In Situ Polymerization To Form Shell, Followed By Polymerization To Form Core Patents (Class 430/137.12)
-
Patent number: 9811015Abstract: In accordance with an embodiment, a toner particle comprises two or more glass transition temperatures. Wherein, a first glass transition temperature is within a range from 5 degrees centigrade to 20 degrees centigrade and a second glass transition temperature is within a range from 50 degrees centigrade to 65 degrees centigrade.Type: GrantFiled: November 23, 2015Date of Patent: November 7, 2017Assignees: KABUSHIKI KAISHA TOSHIBA, TOSHIBA TEC KABUSHIKI KAISHAInventors: Takashi Urabe, Taishi Takano, Junichi Ishikawa, Maiko Yoshida
-
Patent number: 9541851Abstract: A low energy consumption monochrome particle includes a core latex having a core a glass transition temperature and a weight average molecular weight. A shell encapsulates the core and includes a shell latex having a shell glass transition temperature and a weight average molecular weight. The glass transition temperature of the shell latex is higher than the glass transition temperature of the core latex. The weight average molecular weight of the shell latex is lower or higher than the weight average molecular weight of the core latex. The low energy consumption monochrome particles are suitable for high speed printing in SCD systems while decreasing minimum fusing temperature, maintaining excellent hot offset and storage, and exhibiting a matte finish.Type: GrantFiled: December 3, 2013Date of Patent: January 10, 2017Assignee: XEROX CORPORATIONInventors: Grazyna E. Kmiecik-Lawrynowicz, Robert D. Bayley, Maura A. Sweeney, Daniel A. Asarese, Susan J. Lafica
-
Publication number: 20150072282Abstract: An electrostatic latent image developing toner includes toner particles. Each toner particle includes a toner core containing a binder resin, a shell layer coating a surface of the toner core, and particulates having a higher hardness than the shell layer. Each shell layer contains a thermosetting resin, and the particulates are present within the shell layer. Preferably, the content of the particulates having a higher hardness than the shell layer is 0.1% by mass or more and 5.0% by mass or less with respect to a total amount of the toner particles.Type: ApplicationFiled: September 10, 2014Publication date: March 12, 2015Applicant: KYOCERA Document Solutions Inc.Inventor: Seiji OKADA
-
Patent number: 8940468Abstract: Disclosed is a process for production of a decolorable toner, including: aggregating dispersed fine particles of a color material comprising at least a color-forming compound, a color-developing agent and a decoloring agent with dispersed fine particles comprising at least a binder resin comprising a polyester resin to form aggregates in an aqueous medium, adding a reactive polymer having an oxazoline group in to the aqueous medium, and fusing the aggregates in the aqueous medium. As a result, it becomes possible to produce a decolorable toner which suppresses the generation of fine powder due to the release of fine particles of an erasable color material from the toner.Type: GrantFiled: June 29, 2012Date of Patent: January 27, 2015Assignee: Toshiba Tec Kabushiki KaishaInventors: Takayasu Aoki, Takafumi Hara, Tsuyoshi Itou, Masahiro Ikuta, Motonari Udo, Koji Shimokusa, Hiroshi Mizuhata
-
Patent number: 8916098Abstract: A continuous emulsion aggregation process for the production of particles is presented including a plurality of continuous stirred-tank reactors (CSTR). The plurality of continuous stirred-tank reactors includes at least one feed tank of raw materials, at least one reactor for facilitating cold addition, at least two reactors for facilitating an aggregation process, at least one reactor for facilitating a shell addition process; at least one reactor for facilitating a freeze process, at least one reactor for facilitating a chelating process, at least one reactor for facilitating a ramp-up process and at least one reactor for facilitating a coalescence process, wherein the reactors are sequentially assembled in a series configuration and separated by short conduits to produce toner particles that are narrowly distributed.Type: GrantFiled: March 28, 2012Date of Patent: December 23, 2014Assignee: Xerox CorporationInventors: Santiago Faucher, Kimberly Nosella, David Thomas Borbely, Gaetano Lavigne, Simon Burke
-
Patent number: 8785097Abstract: Disclosed is a decolorable toner produced by aggregating dispersed fine particles of a color material containing at least a color-forming compound, a color-developing agent and a decoloring agent with dispersed fine particles containing at least a binder resin having a carboxyl group, then adding a compound having a carbodiimide group or an epoxy group reactive with the carboxyl group of the binder resin, and thereafter fusing the aggregate particles, respectively in an aqueous medium. The thus obtained decolorable toner can suppress the generation of fine powder by the release of erasable color material fine particles from the toner particles.Type: GrantFiled: June 29, 2012Date of Patent: July 22, 2014Assignee: Toshiba Tec Kabushiki KaishaInventors: Takayasu Aoki, Motonari Udo, Tsuyoshi Itou, Masahiro Ikuta, Takafumi Hara
-
Patent number: 8663565Abstract: A continuous emulsion aggregation process for the production of particles is presented including a plurality of continuous stirred-tank reactors (CSTR). The plurality of continuous stirred-tank reactors includes at least one feed tank of raw materials, at least one reactor for facilitating cold addition, at least two reactors for facilitating an aggregation process, at least one reactor for facilitating a shell addition process; at least one reactor for facilitating a freeze process, at least one reactor for facilitating a chelating process, at least one reactor for facilitating a ramp-up process and at least one reactor for facilitating a coalescence process, wherein the reactors are sequentially assembled in a series configuration and separated by short conduits to produce toner particles that are narrowly distributed.Type: GrantFiled: February 11, 2011Date of Patent: March 4, 2014Assignee: Xerox CorporationInventors: Santiago Faucher, Kimberly D. Nosella, David Thomas Borbely, Gaetano Lavigne, Simon C. Burke
-
Patent number: 8642239Abstract: A toner for developing an electrostatic charge image includes a core layer including a first binder resin, a colorant and a releasing agent; and a shell layer coating the core layer and including a second binder resin. The first binder resin of the core layer includes a low molecular weight amorphous polyester resin having a weight-average molecular weight of about 6000 g/mol to about 20000 g/mol, a high molecular weight amorphous polyester resin having a weight-average molecular weight of about 25000 g/mol to about 100000 g/mol, and a crystalline polyester resin having a weight-average molecular weight of about 8000 g/mol to about 30000 g/mol. The second binder resin of the shell layer includes the low and high molecular weight amorphous polyester resins.Type: GrantFiled: January 10, 2012Date of Patent: February 4, 2014Assignee: Samsung Electronics Co., Ltd.Inventors: Jin-mo Hong, Takeshi Yoshida, Sung-jin Park
-
Patent number: 8628852Abstract: Disclosed are core-shell resin particles (C2) each comprising one or more film-like shell layers (P) comprising a resin (a) which is a polyurethane resin and a core layer (Q) comprising a resin (b). A core-shell resin particle (C2) is characterized in that the weight ratio between (P) and (Q) is from 0.1:99.9 to 70:30, the volatile content in the resin particle (C2) is not more than 2 weight %, and the content of vinyl resins in the resin (b) is not more than 30 weight %. Such resin particles have a uniform particle diameter and are excellent in electrostatic properties, thermal and storage stability and thermal characteristics.Type: GrantFiled: July 27, 2006Date of Patent: January 14, 2014Assignee: Sanyo Chemical Industries Ltd.Inventors: Takashi Akutagawa, Tsuyoshi Izumi
-
Patent number: 8586278Abstract: A method of producing an electrostatic image developing toner comprising toner particles comprising a binder resin containing at least a non-crystalline polyester resin having a crosslinking structure and a crystalline polyester resin, the method comprising the steps of (a-1) preparing a crystalline polyester resin particle aqueous dispersion liquid; (a-2) preparing a polymerizable unsaturated non-crystalline polyester resin aqueous dispersion liquid; (b) preparing crosslinking non-crystalline polyester resin particles by adding a radical polymerization initiator to the aqueous dispersion liquid of particles containing the non-crystalline polyester resin having a polymerizable unsaturated bond; (c) preparing core particles by aggregating at least the particles containing the crystalline polyester resin in an aqueous medium; and (d) preparing a shell layer containing the non-crystalline polyester resin having a crosslinking structure by fusing the particles containing the non-crystalline polyester resin havingType: GrantFiled: October 13, 2011Date of Patent: November 19, 2013Assignee: Konica Minolta Business Technologies, Inc.Inventors: Mikihiko Sukeno, Hajime Tadokoro, Ken Ohmura, Tatsuya Nagase, Tomomi Oshiba, Kenji Hayashi, Saburou Hiraoka, Tomoko Mine
-
Patent number: 8530131Abstract: Toner particles are provided which may, in embodiments, include a core and a shell, one or both of which may include a polyester gel. The gel in the shell and/or core may prevent a crystalline resin in the core from migrating to the toner surface.Type: GrantFiled: August 27, 2008Date of Patent: September 10, 2013Assignee: Xerox CorporationInventors: Ke Zhou, Karen Ann Moffat, Maria N. V. McDougall, Edward G. Zwartz, Paul J. Gerroir
-
Patent number: 8493648Abstract: Provided are a method of fabricating an electrophoretic ink, the electrophoretic ink formed using the method, and an electrophoretic display having the same. The method of fabricating an electrophoretic ink includes dispersing pigment particles into a dielectric fluid; adding at least one monomer and an initiator into the dielectric fluid; and forming polymeric membranes surrounding the pigment particles in the dielectric fluid. Since the pigment particle surrounded by the polymeric membrane and the dielectric fluid in which the pigment particle is dispersed can be utilized as the electrophoretic ink as they are without a follow-up cleaning process, the method of fabricating the electrophoretic ink is simplified.Type: GrantFiled: April 22, 2010Date of Patent: July 23, 2013Assignee: Electronics and Telecommunications Research InstituteInventors: Chul Am Kim, Hyeonjung Yoo, Kyung Soo Suh, Seung Youl Kang
-
Patent number: 8426096Abstract: A capsule toner in which fine solid particles constituting a shell layer are less likely to become detached from the surfaces of toner particles in spite of a long-term use within an image forming apparatus and which is capable of prevention of occurrence of filming on a photoreceptor drum, and a method of manufacturing the capsule toner are provided. The capsule toner includes core particle and shell layers for covering the surface of the core particle. The shell layer is formed of a plurality of fine polyester resin particles. The polyester resins contained in the fine polyester resin particles, respectively, are cross-linked to each other by a cross-linking agent.Type: GrantFiled: April 14, 2010Date of Patent: April 23, 2013Assignee: Sharp Kabushiki KaishaInventor: Nobuhiro Maezawa
-
Patent number: 8288071Abstract: A resin particle liquid dispersion for an electrostatic image developing toner, comprising: an aqueous medium; and a resin particle dispersed in the aqueous medium to have a median diameter of 0.05 to 2.0 ?m, the resin particle comprising a polycondensable polymer obtained by polycondensing polycondensable monomers, wherein a storage modulus GL(30) of the resin particle at 30° C. is 1×107 Pa or more, and a melting point of the polycondensable polymer is from 45 to 110° C.Type: GrantFiled: May 26, 2009Date of Patent: October 16, 2012Assignee: Fuji Xerox Co., Ltd.Inventors: Yuki Sasaki, Satoshi Hiraoka, Fumiaki Mera, Hirotaka Matsuoka, Yasuo Matsumura
-
Patent number: 8192912Abstract: Processes for producing emulsion aggregation toners are provided. In embodiments, methods of the present disclosure may be utilized to produce toners suitable for low melt applications, including use in flexible packaging applications, where low pile height is desired for low cost and flexibility. In embodiments, the EA toners may be prepared by optimizing the particle size of the emulsion, the choice of and amount of aggregating agent utilized, and the solids content of the emulsion.Type: GrantFiled: May 8, 2009Date of Patent: June 5, 2012Assignee: Xerox CorporationInventors: Guerino G. Sacripante, Nathan C. Dyck, Daryl W. Vanbesien, Edward G. Zwartz, Cuong Vong
-
Publication number: 20120107741Abstract: Provided is a method of manufacturing toner by which the toner capable of forming high quality images and reproducing high density gradation, which exhibits an excellent high-temperature offsetting property together with excellent low-temperature fixability, and provides appropriate gloss with respect to images to be formed, can be stably prepared; and also provided is the toner. After conducting a step in which particles made of at least a crystalline polyester resin are coagulated to form core coagulated particles, and an unsaturated amorphous polyester resin particle is attached onto the surface of each of the core coagulated particles to form core-shell type coagulated particles, radical polymerization reaction is conducted by acting a radical polymerization initiator on the foregoing core-shell type coagulated particles to conduct a step in which a layer made of a crosslinking amorphous polyester resin is formed on the surface of each of the core coagulated particles.Type: ApplicationFiled: October 26, 2011Publication date: May 3, 2012Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.Inventors: Saburou HIRAOKA, Mikihiko SUKENO, Hajime TADOKORO, Ken OHMURA, Tatsuya NAGASE, Tomomi OSHIBA, Kenji HAYASHI, Tomoko MINE
-
Patent number: 8092972Abstract: Toner particles are provided which may, in embodiments, include a core and a shell formed in situ. The resins utilized to form the core, the shell, or both, may be contacted with a water soluble initiator. The resin, in embodiments present in the shell, cross-links at a temperature near the temperature for coalescence, and may prevent a crystalline resin in the core from migrating to the toner surface.Type: GrantFiled: August 27, 2008Date of Patent: January 10, 2012Assignee: Xerox CorporationInventors: Ke Zhou, Edward G. Zwartz, Karen Ann Moffat
-
Patent number: 8067143Abstract: A functional particle is manufactured by a method including an aggregating step, a depressurizing step, and a cooling step. In the aggregating step, the functional particle is obtained by flowing a mixed slurry containing a core particle and a shell particle through a coiled pipeline while heating the mixed slurry to a glass transition temperature or higher of the core particle, to deposit the shell particles on the surface of the core particle. In the depressurizing step, the grain size of the functional particle is controlled and the coarse particle is pulverized to make the grain size of the functional particles uniform. In the cooling step, re-aggregation of the functional particles with unified grain size is prevented.Type: GrantFiled: September 7, 2007Date of Patent: November 29, 2011Assignee: Sharp Kabushiki KaishaInventors: Keiichi Kikawa, Katsuru Matsumoto, Nobuhiro Maezawa
-
Patent number: 8053073Abstract: A process for producing resin-coated metal particles includes coating surfaces of metal particles with silica; allowing a polymerizable group to adsorb onto the surfaces of the silica-coated particles by the use of a silane coupling agent; and coating the surfaces of the silica-coated particles with a polymeric resin by mixing the particles to which the polymerizable groups have been adsorbed, a polymerizable monomer, a polymerization initiator, and a dispersant to polymerize the polymerizable monomer and the polymerizable groups.Type: GrantFiled: September 15, 2004Date of Patent: November 8, 2011Assignee: Murata Manufacturing Co., Ltd.Inventors: Kiyoko Ueda, Ichiro Nakamura, Kiyoyasu Sakurada
-
Patent number: 7867682Abstract: A toner including a core including at least a colorant, a release agent and a first binder resin; and a shell located overlying the core and including at least a second binder resin, wherein the first binder resin includes a polyester resin including a unit obtained from a diol selected from the group consisting of aliphatic diols and alicyclic diols, and the second binder resin includes a vinyl copolymer, and wherein a weight ratio (S/C) of the shell (S) to the core (C) is from 0.05 to 0.5 and the toner has a volume average particle diameter of from 3 to 8 ?m.Type: GrantFiled: March 13, 2007Date of Patent: January 11, 2011Assignee: Ricoh Company LimitedInventors: Tsuyoshi Nozaki, Chiyoshi Nozaki, Minoru Nakamura, Atsushi Yamamoto
-
Patent number: 7794908Abstract: Provided is magnetic toner including capsule type toner particles each having a surface layer (B) on a surface of a toner base particle (A) containing at least a binder resin (a) mainly formed of a polyester, a magnetic substance, and a wax, in which, the surface layer (B) includes a resin (b), and the resin (b) includes a resin selected from the group consisting of a polyester resin (b1), a vinyl resin (b2), and a urethane resin (b3); a glass transition temperature Tg(a) of the binder resin (a) and a glass transition temperature Tg(b) of the resin (b) satisfy a relationship of Tg(a)<Tg(b); a magnetization (?t) in an external magnetic field of 79.6 kA/m of the magnetic toner is 12 Am2/kg or more and 30 Am2/kg or less; and an average circularity of the toner is 0.960 or more and 1.000 or less.Type: GrantFiled: March 2, 2009Date of Patent: September 14, 2010Assignee: Canon Kabushiki KaishaInventors: Takaaki Kaya, Shigeto Tamura, Ryoichi Fujita, Makoto Kambayashi, Takeshi Ikeda
-
Patent number: 7759041Abstract: A method of preparing a toner, includes: preparing a high molecular weight latex particle by polymerizing a toner composition including a macromonomer having a hydrophilic group, a hydrophobic group and at least one reactive functional group, and at least one polymerizable monomer; forming a core particle by aggregating the high molecular weight latex particle; forming a shell layer by coating the core particle using a polymer having a higher glass transition temperature than a glass transition temperature of the core particle. Also, provided are a toner prepared using the method, an image forming method using the toner, and an image forming apparatus using the toner. Using the toner, an image can be fused at a low temperature. Also, durability of the toner is improved.Type: GrantFiled: November 8, 2006Date of Patent: July 20, 2010Assignee: Samsung Electronics Co., Ltd.Inventors: Chang-kook Hong, Kyung-yol Yon, Min-young Cheong
-
Patent number: 7759039Abstract: Toner particles, preferably emulsion aggregation toner particles, have improved relative humidity sensitivity through inclusion therein of silicate clay particles such as kaolin clay. The toner particles include a binder, preferably an acrylate-containing binder, at least one colorant, and silicate clay particles distributed in the binder. In a core-shell embodiment, the silicate particles are distributed in the core, the shell layer, or both. Developers of the toner in combination with carrier particles are also described.Type: GrantFiled: July 1, 2005Date of Patent: July 20, 2010Assignee: Xerox CorporationInventors: Richard P. N. Veregin, Daryl W. Vanbesien, Cuong Vong
-
Publication number: 20100151372Abstract: Provided are toner for developing an electrostatic latent image and a method of preparing the same. The toner has G?(60) of about 4.0×107 Pa to about 4.0×108 Pa, G?(60)/G?(80) of about 100 to about 500, and G?(100, 140) of about 3.0×103 Pa to about 1.5×105 Pa. The G?(60) and G?(80) are storage moduli Pa at about 60° C. and about 80° C. under measurement conditions of an angular velocity of about 6.28 rad/s and a heating rate of about 2.0° C./minute, respectively. The G?(100, 140) is a storage modulus Pa at a temperature of about 100° C. to about 140° C. under measurement conditions of an angular velocity of about 6.28 rad/s and a heating rate of about 2.0° C./minute.Type: ApplicationFiled: October 2, 2009Publication date: June 17, 2010Applicant: SAMSUNG ELECTRONICS CO., LTD.Inventors: Jae-Hwan KIM, Jun-Young Lee, Yo-da Shin, Tae-Hoe Koo
-
Patent number: 7662531Abstract: The toner described herein contains toner particles containing polymer, colorant and cross-linked polymer. The cross-linked polymer is incorporated at least in the shell of the toner particles. Incorporating cross-linked polymer in the shell of the toner particles provide bumps in the surface of the toner particles. These bumps can behave as spacers. Such toner can be formed by aggregating at least polymer particles and colorant particles to form core particles; aggregating at least cross-linked polymer particles to the surface of the core particles; and coalescing the resulting particles to form toner particles.Type: GrantFiled: September 19, 2005Date of Patent: February 16, 2010Assignee: Xerox CorporationInventors: Paul J. Gerroir, Daryl W. Vanbesien, Vladislav Skorokhod, Maria N.V. McDougall, Eric Strohm, Edward G. Zwartz
-
Patent number: 7507516Abstract: Disclosed is a method of manufacturing toner comprising the steps of adding oil-droplets containing a radically polymerizable monomer into an associated particle dispersion formed by association-fusing resin particles and colorant particles, and forming a shell by coating a resin produced via polymerization on a surface of the associated particle by polymerizing the radically polymerizable monomer in the associated particle dispersion, wherein a hydrophilicity degree of the resin contained in the shell is larger than a hydrophilicity degree of a resin contained in the associated particle.Type: GrantFiled: June 1, 2006Date of Patent: March 24, 2009Assignee: Konica Minolta Business Technologies, Inc.Inventors: Kenji Hayashi, Kenji Yamane, Ryuji Kitani, Kouji Sugama
-
Patent number: 7452652Abstract: Liquid toners suitable for use in the electrostatic printing of functional materials to produce microstructures such as ribs, electrodes, spacers or filters, and methods of producing the liquid toners. The functional materials, which may include metals, glass and phosphors, are suspended as particles in a dilutent, which may be a non-polar liquid. The surface, or portions of the surface, of the functional material particles are given an appropriate acidic or hydroxyl functionality necessary for their use in electrostatic imaging either by etching or by coating with a material having the appropriate surface functionality.Type: GrantFiled: December 22, 2004Date of Patent: November 18, 2008Inventor: Robert H. Detig
-
Patent number: 7452653Abstract: A process for producing a polymerized toner, which comprises steps of forming an aqueous dispersion comprising the colored polymer particles, subjecting the aqueous dispersion comprising the colored polymer particles to stripping treatment in the presence of a nonionic surfactant, dehydrating and washing the aqueous dispersion, wherein washing is carried out by using a washing water a temperature of which is controlled to lower than the cloud point of the nonionic surfactant, drying the wet colored polymer particles, and then getting the colored polymer particles.Type: GrantFiled: August 26, 2004Date of Patent: November 18, 2008Assignee: Zeon CorporationInventor: Katsutomo Tanaka
-
Publication number: 20080145776Abstract: A method of preparing toner includes: preparing a primary latex by polymerizing a toner composition including a macromonomer having a hydrophilic group, a hydrophobic group and at least one reactive functional group, and at least one polymerizable monomer; preparing a primary agglomerated toner by mixing the primary latex with a pigment dispersion dispersed by the macromonomer and adding an inorganic salt to the mixture; and coating the primary agglomerated toner using a secondary latex including a core formed by polymerizing the macromonomer and at least one polymerizable monomer, a wax layer formed on the core by applying a dispersion in which at least one polymerizable monomer is dispersed in a wax, and a shell layer formed on the wax layer by adding at least one polymerizable monomer to the wax layer. A toner prepared by the method is also provided.Type: ApplicationFiled: September 14, 2007Publication date: June 19, 2008Inventors: Yo-da Shin, Tae-hoe Koo, Kyung-yol Yon, Min-young Cheong
-
Publication number: 20080081275Abstract: A process for producing resin-coated metal particles includes coating surfaces of metal particles with silica; allowing a polymerizable group to adsorb onto the surfaces of the silica-coated particles by the use of a silane coupling agent; and coating the surfaces of the silica-coated particles with a polymeric resin by mixing the particles to which the polymerizable groups have been adsorbed, a polymerizable monomer, a polymerization initiator, and a dispersant to polymerize the polymerizable monomer and the polymerizable groups.Type: ApplicationFiled: September 15, 2004Publication date: April 3, 2008Inventors: Kiyoko Ueda, Ichiro Nakamura, Kiyoyasu Sakurada
-
Publication number: 20080063970Abstract: A functional particle is manufactured by a method including an aggregating step, a depressurizing step, and a cooling step. In the aggregating step, the functional particle is obtained by flowing a mixed slurry containing a core particle and a shell particle through a coiled pipeline while heating the mixed slurry to a glass transition temperature or higher of the core particle, to deposit the shell particles on the surface of the core particle. In the depressurizing step, the grain size of the functional particle is controlled and the coarse particle is pulverized to make the grain size of the functional particles uniform. In the cooling step, re-aggregation of the functional particles with unified grain size is prevented.Type: ApplicationFiled: September 7, 2007Publication date: March 13, 2008Applicant: Sharp Kabushiki KaishaInventors: Keiichi KIKAWA, Katsuru MATSUMOTO, Nobuhiro MAEZAWA
-
Patent number: 7318988Abstract: The invention provides dry electrographic toner compositions comprising toner particles. The toner particles comprise polymeric binder comprising at least one amphipathic copolymer comprising one or more S material portions and one or more D material portions prepared from an organosol reaction process utilizing a liquid carrier reaction medium having a Kauri-Butanol number less than about 30 mL. The S material portion comprises at least one soluble component and at least one non-sorptive component, wherein the non-sorptive component is the reaction product of monomers having an absolute difference in Hildebrand solubility parameter from the liquid carrier of about 3.0 MPa1/2 or greater. Additionally, dry electrographic toner compositions are provided wherein the toner particles comprise polymeric binder comprising at least one amphipathic copolymer comprising one or more S material portions and one or more D material portions.Type: GrantFiled: October 28, 2004Date of Patent: January 15, 2008Assignee: Samsung Electronics CompanyInventors: Jiayi Zhu, James A. Baker
-
Patent number: 7078144Abstract: The present invention relates to a method for manufacturing a toner with adjusted particle size distribution having a step of preparing colored particles that contain a binder resin and a colorant, and a step of classifying the colored particles. In the classification step, a classifier that has a plurality of vane-wheel classifying rotors coaxially in a casing, enables the rotating speed of each classifying rotor to be set to be the same as or different from each other, and can simultaneously perform a plurality of stages of classification corresponding to each classifying rotor is used; and the powder material comprising colored particles to which a fluidizing agent is added is fed to the classifier to perform classification.Type: GrantFiled: December 17, 2003Date of Patent: July 18, 2006Assignee: Zeon CorporationInventors: Nobuyasu Ota, Toshihiko Yamato
-
Patent number: 7005225Abstract: The present invention relates to amphipathic copolymeric binder particles that incorporate polymerizable crystallizable compounds chemically incorporated into a dispersible (D) portion and/or solvatable (S) portion of the copolymer. The invention also pertains to dry particulate electrophotographic toners incorporating an amphipathic copolymer comprising one or more polymerizable crystallizable compounds. Methods of making these dry electrophotographic toner particles, and methods of electrophotographically forming an image on a substrate using these toners, are also described.Type: GrantFiled: June 30, 2003Date of Patent: February 28, 2006Assignee: Samsung Electronics CompanyInventors: Julie Y. Qian, Gay L. Herman, James A. Baker
-
Patent number: 6951703Abstract: A liquid developer for high-quality image reproduction and a method of preparing the liquid developer. The liquid developer exhibits good pigment dispersion by the introduction of organosol. The liquid developer contains fine toner particles of a uniform size with a volume-average to number-average particle diameter ratio of 1.5-2.5, and thus can produce high-resolution images. The liquid developer preparation method is environmentally friendly, simple, and cost effective because no cosolvent is used, thus eliminating the need for a cosolvent removal process.Type: GrantFiled: April 28, 2003Date of Patent: October 4, 2005Assignee: Samsung Electronics Co., Ltd.Inventors: Seong-joon Chae, Kyung-yol Yon, Joong-hwan Choi, Jeong-hun Pang
-
Patent number: 6939656Abstract: Methods for producing a polymerized toners are provided, where, a dispersion including colored polymer particles obtained by polymerizing a polymerizable composition is treated stably in the process of reducing the remaining monomer, the resultant polymerized toners include a sufficiently low content of remaining monomer, and the resultant polymerized toners have excellent properties and are useful as developers for printing and copying. In the process of reducing the remaining monomer, the dispersion of the colored polymer particles is treated by stripping in the presence of a specific antifoaming agent.Type: GrantFiled: July 31, 2003Date of Patent: September 6, 2005Assignee: Zeon CorporationInventors: Katsutomo Tanaka, Makoto Watanabe, Keita Sensui
-
Patent number: 6890696Abstract: A toner process comprising heating a mixture of a latex and a colorant, which heating is accomplished below about the glass transition temperature, Tg, of polymer contained in the latex; cooling; and subsequently adding a methacrylate polymer solution; adjusting the pH of the mixture resulting to permit the methacrylate polymer to precipitate on said mixture of latex and said colorant; and wherein resulting product is heated above about the glass transition temperature, Tg, of said latex polymer.Type: GrantFiled: May 27, 2003Date of Patent: May 10, 2005Assignee: Xerox CorporationInventors: Valerie M. Farrugia, Michael S. Hawkins
-
Publication number: 20040253531Abstract: The present invention relates to a method for manufacturing a toner with adjusted particle size distribution having a step of preparing colored particles that contain a binder resin and a colorant, and a step of classifying the colored particles. In the classification step, a classifier that has a plurality of vane-wheel classifying rotors coaxially in a casing, enables the rotating speed of each classifying rotor to be set to be the same as or different from each other, and can simultaneously perform a plurality of stages of classification corresponding to each classifying rotor is used; and the powder material comprising colored particles to which a fluidizing agent is added is fed to the classifier to perform classification.Type: ApplicationFiled: December 17, 2003Publication date: December 16, 2004Applicant: ZEON CORPORATIONInventors: Nobuyasu Ota, Toshihiko Yamato
-
Patent number: 6808855Abstract: A toner production process comprising the step of polymerizing a polymerizable monomer in the presence of (i) base particles containing at least a binder resin and (ii) a polymerization initiator. The polymerization initiator has in one molecule a hydrophilic moiety and a hydrophobic moiety and a reactive moiety between them, and the base particles are enlarged and/or surface-modified upon polymerization of the polymerizable monomer. Also disclosed is a toner having a circularity of from 0.92 to 1.0, which is produced by this process.Type: GrantFiled: May 23, 2002Date of Patent: October 26, 2004Assignee: Canon Kabushiki KaishaInventors: Yasukazu Ayaki, Hitoshi Itabashi, Yayoi Tazawa
-
Publication number: 20040048182Abstract: A multi-layered toner comprises a core and a covering layer. The binder resin in the core has an acid value differing from the acid value of the binder resin in the covering layer.Type: ApplicationFiled: September 6, 2002Publication date: March 11, 2004Applicant: TOSHIBA TEC KABUSHIKI KAISHAInventor: Takashi Urabe
-
Patent number: 6322946Abstract: Toner particles may be produced using a semisuspension polymerization process, which includes: (a) providing a mixture of a partially polymerized monomer or comonomers near the onset of the gel-effect; (b) forming a suspension of the partially polymerized monomer or comonomers; and (c) suspension polymerizing the partially polymerized monomer or comonomers while slowly adding a second monomer or comonomers in a starved feed manner. The process may be used to produce toner particles having varied particle properties, and having a morphology ranging from core-shell and inverted core-shell microcapsules to pseudo core-shell microcapsules and to polyblend composites having a low molecular weight phase dispersed in a high molecular weight matrix.Type: GrantFiled: August 31, 1994Date of Patent: November 27, 2001Assignee: Xerox CorporationInventors: Hadi K. Mahabadi, Michael F. Cunningham, Heather M. Wright