Making A Liquid Toner Or Concentrate Patents (Class 430/137.22)
  • Patent number: 10649357
    Abstract: A method for producing a liquid developer containing a resin binder containing a resin having an acidic group, a colorant, a basic dispersant, and an insulating liquid, including: step I: stirring raw materials containing the resin binder, the colorant, and the basic dispersant at a temperature of equal to or higher than a glass transition temperature of the resin binder; and step II: adding dropwise from 50 to 500 parts by mass of the insulating liquid to a stirred mixture of the step I, based on 100 parts by mass of the stirred mixture at a temperature of equal to or higher than a glass transition temperature of the resin binder, thereby carrying out a phase inversion emulsification, to provide a dispersion of toner particles. The liquid developer obtainable by the method of the present invention is suitably used in development or the like of latent images formed in, for example, electrophotography, electrostatic recording method, electrostatic printing method or the like.
    Type: Grant
    Filed: November 2, 2017
    Date of Patent: May 12, 2020
    Assignee: Kao Corporation
    Inventors: Yuri Nannichi, Nobumichi Kamiyoshi
  • Patent number: 9436133
    Abstract: An image forming apparatus includes an electrostatic latent image holding member, a charging device, a latent image forming device, a developing device that stores a liquid developer containing a toner and a non-volatile carrier liquid, and develops the electrostatic latent image formed on the surface of the electrostatic latent image holding member by the liquid developer to form a toner image, a transfer device that transfers the toner image onto a surface of an impermeable recording medium, and a fixing device, wherein when the SP value of the toner is set as SP(t), the SP value of the non-volatile carrier liquid is set as SP(c), and the SP value of the recording medium is set as SP(m), an absolute value of a difference between SP(t) and SP(c) is from 1.5 to 7.0 and the following relational expression (A) is satisfied: |SP(c)?SP(m)|>|SP(t)?SP(m)|.
    Type: Grant
    Filed: April 16, 2014
    Date of Patent: September 6, 2016
    Assignee: FUJI XEROX CO., LTD.
    Inventors: Satoshi Tatsuura, Yutaka Nogami, Keitaro Mori, Yoshihiro Inaba, Takako Kobayashi, Daisuke Yoshino
  • Patent number: 9366979
    Abstract: The disclosure provides robust phase inversion emulsification (PIE) processes, which produces polyester latex particles having particle size distributions with high centering capability indexes (Cpk), for the preparation of toners of good quality.
    Type: Grant
    Filed: April 4, 2014
    Date of Patent: June 14, 2016
    Assignee: XEROX CORPORATION
    Inventors: Shigeng Li, Shigang Qiu, Peter Van Nguyen, Amy Avolia Grillo, Chieh-Min Cheng
  • Patent number: 9034555
    Abstract: A method for producing a liquid developer containing toner particles containing a resin containing a polyester and a pigment, and an insulating liquid, wherein the toner particles are dispersed in the insulating liquid, including: step 1: melt-kneading the resin and the pigment, and pulverizing a melt-kneaded mixture to provide toner particles; step 2: dispersing the toner particles obtained in the step 1 in the insulating liquid in the presence of a basic dispersant to provide a dispersion of toner particles; and step 3: wet-milling the dispersion of toner particles obtained in the step 2 to provide a liquid developer, wherein the basic dispersant is an amide compound obtained by a reaction between a polyethyleneimine and a polyester (D) obtained by self-condensation of 12-hydroxystearic acid.
    Type: Grant
    Filed: December 26, 2013
    Date of Patent: May 19, 2015
    Assignee: Kao Corporation
    Inventors: Tatsuya Yamada, Hiromi Ito, Yoko Hanada
  • Publication number: 20150118448
    Abstract: The present disclosure discloses a liquid electrophotographic ink. The ink includes a liquid vehicle, an ethylene acid copolymer, and an ethylene/(meth)acrylic acid C1-10 alkyl ester copolymer. Also disclosed is a method for the manufacture that ink and a method for performing a liquid electrophotographic process by printing a substrate with the ink.
    Type: Application
    Filed: April 27, 2012
    Publication date: April 30, 2015
    Inventors: Stella Stolin Roditi, Swissa Shay, Eyal Bachar, Getahun Biadglin, Marc Klein
  • Publication number: 20150111149
    Abstract: A method of making a liquid electrophotographic (LEP) paste is disclosed herein. A base paste is made by forming a dispersion of a pigment and a non-polar carrier, adding a transparent resin dispersion to the pigment dispersion to form a dispersion mixture, and homogenizing the dispersion mixture. The transparent resin dispersion includes a polymer dispersed in a non-aqueous carrier. The homogenizing may be accomplished by agitating the dispersion mixture at a frequency of less than 1 kHz, thereby forming the paste.
    Type: Application
    Filed: May 31, 2012
    Publication date: April 23, 2015
    Inventor: Doris Chun
  • Patent number: 8974997
    Abstract: The present disclosure is drawn to LEP toners, systems, and methods of manufacturing LEP liquid toners. Specifically, a high NVS liquid toner can comprise a ground up admixture of a hydrocarbon carrier fluid, pigment particles, and a polymer paste having an NVS content of about 38 wt % to about 65 wt %. The resultant high NVS liquid toner has an NVS content of about 28 wt % to about 38 wt % and a viscosity of about 3,000 cPs to about 25,000 cPs.
    Type: Grant
    Filed: October 4, 2010
    Date of Patent: March 10, 2015
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Eyal Bachar, Swissa Shay, Yaron Grinwald, Merav Shapira, Albert Teishev, Nava Klein
  • Patent number: 8895219
    Abstract: An ink is disclosed. The ink includes a carrier fluid; an encapsulated metallic pigment particle further including a metallic pigment particle and a polymer, wherein the polymer covers between 70% and 100%, inclusive, of the surface area of the metallic pigment particle and wherein the morphology of the metallic pigment particle by itself is substantially the same as the morphology of the metallic pigment particle covered by the polymer; and a polymer resin.
    Type: Grant
    Filed: April 30, 2012
    Date of Patent: November 25, 2014
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Sivapackia Ganapathiappan, Hou T. Ng, Albert Teishev
  • Publication number: 20140242514
    Abstract: A particulate material production method is provided. The particulate material production method includes ejecting a particulate material composition liquid, which includes an organic solvent and a particulate material composition including at least a resin and dissolved or dispersed in the organic solvent, from at least one nozzle to form droplets of the particulate material composition liquid in a gas phase; and solidifying the droplets of the particulate material composition liquid to prepare particles of the particulate material composition. The droplet solidifying step includes contacting the droplets with a poor solvent for the particulate material composition.
    Type: Application
    Filed: December 30, 2013
    Publication date: August 28, 2014
    Inventors: Ryota Inoue, Yoshihiro Moriya, Hiroshi Yamada, Tatsuru Moritani, Minoru Masuda, Akinori Saito, Yasutada Shitara, Kiyotada Katoh, Satoshi Takahashi
  • Publication number: 20140234771
    Abstract: The present invention provides an electrostatic ink composition comprising a carrier liquid, a resin, a pigment and a conductive polymer. Method for producing the electrostatic ink composition and methods for printing the composition are also disclosed.
    Type: Application
    Filed: September 30, 2011
    Publication date: August 21, 2014
    Applicant: Hewlett-Packard Indigo B.V.
    Inventors: Gil Bar-Haim, Anatoly Sobolevsky, Yaron Grinwald
  • Patent number: 8802344
    Abstract: A process for making toner particles is provided. In embodiments, a suitable process includes adding a washing aid agent to toner particles at the time of washing the toner particles prior to their drying and recover. The washing aid agent assist in the removal of ionic species, including surfactants and ions that are part of the emulsion aggregation process, from the resulting toner particles. Utilization of the washing aid agent produces toner particles having improved charging characteristics.
    Type: Grant
    Filed: December 13, 2010
    Date of Patent: August 12, 2014
    Assignee: Xerox Corporation
    Inventors: Zhen Lai, Chieh-Min Cheng, Zhaoyang Ou, Christopher D. Blair
  • Publication number: 20140199627
    Abstract: The present application relates to a method for concentrating an ink for an electrostatic printing process, wherein the method comprises the steps of: (a) providing the ink for an electrostatic printing process, the ink comprising chargeable particles in a liquid carrier; (b) passing the ink between a chargeable conveyor and a first electrode, wherein a potential is applied such that the ink becomes adhered to the chargeable conveyor; (c) passing the ink on the conveyor past a moving surface, wherein the ink contacts the moving surface and a potential is applied between the conveyor and the moving surface, such that the chargeable particles are disposed to move toward the conveyor and some of the liquid carrier is removed to increase the concentration of the chargeable particles in the liquid carrier on the conveyor to form a concentrated ink on the conveyor, the conveyor and the moving surface then diverging from one another, such that substantially all of the concentrated ink remains on the conveyor; (d)
    Type: Application
    Filed: September 9, 2011
    Publication date: July 17, 2014
    Applicant: Hewlett-Packard Indigo B.V.
    Inventors: Mark Sandler, Shai Lior, Avner Schneider, Eyal Bachar
  • Patent number: 8771912
    Abstract: There is provided an emulsion coloring material which can be used on ordinary paper, has good color developability, and can be used for conventional erasable pens or printing inks of black or blue color, having sufficiently high densities. When use is made of an erasable emulsion coloring material capable of controlling color development and decolorization by the presence or absence of the interaction between a chromatic material and a color developer, the colored emulsion comprising a copolymer resin of at least one unit selected from styrene and styrene derivatives and at least one unit selected from an acrylic acid ester and a methacrylic acid ester having a substituent which comprises a carbon chain having 4 or more carbon atoms, coloring ability can be enhanced.
    Type: Grant
    Filed: April 2, 2009
    Date of Patent: July 8, 2014
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Kenji Sano, Satoshi Takayama, Takeshi Gotanda, Yumiko Sekiguchi
  • Patent number: 8765348
    Abstract: A liquid toner is disclosed herein. The liquid toner includes a toner composition with latex particles incorporated therein. The toner composition includes charged toner particles incorporated into a non-polar liquid carrier. The latex particles are polymer particles of acrylic monomers, vinylic monomers, or mixtures thereof, and each latex particle has a particle size ranging from about 20 nm to about 5 ?m.
    Type: Grant
    Filed: January 18, 2012
    Date of Patent: July 1, 2014
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Sivapackia Ganapathiappan, Hou T. Ng, Albert Teishev
  • Patent number: 8722302
    Abstract: The present invention provides a method for producing a liquid developer for electrophotography or electrostatic recording obtained by a coacervation method, which sufficiently maintains the charging property and has good dispersion stability of colored resin particles, as well as a liquid developer obtained by the method. A method for producing a liquid developer by a coacervation method, wherein a colored resin particle is dispersed in an insulating hydrocarbon dispersion medium in the presence of a particle dispersant and an acid group-containing resin, and the particle dispersant is a reaction product of a polyamine compound and a self-condensation product of a hydroxycarboxylic acid.
    Type: Grant
    Filed: September 26, 2008
    Date of Patent: May 13, 2014
    Assignee: Sakata Inx Corp.
    Inventors: Hirohito Maeda, Katsutoshi Okamoto, Takaaki Yodo, Naoya Inazumi, Koji Iwase
  • Publication number: 20140093822
    Abstract: This invention is related to a liquid developer dispersion for use in a digital printing apparatus comprising a non volatile carrier liquid, a marking particle and a dispersing compounds, wherein the marking particle in the liquid developer dispersion is stabilized during storage and wherein at fusing two phases are formed. The invention is also related to the use of the developer in a digital printing apparatus and to a method for preparing the liquid developer dispersion.
    Type: Application
    Filed: September 27, 2013
    Publication date: April 3, 2014
    Applicant: Xeikon IP BV
    Inventors: Lode Erik Dries Deprez, Werner Jozef Johan Op de Beeck, Mathias Jo Bert van Remortel, Dirk Marcel Constant Gijsbrechts
  • Patent number: 8685609
    Abstract: A marking agent concentration method includes concentrating the marking agent by removing at least some liquid carrier between particles without substantially removing retained liquid carrier within the particles and without substantially modifying the particle structure, which is supported by the retained liquid carrier. The concentrated marking agent is supplied to distributors or end users of liquid marking agent. A concentrated marking agent includes solid clumps of agglomerated particles and a liquid carrier retained within the particles' individual structure. The clumps exhibit a median size greater than 90 ?m. The concentrated marking agent exhibiting a solids content of from 40 wt % to less than 90 wt %. A hard imaging method includes combining a concentrated marking agent with additional liquid carrier, applying a shear force, dispersing particles from clumps, forming a liquid marking agent, and forming a hard image using the liquid marking agent.
    Type: Grant
    Filed: June 30, 2009
    Date of Patent: April 1, 2014
    Assignee: Hewlett-Packard Indigo B.V.
    Inventors: Mark Sandler, Shai Lior, Ilan Frydman
  • Patent number: 8684502
    Abstract: A liquid-discharging head including a reservoir for a spray liquid, a nozzle plate having a plurality of nozzles from which the spray liquid reserved in the reservoir can be discharged, and a vibration generating unit having a vibrating surface facing the nozzle plate, wherein the reservoir is divided into a plurality of liquid chambers, wherein the vibration generating unit has elongated convex portions in a plurality of rows, the elongated convex portions being made of a piezoelectric element, wherein each of the liquid chambers is provided so as to correspond to one of the elongated convex portions, and wherein the liquid-discharging head is used in a method for producing particles, and the method comprises periodically discharging liquid droplets of the spray liquid from the nozzles and solidifying the liquid droplets so as to form particles.
    Type: Grant
    Filed: July 7, 2010
    Date of Patent: April 1, 2014
    Assignee: Ricoh Company, Ltd.
    Inventor: Masaru Ohgaki
  • Publication number: 20140087304
    Abstract: Toner particles have a core-shell structure that first resin particles containing a first resin are attached to or cover surfaces of second resin particles containing a second resin. Heat of fusion with differential scanning calorimetry of the second resin satisfies Equations (1) to (2) below. In Equations (1) to (2) below, H1 and H2 represent heats of fusion (J/g) at initial temperature increase and second temperature increase with differential scanning calorimetry of the second resin, respectively. 5?H1?70??Equation (1) 0.2?H2/H1?1.
    Type: Application
    Filed: September 24, 2013
    Publication date: March 27, 2014
    Applicant: Konica Minolta, Inc.
    Inventors: Yukiko Uno, Satoshi Matsumoto, Naoki Yoshie, Chiaki Yamada
  • Publication number: 20140087302
    Abstract: In a liquid developer in which toner particles are dispersed in an insulating liquid, the toner particles have a core-shell structure that first resin particles containing a first resin are attached to or cover surfaces of second resin particles containing a second resin. The second resin particles further contain a pigment and a dispersant for pigment, and solubility of the dispersant for pigment in the insulating liquid is not higher than 10 mass % at 25° C.
    Type: Application
    Filed: September 18, 2013
    Publication date: March 27, 2014
    Applicant: Konica Minolta, Inc.
    Inventors: Sho KIM, Satoshi MATSUMOTO, Naoki YOSHIE, Kenji HAYASHI
  • Publication number: 20140087300
    Abstract: Toner particles contained in a liquid developer have a core-shell structure that first resin particles containing a first resin are attached to or cover surfaces of second resin particles containing a second resin. The second resin satisfies Equations (1) to (2) below. In Equations (1) to (2) below, x represents a number average molecular weight of the second resin and y represents a urethane group concentration (mass %) in the second resin. ?0.00003x+2.03?y??0.00003x+6.
    Type: Application
    Filed: September 18, 2013
    Publication date: March 27, 2014
    Applicant: Konica Minolta, Inc.
    Inventors: Yukiko UNO, Satoshi MATSUMOTO, Naoki YOSHIE, Kenji HAYASHI
  • Patent number: 8669037
    Abstract: A method of manufacturing a liquid electrophotographic ink includes: mixing a first portion of a carrier fluid and a resin to form a resin mixture; heating the resin mixture until the resin has melted; cooling the resin mixture to form a resin cake, followed by pulverizing the resin cake to form a resin powder; and mix the resin powder with a pigment and a second portion of carrier fluid in a microfluidizer to form a concentrating ink containing composite particles. An alternate method of manufacturing a liquid electrophotographic ink includes: mixing a pigment with a resin powder; and microfluidizing the mixture together with a carrier fluid in a microfluidizer in a number of passes to form a concentrated ink containing composite particles.
    Type: Grant
    Filed: April 26, 2012
    Date of Patent: March 11, 2014
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Sivapackia Ganapathiappan, Hou T. Ng, Albert Teishev
  • Publication number: 20140065537
    Abstract: The continuous process for manufacturing toners disclosed herein includes continuously feeding components of a toner composition into a feed section of a screw extruder at a controlled rate. The continuous process for manufacturing toners may include feeding the components of a toner composition into the feed section of a screw extruder without performing an external or secondary dispersion step. That is to say, the components of the toner composition may be fed directly into the extruder without using dispersions of individual components as used in batch processes. Rather, the toner components are added to the extruder in dry form, melt-mixed, and may be dispersed in aqueous form in the extruder. The process may produce micron-sized toner particles, thus no further size reduction may be necessary.
    Type: Application
    Filed: August 29, 2012
    Publication date: March 6, 2014
    Applicant: XEROX CORPORATION
    Inventors: Joo T. CHUNG, Chieh-Min CHENG, Zhen LAI, Mark E. MANG, Eugene F. YOUNG, Brian ANDAYA, Joseph LEONARDO
  • Patent number: 8647802
    Abstract: To provide a toner manufacturing method including: continuously mixing an oil phase with an aqueous phase to form an emulsified liquid using an emulsifying mechanism having an emulsified liquid circulation pathway and an emulsifying device equipped with a stirring blade; forming liquid droplets from the emulsified liquid by controlling the equilibrium between atomization and integration of the liquid droplets; and feeding the liquid droplets with stirring to a series of treatments including at least desolvation, filtration, washing and drying; wherein a product T of the solid content concentration (% by mass) of the oil phase and viscosity (mPa·s) measured with a rotating viscometer at 25° C., and 6 rpm satisfies 30,000?T?50,000.
    Type: Grant
    Filed: March 6, 2008
    Date of Patent: February 11, 2014
    Assignee: Ricoh Company, Ltd.
    Inventors: Shinzo Higuchi, Hiroshi Takahashi
  • Publication number: 20140030651
    Abstract: The present disclosure is drawn to a liquid toner composition comprising: (a) a carrier liquid; (b) particles comprising (i) a first component comprising a polymer having acidic side groups; and (ii) a second component comprising a polymer having ester side groups; and (c) a charge director. Also described herein are a method of producing a liquid toner composition and a method of electrophotographic printing using a liquid toner composition.
    Type: Application
    Filed: March 30, 2011
    Publication date: January 30, 2014
    Inventors: Stella Stolin Roditi, Fernanda Orlik, Haim Cohen, Albert Teishev, Nava Klein
  • Patent number: 8617783
    Abstract: An ink contains dispersed particles, individually including at least one thermoplastic first resin exhibiting a MFI less than or equal to 100, at least one thermoplastic second resin exhibiting a MFI greater than 100, and a white pigment. A liquid toner producing method includes forming a paste containing the resins, combining the paste with a white pigment, and after combining the paste and pigment, applying a shear force, encapsulating the pigment, and dispersing the encapsulated pigment. A digital printing method includes providing a liquid marking agent containing charged particles dispersed in a carrier liquid, individual particles including at least one thermoplastic first resin and at least one thermoplastic second resin encapsulating a white pigment, and printing a hard image on a substrate. At least a portion of the image has a white color.
    Type: Grant
    Filed: July 23, 2009
    Date of Patent: December 31, 2013
    Assignee: Hewlett-Packard Indigo B.V.
    Inventors: Galia Golodetz, Gal Victor
  • Patent number: 8614045
    Abstract: A liquid developer is provided. The liquid developer includes a liquid insulator and toner particles. The liquid insulator toner particles include a resin material, a colorant, a substance A, a substance B, and a substance C. The substance A is an acrylic-modified silicone. The substance B is at least one selected from the group consisting a quaternary cationic silicone, an aminophenyl-modified silicone, and a phenyl-modified silicone. The substance C is at least one of a silanol-containing polysiloxane and a fluorine-modified silicone. The average degree of roundness R1 of the toner particles is 0.890 or greater, if the degree of roundness is expressed as L0/L1, where L1 (?m) is a circumference of a profile view of a measured particle and L0 (?m) is the circumference of a perfect circle of a circumference of a profile view corresponding to the profile view of the measured particle.
    Type: Grant
    Filed: November 22, 2011
    Date of Patent: December 24, 2013
    Assignee: Seiko Epson Corporation
    Inventors: Kenichi Numakura, Yoshihiro Ueno, Masahiro Oki, Tsutomu Teraoka
  • Publication number: 20130323636
    Abstract: The present disclosure is drawn to an electrostatic ink composition comprising: (a) a carrier liquid; (b) particles comprising: (i) a polymer having a melt flow rate of less than 60 g/10 minutes, (ii) a colorant, (c) a charge director, wherein the electrostatic ink composition excludes a positively charged organic molecule or an organic molecule capable of becoming a positively charged organic molecule during an electrostatic printing process. Also disclosed herein is a method of producing a electrostatic ink composition and a method of electrophotographic printing an electrostatic ink composition.
    Type: Application
    Filed: March 30, 2011
    Publication date: December 5, 2013
    Applicant: Hewlett-Packard Indigo B.V.
    Inventors: Gil Bar-Haim, Eyal Bodinger, Albert Teishev, Marc Klein, Alexey Kabalnov, Guang Jin Li
  • Patent number: 8592125
    Abstract: Provided is a liquid developer containing toner particles and an insulating liquid containing an epoxy modified fatty acid alkyl ester.
    Type: Grant
    Filed: February 18, 2010
    Date of Patent: November 26, 2013
    Assignee: Seiko Epson Corporation
    Inventor: Takashi Teshima
  • Patent number: 8592113
    Abstract: A toner including a mother toner comprising a binder resin and a calixarene having a halogen group, and a charge controlling agent having a halogen group that is present on a surface of the mother toner. The ratio of halogen ion to carbon ion on a surface of the toner is from 0.01 to 0.5, when determined by TOF-SIMS. The toner can be prepared by preparing a first liquid by dissolving or dispersing toner components including a calixarene having a halogen group and a binder resin and/or a precursor of the binder resin in an organic solvent; preparing a second liquid by emulsifying or dispersing the first liquid in an aqueous medium; removing the organic solvent from the second liquid; preparing a third liquid by washing the second liquid from which the organic solvent is removed; and adding a charge controlling agent having a halogen group to the third liquid.
    Type: Grant
    Filed: October 6, 2010
    Date of Patent: November 26, 2013
    Assignee: Ricoh Company, Limited
    Inventors: Masaki Watanabe, Hiroshi Yamashita, Tomoh Kubo
  • Publication number: 20130288177
    Abstract: A method of manufacturing a liquid electrophotographic ink includes: mixing a first portion of a carrier fluid and a resin to form a resin mixture; heating the resin mixture until the resin has melted; cooling the resin mixture to form a resin cake, followed by pulverizing the resin cake to form a resin powder; and mix the resin powder with a pigment and a second portion of carrier fluid in a microfluidizer to form a concentrating ink containing composite particles. An alternate method of manufacturing a liquid electrophotographic ink includes: mixing a pigment with a resin powder; and microfluidizing the mixture together with a carrier fluid in a microfluidizer in a number of passes to form a concentrated ink containing composite particles.
    Type: Application
    Filed: April 26, 2012
    Publication date: October 31, 2013
    Inventors: Sivapackia Ganapathiappan, Hou T. Ng, Albert Teishev
  • Publication number: 20130288176
    Abstract: An ink is disclosed. The ink includes a carrier fluid; an encapsulated metallic pigment particle further including a metallic pigment particle and a polymer, wherein the polymer covers between 70% and 100%, inclusive, of the surface area of the metallic pigment particle and wherein the morphology of the metallic pigment particle by itself is substantially the same as the morphology of the metallic pigment particle covered by the polymer; and a polymer resin.
    Type: Application
    Filed: April 30, 2012
    Publication date: October 31, 2013
    Inventors: Sivapackia Ganapathiappan, Hou T. Ng, Albert Teishev
  • Patent number: 8562125
    Abstract: A concentrated inkjet ink for packaging includes a liquid composition present in an amount that is less than 60 wt % of the concentrated inkjet ink, and nonvolatile solids present in an amount ranging from about 40 wt % to about 90 wt % of the concentrated inkjet ink. The nonvolatile solids include encapsulated pigment particles having a particle size ranging from about 50 nm to about 500 nm, and a dispersant. The concentrated inkjet ink is dispersible in an ink vehicle to form a print ready inkjet ink.
    Type: Grant
    Filed: April 23, 2013
    Date of Patent: October 22, 2013
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Doris Pik-Yiu Chun, Thomas Anthony, Hou T. Ng, Howard S. Tom
  • Patent number: 8557497
    Abstract: A method of manufacturing toner including preparing a first liquid by dissolving or dispersing toner components including one or both of a binder resin and a precursor thereof in an organic solvent; preparing a second liquid by dispersing the first liquid in a first aqueous medium including a dispersant; producing primary particles by removing the organic solvent from the second liquid; washing the primary particles; preparing a third liquid by dispersing the washed primary particles in a second aqueous medium and heating the second aqueous medium while or after dispersing the washed primary particles therein; and producing toner particles by adding a charge controlling agent to the third liquid. This method satisfies the following inequation: 0.60?Sb/Sa?1.00 wherein Sa represents a BET specific surface area of the primary particles included in the third liquid and Sb represents that of the toner particles stored for 2 weeks at 40° C., 70% RH.
    Type: Grant
    Filed: December 6, 2010
    Date of Patent: October 15, 2013
    Assignee: Ricoh Company, Limited
    Inventors: Junichi Watanabe, Kenichi Uehara, Junya Koeda, Daisuke Misawa, Keisuke Tada, Miyuki Hirata
  • Patent number: 8501055
    Abstract: A toner manufacturing method, a toner manufacturing apparatus, and a toner are disclosed. The toner manufacturing apparatus includes a droplet generating unit that includes a thin film in which plural nozzles are formed, and an annular vibrating unit that is arranged at a perimeter of a deformable domain of the thin film for vibrating the thin film; a storage unit for storing a toner-containing liquid that includes at least a resin and a colorant, and for supplying the toner-containing liquid 10 to the droplet generating unit; and a granulating unit for solidifying droplets that are periodically breathed out from the nozzles of the droplet generating unit to form toner particles.
    Type: Grant
    Filed: March 5, 2008
    Date of Patent: August 6, 2013
    Assignee: Ricoh Company, Ltd.
    Inventors: Shinji Ohtani, Yoshihiro Norikane, Seichin Kinuta
  • Publication number: 20130183619
    Abstract: A liquid toner is disclosed herein. The liquid toner includes a toner composition with latex particles incorporated therein. The toner composition includes charged toner particles incorporated into a non-polar liquid carrier. The latex particles are polymer particles of acrylic monomers, vinylic monomers, or mixtures thereof, and each latex particle has a particle size ranging from about 20 nm to about 5 ?m.
    Type: Application
    Filed: January 18, 2012
    Publication date: July 18, 2013
    Inventors: Sivapackia Ganapathiappan, Hou T. Ng, Albert Teishev
  • Patent number: 8426100
    Abstract: Liquid electrophotographic ink concentrates and methods of preparing the same are disclosed herein. An example of the method includes preparing a mixture of ink components using a first predetermined thermal profile. The ink components include a resin, a pigment, and a carrier. The method further includes preparing a microfluidizer with a composition at a temperature within a predetermined range and processing the mixture in the prepared microfluidizer to form the concentrate. Processing the mixture includes pressure-feeding the mixture into the prepared microfluidizer, passing the mixture through the prepared microfluidizer for a predetermined number of times, and utilizing a second predetermined thermal profile while passing the mixture through the prepared microfluidizer. A viscosity modifier is added to the mixture before and/or during the processing of the mixture.
    Type: Grant
    Filed: January 31, 2011
    Date of Patent: April 23, 2013
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Doris Pik-Yiu Chun, Sivapackia Ganapathiappan, Hou T. Ng, Albert Teishev
  • Patent number: 8399170
    Abstract: Production process for a liquid developer for use in electrophotograph or electrostatic recording by coacervation method. The process can produce a liquid developer in which a coloring agent (e.g., a pigment) is included completely within a resin particle by distillation of a solvent while retaining the state where the coloring agent is finely dispersed and the resulting colored resin particle is small in particle size with excellent dispersion stability, and excellent optical properties.
    Type: Grant
    Filed: June 26, 2006
    Date of Patent: March 19, 2013
    Assignee: Sakata Inx Corp.
    Inventors: Koji Iwase, Hirohito Maeda, Takaaki Yodo
  • Publication number: 20130059249
    Abstract: A reactor, which heats a slurry raw material including a solid component, including a reaction tube, wherein the slurry raw material is continuously fed from an end of the reaction tube relative to the central axial direction of the reaction tube so as to be flown toward another end of the reaction tube to be heated; and plural perforated plates arranged in the reaction tube so as to separate the inside of the reaction tube into plural compartments. The reactor satisfies the relations (½)·D??D<D?, and 0.2?S/D??5.0, wherein D represents the diameter of each of the perforated plates, D? represents the inner diameter of the reaction tube, and S represents the interval between any two adjacent perforated plates in the central axial direction of the reaction tube.
    Type: Application
    Filed: August 29, 2012
    Publication date: March 7, 2013
    Inventors: Junichi WATANABE, Kenichi UEHARA
  • Publication number: 20130034809
    Abstract: Provided is a nonaqueous dispersion of resin particles, in which the resin particles have uniform particle diameters and shapes and which exhibits excellent fixing properties, particularly when used as a liquid electrophotographic developer. More specifically, provided is a nonaqueous dispersion (X) in which resin particles (C) are dispersed in a nonhydrophilic organic solvent (L) that exhibits a relative permittivity of 1 to 4 at 20° C., the resin particles (C) being core-shell type resin particles each of which comprise a resin particle (B) that contains a resin (b) and fine particles (A) that contain a resin (a) and that either adhere to the surface of the resin particle (B) or form a film on the surface of the resin particle (B), wherein the solubility of (a) in (L) at 25° C. is 10 wt % or less relative to the weight of (a).
    Type: Application
    Filed: March 24, 2011
    Publication date: February 7, 2013
    Applicant: SANYO CHEMICAL INDUSTRIES, LTD.
    Inventors: Masakazu Iwata, Kouji Oota
  • Patent number: 8349530
    Abstract: A magnetic polymer particle develops a magnetic latent image. The magnetic polymer particle includes a magnetic component, a polymer, and a colorant. The magnetic component is a magnetic particle containing iron having a number average particle diameter of from about 0.2 ?m to about 1.2 ?m. The magnetic particle is contained in one magnetic polymer particle in an amount of from 1 to 10 particles. The number average particle diameter of the magnetic polymer particle is from about 2.0 ?m to about 7.0 ?m.
    Type: Grant
    Filed: October 2, 2008
    Date of Patent: January 8, 2013
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Takako Kobayashi, Yoshihiro Inaba
  • Patent number: 8334341
    Abstract: An object of the present invention is to provide a carbodiimide type compound having high dispersibility and dispersion stability of pigments, fine resin particles, and pigment-resin composite fine particles particularly in a silicone dispersion medium; a pigment dispersion composition and a pigment-resin composite fine particles-containing dispersion composition preferably usable in a wide range of fields such as inks for solvent ink jet, liquid developers, and the like by using the compound; and a liquid developer using such a pigment dispersion composition and/or pigment-resin composite fine particles-containing dispersion composition. The present invention provides a carbodiimide type compound obtained by introducing a polysiloxane chain by reaction of a functional group of a polysiloxane chain-containing compound having the functional group reactive with a carbodiimide group with a carbodiimide group of a carbodiimide compound having a carbodiimide equivalent weight of 100 to 50000.
    Type: Grant
    Filed: March 23, 2006
    Date of Patent: December 18, 2012
    Assignee: Sakata INX Corp.
    Inventors: Hideo Shibata, Koji Iwase, Hirohito Maeda, Takaaki Yodo
  • Patent number: 8268200
    Abstract: Provided is a pigment dispersing composition for a color filter including a color material, a resin, and an organic solvent which may dissolve the resin, wherein a modified pigment (D) is contained as the color material which includes, on the surface of a pigment (A), a polymer (P) obtained by polymerizing a polymer (B) containing a polymerizable unsaturated group soluble in a non-aqueous solvent and at least one type of polymerizable unsaturated monomer (C) which is soluble in the non-aqueous solvent and becomes either insoluble or poorly soluble following polymerization, alternatively wherein a modified pigment (D) is contained as the color material which is obtained, under the presence of a pigment (A), a non-aqueous solvent, and a polymer (B) containing a polymerizable unsaturated group soluble in the non-aqueous solvent, by polymerizing at least one type of polymerizable unsaturated monomer (C).
    Type: Grant
    Filed: March 23, 2009
    Date of Patent: September 18, 2012
    Assignee: DIC Corporation
    Inventors: Hiroshi Kinoshita, Seiji Funakura, Eiichi Kiuchi, Yoshinori Katayama
  • Publication number: 20120196222
    Abstract: Liquid electrophotographic ink concentrates and methods of preparing the same are disclosed herein. An example of the method includes preparing a mixture of ink components using a first predetermined thermal profile. The ink components include a resin, a pigment, and a carrier. The method further includes preparing a microfluidizer with a composition at a temperature within a predetermined range and processing the mixture in the prepared microfluidizer to form the concentrate. Processing the mixture includes pressure-feeding the mixture into the prepared microfluidizer, passing the mixture through the prepared microfluidizer for a predetermined number of times, and utilizing a second predetermined thermal profile while passing the mixture through the prepared microfluidizer. A viscosity modifier is added to the mixture before and/or during the processing of the mixture.
    Type: Application
    Filed: January 31, 2011
    Publication date: August 2, 2012
    Inventors: Doris Pik-Yiu Chun, Sivapackia Ganapathiappan, Hou T. Ng, Albert Teishev
  • Patent number: 8232037
    Abstract: A method for printing a substrate by liquid developer electrography, the method comprising: (a) developing a latent image with liquid developer comprising toner particles dispersed in a carrier liquid, said toner particles comprising UV-curable additive; (b) transferring the developed image to the substrate; (c) at least partially fixing the image to the substrate; and (d) irradiating the at least partially fixed image with UV radiation to cure the UV-curable additive.
    Type: Grant
    Filed: October 31, 2006
    Date of Patent: July 31, 2012
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Muhammad Iraqi, Albert Teishev, Gregory Katz
  • Patent number: 8221955
    Abstract: Methods of making ink toners for use in electrostatic imaging are disclosed.
    Type: Grant
    Filed: July 25, 2006
    Date of Patent: July 17, 2012
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Gal Victor, Dan Scheffer, Galia Golodetz, Jose Kuperwasser, Natalia Katz
  • Patent number: 8198001
    Abstract: A process for producing a liquid developer includes: providing a dispersion liquid containing an aqueous dispersion medium and toner mother particles including a rosin resin; chemically modifying surfaces of the toner mother particles with an amine-based material by mixing the amine-based material with the dispersion liquid to obtain toner particles; and dispersing the toner particles in an insulating liquid.
    Type: Grant
    Filed: July 6, 2009
    Date of Patent: June 12, 2012
    Assignee: Seiko Epson Corporation
    Inventors: Yoshihiro Ueno, Masahiro Oki
  • Publication number: 20120058426
    Abstract: A marking agent concentration method includes concentrating the marking agent by removing at least some liquid carrier between particles without substantially removing retained liquid carrier within the particles and without substantially modifying the particle structure, which is supported by the retained liquid carrier. The concentrated marking agent is supplied to distributors or end users of liquid marking agent. A concentrated marking agent includes solid clumps of agglomerated particles and a liquid carrier retained within the particles' individual structure. The clumps exhibit a median size greater than 90 ?m. The concentrated marking agent exhibiting a solids content of from 40 wt % to less than 90 wt %. A hard imaging method includes combining a concentrated marking agent with additional liquid carrier, applying a shear force, dispersing particles from clumps, forming a liquid marking agent, and forming a hard image using the liquid marking agent.
    Type: Application
    Filed: June 30, 2009
    Publication date: March 8, 2012
    Inventors: Mark Sandler, Shai Lior, Ilan Frydman
  • Patent number: 8129084
    Abstract: A liquid developer includes: magnetic polymer particles including a magnetic material containing yttrium iron garnet (YIG), a polymer compound having a carboxylate salt structure, and a colorant; and a dispersion medium in which the magnetic polymer particles are dispersed.
    Type: Grant
    Filed: August 21, 2009
    Date of Patent: March 6, 2012
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Yoshihiro Inaba, Takako Kobayashi, Ryosaku Igarashi
  • Publication number: 20120009516
    Abstract: The present disclosure provides inks, systems, and methods directed towards dispersed pigments. In one embodiment, an electrophotographic ink can comprise an aliphatic solvent and a pigment having a surface comprising carbonyl groups stabilized by an amine dispersant having the structure: R1R2N[(CH2)nNR5]m(CH2)pNR3R4, where R1, R3, R4, and R5 are independently selected from the group of H; COR6; COOR6; CONHR6; linear or branched, substituted or unsubstituted, alkyl; linear or branched, substituted or unsubstituted, aryl; and combinations thereof; R2 is an aliphatic polymer chain; R6 is selected from the group of H; linear or branched, substituted or unsubstituted, alkyl; linear or branched, substituted or unsubstituted, aryl; and combinations thereof; m is from 0 to 200; n is from 1 to 20; and p is from 1 to 20; where the electrophotographic ink has a low field conductivity of less than 200 pS/cm and a viscosity from about 0.5 to about 40 cps.
    Type: Application
    Filed: July 7, 2010
    Publication date: January 12, 2012
    Inventors: Sivapackia Ganapathiappan, Hou T. Ng