: FIELD UPGRADING USA, INC.
    Inventors: Sai Bhavaraju, Mathew Robins
  • Patent number: 9752245
    Abstract: A non-aqueous Magnesium electrolyte comprising: (a) at least one organic solvent; (b) at least one electrolytically active, soluble, inorganic Magnesium (Mg) salt complex represented by the formula: MgaZbXc wherein a, b, and c are selected to maintain neutral charge of the molecule, and Z and X are selected such that Z and X form a Lewis Acid, and 1?a?10, 1?b?5, and 2?c?30. Further Z is selected from a group consisting of aluminum, boron, phosphorus, titanium, iron, and antimony; X is selected from the group consisting of I, Br, Cl, F and mixtures thereof. Rechargeable, high energy density Magnesium cells containing an cathode, an Mg metal anode, and an electrolyte of the above-described type are also disclosed.
    Type: Grant
    Filed: June 19, 2014
    Date of Patent: September 5, 2017
    Assignee: PELLION TECHNOLOGIES, INC.
    Inventors: Robert Ellis Doe, Ruoban Han, Yossef Gofer, Doron Aurbach, Nir Pour, Evgeny Sterenberg
  • Patent number: 9722280
    Abstract: An electrolyte composition (A) containing (i) at least one aprotic organic solvent; (ii) at least one conducting salt; (iii) at least one compound of formula (NC)(A1X1)C?C(X2A2)(CN) wherein X1 and X2 are independently from each other selected from N(R?), P(R1), O, and S, and A1 and A2 are selected from H or organic substituents; and electrochemical cells containing electrolyte composition (A).
    Type: Grant
    Filed: July 7, 2014
    Date of Patent: August 1, 2017
    Assignee: BASF SE
    Inventors: Frederick Francois Chesneau, Zoltan Baan, Boris Gaspar, Michael Schmidt, Arnd Garsuch, Hannes Wolf, Klaus Leitner, Christian Saffert, Wolfgang Klaus, Melanie Kuhl
  • Patent number: 9698415
    Abstract: A nonaqueous electrolyte battery includes a positive electrode containing an active material, a negative electrode, and a nonaqueous electrolyte, the negative electrode including a current collector and a negative electrode active material supported by the current collector, the negative electrode active material having a Li insertion potential not lower than 0.2V (vs. Li/Li+) and an average primary particle diameter not larger than 1 ?m, and a specific surface area of the negative electrode, excluding a weight of the current collector, as determined by the BET method falls within a range of 3 to 50 m2/g.
    Type: Grant
    Filed: November 11, 2013
    Date of Patent: July 4, 2017
    Assignee: KABUSHIKI KAISHA TOSHIBA
    Inventors: Norio Takami, Hiroki Inagaki
  • Patent number: 9673446
    Abstract: A lithium ion secondary battery containing a negative electrode active material containing Si and O as constituent elements and exhibiting excellent charge-discharge cycle characteristics. The lithium ion secondary battery has a positive electrode having a positive electrode material mixture layer, a negative electrode, a separator and a nonaqueous electrolyte containing at least an electrolyte salt and an organic solvent, where the negative electrode has a negative electrode material mixture layer containing a negative electrode active material containing Si and O as constituent elements (the atomic ratio x of O to Si is 0.5?x?1.5). The nonaqueous electrolyte contains the electrolyte salt at a concentration exceeding a concentration at which conductivity in the nonaqueous electrolyte containing the electrolyte salt and the organic solvent is maximized, and the conductivity at 25° C. is 6.5 to 16 mS/cm.
    Type: Grant
    Filed: February 28, 2012
    Date of Patent: June 6, 2017
    Assignee: HITACHI MAXELL, LTD.
    Inventors: Eri Kojima, Takahiro Furutani, Mitsuhiro Kishimi
  • Patent number: 9583751
    Abstract: A method is provided for fabricating a battery using an anode preloaded with consumable metals. The method forms an ion-permeable membrane immersed in an electrolyte. A preloaded anode is immersed in the electrolyte, comprising MeaX, where X is a material such as carbon, metal capable of being alloyed with Me, intercalation oxides, electrochemically active organic compounds, and combinations of the above-listed materials. Me is a metal such as alkali metals, alkaline earth metals, and combinations of the above-listed metals. A cathode is also immersed in the electrolyte and separated from the preloaded anode by the ion-permeable membrane. The cathode comprises M1YM2Z(CN)N.MH2O. After a plurality of initial charge and discharge operations are preformed, an anode is formed comprising MebX overlying the current collector in a battery discharge state, where 0?b<a.
    Type: Grant
    Filed: March 6, 2014
    Date of Patent: February 28, 2017
    Assignee: Sharp Laboratories of America, Inc.
    Inventors: Yuhao Lu, Long Wang, Jong-Jan Lee
  • Patent number: 9537131
    Abstract: A method is presented for fabricating an anode preloaded with consumable metals. The method provides a material (X), which may be one of the following materials: carbon, metals able to be electrochemically alloyed with a metal (Me), intercalation oxides, electrochemically active organic compounds, and combinations of the above-listed materials. The method loads the metal (Me) into the material (X). Typically, Me is an alkali metal, alkaline earth metal, or a combination of the two. As a result, the method forms a preloaded anode comprising Me/X for use in a battery comprising a M1YM2Z(CN)N.MH2O cathode, where M1 and M2 are transition metals. The method loads the metal (Me) into the material (X) using physical (mechanical) mixing, a chemical reaction, or an electrochemical reaction. Also provided is preloaded anode, preloaded with consumable metals.
    Type: Grant
    Filed: March 6, 2014
    Date of Patent: January 3, 2017
    Assignee: Sharp Laboratories of America, Inc.
    Inventors: Long Wang, Yuhao Lu, Jong-Jan Lee
  • Patent number: 9455473
    Abstract: An electrolyte composition for a magnesium electrochemical cell includes a magnesium salt dissolved in an ionic liquid. The ionic liquid includes an organic cation and a first boron cluster anion. The magnesium salt has a magnesium cation and a second boron cluster anion. The magnesium electrochemical cell includes an anode that contains elemental magnesium when charged, a cathode suitable for magnesium insertion or deposition, and the aforementioned electrolyte composition that is in ionic communication with the anode, the cathode, or both.
    Type: Grant
    Filed: October 14, 2015
    Date of Patent: September 27, 2016
    Assignee: Toyota Motor Engineering & Manufacturing North America, Inc.
    Inventors: Rana Mohtadi, Oscar Tutusaus, Fuminori Mizuno
  • Patent number: 9379374
    Abstract: In an example method, a transition metal precursor is selected so its transition metal has a diffusion rate that is slower than a diffusion rate of silicon. An aqueous mixture is formed by dissolving the precursor in an aqueous medium, and adding silicon particles to the medium. The mixture is exposed to a hydroxide, which forms a product including the silicon particles and a transition metal hydroxide precipitate. The product is dried. In an inert or reducing environment, silicon atoms of the silicon particles in the dried product are caused to diffuse out of, and form voids in and/or at a surface of, the particles. At least some silicon atoms react with the transition metal hydroxide in the dried product to form i) a SiOx (0<x?2) coating on the silicon particles and ii) the transition metal, which reacts with other silicon atoms to form silicides.
    Type: Grant
    Filed: July 15, 2014
    Date of Patent: June 28, 2016
    Assignee: GM Global Technology Operations LLC
    Inventors: Zhongyi Liu, Xingcheng Xiao, Michael K. Carpenter
  • Patent number: 9306253
    Abstract: Provided is an electrolyte solution capable of further increasing the output of a lithium air battery, the electrolyte solution for a lithium air battery having a total bonding strength between Li2O2 is no less than 0.14.
    Type: Grant
    Filed: June 15, 2012
    Date of Patent: April 5, 2016
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Hirofumi Nakamoto, Taishi Shiotsuki, Atsushi Shirasawa, Yushi Suzuki
  • Patent number: 9263768
    Abstract: Disclosed are a non-aqueous electrolyte comprising a lithium salt and a solvent, the electrolyte containing, based on the weight of the electrolyte, 10-40 wt % of a compound of Formula 1 or its decomposition product, and 1-40 wt % of an aliphatic nitrile compound, as well as an electrochemical device comprising the non-aqueous electrolyte.
    Type: Grant
    Filed: December 18, 2014
    Date of Patent: February 16, 2016
    Assignee: LG Chem, Ltd.
    Inventors: Young Soo Kim, Soon Ho Ahn, Joon Sung Bae, Cha Hun Ku, Soo Hyun Ha, Duk Hyun Ryu, Sei Lin Yoon
  • Patent number: 9231277
    Abstract: A nonaqueous electrolyte containing a monofluorophosphate and/or a difluorophosphate and a compound having a specific chemical structure or specific properties. The nonaqueous electrolyte can contain at least one of a saturated chain hydrocarbon, a saturated cyclic hydrocarbon, an aromatic compound having a halogen atom and an ether having a fluorine atom.
    Type: Grant
    Filed: June 28, 2012
    Date of Patent: January 5, 2016
    Assignee: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Ryoichi Kato, Hiroyuki Tokuda, Takashi Fujii, Minoru Kotato, Masahiro Takehara, Masamichi Onuki, Youichi Ohashi, Shinichi Kinoshita
  • Patent number: 9183995
    Abstract: A decomposition reaction of an electrolyte solution and the like caused as a side reaction of charge and discharge is minimized in repeated charge and discharge of a lithium ion battery or a lithium ion capacitor, and thus the lithium ion battery or the lithium ion capacitor can have long-term cycle performance. A negative electrode for a power storage device includes a negative electrode current collector and a negative electrode active material layer which includes a plurality of particles of a negative electrode active material. Each of the particles of the negative electrode active material has an inorganic compound film containing a first inorganic compound on part of its surface. The negative electrode active material layer has a film in contact with an exposed part of the negative electrode active material and part of the inorganic compound film. The film contains an organic compound and a second inorganic compound.
    Type: Grant
    Filed: May 21, 2013
    Date of Patent: November 10, 2015
    Assignee: Semiconductor Energy Laboratory Co., Ltd.
    Inventors: Nobuhiro Inoue, Kai Kimura, Sachiko Kataniwa, Ryota Tajima
  • Patent number: 9111694
    Abstract: The present invention provides an electric double layer capacitor having a high withstanding voltage, less deterioration, and excellent long-term reliability, especially an effect of suppressing expansion. The present invention relates to an electrolyte solution for an electric double layer capacitor. The solution comprises an electrolyte-salt-dissolving solvent (I) and an electrolyte salt (II). The electrolyte-salt-dissolving solvent (I) contains a fluorine-containing chain ether and a nitrile compound.
    Type: Grant
    Filed: October 21, 2011
    Date of Patent: August 18, 2015
    Assignee: DAIKIN INDUSTRIES, LTD.
    Inventors: Kenzou Takahashi, Meiten Koh, Mai Koyama, Emi Yamamoto
  • Patent number: 9065146
    Abstract: The invention relates to a nonaqueous electrolyte which comprises a nonaqueous organic solvent and a lithium salt dissolved therein, wherein the nonaqueous organic solvent contains at least one compound selected from the group consisting of acid anhydrides and carbonic esters having an unsaturated bond, and at least one compound selected from the group consisting of sulfonic compounds and fluorine-containing aromatic compounds having 9 carbon atoms or less; and a lithium secondary battery employing the same.
    Type: Grant
    Filed: June 22, 2009
    Date of Patent: June 23, 2015
    Assignee: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Masamichi Onuki, Minoru Kotato, Isao Konno, Shinichi Kinoshita, Noriko Shima
  • Patent number: 9039919
    Abstract: The present disclosure relates to gel-type polymer electrolyte for a dye-sensitized solar cell, a dye-sensitized solar cell comprising the gel-type polymer electrolyte, and a method for manufacturing the dye-sensitized solar cell.
    Type: Grant
    Filed: April 2, 2013
    Date of Patent: May 26, 2015
    Assignee: RESEARCH & BUSINESS FOUNDATION SUNGKYUNKWAN UNIVERSITY
    Inventors: Jong Hyeok Park, Kun Seok Lee
  • Publication number: 20150125761
    Abstract: The present invention includes [1] a nonaqueous electrolytic solution of an electrolyte salt dissolved in a nonaqueous solvent, the nonaqueous electrolytic solution containing from 0.001 to 5% by mass of a specified acyclic lithium salt in the nonaqueous electrolytic solution and being capable of improving electrochemical characteristics in a broad temperature range; and [2] an energy storage device including a positive electrode, a negative electrode, and a nonaqueous electrolytic solution of an electrolyte salt dissolved in a nonaqueous solvent, the nonaqueous electrolytic solution containing from 0.001 to 5% by mass of a specified acyclic lithium salt in the nonaqueous electrolytic solution.
    Type: Application
    Filed: May 13, 2013
    Publication date: May 7, 2015
    Applicant: UBE INDUSTRIES, LTD.
    Inventors: Kei Shimamoto, Yuichi Kotou, Shoji Shikita