Color Correcting Patents (Class 430/359)
  • Patent number: 5948601
    Abstract: The invention relates to a photographic element comprising an emulsion layer comprising a cyan dye forming coupler, an emulsion layer comprising a magenta dye forming coupler, an emulsion layer comprising a yellow dye forming coupler wherein said magenta coupler comprises ##STR1## wherein R.sub.a and R.sub.b independently represent H or a substituent; X is hydrogen or a coupling-off group; and Z.sub.a, Z.sub.b, and Z.sub.c are independently a substituted methine group, .dbd.N--, .dbd.C--, or --NH--, provided that one of either the Z.sub.a --Z.sub.b bond or the Z.sub.b --Z.sub.c bond is a double bond and the other is a single bond, and when the Z.sub.4 --Z.sub.c bond is a carbon-carbon double bond, it may form part of an aromatic ring, and at least one of Z.sub.a, Z.sub.b, and Z.sub.c represents a methine group connected to the group R.sub.
    Type: Grant
    Filed: January 31, 1997
    Date of Patent: September 7, 1999
    Assignee: Eastman Kodak Company
    Inventor: John B. Rieger
  • Patent number: 5948575
    Abstract: In a process for the manufacture of a multi-color filter array element, for use in color flat panel displays, a multi-layer color photographic material is exposed to printing light, modulated by a master. Instead of varying the conditions of the printing light in order to achieve specified calorimetric characteristics, the filter density of the pixels on the master is established such that a correct color print is obtained under fixed standard printing conditions. A method is disclosed for computing and achieving the required spectral densities on the color print and on the master.
    Type: Grant
    Filed: April 18, 1996
    Date of Patent: September 7, 1999
    Assignee: Agfa-Gevaert
    Inventor: Raymond Roosen
  • Patent number: 5939246
    Abstract: A process of compositing two or more separate images comprising: (a) imagewise exposing a color negative photographic recording material to a subject in front of a uniformly colored screen background, wherein the photographic recording material comprises a support bearing red light, green light, and blue light sensitive color records, and at least one distributed red light absorbing compound in an amount such as to reduce the sensitivity of the red light sensitive color record by at least 40%, and the light sensitivities of the green light sensitive color record and the blue light sensitive color record are each reduced by less than 20% by the presence of any distributed light absorbing compounds, (b) forming a color negative image of the subject and screen background by developing the exposed photographic material with a color developing agent, (c) separating the subject image of the color negative from the screen background image, and (d) compositing the separated subject image with a second image.
    Type: Grant
    Filed: January 15, 1998
    Date of Patent: August 17, 1999
    Assignee: Eastman Kodak Company
    Inventors: John C. Brewer, Donald H. Hunger
  • Patent number: 5933578
    Abstract: A method and apparatus for determining a small number of parameters that spectrally characterize colorants by a small number of parameters and for using such colorant parameters to predict the spectral reflection or transmission characteristics of such colorants when laid on top of one another, either on an opaque, transparent or semitransparent carrier of a particular type, each colorant laid with a certain coverage percentage, for example, dot percentage in the case of offset printing, the colorant parameters of any colorant being substantially independent of the color of the substrate. The method involves making measurements of sets prints of varying coverage percentages of a colorant on a number of backgrounds, and solving the resulting set of equations for the colorant. Colorants that are defined by a recipe of basic colorants can be characterized from measurements on prints of the basic colorants.
    Type: Grant
    Filed: April 8, 1997
    Date of Patent: August 3, 1999
    Assignee: Barco Graphics, N.V.
    Inventors: Jean-Pierre Van de Capelle, Baldewin Meireson
  • Patent number: 5863711
    Abstract: In a process for the production of colour photographic prints, in which transparent colour photographic originals having a wide range of brightness are reproduced on a colour photographic paper and the colour photographic paper exposed in this manner is subjected to a process comprising at least the stages colour development and silver removal, satisfactory definition both in the highlights and in the shadows is achieved by locally modifying the sensitivity of the colour negative paper before processing as a function of the original and with the modification not being sharply defined.
    Type: Grant
    Filed: August 5, 1997
    Date of Patent: January 26, 1999
    Assignee: Agfa Gevaert AG
    Inventors: Wolfgang Zahn, Werner Ritter Von Stein
  • Patent number: 5840470
    Abstract: Silver bromide color negative films can be rapidly processed using shortened color development times and specific amounts of color developing agent and bromide ion. After development, and optionally desilvering or fixing, the developed film is scanned to form density representative digital signals for the color records. These signals are then digitally manipulated to correct both interimage interactions and gamma mismatches around the color records to produce a digital record that is capable of providing a display image having desired aim color and tone scale reproduction. That digital record can then be stored or used to provide corrected display images, such as color prints, using output display devices.
    Type: Grant
    Filed: July 7, 1997
    Date of Patent: November 24, 1998
    Assignee: Eastman Kodak Company
    Inventors: Anne E. Bohan, John M. Buchanan, Richard P. Szajewski
  • Patent number: 5834164
    Abstract: An image forming method is disclosed, comprising exposing a silver halide photographic light sensitive material comprising a support having thereon a silver halide emulsion layer containing a dye forming coupler and processing the exposed photographic material, wherein the coupler has, in its molecule, at least two sites capable of chelating with a metal ion to form a 5-membered or 6-membered chelate ring, thereby forming, together with a developing agent and the metal ion, a chelate dye.
    Type: Grant
    Filed: May 10, 1996
    Date of Patent: November 10, 1998
    Assignee: Konica Corporation
    Inventors: Noritaka Nakayama, Tatsuo Tanaka, Shigeto Hirabayashi
  • Patent number: 5830632
    Abstract: Photographic element are described comprising a support bearing a photographic silver halide emulsion layer having associated therewith a micro-precipitated dispersion of a high dye-yield coupler having the formula:COUP--(T).sub.m --L--DYEwhere COUP is the coupler moiety of the coupler capable of reacting at the coupling position with oxidized color developer to form a first dye, T is one or more timing groups with m=0, 1 or 2, L is a linking group selected from the group consisting of --OC(O)--, --OC(S)--, --SC(O)--, --SC(S)--, or --OC(.dbd.NSO.sub.2 R)--, where R is a substituted or unsubstituted alkyl or aryl group, and DYE is a second dye or precursor thereof comprising an electrically neutral chromophore. The invention also provides a photographic coupler dispersion, a photographic silver halide emulsion, and a process for forming an image in a photographic element in accordance with the invention.
    Type: Grant
    Filed: October 31, 1996
    Date of Patent: November 3, 1998
    Assignee: Eastman Kodak Company
    Inventors: Krishnan Chari, David Thomas Southby, David Hoke
  • Patent number: 5804356
    Abstract: Silver bromoiodide color negative films can be rapidly processed using shortened color development times and specific amounts of color developing agent and bromide ion. After development, and optionally desilvering or fixing, the developed film is scanned to form density representative digital signals for the color records. These signals are then digitally manipulated to correct both interimage interactions and gamma mismatches among the color records to produce a digital record that is capable of providing a display image having desired aim color and tone scale reproduction. That digital record can then be stored or used to provide corrected display images, such as color prints, using output display devices.
    Type: Grant
    Filed: October 15, 1996
    Date of Patent: September 8, 1998
    Assignee: Eastman Kodak Company
    Inventors: David Leroy Cole, Anne Elizabeth Bohan
  • Patent number: 5800970
    Abstract: There is disclosed a flaw-mending agent for photographs which comprises a liquid having a refractive index in the range of 1.5 to 1.8, and a viscosity in the range of 0.1 cP to 100 cP. There is also disclosed a method for mending flaws using the flaw-mending agent. The flaw-mending agent is useful for mending flaws on silver halide photographic light-sensitive materials, easy to handle, and high in flaw-mending effect.
    Type: Grant
    Filed: April 15, 1997
    Date of Patent: September 1, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yutaka Tamura
  • Patent number: 5796874
    Abstract: A method of restoring a color image comprised of one or more colorants and which image may have faded over time, which image is represented by an image signal. The method uses both a restoration model and provides a means which enable a user to readily interact with the restoration process to obtain a final restoration. In a second aspect, the restoration model is used in conjunction with a lightness distribution mapping to provide a high quality restoration. The restoration model is a function of a variable time, and is the inverse of a model representing the fade rate of at least one of the colorants as a function of at least a variable time (and preferably also as a function of the other colorants). An apparatus for performing the method is provided. A computer readable medium has computer readable code means which can execute the method in a suitable computer.
    Type: Grant
    Filed: April 30, 1996
    Date of Patent: August 18, 1998
    Assignee: Eastman Kodak Company
    Inventors: Geoffrey John Woolfe, Bruce Harold Pillman, Michael James Barry
  • Patent number: 5750320
    Abstract: Silver halide light sensitive photographic print elements are disclosed comprising a support bearing on one side thereof: a blue color sensitive record comprising at least one blue-sensitive silver halide emulsion yellow-image forming layer, a red color sensitive record comprising at least one red-sensitive silver halide emulsion cyan-image forming layer, and a green color sensitive record comprising at least one green-sensitive silver halide emulsion magenta-image forming layer; wherein at least one of the color records has a fixed best fit contrast less than or equal to 2.2, wherein the fixed best fit contrast for a color record is defined as the slope of a straight line connecting a point B and a point C on the characteristic curve of Status A density versus log Exposure for the color record, where points B and C are located by defining a point A on the characteristic curve at the log Exposure required to attain a density level of 1.
    Type: Grant
    Filed: February 16, 1996
    Date of Patent: May 12, 1998
    Assignee: Eastman Kodak Company
    Inventors: Mitchell Joseph Bogdanowicz, Charles Peter Hagmaier, Leslie Gutierrez
  • Patent number: 5747228
    Abstract: A color corrected display image can be rapidly provided by color developing an imagewise exposed, duplitized color photographic element, scanning the developed image to form digital signals, and digitally manipulating those signals to correct either interimage interactions and/or gamma mismatches among at least two color recording units. The color corrected image can be provided in any desired form. The duplitized elements have at least one light-sensitive silver halide imaging layer on each side of the support.
    Type: Grant
    Filed: April 7, 1997
    Date of Patent: May 5, 1998
    Assignee: Eastman Kodak Company
    Inventors: Anne E. Bohan, John M. Buchanan, Richard P. Szajewski
  • Patent number: 5723263
    Abstract: A multicolor negative photographic element comprises a support bearing a blue light-sensitive silver halide emulsion first layer and a green light-sensitized silver halide emulsion second layer wherein said second layer contains a dye sensitized to green light and wherein said first layer has associated therewith a hue correction coupler which upon coupling with oxidized developer produces a dye having a maximum absorbance in the range of 460 to 510 nm. so that the element has a D480/D440 density ratio which is greater than that exhibited by the element without the hue correction coupler. The invention also encompasses a blue sensitive silver halide emulsion layer associated with the hue correction coupler and a method of forming an image in the photographic element of the invention.
    Type: Grant
    Filed: November 12, 1996
    Date of Patent: March 3, 1998
    Assignee: Eastman Kodak Company
    Inventors: Stephen Paul Singer, Paul Barrett Merkel, Jeffrey Walter Schmoeger
  • Patent number: 5705327
    Abstract: Color negative photographic films having red, green and blue color sensitive records, wherein the ratio of the toe area contrast to the mid-scale contrast for each of the red, green and blue color records is less than or equal to 0.80, and either at least two color records having a toe-area contrast less than or equal to 0.42 or a mid-scale contrast less than or equal to 0.55, or the film having a speed rating of ISO 200 or greater. The mid-scale contrast for a color record is defined as the slope of a straight line connecting a point C and and a point D on the characteristic curve of Status M density versus log Exposure for the color record, where points C and D are located by defining a point A on the characteristic curve at a density level 0.1 above minimum density, a point B is located on the characteristic curve at an exposure value +1.0 Log Exposure beyond point A, and points C and D are located at exposure values -0.45 log Exposure and +0.45 log Exposure with respect to point B, respectively.
    Type: Grant
    Filed: September 16, 1996
    Date of Patent: January 6, 1998
    Assignee: Eastman Kodak Company
    Inventors: John Charles Brewer, John Tyler Keech, John Frank Sawyer
  • Patent number: 5698379
    Abstract: Silver chloride color negative films can be rapidly processed using shortened color development times and specific amounts of color developing agent and bromide ion. After development, and optionally desilvering or fixing, the developed film is scanned to form density representative digital signals for the color records. These signals are then digitally manipulated to correct both interimage interactions and gamma mismatches around the color records to produce a digital record that is capable of providing a display image having desired aim color and tone scale reproduction. That digital record can then be stored or used to provide corrected display images, such as color prints, using output display devices.
    Type: Grant
    Filed: October 15, 1996
    Date of Patent: December 16, 1997
    Assignee: Eastman Kodak Company
    Inventors: Anne E. Bohan, John M. Buchanan, Richard P. Szajewski
  • Patent number: 5679504
    Abstract: A color photographic silver halide material which contains as photosensitive layers on a support at least one red-sensitive silver halide emulsion layer containing at least one cyan coupler, at least one green-sensitive silver halide emulsion layer containing at least one magenta coupler and at least one blue-sensitive silver halide emulsion layer containing at least one yellow coupler, in which, above a photosensitive layer (seen from the support outwards), at least one further layer is provided which contains a colorless compound or combination of colorless compounds, which under processing conditions after exposure gives rise to a uniform, slight color density of a predetermined color and predetermined density over the entire surface, allows correction of the print densities without sensitivity being reduced.
    Type: Grant
    Filed: December 6, 1995
    Date of Patent: October 21, 1997
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Ralf Buscher, Peter Bell, Johannes Willsau, Hans-Ulrich Borst
  • Patent number: 5674665
    Abstract: A color negative photographic film wherein on the curve of density versus log E for each color sensitive record: (1) a straight line, which connects the point at density Dmin+0.1 and the point at 1.5log E above the exposure required for density Dmin+0.2, has a mathematical slope .ltoreq. 0.50; and (2) the difference in log E is .gtoreq.1.7 between the point 0.9log E above the exposure required for density Dmin+0.2 and the point where the density difference is 0.1 between the curve and the straight line which results from a linear regression of the three density points at exposures 0.3log E, 0.9log E, and 1.5log E above the exposure required for the density Dmin+0.2; and (3) the difference in log E is .gtoreq.1.20 between the exposure needed for density Dmin+0.1 and the point that corresponds to the exposure, in lux-seconds, of 9.2/(Film Speed). The exposure of the foregoing gray card is a typical normal exposure based on the film speed rating (i.e. the film is not overexposed or underexposed).
    Type: Grant
    Filed: November 17, 1995
    Date of Patent: October 7, 1997
    Assignee: Eastman Kodak Company
    Inventors: John Frank Sawyer, Michael Paul Keyes, John Charles Brewer, John Tyler Keech, Elizabeth Laura Kelly
  • Patent number: 5667944
    Abstract: A method for producing photographic images from a photographic film strip, of the type that uses density values of the photographic film strip to determine the density values of the produced photographic images, the improvement comprising the steps of:a) forming at least two reference patches of differing exposure conditions onto an otherwise unexposed portion of the photographic film strip prior to photographic processing, each reference patch falling within the total scale of the photographic film strip;b) photographically processing the photographic film strip to form densities corresponding to the photographic images and said reference patches;c) scanning said processed photographic film strip to form density representative digital signals for the photographic images and said reference patches;d) obtaining standard film density values representative of the photographic film strip;e) calculating gamma correction values from said density representative digital signals corresponding to said reference patches
    Type: Grant
    Filed: April 22, 1996
    Date of Patent: September 16, 1997
    Assignee: Eastman Kodak Company
    Inventors: Richard Carroll Reem, James Edward Sutton
  • Patent number: 5658718
    Abstract: Multilayer silver halide color photographic element comprising a support having thereon at least a blue sensitive silver halide emulsion layer containing a yellow dye-forming coupler, at least a green-sensitive silver halide emulsion layer containing a magenta dye-forming coupler, and at least a red-sensitive silver halide emulsion layer containing a cyan dye-forming coupler, said red-sensitive layer containing a non-diffusible, cyan dye-forming magenta masking coupler.
    Type: Grant
    Filed: December 22, 1995
    Date of Patent: August 19, 1997
    Assignee: Imation Corp
    Inventors: Anna Maria Canuti, Roberto Sardelli, Massimo Bertoldi
  • Patent number: 5658717
    Abstract: Multilayer silver halide color photographic element comprising a support having thereon at least a blue sensitive silver halide emulsion layer containing a yellow dye-forming coupler, at least a green-sensitive silver halide emulsion layer containing a magenta dye-forming coupler, and at least a red-sensitive silver halide emulsion layer containing a cyan dye-forming coupler, said red-sensitive layer or a gelatin interlayer adjacent said red-sensitive layer containing a non-diffusible, non-coupling magenta colored azo dye.
    Type: Grant
    Filed: December 22, 1995
    Date of Patent: August 19, 1997
    Assignee: Imation Corp.
    Inventors: Anna Maria Canuti, Roberto Sardelli, Massimo Bertoldi
  • Patent number: 5654123
    Abstract: Multilayer color photographic elements are described which contain a release compound that during photographic processing provides an imagewise distribution of a nucleophile which can react with a uniform distribution of a sulfinate blocked dye moiety contained in the element to release a solubilized unblocked dye.
    Type: Grant
    Filed: June 28, 1996
    Date of Patent: August 5, 1997
    Assignee: Eastman Kodak Company
    Inventors: Xiqiang Yang, Zbyslaw R. Owczarczyk, Daniel L. Kapp
  • Patent number: 5641613
    Abstract: The invention provides a photographic element comprising a support bearing a light-sensitive photographic silver halide layer containing (1) a bicyclic azole coupler (2) an azopyrazolone masking coupler and (3) a low impact development inhibitor releasing (LIDIR) coupler having at least one hydrogen atom at the coupling site and which does not substantially reduce contrast in the layer in which it is coated.
    Type: Grant
    Filed: January 25, 1996
    Date of Patent: June 24, 1997
    Assignee: Eastman Kodak Company
    Inventors: Jane Sarah Boff, Stephen Paul Singer
  • Patent number: 5635340
    Abstract: A method of image formation using mask for exposure to form an image on photographic paper is disclosed. The mask is composed of transferred images of the dyes of yellow, cyan and magenta. The spectral absorption peak wavelength of the dye is set in a range close to the wavelength at the maximum value of each of the regular, orthochromatic and panchromatic spectral sensitivities of the photographic paper to be used. In the spectral absorption of cyan of the mask for exposure, the absorbance of the wavelength at the maximum value of each of the regular and orthochromatic spectral sensitivities of the photographic paper to be used, is set at a value not more than a predetermined value. In the spectral absorption of yellow of the mask for exposure, the absorbance of the wavelength at the maximal value of each of the orthochromatic and panchromatic spectral sensitivities of the photographic paper to be used, is set at a value not more than a predetermined value.
    Type: Grant
    Filed: August 1, 1995
    Date of Patent: June 3, 1997
    Assignee: Konica Corporation
    Inventors: Shigeru Mano, Ichiroh Maeda, Ken Okauchi
  • Patent number: 5622818
    Abstract: A multilayer silver halide color photographic element comprising a support bearing a light-sensitive silver halide emulsion layer and a non-diffusible yellow-colored magenta dye-forming masking coupler wherein the masking coupler is a 2'-hydroxy-5'-substituted-4-phenylazo-5-pyrazolone. The masking coupler has good coupling activity and desirable hues, and can be obtained in good yields by simple syntheses.
    Type: Grant
    Filed: November 29, 1995
    Date of Patent: April 22, 1997
    Assignee: Eastman Kodak Company
    Inventors: Daniel L. Kapp, Janet N. Younathan, Robert J. Ross, James P. Merrill
  • Patent number: 5576128
    Abstract: A color negative photographic film with at least one color record thereof having a mid-scale contrast less than or equal to 0.45, wherein the mid-scale contrast for the color record is defined as the slope of a straight line connecting a point C and and a point D on the characteristic curve of density versus log Exposure for the color record, where points C and D are located by defining a point A on the characteristic curve at a density level 0.1 above minimum density, a point B is located on the characteristic curve at an exposure value +1.0 Log Exposure beyond point A, and points C and D are located at exposure values -0.45 log Exposure and +0.45 log Exposure with respect to point B, respectively. Use of such a color negative film is particularly advantageous in making telecine transfers.
    Type: Grant
    Filed: December 5, 1994
    Date of Patent: November 19, 1996
    Assignee: Eastman Kodak Company
    Inventors: John T. Keech, John C. Brewer
  • Patent number: 5576159
    Abstract: The invention relates to a photographic element comprising at least one emulsion layer comprising coupler and silver halide grains, adjacent to said at least one emulsion layer a color enhancer layer comprising the same coupler as in said at least one coupler layer and adjacent to said color enhancer layer a Dox scavenging layer.
    Type: Grant
    Filed: February 17, 1995
    Date of Patent: November 19, 1996
    Assignee: Eastman Kodak Company
    Inventors: Erika M. Sato, Paul T. Hahm, Walter H. Isaac
  • Patent number: 5576157
    Abstract: A color photographic negative element which has a transparent base and a blue sensitive silver halide emulsion layer. The foregoing blue sensitive layer meets each of the following spectral sensitivity requirements:S.sub.max (426-444 nm) .gtoreq.65%S.sub.max(400-500 nm)IS.sub.(425-450) .gtoreq.25%(IS.sub.(400-500))in which S.sub.max(426-444 nm) is the maximum sensitivity between 426 to 444 nm, S.sub.max(400-500 nm) is the maximum sensitivity between 400-500 nm, IS.sub.(425-450) is the integrated spectral sensitivity of the blue sensitive layer from 425 to 450 nm, and IS.sub.(400-500) is the integrated spectral sensitivity of the blue sensitive layer in the region 400-500 nm. A method for printing a negative obtained from exposing and processing an element of the foregoing type, on automatic printers which automatically compensate for color bias, is also provided.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: November 19, 1996
    Assignee: Eastman Kodak Company
    Inventors: Jon N. Eikenberry, John D. Buhr, Jeffrey L. Hall
  • Patent number: 5576158
    Abstract: A color reversal photographic element comprises a support bearing a red-sensitive, cyan dye-forming unit, a green-sensitive, magenta dye-forming unit, and a blue-sensitive, yellow dye-forming unit, each unit comprising a photosensitive silver halide layer and an image-dye forming coupler; the element contains an interimage effect-controlling means which is characterized as having the capability of simultaneously forming a red image of high relative chroma and a yellow-red tint image of substantially lower relative chroma when the element is exposed to a red color standard object having CIELab values for D.sub.55 reference white a*=30.46, b*=19.16, C*=35.98, L*=40.12 and a yellow-red tint color standard object having CIELab values for D.sub.55 reference white a*=17.26, b*=18.01, C*=24.95, L*=66.98; the resulting images have a red reproduction coefficient equal to or greater than 0.88 and a ratio of red reproduction coefficient to yellow-red tint reproduction coefficient equal to or greater than 1.15.
    Type: Grant
    Filed: September 26, 1994
    Date of Patent: November 19, 1996
    Assignee: Eastman Kodak Company
    Inventors: Frederick E. Ford, Arlyce T. Bowne, Carl Kotlarchik, Jr.
  • Patent number: 5571663
    Abstract: A silver halide light-sensitive material comprising a support having thereon at least four silver halide emulsion layers having different color sensitivity, wherein three layers of the silver halide emulsion layers each contains a specific coupler and the other silver halide emulsion layer contains coupler(s) capable of correcting colors so as to provide a substantially black color having a transmission density of 2.5 or more when all couplers on the support are reacted. A color filter comprising blue, green, red and black parts prepared by subjecting the above-described silver halide light-sensitive material to pattern exposure, color development, bleach-fixing and water washing.
    Type: Grant
    Filed: July 5, 1995
    Date of Patent: November 5, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Hiroyuki Hirai
  • Patent number: 5563024
    Abstract: An improved image display material comprising a light sensitive tabular grain silver chloride emulsion spectrally sensitized to a peak wavelength of less than about 475 nm, and a method of use comprising the step of optically printing a color image onto the improved color photographic display material is provided. The material and method enable reduced printing times, improved color reproduction and lowered image granularity.
    Type: Grant
    Filed: May 8, 1995
    Date of Patent: October 8, 1996
    Assignee: Eastman Kodak Company
    Inventors: Anne E. Bohan, Jerzy A. Budz, Pamela M. Ferguson, Alberto M. Martinez, James P. Merrill, Scott F. O'Dell, Richard P. Szajewski
  • Patent number: 5563026
    Abstract: The invention provides a multicolor negative photographic element comprising a support bearing at least two green light sensitive silver halide emulsion layers of differing light sensitivity, the least and only the least sensitive layer containing a 1-phenyl-3-acylamino-4-nitrogenheterocycle-pyrazolin-5-one dye forming hue correction coupler which reacts with oxidized developer during development to form a dye having a D580/D550 ratio greater than that exhibited by the element absent the hue correction coupler. The invention also provides an imaging process.
    Type: Grant
    Filed: April 28, 1995
    Date of Patent: October 8, 1996
    Assignee: Eastman Kodak Company
    Inventor: Stephen P. Singer
  • Patent number: 5561012
    Abstract: Color negative photographic films having red, green and blue color sensitive records, wherein the ratio of the toe area contrast to the mid-scale contrast for each of the red, green and blue color records is less than or equal to 0.80, and either at least two color records having a toe-area contrast less than or equal to 0.42 or a mid-scale contrast less than or equal to 0.55, or the film having a speed rating of ISO 200 or greater. The mid-scale contrast for a color record is defined as the slope of a straight line connecting a point C and and a point D on the characteristic curve of Status M density versus log Exposure for the color record, where points C and D are located by defining a point A on the characteristic curve at a density level 0.1 above minimum density, a point B is located on the characteristic curve at an exposure value +1.0 Log Exposure beyond point A, and points C and D are located at exposure values -0.45 log Exposure and +0.45 log Exposure with respect to point B, respectively.
    Type: Grant
    Filed: December 5, 1994
    Date of Patent: October 1, 1996
    Assignee: Eastman Kodak Company
    Inventors: John C. Brewer, John T. Keech, John F. Sawyer
  • Patent number: 5534399
    Abstract: A silver halide color photographic photosensitive material is disclosed, comprising a support having thereon at least one hydrophilic colloid layer, at least one layer of which is a photosensitive silver halide emulsion layer. At least 50% of the total projected area of the silver halide grains constituting the at least one silver halide emulsion layer is accounted for by tabular grains having an average aspect ratio of at least 2:1, and a yellow colored cyan coupler is contained in at least one hydrophilic colloid layer.
    Type: Grant
    Filed: October 25, 1994
    Date of Patent: July 9, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Keiji Mihayashi
  • Patent number: 5500316
    Abstract: The process for forming a video image with a telecine transfer device typically comprises (a) exposing a color negative photographic film comprising red, green and blue color sensitive records which generate image dyes upon exposure and processing of the film, (b) processing the exposed film to form a developed image, and (c) converting the developed image into video signals representative of the developed image with a telecine transfer device, wherein the peak spectral absorbance wavelength of the image dyes generated by the red color record of the film is substantially more offset from the red peak spectral response of the telecine transfer device than the peak spectral absorbance wavelength of the image dyes generated by the green color record of the film is offset from the green peak spectral response of the the telecine transfer device.
    Type: Grant
    Filed: December 5, 1994
    Date of Patent: March 19, 1996
    Assignee: Eastman Kodak Company
    Inventors: Mitchell J. Bogdanowicz, Christopher L. DuMont
  • Patent number: 5492799
    Abstract: The invention provides a photographic element comprising a support bearing a light-sensitive photographic silver halide layer having associated therewith a masking coupler comprising:(1) a parent group containing a -1-phenyl-3-anilinopyrazolin-5-one having electron-withdrawing substituents on the phenyl and anilino rings of a type and number sufficient to provide a combined Hammett sigma(para) value for such substituents of at least 1.
    Type: Grant
    Filed: June 22, 1994
    Date of Patent: February 20, 1996
    Assignee: Eastman Kodak Company
    Inventors: Daniel L. Kapp, Robert J. Ross, Stephen P. Singer, Bernard A. Clark
  • Patent number: 5466568
    Abstract: A photographic element and imaging process used therewith provides reduced fogging where the element comprises a light sensitive silver halide layer containing (1) an azopyrazolone masking coupler and (2) a ballasted aromatic nitro compound having a reduction peak potential which is more positive than -1.3 V vs. the Standard Calomel Electrode.
    Type: Grant
    Filed: September 30, 1993
    Date of Patent: November 14, 1995
    Assignee: Eastman Kodak Company
    Inventors: Daniel L. Kapp, Robert J. Ross, Janet N. Younathan, Stephen P. Singer
  • Patent number: 5460928
    Abstract: A color photographic element has a blue sensitive tabular grain silver halide emulsion layer the halide content of which is less than 80% chloride and which has a tabularity of at least 8. The foregoing emulsion is sensitized such that the wavelength of maximum sensitivity of the emulsion between 400-500 nm (".lambda..sub.Bmax "), the sensitivity at 485 nm ("S.sub.485 "), the sensitivity at 410 nm ("S.sub.410 "), and the sensitivity at .lambda..sub.Bmax (".lambda..sub.Bmax "), are defined by:430 nm.gtoreq..lambda..sub.Bmax .gtoreq.440 nm or 450 nm.gtoreq..lambda..sub.Bmax .gtoreq.480 nmandS.sub.485 .gtoreq.50% (S.sub.Bmax)S.sub.410 .gtoreq.60% (S.sub.Bmax)and the maximum sensitivity of the emulsion between 430-440 nm ("S.sub.(430-440)max "), and the maximum sensitivity between 450-480 nm ("S.sub.(450-480)max "), have the following relationship:90% (S.sub.(450-480)max).gtoreq.S.sub.(430-440)max .gtoreq.110%(S.sub.(450-480)max).
    Type: Grant
    Filed: April 15, 1994
    Date of Patent: October 24, 1995
    Assignee: Eastman Kodak Company
    Inventors: Mamie Kam-Ng, Drake M. Michno, John D. Buhr
  • Patent number: 5459022
    Abstract: A silver halide color photographic material comprises a support having thereon at least one silver halide emulsion layer, a yellow-colored cyan coupler, and a compound capable of releasing a bleaching accelerator or a precursor thereof on reaction with an oxidation product of an aromatic primary amine developing agent.
    Type: Grant
    Filed: November 12, 1993
    Date of Patent: October 17, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshio Ishii, Yoshihiro Fujita, Keiji Mihayashi
  • Patent number: 5457004
    Abstract: The invention provides a photographic element comprising a substrate bearing a photographic silver halide emulsion layer having associated therewith a high dye-yield coupler having the formula: ##STR1## wherein: COUP is a photographic coupler residue capable of coupling with oxidized color developer to form a first dye;T is a timing group;m is an integer from 0 to 2;L is a linking group selected from the group consisting of --OC(.dbd.O)--, --OC(.dbd.S)--, --SC(.dbd.O)--, --SC(.dbd.S)--, and --OC(.dbd.NSO.sub.2 R) where R is substituted or unsubstituted alkyl or aryl; andDYE is a releasable second dye or dye precursor having a particular formula including a methine dye chromophore.
    Type: Grant
    Filed: May 27, 1994
    Date of Patent: October 10, 1995
    Assignee: Eastman Kodak Company
    Inventors: Jared B. Mooberry, James J. Seifert, David Hoke, Zheng Z. Wu, David T. Southby, Frank D. Coms
  • Patent number: 5457007
    Abstract: The image forming process of the present invention includes subjecting a photosensitive material having at least one dye-forming layer for each of the three primary colors on a support to scanning exposure using light sources modulated in accordance with the image data, thereby reproducing a full color image of quality in which delicate shades in a high density color developed portion of high purity are reproduced stably.
    Type: Grant
    Filed: July 13, 1994
    Date of Patent: October 10, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Masahiro Asami
  • Patent number: 5455150
    Abstract: A silver halide photographic negative has a red sensitive layer containing a coupler which reacts with oxidized color developer to form a cyan dye, a blue sensitive layer containing a coupler which reacts with oxidized color developer to form a yellow dye, and a green sensitive layer containing a coupler which reacts with oxidized color developer to form a magenta dye. The coupler in the green sensitive layer produces a magenta dye which has relatively low density in the 560-590 nm range as compared with magenta dyes produced by pyrazolotriazole type couplers or 1-phenyl-3-acylamino-5-pyrazolone couplers. The element additionally has an inert dye present, preferably positioned below the green sensitive layer containing the foregoing coupler. The inert dye has a peak absorption between 560-590 nm so that the negative has a ratio of density at 580 nm to density at 550 nm, both as measured at neutral midscale exposure, which is greater than exhibited by the element absent the inert dye.
    Type: Grant
    Filed: June 10, 1993
    Date of Patent: October 3, 1995
    Assignee: Eastman Kodak Company
    Inventors: Jared B. Mooberry, Paul B. Merkel, Stephen P. Singer
  • Patent number: 5451493
    Abstract: The present invention provides a photographic element comprising a support bearing a blue-light sensitive silver halide emulsion layer containing an acylacetanilide yellow image dye-forming coupler having formula I or II: ##STR1## wherein: R.sub.a is a substituted or unsubstituted alkyl groups, alkoxy group or aryloxy group;R.sub.b is a substituted or unsubstituted alkyl or aryl group;R.sub.c is hydrogen or a substituted or unsubstituted alkyl group;R.sub.1 is a substituent;n is an integer from 0 to 2;R.sub.2 is selected from the group consisting of halogen, trifluoromethyl, and substituted or unsubstituted alkoxy and aryloxy;R.sub.3 is substituted or unsubstituted alkyl;R.sub.4 is hydrogen, halogen, alkoxy carbonyl (--CO.sub.2 R), carbamoyl (--CONRR'), carbonamido (--NRCOR'), sulfonamido (--NRSO.sub.2 R') or trifluoromethyl; andX is hydrogen or a coupling-off group;and wherein the blue-light sensitive silver halide emulsion layer has associated therewith a development inhibitor releasing coupler.
    Type: Grant
    Filed: March 17, 1994
    Date of Patent: September 19, 1995
    Assignee: Eastman Kodak Company
    Inventors: Paul B. Merkel, Jerrold N. Poslusny, James P. Merrill, Bernard A. Clark, Paul L. R. Stanley, Hugh M. Williamson
  • Patent number: 5451492
    Abstract: The present invention provides a photographic element comprising a support bearing a blue light sensitive silver halide emulsion layer containing an acylacetanilide yellow image dye-forming coupler having formula I: ##STR1## wherein: R.sub.a is a substituted or unsubstituted alkyl, alkoxy, or aryloxy group;R.sub.b is a substituted or unsubstituted alkyl or aryl group;R.sub.c is hydrogen or a substituted or unsubstituted alkyl group;R.sub.1 is a substituent;R.sub.2 is selected from the group consisting of halogen, trifluoromethyl, and substituted or unsubstituted alkoxy and aryloxy;each R.sub.3 is bonded at the 4- or 5- position relative to the anilino nitrogen and is independently a substituent selected from the group consisting of halogen, alkoxycarbonyl (--CO.sub.2 R), carbamoyl (--CONRR'), sulfonate (--OSO.sub.2 R), sulfamoyl (--SO.sub.2 NRR'), sulfonyl (--SO.sub.2 R), trifluoromethyl, cyano, and sulfonamido (--NRSO.sub.2 R'), in which each R and R' is independently hydrogen or a substituent;q is 1 or 2;R.
    Type: Grant
    Filed: March 17, 1994
    Date of Patent: September 19, 1995
    Assignee: Eastman Kodak Company
    Inventors: Paul B. Merkel, Jerrold N. Poslusny, James P. Merrill, Bernard A. Clark, Paul L. R. Stanley
  • Patent number: 5447819
    Abstract: The invention provides a photographic element comprising a support bearing a photographic silver halide emulsion layer having associated therewith a high dye-yield coupler having the formula:COUP--(T).sub.m --L--DYEwhere COUP is the parent group of the coupler capable of reacting at the coupling position with oxidized color developer to form a first dye, T is one or more timing groups with m=1 or 2, L is a linking group selected from the group consisting of --OC(O)--, --OC(S)--, --SC(O)--, --SC(S)--, or --OC(.dbd.N SO.sub.2 R)--, where R is substituted or unsubstituted alkyl or aryl, and DYE is a second dye or precursor thereof, wherein there is present at least one T group that contains a substituent having the formula:--(LINK).sub.p --A--B--(C--D).sub.nwherein:LINK is an alkylene group capable of linking the above group to the group T, where p=0 or 1;A is a member selected from the group consisting of --NHCO--, --N(R')C(O)N(R--)--, --CONH--, --NR'SO.sub.2 --, --SO.sub.2 NR'--, and --OPO.sub.
    Type: Grant
    Filed: May 27, 1994
    Date of Patent: September 5, 1995
    Assignee: Eastman Kodak Company
    Inventors: Jared B. Mooberry, James J. Seifert, David Hoke, Zheng Z. Wu, David T. Southby, Frank D. Coms
  • Patent number: 5447831
    Abstract: The invention provides a silver halide color negative photographic element comprising a red sensitive silver halide emulsion layer containing a coupler which reacts with oxidized color developer to form a cyan dye, a blue sensitive silver halide emulsion layer containing a coupler which reacts with oxidized color developer to form a yellow dye, and a green sensitive silver halide emulsion layer containing a coupler which upon reaction with oxidized color developer forms a magenta image dye, the element additionally comprising a hue correction coupler associated with a green sensitive layer which coupler reacts with oxidized developer to form a magenta dye having a peak absorption between 565-600 nm so that the element has a D580/D550 ratio which is greater than that exhibited by the element absent the hue correction coupler. The invention also provides a process for forming an image in the element described.
    Type: Grant
    Filed: October 19, 1993
    Date of Patent: September 5, 1995
    Assignee: Eastman Kodak Company
    Inventors: Stephen P. Singer, Jared B. Mooberry
  • Patent number: 5447811
    Abstract: A system and method of image reproduction in color with preferential tone mapping are provided in which the method includes the steps of capturing original scene parameters and creating a visual reproduction of the scene, the method additionally comprising:performing a transformation of said captured scene parameters, said transformation being such that, taken in conjunction with untransformed characteristics of the capturing and creating steps, it results in a reproduced tone mapping having instantaneous gamma values of viewed reproduction density relative to density of the original scene which are greater than a minimum value of A and less than A plus 0.35 times scene exposure density over a scene exposure density range of from 0.60 to 1.45 as measured relative to a zero density, 100% diffuse reflector in the original scene, the instantaneous gamma values within scene exposure density range further lying entirely within a range of values subtended by an angle of 14.degree.
    Type: Grant
    Filed: March 23, 1994
    Date of Patent: September 5, 1995
    Assignee: Eastman Kodak Company
    Inventors: John D. Buhr, Harry D. Franchino
  • Patent number: 5445928
    Abstract: A color photographic material comprising at least one cyan-coupling silver halide emulsion layer containing a red sensitizer, at least one magenta-coupling silver halide emulsion layer containing a green sensitizer and at least one yellow-coupling silver halide emulsion layer containing a blue sensitizer on a support, in which a silver halide emulsion is provided in a coupler-free layer sensitized with another spectral sensitizer (a gap sensitizer) of which the sensitization maximum lies between the sensitization maxima of the red- and green-sensitive layers or the green- and blue-sensitive layers, is distinguished by an extended gradation range towards the maximum densities and by distinctly improved detail reproduction in the region of high densities.
    Type: Grant
    Filed: January 6, 1994
    Date of Patent: August 29, 1995
    Assignee: Agfa-Gevaert AG
    Inventors: Arno Schmuck, Edgar Draber, Michael Missfeldt
  • Patent number: 5437969
    Abstract: A color photographic silver halide material having at least one silver halide emulsion layer which is cyan coupling and contains a red sensitizer, at least one magenta coupling silver halide emulsion layer containing a green sensitizer and at least one yellow coupling silver halide emulsion layer containing a blue sensitizer on a support, in which the at least one blue sensitive halide emulsion layer contains a further spectral sensitizer (gap sensitizer) whose sensitization maximum lies between the sensitization maxima of the red and green sensitive silver halide emulsion layer and/or the at least one red sensitive silver halide emulsion layer contains an additional spectral sensitizer (gap sensitizer) whose sensitization maximum lies between the sensitization maxima of the green sensitive and the blue sensitive silver halide emulsion layer is distinguished by an increased range of gradations in the region of the maximum densities and a markedly improved detail reproduction in the region of high densities.
    Type: Grant
    Filed: January 6, 1994
    Date of Patent: August 1, 1995
    Assignee: Agfa-Gevaert AG
    Inventors: Arno Schmuck, Edgar Draber, Michael Missfeldt
  • Patent number: 5427901
    Abstract: A heat-developable color light-sensitive material comprising a support having thereon at least three silver halide emulsion layers each sensitive to a different spectral wavelength region, one silver halide emulsion layer or a light-insensitive layer adjacent thereto containing a yellow dye-providing compound, a second silver halide emulsion layer or a light-insensitive layer adjacent thereto containing a magenta dye-providing compound and a third silver halide emulsion layer or a light-insensitive layer adjacent thereto containing a cyan dye-providing compound; at least one of said silver halide emulsion layers having a maximum spectral sensitivity at a wavelength of at least 700 nm and a spectral sensitivity at a wavelength 20 nm longer than said maximum spectral sensitivity wavelength of at most 1/10 of said maximum spectral sensitivity.
    Type: Grant
    Filed: January 3, 1994
    Date of Patent: June 27, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Arakatsu, Yoshio Inagaki, Hiroyuki Ozaki, Takanori Hioki