Stripping Layer Containing Specified Synthetic Nonradiation Sensitive Polymer Patents (Class 430/262)
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Patent number: 5738971Abstract: A photosensitive composition comprises an organic polymer and a photo-polymerizable monomer. The photo-polymerizable monomer has the following formula: ##STR1## in which R.sup.1 represents an alkylene group having 2 to 5 carbon atoms, R.sup.2 represents a hydrogen atom or an alkyl group having 1 to 5 carbon atoms, and n represents the number of 0.5 to 5.Type: GrantFiled: December 20, 1995Date of Patent: April 14, 1998Assignee: Fuji Photo Film Co., Ltd.Inventors: Tamotsu Suzuki, Mikio Totsuka
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Patent number: 5738970Abstract: A negative-acting color proofing element comprising, sequentially, (i) a strippable, transparent cover sheet; (ii) a crosslinked layer, which comprises a polymer having phenolic groups; (iii) a color layer, which comprises an organic binder, a polymerizable monomer, a colorant, and an optional photoinitiator, (iv) a photoadhering layer, which comprises a polymerizable component having at least one ethylenically unsaturated group; a polymer comprising polyvinyl acetal and polyvinyl alcohol segments, having from about 1 to about 40 weight % polyvinyl alcohol content; and an optional photoinitiator, wherein least one of either the color layer or the photoadhering layer contains a photoinitiator; (v) a thermoplastic adhesive layer; and (vii) a receiver sheet. Preferably the polymerizable component and photoinitiator diffuse into the color layer during assembly of the element.Type: GrantFiled: March 24, 1997Date of Patent: April 14, 1998Assignee: Bayer CorporationInventors: Shane Hsieh, Rusty Koenigkramer, Shuchen Liu, Richard Shadrach, David Siegfried, Wojciech Wilczak
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Patent number: 5725988Abstract: This invention provides an improved negative-working or positive-working, single sheet color proofing method which can accurately reproduce images by using colored, photosensitive layers on substrates which are then overcoated with partially developable adhesive layers. The final construction is useful in predicting the image quality from a lithographic printing process. The partial removal of the adhesive layers cleans out any background stain which may remain from the incomplete removal of the photosensitive layer.Type: GrantFiled: December 7, 1993Date of Patent: March 10, 1998Assignee: Bayer CorporationInventor: Stephan J. W. Platzer
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Patent number: 5695919Abstract: Imaging elements, such as photographic films and papers, are comprised of a support, an image-forming layer and at least one auxiliary layer containing solvent-dispersible polymer particles. The auxiliary layer having been formed from a coating solution comprising a continuous liquid organic medium having dispersed therein lubricant impregnated core/shell polymer particles, the polymer particles comprising a core portion which is insoluble in the organic medium and a shell portion which has an affinity for both the core portion and the organic medium.Type: GrantFiled: August 12, 1996Date of Patent: December 9, 1997Assignee: Eastman Kodak CompanyInventors: Yongcai Wang, Charles Chester Anderson, James Lee Bello, Mario Dennis DeLaura
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Patent number: 5683852Abstract: A light-sensitive material for producing color-test films for multi-color printing is disclosed. The material has (A) a transparent flexible base film of a plastic, (B) a photopolymerizable layer containing (B1) a polymeric binder, (B2) a compound polymerizable by a free-radical mechanism, (B3) a compound capable of initiating the polymerization of (B2) under the action of actinic light, and (B4) a dye or a colored pigment in one of the basic colors of multi-color printing, and (C) a thermoplastic adhesion layer on the light-sensitive layer is described. A polymer of a vinyl alkyl ether is present in at least one of the layers (B) and (C). The material is processed by lamination to an image-receiving material, with subsequent exposure and peeling-apart of base film and image-receiving material. The unexposed layer areas remain together with the adhesion layer on the image-receiving material. These steps are repeated with at least one further part-color image.Type: GrantFiled: January 29, 1996Date of Patent: November 4, 1997Assignee: Agfa-Gevaert AGInventors: Karin Maerz, Stephan J. W. Platzer
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Patent number: 5677106Abstract: A lithographic printing plate is comprised of a support having a porous hydrophilic surface, such as grained and anodized aluminum, and an oleophilic imaging layer overlying the porous hydrophilic surface. The imaging layer is comprised of an oleophilic, radiation-absorbing, heat-sensitive, film-forming composition which is readily removable from the porous hydrophilic surface prior to imagewise exposure and which is adapted to form a lithographic printing surface as a result of imagewise exposure to absorbable electromagnetic radiation and subsequent removal of the non-exposed areas to reveal the underlying porous hydrophilic surface. Examples of suitable techniques for removing the non-exposed areas include contact with printing ink on the press, removal by lamination and peel development steps and removal by use of an integral stripping layer.Type: GrantFiled: August 16, 1996Date of Patent: October 14, 1997Assignee: Eastman Kodak CompanyInventors: Mitchell Stewart Burberry, Sharon Wheten Weber, Charles David DeBoer
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Patent number: 5674658Abstract: A lithographic printing plate is comprised of a support having a porous hydrophilic surface, such as grained and anodized aluminum, and an oleophilic imaging layer overlying the porous hydrophilic surface. The imaging layer is comprised of an oleophilic, radiation-absorbing, heat-sensitive, film-forming composition which is readily removable from the porous hydrophilic surface prior to imagewise exposure and which is adapted to form a lithographic printing surface as a result of imagewise exposure to absorbable electromagnetic radiation and subsequent removal of the non-exposed areas to reveal the underlying porous hydrophilic surface. Examples of suitable techniques for removing the non-exposed areas include contact with printing ink on the press, removal by lamination and peel development steps and removal by use of an integral stripping layer.Type: GrantFiled: August 14, 1995Date of Patent: October 7, 1997Assignee: Eastman Kodak CompanyInventors: Mitchell Stewart Burberry, Sharon Wheten Weber, Charles David DeBoer
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Patent number: 5667935Abstract: An element comprising, in order: (a) a removable substrate; (b) a transparent, nonphotosensitive, polymeric layer having a thickness of less than about 0.002 cm and a gloss of 45-70; said polymeric layer consisting essentially of at least one thermoplastic polymer having an elongation at break of greater than 30%, a glass transition temperature of 35.degree.-70.degree. C.; and (c) an elastomeric layer and optionally an additional, different removable substrate (d) adjacent to the elastomeric layer, wherein the polymeric layer exhibits improved adhesion to the removable substrate (a) when removable substrate (d) is removed is described.Type: GrantFiled: May 4, 1995Date of Patent: September 16, 1997Assignee: E. I. Du Pont de Nemours and CompanyInventor: Anchi Hou
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Patent number: 5665516Abstract: The present invention provides an imaging element comprising in the order given on a hydrophilic surface of a support (i) an image receiving layer containing physical development nuclei, (ii) a photosensitive layer containing a silver halide emulsion being in water permeable relationship with said image receiving layer and (iii) an intermediate layer between said image receiving layer and said photosensitive layer, characterized in that said intermediate layer comprises particles of an alkali insoluble polymeric organic compound obtainable by polycondensation, said particles having a number average size between 0.02 .mu.m and 10 .mu.m.According to the present invention there is also provided a method for making an offset printing plate according to the silver salt diffusion transfer process by using said imaging element.Type: GrantFiled: November 6, 1996Date of Patent: September 9, 1997Assignee: AGFA-Gevaert, N.V.Inventors: Hendrik Kokelenberg, Ronny De Clercq, Jan Gilleir, Paul Coppens, Johan Loccufier
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Patent number: 5643657Abstract: An aqueous processable, photoimageable element for use as a permanent coating for the protection of printed circuits composed of multiple layers of photoimageable compositions has suffiently low tack to avoid premature adhesion to the printed circuit substrate but develops good adhesion to the circuit substrate upon application of heat and pressure during lamination.Type: GrantFiled: April 28, 1995Date of Patent: July 1, 1997Assignee: E. I. du Pont de Nemours and CompanyInventors: Thomas Eugene Dueber, Frank Leonard Schadt, III
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Patent number: 5643710Abstract: The present invention provides an imaging element comprising in the order given (i) a hydrophilic base, (ii) an image receiving layer containing physical development nuclei, (iii) a photosensitive layer containing a silver halide emulsion being in water permeable relationship with said image receiving layer and (iv) an intermediate layer between said image receiving layer and said photosensitive layer, characterized in that said intermediate layer comprises particles of a water insoluble inorganic compound having a number average size not lower than 0.02 .mu.m and lower than 3 .mu.m.According to the present invention there is also provided a method for making an offset printing plate according to the silver salt diffusion transfer process by using said imaging element.sup.+.Type: GrantFiled: December 8, 1995Date of Patent: July 1, 1997Assignee: Agfa-Gevaert, N.V.Inventors: Paul Coppens, Eric Hoes, Johan Loccufier, Ronny De Clercq
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Patent number: 5635331Abstract: Blocking is substantially reduced between individual sheets having a thermal adhesive coated thereon by including a release agent with the thermal adhesive. Preferred release agents are materials which have previously been used as low-adhesion backsize (LAB) coatings in pressure-sensitive adhesive applications.Type: GrantFiled: October 13, 1994Date of Patent: June 3, 1997Assignee: Minnesota Mining and Manufacturing CompanyInventors: Steven L. Kangas, Charles W. Graves, Ramesh C. Kumar
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Patent number: 5633114Abstract: An image-receiving element for use in photographic and photothermographic diffusion transfer film units of the type wherein the image-receiving element is designed to be removed or "peeled-apart" from a photosensitive element following exposure and processing. The present image-receiving element comprises in sequence, a support, an image-receiving layer, and an overcoat layer. The overcoat layer comprises a major amount by dry weight of water-insoluble particles and a minor amount by dry weight of a water-insoluble polymeric latex binder material. The water-insoluble particles may comprise inorganic particles such as colloidal silica, and/or organic particles such as water-insoluble polymeric latex particles.Type: GrantFiled: June 28, 1996Date of Patent: May 27, 1997Assignee: Polaroid CorporationInventor: Kenneth C. Waterman
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Patent number: 5631107Abstract: Disclosed is a method for producing an optical member having excellent optical characteristics. An optical member is composed of a support plate and an optical sheet stuck on said plate via an optical adhesive. The optical adhesive is made sticky after it is coated, including ultraviolet-curing adhesives, epoxy adhesives and their mixtures. To produce the optical member, the optical sheet is formed on the surface of a fixed substrate via a transfer film. The optical adhesive is coated onto the optical sheet, the adhesive is made sticky on the sheet, the fixed substrate is peeled off, the sheet is stuck onto the support plate using the adhesive, and the adhesive is cured.Type: GrantFiled: August 30, 1996Date of Patent: May 20, 1997Assignee: Nippondenso Co., Ltd.Inventors: Hiroyuki Tarumi, Teiyuu Kimura, Satoshi Koike, Kazumasa Kurokawa, Tetsuya Kato, Masayuki Goto
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Patent number: 5631117Abstract: A method of manufacturing a light-heat converting heat mode recording material comprises a first support having thereon a cushion layer, an intermediate layer and an image forming layer in that order, the material comprising a light-heat converting substance, the method comprising the steps of a) providing a first unit comprising a first support; b) providing a second unit comprising a second support having thereon the image forming layer; c) superposing the second unit on the first unit so that the image forming layer is in close contact with the first unit; and d) separating the second support from the image forming layer to form the recording material, wherein the second support has a releasing layer containing a cross-linked compound on the image forming layer side, the releasing layer being insoluble in a coating solvent for both the intermediate layer and the image forming layer, and provided between the second support, or has a releasing layer containing a fluorine-containing compound or a long chain aType: GrantFiled: January 18, 1996Date of Patent: May 20, 1997Assignee: Konica CorporationInventors: Atsushi Nakajima, Ai Katsuda, Sota Kawakami, Shinji Kudo
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Patent number: 5629132Abstract: A method for engraving and/or etching comprising the steps of: (a) a process for exposing, to light, a layer of a water-soluble resin composition of a laminated photo-sensitive film which comprises a supporting sheet, a image mask-protection layer peelablly adhered to the supporting sheet and a layer of a water-soluble resin composition having photocrosslinkability to thus cause crosslinking of the exposed area of the resin layer to thereby form a predetermined pattern on the resin layer; (b) a process for dissolving out the non-crosslinked portion of the layer of the water-soluble photo-sensitive resin composition by developing the layer with water to thus from an image-carrying mask which is constituted from the crosslinked area of the photo-sensitive resin composition remaining on the image mask-protection layer; (c) a process for adhering the photo-sensitive laminate film on which the images are formed to the surface of a material to be processed; (d) a process for peeling off the supporting sheet from thType: GrantFiled: February 28, 1996Date of Patent: May 13, 1997Assignee: Aicello Chemical Co., Ltd.Inventors: Tsutomu Suzuki, Ikuo Suzuki
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Patent number: 5627009Abstract: The invention relates to a photosensitive material for the production of color proofing films for multicolor printing comprising:A) a transparent, flexible film support,B) a photopolymerizable layer containing:B1) a polymeric binder,B2) a free radical-polymerizable compound,B3) a compound which is capable of initiating the polymerization of (B2) on exposure to actinic light, andB4) a dye or colored pigment in a primary color of multicolor printing, andC) a thermoplastic adhesive layer on the photosensitive layer,which contains at least about 1.5% by weight of a water-soluble, colorless, low-molecular-weight salt whose aqueous solution is not highly acidic.The material is processed by lamination onto an image-receiving material, exposure and peeling apart of the film support and the image-receiving material, the unexposed areas of the layer and the adhesive layer remaining on the image-receiving material.Type: GrantFiled: September 26, 1995Date of Patent: May 6, 1997Assignee: Agfa-Gevaert AGInventors: Karin Maerz, Ine Gramm, Manfred Hilger, Dieter Mohr, Stephan J. W. Platzer
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Patent number: 5612168Abstract: An image transfer sheet comprises a base sheet, an intermediate thermoplastic resin layer and a top developer layer containing a binder. The binder of the top layer and the thermoplastic resin of the intermediate layer include a polymer having a common monomer component so that separation of the top layer from the intermediate layer and splitting of the top layer are effectively prevented. This provides a clear, high quality image on an image receiving surface such as paper by transference of a developed image on the developer layer.Type: GrantFiled: May 19, 1993Date of Patent: March 18, 1997Assignee: Brother Kogyo Kabushiki KaishaInventor: Keiko Ishikawa
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Patent number: 5609984Abstract: An element comprising, in order: (a) a removable substrate; (b) a transparent, nonphotosensitive, polymeric layer having a thickness of less than about 0.002 cm and a gloss of 45-70; said polymeric layer consisting essentially of at least one thermoplastic polymer having an elongation at break of greater than 30%, a glass transition temperature of 35.degree.-70.degree. C.; and (c) an elastomeric layer and optionally an additional, different removable substrate (d) adjacent to the elastomeric layer, wherein the polymeric layer exhibits improved adhesion to the removable substrate (a) when removable substrate (d) is removed is described.Type: GrantFiled: May 4, 1995Date of Patent: March 11, 1997Assignee: E. I. Du Pont de Nemours and CompanyInventor: Anchi Hou
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Patent number: 5609985Abstract: Disclosed are a color image-formable material which comprises a support, a cushion layer provided on the support and a color light-sensitive layer containing a light-sensitive composition and a coloring agent provided on the cushion layer and gives a transferred image by forming a color image portion by imagewise exposure and developing treatment and then transferring the color image portion alone to an image-receiving material,wherein the surface at a color light-sensitive layer side of the cushion layer has an average gloss (GS (60.degree. )) of 30 or more and the color light-sensitive layer is provided on the cushion layer, a process for preparing the same.Type: GrantFiled: September 20, 1994Date of Patent: March 11, 1997Assignees: Konica Corporation, Mitsubishi Chemical CorporationInventors: Tetsuya Taniguchi, Kiyoshi Goto, Takeo Akiyama, Miyuki Hosoi, Tetsuya Masuda, Hideaki Mochizuku
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Patent number: 5599648Abstract: Surface reforming of a polymeric article containing a polymerizable compound is effectively performed by polymerizing the polymeric article in contact with a surface reforming medium because the transfer of the material constituting the surface reforming medium to the polymeric article is enhanced by the polymerization. The surface reforming can be performed locally selectively, i.e., imagewise. The remaining un-polymerized part may be subjected to further surface reforming, e.g., by using another type of surface reforming medium or attachment of powder, to provide an enhanced contrast of surface property. Such an enhanced contrast of surface property can be effectively used, e.g., for production of a printing plate.Type: GrantFiled: November 26, 1993Date of Patent: February 4, 1997Assignee: Canon Kabushiki KaishaInventors: Yuji Kondo, Masato Katayama, Akihiro Mouri
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Patent number: 5597676Abstract: The present invention provides a method for obtaining an imaging element suitable for use in a silver salt diffusion transfer process by the steps of:preparing an image receiving element by coating the anodized surface of an aluminum foil with an image-receiving layer comprising physical development nuclei,preparing a photosensitive layer packet by coating a temporary base with at least one photosensitive silver halide emulsion layer,pressing the thus formed photosensitive layer packet with its photosensitive silver halide emulsion coated side against said image receiving layer, which has been wet with an aqueous moistening liquid, andoptionally removing said temporary base, characterized in that between said temporary base and said at least one photosensitive silver halide emulsion layer a barrier layer is present which is substantially free of developing agents, is substantially unhardened, comprises one or more hydrophilic binders in an amount of at least 0.25 g/m.sup.Type: GrantFiled: August 17, 1995Date of Patent: January 28, 1997Assignee: AGFA-Gevaert. N.V.Inventors: Ludo Van Rompuy, Paul Coppens
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Patent number: 5593811Abstract: (A) being a photosensitive relief-forming layer in which imagewise exposure to actinic light results in different solubilities of the exposed and unexposed parts, and this layer consists of a mixture of:(a1)one or more polymeric binders,(a2)one or more photopolymerization initiators,(a3)one or more organic compounds which are compatible with the binder (a1) and contain photopolymerizable olefinically unsaturated groups and, if required,(a4)one or more assistants,(B) being a smooth or dull, nontacky release layer (B) which is transparent to light, soluble or swellable in the relevant liquid media and formed by a polymer forming strong films and additives contained therein, and(C) being a cover sheet which can be detached from the release layer (B), the release layer (B) containing a metal salt as an additive,is suitable for the production of printing plates.Type: GrantFiled: December 21, 1995Date of Patent: January 14, 1997Assignee: BASF Lacke+Farben AktiengesellschaftInventors: Thomas Loerzer, Stefan Wegener, Friedrich Goffing
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Patent number: 5593809Abstract: There are described a diffusion transfer photographic film unit of the type wherein an image-receiving element is designed to be separated from a photosensitive element after photoexposure and processing and a photographic process which utilizes the film unit. The photographic film unit comprises a photosensitive element including a support carrying at least one silver halide emulsion, an image-receiving element comprising a support, an image-receiving layer and, optionally, an overcoat layer and/or a strip-coat layer. At least one of the image-receiving layer, overcoat layer or strip-coat layer includes a "crosslinkable material" which is crosslinked during processing. The film unit further includes means for providing an aqueous alkaline processing composition to the photosensitive element and the image-receiving element for developing an image. The aqueous alkaline processing composition includes a borate compound for crosslinking the crosslinkable material of the image-receiving element during processing.Type: GrantFiled: December 7, 1995Date of Patent: January 14, 1997Assignee: Polaroid CorporationInventors: Gia Y. Kim, Lloyd D. Taylor, Kenneth C. Waterman
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Patent number: 5578413Abstract: A photosensitive transfer material is disclosed including a temporary substrate having provided thereon an alkali-soluble thermoplastic resin layer, an intermediate layer, and a photosensitive resin layer in this order, the transfer material having an interlaminar adhesion which is lowest between the thermoplastic resin layer and the temporary substrate, wherein the alkali-soluble thermoplastic resin layer contains (A) an alkali-soluble thermoplastic resin having a weight average molecular weight of from 50,000 to 500,000 and a glass transition temperature of from 0.degree. to 140.degree. C. and (B) an alkali-soluble thermoplastic resin layer having a weight average molecular weight of from 3,000 to 30,000 and a glass transition temperature of from 30.degree. to 170.degree. C. at an (A)/(B) weight ratio of from 5/95 to 95/5. The transfer material can be transferred to a permanent substrate at a high speed without entrapping air bubbles due to unevenness on the permanent substrate.Type: GrantFiled: March 15, 1996Date of Patent: November 26, 1996Assignee: Fuji Photo Film Co., Ltd.Inventors: Sadao Fujikura, Minoru Wada
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Patent number: 5565301Abstract: A process for forming a colored image comprising, in order:(A) imagewise exposing to actinic radiation a photosensitive element comprising a carrier support, a carrier surface, a first adhesive layer and a first photosensitive layer,(B) developing the exposed first photosensitive layer,(C) laminating to the element a transfer element comprising a transfer support, and a transfer surface layer which is adjacent to a colored pattern in the element of step (A) with the proviso that the transfer element does not have an adhesive layer which transfers to the colored pattern,(D) removing said carrier support and said carrier surface, revealing said first adhesive layer,(E) laminating the element the element from step (D) to a permanent support wherein the first adhesive layer is adjacent to the permanent support; and(F) removing said transfer support and said transfer surface layer.Type: GrantFiled: August 2, 1993Date of Patent: October 15, 1996Assignee: E. I. Du Pont de Nemours and CompanyInventor: Gregory A. Bodager
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Patent number: 5563020Abstract: The present invention provides a photosensitive transfer sheet which does not generate cutting powder when the exposed and developed transfer sheet is cut with scissors as needed after forming an image. Additionally, no film floating and image disruption accompanied by a kink mark generated on handling the exposed and developed transfer sheet are observed. Furthermore, the above-described performance and transferability are maintained even under low humidity conditions.Type: GrantFiled: April 24, 1995Date of Patent: October 8, 1996Assignee: Fuji Photo Film Co., Ltd.Inventors: Mikio Totsuka, Takekatsu Sugiyama
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Patent number: 5547811Abstract: A photosensitive material for making color-proofing films for multicolor printing is described, withA) a transparent flexible support of plastic,B) a photopolymerizable layer on (A) which containsB1) a polymeric binder,B2) a compound polymerizable by a free-radical mechanism,B3) a compound which is capable of initiating the polymerization of (B2) under the action of actinic light andB4) a dye or a color pigment in a primary color of the multicolor print, andC) a thermoplastic adhesive layer which comprises at least one polymer which contains units (C1) with aliphatic side chains having at least 5 carbon atoms.The material is processed by laminating to an image receptor sheet, exposure and peeling apart of support and image receptor sheet, the unexposed layer areas remaining together with the adhesive layer on the image receptor sheet. These steps are repeated with at least one further image in primary colors. The material provides for a reduction of the background stain in the non-image areas.Type: GrantFiled: November 14, 1995Date of Patent: August 20, 1996Assignee: Agfa-Gevaert AGInventors: Karin Maerz, Volker Matz, Detlev Seip, Stephen J. W. Platzer
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Patent number: 5543273Abstract: Radiation-sensitive photographic plates are prepared by laminating to a rigid transparent plate support a photographic element comprised of a flexible photographic film support having a radiation-sensitive silver halide emulsion layer on one side thereof and a remoistenable adhesive layer on the opposite side thereof. The adhesive layer is non-tacky in the dry state but is reactivated by moistening so as to strongly bond the photographic element to the rigid transparent plate support.Type: GrantFiled: February 24, 1995Date of Patent: August 6, 1996Assignee: Eastman Kodak CompanyInventors: Thomas M. Smith, Arlene L. Meyer
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Patent number: 5534384Abstract: A photosensitive material for the production of color proofing films for multicolor printing, having(A) a transparent, flexible film support of plastic,(B) a photopolymerizable layer which contains(B1) a polymeric binder,(B2) a free-radically polymerizable compound,(B3) a compound which is capable of initiating the polymerization of (B2) on exposure to actinic light, and(B4) a dye or a colored pigment in a primary color of multicolor printing, and(C) a thermoplastic adhesive layer having a layer weight of from about 2 to about 30 g/m.sup.2 on the photo-sensitive layer, wherein the thermoplastic adhesive layer contains from about 0.01 to about 0.5% by weight of a colorless pigment having a mean particle size which corresponds to from 1 to 100% of the layer thickness.Type: GrantFiled: February 19, 1993Date of Patent: July 9, 1996Assignee: Hoechst AktiengesellschaftInventors: Stephan J. W. Platzer, Siegfried Nuernberger, Karin Maerz
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Patent number: 5534094Abstract: A method and apparatus for releasing a workpiece from a substrate including providing a substrate which is transparent to a predetermined wavelength of electromagnetic radiation; forming, on the substrate, a separation layer which degrades in response to the predetermined radiation; providing the workpiece on the separation layer; and directing the predetermined radiation at the separation layer through the transparent substrate so as to degrade the separation layer and to separate the workpiece from the substrate.Type: GrantFiled: September 29, 1994Date of Patent: July 9, 1996Assignee: IBM CorporationInventors: Gnanalingam Arjavalingam, Alina Deutsch, Fuad E. Doany, Bruce K. Furman, Donald J. Hunt, Chandrasekhar Narayan, Modest M. Oprysko, Sampath Purushothaman, Vincent Ranieri, Stephen Renick, Jane M. Shaw, Janusz S. Wilczynski, David F. Witman
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Patent number: 5529879Abstract: This invention relates to a photosensitive sheet having on a substrate one or more resin layers that are peelable from the substrate and heat-fusible, and a colored photosensitive layer in this order, said substrate comprising a biaxially stretched plastic film and having a molecular orientation ratio in the range of from 1.0 to 1.4.The object of this invention is to solve the problem of misregister without decreasing productivity during the formation of plastic film (substrate) or during the production of a photosensitive sheet in a method in which said photosensitive sheet having an image formed thereon and an image receiving sheet for receiving the image are superimposed on each other, and pressed and heated for image transfer.Type: GrantFiled: March 31, 1993Date of Patent: June 25, 1996Assignee: Nippon Paper Industries Co., Ltd.Inventors: Mitsuhide Hoshino, Fukuo Murata, Norio Yabe, Masahide Takano
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Patent number: 5525454Abstract: A photosensitive transfer material is disclosed including a temporary substrate having provided thereon an alkali-soluble thermoplastic resin layer, an intermediate layer, and a photosensitive resin layer in this order, the transfer material having an interlaminar adhesion which is lowest between the thermoplastic resin layer and the temporary substrate, wherein the alkali-soluble thermoplastic resin layer contains (A) an alkali-soluble thermoplastic resin having a weight average molecular weight of from 50,000 to 500,000 and a glass transition temperature of from 0.degree. to 140.degree. C. and (B) an alkali-soluble thermoplastic resin layer having a weight average molecular weight of from 3,000 to 30,000 and a glass transition temperature of from 30.degree. to 170.degree. C. at an (A)/(B) weight ratio of from 5/95 to 95/5. The transfer material can be transferred to a permanent substrate at a high speed without entrapping air bubbles due to unevenness on the permanent substrate.Type: GrantFiled: July 8, 1994Date of Patent: June 11, 1996Assignee: Fuji Photo Film Co., Ltd.Inventors: Sadao Fujikura, Minoru Wada
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Patent number: 5518857Abstract: A method for engraving and/or etching comprising the steps of: (a) a process for exposing, to light, a layer of a water-soluble resin composition of a laminated photo-sensitive film which comprises a supporting sheet, a image mask-protection layer peelablly adhered to the supporting sheet and a layer of a water-soluble resin composition having photocrosslinkability to thus cause crosslinking of the exposed area of the resin layer to thereby form a predetermined pattern on the resin layer; (b) a process for dissolving out the non-crosslinked portion of the layer of the water-soluble photo-sensitive resin composition by developing the layer with water to thus from an image-carrying mask which is constituted from the crosslinked area of the photo-sensitive resin composition remaining on the image mask-protection layer; (c) a process for adhering the photo-sensitive laminate film on which the images are formed to the surface of a material to be processed; (d) a process for peeling off the supporting sheet from thType: GrantFiled: January 13, 1995Date of Patent: May 21, 1996Assignee: Aicello Chemical Co., Ltd.Inventors: Tsutomu Suzuki, Ikuo Suzuki
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Patent number: 5492791Abstract: A photosensitive material for making color-proofing films for multicolor printing is described, withA) a transparent flexible support of plastic,B) a photopolymerizable layer on (A) which containsB1) a polymeric binder,B2) a compound polymerizable by a flee-radical mechanism,B3) a compound which is capable of initiating the polymerization of (B2) under the action of actinic light andB4) a dye or a color pigment in a primary color of the multicolor print, andC) a thermoplastic adhesive layer which comprises at least one polymer which contains units (C1) with aliphatic side chains having at least 5 carbon atoms.The material is processed by laminating to an image receptor sheet, exposure and peeling apart of support and image receptor sheet, the unexposed layer areas remaining together with the adhesive layer on the image receptor sheet. These steps are repeated with at least one further image in primary colors. The material provides for a reduction of the background stain in the non-image areas.Type: GrantFiled: April 28, 1995Date of Patent: February 20, 1996Assignee: Hoechst AktiengesellschaftInventors: Karin Maerz, Volker Matz, Detlev Seip, Stephan J. W. Platzer
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Patent number: 5478694Abstract: The invention relates to a photosensitive material for the production of color proofing films for multicolor printing comprising:A) a transparent, flexible film support,B) a photopolymerizable layer containing:B1) a polymeric binder,B2) a free radical-polymerizable compound,B3) a compound which is capable of initiating the polymerization of (B2) on exposure to actinic light, andB4) a dye or colored pigment in a primary color of multicolor printing, andC) a thermoplastic adhesive layer on the photosensitive layer,which contains at least about 1.5% by weight of a water-soluble, colorless, low-molecular-weight salt whose aqueous solution is not highly acidic.The material is processed by lamination onto an image-receiving material, exposure and peeling apart of the film support and the image-receiving material, the unexposed areas of the layer and the adhesive layer remaining on the image-receiving material.Type: GrantFiled: May 17, 1993Date of Patent: December 26, 1995Assignee: Hoechst AktiengesellschaftInventors: Karin Maerz, Ine Gramm, Manfred Hilger, Dieter Mohr, Stephan J. W. Platzer
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Patent number: 5478695Abstract: Heat-sensitive imaging element comprising a support carrying a binder layer, optionally an intermediate adhesive layer, and and a barrier layer that is ablatable by a laser beam or permeabilizable under the influence of a laser beam, wherein said binder layer contains at least one hydrophobizing agent capable of diffusing under the influence of heat through holes made in said barrier layer or through permeabilized parts of said barrier layer and capable of reacting with the oleophobic surface of a printing plate precursor brought in face-to-face contact with said barrier layer. The present invention also relates to a process for producing a lithographic printing plate, wherein use is made of such heat-sensitive imaging element.Type: GrantFiled: November 22, 1993Date of Patent: December 26, 1995Assignee: AGFA-Gevaert, N.V.Inventor: Luc Leenders
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Patent number: 5443939Abstract: A light-sensitive material for producing color-test films for multi-color printing is disclosed. The material has (A) a transparent flexible base film of a plastic, (B) a photopolymerizable layer containing (B1) a polymeric binder, (B2) a compound polymerizable by a free-radical mechanism, (B3) a compound capable of initiating the polymerization of (B2) under the action of actinic light, and (B4) a dye or a colored pigment in one of the basic colors of multi-color printing, and (C) a thermoplastic adhesion layer on the light-sensitive layer is described. A polymer of a vinyl alkyl ether is present in at least one of the layers (B) and (C). The material is processed by lamination to an image-receiving material, with subsequent exposure and peeling-apart of base film and image-receiving material. The unexposed layer areas remain together with the adhesion layer on the image-receiving material. These steps are repeated with at least one further part-color image.Type: GrantFiled: March 14, 1994Date of Patent: August 22, 1995Assignee: Hoechst AktiengesellschaftInventors: Karin Maerz, Stephan J. W. Platzer
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Patent number: 5437963Abstract: The present invention provides a heat mode recording material comprising on the same side of a non-conductive support a conductive recording layer and an elastomeric image forming layer being non-conductive characterised in that a peelable polymeric film is provided as an outermost layer on the side of said support containing said elastomeric image forming layer.Type: GrantFiled: September 8, 1994Date of Patent: August 1, 1995Assignee: Agfa-Gevaert, N.V.Inventors: Yves Verburgh, Luc Leenders
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Patent number: 5437960Abstract: A process for laminating a photosensitive-layer which includes providing (A) a base having a laminating region and a non-laminating region, and (B) a support having thereon, in order, a photosensitive layer and a protective film, where part of the protective film corresponds to the laminating region and part of the protective film corresponds to the non-laminating region, removing the part of the protective film which corresponds to the laminating region from the photosensitive layer such that the photosensitive layer can be laminated to the base in the laminating region, feeding the base and the support having thereon the photosensitive layer from which protective film has been removed to a nip between a pair of heated pressure rollers, passing the base and photosensitive-layer-covered support forward through the rollers while the base and photosensitive-layer-covered support are being nipped and hot-pressed by the rollers, with the photosensitive layer being in contact with the laminating region of the baseType: GrantFiled: August 5, 1994Date of Patent: August 1, 1995Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroshi Nagate, Hiroya Endo, Ken-ichi Miyata
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Patent number: 5437959Abstract: An element comprising, in order: (a) a removable substrate; (b) a transparent, nonphotosensitive, polymeric layer having a thickness of less than about 0.002 cm and a gloss of 45-70; said polymeric layer consisting essentially of at least one thermoplastic polymer having an elongation at break of greater than 30%, a glass transition temperature of 35.degree.-70.degree. C.; and (c) an elastomeric layer and optionally an additional, different removable substrate (d) adjacent to the elastomeric layer, wherein the polymeric layer exhibits improved adhesion to the removable substrate (a) when removable substrate (d) is removed is described.Type: GrantFiled: January 25, 1994Date of Patent: August 1, 1995Assignee: E. I. Du Pont de Nemours and CompanyInventor: Anchi Hou
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Patent number: 5427890Abstract: A method for engraving and/or etching comprising the steps of: (a) a process for exposing, to light, a layer of a water-soluble resin composition of a laminated photosensitive film which comprises a supporting sheet, a image mask-protection layer peelablly adhered to the supporting sheet and a layer of a water-soluble resin composition having photocrosslinkability to thus cause crosslinking of the exposed area of the resin layer to thereby form a predetermined pattern on the resin layer; (b) a process for dissolving out the non-crosslinked portion of the layer of the water-soluble photo-sensitive resin composition by developing the layer with water to thus from an image-carrying mask which is constituted from the crosslinked area of the photo-sensitive resin composition remaining on the image mask-protection layer; (c) a process for adhering the photo-sensitive laminate film on which the images are formed to the surface of a material to be processed; (d) a process for peeling off the supporting sheet from theType: GrantFiled: September 3, 1993Date of Patent: June 27, 1995Assignee: Aicello Chemical Co., Ltd.Inventors: Tsutomu Suzuki, Ikuo Suzuki
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Patent number: 5422229Abstract: A photosensitive layered sheet for producing transferrable decorative foil designs comprising a solvent resistant, hydrophobic plastic film having superimposed thereon the following sequential layers of coatings:(a) a clear or colored water insoluble lacquer;(b) a clear water soluble polymer;(c) an organic solvent containing from 2-8% by weight of aluminum platelets having their largest dimension not greater than about 5000 microns and a thickness not greater than 1000 angstroms;(d) an ink extender;(e) an ink coat powder, and(f) a pre-sensitized photographic emulsion.A method of making these photosensitive layered sheets.Type: GrantFiled: February 18, 1994Date of Patent: June 6, 1995Assignee: Fabco Products, Inc.Inventors: Barry Typlin, John E. Murtaugh
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Patent number: 5415969Abstract: An image-receiving element for use in photographic diffusion transfer film units of the type Wherein the image-receiving element, which includes an image-receiving layer, is designed to be removed, or "peeled-apart", from a photosensitive element after exposure and development have been carried out. The image-receiving element includes an overcoat layer which overlies the image-receiving layer for reducing the time period for which the image-receiving element remains tacky after the element has been separated from the photosensitive element and for improving the handling and/or storage of the resulting photograph under high humidity conditions. The overcoat layer comprises colloidal silica particles and binder material.Type: GrantFiled: October 6, 1993Date of Patent: May 16, 1995Assignee: Polaroid CorporationInventor: Kenneth C. Waterman
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Patent number: 5409800Abstract: A photosensitive transfer material comprises a temporary substrate having provided thereon an alkali-soluble thermoplastic resin layer, an intermediate layer, and a photosensitive resin layer in this order, the interlaminar adhesion in the transfer material being the smallest at the interface between the thermoplastic resin layer and the temporary substrate. The photosensitive resin layer can be transferred to a permanent substrate without involving failure due to fine dust, air bubbles or unevenness of the permanent substrate. An image can be formed with the transfer material by adhering the transfer material to a permanent substrate at least under heat and, after stripping the temporary substrate, imagewise exposing the photosensitive resin layer to light, and processing the transferred layers to develop the photosensitive resin layer.Type: GrantFiled: March 25, 1994Date of Patent: April 25, 1995Assignee: Fuji Photo Film Co., Ltd.Inventors: Morimasa Sato, Masayuki Iwasaki, Fumiaki Shinozaki, Koji Inoue
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Patent number: 5405731Abstract: The use of a two layer photoimageable, aqueous processable, resist with a hydrophic binder in the outermost layer provides a permanent coating highly resistant to printed circuit processing chemicals. This resistance results in levels of adsorbed or absorbed ionic contamination less than 14 micrograms per square inch.Type: GrantFiled: December 22, 1992Date of Patent: April 11, 1995Assignee: E. I. Du Pont de Nemours and CompanyInventors: Karuppiah Chandrasekaran, Mark R. McKeever, James W. O'Neil
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Patent number: 5401616Abstract: A patterning method includes the steps of irradiating an excimer laser beam to a material layer so as to form a pattern on the material layer; and transferring onto a substrate, the material layer formed with the pattern; and irradiating the excimer laser beam to the material layer transferred onto the substrate so as to form a further pattern on the material layer.Type: GrantFiled: September 15, 1993Date of Patent: March 28, 1995Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Akira Isomi, Masato Hagino
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Patent number: 5395720Abstract: A dye transfer receptor sheet suitable, for thermal dye transfer imaging is described. The receptor sheet comprises a substrate having a receptor layer comprising a vinyl resin mixed or blended with a linear saturated thermoplastic polyester having aliphatic and aromatic groups.Type: GrantFiled: March 24, 1994Date of Patent: March 7, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventors: Susan K. Jongewaard, Robert A. Braun
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Patent number: 5393640Abstract: A photosensitive material either comprises a support, a peel layer, a barrier layer and a coloring material-containing photosensitive layer or a laminate of a coloring material layer and a photosensitive layer, superposed in order, or comprises a support having a releasing surface, an intermediate layer instead of both the peel layer and the barrier layer as mentioned above, a coloring material-containing photosensitive layer or a laminate of a coloring material layer and a photosensitive layer, superposed in order. The barrier layer or the intermediate layer comprises a polymer having a glass transition temperature not higher than 70.degree. C.Type: GrantFiled: May 26, 1994Date of Patent: February 28, 1995Assignee: Fuji Photo Film Co., Ltd.Inventors: Yuichi Wakata, Chiyomi Niitsu
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Patent number: 5391458Abstract: A method is provided for forming a high-resolution photoresist layer on a substrate, such as a metal-clad circuit board blank. A dry film is used which comprises a support sheet, a negative-acting, alkaline aqueous developable photoresist layer in direct contact with the support sheet, and a protective sheet. The protective sheet is removed and the photoresist layer is cut sheet laminated to the substrate. Then the support sheet is removed. The photoresist layer is baked until its exposed surface is non-tacky. Artwork is laid directly in contact with the non-tacky exposed surface, and the photoresist layer is exposed to actinic radiation through the art work. The photoresist layer is then developed in alkaline aqueous solution. The photoresist layer is highly resolved. Subsequent processing steps, such as plating or etching and stripping yield a printed circuit board having highly resolved lines and spaces.Type: GrantFiled: December 18, 1992Date of Patent: February 21, 1995Assignee: Morton International, Inc.Inventor: Charles T. Conrad