Negative Image Prepared Patents (Class 430/147)
  • Patent number: 10377734
    Abstract: The present invention provides a resist composition which is excellent in heat resistance, has high solubility in a safe solvent, has high sensitivity, and can impart a good shape to a resist pattern.
    Type: Grant
    Filed: January 28, 2014
    Date of Patent: August 13, 2019
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Masatoshi Echigo, Masako Yamakawa
  • Patent number: 9448212
    Abstract: A method is provided for detecting sulphur-containing species (such as thiophosphorous esters, in particular phosphorylating agents), in which a suspected sulphur-containing species is brought into contact with a tetrazolium compound in the presence of base, typically at a pH of at least 8. A device, kit and tetrazolium compounds for use in such a method are also disclosed.
    Type: Grant
    Filed: October 17, 2011
    Date of Patent: September 20, 2016
    Assignee: UNIVERSITY COLLEGE CARDIFF CONSULTANTS LIMITED
    Inventors: Ian Fallis, Ian Morgan
  • Patent number: 8569144
    Abstract: In the present invention, in the exposure to light of a memory cell array or the like of a semiconductor memory or the like, when a group of unit openings for etching the STI trench regions in which the unit openings for etching the STI trench regions each having a rectangular shape are arranged in rows and columns are transferred by the exposure onto a negative resist film, multiple exposure is appropriately used which includes a first exposure step using a first optical mask having a group of first linear openings extending in a column direction and a second exposure step using a second optical mask having a group of second linear openings extending in a row direction.
    Type: Grant
    Filed: February 2, 2012
    Date of Patent: October 29, 2013
    Assignee: Renesas Electronics Corporation
    Inventors: Kota Funayama, Hiraku Chakihara
  • Publication number: 20030082474
    Abstract: The present invention provides a thermally imageable composition, which includes an acid curable composition, an acid generator, a strong acid and optionally an infrared absorber. The present invention further provides an imageable element, which includes a substrate and a thermally imageable composition according to the present invention coated on a surface of the substrate. Also provided are methods of producing an imaged element according to the present invention.
    Type: Application
    Filed: August 21, 2001
    Publication date: May 1, 2003
    Applicant: Kodak Polychrome Graphics, L.L.C
    Inventors: Neil Haley, John Kalamen
  • Publication number: 20030073011
    Abstract: A method of manufacturing a selectively relief-treated image member comprises:
    Type: Application
    Filed: August 17, 2001
    Publication date: April 17, 2003
    Inventors: Kevin Barry Ray, Hans-Horst Glatt, Ali Cam
  • Publication number: 20020048714
    Abstract: A support for a lithographic printing plate with no damage in appearance such as unevenness in the form of streaks and with excellent pit homogeneity. A support for a lithographic printing plate obtained by subjecting a surface of an aluminum alloy plate to a surface treatment including alkali etching and an electrochemical graining treatment, wherein the aluminum alloy plate shows dispersion of 50% or lower for each element, the dispersion being defined by an specific equation with regard to contents of Fe, Si, Mn, Mg and Sn in a surface layer portion thereof which is from the surface to a depth of 1 &mgr;m.
    Type: Application
    Filed: September 6, 2001
    Publication date: April 25, 2002
    Inventors: Hirokazu Sawada, Atsuo Nishino, Akio Uesugi
  • Patent number: 6151058
    Abstract: A method for controlling the intensity of an imaging laser of an electrophotographic device in order to produce both positive and negative output. This is accomplished by using a software controlled digital circuit to increase or decrease the power supplied to the laser based on the user's desire to print positive or negative output. When the user desires to print positive output, the laser is set to full power. When the user selects negative mode printing, the power to the laser is digitally reduced by a factor unique to the electrophotographic characteristics of the printing device.
    Type: Grant
    Filed: March 18, 1997
    Date of Patent: November 21, 2000
    Assignee: Xante Corporation
    Inventor: Robert C. Ross
  • Patent number: 5430130
    Abstract: An photosensitive polyfunctional aromatic diazo compound having at least two groups of Formula (uD) in the molecule, and a photosensitive composition using the same. The diazo compound can be handled under visible light free from ultraviolet, is highly photosensitive, has good shelf life, and is adequate as a photosensitive agent for lithographic printing plates and screen printing plates: ##STR1## wherein G.sup.1 is a substituent derived from alcoholic hydroxyl group; R.sup.1 and R.sup.2 are hydrogen, or alkyl or alkyloxy of 1 to 8 carbon atoms;R.sup.3 is alkyl or substituted alkyl of 1 to 8 carbon atoms, aralkyl or substituted aralkyl of 7 to 14 carbon atoms, or --CH.sub.2 CHG.sup.2 --CH.sub.2 --;X.sup.- is an anion based on protonic acid from which a proton is removed.
    Type: Grant
    Filed: July 21, 1993
    Date of Patent: July 4, 1995
    Assignee: Toyo Gosei Kogyo Co., Ltd.
    Inventors: Hirotada Iida, Noriaki Tochizawa, Yasuo Kuniyoshi, Masaharu Watanabe, Katsuyo Tokuda, Ichiro Hozumi
  • Patent number: 5368995
    Abstract: Imaging elements, such as photographic, electrostatographic and thermal imaging elements, are comprised of a support, an image-forming layer and an electrically-conductive layer comprising a dispersion in a film-forming binder of fine particles of an electronically-conductive metal antimonate. Use of metal antimonate particles provides a controlled degree of electrical conductivity and beneficial chemical, physical and optical properties which adapt the electrically-conductive layer for such purposes as providing protection against static or serving as an electrode which takes part in an image-forming process.
    Type: Grant
    Filed: April 22, 1994
    Date of Patent: November 29, 1994
    Assignee: Eastman Kodak Company
    Inventors: Paul A. Christian, Charles C. Anderson
  • Patent number: 4937170
    Abstract: A photographic element formed from a substrate and light sensitive coating on the substrate wherein the coating comprises a mixture of a diazo compound and an aromatic carboxylic coupling agent having phenolic hydroxy groups, in an acidic medium.
    Type: Grant
    Filed: March 1, 1988
    Date of Patent: June 26, 1990
    Assignee: Hoechst Celanese Corporation
    Inventor: Dieter Mohr
  • Patent number: 4937176
    Abstract: A method of manufacturing a semiconductor device, in which a layer of photolacquer (5) containing as a photoactive component a diazo oxide is provided on a semiconductor substrate. Of this layer, parts (9) are irradiated by a first patterned irradiation (7) and these parts are then rendered poorly developable by an intermediate treatment. Subsequently, the lacquer layer (5) is subjected to a second non-patterned irradiation (11) and is then developed. According to the invention, in the parts (9) irradiated by the first irradiation a pigment is formed, which absorbs radiation having a wavelength at which diazo oxide is photosensitive. The second irradiation is carried out with radiation of that wavelength. Thus, lacquer tracks having a rectangular profile can be obtained in a simple manner.
    Type: Grant
    Filed: September 27, 1988
    Date of Patent: June 26, 1990
    Assignee: U.S. Philips Corporation
    Inventors: Franciscus A. Vollenbroek, Wilhelmus P. M. Nijssen, Marcellinus J. H. J. Geomini
  • Patent number: 4888266
    Abstract: The invention relates to a process for producing supports intended for the optical recording and reading of information. A layer containing a diazo compound is deposited onto a metallized substrate. Recording is obtained by exposing the support to light through a mask, the exposed zones of the layer of diazo compound being decomposed. Dry development in ammonia vapors shows up transparent zones and opaque zones corresponding to the information.
    Type: Grant
    Filed: March 13, 1987
    Date of Patent: December 19, 1989
    Assignee: Thomson Brandt
    Inventors: Jean-Pierre Lacotte, Claude Puech
  • Patent number: 4711830
    Abstract: An image recording material is provided which comprises an electroconductive base plate, a recording layer provided on at least one side of said plate and a photosensitive layer provided on said recording layer. The recording layer may constituted of a electrolytically polymerized film, and the photosensitive layer may constituted of a polymer complex formed from a basic polymer and an acidic polymer. A method for image recording is also provided.
    Type: Grant
    Filed: January 22, 1986
    Date of Patent: December 8, 1987
    Assignee: Canon Kabushiki Kaisha
    Inventors: Masahiro Haruta, Yoko Kuwae, Satoshi Yuasa, Toshihiko Miyazaki
  • Patent number: 4642283
    Abstract: A negative working light-sensitive lithographic plate requiring no dampening solution and a plate making process are described, the negative working light-sensitive lithographic plate comprising a support having, in sequence, on said support, (A) a light-sensitive layer containing (1) an o-quinonediazide compound and (2) a coupling component which causes a diazo coupling reaction under a basic environment, and (B) a silicone rubber layer, and the plate making process comprising imagewise exposing the negative working light-sensitive lithographic plate and developing said exposed plate to obtain a lithographic plate requiring no dampening solution, wherein a step of processing with base is carried out after imagewise exposure.
    Type: Grant
    Filed: March 14, 1985
    Date of Patent: February 10, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Takahashi, Yasuhisa Narutomi, Yoshimasa Aotani, Keisuke Shiba
  • Patent number: 4556625
    Abstract: The present invention discloses a method of photolytically developing a colored image on a cellulosic material. In this method, the material is contacted with a nitrogen containing polymer in solution and a mono-sulfonyl azide compound in solution. The sample is thereafter exposed to a UV-containing light source for an amount of time sufficient to develop a color thereon.
    Type: Grant
    Filed: November 25, 1983
    Date of Patent: December 3, 1985
    Assignee: Armstrong World Industries, Inc.
    Inventors: Ronald S. Lenox, Anne L. Schwartz, Charles E. Hoyle
  • Patent number: 4431725
    Abstract: A light-sensitive material having on a support a light-sensitive layer containing an o-quinonediazide compound as a main component and, additionally, a particular compound represented by the following general formula (I): ##STR1## wherein Z represents the nonmetallic atoms forming a 5-membered ring; X represents S, O, ##STR2## or .dbd.N--R.sub.c (where R.sub.a, R.sub.b and R.sub.c are each a hydrogen atom or an organic group other than a carboxylic acid group); and Y is a hydrogen atom or an organic group other than a carboxylic acid group, is disclosed. This material can provide both positive and negative working images having high resolution and good adhesiveness to the support. A process for producing positive working images includes the steps of imagewise exposure and development processing, while a process for producing negative working images includes the steps of imagewise exposure, heating, uniform (overall) exposure and development processing.
    Type: Grant
    Filed: July 19, 1982
    Date of Patent: February 14, 1984
    Inventors: Hiromichi Tachikawa, Yohnosuke Takahashi, Fumiaki Shinozaki, Tomoaki Ikeda
  • Patent number: 4431720
    Abstract: An improved rear-projection viewing screen is disclosed which is characterized by having on the viewed front surface of a lenticulated transparent substrate, a single layer having image-transmitting areas and intervening light-absorbing areas. The improved screen according to the invention includes light-scattering and photographically formed light-absorbing elements in a common binder system in the image-transmitting areas and in the intervening light-absorbing areas. The light-scattering elements provide for the diffusion of the viewed image in the light-transmitting areas. The light-scattering elements in the light-absorbing areas are effective to scatter light falling on the front surface of the screen thereby improving contrast of pictures viewed on the screen.
    Type: Grant
    Filed: July 19, 1982
    Date of Patent: February 14, 1984
    Assignee: Zenith Radio Corp.
    Inventor: Meyer L. Sugarman
  • Patent number: 4421839
    Abstract: A heat-sensitive recording sheet is proposed which has a heat-sensitive recording layer laminated on one surface of a support body and containing a diasosulfonate; a acid coupling agent comprising a compound having aromatic ring, hetroaromatic ring or substituted aromatic ring bonded thereto OH group and COOH group; and a thermoplastic resin having a glass transition point of 70.degree.-150.degree. C. or a photocuring resin.
    Type: Grant
    Filed: March 3, 1982
    Date of Patent: December 20, 1983
    Assignees: Dai Nippon Printing Co., Ltd., Tokyo Shibaura Denki Kabushiki Kaisha
    Inventors: Ryohei Takiguchi, Masayoshi Nagashima
  • Patent number: 4331479
    Abstract: A light-sensitive nameplate material comprising an aluminum support having a porous aluminum oxide film on the surface thereof and a light-sensitive organic coating layer comprising an o-quinone diazide provided on the aluminum oxide film.
    Type: Grant
    Filed: September 8, 1977
    Date of Patent: May 25, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Tadao Toyama
  • Patent number: 4324852
    Abstract: A radiation-sensitive element is disclosed including a radiation-sensitive layer comprised of a cobalt(III)complex and a photoreductant. A process is disclosed in which the photoreductant is converted to a reducing agent by exposure to electromagnetic radiation longer than 300 nanometers. The reducing agent is then reacted with a cobalt(III)complex. Images can be recorded directly within the radiation-sensitive layer or in a separate image-recording element or layer by use of the residual cobalt(III)complex not exposed or one or more of the reaction products produced by exposure. By using the ammonia liberated from ammine ligand containing cobalt(III)complexes on exposure in combination with imagewise and uniform exposures, positive or negative images can be formed in diazo image-recording layers or elements associated with the radiation-sensitive layer.
    Type: Grant
    Filed: June 7, 1979
    Date of Patent: April 13, 1982
    Assignee: Eastman Kodak Company
    Inventors: Anthony Adin, James C. Fleming
  • Patent number: 4307170
    Abstract: Negative-working diazography formulation is comprised of (i) at least one hexafluorophosphate diazonium salt adapted to photolytically cleave into an acid catalyst, (ii) at least one acid labile enolic, preferably arylenolic blocked-coupler adapted to be converted in the presence of acid to an active azo-coupling component, and (iii) an effective amount of an additive, such as p-toluenesulfonyl benzamide, capable of controlling the pH of films prepared from said formulation when subjected to a clearing step as defined herein.
    Type: Grant
    Filed: June 18, 1980
    Date of Patent: December 22, 1981
    Assignee: James River Graphics, Inc.
    Inventor: Robert C. Desjarlais
  • Patent number: 4307171
    Abstract: Negative-working diazography material is comprised of (i) at least one hexafluorophosphate diazonium salt adapted to photolytically cleave into an acid catalyst, (ii) at least one acid labile enolic, preferably arylenolic blocked-coupler adapted to be converted in the presence of acid to an active azo-coupling component, and (iii) an effective amount of at least one additive such as benzotriazole, urea, thiourea and derivatives thereof. The additives are believed to react with the acid released during imaging to the extent that migration thereof into the areas which have not been exposed to light is reduced or eliminated. The reduction in the migration of the liberated acid improves the D-min and line acuity of the image obtained from the formulation and the presence of the additive provides a means for decreasing the photo speed of the formulation.
    Type: Grant
    Filed: June 18, 1980
    Date of Patent: December 22, 1981
    Assignee: James River Graphics, Inc.
    Inventor: Robert C. Desjarlais
  • Patent number: 4289839
    Abstract: Negative-working diazography material is comprised of (i) at least one diazonium compound, (ii) at least one acid labile enolic, preferably phenolic blocked-coupler adapted to be converted in the presence of acid to an active azo-coupling component, (iii) at least one light-sensitive acid progenitor, and (iv) at least one carboxylic acid anhydride. The diazonium compound can itself concurrently function as the acid progenitor, e.g., when complexed with a Lewis acid. Upon imagewise exposure to light, acid catalyst is photochemically liberated, thus unblocking coupler molecules such that dye image forms under alkaline developing conditions only where the material has been irradiated. Under alkaline developing conditions, the anhydride reacts to render the unused diazo component remaining in the unexposed areas inactive.
    Type: Grant
    Filed: February 15, 1980
    Date of Patent: September 15, 1981
    Assignee: James River Graphics, Inc.
    Inventor: Carmine A. DiPippo
  • Patent number: 4284704
    Abstract: Imaging means, such as a tetrazolium salt, capable of reduction to form a visible image is present in a radiation-sensitive layer in combination with a photoreductant incorporating one or more labile hydrogen atoms and capable of producing a reducing agent precursor in radiation-struck areas of the layer. An image is produced in the layer by processing the layer after imagewise exposure to actinic radiation.
    Type: Grant
    Filed: September 29, 1978
    Date of Patent: August 18, 1981
    Assignee: Eastman Kodak Company
    Inventors: James C. Fleming, Joseph W. Manthey, Ralph T. Brongo
  • Patent number: 4268600
    Abstract: A photochemical color-printing process for textile articles wherein a photosensitive triazene and azo dye coupling agent are applied to surface of textile article, the coated textile is exposed to light with a negative image, unreacted chemical products are removed by washing and rinsing the coated textile article after imaging, and then the coated textile article is dried.
    Type: Grant
    Filed: December 1, 1978
    Date of Patent: May 19, 1981
    Assignee: Issec and Tissages de Soieries Rennis
    Inventors: Jean J. Robillard, Claude R. Riou
  • Patent number: 4252884
    Abstract: Negative-working diazography material is comprised of (i) at least one diazonium compound, (ii) at least one acid labile enolic, preferably phenolic blocked-coupler adapted to be converted in the presence of acid to an active azo-coupling component, and (iii) at least one light-sensitive acid progenitor. The diazonium compound can itself concurrently function as the acid progenitor, e.g., when complexed with a Lewis acid. Upon imagewise exposure to light, acid catalyst is photochemically liberated, thus unblocking coupler molecules such that dye image forms under alkaline developing conditions only where the material has been irradiated.
    Type: Grant
    Filed: August 14, 1979
    Date of Patent: February 24, 1981
    Assignee: James River Graphics, Inc.
    Inventor: Everett W. Bennett
  • Patent number: 4247615
    Abstract: There is disclosed a composition and element, comprising a diazo resin and a mordant for anionic dyes that is compatible with the resin. The element of the invention is suitable for dye immersion and dye transfer to a mordanted receiver.
    Type: Grant
    Filed: March 6, 1980
    Date of Patent: January 27, 1981
    Assignee: Eastman Kodak Company
    Inventors: Hugh G. McGuckin, Hyman L. Cohen
  • Patent number: 4220700
    Abstract: There is disclosed a composition and element, comprising a diazo resin and a mordant for anionic dyes that is compatible with the resin. The element of the invention is suitable for dye immersion and dye transfer to a mordanted receiver.
    Type: Grant
    Filed: February 3, 1978
    Date of Patent: September 2, 1980
    Assignee: Eastman Kodak Company
    Inventors: Hugh G. McGuckin, Hyman L. Cohen