Having Means To Accommodate Electrode Expansion Patents (Class 429/66)
  • Publication number: 20010038941
    Abstract: The present invention provides a nonaqueous electrolyte secondary cell having a construction wherein a flat spiral-shaped electrode assembly, in which positive and negative electrodes capable of intercalating and deintercalating lithium ions are wound with a separator disposed therebetween, is enclosed in a casing which changes shape with a slight increase in the internal pressure of the cell, a gel polymer containing a nonaqueous liquid electrolyte exists between the positive electrode and the separator, bonding the positive electrode and the separator, and the adhesive strength between the separator and the positive electrode is 0.02 N/10 mm or higher. In the above construction of a nonaqueous electrolyte secondary cell, even when the cell is overcharged and gas is generated in the cell, explosion caused by detachment of the bonded portion of the positive electrode and the separator is prevented.
    Type: Application
    Filed: March 30, 2001
    Publication date: November 8, 2001
    Applicant: SANYO ELECTRIC CO., LTD.
    Inventor: Taizo Sunano
  • Patent number: 6284403
    Abstract: A closure assembly for sealed batteries in which explosion-proof features are incorporated. A metal plate (8) having a hole (81), an insulating resin sheet (9), a metal thin sheet (6b), an insulating sheet (4) having an air hole (41), a metal guide plate (3) having a hole (31), and a metal cap (1b) are laid upon one another within an insulating gasket (5b). Metal plate (8) and metal guide plate (3) are in contact with each other and electrically connected. Upon a build-up of pressure within the battery, the insulating-resin sheet (9) expands and ruptures, whereby a narrow part (69) provided in the metal thin sheet (6b) positioned above the insulating resin sheet (9) breaks, thus cutting supply of electric current.
    Type: Grant
    Filed: August 17, 1999
    Date of Patent: September 4, 2001
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Shinji Tsurutani, Seiichi Mizutani, Hideaki Yoshio, Kenjin Masumoto, Hideyuki Kobayashi
  • Publication number: 20010016282
    Abstract: A gastight-sealed alkaline nickel/metal hydride storage battery in the form of a button cell having positive and negative electrodes which are arranged in the cell case and separated by a separator. Both electrodes have a support and conductor framework, which consists of a porous metal foam or metal felt, the positive electrode having a metallic region which is free of active material on the side bearing against the cell case.
    Type: Application
    Filed: January 29, 2001
    Publication date: August 23, 2001
    Applicant: Varta Geratebatterie, GmbH
    Inventors: Manfred Kilb, Eduard Pytlik, Dejan Ilic, German Schulz, Thomas Koke
  • Publication number: 20010014417
    Abstract: Cracking or the like is prevented from being formed in an outer wall of a container of a closed battery module whose internal space is divided by partitions. Each partition dividing the internal space of the container of the closed battery module is provided with a deformable portion that deforms before a stress greater than an allowable value is caused in a container outer wall by load applied to the container. When a load is applied to the module container, the partitions dividing the container internal space restrict deformation of the container outer walls, so that great stress is likely to occur in the outer walls. However, as the deformable portion of a partition deforms due to such load, the stress caused in the container outer walls decreases, so that formation of a crack or the like in the container outer walls becomes less likely.
    Type: Application
    Filed: February 15, 2001
    Publication date: August 16, 2001
    Inventor: Toyohiko Etou
  • Publication number: 20010008724
    Abstract: In order to be able to produce prismatic, unsealed nickel-cadmium batteries without limiting the amount of electrolyte, employing fiber-structure electrodes which, while retaining the above-described advantages over conventional nicad batteries in terms of the charging voltages, are compatible with these conventional products by not requiring higher charging voltages yet involve less maintenance in connection with water consumption, the invention proposes the manufacture of an electrode system for nicad batteries under at least partial utilization of fiber-structure electrodes, for which purpose positive and negative lamellar electrodes are produced and, with separator material interlayered, stacked in alternating fashion in a defined number to form an electrode assembly, with the respective equidirectional electrodes mutually connected by means of connecting straps; the said electrode assembly is pressed and positionally locked between mechanical clamping elements into a unitized, coplanar, undeformable bloc
    Type: Application
    Filed: February 5, 1999
    Publication date: July 19, 2001
    Inventors: DETLEF OHMS, WILLI KITZHOFER, UWE SCHAFFRATH, GABOR BENCZUR-URMOSSY
  • Patent number: 6218039
    Abstract: A fuel cell assembly includes a stack assembly having fuel cell plates and a frame having a bottom section and at least two side sections integrally formed with the bottom section. The stack assembly is placed on the frame bottom section, and one or more fasteners are used to attach the frame to an upper portion of the stack assembly to apply a compressive force on the stack assembly.
    Type: Grant
    Filed: August 25, 1999
    Date of Patent: April 17, 2001
    Assignee: Plug Power, Inc.
    Inventors: Kevin L. Mease, Adam K. Brunner, Larry A. Pitts, Alan F. Winslow
  • Patent number: 6183903
    Abstract: A plastic battery container for a recombinant sealed lead-acid battery having reduced end wall deflection, the end wall comprising a base portion from which extends a series of integrally molded ribs disposed at approximately +/−45° to the horizontal, substantially all intersection points of the ribs with the base portion having a rounded character to enhance processing characteristics.
    Type: Grant
    Filed: February 3, 1998
    Date of Patent: February 6, 2001
    Assignee: GNB Technologies, Inc.
    Inventors: Kris Campbell, John E. Kopala
  • Patent number: 6162559
    Abstract: This invention relates to a battery cell housing for valve-regulated, lead-acid batteries. The housing includes a tray base, vertical side walls attached to the base so that the tray base and vertical side walls define a single battery compartment. A top wall is secured to the side walls and has at least one opening. A compression member is positioned in the battery compartment beneath the top wall for movement between the side walls so as to compress a stack of battery cells stacked in a horizontal position in the battery compartment. At least one internally threaded member is included with the top wall and is aligned with at least one opening. At least one compression bolt extends through the top wall opening and contacts the compression member while threadedly engaging at least one internally threaded member.
    Type: Grant
    Filed: September 21, 1998
    Date of Patent: December 19, 2000
    Assignee: Douglas Battery Manufacturing Company
    Inventors: David G. Vutetakis, Christopher R. Cestone, Stanley K. Wilkie
  • Patent number: 6132896
    Abstract: An electrochemical cell has a silver vanadium oxide cathode material formed into a pellet shape which expands as the cell is discharged. A cathode current collector circumferentially surrounds the cathode pellet and is in contact with the peripheral edge of the cathode pellet to prevent peripheral cathode expansion. The peripheral cathode current collector maintains a stable cell impedance during cell discharge. The cell has a D-shaped housing in which the cathode is disposed adjacent to a first interior surface, and a lithium anode is disposed adjacent to a second interior surface.
    Type: Grant
    Filed: August 11, 1998
    Date of Patent: October 17, 2000
    Assignee: Medtronics, Inc.
    Inventors: Walter C. Sunderland, Anthony W. Rorvick, Donald R. Merritt, Craig L. Schmidt, David P. Haas
  • Patent number: 6120930
    Abstract: An improved electrochemical generator is disclosed. The electrochemical generator includes a thin-film electrochemical cell which is maintained in a state of compression through use of an internal or an external pressure apparatus. A thermal conductor, which is connected to at least one of the positive or negative contacts of the cell, conducts current into and out of the cell and also conducts thermal energy between the cell and thermally conductive, electrically resistive material disposed on a vessel wall adjacent the conductor. The thermally conductive, electrically resistive material may include an anodized coating or a thin sheet of a plastic, mineral-based material or conductive polymer material. The thermal conductor is fabricated to include a resilient portion which expands and contracts to maintain mechanical contact between the cell and the thermally conductive material in the presence of relative movement between the cell and the wall structure.
    Type: Grant
    Filed: July 25, 1997
    Date of Patent: September 19, 2000
    Assignees: 3M Innovative Properties Corporation, Hydro-Quebec
    Inventors: Roger Rouillard, Michael K. Domroese, Joseph A. Hoffman, David D. Lindeman, Joseph-Robert-Gaetan Noel, Vern E. Radewald, Michel Ranger, Anthony Sudano, Jennifer L. Trice, Thomas A. Turgeon
  • Patent number: 6117584
    Abstract: A thermal conductor for use with an electrochemical energy storage device is disclosed. The thermal conductor is attached to one or both of the anode and cathode contacts of an electrochemical cell. A resilient portion of the conductor varies in height or position to maintain contact between the conductor and an adjacent wall structure of a containment vessel in response to relative movement between the conductor and the wall structure. The thermal conductor conducts current into and out of the electrochemical cell and conducts thermal energy between the electrochemical cell and thermally conductive and electrically resistive material disposed between the conductor and the wall structure. The thermal conductor may be fabricated to include a resilient portion having one of a substantially C-shaped, double C-shaped, Z-shaped, V-shaped, O-shaped, S-shaped, or finger-shaped cross-section.
    Type: Grant
    Filed: July 25, 1997
    Date of Patent: September 12, 2000
    Assignee: 3M Innovative Properties Company
    Inventors: Joseph A. Hoffman, Michael K. Domroese, David D. Lindeman, Vern E. Radewald, Roger Rouillard, Jennifer L. Trice
  • Patent number: 6117583
    Abstract: The invention concerns a lead-acid battery having all the surfaces of all the electrodes under high pressure and their circumferences kept unchanged by support from mechanically rigid cell walls such that only the thickness of the electrodes is allowed to expand under strong resilient load during the discharge and return during charge. The pressure is 0.49-10.sup.5 -9.81-10.sup.5 Pa (0.5-10 kp/cm.sup.2), and may be obtained by separators or by springs applied to the outer sides of the cell container and may be changed for increased or decreased capacity. The construction of the tubular battery design, prevents material losses due to sludging and a long working life is obtained, since also a totally corroded lead conductor under high pressure may function as a current conductor. The rigid outer containers also allow high liquid pressure and thus a high oxygen solubility and oxygen recombination for sealed cells.
    Type: Grant
    Filed: July 22, 1997
    Date of Patent: September 12, 2000
    Assignee: Advanced Power Devices, Inc.
    Inventors: Ove Nilsson, Erik Sundberg
  • Patent number: 6087036
    Abstract: An improved electrochemical energy storing device includes a number of thin-film electrochemical cells which are maintained in a state of compression through use of an internal or an external pressure apparatus. A thermal conductor, which is connected to at least one of the positive or negative contacts of each electrochemical cell, conducts current into and out of the electrochemical cells and also conducts thermal energy between the electrochemical cells and thermally conductive material disposed on a wall structure adjacent the conductors. The wall structure includes electrically resistive material, such as an anodized coating or a thin film of plastic. The thermal conductors are fabricated to include a spring mechanism which expands and contacts to maintain mechanical contact between the electrochemical cells and the thermally conductive material in the presence of relative movement between the electrochemical cells and the wall structure.
    Type: Grant
    Filed: July 25, 1997
    Date of Patent: July 11, 2000
    Assignees: 3M Innovative Properties Company, Hydro-Quebec Corporation
    Inventors: Roger Rouillard, Michael K. Domroese, Michel Gauthier, Joseph A. Hoffman, David D. Lindeman, Joseph-Robert-Gaetan Noel, Vern E. Radewald, Michel Ranger, Jean Rouillard, Toshimi Shiota, Philippe St-Germain, Anthony Sudano, Jennifer L. Trice, Thomas A. Turgeon
  • Patent number: 6040085
    Abstract: The subject invention discloses apparatus and methods to provide compression of an electrochemical cell independent of atmospheric pressure. One aspect of this invention is directed towards a lithium ion cell assembly which is surrounded by a layer of material under tension, so that the material applies pressure which compresses the cell to enhance contact between the anode, separator, and cathode layers. Specifically, a heat shrink material (material which reduces in size, or contracts in at least one dimension of a three-dimensional conformation, due to the application of heat) is provided about a laminar battery and shrunk in situ to provide a battery package. Another embodiment of this invention is directed towards a lithium ion cell asembly in which a sealed package contains both the battery and a spring element. The spring element within the package applies pressure to the battery to compress it and improve contact between the anode, separator, and cathode layers.
    Type: Grant
    Filed: March 4, 1997
    Date of Patent: March 21, 2000
    Assignee: Valence Technology, Inc.
    Inventors: S. Scot Cheu, Russell D. Moulton
  • Patent number: 6007935
    Abstract: Rechargeable generator consisting of an anode of an alkali metal or a malleable alkali alloy, at least one polymer electrolyte which is conductive with respect to alkali cations and acts as separator, as well as at least one cathode which is reversible to cations of alkali metal and its current collector. The anode comprises a thin metallic sheet, which includes at the surface thereof a passivation film SEI capable of limiting reaction between the metal and the polymer electrolyte and to exchange lithium ions. The polymer electrolyte comprises a homogeneous separator which is capable of transmitting a pressure on the anode to resist against the dendridic strain of the metal of the anode by undergoing a rate of deformation lower than 35% of its thickness.
    Type: Grant
    Filed: April 23, 1997
    Date of Patent: December 28, 1999
    Assignee: Hydro-Quebec
    Inventors: Michel Gauthier, Andre Belanger, Alain Vallee
  • Patent number: 5972534
    Abstract: A cell contains a device for inserting a stack of electrodes and holding it in place. This device enables a stack of electrodes to be inserted and held in place in a container having a base and receiving a lid, the stack having two opposite plane faces and the container having two opposite plane walls. The device comprises two tapes connected by a central blade and is disposed between the plane faces of the stack and the plane walls of the container. The two tapes form elastic cylindrical sectors, advantageously parabolic in shape, with the concave side facing outwards when fitted.
    Type: Grant
    Filed: September 30, 1997
    Date of Patent: October 26, 1999
    Assignee: Saft
    Inventor: Eric Pasquier
  • Patent number: 5945234
    Abstract: This invention pertains to electrode cans and metal air electrochemical cells made with the electrode cans. The invention provides improved structure, and methods for making the outer edge of the closed end of the can at the joinder of the closed end of the can with an side wall extending from the closed end. A substantially flat portion of the outer surface of the closed end of the can extends outwardly of the inner surface of the side wall. The electrochemical cells are assembled using improved assembly methods. Button-type electrochemical cells made using the invention are free of the inward dishing common to especially cathode cans in such button cells.
    Type: Grant
    Filed: January 6, 1997
    Date of Patent: August 31, 1999
    Assignee: Rayovac Corporation
    Inventor: John David Burns
  • Patent number: 5916709
    Abstract: An improved bipolar lead-acid battery including a novel "cup" design of a bipolar plate, a resilient sliding rim seal for each battery cell, spring conductors for achieving both high compression and current collection, unique current collecting plates, and a self-sealing venting port on the external container.
    Type: Grant
    Filed: July 30, 1996
    Date of Patent: June 29, 1999
    Assignee: Bipolar Power Corporation
    Inventors: Jeffrey L. Arias, Julio A. Aldecoa
  • Patent number: 5853914
    Abstract: A rechargeable lithium battery comprising at least a cathode, a separator, an anode, and an electrolyte or electrolyte solution integrated in a battery housing, characterized in that said rechargeable lithium battery is provided with a pressure means comprising a polymer gel for pressing said anode and cathode.
    Type: Grant
    Filed: September 6, 1996
    Date of Patent: December 29, 1998
    Assignee: Canon Kabushiki Kaisha
    Inventor: Soichiro Kawakami
  • Patent number: 5804333
    Abstract: A coin-shaped lithium battery is disclosed. The coin-shaped lithium battery comprises a battery can containing therein an anode pellet composed of lithium or lithium alloy and a cathode pellet which are arranged to face each other with a separator provided between the pellets. At least one of the anode pellet and the cathode pellet has its central part swollen to form a curved surface. The battery can is elastically deformed to be aligned with the curved surface. In the coin-shaped lithium battery, total height of the anode pellet and the cathode pellet in outer rim part is smaller than total height in central part by 4 to 12%.
    Type: Grant
    Filed: March 31, 1997
    Date of Patent: September 8, 1998
    Assignee: Sony Corporation
    Inventors: Masatsugu Shioda, Koichi Miyoda
  • Patent number: 5716729
    Abstract: An electrochemical cell has a cathode material formed into a pellet shape which expands as the cell is discharged. A cathode current collector circumferentially surrounds the cathode pellet and is in contact with the peripheral edge of the cathode pellet to prevent peripheral cathode expansion. The peripheral cathode current collector maintains a stable cell impedance during cell discharge.
    Type: Grant
    Filed: April 26, 1996
    Date of Patent: February 10, 1998
    Assignee: Medtronic, Inc.
    Inventors: Walter C. Sunderland, Anthony W. Rorvick, Donald R. Merritt, Craig L. Schmidt, David P. Haas
  • Patent number: 5660946
    Abstract: Sealed lead-acid cells and batteries include an expandable cover capable of accommodating the grid growth which occurs in service, the expandable cover comprises a first region which expands outwardly toward a second region and a flange which defines the terminal opening, and the cells or batteries include a terminal cover sealing assembly comprising inner-and outer-cell sealing members which together form an annulus in which the flange is seated and retain one or both include resilient seals such as an O-ring that provide a terminal-cover seal.
    Type: Grant
    Filed: July 2, 1996
    Date of Patent: August 26, 1997
    Assignee: GNB Technologies, Inc.
    Inventors: William H. Kump, Deborah Huke, Edward Mattan
  • Patent number: 5654110
    Abstract: A thin profile battery includes: a) an anode, b) a cathode positioned adjacent to the anode; c) a separator and electrolyte between the anode and the cathode; d) a conductive first terminal housing member in electrical contact with one of the anode or the cathode, the first terminal housing member having a surrounding periphery and a concave central portion intermediate of its surrounding periphery; e) a conductive second terminal housing member in electrical contact with the other of the anode or the cathode, the second terminal housing member having a surrounding periphery and a concave central portion intermediate of its surrounding periphery which is opposingly concave to the concave central portion of the first terminal housing member; and f) the first and second terminal housing members being insulatingly joined and sealed at their respective peripheries to form an enclosed housing which retains and protects the anode, cathode, separator and electrolyte, with the concave central portions of the first an
    Type: Grant
    Filed: June 24, 1996
    Date of Patent: August 5, 1997
    Assignee: Micron Communications, Inc.
    Inventors: John R. Tuttle, Mark E. Tuttle
  • Patent number: 5650241
    Abstract: A metal-air battery assembly having plurality of free standing metal-air cells forming a cell group within a battery case assembly. Each free standing cell has flexible, compressible walls capable of containing electrolyte, the walls comprising air cathodes including cathode current distributors. Each cell has a split anode assembly and current. The anode assembly has one or more reactive anode fuel plates and an anode current collector. Each of the cells is free standing and easily replaced. The battery case assembly has a mechanism for compressing the cells when the lid is closed and releasing the cell group for servicing when the lid is open.
    Type: Grant
    Filed: November 30, 1995
    Date of Patent: July 22, 1997
    Inventor: Richard L. McGee
  • Patent number: 5629107
    Abstract: A coin-shaped lithium battery is disclosed. The coin-shaped lithium battery comprises a battery can containing therein an anode pellet composed of lithium or lithium alloy and a cathode pellet which are arranged to face each other with a separator provided between the pellets. At least one of the anode pellet and the cathode pellet has its central part swollen to form a curved surface. The battery can is elastically deformed to be aligned with the curved surface. In the coin-shaped lithium battery, total height of the anode pellet and the cathode pellet in outer rim part is smaller than total height in central part by 4 to 12%.
    Type: Grant
    Filed: January 23, 1996
    Date of Patent: May 13, 1997
    Assignee: Sony Corporation
    Inventors: Masatsugu Shioda, Koichi Miyoda
  • Patent number: 5618641
    Abstract: The Bipolar Battery Construction disclosed and claimed above solves the problem of constructing a bipolar battery (11,12) with a desired, uniform, constant, pressure between each bipolar plate (20) and separator (30) in the battery cell stack (48). The provision of such a pressure dramatically increases battery life, and increases the power of the cell stack (48). Compressive force is provided by spring-loaded clamping internal to the battery (11,12). A sealed battery case (52) provides common confinement of gases and vapors from all cells (58), minimizing battery sealing requirements. An inhibitor device (80,81) is provided for minimizing or eliminating leakage current between adjacent battery cells (58) through electrolyte (32), avoiding self-discharge of the cells (58). Insulation (54) minimize temperature gradients in the cell stack (48) which assures uniform and stable performance.
    Type: Grant
    Filed: December 3, 1993
    Date of Patent: April 8, 1997
    Assignee: Bipolar Power Corporation
    Inventor: Jeffrey L. Arias
  • Patent number: 5614332
    Abstract: A method and apparatus for increasing charging and discharging efficiency of a battery. A battery is provided having electrodes and an electrolyte. The electrodes are connected to a charging or discharging circuit and at least one electrode is mechanically manipulated during the charging or discharging.
    Type: Grant
    Filed: August 5, 1996
    Date of Patent: March 25, 1997
    Inventors: Richard Pavelle, Ronald M. Latanision, Paul Burstein
  • Patent number: 5580674
    Abstract: A button-type battery includes: a) an anode; b) a cathode positioned adjacent to the anode; c) a separator and electrolyte between the anode and the cathode; d) a conductive first terminal housing member in electrical contact with one of the anode or the cathode, the first terminal housing member having a surrounding periphery and a concave central portion intermediate of its surrounding periphery; e) a conductive second terminal housing member in electrical contact with the other of the anode or the cathode, the second terminal housing member having a surrounding periphery and a concave central portion intermediate of its surrounding periphery which is opposingly concave to the concave central portion of the first terminal housing member; and f) the first and second terminal housing members being insulatingly joined and sealed at their respective peripheries to form an enclosed housing which retains and protects the anode, cathode, separator and electrolyte, with the concave central portions of the first and
    Type: Grant
    Filed: October 11, 1995
    Date of Patent: December 3, 1996
    Assignee: Micron Communication, Inc.
    Inventors: John R. Tuttle, Mark E. Tuttle
  • Patent number: 5580677
    Abstract: The present invention provides a unit battery of sealed alkaline storage battery comprising a plurality of cells each of which comprises a container in which are inserted an alkali electrolyte and an electrode group comprising a plurality of positive plates and a plurality of negative plates with separators provided between the adjacent plates and which is sealed by a cap provided with a safety valve, the adjacent cells being electrically connected, wherein at least a part of the outermost portion of the electrode group in the cell contacts with the container, the adjacent cells contact with each other at at least a part of their container and a space through which air can pass in at least one direction is provided between the adjacent cells, the unit battery being constrained by holders at a part or the whole surface of both ends in the direction of arranging of the cells.
    Type: Grant
    Filed: December 22, 1993
    Date of Patent: December 3, 1996
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Nobuyasu Morishita, Shinji Hamada, Hiromu Matsuda, Munehisa Ikoma
  • Patent number: 5567541
    Abstract: The state of charge of electrochemical batteries of different kinds is determined by measuring the incremental change in the total volume of the reactive masses in the battery. The invention is based on the principle that all electrochemical batteries, either primary or secondary (rechargeable), produce electricity through a chemical reaction with at least one electrode, and the chemical reactions produce certain changes in the composition and density of the electrode. The reactive masses of the electrodes, the electrolyte, and any separator or spacers are usually contained inside a battery casing of a certain volume. As the battery is used, or recharged, the specific volume of at least one of the electrode masses will change and, since the masses of the materials do not change considerably, the total volume occupied by at least one of the electrodes will change. These volume changes may be measured in many different ways and related to the state of charge in the battery.
    Type: Grant
    Filed: March 21, 1995
    Date of Patent: October 22, 1996
    Assignee: Lockheed Idaho Technologies Company
    Inventor: S. Zia Rouhani
  • Patent number: 5558958
    Abstract: A flexible spacer for positioning a cell element in a cell compartment of a container of a storage battery includes a sheet member folded over on itself to a U-shaped configuration with the space between opposing surfaces of the sheet member defining a compartment for receiving the cell element, enabling the cell element and the spacer to be inserted as a unit into the cell compartment, the opposing surfaces of the sheet member each including a ribbed section that flexes upon insertion of the spacer and element into the cell, automatically adjusting for differences in cell element thickness.
    Type: Grant
    Filed: October 13, 1994
    Date of Patent: September 24, 1996
    Assignee: Globe-Union, Inc.
    Inventors: Edward N. Mrotek, Norbert Schilling
  • Patent number: 5532086
    Abstract: An anode for use in an electrochemical cell comprising a current collector layer having a thickness less than about 10 mils, and desirably less than about 4 mils, and a rigid support extending adjacent one side of the current collector layer so that the current collector layer is sandwiched between the anodic layer of the anode and the rigid support. The rigid support maintains the current collector layer in the original configuration of the current collector layer during discharge and recharge cycles of the cell. A cell containing the anode is also disclosed. The rigid support for the anode current collector can be mounted in the electrochemical cell case so as to allow for the release from the cell of gas produced at the anode.
    Type: Grant
    Filed: June 30, 1994
    Date of Patent: July 2, 1996
    Assignee: AER Energy Resources, Inc.
    Inventors: William C. Thibault, Edward S. Buzzrelli
  • Patent number: 5510204
    Abstract: A galvanic cell employing an anode electrode that is disposed within the cathode electrode, and that extends up to at least 80 percent of the height of the cathode electrode.
    Type: Grant
    Filed: February 13, 1995
    Date of Patent: April 23, 1996
    Assignee: Eveready Battery Company, Inc.
    Inventor: Lewis F. Urry
  • Patent number: 5486431
    Abstract: A button-type battery includes: a) an anode; b) a cathode positioned adjacent to the anode.
    Type: Grant
    Filed: March 2, 1994
    Date of Patent: January 23, 1996
    Assignee: Micron Communications, Inc.
    Inventors: John R. Tuttle, Mark E. Tuttle
  • Patent number: 5480742
    Abstract: An electrochemical cell including a housing containing a cathode electrode, an anode electrode, electrode terminals, and a liquid electrolyte; characterized in that the electrodes are in the form of unbonded granules located in separate compartments within the housing and separated by a separator; the granules filling their respective compartments and being subjected to a compressive force to produce good electrical contact between their outer surfaces; the electrolyte filling the interstitial spaces between the granules.
    Type: Grant
    Filed: May 9, 1994
    Date of Patent: January 2, 1996
    Inventors: Mordechai Erez, Israel Reshef
  • Patent number: 5474858
    Abstract: A non-aqueous electrochemical cell comprising an active metal anode, an organic electrolyte and a cathode comprising a minor amount of a desiccant which is insoluble in the organic electrolyte and non-reactive during cell discharge. The resulting cell has been found to be resistant to internal gas generation. Such a desiccant is particularly useful in lithium/manganese dioxide cells.
    Type: Grant
    Filed: November 23, 1993
    Date of Patent: December 12, 1995
    Assignee: Medtronic, Inc.
    Inventor: Donald R. Merritt
  • Patent number: 5466354
    Abstract: Accumulated dimensional variations in fuel cells and electrolysis cell assemblies can reduce the efficiency of the assembly and provide leakage paths for fuel and oxidant. A metal compression pad comprised of a metal having an elastic strain of about 3% to about 40% at about 2,500 psig can compensate for component dimensional variations and improve inter-cell conductivity at pressures up to and exceeding about 10,000 psig.
    Type: Grant
    Filed: September 20, 1994
    Date of Patent: November 14, 1995
    Assignee: United Technologies Corporation
    Inventors: Andrei Leonida, Lawrence C. Moulthrop, Kurt M. Critz
  • Patent number: 5464705
    Abstract: A novel battery construction which incorporates a disconnect safety device which is hydraulically activated by an increase in solid volume upon abusive overcharge of the battery to disconnect the cathode or anode. A rechargeable battery which comprises: (a) a Li.sub.x MO.sub.2 cathode wherein x, is equal to or less than 1.1, and M is Ni, Co, Mn or combinations thereof; (b) a carbonaceous anode; (c) an electrolyte of one or more lithium salts dissolved in one or more non-aqueous organic solvents; and (d) an internal disconnect device which activates by hydraulic means on overcharge.
    Type: Grant
    Filed: February 24, 1994
    Date of Patent: November 7, 1995
    Assignee: Moli Energy (1990) Limited
    Inventor: David Wainwright
  • Patent number: 5458988
    Abstract: The subject invention provides for a prismatic zinc-air cell comprising a prismatic container, an air cathode, and an anode assembly. The prismatic container has one or more oxygen access openings, and the air cathode is disposed in the container in gaseous communication with the oxygen access openings. The anode assembly comprises a rectangular anode frame having peripheral members, a separator mounted proximate to one end of the anode frame and extending substantially continuously between the anode frame peripheral members. The anode frame and separator thereby define a trough. The anode assembly also comprises a zinc anode which comprises zinc, an aqueous electrolyte, and a gelling agent. The zinc anode is disposed in the trough in electrolytic contact with a first side of the separator, and the anode assembly is disposed in the containers such that a second side of the separator is in electrolytic contact with the air cathode.
    Type: Grant
    Filed: August 10, 1993
    Date of Patent: October 17, 1995
    Assignee: Matsi, Inc.
    Inventor: Ronald A. Putt
  • Patent number: 5441825
    Abstract: A device for compressing the cell stack disposed within the battery case of a multicell battery and providing a gas-tight, electrically isolated seal for one of the battery terminals. The device comprising an expandable unit disposed between the cell stack and a surface of the battery case. The unit having a cavity disposed therein and a sealable port through which a pressurized fluid may be provided to the cavity thereby expanding the unit. The unit is preferably comprised of two concentric annular metal bellows.
    Type: Grant
    Filed: January 24, 1994
    Date of Patent: August 15, 1995
    Assignee: Westinghouse Electric Corporation
    Inventor: Geoffrey Barlow
  • Patent number: 5419981
    Abstract: An electrochemical battery made of stacked cells which are separated by separator plates comprising a good heat conductive material, e.g. nickel, stainless steel, copper. The separator plates extend beyond the edge of the stacked cells and outside the enclosure of the battery. The separator plates directly conduct heat, which is generated by the electrochemical process, from the battery cells to the ambient environment. Sealing of the enclosure between the separator plates is provided by an O-ring or, alternatively, by a bellows sealed to adjacent separator plates by O-rings. Sealing is possible for hydrogen at low pressure which is presented in batteries utilizing a metal-hydride hydrogen storage capacity.
    Type: Grant
    Filed: November 1, 1993
    Date of Patent: May 30, 1995
    Assignee: Ergenics, Inc.
    Inventor: P. Mark Golben
  • Patent number: 5409787
    Abstract: This invention relates to method and apparatus for compressing an assembly of plates inside a valve regulated lead-acid battery thereby allowing the battery case to expand without causing slippage or partial loss of contact between the battery plates.
    Type: Grant
    Filed: February 17, 1993
    Date of Patent: April 25, 1995
    Assignee: Electrosource, Inc.
    Inventors: Richard J. Blanyer, Benny E. Jay
  • Patent number: 5389457
    Abstract: A galvanic cell, such as an alkaline cell employing an anode that expands during discharge, such as a zinc electrode, in which a gas filled collapsible member is disposed within the anode to accommodate any expansion of the anode during discharge or during storage.
    Type: Grant
    Filed: August 9, 1993
    Date of Patent: February 14, 1995
    Assignee: Eveready Battery Company, Inc.
    Inventor: Lewis F. Urry
  • Patent number: 5384212
    Abstract: A flexible rib plaque is provided for insertion between battery cell elements and the end and/or an interior wall of the battery container. The plaque improves performance by limiting the harmful effects caused by flexing of the container walls due to hydraulic pressure changes of the electrolyte contained within the battery. The ribs of the plaques may be located on one or both sides of the plaque. If ribs extend from only one side, they may contact the cell element or the container wall.
    Type: Grant
    Filed: April 25, 1994
    Date of Patent: January 24, 1995
    Assignee: Globe-Union Inc.
    Inventors: Jerome R. Heiman, Jack Bruss
  • Patent number: 5378551
    Abstract: A rechargeable battery cell (10) has an integral vibrating means. The cell has a positive electrode (14), a negative electrode (16), and an electrolyte (18) disposed between the two electrodes. The electrolyte contains a piezoelectric material (20) that vibrates when subjected to an alternating electric field. In one embodiment, at least one of the electrodes contains a piezoelectric material that functions as a vibrating means when subjected to an alternating electric field. In another embodiment, a piezoelectric material that functions as a vibrating means when subjected to an alternating electric field is attached as part of a current collector (22) to at least one of the electrodes. The piezoelectric material performs an additional function of being an electronic insulator for the purpose of stacking the cells.
    Type: Grant
    Filed: July 19, 1993
    Date of Patent: January 3, 1995
    Assignee: Motorola, Inc.
    Inventors: Vernon Meadows, George Thomas, Anaba A. Anani
  • Patent number: 5366823
    Abstract: Accumulated dimensional variations in fuel cells and electrolysis cell assemblies can reduce the efficiency of the assembly and provide leakage paths for fuel and oxidant. A metal compression pad comprised of a metal having an elastic strain of about 3% to about 40% at about 2,500 psig can compensate for component dimensional variations and improve inter-cell conductivity at pressures up to and exceeding about 10,000 psig.
    Type: Grant
    Filed: December 17, 1992
    Date of Patent: November 22, 1994
    Assignee: United Technologies Corporation
    Inventors: Andrei Leonida, Lawrence C. Moulthrop, Kurt M. Critz
  • Patent number: 5364713
    Abstract: A storage battery cell based on the principle of the oxygen cycle, having a block-shaped, gastightly sealed cell housing in which the rectangular electrode plates of different polarity are stacked. The electrode plates are electrically connected via current collector lugs to positive and negative terminal pillars of corresponding polarity passed through the wall of the same housing side. In order to achieve a longer service life of the cell, the electrode plates are arranged in parallel with the housing wall of the terminal pillars and are enclosed in an equidistant manner on all four peripheral sides of the electrode plates by the walls of the cell housing. All the electrode plates have in each case a central hole on whose inner edge the current collector lugs are mounted, the current collector lugs being routed elastically in the duct formed by the central holes to the terminal pillars of the corresponding polarity.
    Type: Grant
    Filed: June 3, 1993
    Date of Patent: November 15, 1994
    Assignee: Daimler-Benz AG
    Inventors: Klaus Von Benda, Gunter Gutmann, Wolfgang Weger
  • Patent number: 5348813
    Abstract: A battery charge indicator is permanently incorporated into a battery to indicate the state of charge. In one embodiment, the indicator includes a compressible chamber which is filled with a viscous gel and which is exposed to the expandable cathode of the battery. As the battery discharges, the cathode expands thus causing the gel within the chamber to be extruded out through an outlet into a viewing channel in an overlying disk. The amount of gel flowing into the viewing channel is proportional to the amount of expansion of the cathode and, thus, indicates the amount of discharge and, conversely, the remaining life of the battery. In a second embodiment, a piston assembly is caused to move with a deformable end wall of the battery and indicia on the side wall of the piston assembly is viewed through a lens as a measure of the remaining amount of expect expansion of the cathode.
    Type: Grant
    Filed: September 16, 1991
    Date of Patent: September 20, 1994
    Assignee: Display Matrix Corporation
    Inventors: William Bohmer, Clark F. Bow
  • Patent number: 5346783
    Abstract: This invention relates to rechargeable manganese dioxide cells (usually alkaline cells with zinc anodes or cells having non-aqueous electrolyte and lithium anodes), and particularly to the cathodes therefore. In keeping with the present invention, the cathodes are essentially unconstrained--that is, no cage is used in the cell between the cathodes and the anodes. The cathode is restricted from significantly changing its dimensions during discharge of the cell, when it is inclined to swell--as opposed to the tendency of the cathode to contract during a charge cycle. The cathode substantially fills the entire space allotted for it within the cell, with a light accommodation for height-wise or longitudinal expansion or growth of the cathode of bobbin-type cells, or crosswise expansion or growth of button-type cells.
    Type: Grant
    Filed: April 6, 1993
    Date of Patent: September 13, 1994
    Assignee: Battery Technologies Inc.
    Inventors: Klaus Tomantschger, Christopher Michalowski
  • Patent number: 5336571
    Abstract: This invention relates to rechargeable manganese dioxide cells (usually alkaline cells with zinc anodes or cells having non-aqueous electrolyte and lithium anodes), and particularly to the cathodes therefore. In keeping with the present invention, the cathodes are essentially unconstrained--that is, no cage is used in the cell between the cathodes and the anodes. The cathode is restricted from significantly changing its dimensions during discharge of the cell, when it is inclined to swell--as opposed to the tendency of the cathode to contract during a charge cycle. The cathode substantially fills the entire space allotted for it within the cell, with a light accommodation for height-wise or longitudinal expansion or growth of the cathode of bobbin-type cells, or cross-wise expansion or growth of button-type cells.
    Type: Grant
    Filed: April 6, 1993
    Date of Patent: August 9, 1994
    Assignee: Battery Technologies Inc.
    Inventors: Klaus Tomantschger, Christopher Michalowski