Abstract: A lithium secondary battery includes a cathode including a cathode current collector, and a first cathode active material layer and a second cathode active material layer sequentially formed on the cathode current collector, an anode, and a separation layer interposed between the cathode and the anode. The first cathode active material layer and the second cathode active material layer include a first cathode active material particle and a second cathode active material particle, respectively, which have different compositions or crystalline structures from each other, and the first cathode active material particle and the second cathode active material particle include lithium metal oxides containing nickel. The second cathode active material particle has a single particle structure.

Abstract: A nonaqueous electrolyte secondary battery includes a negative electrode mixture layer formed on a negative electrode current collector. The negative electrode mixture layer includes a first layer and a second layer. The first layer is formed on the negative electrode current collector and includes a negative electrode active material and a first binding agent. The negative electrode active material in the first layer includes a carbon material A and a Si-containing compound. The second layer is formed on the first layer and includes a negative electrode active material and a second binding agent. The negative electrode active material in the second layer includes a carbon material B. The carbon material B has a tap density higher than a tap density of the carbon material A. A packing density of the second layer is lower than a packing density of the first layer.

Abstract: Provided are electrochemically active particles suitable for use as an active material in a cathode of a lithium ion electrochemical cell that include: a plurality of crystallites comprising a first composition comprising lithium, nickel, and oxygen; and a grain boundary between adjacent crystallites of the plurality of crystallites and comprising a second composition comprising lithium, nickel, and oxygen; wherein the grain boundary has a higher electrochemical affinity for lithium than the crystallites. The higher electrochemical affinity for Li leads to increased Li retention in the grain boundaries during or at charge relative to the bulk crystallites and stabilizes the structure of the grain boundaries and crystallites for improved cycling stability with no appreciable loss in capacity.

Abstract: An apparatus includes a battery stack including a plurality of alternating anodes and cathodes, wherein each of the anodes is positioned between first and second separators, and wherein a tab of the anode extends out from between the first and second separators, and an edge tape extending across a top of the first and second separators.

Abstract: A lithium battery includes a cathode including a cathode active material, an anode including an anode active material, and an organic electrolytic solution between the cathode and the anode. The anode active material includes a metal-based anode active material. The organic electrolytic solution includes a first lithium salt; an organic solvent; and a bicyclic sulfate-based compound represented by Formula 1 below: wherein, in Formula 1, each of A1, A2, A3, and A4 is independently a covalent bond, a substituted or unsubstituted C1-C5 alkylene group, a carbonyl group, or a sulfinyl group, wherein both A1 and A2 are not a covalent bond and both A3 and A4 are not a covalent bond.

Abstract: Disclosed are an electrolyte for a lithium secondary battery and a lithium secondary battery including the same. The electrolyte for the lithium secondary battery includes a lithium salt, a solvent component and an additive including one or more of the following compounds, wherein each of R1, R2 and R3 is independently hydrogen, an alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, an aryl group having 6 to 30 carbon atoms, or an arylalkyl group having 6 to 30 carbon atoms.

Abstract: Disclosed herein are electrolyte compositions comprising at least one electrolyte component comprising a cyclic carbonate, such as a fluoroethylene carbonate, and at least one additive comprising a 6-member ring heterocyclic sulfate, such as a 1,3 propylene sulfate. The disclosed electrolyte compositions can comprise additional electrolyte components, such as fluorinated acyclic carboxylic acid esters, and additional additives, such as lithium boron compounds, and cyclic carboxylic acid anhydrides, such as maleic anhydride. The improved battery performances, which include high temperature cycling conditions and/or room temperature stability, make these electrolyte compositions useful in electrochemical cells, such as lithium ion batteries.

Abstract: A lithium ion battery is provided that includes: a positive electrode; a negative electrode; a separator comprising a material having a melt temperature of greater than 150° C.; and an electrolyte including an organic solvent and a lithium salt. A method for sterilizing a lithium ion battery is also provided that includes: providing a lithium ion battery (particularly one as described herein); either charging or discharging the battery to a state of charge (SOC) of 20% to 100%; and steam sterilizing the battery to form a sterilized lithium ion battery.

Abstract: A battery comprises a cathode, an anode and an electrolyte. The cathode comprises a cathode active material which is capable of reversibly intercalating and deintercalating a plurality of first metal ions; and a conductive agent, wherein the particle size of the conductive agent graphite is less than 50 ?m and the crystallinity of the conductive agent graphite is no less than 90%.

Abstract: The present disclosure provides an electrolyte and an electrochemical energy storage device. The electrolyte comprises an electrolyte salt and an additive. The additive comprises a sulfonic ester cyclic quaternary ammonium salt and a dioxide heterocyclic compound. Under the combined effect of the sulfonic ester cyclic quaternary ammonium salt and the dioxide heterocyclic compound, a dense, uniform and stable passive film on a surface of each of the positive electrode film and the negative electrode film of the electrochemical energy storage device, thereby reducing the contact between the positive, negative electrode active materials and the electrolyte, thus avoiding the occurrence of continuous oxidation and reduction reaction of the electrolyte on the surface of each of the positive electrode film and the negative electrode film, so as to make the electrochemical energy storage device has excellent high temperature storage performance and high temperature cycle performance.

Abstract: Provided are electrochemically active secondary particles that provide excellent capacity and improved cycle life. The particles are characterized by selectively enriched grain boundaries where the grain boundaries are enriched Al. The enrichment with Al reduces impedance generation during cycling thereby improving capacity and cycle life. Also provided are methods of forming electrochemically active materials, as well as electrodes and electrochemical cells employing the secondary particles.

Abstract: An energy storage device can include a cathode, an anode, and a separator between the cathode and the anode, and an electrolyte where the electrolyte includes one or more additives and/or solvent components selected from vinylene carbonate (VC), vinyl ethylene carbonate (VEC), dimethylacetamide (DMAc), hydro fluorinated ether branched cyclic carbonate, a hydro fluorinated ether ethylene carbonate (HFEEC), hydro fluorinated ether (HFE), and fluorinated ethylene carbonate (FEC). The electrolyte may include a carbonate based solvent and one or more solvent components and/or one or more of vinylene carbonate (VC), vinyl ethylene carbonate (VEC), dimethylacetamide (DMAc), hydro fluorinated ether branched cyclic carbonate, a hydro fluorinated ether ethylene carbonate (HFEEC), hydro fluorinated ether (HFE), and fluorinated ethylene carbonate (FEC).

Abstract: A hybrid supercapacitor, including at least one negative electrode having a statically capacitive active material, an electrochemical redox-active material, or a mixture of them; at least one positive electrode having a statically capacitive active material, an electrochemical redox-active material, or a mixture of them; at least one separator situated between the at least one negative electrode and the at least one positive electrode; and an electrolyte mixture; with the provision that at least one electrode includes a statically capacitive active material, and at least one electrode includes an electrochemical, redox-active material; the electrolyte mixture being a liquid electrolyte mixture and including at least one liquid, aprotic, organic solvent, at least one conducting salt, and at least one at least partially halogenated, aromatic compound.

Abstract: Provided are novel electrolytes for use in rechargeable lithium ion cells containing high capacity active materials, such as silicon, germanium, tin, and/or aluminum. These novel electrolytes include one or more pyrocarbonates and, in certain embodiments, one or more fluorinated carbonates. For example, dimethyl pyrocarbonate (DMPC) may be combine with mono-fluoroethylene carbonate (FEC). Alternatively, DMPC or other pyrocarbonates may be used without any fluorinated carbonates. A weight ratio of pyrocarbonates may be between about 0% and 50%, for example, about 10%. Pyrocarbonates may be combined with other solvents, such as ethylene carbonate (EC), propylene carbonate (PC), dimethyl carbonate (DMC), diethyl carbonate (DEC), and/or ethyl-methyl carbonate (EMC). Alternatively, pyrocarbonates may be used without such solvents.

Abstract: There is provided a lithium ion secondary battery with a high capacity and having excellent cycle characteristics. The lithium ion secondary battery, including a positive electrode, a negative electrode, a separator and a nonaqueous electrolyte liquid. Here, the positive electrode comprises a positive electrode material in which a surface of particles of a positive electrode active material is coated with an Al-containing oxide. The Al-containing oxide has an average coating thickness of 5 to 50 nm. The positive electrode active material contained in the positive electrode material comprises a lithium cobalt oxide comprising Co and at least one kind of an element M1 selected from the group consisting of Mg, Zr, Ni, Mn, Ti and Al. The negative electrode comprises a material S including SiOx (0.5?x?1.

Abstract: A lithium-ion secondary battery includes a positive electrode, a negative electrode containing an active material, and an electrolytic solution, in which the active material contains, as constituent elements, Si, O, and at least one element M1 selected from Li, C, Mg, Al, Ca, Ti, Cr, Mn, Fe, Co, Ni, Cu, Ge, Zr, Mo, Ag, Sn, Ba, W, Ta, Na, and K, and the atomic ratio x (O/Si) of O to Si is 0.5?x?1.8.

Abstract: A lithium secondary battery has a positive electrode (1) containing a positive electrode active material having particles of lithium cobalt oxide, a negative electrode (2) containing a negative electrode active material having silicon particles, a separator interposed between the positive electrode (1) and the negative electrode (2), and a non-aqueous electrolyte. Particles of erbium hydroxide or erbium oxyhydroxide are adhered to a surface of the lithium cobalt oxide particles in a dispersed form.

Abstract: There is provided a positive electrode for a nonaqueous electrolyte secondary battery, the positive electrode being capable of improving the charge-discharge cycle characteristics of the nonaqueous electrolyte secondary battery. A positive electrode 12 of a nonaqueous electrolyte secondary battery 1 contains positive electrode active material particles. The positive electrode active material particles contain a lithium-containing transition metal oxide. The lithium-containing transition metal oxide has a crystal structure that belongs to the space group P63mc. A compound of at least one selected from the group consisting of boron, zirconium, aluminum, magnesium, titanium, and a rare-earth element is attached to surfaces of the positive electrode active material particles.

Abstract: There is provided an improvement for capacitors having activated carbon electrodes by the use of an electrolyte solution containing a carbonate of the formula RO(C?O)OR1 and a conductive salt such as a lithium salt or a quaternary ammonium salt at a concentration of from 0.6 to 3 mol/l.

Abstract: An energy storage device comprising: (A) an anode comprising graphite; and (B) an electrolyte composition comprising: (i) at least one carbonate solvent; (ii) an additive selected from CsPF6, RbPF6, Sr(PF6)2, Ba(PF6)2, or a mixture thereof; and (iii) a lithium salt.

Abstract: What is disclosed is a non-aqueous electrolyte for non-aqueous electrolyte battery including a non-aqueous solvent and at least lithium hexafluorophosphate as a solute. This electrolyte is characterized by containing at least one siloxane compound represented by the general formula (1) or the general formula (2). This electrolyte has a storage stability which is improved than electrolytes prepared by adding conventional siloxane compounds.

Abstract: A rechargeable lithium battery including a negative electrode including a negative active material, a positive electrode, and an electrolyte solution including an additive, wherein the negative active material includes a Si-based material included in an amount of about 1 to about 70 wt % based on the total amount of the negative electrode, and the additive includes fluoroethylene carbonate and a compound represented by Chemical Formula 1. In the above Chemical Formula 1, R1 to R3 are each independently a substituted or unsubstituted C2 to C5 alkylene group.

Abstract: The present invention provides an electrolytic solution for a nonaqueous electrolyte battery and a nonaqueous electrolyte battery having excellent cycle characteristics and high-temperature storage characteristics without causing hydrolysis of a fluorine-containing lithium salt, such as LiPF6, contained as a solute and containing a less amount of free fluorine ions, as well as a method of producing the electrolytic solution for a nonaqueous electrolyte battery.

Abstract: A rechargeable lithium ion battery including a negative active material, the negative active material including a carbon-based active material, and an electrolyte solution that includes a S?O-containing compound, the S?O-containing compound having a structure that is selected according to a G band/D band ratio of the carbon-based active material.

Abstract: An electrolyte includes a solvent and an electrolyte salt. The solvent contains at least one selected from ester compounds, lithium monofluorophosphate, and lithium difluorophosphate, and at least one selected from anhydrous compounds. The ester compounds are chain compounds having ester moieties, such as (—O—C(?O)—O—R), at both ends. The anhydrous compounds are cyclic compounds having, for example, a disulfonic anhydride group, (—S(O?)2—O—S(O?)2—).

Abstract: A lithium ion secondary battery that operates at a high voltage, has a high cycle life, and generates less gas, and an electrolytic solution for such a lithium ion secondary battery. An electrolytic solution for a non-aqueous energy storage device, comprising: a non-aqueous solvent; a lithium salt (A) having no boron atom; a predetermined lithium salt (B) containing a boron atom; and a compound (C) in which at least one of hydrogen atoms in an acid selected from the group consisting of proton acids having a phosphorus atom and/or a boron atom, sulfonic acids, and carboxylic acids is replaced with a substituent represented by formula (3): wherein R3, R4, and R5 each independently represent an organic group which has 1 to 10 carbon atoms and which may have a substituent.

Abstract: An improved electrolyte including a strontium additive suitable for lithium-sulfur batteries, a battery including the electrolyte, and a battery including a separator containing a strontium additive are disclosed. The presence of the strontium additive reduces sulfur-containing deposits on the battery anode, thereby providing a battery with relatively high energy density and good partial discharge performance.

Abstract: An improved lithium-sulfur battery containing a surface-functionalized carbonaceous material. The presence of the surface-functionalized carbonaceous material generates weak chemical bonds between the functional groups of the surface-functionalized carbonaceous material and the functional groups of the polysulfides, which prevents the polysulfide migration to the battery anode, thereby providing a battery with relatively high energy density and good partial discharge efficiency.

Abstract: The present disclosure relates to additives for electrolytes and preparation of aluminum-based, silicon-based, and bismuth-based additive compounds that can be used as additives or solutes in electrolytes and test results in various electrochemical devices. The inclusion of these aluminum, silicon, and bismuth compounds in electrolyte systems can enable rechargeable chemistries at high voltages that are otherwise unsuitable with current electrolyte technologies. These compounds are so chosen because of their beneficial effect on the interphasial chemistries formed at high potentials, such as 5.0 V class cathodes for Li-ion chemistries. The application of these compounds goes beyond Li-ion battery technology and covers any electrochemical device that employs electrolytes for the benefit of high energy density resultant from high operating voltages.

Abstract: The present disclosure relates to several families of commercially available oxirane compounds that can be used as electrolyte co-solvents, solutes, or additives in non-aqueous electrolyte and their test results in various electrochemical devices. The presence of these compounds can enable rechargeable chemistries at high voltages. These compounds were chosen for their beneficial effect on the interphasial chemistries that occur at high potentials on the classes of 5.0V cathodes used in experimental Li-ion systems.

Abstract: The present invention provides an electrolyte for a Li storage battery comprising a compound that can improve safety of a storage battery without causing the degradation in performances thereof and a Li storage battery comprising the electrolyte. The electrolyte comprises at least 1,1-diphenylethane the Li storage battery comprises the electrolyte. Particularly preferably provided are an electrolyte for a Li storage battery comprising 1,1-diphenylethane, a cyclic carbonate (e.g., ethylene carbonate), a chain carbonate (e.g., dimethyl carbonate, diethyl carbonate, ethyl methyl or ethylmethyl carbonate) and a Li salt and a Li storage battery comprising such an electrolyte.

Abstract: An electrolyte for a lithium battery, a lithium battery including the electrolyte, and a method of preparing the electrolyte for a lithium battery. The electrolyte for a lithium battery includes a non-aqueous organic solvent; and about 0.1 wt % to about 1 wt % of lithium nitrate (LiNO3) based on a total weight of the non-aqueous organic solvent. By using the electrolyte for a lithium battery, lifespan cycle properties of the lithium battery may be improved.

Abstract: Provided are a lithium secondary battery wherein gas generation associated with charging and discharging can be suppressed even in case where silicon and silicon oxide are contained as negative electrode active materials, and wherein deformation due to the gas generation can be suppressed even in case where a resin film is used as an outer package; and a method for manufacturing the lithium secondary battery. A lithium secondary battery comprises a negative electrode containing a negative electrode active material, a positive electrode containing a positive electrode active material, and an electrolytic solution used to immerse the negative electrode active material and the positive electrode active material, wherein the negative electrode active material contains silicon and silicon oxide that have been subjected to a reduction treatment.

Abstract: A nonaqueous electrolytic solution that can provide a battery that is low in gas generation, has a large capacity, and is excellent in storage characteristics and cycle characteristics contains an electrolyte and a nonaqueous solvent dissolving the electrolyte and further contains 0.001 vol % or more and less than 1 vol % of a compound represented by Formula (1) in the nonaqueous solvent. Alternatively, the nonaqueous electrolytic solution contains 0.001 vol % or more and less than 5 vol % of a compound represented by Formula (1) in the nonaqueous solvent and further contains at least one compound selected from the group consisting of cyclic carbonate compounds having carbon-carbon unsaturated bonds, cyclic carbonate compounds having fluorine atoms, monofluorophosphates, and difluorophosphates. In Formula (1), R1 to R3 each independently represent an alkyl group of 1 to 12 carbon atoms, which may be substituted by a halogen atom; and n represents an integer of 0 to 6.

Abstract: A lithium ion cell includes a cathode including a cathode active material having an operating voltage of 4.6 volts or greater; an anode including an anode material and a lithium additive including a lithium metal foil, lithium alloy, or an organolithium material; a separator; and an electrolyte.

Abstract: The invention relates to lithium 1-trifluoromethoxy-1,2,2,2-tetra-fluoroethanesulphonate, the use of lithium 1-trifluoromethoxy-1,2,2,2-tetra-fluoroethanesulphonate as electrolyte salt in lithium-based energy stores and also ionic liquids comprising 1-trifluoro-methoxy-1,2,2,2-tetrafluoro-ethanesulphonate as anion.

Abstract: An electrolyte may include compounds of general Formula IVA or IVB. where, R8, R9, R10, and R11 are each independently selected from H, F, Cl, Br, CN, NO2, alkyl, haloalkyl, and alkoxy groups; X and Y are each independently O, S, N, or P; and Z? is a linkage between X and Y, and at least one of R8, R9, R10, and R11 is other than H.

Abstract: A secondary lithium battery electrolyte including a lithium salt, a nonaqueous organic solvent, and an electrolyte additive represented by Formula 1: where n is an integer in the range of 1 to 4. A secondary lithium battery having excellent cycle and high temperature retention characteristics can be provided by using such secondary lithium battery electrolyte.

Abstract: A nonaqueous electrolyte includes: a nonaqueous solvent containing 0.1% by volume or more and not more than 50% by volume of at least one member selected from the group consisting of a halogen element-containing chain carbonate represented by the following formula (1) and a halogen element-containing cyclic carbonate represented by the following formula (2); and an electrolyte salt containing a compound represented by the following formula (3) in an amount of 0.001 moles/L or more and not more than 0.

Abstract: The invention relates to the use of lithium-2-pentafluoroethoxy-1,1,2,2-tetrafluoro-ethanesulfonate as a conductive salt in lithium-based energy stores and to electrolytes containing lithium-2-pentafluoroethoxy-1,1,2,2-tetrafluoro-ethanesulfonate.

Abstract: A process for producing a separator-electrolyte layer for use in a lithium battery, comprising: (a) providing a porous separator; (b) providing a quasi-solid electrolyte containing a lithium salt dissolved in a first liquid solvent up to a first concentration no less than 3 M; and (c) coating or impregnating the separator with the electrolyte to obtain the separator-electrolyte layer with a final concentration ?the first concentration so that the electrolyte exhibits a vapor pressure less than 0.01 kPa when measured at 20° C., a vapor pressure less than 60% of that of the first liquid solvent alone, a flash point at least 20 degrees Celsius higher than a flash point of the first liquid solvent alone, a flash point higher than 150° C., or no detectable flash point. A battery using such a separator-electrolyte is non-flammable and safe, has a long cycle life, high capacity, and high energy density.

Abstract: In an aspect, a lithium secondary battery including a compound as disclosed and described herein; and an electrolyte for a lithium secondary battery including a non-aqueous organic solvent and a lithium salt is provided.

Abstract: The present invention relates to an electrolyte having improved high-rate charge and discharge property, and a capacitor comprising the same, and more particularly to an electrolyte having improved high-rate charge and discharge property comprising an aromatic compound, which comprises at least one compound of the following Chemical Formula 1 to Chemical Formula 11 that can induce resonance effect of electron movement, and which is a substituted organic compound in which a functional group is present at a location that can structurally prevent local polarization effect, and the boiling point of which is 80° C. or higher, wherein R in the Chemical Formula 1 to Chemical Formula 11 is at least one functional group selected from the alkyl group consisting of methyl, ethyl, propyl and butyl, and a capacitor comprising the same.

Abstract: A method of manufacture an article of a cathode (positive electrode) material for lithium batteries. The cathode material is a lithium molybdenum composite transition metal oxide material and is prepared by mixing in a solid state an intermediate molybdenum composite transition metal oxide and a lithium source. The mixture is thermally treated to obtain the lithium molybdenum composite transition metal oxide cathode material.

Abstract: A lithium secondary battery including a positive electrode including a positive electrode active material capable of intercalating and deintercalating lithium ions, a negative electrode including a negative electrode active material capable of intercalating and deintercalating lithium ions, and a nonaqueous electrolytic solution, wherein the positive electrode active material includes an active material capable of intercalating or deintercalating lithium ions at a potential of 4.5 V or more, and the nonaqueous electrolytic solution includes a particular fluorine-containing ether compound.

Abstract: A nonaqueous electrolyte secondary battery includes a positive electrode having a positive-electrode active material, a negative electrode having a negative-electrode active material, and a nonaqueous electrolytic solution having a nonaqueous solvent dissolving a solute. The negative-electrode active material includes powdered silicon and/or a silicon alloy, the nonaqueous electrolytic solution includes additives composed of at least one fluorinated lithium phosphate selected from the group consisting of lithium monofluorophosphate, lithium difluorophosphate, and lithium trifluorophosphate and a diisocyanate compound, and the nonaqueous solvent includes a chain carbonate compound.

Abstract: A non-aqueous electrolyte including (i) a compound represented by the general formula X—R—SO2F??(1) where R is a C1-12 linear or branched alkylene group optionally containing an ether bond and optionally hydrogen atoms of the alkylene group are partly substituted by a fluorine atom(s); and X is a carboxylic acid derivative group), (ii) a non-aqueous solvent and (iii) an electrolyte salt.

Abstract: The invention relates to lithium-2-methoxy-1,1,2,2-tetrafluoro-ethanesulfonate, to the use thereof as conductive salt in lithium-based energy accumulators, and ionic liquids comprising 2-methoxy-1,1,2,2-tetrafluoro-ethanesulfonate as an anion.

Abstract: An electrolyte for a lithium ion secondary battery and a lithium ion secondary battery including the same are provide. The electrolyte includes a non-aqueous organic solvent, a lithium salt which is dissolved in the non-aqueous solvent and a additive shown as general formula I. Wherein R1, R2 and R3 are each independently selected from H, alkyl group including from 1 to 12 carbon atoms, cycloalkyl group including from 3 to 8 carbon atoms and aromatic group including 6 to 12 carbon atoms; n represents an integer from 0 to 7. This additive in electrolyte can passivate cathode and anode effectively, restrain their reaction with electrolyte, reduce gases generation and battery's expansion in high temperature surrounding, provide as safety lithium ion secondary batteries.

Abstract: Provided are an additive for a lithium battery electrolyte, wherein the additive is an ethylene carbonate based compound represented by the following Formula 1 or 2, an organic electrolyte solution including the additive, and a lithium battery including the organic electrolyte solution: in the above Formulae, R1, R2, R3, and R4 are each independently a non-polar functional group or a polar functional group, the polar functional group including a heteroatom belonging to groups 13 to 16 of the periodic table of elements, and one or more of R1, R2, R3, and R4 are the polar functional groups.