Inorganic Silicon Compound Adjuvant Patents (Class 430/108.7)
  • Patent number: 7316880
    Abstract: A toner for developing an electrostatic charge image comprising a resin, a colorant, and a particle having domain-matrix structure and the particle having two or more kinds of metal elements.
    Type: Grant
    Filed: August 23, 2004
    Date of Patent: January 8, 2008
    Assignee: Konica Minolta Holdings, Inc.
    Inventors: Yasuko Yamauchi, Hiroshi Yamazaki, Masafumi Uchida, Kenji Yamane
  • Patent number: 7314696
    Abstract: Toners and developers are disclosed. The toner of the present invention contains at least one toner resin, at least one charge control agent, at least one surface treatment agent, and optionally at least one release agent and/or colorant. The toners of the present invention have excellent triboelectric stability over a wide range of temperatures and relative humidity environmental conditions. Further, the toners of the present invention have excellent charge to mass stability over long periods of time. Development systems and methods for developing electrostatic images with toner are further disclosed.
    Type: Grant
    Filed: June 13, 2001
    Date of Patent: January 1, 2008
    Assignee: Eastman Kodak Company
    Inventors: Robert D. Fields, Patrick M. Lambert, Dinesh Tyagi, James H. Anderson
  • Publication number: 20070298343
    Abstract: The invention relates to a developer for developing electrostatic images. The developer includes magnetic carrier particles at a loading of from 60 to 99 weight percent of the developer. Toner particles are at a loading of 1 to 40 weight percent of the developer. The toner particles include a resin core particle having an outer surface and 0.05 to 5 weight percent a first metal oxide powder is substantially fixed to the outer surface. The toner particles further include 0.05 to 2 weight percent of a second metal oxide powder that is substantially free to transfer between outer surface of the toner particles and an outer surface of the magnetic carrier surface.
    Type: Application
    Filed: June 23, 2006
    Publication date: December 27, 2007
    Inventors: Kevin D. Lofftus, Satyanarayan Srinivsan, David D. Putnam, Peter S. Alexandrovich
  • Patent number: 7312009
    Abstract: The present invention relates to a non-magnetic mono-component toner comprising a toner mother particle, and a coating layer formed on the mother particle where the coating layer comprises fatty acid metal salt having average particle size of 0.05 to 3.0 ?m, a first organic particle having average particle size of 0.3 to 2.0 ?m, a second organic particle having average particle size of 0.05 to 0.25 ?m, and silica having average particle size of 0.006 to 0.04 ?m. The color toner has narrow charge distribution, high chargeability, a low environmental dependence, and excellent image quality, transfer efficiency, and long-term stability by significantly reducing the contamination of the charging elements.
    Type: Grant
    Filed: May 13, 2005
    Date of Patent: December 25, 2007
    Assignee: LG Chem, Ltd
    Inventors: Hyeung-Jin Lee, Joo-Yong Park, Chang-Soon Lee
  • Patent number: 7309554
    Abstract: A negatively chargeable toner containing: resin particles containing a colorant; and an external additive which coats the surface of the resin particles, wherein the external additive contains; first silica particles having a number mean primary particle size of 5 to 20 nm and second silica particles having a number mean primary particle size of 30 to 50 nm; surface-modified silica particles which are surface modified by wet treatment using an oxide or hydroxide of at least one metal selected from the group consisting of titanium, tin, zirconium and aluminum, and are further subjected to hydrophobic treatment; and aluminum oxide-silicon dioxide composite oxide particles obtained by flame hydrolysis and hydrophobic treatment.
    Type: Grant
    Filed: July 15, 2004
    Date of Patent: December 18, 2007
    Assignee: Seiko Epson Corporation
    Inventor: Nobuhiro Miyakawa
  • Patent number: 7309556
    Abstract: A developer includes black toner particles and carrier particles, the black toner particles including at least one binder, at least one black colorant and one or more external additives, wherein the toner particles comprise from about 7 to about 15 pph of the developer, and wherein the toner particles exhibit a triboelectric charge of from about ?25 to about ?50 ?C/g at toner particle concentrations of about 7 to about 15 pph of the developer. The developer is ideally suited for use in a high speed (greater than 100 prints per minute) semiconductive magnetic brush development apparatus. Preferably, the black toner particles include a styrene acrylate binder, and the external additives include from about 1.3 to about 2.1% by weight of the toner particles of a first silica having an average particle size of from about 35 to about 45 nm, from about 0.5 to about 1.0% by weight of the toner particles of a second silica having an average particle size of from about 135 to about 160 nm, and from about 0.
    Type: Grant
    Filed: March 21, 2005
    Date of Patent: December 18, 2007
    Assignee: Xerox Corporation
    Inventors: Maria N. V. Mc Dougall, Richard P. N. Veregin, Vladislav Skorokhod, Mary L. Mc Stravick, Deepak R. Maniar, Paul W. Morehouse, Jr., Rachael L. Mc Grath, Jackie Parker, Shigang Qui, Mary B. Schlitzer, Michael D. Thompson, Christopher M. Pattison, Thomas C. Dombroski
  • Publication number: 20070287090
    Abstract: A toner having a BET specific surface area of from 1.5 to 3.5 m2/g, obtainable by a process including the steps of; step (1): pulverizing a toner composition containing at least a resin binder and a colorant in the presence of fine inorganic particles having an average primary particle size of from 6 to 20 nm to obtain mother toner particles having a volume-median particle size of from 3 to 8 ?m; and step (2): externally adding silica having an average primary particle size of from 25 to 60 nm to the mother toner particles obtained in the above step (1). The toner of the present invention is suitably used for, for example, developing a latent image formed in electrophotography, electrostatic recording method, electrostatic printing method, or the like.
    Type: Application
    Filed: June 6, 2007
    Publication date: December 13, 2007
    Applicant: Kao Corporation
    Inventor: Akihiro Eida
  • Publication number: 20070281233
    Abstract: A toner comprising a resin and having on a surface thereof, an additive package comprising coated strontium titanate.
    Type: Application
    Filed: May 31, 2006
    Publication date: December 6, 2007
    Inventor: Thomas R. Pickering
  • Publication number: 20070281232
    Abstract: A toner, and an electrophotographic apparatus and an electrophotographic process cartridge using the toner are provided having excellent charge stability without adversely affecting electric properties of the toner even when used for a long period of time and having excellent image density stability without bringing about image deletion and blurring. The toner includes colored particles containing at least a binder resin and a colorant, and two or more external additives. At least one of the external additives includes hydrophobic treated mesoporous particles, and the mesoporous particles are inorganic particles of at least one type selected from the group consisting of silica, titanium oxide, alumina, cerium oxide, and strontium titanate.
    Type: Application
    Filed: May 29, 2007
    Publication date: December 6, 2007
    Applicant: CANON KABUSHIKI KAISHA
    Inventor: Kimihiro Yoshimura
  • Publication number: 20070254230
    Abstract: A process for toner preparation includes forming toner particles by mixing an emuslion comprising at least binder resin and a colorant, aggregating the toner particles, and blending external additives with the toner particles in a blender to form a toner, wherein the blender has a blend intensity of from about 90.5 to about 100.5 W/lb, a specific blend energy of from about 20.3 to about 35.3 W-h/lb and a blender loading density of from about 0.25 to about 0.55 lb/L.
    Type: Application
    Filed: June 26, 2006
    Publication date: November 1, 2007
    Applicant: XEROX CORPORATION
    Inventors: Juan A. Morales-Tirado, Daniel A. Harrington, William H. Hollenbaugh, Vladislav Skorokhod, Wafa F. Bashir, Jackie B. Parker, Robert E. Grace, James M. Chappell, Karen A. Moffat, Richard P.N. Veregin, Cuong Vong
  • Patent number: 7288352
    Abstract: A toner composition including a binder, a colorant, and a surface additive package including a surface treated silica, a surface treated titania, and magnesium stearate.
    Type: Grant
    Filed: May 3, 2005
    Date of Patent: October 30, 2007
    Assignee: Xerox Corporation
    Inventor: Thomas R. Pickering
  • Publication number: 20070218383
    Abstract: An image forming apparatus including an image bearer; a charging device charging the image bearer; a light irradiating device irradiating the charged image bearer with light to form an electrostatic image; a developing device developing the electrostatic image with a developer including a toner to form a toner image on the image bearer; a transfer device transferring the toner image; and a cleaning device cleaning the image bearer, wherein the volume average particle diameter of the toner is greater than 5.0 ?m and less than 5.5 ?m, the content of toner particles having a particle diameter of not greater than 4.0 ?m is not higher than 20% by number, the ratio of the first shape factor SF-1 to the second shape factor SF-2 is from 1.00 to 1.15, and the content of toner particles having a SF-2 of not less than 115 is not less than 67.8% by number.
    Type: Application
    Filed: March 16, 2007
    Publication date: September 20, 2007
    Inventors: Takuya Seshita, Toyoshi Sawada, Tomomi Suzuki, Tsuneyasu Nagatomo, Satoshi Kojima
  • Publication number: 20070207399
    Abstract: Toner for electrostatic charge development wherein no scumming occurs, and toner leakage caused by charge defect of the toner on a developing roller can be inhibited, and an excellent image stability is obtained is provided.
    Type: Application
    Filed: March 2, 2007
    Publication date: September 6, 2007
    Inventors: Takuya KADOTA, Masayuki Hagi, Yoshihiro Mikuriya, Katsunori Kurose, Hiroaki Kato, Atsushi Yamamoto, Yoshimichi Ishikawa, Masahide Inoue, Minoru Nakamura, Hideaki Yasunaga
  • Publication number: 20070202426
    Abstract: An object of the present invention is to provide a two-component developer that suppresses burying of an external additive into toner particles and a change in charging performance of a toner with time, and secures stable development performance. To achieve this object, the two-component developer of the present invention including a toner containing resin microparticles and silica microparticles and a carrier containing resin coat layers is adjusted so that a rate of change ?A % in BET specific surface area A (m2/g) of the toner (=((A120?A1)/A1)×100) and a rate of change ?C % in charge quantity C (?C/g) of the carrier (=((C120?C1)/C1)×100) when a mixture of the toner and the carrier is stirred and mixed by a TURBULA shaker mixer are both within 10%.
    Type: Application
    Filed: February 21, 2007
    Publication date: August 30, 2007
    Applicant: KYOCERA MITA CORPORATION
    Inventor: Seiji Kikushima
  • Patent number: 7258959
    Abstract: The object of the present invention is to provide a developer having a sharp charge amount distribution and bringing out high-quality image without substantially smearing a charging unit, developing units, a photoconductor, and an intermediate transferring member by the developer, namely, a developer capable of providing an appropriate image density and exhibiting extremely little background smear even when used over a long period of time and repeatedly used for a number of sheets of paper as well as to provide an image forming apparatus for electrophotography using the developer.
    Type: Grant
    Filed: September 26, 2005
    Date of Patent: August 21, 2007
    Assignee: Ricoh Company, Ltd.
    Inventors: Shinya Nakayama, Satoshi Mochizuki, Yasuaki Iwamoto, Yasuo Asahina, Kazuhiko Umemura, Hideki Sugiura, Hisashi Nakajima, Tomoyuki Ichikawa, Tomoko Utsumi, Koichi Sakata, Akihiro Kotsugai, Osamu Uchinokura, Masayuki Ishii
  • Publication number: 20070190443
    Abstract: A toner including toner particles including a binder resin, a colorant and a release agent, and an external additive including a first particulate inorganic material having a formula of MgxSiyOx+2y where each of x and y is an integer, and a number average secondary particle diameter of from 0.02 ?m to 2 ?m, wherein the first atomic ratio (Mg/Si) s in a surface portion of the first particulate inorganic material is not greater than (preferably less than) the second atomic ratio (Mg/Si)e in the entire first particulate inorganic material. Alternatively, a toner including toner particles including a binder resin and a colorant, and an external additive which includes a particulate inorganic material having a formula of MgxSiyOx+2y where each of x and y is an integer and which has a surface treated with a fatty acid.
    Type: Application
    Filed: February 1, 2007
    Publication date: August 16, 2007
    Inventors: Masayuki Hagi, Takuya Kadota, Hiroaki Katoh, Atsushi Yamamoto, Katsunori Kurose, Yoshihiro Mikuriya, Masahide Inoue, Hideaki Yasunaga, Minoru Nakamura, Yoshimichi Ishikawa, Hiroyuki Murakami
  • Patent number: 7252915
    Abstract: The present invention relates to a magnetic mono-component toner composition, and more particularly to a mono-component toner composition that comprises magnetic toner particle comprising a binder resin, a magnetic component, and a charge control agent; a hydrophobic treated silica having a specific surface area of 20 to 80 m2/g; a hydrophobic treated silica having a specific surface area of 130 to 230 m2/g; and a metal oxide fine powder. A magnetic mono-component toner composition of the present invention has such good flowability that it provides smooth toner supply even when the developing roller surface has been worn due to long time use, and it has such excellent uniform chargeability that it prevents image deterioration (“wave” patterns of toner may form on developing roller, that is, magnetic sleeve) by forming an uniform toner layer on the developing roller.
    Type: Grant
    Filed: December 24, 2002
    Date of Patent: August 7, 2007
    Assignee: LG Chem, Ltd.
    Inventors: Won-Sup Lee, Chang-Soon Lee, In-Hee Lim
  • Patent number: 7252916
    Abstract: A non-magnetic one-constituent developing agent is an electro-photographic developing agent that provides high quality images without fogging, scattering of toners and ineffective development by maintaining stable charges and a uniform distribution of toners over an extended lifetime in a developing apparatus of an electro-photographic image processing device. In addition, the developing agent has deodorizing, anti-bacterial and sterilizing functions.
    Type: Grant
    Filed: August 25, 2004
    Date of Patent: August 7, 2007
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Duck-hee Lee, Jong-moon Eun
  • Patent number: 7250243
    Abstract: A nonmagentic one-component toner for an electrophotographic image forming apparatus includes a toner with toner particles, a binder resin having a coloring agent, a charging control agent, and a release agent, and an external additive added to the toner particles. The external additive includes approximately 0.1 to 3.0 wt % of silica having a charge opposite to the toner particles, approximately 0.1 to 3.0 wt % of silica having a same charge as the toner particles, and approximately 0.1 to 4.0 wt % of titanium dioxide.
    Type: Grant
    Filed: May 12, 2004
    Date of Patent: July 31, 2007
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Duck-hee Lee, Jong-moon Eun
  • Publication number: 20070160925
    Abstract: A developer contains a resin, a coloring agent, and an external additive in an amount of 2.5 to 4.5 weight parts added to the resin in an amount of 100 weight parts resin. The developer has an average volume mean particle diameter in the range of 4.5 to 6.5 ?m and a BET specific surface in the range of 2.45 to 3.74 m2/g. The external additive may be silica.
    Type: Application
    Filed: December 29, 2006
    Publication date: July 12, 2007
    Applicant: OKI DATA CORPORATION
    Inventor: Kenji Koido
  • Patent number: 7229735
    Abstract: A toner composition for use in a xerographic or electrostatographic imaging process. The toner composition includes a toner particle and an optional primary external surface additive and a friable external surface additive. The friable external surface additive may also be a material that is capable of functioning as a primary external surface additive. The friable external surface additive is generally larger than the primary surface additive and capable of having portions of the friable particle broken or abraded off during the imaging process. The particles that are abraded off the friable additive can replace the primary external additive particles that become embedded into toner particles during the development process. The friable additives contribute to reducing toner aging and provide a toner with satisfactory flow and triboelectric properties.
    Type: Grant
    Filed: July 26, 2004
    Date of Patent: June 12, 2007
    Assignee: Xerox Corporation
    Inventors: Thomas R. Pickering, Louis V. Isganitis
  • Patent number: 7217486
    Abstract: The present invention provides a toner containing toner mother particles containing a binder resin and a colorant having added thereinto external additives, e.g., positively electrifiable silica fine particles, negatively electrifiable silica fine particles, titanium oxide fine particles and a long chain fatty acid or a salt thereof, wherein the external additives are added by multistage process, thereby is low in desorption of external additives, has the electrification property for a long period of time, shows high flowability and transfer efficiency, and is not accompanied by the reduction of image density.
    Type: Grant
    Filed: January 16, 2004
    Date of Patent: May 15, 2007
    Assignee: Seiko Epson Corporation
    Inventors: Hiroshi Kato, Nobuhiro Miyakawa
  • Patent number: 7208252
    Abstract: Magnetic toner compositions, conductive developer compositions, and methods for producing images in a hybrid jumping development system, more specifically, in a magnetic ink character recognition system, are disclosed. The developer compositions contain coated magnetic toner particles and coated carrier particles. The toner compositions include a resin, colorant, wax, magnetic component, and surface additives of coated silica, titania, and zinc stearate.
    Type: Grant
    Filed: June 30, 2004
    Date of Patent: April 24, 2007
    Assignee: Xerox Corporation
    Inventors: Michael L. Grande, William H. Hollenbaugh, Jr.
  • Patent number: 7189485
    Abstract: A toner having high mechanical strength and being capable of exhibiting a sufficient fixing property in a wide temperature range is provided. Further, a fixing device and an image forming apparatus in which such a toner can be suitably used are provided. The toner contains polyester-based resin as a main resin component, and the acid value of the toner is 8.0 KOHmg/g or less. The polyester-based resin includes block polyester mainly composed of a block copolymer, and amorphous polyester having crystallinity lower than that of the block polyester. The block polyester has a crystalline block obtained by the condensation of a diol component with a dicarboxylic acid component and an amorphous block having crystallinity lower than that of the crystalline block.
    Type: Grant
    Filed: October 20, 2003
    Date of Patent: March 13, 2007
    Assignee: Seiko Epson Corporation
    Inventors: Soichi Yamazaki, Hiroyuki Murakami
  • Patent number: 7187396
    Abstract: Laser marking of plastic material is achieved by incorporating into the plastic a laser marking particulate additive having a particle size of less than 100 nm. A mixed oxide particle of tin and antimony having a particle size of 10–70 nm is useful as a laser marking additive when using a YAG laser. A metallic powder can further be added to improve marking contrast.
    Type: Grant
    Filed: November 1, 2004
    Date of Patent: March 6, 2007
    Assignee: Engelhard Corporation
    Inventors: James B. Carroll, Jr., Steven A. Jones
  • Patent number: 7160663
    Abstract: A toner includes toner particles and an inorganic fine powder mixed with the toner particles. The toner particles contain a binder resin, a coloring agent, a releasing agent, and a sulfur-containing resin. The toner particles contain at least one element selected from the group consisting of magnesium, calcium, barium, zinc, aluminum, and phosphorus and satisfy the relationship: 4?T/S?30 wherein T represents the total content of the element in ppm, and S represents the content of sulfur in ppm. The weight-average particle diameter (D4) of the toner is in the range of 3 to 10 ?m. The average circularity of the toner is within the range of 0.950 to 0.995.
    Type: Grant
    Filed: March 25, 2004
    Date of Patent: January 9, 2007
    Assignee: Canon Kabushiki Kaisha
    Inventors: Keiji Komoto, Yasushi Katsuta, Yushi Mikuriya, Takeshi Kaburagi, Emi Tosaka
  • Patent number: 7160662
    Abstract: The present invention relates to an image forming method including: a charging step; an electrostatic latent image forming step; a developing step; a transfer step; a fixing step; and a cleaning step, wherein an electrostatic latent image developing agent comprises a toner and a carrier, wherein particles which have a volume resistivity of at least 1×1014 ?cm and an average primary particle diameter of 50 nm or less has a higher covering ratio than other particles on the toner particle surfaces, a shape factor SF1 of the toner is in the range of from 100 to 140, the carrier is a resin coated carrier, and at least a coating resin layer comprises a positively charging resin and a quaternary ammonium salt compound.
    Type: Grant
    Filed: December 11, 2003
    Date of Patent: January 9, 2007
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Susumu Yoshino, Yoshifumi Iida, Seki Yamaguchi, Motoko Sakai, Sueko Sakai
  • Patent number: 7157200
    Abstract: A black toner of toner particles including at least one binder, at least one black colorant, and a package of external additives is described, wherein the at least one binder includes a styrene acrylate binder and wherein the external additives include each of a first silica having an average particle size of from about 35 to about 45 nm, a second silica having an average particle size of from about 135 to about 160 nm, and a titania having an average particle size of from about 35 to about 45 nm. Also described is a developer that includes the black toner and carrier particles comprising a core of ferrite coated with a coating comprising a polymethyl methacrylate polymer and fluoro-copolymer, carbon black and melamine beads. The black toner and developer are preferably used in a semiconductive magnetic brush development system.
    Type: Grant
    Filed: May 6, 2004
    Date of Patent: January 2, 2007
    Assignee: Xerox Corporation
    Inventors: Mary L. Mc Stravick, Paul C. Julien, Sue E. Blaszak, William H. Hollenbaugh, Jr.
  • Patent number: 7150953
    Abstract: A developer capable of providing an excellent image without causing a charging failure even after a long-term and repeated use contains a toner particle having a binder resin and a colorant, an inorganic fine particle, and a conductive fine particle, in which a volume average particle diameter Da of the conductive fine particle and an number average primary particle diameter Db of the inorganic fine particle satisfy the expression (1) below, and a rate of liberation “a” of the conductive fine particle from the toner particle is 40 to 95% and a rate of liberation “b” of the inorganic fine particle from the toner particle is 0.1 to 5% Da?10Db.
    Type: Grant
    Filed: September 12, 2003
    Date of Patent: December 19, 2006
    Assignee: Canon Kabushiki Kaisha
    Inventors: Katsuhisa Yamazaki, Takashige Kasuya, Tsuyoshi Takiguchi, Kaori Hiratsuka
  • Patent number: 7144666
    Abstract: A toner having toner particles containing a binder resin and a colorant; and a first external additive having 0.1 to 3.0 wt % of large silica particles with an average particle size of 20 to 200 nm; a second external additive having 0.1 to 3.0 wt % of small silica particles with an average particle size of 5 to 20 nm; a third external additive having 0.1 to 2.0 wt % of hydrophobic titanium dioxide microparticles with a resistance of 105 to 1012 ?cm; and a fourth external additive having at least one of 0.1 to 2.0 wt % of conductive titanium dioxide particles with a resistance of 1 to 105 ?cm and 0.1 to 2.0 wt % of positively chargeable aluminum oxide particles. Therefore, a thin toner layer with a uniform toner amount is formed on a toner carrier and stable charge distribution and toner flowability are maintained for a long time, thereby resulting in prevention of fog and toner scattering, and improvements in developing efficiency and toner durability.
    Type: Grant
    Filed: February 20, 2004
    Date of Patent: December 5, 2006
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Duck-hee Lee, Jong-moon Eun
  • Patent number: 7141344
    Abstract: An image-forming process, which comprises steps of developing an electrostatic latent image on an inorganic photoreceptor with an electrostatic image developer containing 0.1 to 5.0% by weight, based on the toner particles, of silicon carbide fine powder of 0.2 to 1.5 ?m in average primary particle size, 10 to 50 m2/g in specific surface area and 10 to 60% in amount of agglomerated particles, said silicon carbide fine powder being contained in an amount of 0.1 to 5.0% by weight, transferring the developed image to a transfer member, then removing residual toner particles on the photoreceptor by means of a cleaning blade.
    Type: Grant
    Filed: October 28, 2003
    Date of Patent: November 28, 2006
    Assignees: Toyo Ink Manufacturing Co., Ltd., Fujimi Incorporated
    Inventors: Yasushi Nakanishi, Hirofumi Iemura, Shigehiro Hayashi
  • Patent number: 7141343
    Abstract: A toner exhibits excellent image characteristics, and also has an excellent charging property even if the toner is used in a cleaning-simultaneous-with-developing system having a direct injection charging mechanism. The toner includes toner particles and non-magnetic metallic-compound fine particles. The weight average particle diameter of the toner is 3.0 ?m to 12.0 ?m. The metallic-compound fine particles are conductive metallic-compound fine particles having a specific surface area (cm2/cm3) of 5×105 to 100×105; a medium diameter (D50) of 0.4 ?m to 4.0 ?m with respect to a volume-based particle diameter distribution, the medium diameter (D50) being smaller than the weight average particle diameter of the toner; and a 90% particle diameter D90 of 6.0 ?m or less with respect to a volume-based particle diameter.
    Type: Grant
    Filed: April 18, 2003
    Date of Patent: November 28, 2006
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tsuyoshi Takiguchi, Yosuke Morikawa, Takashige Kasuya, Kimihiro Yoshimura, Katsuhisa Yamazaki, Kaori Hiratsuka
  • Patent number: 7135263
    Abstract: In a toner having toner particles which have toner base particles having at least a colorant and a binder resin, and an inorganic fine powder; the inorganic fine powder has a primary-particle average particle diameter of from 30 nm to 300 nm, and has particles having at least one of a cubic particle shape, a cube-like particle shape, a rectangular particle shape and a rectangle-like particle shape and having perovskite type crystals; and the inorganic fine powder has particles and agglomerates both having particle diameters of 600 nm or more, in a content of 0% to 1% by number.
    Type: Grant
    Filed: September 8, 2004
    Date of Patent: November 14, 2006
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hiroaki Kawakami, Fumihiro Arahira, Masayuki Hama, Noriyoshi Umeda
  • Patent number: 7097952
    Abstract: An electrophotographic toner is formed as a blend of toner particles and external additives. The external additives include (1) first inorganic fine particles having an average primary particle size of 80-800 nm of oxide of a metal selected from the group consisting of titanium, aluminum, zinc and zirconium, (2) second inorganic fine particles other than silica having an average primary particle size of below 80 nm and (3) silica fine particles having an average primary particle size of below 30 nm. As a result, the toner can be made free from difficulties, such as melt-sticking onto an image-bearing member in a low humidity environment, roughening of halftone images in a low humidity environment, toner blot-down after storage at high temperatures or in continuous image formation on a large number of sheets, fog in continuous formations of images of low color area percentage in a low humidity environment, and re-transfer in multi-color image formation.
    Type: Grant
    Filed: May 10, 2005
    Date of Patent: August 29, 2006
    Assignee: Canon Kabushiki Kaisha
    Inventors: Keita Nozawa, Atsushi Kubo, Masanori Ito, Tomoaki Igarashi, Kiyokazu Suzuki
  • Patent number: 7097951
    Abstract: A toner of the present invention comprises at least a binder resin comprising as a main component a polyester resin, a wax, and a colorant, in which in case of measuring a wettability of the toner with respect to a mixed solvent of methanol and water in terms of an optical transimittance at an optical wavelength of 780 nm, a methanol concentration of the mixed solvent is in a range of 45 to 65% by volume when an optical transmittance is 80% and 10%, respectively; a melt index (MI) is of 0.1 to 10 g/10 min at a temperature of 125° C.
    Type: Grant
    Filed: August 29, 2005
    Date of Patent: August 29, 2006
    Assignee: Canon Kabushiki Kaisha
    Inventors: Syuhei Moribe, Hiroshi Yusa, Takashige Kasuya, Yoshihiro Ogawa
  • Patent number: 7083888
    Abstract: An external additive for electrostatically charged image developing toner is provided. The additive includes spherical hydrophobic fine silica particles having primary particles with a particle diameter of from 0.01 to 5 ?m and having been treated with a compound selected from the group consisting of a quaternary ammonium salt compound, a fluoroalkyl-group- or fluoroalkenyl-group- containing betaine compound and a silicone oil. The fine silica particles fulfill conditions (i) and (ii), as described in the disclosure. The external additive does not react or has no interaction with an organic photoreceptor and therefore change in quality does not occur or the photoreceptor is not scraped. Furthermore, it has a good flowability and therefore adhesion of a toner to the photoreceptor does not occur.
    Type: Grant
    Filed: September 6, 2001
    Date of Patent: August 1, 2006
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Muneo Kudo, Masaki Tanaka
  • Patent number: 7083770
    Abstract: The amorphous-silica particle having 0.1–0.7 ?m of the average particle diameter, 5–30 m2/g of the specific surface area, less than 40% of the dispersion coefficient, and 20 ?C/m2 of the absolute value of the triboelectrostatic charge, can be obtained, by setting flame temperature to more than melting point of silica, raising the silica concentration in a flame, and staying the generated silica particle in the flame for a short time to be grew up. Since this silica particle has a particle shape being near a true sphere, and a particle size of said particle is remarkably uniform, so it is suitable for a filler of a semiconductor sealing agent or various materials, etc. In addition, since said particle has strong electrification, it is also suitable for an outer or an inner additional agent of a toner for an electronic photograph, a photo conductor material for a electronic photograph, and a material of an electric charge transportation layer, etc.
    Type: Grant
    Filed: June 20, 2001
    Date of Patent: August 1, 2006
    Assignee: Nippon Aerosil Co., Ltd.
    Inventors: Takeyoshi Shibasaki, Kazuyoshi Honda, Masamichi Murota, Hirokuni Shirono
  • Patent number: 7070895
    Abstract: The present invention relates to a magnetic toner composition, and more particularly to a magnetic toner composition having an improved chargeability and excellent uniform chargeability, and that is capable of reducing a difference in electrostatic charge between a toner remaining in a cartridge or in a developing unit and that of a newly supplied toner. A magnetic toner composition of the present invention comprises magnetic toner particulate comprising a binder resin and a magnetic substance, a conductive fine powder having a specific surface area of 30 to 300 m2/g, a hydrophobic silica having a specific surface area of 100 to 240 m2/g, and an inorganic fine powder having an average diameter of 0.1 to 4.O ?m.
    Type: Grant
    Filed: December 20, 2002
    Date of Patent: July 4, 2006
    Assignee: LG Chem, Ltd.
    Inventors: In-Hee Lim, Chang-Soon Lee, Won-Sup Lee
  • Patent number: 7063927
    Abstract: A toner for electrostatic latent image development having coloring particles containing at least a binding resin, a coloring agent and a release agent, and an external additive, wherein a variation in a number average particle diameter of the coloring particles is 25 or less, an average circularity of the coloring particles is 0.975 or more, and a variation in a circularity of the coloring particles is 2.5 or less.
    Type: Grant
    Filed: September 11, 2003
    Date of Patent: June 20, 2006
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Masanobu Ninomiya, Toshiyuki Yano
  • Patent number: 7041420
    Abstract: A toner of the invention includes toner particles comprising a styrene acrylate binder and at least one colorant, and wherein the toner particles, in the absence of external additives, have a mean circularity of from about 0.94 to about 0.98 and a particle size distribution with a lower number ratio geometric standard deviation (GSD) of approximately 1.28 to approximately 1.31 and an upper volume GSD of approximately 1.24 to approximately 1.27. Also included is a set of toners for forming a color image, comprising a cyan toner, a magenta toner, a yellow toner and a black toner, wherein each of the cyan toner, the magenta toner, the yellow toner and the black toner, wherein each of about 70 to about 95% by weight, dry basis, of a styrene acrylate binder, about 5 to about 15% by weight, dry basis, of a wax dispersion, and at least one colorant.
    Type: Grant
    Filed: December 23, 2003
    Date of Patent: May 9, 2006
    Assignee: Xerox Corporation
    Inventors: Judith M. Vandewinckel, Vincenzo G. Marcello, Grazyna E. Kmiecik-Lawrynowicz, Tie Hwee Ng, Chieh-Min Cheng
  • Patent number: 7033718
    Abstract: A toner including toner particles including a binder resin and a colorant, wherein particles of the toner have such a rolling property as to relatively easily roll in one direction compared to other directions. It is preferable that the toner particles preferably have a spindle form and satisfies the following relationships: 0.5?(r2/r1)?0.8, 0.7?(r3/r2)?1.0, and r3?r2?r1, wherein r1, r2 and r3 represent an average major axis particle diameter, an average minor axis particle diameter and an average thickness of the toner particles. An image forming apparatus including at least an image bearing member; a developing device configured to develop an electrostatic latent image with a developer including the above-mentioned toner; a transferring device configured to transfer a toner image onto a receiving material; and a cleaning device configured to clean a surface of the image bearing member.
    Type: Grant
    Filed: November 14, 2003
    Date of Patent: April 25, 2006
    Assignee: Ricoh Company, Limited
    Inventors: Masami Tomita, Hiroaki Matsuda
  • Patent number: 7026087
    Abstract: A toner composition, comprising a binder resin, a wax, a copolymer and a colorant; the copolymer being a copolymer between an ?-olefin, maleic anhydride and maleic anhydride monoester.
    Type: Grant
    Filed: September 30, 2003
    Date of Patent: April 11, 2006
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Yoshihiro Mikuriya, Masahiro Anno, Katsunori Kurose, Masahide Inoue
  • Patent number: 7022447
    Abstract: The present invention provides a toner which ensures large mean charging amount and excellent transfer efficiency with no or little amount of reversely charged toner and provides an image forming apparatus using the same. The toner is produced by adding external additives to resin particles containing a coloring agent, wherein the external additives are silica particles and modified silica particles of which outer surfaces are modified with oxide or hydroxide of at least one metal selected from a group consisting of titanium, tin, zirconium, and aluminum, the amount of the modified silica particles being 1.5 times or less of the amount the silica particles. The image forming apparatus uses the toner.
    Type: Grant
    Filed: August 29, 2003
    Date of Patent: April 4, 2006
    Assignee: Seiko Epson Corporation
    Inventor: Nobuhiro Miyakawa
  • Patent number: 7018762
    Abstract: In a toner T of the present invention, the liberated mother particle ratio is set to be 10% or less and the liberated silica particle ratio is set to be 0.2–10%, thereby reducing the possibility that the liberated mother particles 18? and the mother particles 18 with silica particles 19 therein will be fused on toner-contact members such as a latent image carrier, a toner carrier, and a toner regulating member, and thus effectively preventing the filming of toner T. Therefore, according to the toner T of the present invention, the durability of the toner-contact members such as the latent image carrier, the toner carrier, and the toner regulating member can be improved.
    Type: Grant
    Filed: December 11, 2003
    Date of Patent: March 28, 2006
    Assignee: Seiko Epson Corporation
    Inventor: Takuya Kadota
  • Patent number: 7018763
    Abstract: The invention relates to a static latent image developing toner comprising toner particles, each of the toner particles comprising a toner intermediate particle having inorganic oxide particles on the surface, wherein a surface existence density of the inorganic oxide particle having a feret's diameter of 110 nm to 160 nm on the toner intermediate particle is 5 to 50 per ?m2, and relates to a developer comprising the toner and an image forming method utilizing the toner.
    Type: Grant
    Filed: May 20, 2003
    Date of Patent: March 28, 2006
    Assignee: Konica Corporation
    Inventors: Yoshiyasu Matsumoto, Ken Ohmura, Tatsuya Nagase, Kaori Soeda
  • Patent number: 7016632
    Abstract: Development systems and methods for developing using chemically prepared toners are disclosed. The present invention further discloses developers used in development systems. The use of chemically prepared toners with hard magnetic carrier particles with a non-magnetic, cylindrical shell for transporting developers provides excellent benefits with respect to image quality by reducing granularity and by providing a typically constant, stable developer life as shown by the consistent level of charge to mass over time during operation.
    Type: Grant
    Filed: June 23, 2003
    Date of Patent: March 21, 2006
    Assignee: Eastman Kodak Company
    Inventors: Jan Bares, James H. Anderson, Matthew Ezenyilimba, William K. Goebel
  • Patent number: 7014969
    Abstract: The present invention provides a silica fine particle capable of preventing a charging member or an image bearing member from being contaminated with toner when the toner contains the particle and also capable of providing the toner with a stable developing property. The silica fine particle of the present invention has been hydrophobic treated. Furthermore, the particle has a peak in a range of 0.04 ?m to 1 ?m and a peak in the range of 1 ?m to 100 ?m in a volume-basis particle diameter distribution. The particle has a frequency ratio of 10 to 80% for the particles with a particle diameter of 0.04 ?m to 1 ?m to a total of all the peaks, and the particles has the frequency ratio of less than 16% for the particles with a particle diameters of 20 ?m to 2000 ?m to the total of all the peaks.
    Type: Grant
    Filed: October 2, 2003
    Date of Patent: March 21, 2006
    Assignee: Canon Kabushiki Kaisha
    Inventors: Shinya Yachi, Yushi Mikuriya, Katsuyuki Nonaka, Shuntaro Watanabe
  • Patent number: 6990306
    Abstract: An image is formed by using in combination a photoreceptor having a surface roughness Rz not larger than 1.0 and a developing agent comprising a toner containing toner particles containing a binder resin and a coloring agent, silica particles, and a metal soap, the weight ratio of the silica particles to the metal soap falling within a range of between 10 and 60.
    Type: Grant
    Filed: June 12, 2003
    Date of Patent: January 24, 2006
    Assignees: Kabushiki Kaisha Toshiba, Toshiba Tec Kabushiki Kaisha
    Inventor: Takahiro Mochizuki
  • Patent number: 6972166
    Abstract: An electrophotographic toner is formed as a blend of toner particles and external additives. The external additives include (1) first inorganic fine particles having an average primary particle size of 80-800 nm of oxide of a metal selected from the group consisting of titanium, aluminum, zinc and zirconium, (2) second inorganic fine particles other than silica having an average primary particle size of below 80 nm and (3) silica fine particles having an average primary particle size of below 30 nm. As a result, the toner can be made free from difficulties, such as melt-sticking onto an image-bearing member in a low humidity environment, roughening of halftone images in a low humidity environment, toner blot-down after storage at high temperatures or in continuous image formation on a large number of sheets, fog in continuous formations of images of low color area percentage in a low humidity environment, and re-transfer in multi-color image formation.
    Type: Grant
    Filed: December 23, 2003
    Date of Patent: December 6, 2005
    Assignee: Canon Kabushiki Kaisha
    Inventors: Keita Nozawa, Atsushi Kubo, Masanori Ito, Tomoaki Igarashi, Kiyokazu Suzuki
  • Patent number: 6919156
    Abstract: A toner comprising a resin binder, a colorant, and fine inorganic particles having a BET specific surface area of 30 m2/g or less, wherein the fine inorganic particles are added as an external additive, wherein the toner has a storage modulus at 100° C. using a 25 mm parallel plate of 7×104 Pa or less, a storage modulus at 60° C. using a 7.9 mm parallel plate of from 3×108 to 1×109 Pa, and a storage modulus at 70° C. using a 7.9 mm parallel plate of from 7×106 to 3×108 Pa; and a two-component developer comprising the toner. The toner can be used for the development of a latent image formed in electrophotography, electrostatic recording method, electrostatic printing method or the like.
    Type: Grant
    Filed: September 25, 2003
    Date of Patent: July 19, 2005
    Assignee: Kao Corporation
    Inventors: Koji Kameyama, Masahito Yamazaki, Koji Akiyama, Hiroyuki Kawaji