Organic Nitrogen Or Organic Phosphorus Compound Adjuvant Patents (Class 430/108.2)
  • Patent number: 11294295
    Abstract: A developer includes a metallic pigment and a binder resin. The developer includes a fine powder having a particle size smaller than a mode value in a volume particle size distribution of the metallic pigment. A proportion of the fine powder relative to the developer is equal to or higher than 4.6 percent and equal to or lower than 9.6 percent.
    Type: Grant
    Filed: February 12, 2020
    Date of Patent: April 5, 2022
    Assignee: Oki Electric Industry Co., Ltd.
    Inventor: Manami Hiraide
  • Patent number: 11292778
    Abstract: The present disclosure provides SWIR-active small molecule polymethine dyes with improved properties for use in optical imaging, photothermal therapy, photodynamic therapy, and SWIR-promoted drug delivery.
    Type: Grant
    Filed: June 5, 2018
    Date of Patent: April 5, 2022
    Assignee: The Regents of the University of California
    Inventors: Ellen M. Sletten, Emily D. Cosco
  • Patent number: 11249410
    Abstract: A toner having an adequate storage stability and adequately suppressing an ejected paper adhesion, while achieving improving low-temperature fixability, has a toner particle containing a binder resin and a plasticizer, wherein Tg1 is 53° C. or lower and Tg2 is 55° C. or higher, in DSC measurement using the toner as a sample, when the following steps (i) to (iii) are performed: (i): the temperature of the toner is raised for the first time at a rate of temperature increase of 10° C./min, (ii): after the step (i), the temperature of the toner is lowered at a rate of temperature decrease of 10° C./min, (iii): after the step (ii), the temperature of the toner is raised for the second time at a rate of temperature increase of 10° C./min, Tg1 represents a glass transition temperature measured at the step (i), and Tg2 represents a glass transition temperature measured at the step (iii).
    Type: Grant
    Filed: December 9, 2019
    Date of Patent: February 15, 2022
    Assignee: CANON KABUSHIKI KAISHA
    Inventors: Toru Takahashi, Daisuke Tsujimoto, Hiroki Watanabe, Yoshihiro Ogawa, Wakashi Iida
  • Patent number: 11215936
    Abstract: A toner is provided. The toner comprises a binder resin, a release agent, and a function imparting agent comprising a fatty acid amide having a melting point of from 110 to 160 degrees C. When the toner is heated by a differential scanning calorimeter, the toner exhibits no endothermic peak within a temperature range of ±20 degrees C. of a temperature at a highest endothermic peak derived from the fatty acid amide.
    Type: Grant
    Filed: November 26, 2019
    Date of Patent: January 4, 2022
    Assignee: RICOH COMPANY, LTD.
    Inventors: Namie Suzuki, Yoshitaka Yamauchi
  • Patent number: 11126103
    Abstract: A polymeric composition including a copolymer comprising a first monomer having a high carbon to oxygen ratio of from about 3 to about 8; a second monomer comprising two or more vinyl groups, wherein the second monomer is present in the copolymer in an amount of from greater than about 8 percent by weight to about 40 percent by weight, based on the weight of the copolymer; and optionally, a third monomer comprising an amine, wherein the third monomer is present in an amount of from about 0.1 percent by weight to about 1.5 percent by weight, based on the weight of the copolymer; and a surfactant, wherein the surfactant has a minimum surface tension at critical micelle concentration of less than about 30 mN/m. A toner including the copolymer as a toner surface additive. An emulsion aggregation toner process including the copolymer as a toner surface additive.
    Type: Grant
    Filed: June 4, 2020
    Date of Patent: September 21, 2021
    Assignee: Xerox Corporation
    Inventors: Richard P. N. Veregin, Shivanthi Easwari Sriskandha, David R. Kurceba, Scott Edward Silver, Melanie Lynn Davis, Cuong Vong
  • Patent number: 10969704
    Abstract: Provided is a magnetic toner having a toner particle containing a binder resin and a magnetic body, wherein the binder resin contains a polymer A having a first monomer unit and a second monomer unit, the first polymerizable monomer is at least one selected from the group consisting of the (meth)acrylic acid esters having C18-36 alkyl groups, a content of the first monomer unit and a content of the second monomer unit based on the total moles of all monomer units in the polymer A are respectively 5.0 to 60.0 mol % and 20.0 to 95.0 mol %, and assuming that an SP value of the first monomer unit and the second monomer unit are taken as SP11 (J/cm3)0.5 and SP21(J/cm3)0.5, respectively, 3.00?(SP21?SP11)?25.00 is satisfied, and an oil absorption of the magnetic body is 5 to 40 ml/100 g.
    Type: Grant
    Filed: June 12, 2019
    Date of Patent: April 6, 2021
    Assignee: CANON KABUSHIKI KAISHA
    Inventors: Hiroki Kagawa, Shuntaro Watanabe, Hiroki Akiyama, Tatsuya Saeki, Takashi Matsui
  • Patent number: 10754269
    Abstract: An electrostatic-image developing toner includes toner particles including a binder resin including an amorphous resin including a polyester resin segment and a styrene acrylate resin segment and a release agent. The content of 5?-chloro-3-hydroxy-2?-methoxy-2-naphthanilide in the electrostatic-image developing toner is 1,000 ppm by mass or less.
    Type: Grant
    Filed: July 22, 2019
    Date of Patent: August 25, 2020
    Assignee: FUJI XEROX CO., LTD.
    Inventors: Yasuo Kadokura, Daisuke Tomita, Atsushi Sugawara
  • Patent number: 10739690
    Abstract: A toner for electrostatic image development includes: toner base particles containing at least a nonionic surfactant, a binder resin, and a release agent; and an external additive. The content of the nonionic surfactant is from 0.05% by mass to 1% by mass inclusive based on the total mass of the toner, and the external additive contains particles with an arithmetic mean particle diameter of from 50 nm to 400 nm inclusive. The amount of the external additive released is 5% by mass or less.
    Type: Grant
    Filed: July 22, 2019
    Date of Patent: August 11, 2020
    Assignee: FUJI XEROX CO., LTD.
    Inventors: Sakiko Takeuchi, Yutaka Saito, Yuka Yamagishi, Kazuhiko Nakamura
  • Patent number: 10732533
    Abstract: Provided is a magenta toner, which is excellent in image density, has an enhanced chargeability, and can be produced at a low cost. The magenta toner comprising a binder resin and a magenta colorant, wherein a compound A represented by the general formula (1) and a compound B represented by the general formula (2) are contained as the magenta colorant, and wherein a total content of the compound A and the compound B is from 3 to 30 parts by mass with respect to 100 parts by mass of the binder resin, and a mass ratio of the content of the compound A to the content of the compound B (compound A/compound B) is from 0.8 to 20.
    Type: Grant
    Filed: July 24, 2017
    Date of Patent: August 4, 2020
    Assignee: ZEON CORPORATION
    Inventor: Masashi Watanabe
  • Patent number: 10732531
    Abstract: A toner contains at least a crystalline polyester resin and an amorphous linear polyester resin that uses diethylene glycol as an alcohol component, and a monoester wax and a montan ester wax as release agent components, wherein 6???8 and 14?mw/?<30 are satisfied, where ? represents an amount of the crystalline polyester resin added relative to 100 parts by weight of the amorphous linear polyester resin and mw represents an amount of the montan ester wax added.
    Type: Grant
    Filed: March 28, 2019
    Date of Patent: August 4, 2020
    Assignee: SHARP KABUSHIKI KAISHA
    Inventors: Keiichi Kikawa, Yoritaka Tsubaki, Takeshi Katoh, Osamu Wada, Tadanori Kano, Yuya Kondo, Shoji Nakai, Hiroki Maeda
  • Patent number: 10725394
    Abstract: A polymeric composition including a copolymer comprising a first monomer having a high carbon to oxygen ratio of from about 3 to about 8; a second monomer comprising two or more vinyl groups, wherein the second monomer is present in the copolymer in an amount of from greater than about 8 percent by weight to about 40 percent by weight, based on the weight of the copolymer; and optionally, a third monomer comprising an amine, wherein the third monomer is present in an amount of from about 0.1 percent by weight to about 1.5 percent by weight, based on the weight of the copolymer; and a surfactant, wherein the surfactant has a minimum surface tension at critical micelle concentration of less than about 30 mN/m. A toner including the copolymer as a toner surface additive. An emulsion aggregation toner process including the copolymer as a toner surface additive.
    Type: Grant
    Filed: March 29, 2019
    Date of Patent: July 28, 2020
    Assignee: Xerox Corporation
    Inventors: Richard P. N. Veregin, Shivanthi Easwari Sriskandha, David R. Kurceba, Scott Edward Silver, Melanie Lynn Davis, Cuong Vong
  • Patent number: 10725393
    Abstract: A toner for electrostatic image development includes: toner base particles containing at least a nonionic surfactant, a binder resin, and a release agent; and an external additive. The content of the nonionic surfactant is from 0.05% by mass to 1% by mass inclusive based on the total mass of the toner. The external additive contains inorganic particles having an arithmetic mean particle diameter of from 50 nm to 400 nm inclusive and an average circularity of from 0.5 to 0.8 inclusive.
    Type: Grant
    Filed: July 19, 2019
    Date of Patent: July 28, 2020
    Assignee: FUJI XEROX CO., LTD.
    Inventors: Yuka Yamagishi, Yutaka Saito, Kazuhiko Nakamura, Kazutsuna Sasaki, Takashi Inukai, Sakiko Takeuchi
  • Patent number: 10656546
    Abstract: An electrostatic-image developing toner includes toner particles including a binder resin including an amorphous resin including a polyester resin segment and a styrene acrylate resin segment and a release agent. The content of 1-amino-2-methoxybenzene in the electrostatic-image developing toner is 200 ppm by mass or less.
    Type: Grant
    Filed: July 23, 2019
    Date of Patent: May 19, 2020
    Assignee: FUJI XEROX CO., LTD.
    Inventors: Daisuke Tomita, Yasuo Kadokura, Atsushi Sugawara
  • Patent number: 10564560
    Abstract: Provided is a toner having a toner particle, wherein the toner particle contains a polyester resin and a fatty acid metal salt, the toner contains a tetrahydrofuran-soluble component A with a molecular weight of at least 1,000 and not more than 5,000, as measured by gel permeation chromatography, in an amount of at least 25 mass % and not more than 80 mass %, and a mass ratio of the fatty acid metal salt to the tetrahydrofuran-soluble component A is at least 0.003 and not more than 0.060.
    Type: Grant
    Filed: June 4, 2018
    Date of Patent: February 18, 2020
    Assignee: CANON KABUSHIKI KAISHA
    Inventors: Yuto Onozaki, Takeshi Hashimoto, Ichiro Kanno, Masayuki Hama, Nozomu Komatsu, Hiroyuki Fujikawa
  • Patent number: 10551761
    Abstract: To provide a toner for electrophotography exhibiting an excellent charge rise property, and a process for producing the same. [1] A toner for electrophotography containing a binder resin, and a polyhydroxyamine compound represented by the following formula (1) in an amount of 0.001 part by mass or more and 5.0 parts by mass or less per 100 parts by mass of the binder resin, and [2] a process for producing a toner for electrophotography, including: melt-kneading a toner raw material mixture containing a binder resin, and a polyhydroxyamine compound represented by the following formula (1) in an amount of 0.001 part by mass or more and 5.0 parts by mass or less per 100 parts by mass of the binder resin; and pulverizing a resulting melt-kneaded material.
    Type: Grant
    Filed: February 9, 2017
    Date of Patent: February 4, 2020
    Assignee: KAO CORPORATION
    Inventors: Takashi Kubo, Kota Ijichi
  • Patent number: 10551785
    Abstract: An image forming apparatus includes: an image carrier to which a lubricant is applied; a developing device that develops an electrostatic latent image carried on the image carrier with toner, and includes a casing accommodating a toner-containing developer and a developing sleeve supplying the image carrier with the toner contained in the developer accommodated in the casing; and a hardware processor that detects information indicating a state of lubricant adhesion to the developing sleeve, and performs, based on a result of the detection by the hardware processor, a lubricant removing operation as an operation for removing the lubricant adhering to the developing sleeve.
    Type: Grant
    Filed: January 25, 2019
    Date of Patent: February 4, 2020
    Assignee: KONICA MINOLTA, INC.
    Inventors: Kengo Fushiya, Hideaki Tanaka
  • Patent number: 10353307
    Abstract: Provided here are toners and image forming apparatus and methods for the formation of a bright image with excellent brightness and concealability. A bright toner according to an embodiment comprises a plurality of toner particles containing a bright pigment and a binder resin, and has a volume particle diameter distribution with a coefficient of variation CV of 0.26 or more.
    Type: Grant
    Filed: January 16, 2018
    Date of Patent: July 16, 2019
    Assignees: KABUSHIKI KAISHA TOSHIBA, TOSHIBA TEC KABUSHIKI KAISHA
    Inventors: Maiko Miyoshi, Li Xu, Taishi Takano
  • Patent number: 10254667
    Abstract: An electrostatic charge image developing toner set includes a white toner that includes white toner particles containing a core and a coating layer which does not contain a coloring agent and a colored toner that includes colored toner particles containing a core and a coating layer which does not contain a coloring agent, wherein with respect to a difference between an average equivalent circle diameter [Rw1] of the cores (Win) in the white toner particles and an average equivalent circle diameter [Rw2] of the white toner particles [Rw2?Rw1], and a difference between the average equivalent circle diameter [Rc1] of the cores (Cin) in the colored toner particles and the average equivalent circle diameter [Rc2] of the colored toner particles [Rc2?Rc1], a relationship of the following Expression (1) is satisfied: [Rw2?Rw1]<[Rc2?Rc1]??(1).
    Type: Grant
    Filed: October 16, 2017
    Date of Patent: April 9, 2019
    Assignee: FUJI XEROX CO., LTD.
    Inventors: Tomoaki Tanaka, Tetsuya Taguchi, Shinya Sakamoto, Ryutaro Kembo
  • Patent number: 10215897
    Abstract: Disclosed are infrared light absorbing aminium and diimmonium compositions that have at least one absorption maximum in the infrared spectral region between about 700 and 1500 nm and that are useful, for example, as infrared absorbers. In one example, an infrared light aminium absorbing composition includes an anionic borate moiety and an aminium radical cation, which has at least one absorption peak in the near infrared wavelength region between about 700 and 1500 nm. In another example, an infrared light diimmonium absorbing composition includes two anionic borate moieties and a diimmonium radical cation, which has at least one absorption peak in the near infrared wavelength region between about 700 and 1500 nm. Such compositions may be incorporated into films or bulk materials to form light filters for electromagnetic radiation, including laser radiation.
    Type: Grant
    Filed: February 2, 2016
    Date of Patent: February 26, 2019
    Assignee: NOTICXE, INC.
    Inventors: Paul A. Cahill, Richard Steppel
  • Patent number: 10180625
    Abstract: A resist composition which generates acid upon exposure and exhibits changed solubility in a developing solution under action of acid, the resist composition including a base component (A) which exhibits changed solubility in a developing solution under action of acid, and a compound (D1) represented by general formula (d1), wherein Z? represents an anion having an aromatic ring containing a hydroxybenzoic acid skeleton, provided that at least one hydrogen atom of the aromatic ring has been substituted with a halogen atom; m represents an integer of 1 or more; and Mm+ represents an organic cation having a valency of m.
    Type: Grant
    Filed: June 27, 2017
    Date of Patent: January 15, 2019
    Assignee: TOKYO OHKA KOGYO CO., LTD.
    Inventors: Takashi Nagamine, Kotaro Endo, Hideto Nito
  • Patent number: 10144816
    Abstract: Provided is a spherical alumina powder which, when incorporated into resins in a high concentration, enables a resin composition to have low viscosity and which has reduced viscosity increase in the resin composition over time after surface treatment of the spherical alumina powder. The spherical alumina powder has an alkyl group(s) derived from a silane compound(s) on its surface, and is characterized in that an intensity ratio {I (CH3)/I (CH2)} of a peak (2960±5 cm?1) associated with asymmetric vibration of CH3 to a peak (2925±5 cm?1) associated with asymmetric vibration of CH2 in the alkyl group(s) of the silane compound(s) in the same spectral data obtained by infrared spectroscopic analysis measurement is 0.2 or more and less than 2.0.
    Type: Grant
    Filed: July 28, 2015
    Date of Patent: December 4, 2018
    Assignee: DENKA COMPANY LIMITED
    Inventors: Kazuyoshi Ikeda, Motoharu Fukazawa, Takafumi Komaki
  • Patent number: 10139745
    Abstract: A toner according to the present disclosure maintains high transfer efficiency for the long term and obtains images which are not affected by toner base particles easily, which exhibit excellent charge stability, and which exhibit less fogging, wherein the toner is obtained by making inorganic fine particles and charge control particles, which satisfy specific conditions, present on the surfaces of toner base particles so as to satisfy a specific coverage relationship.
    Type: Grant
    Filed: May 4, 2016
    Date of Patent: November 27, 2018
    Assignee: Canon Kabushiki Kaisha
    Inventors: Atsushi Nakamoto, Makoto Fukatsu, Manami Haraguchi, Masayoshi Kato, Kei Inoue, Kazuyuki Sato
  • Patent number: 10082744
    Abstract: A method of producing an emissive toner composition including selecting a photoluminescent agent, a charge control agent, and one or more additives and combining the photoluminescent agent, charge control agent, and one or more additives to form an emissive toner composition that when printed to produce an image component on a substrate, the emission spectra of the image component for irradiation with a first excitation energy includes only dominant emission peaks corresponding to one or more dominant emission peaks of the photoluminescent agent. The photoluminescent agent is selected such that it emits light having one or more dominant emission peaks in a first emission spectral region when irradiated with the first excitation energy. The charge control agent and one or more additives are selected such that they do not emit light in the visible spectrum when irradiated with visible light and does not emit light in the first emission spectral region when irradiated with the first excitation energy.
    Type: Grant
    Filed: November 20, 2017
    Date of Patent: September 25, 2018
    Assignee: Angstrom Technologies, Inc.
    Inventors: William J. Coyle, Anthony Stramondo
  • Patent number: 10073367
    Abstract: An object of the embodiments herein is to provide a toner having excellent visibility upon irradiation with UV light, a toner cartridge, and an image forming apparatus. According to one embodiment, a toner contains at least two or more fluorescent coloring agents selected from the group consisting of a first fluorescent coloring agent, a second fluorescent coloring agent, and a third fluorescent coloring agent, and a binder resin. The first fluorescent coloring agent has a fluorescence peak in a wavelength region of 400 nm or more and less than 500 nm. The second fluorescent coloring agent has a fluorescence peak in a wavelength region of 500 nm or more and less than 600 nm. The third fluorescent coloring agent has a fluorescence peak in a wavelength region of 600 nm or more and less than 650 nm.
    Type: Grant
    Filed: April 12, 2017
    Date of Patent: September 11, 2018
    Assignees: Kabushiki Kaisha Toshiba, Toshiba Tec Kabushiki Kaisha
    Inventor: Shiho Moriya
  • Patent number: 10067436
    Abstract: A two-component developer includes a toner and a carrier. The toner is a positively chargeable toner that is positively charged by friction with the carrier. The toner includes a plurality of toner particles each including a toner mother particle and a plurality of first resin particles. An anionic surfactant having higher negative chargeability than the first resin particles is present on surfaces of the first resin particles. The carrier includes a plurality of carrier particles each including a carrier mother particle and a plurality of second resin particles. A cationic surfactant having higher positive chargeability than the second resin particles is present on surfaces of the second resin particles. The first resin particles have a zeta potential lower than 0 mV at a pH of 5. The second resin particles have a zeta potential higher than 0 mV at a pH of 5.
    Type: Grant
    Filed: September 5, 2017
    Date of Patent: September 4, 2018
    Assignee: KYOCERA Document Solutions Inc.
    Inventor: Ryota Kobayashi
  • Patent number: 10061216
    Abstract: An electrostatic image developing toner contains: toner particles, first silica particles having an average equivalent circle diameter of 10 nm to 120 nm and second silica particles having a compressive agglomeration degree of 60% to 95%, a particle compression ratio of 0.20 to 0.40 and an average equivalent circle diameter being greater than the average equivalent circle diameter of the first silica particles.
    Type: Grant
    Filed: August 1, 2016
    Date of Patent: August 28, 2018
    Assignee: FUJI XEROX CO., LTD.
    Inventors: Yuka Zenitani, Hiroyoshi Okuno, Satoshi Inoue, Yoshifumi Iida, Tomohito Nakajima, Yoshifumi Eri, Takeshi Iwanaga, Sakae Takeuchi, Shunsuke Nozaki, Yasuo Kadokura, Yasuhisa Morooka
  • Patent number: 10018930
    Abstract: A toner including a resin; and a colorant wax comprising a plurality of colorant wax particles comprising a colorant core surrounded by a wax shell, wherein the colorant wax particles exhibit a particle size distribution of from about 150 nanometers to less than about 300 nanometers; and wherein the colorant wax is prepared by (a) melting and mixing a dry colorant with at least one wax to form a colorant concentrate, wherein the colorant concentrate contains at least 25 percent by weight of colorant; (b) milling the colorant concentrate of step (a) to form a milled colorant concentrate; (c) combining the milled colorant concentrate of (b) with water and dispersing to form the plurality of colorant wax particles; wherein the melting and mixing of step (a) and the milling of step (b) is done in an immersion media mill; and wherein the combining of step (c) is done using a piston homogenizer.
    Type: Grant
    Filed: January 25, 2017
    Date of Patent: July 10, 2018
    Assignee: Xerox Corporation
    Inventors: Frank Ping-Hay Lee, Richard P. N. Veregin, Shigang S. Qiu, Michael J. D'Amato, Aurelian Valeriu Magdalinis, David John William Lawton
  • Patent number: 9817327
    Abstract: A toner comprises a binder resin, a colorant, and a compound represented by the following general formula [1]: (in the formula, R1 to R8 each independently represent a group selected from the hydrogen atom, fluorine atom, bromine atom, iodine atom, hydroxy group, acetyl group, aldehyde group, C1 to C6 hydrocarbon groups, and amino group; X represents a group selected from the oxygen atom, sulfur atom, carbonyl group, and —CR9R10—; and R9 and R10 each independently represent a group selected from the hydrogen atom, bromine atom, C1 to C3 hydroxyalkyl groups, hydroxy group, phenyl group, and C1 to C6 hydrocarbon groups).
    Type: Grant
    Filed: September 29, 2016
    Date of Patent: November 14, 2017
    Assignee: CANON KABUSHIKI KAISHA
    Inventors: Toru Takahashi, Daisuke Tsujimoto, Yoshihiro Ogawa, Hiroki Watanabe, Wakashi Iida
  • Patent number: 9804516
    Abstract: A toner includes a base particle; and an external additive covering the base particle. The toner includes a tetrahydrofuran (THF)-insoluble component having a glass transition temperature determined from a DSC curve when heated for the second time of from ?50° C. to 10° C. and an average circularity not greater than 0.98, and satisfies the following relation: Bt?0.025×Ct?1.80 wherein Bt represents a BET specific surface area [m2/g]; and Ct represents a coverage [%] of the external additive covering the base particle.
    Type: Grant
    Filed: April 21, 2016
    Date of Patent: October 31, 2017
    Assignee: Ricoh Company, Ltd.
    Inventors: Keiji Makabe, Tsuneyasu Nagatomo, Kohsuke Satoh, Junichi Watanabe, Kenji Yoneda, Daichi Hisakuni
  • Patent number: 9665023
    Abstract: Provided is a toner, including toner particles each containing a binder resin containing a polyester ? as a main component, a colorant, a wax, and a crystalline polyester, in which: the polyester ? has a polyhydric alcohol unit and a polyvalent carboxylic acid unit; and the polyester ? has, as the polyhydric alcohol unit, a polyhydric alcohol unit N derived from an alkylene oxide adduct of a novolac type phenol resin.
    Type: Grant
    Filed: December 10, 2014
    Date of Patent: May 30, 2017
    Assignee: CANON KABUSHIKI KAISHA
    Inventors: Kentaro Kamae, Ryuichiro Matsuo, Koh Ishigami, Masaharu Miura, Masayuki Hama, Hiroaki Kawakami
  • Patent number: 9566800
    Abstract: A system for producing a security feature on a physical printed document that has a first image printed on a first side of a piece of medium is provided. The system includes a security portion forming device that melts a marking substance that forms the security portion of the first image such that the security portion soaks into the piece of medium and is visible from a second side of the piece of medium, the second side being opposite to the first side. The security portion is less than the entire first image, and a remainder portion of the first image is equal to the entire first image less the security portion.
    Type: Grant
    Filed: February 28, 2014
    Date of Patent: February 14, 2017
    Assignee: Xerox Corporation
    Inventor: Chu-heng Liu
  • Patent number: 9529290
    Abstract: The present invention relates to a process for producing a toner for electrophotography which is capable of suppressing liberation of a wax from a resin binder and exposure of the wax to a surface of respective toner particles in the step of obtaining fused particles upon production of the toner, and reducing a content of fine powders in the toner, and which is characterized by an excellent low-temperature fusing property and an excellent anti-high-temperature offset property.
    Type: Grant
    Filed: October 4, 2013
    Date of Patent: December 27, 2016
    Assignee: KAO CORPORATION
    Inventors: Yasuhiro Shidahara, Manato Ikeda, Hiroshi Mizuhata, Koji Shimokusa
  • Patent number: 9389528
    Abstract: A toner includes an amorphous resin; and a crystalline polyester resin dispersed in the amorphous resin. The crystalline polyester resin has a volume-average particle diameter (Dv) of from 0.07 to 0.20 ?m, and a ratio (Dv/Dn) of the volume-average particle diameter (Dv) to a number-average particle diameter (Dn) thereof of from 1.00 to 2.25.
    Type: Grant
    Filed: August 27, 2014
    Date of Patent: July 12, 2016
    Assignee: Ricoh Company, Ltd.
    Inventors: Mio Kumai, Hideki Sugiura
  • Patent number: 9377704
    Abstract: Red toners that approximate PANTONE® Red 032 and PANTONE® Warm Red are described. The colorant includes an orange colorant and a red colorant, where the orange colorant absorbs light having a wavelength of from about 400 to about 520 nm, and where the red colorant absorbs light having a wavelength of from about 500 to 580 nm.
    Type: Grant
    Filed: November 2, 2012
    Date of Patent: June 28, 2016
    Assignee: Xerox Corporation
    Inventors: Valerie M Farrugia, Jordan H Wosnick, Eric Rotberg, Karen A Moffat, Richard P N Veregin, Suxia Yang, C Geoffrey Allen
  • Patent number: 9341966
    Abstract: A process includes dissolving a polyester resin in a mixture of a single organic solvent, a base and water to form a resin mixture; neutralizing the resin mixture with a neutralizing agent to provide a neutralized resin mixture; adding water to the neutralized resin mixture until phase inversion occurs to form a toner resin emulsion; removing the single solvent to form a polyester latex.
    Type: Grant
    Filed: December 18, 2014
    Date of Patent: May 17, 2016
    Assignee: XEROX CORPORATION
    Inventors: Yanjia Zuo, Shigeng Li, Peter Nguyen, Chieh-Min Cheng
  • Patent number: 9298113
    Abstract: An electrophotographic photoconductor, including: an electroconductive substrate; and at least a photoconductive layer and a surface layer in this order over the electroconductive substrate, wherein the surface layer includes a resin having no charge transport properties, and first inorganic fine particles, and wherein the first inorganic fine particles are inorganic fine particles having surfaces modified with at least one of a primary amino group and a secondary amino group, and a volume resistivity of the first inorganic fine particles is 1×108 ?·cm or less.
    Type: Grant
    Filed: January 15, 2014
    Date of Patent: March 29, 2016
    Assignee: Ricoh Company, Ltd.
    Inventors: Toshihiro Ishida, Hiroshi Ikuno, Tetsuya Toshine, Naohiro Toda, Takafumi Iwamoto, Kazuhiro Egawa
  • Patent number: 9274449
    Abstract: An image forming apparatus includes a first image forming unit configured to form a first image to be transferred to a sheet with a first toner that is decolorizable and has a first brightness, and a second image forming unit configured to form a second image to be transferred to the sheet with a second toner that has a second brightness that is greater than the first brightness. At least a part of the first image transferred to the sheet is formed above the second image transferred to the sheet.
    Type: Grant
    Filed: March 25, 2014
    Date of Patent: March 1, 2016
    Assignees: Kabushiki Kaisha Toshiba, Toshiba TEC Kabushiki Kaisha
    Inventor: Koji Takahashi
  • Patent number: 9244369
    Abstract: Provided is an electrophotographic photosensitive member including a surface layer containing particles which include: silica particles; and a compound-A adsorbed to each of the silica particles, in which the silica particles have a volume average particle diameter of 0.1 ?m or more and 4 ?m or less, and a specific surface area of 400 m2/g or more and 1000 m2/g or less, the compound-A is a tertiary amine compound and/or a urea compound, and the compound-A has a molecular weight of 150 or more and 550 or less.
    Type: Grant
    Filed: October 1, 2013
    Date of Patent: January 26, 2016
    Assignee: CANON KABUSHIKI KAISHA
    Inventors: Masato Tanaka, Masaki Nonaka
  • Patent number: 9201321
    Abstract: A phase inversion emulsification process includes dissolving a polyester resin in a mixture comprising (1) an organic solvent, (2) a first portion of a total amount of neutralizing agent, and (3) a first portion of water, neutralizing the dissolved polyester resin with a second portion of neutralizing agent, the second portion of neutralizing agent including the remaining amount of the total amount neutralizing agent, forming an emulsion by adding a second portion of water after the neutralizing step, and removing a portion of the organic solvent from the emulsion to provide a latex.
    Type: Grant
    Filed: June 17, 2013
    Date of Patent: December 1, 2015
    Assignee: XEROX CORPORATION
    Inventors: Shigang Steven Qiu, Chieh-Min Cheng, Amy Grillo, Yulin Wang, Rashid Mahmood, David Kurceba
  • Patent number: 9187605
    Abstract: A process includes dissolving a polyester resin in an organic solvent to form a solution, the polyester resin has a latex-destabilizing cation, removing substantially all of the latex-destabilizing cation, neutralizing the solution of the polyester resin, adding a sufficient amount of water to the neutralized solution form an emulsion, and removing a portion of the organic solvent from the emulsion to form a latex of the polyester resin.
    Type: Grant
    Filed: July 18, 2013
    Date of Patent: November 17, 2015
    Assignee: XEROX CORPORATION
    Inventors: Yulin Wang, Karen Moffat, John L. Pawlak, Kevin F. Marcell, Steven M. Malachowski
  • Patent number: 9182688
    Abstract: An image forming apparatus, including: an electrostatic latent image bearing member; an electrostatic latent image forming unit configured to form an electrostatic latent image on the electrostatic latent image bearing member; and a developing unit containing a toner and configured to develop the electrostatic latent image with the toner to thereby form a visible image, wherein the developing unit is a contact type one-component developing unit which includes a toner bearing member being in contact with the electrostatic latent image bearing member, wherein a contact pressure between the electrostatic latent image bearing member and the toner bearing member is 2.0×104 N/m2 to 7.5×104 N/m2, wherein the toner contains a binder resin and a releasing agent, and wherein an extracted amount of the releasing agent extracted with hexane from the toner is 10 mg/g to 25 mg/g.
    Type: Grant
    Filed: November 25, 2013
    Date of Patent: November 10, 2015
    Assignee: Ricoh Company, Ltd.
    Inventors: Takuya Kadota, Yoshihiro Mikuriya, Tsuyoshi Nozaki, Yoshimichi Ishikawa, Kazuoki Fuwa, Tomohiro Fukao, Yuta Takeuchi, Tomoharu Miki, Takayuki Nakamura, Naoki Nakatake, Yasuhide Matsuno
  • Patent number: 9170509
    Abstract: Disclosed is a toner for developing electrostatic images comprising a colored resin particle containing a binder resin, a colorant and a softening agent, and an external additive, wherein the colored resin particle contains a diester compound represented by the following general formula (1) as the softening agent, and a content of the diester compound is in the range from 1 to 15 parts by mass with respect to 100 parts by mass of the colored resin particle, and the toner has a softening temperature “Ts” of 55 to 70° C., a flow starting temperature “Tfb” of 80 to 100° C. and a glass transition temperature of 40 to 70° C. in a flow tester: wherein, R1 is an ethylene group or a trimethylene group; and each of R2 and R3 is independently a linear alkyl group having 11 to 25 carbons.
    Type: Grant
    Filed: September 19, 2012
    Date of Patent: October 27, 2015
    Assignee: ZEON CORPORATION
    Inventor: Azusa Masuda
  • Patent number: 9088751
    Abstract: A control device includes a toner-density-related value identifying unit, a supply-amount-related value identifying unit, and a correcting unit. The toner-density-related value identifying unit identifies a toner-density-related value indicating the ratio of toner in developer including toner and carrier and contained in a developing unit that contains and agitates the developer. The supply-amount-related value identifying unit identifies the supply-amount-related value of developer to the developing unit. The correcting unit corrects the toner-density-related value identified by the toner-density-related value identifying unit in accordance with the supply-amount-related value identified by the supply-amount-related value identifying unit. The supply-amount-related value identifying unit estimates the supply-amount-related value on the basis of the consumption-amount-related value of developer.
    Type: Grant
    Filed: November 21, 2011
    Date of Patent: July 21, 2015
    Assignee: FUJI XEROX CO., LTD.
    Inventor: Satoshi Tanaka
  • Patent number: 9034546
    Abstract: A toner includes a polymeric resin, optionally a colorant, and a small molecule crystalline imide having a molecular weight less than 1,000 g/mol. The polymeric resin may be an amorphous resin and a mixture of the amorphous resin and the crystalline imide may be characterized by a reduction in glass transition temperature from that of the resin and by the lack of a melting point for the crystalline imide as determined by differential scanning calorimetry, the enthalpy of fusion for the crystalline imide in the mixture being measured to be less than 10% of the enthalpy of fusion of the crystalline imide in pure form. Furthermore, the toner may be configured to have a crease fix minimum fusing temperature (MFT) less than or equal to the crease fix MFT of a benchmark ultra-low-melt emulsion aggregation toner. Suitable crystalline imides may include N-alkyl and N-aryl imides, such as N-benzylphthalimide.
    Type: Grant
    Filed: November 11, 2013
    Date of Patent: May 19, 2015
    Assignee: XEROX CORPOARATION
    Inventors: Jordan H. Wosnick, Ke Zhou, Kentaro Morimitsu, Michael S. Hawkins, Edward G. Zwartz, Valerie M. Farrugia
  • Patent number: 9034553
    Abstract: A method of transferring a foil comprising: forming a foil transferring face on a photoreceptor employing a foil transferring face forming toner; transferring the foil transferring face onto a base substance, followed by fixing the foil transferring face; supplying a transfer foil having at least a foil and an adhesive layer on the base substance having the fixed foil transferring face, heating the transfer foil and the foil transferring face while the adhesive layer of the transfer foil is in contact with the foil transferring face to adhere the foil onto the foil transferring face; removing the transfer foil from the base substance while leaving the foil adhered onto the foil transferring face, wherein the foil transferring face forming toner comprises at least a binder resin, wherein the binder resin comprises a polymer formed by using a vinyl monomer comprising at least a carboxyl group.
    Type: Grant
    Filed: March 16, 2011
    Date of Patent: May 19, 2015
    Assignee: KONICA MINOLTA BUSINESS TECHNOLOGES, INC.
    Inventors: Ryuichi Hiramoto, Takao Yamanouchi, Kazue Nakamura, Michiyo Fujita
  • Publication number: 20150132693
    Abstract: An emulsion aggregation (EA) toner includes an amorphous polymeric resin, optionally a colorant, and a small molecule crystalline organic compound having molecular weight less than 1,000 g/mol and melting point less than the fusing temperature of the EA toner, wherein a mixture of the resin and the small molecule compound is characterized by a reduction in glass transition temperature from that of the resin and by the lack of a significant solid to liquid phase transition peak for the small molecule compound as determined by differential scanning calorimetry, the enthalpy of fusion for the small molecule compound in the mixture being measured to be less than 10% of the enthalpy of fusion of the compound in pure form. Furthermore, the EA toner may be configured to have a crease fix minimum fusing temperature (MFT) less than or equal to the crease fix MFT of a benchmark ultra-low-melt emulsion aggregation toner.
    Type: Application
    Filed: November 11, 2013
    Publication date: May 14, 2015
    Applicant: XEROX CORPORATION
    Inventors: JORDAN H. WOSNICK, Ke Zhou, Valerie M. Farrugia, Kentaro Morimitsu, Edward G. Zwartz
  • Publication number: 20150132692
    Abstract: A toner includes a polymeric resin, optionally a colorant, and a small molecule crystalline imide having a molecular weight less than 1,000 g/mol. The polymeric resin may be an amorphous resin and a mixture of the amorphous resin and the crystalline imide may be characterized by a reduction in glass transition temperature from that of the resin and by the lack of a melting point for the crystalline imide as determined by differential scanning calorimetry, the enthalpy of fusion for the crystalline imide in the mixture being measured to be less than 10% of the enthalpy of fusion of the crystalline imide in pure form. Furthermore, the toner may be configured to have a crease fix minimum fusing temperature (MFT) less than or equal to the crease fix MFT of a benchmark ultra-low-melt emulsion aggregation toner. Suitable crystalline imides may include N-alkyl and N-aryl imides, such as N-benzylphthalimide.
    Type: Application
    Filed: November 11, 2013
    Publication date: May 14, 2015
    Applicant: XEROX CORPORATION
    Inventors: JORDAN H. WOSNICK, Ke Zhou, Kentaro Morimitsu, Michael S. Hawkins, Edward G. Zwartz, Valerie M. Farrugia
  • Patent number: 9012114
    Abstract: An electrostatic charge image developing toner includes toner particles; and an external additive that is externally added to surfaces of the toner particles, in which a content of nitrogen atoms on the surfaces of the toner particles is from 0.8 atomic % to 5.0 atomic % and a content of nitrogen atoms at a depth of 10 nm inside from the surfaces of the toner particles is 0.4 atomic % or less when measured by X-ray photoelectron spectroscopy.
    Type: Grant
    Filed: October 8, 2013
    Date of Patent: April 21, 2015
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Noriyuki Mizutani, Tsuyoshi Murakami, Yukiaki Nakamura, Satoshi Kamiwaki
  • Patent number: 9012115
    Abstract: To provide a yellow toner having a colorant in a good dispersed state, obtained through excellent granulation performance and having stable developing performance, the yellow toner contains a binder resin, a wax and a colorant, and is characterized by containing as the colorant a compound represented by the following general formula (1) and a compound represented by the following general formula (2).
    Type: Grant
    Filed: June 21, 2012
    Date of Patent: April 21, 2015
    Assignee: Canon Kabushiki Kaisha
    Inventors: Takayuki Ujifusa, Taichi Shintou, Yutaka Tani, Masao Nakano, Kaoru Takahashi, Satoshi Saito, Takeshi Miyazaki, Masashi Hirose
  • Patent number: 8993208
    Abstract: A foil transferring method employing an electrophotography is disclosed, in which a toner used for forming a foil transferring layer contains at least a vinyl based resin and a polyester based resin as a binder resin and an amount of the vinyl based resin is 50 to 95% by weight based on the total amount of the binder resin.
    Type: Grant
    Filed: April 4, 2012
    Date of Patent: March 31, 2015
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Asao Matsushima, Tatsuya Nagase, Yasuko Uchino, Aya Shirai, Ryuichi Hiramoto, Michiyo Fujita