Abstract: An image transfer method is disclosed, characterized in for the preparation of a color proof wherein separate-in-color images are formed in each colored photosensitive layer of photosensitive material coated on a thermosensitive adhesive layer on a release surface provided on a support from which the thermosensitive adhesive layer is releasable, and a multicolor image is formed on an image receiver by transferring said separate-in-color images onto said image receiver one by one together with said adhesive layer, repeating concurrent heating and pressurizing procedures, and thereafter further submitting the image receiver with the multicolor image formed thereon to heat treatment.

Abstract: The invention provides a photographic article having a protected image which comprisesa) a colored image disposed on a substrate; andb) a thin, transparent, colorless, thermoplastic adhesive composition directly on the surface of the image, wherein said adhesive is substantially non-tacky at room temperature, and comprises one or more thermoplastic polymers of copolymers capable of forming a flexible film, said adhesive being capable of being transferred directly to the image when the adhesive is first disposed on the release surface of a temporary support and said image and adhesive are laminated together under pressure at temperatures of between about 60.degree. C. and about 90.degree. C. and said temporary support is peeled away; andc) a non-self supporting antiblocking layer directly on said adhesive said antiblocking layer being transparent, colorless and comprises one or more organic polymers or copolymers, which coating does not cohesively block at about 50.degree. C. or less.

Abstract: This invention relates to an image reproduction process, more particularly a color proofing process, which utilizes a peel-apart photosensitive element comprising a strippable coversheet, a photohardenable layer, an elastomeric layer, and a support, to produce a positive image of the transparency on the coversheet and a negative image of the transparency on the elastomeric layer.

Abstract: This invention relates to positive working color proofing sheet construction which, upon exposure to an actinic radiation source through a screened image, can accuratley reprouce said image. The construction is useful as a color proofing film which can be employed to accurately predict the image quality from a lithographic printing process. The image is produced by forming a composite of a receiver base, diazo or diazide layer, photopolymerizable layer and cover sheet. Upon imagewise exposure, a positive image appears on the receiver base after dry peel apart development.

Abstract: Presensitized sheets for color proofing comprising a removable carrier sheet bearing a photosensitive medium sensitive to radiation within the wavelength band 325 to 700 nm and comprising photohardenable, photoadherent, photoinsolubilisable or photosolubilisable material, the sheet including a removable antihalation layer which is removed either when stripping the carrier sheet or during subsequent processing. The antihalation dyes may be positioned within a transparent carrier sheet, in a layer on the carrier sheet opposite to the photosensitive medium or in a layer positioned between the carrier sheet and light-sensitive medium.

Abstract: This invention relates to positive working photosensitized sheet constructions which, upon exposure to an actinic radiation source through a screened image, can accurately reproduce said image. The construction is useful as a color proofing film which can be employed to predict the image quality from a lithographic printing process.

Abstract: This invention relates to an improved negative- or positive-working, single sheet color proofing method which can accurately reproduce said images on diverse paper stocks by using a carrier to transfer the processed images to paper receiver bases. The final construction is useful in predicting the image quality from a lithographic printing process.

Abstract: This invention relates to a method for making a dry transfer, photopolymerizable positive-working imaging system which provides a photopolymerizable layer on a support and a colored layer on a substrate. Upon imagewise exposure of the photopolymerizable layer, subsequent lamination of the colored layer to the photopolymerized layer and peel apart, a colored image is produced due to the preferred adhesion of the colored layer to the nonexposed areas of the photopolymerized layer.

Abstract: The invention relates to negative photosensitized sheet constructions which, upon exposure to an actinic radiation source through a screened image, can accurately reproduce said image. The construction is useful as a color proofing film which can be employed to predict the image quality from a lithographic printing process.

Abstract: This invention relates to a process for preparing a reverse image using a pigmented peel-apart element containing a photoinhibitor. More particularly this invention relates to a process for preparing a negative or reverse surprint proof using peel-apart photosensitive elements comprising a strippable cover sheet; a photoadherent layer containing a colorant and a photoinhibitor compound; a tacky, essentially nonphotosensitive contiguous layer; and a support.

Abstract: This invention relates to water developable, negative working photosensitized sheet constructions which, upon exposure to an actinic radiation source through a screened image, can accurately reproduce said image. The construction is useful as a color proofing film which can be employed to predict the image quality from a lithographic printing process. The invention provides both overlay and transfer type proofing sheets which have good fingerprint resistance.

Abstract: A method of producing a polydiacetylene thin film comprises spreading on a water surface a diacetylene compound having one or more conjugated diacetylene groups, subjecting the diacetylene compound to incomplete polymerization by irradiation with ultraviolet rays to an extent incapable of causing complete polymerization, transferring the spread film to a substrate to form a monolayer or built-up film thereon, and irradiating the transferred film with ultraviolet rays or an electron beam to complete the polymerization thereof.

Abstract: A process for preparing a color display comprising the following steps:(a) preparing an uncolored base plate comprising a base plate, an electroconductive layer formed on said base plate and a photosensitive resin layer formed thereon, said photosensitive resin layer being patterned by exposing to light through a mask and developing it to let a portion of the electroconductive layer to be colored appear,(b) forming a color layer by electrodeposition on the portion of the electroconductive layer to be colored,(c) transferring the color layer onto a transfer plate, and(d) further transferring and fixing the color layer onto a transparent substrate from the transfer plate,wherein if the color display is colored with more than one color, the processes (a) to (d) are repeated for the other colors, but once said uncolored base plate is formed, the processes (b) to (d) are repeated.

Abstract: This invention relates to positive working photopolymerizable sheet constructions which, upon exposure to an actinic radiation source through a screened image, can accurately reproduce said image. The construction is useful as a color proofing film which can be employed to accurately predict the image quality from a lithographic printing process.

Abstract: A method of obtaining a color proof in which color-separated images are successively exposed onto colored light-sensitive layers. The layers are all transferred to a printing paper. The exposures are performed through a mask having dots of predetermined density and diameter, depending on the type of printing paper. If the color-separated images are positive, the dots are transparent on a dark background. If the color-separated images are negative, the dots are dark on a transparent background and additional exposures are made without the mask.

Abstract: An image-forming process comprising the steps of:(A) transferring an image layer, formed on a transferable light-sensitive material, onto an image-receiving sheet, and(B) transferring the image layer onto a permanent support, wherein the image-receiving sheet comprises a support having formed thereon an image-receiving layer composed of a composition containing an organic high molecular material as the main component, wherein an adhesive power P.sub.1 between the support of the image-receiving sheet and the image-receiving layer and an adhesive power P.sub.2 between the image-receiving layer and the image layer are higher than an adhesive power P.sub.3 between the image layer and the support of the transferable light-sensitive material, and also an adhesive power P.sub.4 between the permanent support and the image layer and adhesive power P.sub.1 are higher than adhesive power P.sub.

Abstract: A liquid crystal display having display filter elements in registration with display electrodes. The filters are produced using color proofing films which are imaged to produce a regular pattern of dots. Filter elements are illuminated by electrodes selection to produce changeable images.

Abstract: This invention relates to positive working photosensitized sheet constructions which, upon exposure to an actinic radiation source through a screened image, can accurately reproduce said image. The construction is useful as a color proofing film which can be employed to predict the image quality from a lithographic printing process. The element is composed of a substrate, colored photosensitive layer and adhesive layer. The adhesive layer contains an optical brightener compound which reduces residual yellow staining derived from the naphthoquinone diazide sensitizer.

Abstract: In producing a transfer print, a lacquer layer is deposited on a substrate and, in turn, a color layer, an adhesive layer, another lacquer layer, a talcum layer and a photo layer are placed on the lacquer layer. After a portion of the photo layer is exposed, the non-exposed areas of the photo layer and the other layers in register with the non-exposed areas are removed. After the exposed area of the photo layer is removed along with selected subjacent layers, the end product includes the substrate and the remaining areas of the lacquer area on the substrate, the color layer and the adhesive layer.

Abstract: A method is described for forming an image by transferring an image layer formed on a transferable light-sensitive material to an image-receiving sheet, and then further transferring the image to a permanent support, wherein the image-receiving sheet comprises a support, a first layer on the support, said first layer being made of a first organic polymeric substance, and a second layer on the first layer, said second layer being made of a second organic polymeric substance, whereinin peeling apart the image-receiving sheet from the transferable light-sensitive material,P.sub.1, P.sub.2, P.sub.3 >P.sub.4wherein P.sub.1 is an adhesion force between the support and the first layer, P.sub.2 is an adhesion force between the first and second layers, P.sub.3 is an adhesion force between the second layer and the image layer, and P.sub.

Abstract: A dry transfer film and a method for preparing transfer characters therefrom in which the transfer film includes a carrier layer, a photosensitized color carrying layer disposed adjacent to the carrier layer and a photosensitized adhesive layer disposed adjacent to the color carrying layer. Both the color carrying and adhesive layers are photosensitive to certain respective wavelengths of the electromagnetic spectrum so that when exposed to such wavelengths, they become soluble in a respective solvent or solvents. The unexposed portions of these layers remain insoluble in such solvents.

Abstract: Dry-film, negative-acting photoresist layers are used in the formation of many articles such as circuit boards, printing plates and the like. Laminable monolayers of photoresist can suffer from slow speeds, brittleness, variable adhesive characteristics, and narrow processing latitude during development and exposure. The use of a crosslinked or crosslinkable integral thermoplastic adhesive laer on the dry-film, negative-acting photoresist layer improves the properties and performance of the photoresist.

Abstract: Photopolymer positive surprint color proofing film based on epoxy acrylate monomer exhibits low dot gain, low time dependence of toning and good tonal range. Binder can be methylmethacrylate/ethyl acrylate/acrylic acid copolymer, preferably crosslinked with zinc ions and plasticized with a second acrylate monomer and a mixture of triacetin and trimethylol propane.

Abstract: The invention provides a method for protecting an image which comprises providing a colored image on a substrate and either:A. Applying an antiblocking layer to a release surface of a temporary support; bonding a thermoplastic adhesive layer to said antiblocking layer; laminating said applied support to said colored image via said adhesive; and peeling away said temporary support from said antiblocking layer; orB. applying a thermoplastic adhesive layer to a release surface of a first temporary support; applying an antiblocking layer onto a release surface of a second temporary support, laminating said adhesive onto said colored image and peeling away said first temporary support; and laminating said antiblocking layer onto said adhesive layer and peeling away said second temporary support;wherein said adhesive layer is substantially nontacky at room temperature, is laminated at temperatures between about 60.degree. C. and 90.degree. C.

Abstract: Photopolymerizable compositions containing thermally-softenable, developer resistive polymeric binders are particularly useful in image transfer systems and processes.

Abstract: A method and photo-sensitive ink solution used for producing a tone-accurate color process proof or color transfer is disclosed. The method includes multiple applications of sequential layers of extender coat powder and photo-sensitive ink solution coats. These layers are individually exposed to actinic light through a design bearing film, and that material not underlying the exposed ink coat is removed by means of a light water spray before a new series of sequential layers are applied.

Abstract: Process for forming a halftone multicolor pattern which comprises in sequence given the following steps:(1) scanningwise exposing a multicolor original attached to a rotating scanner drum to produce series of electrical signals that are fed into a computer,(2) exposing in a single scan separate black-and-white light-sensitive silver halide emulsion layer materials under the control of the computer in accordance with said signals,(3) developing the exposed silver halide emulsion layers with a hardening or tanning developing agent producing a negative or positive silver selection image that can be used as intermediate original in the production of a printing plate, a pattern of oxidized hardening developing agent being imagewise transferred during development from the emulsion layer onto a hardenable non-photosensitive colored gelatin layer originally carried on a temporary support or carried directly on a permanent support,(4) producing a colored relief image by wash-off processing of said colored gelating lay

Abstract: Process for forming a halftone or multicolor colloid pattern by the following steps in sequence:(1) scanningwise exposing to light a multicolor original carried, e.g., by a rotating scanner drum, to obtain separate red light, green light and blue light, out signals which are received by corresponding photon-conductors to produce corresponding separate series of electrical signals, which are, e.g.

Abstract: A light-sensitive color-proofing sheet is described for producing an image on various substrates. A light-sensitive continuous color layer is releasably attached to a carrier. Overlaying the color layer is a water-insoluble transparent colorless barrier layer. On the opposite surface of the barrier layer is a thermally laminable adhesive layer. Upon lamination of the sheet to a substrate, removal of the carrier and exposure to actinic radiation, the color layer is formed into an image, photomechanically, by removal of the non-image areas.

Abstract: This invention relates to positive working photosensitized sheet constructions which, upon exposure to an actinic radiation source through a screened image, can accurately reproduce said image. The construction is useful as a color proofing film which can be employed to predict the image quality from a lithographic printing process.

Abstract: A light-sensitive color proofing sheet is described for producing an image on various substrates. A light-sensitive continuous color layer is releasably attached to a carrier. Overlying the color layer is a water-insoluble transparent colorless barrier layer. On the opposite surface of the barrier layer is a thermally laminable adhesive layer. Upon lamination of the sheet to a substrate, removal of the carrier and exposure to actinic radiation, the color layer is formed into an image, photomechanically, by removal of the non-image areas.

Abstract: This invention relates to negative photosensitized sheet constructions which, upon exposure to an actinic radiation source through a screened image, can accurately reproduce said image. The construction is useful as a color proofing film which can be employed to predict the image quality from a lithographic printing process.

Abstract: There is described a photomechanical method for forming pressure sensitive transfer reproductions of color images, either single color or multicolor, upon a substrate involving the forming of a base coat protective layer on a substrate, applying one color ink layer on the base layer and a white ink overlayer on the one color ink layer. The surface of the white ink overlayer is powdered and a layer of photoresist composition is applied. The photoresist covered layered substrate is exposed to a light source through an image carrying photographic negative film to harden the photoresist at the imaged areas thereby forming a mask. Nonhardened photoresist composition areas along with their underlaying layers are removed using stepwise solvent development steps. The steps are repeated where different ink colors are to be applied to form a multicolored image.

Abstract: Disclosed is a photosensitive material which has a first photosensitive layer formed on a support body such as an aluminum plate, a peel-off layer thereon and a second photosensitive layer formed on the peel-off layer in such a manner that the second layer can be photographically exposed to light and photographically developed independently from the first photosensitive layer and the first photosensitive layer may be subsequently photographically exposed with the picture image formed on the second photosensitive layer acting as a photographic mask. After the first photosensitive layer has been photographically developed, the two photosensitive layers may be used for different purposes, for instance, using the first photosensitive layer as a printing plate and the second photosensitive layer as a photographic film for making duplicate printing plates.

Abstract: There is described a photomechanical method for forming pressure sensitive transfer reproductions of multicolor images upon a substrate involving the forming of a base coat protective layer on a substrate, applying one color ink on the base layer and a white ink overlayer on the color ink layer. The surface of the white ink overlayer is powdered and a layer of photoresist composition is applied. The photoresist covered layered substrate is exposed to a light source through an image carrying photographic negative film to harden the photoresist at the imaged areas forming a mask. Nonhardened photoresist composition areas along with their underlying layers are removed using stepwise solvent development steps. The steps are repeated for different colors with the final multicolor image being thoroughly dried and coated with a pressure sensitive adhesive to form the image transfer sheet. Drying between each step of formation is essential.

Abstract: This invention relates to photosensitized sheet constructions which, upon exposure to an actinic radiation source through a screened image, can accurately reproduce said image. The construction is useful as a color proofing film which can be employed to accurately predict the image quality from a lithographic printing process. This system allows the operator to use either a full layer transfer or an image transfer method of color proofing.

Abstract: Simplified clamshell type printed wiring board production apparatus employs a reusable thin flexible plastic film as a carrier for a photopolymer coating layer for covering part of the conductive layer of a printed wiring board with a photoproduced pattern of high resolution. For solder mask coatings, two superimposed layers of polymer with diverse characteristics are employed to give significant advantages of high resolution, low cost, less production time with unskilled labor, better adherence to bare copper conductors, better environmental and electrical properties, and low tooling costs, without problems of outgassing and without the necessity for heating and cooling cycles during lamination. Low cost liquid photopolymer coatings are used advantageously by screen transfer with a scanning squeegee in an air free bond over circuit traces of considerable thickness in the absence of a vacuum.

Abstract: The present invention provides a photosensitive element which comprises a substrate bearing on at least one surface thereof at least one photosensitive layer comprising a film forming polymer, a surfactant acid masked with a photolabile blocking group, and at least one spectral sensitizing compound conferring sensitivity within the wavelength range of 300 to 900 nm, i.e., the near UV (300 nm to 400 nm), the visible range (400 nm to 750 nm), and even into the near infrared region of the spectrum (750 to 900 nm). The composition can exhibit an increase in surface activity on irradiation with light in the wavelength range of 300 to 900 nm.In another aspect, a peel-apart imaging article and process therefor is provided having photosensitivity within the wavelength region covering the near UV, visible, and near IR, yet having good stability of the unexposed material.

Abstract: A microform article useful for producing composite images has an image-forming layer separate from a photosensitive layer and allows for the subsequent addition, when needed, just prior to imaging, of a second photosensitive, resist layer for an add-on image. The unique construction and method therefor provide a positive or negative first image, with the possibility of either positive or negative additional images, the images not necessarily being in the same phase.

Abstract: An image-forming laminate is formed by the combination of a thin, frangible light opaque material on top of a photosensitive layer which changes its surfactant properties when irradiated. The photosensitive layer according to the present invention comprises a film-forming polymeric binder, a photosensitive acid generator, and a surfactant selected from nonionic surfactants, the neutral form of cationic surfactants, amphoteric surfactants, and surfactant acid salts. Preferably the frangible light opaque material is a thin metal layer. There can also be present a support layer on the other surface of the photosensitive layer, as well as there can be an adhesive layer secured to the upper surface of the frangible light opaque material. The strength of adherence of the adhesive layer to the metal should be intermediate the strength of the adherence of the light opaque material prior to and after photoactivation.

Abstract: An improved printed wiring board (PWB) with solder mask coatings is achieved by means of a two layer composite coating. One inner adhesive photopolymer layer is applied to the PWB in the liquid state, displacing air from PWB surface. The outer layer of the composite is dry and is carried on a thin plastic sheet and overlaminated onto the liquid inner layer, without the need for a vacuum laminator. The dry film solder mask so laminated is then exposed through a phototransparency to harden the light struck dry film solder mask and light struck inner layer photopolymer, thereby cojoining the dry film solder mask, inner layer and PWB surface. A solvent washout step removes unexposed dry film solder mask and unexposed inner layer photopolymer. This provides a faster process, requires less equipment, and improves adhesion to metal conductors. The outer layer need not be photoimaged.

Abstract: Process for preparing a surprint proof using an imagewise exposed peel apart photosensitive element comprising a strippable cover sheet, a photoadherent layer containing a colorant, a tacky nonphotosensitive contiguous layer, and a support wherein after peeling apart, if exposed through a separation negative, a positive colored photoadherent image on the cover sheet is adhered to a substrate, or, if exposed through a separation positive, a positive colored photoadherent image on the supported contiguous layer is adhered to a substrate. By repeating the process different colored layers can be built upon the substrate to form the surprint proof.

Abstract: Process for preparing a positive overlay using an imagewise exposed peel apart photosensitive element comprising a strippable cover sheet, photoadherent layer containing a colorant, a tacky, nonphotosensitive contiguous layer, and a support wherein after peeling apart the element bearing the contiguous layer and complementary colored unexposed areas is adhered to a transparent receptor, and the transparent and colored unexposed image adhered thereto are removed. By repeating the procedure with peel apart elements of different color and overlaying the images in register colored proofs are prepared.

Abstract: A process for preparing a color proofing sheet is disclosed. The process comprises imagewise exposing a light-sensitive image-forming material comprising a transparent support having provided thereon a dye- or pigment-containing light-sensitive photoresist composition layer or both a dye- or pigment-containing colorant layer and a light-sensitive photoresist composition layer through a color separation mask, developing the material to form a color separation image, transferring the color separation image onto a photopolymerizable image-receiving layer, transferring in registration at least one more color separation image onto the same image-receiving layer to obtain a multicolored color proofing sheet on a single support, and totally exposing the image-receiving layer after the image transfer in an amount sufficient to induce photopolymerization thereof.

Abstract: The finished surface of a multicolor surprint proof is made to exhibit a matte appearance and closely simulate the surface texture of the printing stock to which it is applied. Individual colored image adhesive layers are laminated in register to a receptor sheet which comprises a coated layer of film-forming polymer composition on a polyester carrier sheet having a matte texture surface. Subsequent to final adhesive lamination of the assembled surprint to desired printing stock, the receptor carrier sheet is stripped from the polymer film layer to yield a tough protective film overlayer which complements the matte texture of the original receptor carrier sheet surface and provides the desired matte appearance of the multicolor proof.

Abstract: A photosensitive element is provided by an actinic radiation-transmissive film-forming polymeric material which contains photolabile blocked surfactant capable upon exposure to actinic radiation of releasing a detectable quantity of surfactant in actinic radiation exposed areas in areas not exposed to actinic radiation and unblocked surfactant in an image-wise pattern in the actinic radiation exposed areas. An imaging process is also provided comprising providing the actinic radiation-sensitive element and exposing the actinic radiation-sensitive element to actinic radiation in an image-wise pattern at an intensity and for a time sufficient to release an image-wise pattern of released surfactant in the exposed area.

Abstract: Image color faithfulness can be improved by permanent lamination of the individual proofing sheets. Color proofing sheets are used with transparent, colorless adhesive on the backside of the sheets.

Abstract: An image reproduction process which comprises exposing a multilayer element comprising (1) cover sheet, (2) photoadherent layer, and (3) tonable contiguous layer; stripping the cover sheet with either the exposed or unexposed areas of the photoadherent layer adhered thereto while the other areas of the photoadherent layer remain on the contiguous layer; and toning the areas of the contiguous layer from which the photoadherent layer were removed. Reverse and duplicate images can be produced.

Abstract: An improved printed wiring board (PWB) with solder mask coatings is achieved by means of a two layer composite coating. One inner adhesive photopolymer layer is applied to the PWB in the liquid state, displacing air from PWB surface. The outer layer of the composite is dry and is carried on a thin plastic sheet and overlaminated onto the liquid inner layer, without the need for a vacuum laminator. The dry film solder mask so laminated is then exposed through a phototransparency to harden the light struck dry film solder mask and light struck inner layer photopolymer, thereby cojoining the dry film solder mask, inner layer and PWB surface. A solvent washout step removes unexposed dry film solder mask and unexposed inner layer photopolymer. This provides a faster process, requires less equipment, and improves adhesion to metal conductors. The outer layer need not be photoimaged.