Using Identified Radiation Sensitive Composition In The Formation Of Color Image Patents (Class 430/374)
  • Publication number: 20140127429
    Abstract: A method of forming a coloured substrate, comprising applying to or incorporating within the substrate a diacetylene compound, and exposing the substrate to (i) a first, activating stimulus that converts the diacetylene compound from an unreactive to a reactive form, and (ii) a second stimulus that causes the reactive form of the diacetylene compound to polymerize and form the coloured substrate, wherein the diacetylene compound reverts to its unreactive form on removal of the activating stimulus and is of formula I: Y—C?C—C?C—(CH2)n-T-Q-Z (I) wherein: n=an odd integer; T=CO, CS or a bond; Q=NH, S, O, OCONH, NHCONH, NH—CHE-CONH, NHCOO or NHCSNH wherein E is H or a C1-20 alkyl group; Z=H or a hydrocarbon group containing 1 to 20 carbon atoms; Y=H or any group comprising at least one carbon atom.
    Type: Application
    Filed: February 24, 2012
    Publication date: May 8, 2014
    Applicant: DATALASE LTD.
    Inventors: Anthony N. Jarvis, Christopher A. Wyres, Benjamin Mulchin, Adam O'Rourke
  • Patent number: 8637228
    Abstract: A color photographic element has a reflective support and a blue light sensitive color record, a green light sensitive color record, and a red light sensitive color record and can be used to provide color photographic prints. The element also has a non-light sensitive layer over the red light sensitive color record. This non-light sensitive layer has (1) a hydrophilic colloid in an amount of at least 200 mg/m2 to and including 2,000 mg/m2, (2) matte particles, and (3) an acrylate latex polymer having latex particles having an average size of less than 1 ?m and a glass transition temperature of at least 70° C. The dry weight ratio of the acrylate latex polymer to the hydrophilic colloid is at least 0.8:1 and the dry weight ratio of the acrylate latex polymer to the total matte particles is at least 15:1.
    Type: Grant
    Filed: November 8, 2012
    Date of Patent: January 28, 2014
    Assignee: Kodak Alaris Inc.
    Inventors: Jess B. Hendricks, III, Paul L. Zengerle, Andrew D. Church, Darrell B. Austin
  • Patent number: 8409792
    Abstract: Silver halide photographic elements that are color intermediate motion picture films have at least one green sensitive silver halide emulsion that includes a green sensitizing dye that is a cyanine dye having two oxazole groups in the molecule, and another green sensitizing dye having either two imidazole groups in the molecule or one oxazole group and one thiazole group in the molecule. The molar ratio of the first green sensitizing dye to the second green sensitizing dye is from about 4:1 to about 0.3:1. The magenta dye image forming unit has at least one green sensitive silver halide emulsion layer that comprises predominantly cubic silver iodobromide grains having at least 90 mol % bromide and at least 1 mol % iodide, which grains have an average equivalent spherical diameter (ESD) of less than 0.25 ?m.
    Type: Grant
    Filed: February 14, 2011
    Date of Patent: April 2, 2013
    Assignee: East Kodak Company
    Inventor: Jeffrey C. Hansen
  • Patent number: 8357485
    Abstract: A multi-color photographic silver halide element has a total gelatin level on the imaging side of the support is less than 9000 mg/m2, and bulk gelatin-to-junk weight ratio for all of the light sensitive layers on the imaging side of the support is greater than 1.5. This weight ratio is defined by: Bulk gelatin-to-junk ratio=[(Bgel×Bgel/junk)+(Rgel×Rgel/junk)+(Ggel+Ggel/junk)]÷(Bgel+Rgel+Ggel) wherein Bgel is the total gelatin level for blue light sensitive layers, Bgel/junk is the gelatin-to-junk ratio for blue light sensitive layers, Rgel is the total gelatin level for red light sensitive layers, Rgel/junk is the gelatin-to-junk ratio for red light sensitive layers, Ggel is the total gelatin level for green light sensitive layers, and Ggel/junk is the gelatin-to-junk ratio for green light sensitive layers.
    Type: Grant
    Filed: October 25, 2010
    Date of Patent: January 22, 2013
    Assignee: Eastman Kodak Company
    Inventors: Christopher J. Haller, Daniel R. May, Paul L. Zengerle
  • Patent number: 8133665
    Abstract: Disclosed is a silver halide photographic photosensitive material which includes a support and at least one silver halide photosensitive layer on the support, wherein the average equivalent sphere diameter of the silver halide of the silver halide photosensitive layer is 0.30 ?m or less, the silver halide photosensitive layer includes four or more kinds of silver halide grains having mutually different average equivalent sphere diameters, and the thickness between a surface of the support at a side at which the silver halide photosensitive layer is provided and a surface of the silver halide photosensitive layer at a side opposite to the support is 10 ?m or less.
    Type: Grant
    Filed: September 18, 2009
    Date of Patent: March 13, 2012
    Assignee: FUJIFILM Corporation
    Inventors: Yoichi Hosoya, Naoharu Kiyoto, Junichiro Hosokawa, Masaaki Miki, Kouichi Yokota, Ryoji Nishimura
  • Publication number: 20120021363
    Abstract: A method of forming an image on a substrate by irradiation thereof, wherein the substrate comprises therein or thereon a co-crystal of a polymerisable unsaturated monomer and a spacing component, wherein the co-crystal is capable of undergoing a radiation-activated colour change reaction. A co-crystal of a diacetylene and a spacing component, whereby the reactivity of the diacetylene is reduced is also provided, together with a surface coating composition comprising this co-crystal.
    Type: Application
    Filed: February 4, 2010
    Publication date: January 26, 2012
    Inventor: Anthony Jarvis
  • Patent number: 7998665
    Abstract: Silver halide photographic elements that are color intermediate motion picture films have at least one green sensitive silver halide emulsion that includes a green sensitizing dye that is a cyanine dye having two oxazole groups in the molecule, and another green sensitizing dye having either two imidazole groups in the molecule or one oxazole group and one thiazole group in the molecule. The molar ratio of the first green sensitizing dye to the second green sensitizing dye is from about 4:1 to about 0.3:1. The magenta dye image forming unit has at least one green sensitive silver halide emulsion layer that comprises predominantly cubic silver iodobromide grains having at least 90 mol % bromide and at least 1 mol % iodide, which grains have an average equivalent spherical diameter (ESD) of less than 0.25 ?m.
    Type: Grant
    Filed: March 8, 2010
    Date of Patent: August 16, 2011
    Assignee: Eastman Kodak Company
    Inventor: Jeffrey C. Hansen
  • Patent number: 7993807
    Abstract: A composition, method, and system for recording an image. The system includes a multiphase imaging material in which energy is absorbed by an antenna material. The absorbed energy causes the reaction of an activator and a color-forming material to form a mark. A fixer is employed to retard the fading of the mark.
    Type: Grant
    Filed: April 28, 2004
    Date of Patent: August 9, 2011
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Vladek Kasperchik, William Dorogy, Makarand Gore, Marshall Field
  • Patent number: 7732124
    Abstract: A color-image forming method in a silver halide color photographic light-sensitive material, having the steps of: performing exposure of the light-sensitive material cut into sheets; and subjecting the exposed light-sensitive material sheets to photographic processing, while conveying them with conveying rollers, with the sheet conveying speed being 40.0 to 100 mm/sec; wherein the light-sensitive material to be exposed contains any of: 1) a dye-forming coupler of formula (IA), 2) a compound of formula (I), and 3) 1.4 mg/m2 or more of a compound of formula (II); wherein R? and R? are a substituent; Z is a hydrogen atom, or a coupling split-off group; A is an alkyl group, M is a cation, and R is an atom or group having 100 or lower total molecular weight.
    Type: Grant
    Filed: November 20, 2008
    Date of Patent: June 8, 2010
    Assignee: Fujifilm Corporation
    Inventors: Yasuaki Deguchi, Shin Soejima, Naoto Ohshima, Tatsuya Ishizaka, Katsuyuki Takada, Futoshi Yoshida, Atsushi Maruhashi, Yoshinori Morimoto, Takehisa Ohno
  • Patent number: 7687229
    Abstract: A silver halide color photographic light-sensitive material having, on a support, at least each one light-sensitive silver halide emulsion layers containing yellow-, magenta-, or cyan-dye-forming-coupler, and at least one light-insensitive hydrophilic colloid layer, wherein at least one of the dye-forming couplers is a dye-forming coupler that forms an azomethine dye having a solubility of 1×10?8 mol/L to 5×10?3 mol/L in ethyl acetate; and an image forming method using the light-sensitive material.
    Type: Grant
    Filed: August 23, 2005
    Date of Patent: March 30, 2010
    Assignee: FUJIFILM Corporation
    Inventors: Yasuaki Deguchi, Kiyoshi Takeuchi, Mamoru Sakurazawa, Makoto Yamada, Takehiko Satou
  • Patent number: 7632632
    Abstract: Silver halide color photographic elements having multiple color imaging layers contain a permanent, pre-formed magenta dye that is present in an amount to provide a status M green density greater than 0.005 per mg/m2. This dye provides minimum density at lower cost and enables lower dye levels and a reduced organic load that may lead to improved film physical properties.
    Type: Grant
    Filed: June 27, 2008
    Date of Patent: December 15, 2009
    Assignee: Eastman Kodak Company
    Inventors: Paul L. Zengerle, John W. Harder, Drake M. Michno, James H. Reynolds, Steven P. Szatynski
  • Patent number: 7629112
    Abstract: Silver halide color photographic elements having multiple color imaging layers contain a permanent, pre-formed yellow colorant that is present in an amount to provide a status M blue density greater than 0.003 per mg/m2. This colorant provides minimum density at lower cost and can be incorporated with minimal or no organic solvents and thus enable a reduced organic load that may lead to improved film physical properties.
    Type: Grant
    Filed: May 30, 2008
    Date of Patent: December 8, 2009
    Assignee: Eastman Kodak Company
    Inventors: Paul L. Zengerle, Drake M. Michno, James H. Reynolds, Steven P. Szatynski, John W. Harder
  • Patent number: 7611829
    Abstract: A color-image forming method in a silver halide color photographic light-sensitive material, having the steps of: performing exposure of the light-sensitive material cut into sheets; and subjecting the exposed light-sensitive material sheets to photographic processing, while conveying them with conveying rollers, with the sheet conveying speed being 40.0 to 100 mm/sec; wherein the light-sensitive material to be exposed contains any of: 1) a dye-forming coupler of formula (IA), 2) a compound of formula (I), and 3) 1.4 mg/m2 or more of a compound of formula (II); wherein R? and R? are a substituent; Z is a hydrogen atom, or a coupling split-off group; A is an alkyl group, M is a cation, and R is an atom or group having 100 or lower total molecular weight.
    Type: Grant
    Filed: January 27, 2005
    Date of Patent: November 3, 2009
    Assignee: Fujifilm Corporation
    Inventors: Yasuaki Deguchi, Shin Soejima, Naoto Ohshima, Tatsuya Ishizaka, Katsuyuki Takada, Futoshi Yoshida, Atsushi Maruhashi, Yoshinori Morimoto, Takehisa Ohno
  • Patent number: 7476494
    Abstract: A silver halide photosensitive material having at least one blue-sensitive layer, at least one green-sensitive layer, and at least one red-sensitive layer, on a transparent support, wherein at least one of the green-sensitive layers contains a coupler represented by general formula (I) or general formula (Z), and all of the green-sensitive layers contain silver halide emulsion having an average equivalent-spherical diameter of 0.
    Type: Grant
    Filed: July 27, 2007
    Date of Patent: January 13, 2009
    Assignee: Fujifilm Corporation
    Inventors: Junichiro Hosokawa, Koichi Yokota, Masaaki Miki, Yoichi Hosoya, Ryoji Nishimura
  • Patent number: 7270932
    Abstract: Imaging compositions and methods of using the compositions are disclosed. The imaging compositions are sensitive to low levels of energy such that upon application of the low levels of energy the compositions change color or shade. The compositions may be used in methods of marking.
    Type: Grant
    Filed: February 6, 2004
    Date of Patent: September 18, 2007
    Assignee: Rohm and Haas Electronic Materials LLC
    Inventors: Robert K. Barr, James T. Fahey, Corey O'Connor, James G. Shelnut, John J. Piskorski
  • Patent number: 7241562
    Abstract: This invention relates to a color silver halide photographic element comprising gelatin, a support bearing at least one dye image forming unit selected from a dye image forming unit comprising at least one red sensitive silver halide emulsion layer having associated therewith a dye-forming coupler, a dye image forming unit comprising at least one green sensitive silver halide emulsion layer having associated therewith a dye-forming coupler, and a dye image forming unit comprising at least one blue sensitive silver halide emulsion layer having associated therewith a dye-forming coupler; and a polymer represented by Formula 1.
    Type: Grant
    Filed: January 21, 2004
    Date of Patent: July 10, 2007
    Assignee: Eastman Kodak Company
    Inventors: Sidney J. Bertucci, David M. Teegarden, David E. Decker, Thomas H. Whitesides, Larry D. Edwards
  • Patent number: 7223530
    Abstract: The invention relates to a photographic element comprising a support and at least three color records comprising at least three light sensitive layers and at least two interlayers, wherein the light sensitive layers include cyan, magenta, or yellow dye-forming coupler, the light sensitive layers include silver halide grains comprising greater than 90% silver chloride, scavengers are included in the interlayers, the ratio of the total level of scavenger to the total level of coupler is from 0.15 to 0.50, the ratio of the total level of scavenger to the total level of silver is from 0.05 to 0.15, and the reciprocity characteristics of the silver halide grains are such that for a separation exposure of 1 microsecond and 0.4 seconds, upon development, the difference in maximum density is 10% or less and a method for processing the element comprising color developing the element for less than 30 seconds.
    Type: Grant
    Filed: September 20, 2005
    Date of Patent: May 29, 2007
    Assignee: Eastman Kodak Company
    Inventors: Jess B. Hendricks, III, Patti L. Mellars, Jayme D. Ribeiro, Ronald A. Gogle
  • Patent number: 7223519
    Abstract: Imaging compositions and methods of using the compositions are disclosed. The imaging compositions are sensitive to low levels of energy such that upon application of the low levels of energy the compositions change color or shade. The compositions may be applied to a work piece to mark it and removed from the work piece by peeling.
    Type: Grant
    Filed: July 13, 2005
    Date of Patent: May 29, 2007
    Assignee: Rohm and Haas Electronic Materials LLC
    Inventors: Robert K. Barr, Corey O'Connor
  • Patent number: 7144676
    Abstract: Imaging compositions and methods of using the compositions are disclosed. The imaging compositions are sensitive to low levels of energy such that upon application of the low levels of energy the compositions change color or shade. The compositions may be applied to a work piece to mark it and removed from the work piece by peeling.
    Type: Grant
    Filed: July 12, 2004
    Date of Patent: December 5, 2006
    Assignee: Rohm and Haas Electronic Materials LLC
    Inventors: Robert K. Barr, Corey O'Connor
  • Patent number: 7060424
    Abstract: A method of increasing speed of a silver halide color photosensitive material. The photosensitive material has, on a support, a blue-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer, a red-sensitive silver halide emulsion layer, and a nonsensitive layer. The method comprises adding, to the emulsion layer or the nonsensitive layer, a compound represented by formula (M) or (C): in the formula (M), R1 represents H or a substituent, Z represents a group of non-metallic atoms required to form a 5-membered azole ring containing 2 to 4 nitrogen atoms, and X represents H or a substituent, and in the formula (C), Za represents —NH— or —CH(R3)—, Zb and Zc represent —C(R4)? or —N?, R1, R2 and R3 represent an electron attractive group having a Hammett constant ?p of 0.2 to 1.0, R4 represents H or substituent, and X represents H or a substituent.
    Type: Grant
    Filed: November 22, 2002
    Date of Patent: June 13, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Junichiro Hosokawa, Yasuhiro Shimada, Osamu Uchida, Yasuhiro Ishiwata, Toshio Kawagishi
  • Patent number: 6921631
    Abstract: A silver halide color photographic material, which can provide photographs reduced in unevenness of finished image density with high productivity and at low prices even when it undergoes exposure and photographic processing operations under high-speed transport in the form of sheets, and a method of forming images by use of such a photographic material.
    Type: Grant
    Filed: July 17, 2003
    Date of Patent: July 26, 2005
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yasuaki Deguchi, Hiroyuki Yoneyama, Kazuaki Yoshida, Shin Soejima, Yoshiro Ochiai, Shinichi Nakahira
  • Publication number: 20040180302
    Abstract: A method for forming images on a silver halide color photographic photosensitive material having a substrate and photographic structural layers thereon, including, at least three silver halide color photosensitive layers having different photosensitive regions, respectively, and at least one non-photosensitive hydrophilic colloid layer is disclosed. At least one of the photosensitive layers contains 90 mol % or more of silver chloride. Shortly after the silver halide color photographic photosensitive material has been scan-exposed with laser beams, the material is rapid-processed with a low replenishing amount.
    Type: Application
    Filed: February 13, 2004
    Publication date: September 16, 2004
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventors: Naoto Ohshima, Akito Yokozawa, Naoya Shibata
  • Publication number: 20040126720
    Abstract: The present invention relates to a silver halide color photographic light-sensitive material wherein at least one of light-sensitive silver halide emulsion layers includes a silver halide emulsion having a silver chloride content of at least 95 mol % and a silver iodide content of 0.05 mol % to 0.75 mol % and/or a silver bromide content of 0.05 mol % to 4.
    Type: Application
    Filed: December 18, 2003
    Publication date: July 1, 2004
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventors: Atsushi Matsunaga, Tadashi Inaba, Shinichi Ichikawa
  • Patent number: 6706469
    Abstract: A silver halide emulsion which comprises silver halide grains having a silver chloride content of at least 90 mole %, wherein tabular grains satisfying the following conditions (1) and (2) account for at least 70% of the total projected area of all the silver halide grains present: (1) the grain has {111} major faces, an aspect ratio of 2 or more and a thickness of 0.30 &mgr;m or less; and (2) a ratio (b/a) of the grain thickness (b) to the longest distance (a) between at least two parallel twin planes of the tabular grain is in the following range: 1.5≦(b/a)<5.
    Type: Grant
    Filed: March 29, 2001
    Date of Patent: March 16, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Katsuyuki Takada
  • Publication number: 20040048191
    Abstract: An on-press developable heat-sensitive lithographic printing plate precursor comprising: a support having a water-wettable surface; and an image forming layer, wherein the image forming layer comprises microcapsules containing a lipophilic compound and one of a leuco dye which forms a color by an action of an acid and a dye which reduces the maximum absorption intensity in a visible region by an action of an acid, an acid generator capable of generating an acid on heat application, and a light-heat converting substance.
    Type: Application
    Filed: August 26, 2003
    Publication date: March 11, 2004
    Applicant: FUJI PHOTO FILM CO., LTD
    Inventor: Toshifumi Inno
  • Publication number: 20030044733
    Abstract: A three-part color developing kit includes (I) a first concentrated aqueous solution having a pH of from about 11 to about 13.5 and comprising at least 0.25 mol/l of sulfite ions, at least 2.5×10−5 mol/l of iodide ions, at least 0.05 mol/l of bromide ions, and at least 0.5 mol/l of a buffer having a pKa of from about 11 to about 13.5, (II) a second concentrated aqueous solution having a pH of from about 3 to about 6 and comprising at least 1 g/l of a vinyl pyrrolidone polymer, and at least 0.05 mol/l of an organic antioxidant, and a third concentrated aqueous solution having a pH of from about 1 to about 3 and comprising at least 0.05 mol/l of a color developing agent, and at least 0.005 mol/l of sulfite ions.
    Type: Application
    Filed: October 24, 2002
    Publication date: March 6, 2003
    Inventors: Shirleyanne E. Haye, Janet M. Huston
  • Patent number: 6410215
    Abstract: Silver bromoiodide color negative films can be rapidly color developed using stabilized color developer solutions kept at high temperatures with minimal changes in the resulting color record densities. The compositions are stabilized by adjusting or maintaining the pH to 9 or more, but below 10.
    Type: Grant
    Filed: August 27, 1996
    Date of Patent: June 25, 2002
    Assignee: Eastman Kodak Company
    Inventor: David Leroy Cole
  • Patent number: 6329120
    Abstract: An image recording medium is disclosed which comprising: an acid generating agent capable of generating an acid by the action of heat or an acid, which is represented by the following formula (1); and a compound of causing variation in the absorption region of from 360 to 900 nm by the intramolecular or intermolecular reaction triggered by the action of an acid: W1OP  (1) wherein W1 represents a residue of an acid represented by W1OH, and P represents an acid-sensitive substituent capable of splitting off at a temperature of 150° C. or less due to catalysis by W1OH.
    Type: Grant
    Filed: May 16, 2000
    Date of Patent: December 11, 2001
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tatsuhiko Obayashi, Junichi Yamanouchi, Atsuhiro Ohkawa
  • Patent number: 6329121
    Abstract: An image recording medium is disclosed which comprising: an acid generating agent capable of generating an acid by the action of heat or an acid, which is represented by the following formula (1); and a compound of causing variation in the absorption region of from 360 to 900 nm by the intramolecular or intermolecular reaction triggered by the action of an acid: W1OP  (1) wherein W1 represents a residue of an acid represented by W1OH, and P represents an acid-sensitive substituent capable of splitting off at a temperature of 150° C. or less due to catalysis by W1OH.
    Type: Grant
    Filed: December 21, 2000
    Date of Patent: December 11, 2001
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tatsuhiko Obayashi, Junichi Yamanouchi, Atsuhiro Ohkawa
  • Patent number: 6284446
    Abstract: A multilayer silver halide color photographic material, wherein when the multilayer silver halide color photographic material is development processed with a color developing solution containing a p-phenylenediamine derivative as a color developing agent, the relationship between the development proceeding velocity a of the lowermost layer of the constituting emulsion layers of the photographic material and the development proceeding velocity b of the uppermost layer satisfies the following equation (R-1): 0.65≦a/b≦2.0  (R-1) provided that the development proceeding velocity is expressed by the reciprocal of the developing time required for the density value by development to reach ½ of the maximum density.
    Type: Grant
    Filed: June 14, 2000
    Date of Patent: September 4, 2001
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazuaki Yoshida, Yasuaki Deguchi, Hiroyuki Yoneyama
  • Patent number: 6180315
    Abstract: Novel compositions for making structured color images and application thereof Compositions for making structured color images comprising (a) a soluble pigment precursor which can be transformed to an insoluble pigment by means of chemical, thermal, photolytic or radiation-induced method, and (b) a binder polymer or prepolymer, or a positive or negative resist-type resin which can be structured by crosslinking, polymerization or depolymerization by applying heat or electromagnetic irradiation. The compositions can be applied to optical and thermal recording, printing, and the production of color filters for Liquid Crystal Displays, with high accuracy, high transparency and high stability.
    Type: Grant
    Filed: December 10, 1999
    Date of Patent: January 30, 2001
    Assignee: Ciba Specialty Chemcials Corporation
    Inventors: Ulrich Sch{umlaut over (a)}deli, John S. Zambounis, Abul Iqbal, Zhimin Hao, Henri Dubas
  • Patent number: 6133336
    Abstract: Process for forming a selectively colored polymeric layer, or a three-dimensional article made of polymeric layers, wherein a photocurable, photocolorable composition is irradiated with a low dose of light to cure and a different, preferably higher, dose of light to color. The process is particularly useful for preparing selectively colored ornamental and industrial articles and models of plant and animal parts, especially medical models.
    Type: Grant
    Filed: August 30, 1996
    Date of Patent: October 17, 2000
    Assignee: Zeneca Limited
    Inventors: Ajay Haridas Popat, Martin Russell Edwards
  • Patent number: 6040108
    Abstract: Compositions for making structured color images comprising(a) a soluble pigment precursor which can be transformed to an insoluble pigment by means of chemical, thermal, photolytic or radiation-induced method, and(b) a binder polymer or prepolymer, or a positive or negative resist-type resin which can be structured by crosslinking, polymerization or depolymerization by applying heat or electromagnetic irradiation.The compositions can be applied to optical and thermal recording, printing, and the production of color filters for Liquid Crystal Displays, with high accuracy, high transparency and high stability.
    Type: Grant
    Filed: December 3, 1998
    Date of Patent: March 21, 2000
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Ulrich Schadeli, John S. Zambounis, Abul Iqbal, Zhimin Hao, Henri Dubas
  • Patent number: 5998105
    Abstract: Disclosed is a method of image formation comprising the steps of: (i) subjecting a silver halide color photographic material to scanning exposure with a beam modulated in accordance with image information to prepare a scanning-exposed photographic material, wherein the silver halide color photographic material comprises a support having provided thereon a photographic constituent layer containing at least one reducing agent for color formation represented by formula (I) and at least one dye-forming coupler, and wherein a scanning pitch of the beam is smaller than an effective beam diameter of the beam, and an inter-raster overlap width of the beam is from 5% to 95% of the effective beam diameter; and (ii) developing the scanning-exposed photographic material:R.sup.11 --NHNH--X--R.sup.12 (I)wherein R.sup.11 represents an aryl group or a heterocyclic group; R.sup.12 represents an alkyl group, an alkenyl group, an alkinyl group, an aryl group or a heterocyclic group; X represents --SO.sub.
    Type: Grant
    Filed: December 2, 1996
    Date of Patent: December 7, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yasuhiro Murakoshi
  • Patent number: 5965332
    Abstract: A silver halide color photosensitive material comprises a support provided thereon with a photosensitive silver halide, a developing agent, a coupler, and a binder. After exposure, the photosensitive material is placed, onto a processing material comprising a support provided with a processing layer thereon which contains a base and/or a precursor of a base, with water being present between the photosensitive material and the processing material in an amount of 1/10through 1 times that required to maximally swell the layers of the materials. The resultant assembly is heated to form an image on the photosensitive material. The photosensitive material includes an emulsion in which tabular silver halide grains having an aspect ratio of 2 to 30 account for 50% to 100% of the total projected area of all silver halide grains and in which 50% to 100% of all silver halide grains in number include 10 or more dislocation lines per grain. A method of forming images using this photosensitive material is also disclosed.
    Type: Grant
    Filed: August 19, 1997
    Date of Patent: October 12, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Makoto Kikuchi
  • Patent number: 5914225
    Abstract: A color negative photographic element is disclosed that a pair of fast green and red recording layer units coated to receive exposing radiation prior to at least one pair of slow green and red recording layer units. The green recording layer units together contain at least 1.0 g/m.sup.2 of silver with at least 60 percent of the silver in the green recording layer units being in a location other than the fast green recording layer unit, and the red recording layer units together contain at least 1.8 g/m.sup.2 of silver with at least 70 percent of the silver in the red recording layer units being in a location other than the fast red recording layer unit. When development times are reduced to 2 minutes or less during processing increased red speed, reduced granularity of the green record, and increased sharpness of the red record are observed.
    Type: Grant
    Filed: January 28, 1998
    Date of Patent: June 22, 1999
    Assignee: Eastman Kodak Company
    Inventor: John H. Becher
  • Patent number: 5902721
    Abstract: When a color negative film is developed in 2 minutes or less at a temperature of less than 40.degree. C. and contains in overlying blue and green recording layer units high bromide silver halide grains containing from 1 to 10 mole percent iodide, based on silver, and in an underlying red recording layer unit high bromide silver halide grains containing less than 0.05 mole percent iodide, based on silver, and at least 1.times.10.sup.-6 mole per silver mole of a hexacoordination complex of a Group 8 metal and coordination ligands, at least four of the ligands being anionic and at least one of the ligands being more electronegative than halide ligands, loss of lower scale contrast in the red record attributable to the faster time of development is avoided.
    Type: Grant
    Filed: February 17, 1998
    Date of Patent: May 11, 1999
    Assignee: Eastman Kodak Company
    Inventors: John H. Becher, Roger A. Bryant
  • Patent number: 5804359
    Abstract: Photographic elements are disclosed in which exposure to at least one portion of the spectrum is recorded by a silver halide emulsion layer unit as an image having its optical density provided by silver. The layer unit is comprised of a plurality of radiation sensitive silver halide emulsion layers that are responsive to the same region of the spectrum, but differ in sensitivity, including a non-wandering silver halide reducing agent. A molar ratio of reducing agent to silver halide in one of the emulsion layers is less than that stoichiometrically required for complete silver halide reduction to silver. A higher molar ratio of reducing agent to silver halide is contained in a remaining of the two emulsion layers.
    Type: Grant
    Filed: May 17, 1996
    Date of Patent: September 8, 1998
    Assignee: Eastman Kodak Company
    Inventor: Michael John Simons
  • Patent number: 5723265
    Abstract: A color image forming method is disclosed, comprising developing a silver halide photographic material and bleach and/or fixing the photographic material, wherein the color image is formed in the presence of a dextran. The dextran may be incorporated in the photographic material or a processing solution.
    Type: Grant
    Filed: October 8, 1996
    Date of Patent: March 3, 1998
    Assignee: Konica Corporation
    Inventors: Shinsaku Nagaoka, Takehiko Shoji, Kiyokazu Morita, Tsukasa Ito, Yoshihiko Suda
  • Patent number: 5723263
    Abstract: A multicolor negative photographic element comprises a support bearing a blue light-sensitive silver halide emulsion first layer and a green light-sensitized silver halide emulsion second layer wherein said second layer contains a dye sensitized to green light and wherein said first layer has associated therewith a hue correction coupler which upon coupling with oxidized developer produces a dye having a maximum absorbance in the range of 460 to 510 nm. so that the element has a D480/D440 density ratio which is greater than that exhibited by the element without the hue correction coupler. The invention also encompasses a blue sensitive silver halide emulsion layer associated with the hue correction coupler and a method of forming an image in the photographic element of the invention.
    Type: Grant
    Filed: November 12, 1996
    Date of Patent: March 3, 1998
    Assignee: Eastman Kodak Company
    Inventors: Stephen Paul Singer, Paul Barrett Merkel, Jeffrey Walter Schmoeger
  • Patent number: 5714307
    Abstract: A silver halide photographic material comprises a support, at least one silver halide emulsion layer and at least one non-light-sensitive hydrophilic colloidal layer. The silver halide emulsion layer or the hydrophilic colloidal layer contains a colorant having the absorption maximum wavelength within the infrared region of 700 to 1,100 nm. The colorant is in the form of solid particles dispersed in the silver halide emulsion layer or in the hydrophilic colloidal layer. The solid particles cannot substantially be removed by a processing solution of the silver halide photographic material. An image forming process employing the silver halide photographic material is also disclosed.
    Type: Grant
    Filed: September 22, 1995
    Date of Patent: February 3, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toru Harada, Keiichi Suzuki, Shigeru Ohno, Koji Wariishi, Yoshiharu Yabuki
  • Patent number: 5672465
    Abstract: Described is a radiation sensitive imaging film containing a heat fixable radiation sensitive element, e.g., a diacetylene, of the formula: R--C.tbd.C--C.tbd.C--R', where R and R' are, e.g., both --CH.sub.2 --O--CONH--(CH.sub.2).sub.5 CH.sub.3. After exposure to X-radiation during diagnostic or X-ray therapy, the resulting image can be permanently dry fixed by a short heating step and then stored for a long period. Processes for making the film, new binder-convertor systems, and a device incorporating the film are described as well as other imaging, diagnostic and therapeutic methods utilizing the film in high energy radiation applications in the health care field.
    Type: Grant
    Filed: January 9, 1995
    Date of Patent: September 30, 1997
    Assignee: JP Laboratories, Inc.
    Inventors: Gordhanbhai N. Patel, Yao-Ming Cheng, Subhash H. Patel
  • Patent number: 5635340
    Abstract: A method of image formation using mask for exposure to form an image on photographic paper is disclosed. The mask is composed of transferred images of the dyes of yellow, cyan and magenta. The spectral absorption peak wavelength of the dye is set in a range close to the wavelength at the maximum value of each of the regular, orthochromatic and panchromatic spectral sensitivities of the photographic paper to be used. In the spectral absorption of cyan of the mask for exposure, the absorbance of the wavelength at the maximum value of each of the regular and orthochromatic spectral sensitivities of the photographic paper to be used, is set at a value not more than a predetermined value. In the spectral absorption of yellow of the mask for exposure, the absorbance of the wavelength at the maximal value of each of the orthochromatic and panchromatic spectral sensitivities of the photographic paper to be used, is set at a value not more than a predetermined value.
    Type: Grant
    Filed: August 1, 1995
    Date of Patent: June 3, 1997
    Assignee: Konica Corporation
    Inventors: Shigeru Mano, Ichiroh Maeda, Ken Okauchi
  • Patent number: 5563024
    Abstract: An improved image display material comprising a light sensitive tabular grain silver chloride emulsion spectrally sensitized to a peak wavelength of less than about 475 nm, and a method of use comprising the step of optically printing a color image onto the improved color photographic display material is provided. The material and method enable reduced printing times, improved color reproduction and lowered image granularity.
    Type: Grant
    Filed: May 8, 1995
    Date of Patent: October 8, 1996
    Assignee: Eastman Kodak Company
    Inventors: Anne E. Bohan, Jerzy A. Budz, Pamela M. Ferguson, Alberto M. Martinez, James P. Merrill, Scott F. O'Dell, Richard P. Szajewski
  • Patent number: 5508147
    Abstract: Yellowing of a processed photographic element is inhibited by incorporating a scavenger comound capable of reacting with magenta coupler, e.g. an epoxy compound, in a layer adjacent a layer containing the magenta coupler. In a preferred embodiment, the magenta coupler containing layer is sandwiched between layers containing the scavenger compound. Prior to processing at least one of these layers contains a solubilizing agent for the scavenger compound. In preferred embodiments, the processing solution used to process the photographic element containing an external solubilizing agent for the scavenger compound, preferably benzyl alcohol.
    Type: Grant
    Filed: January 4, 1993
    Date of Patent: April 16, 1996
    Assignee: Eastman Kodak Company
    Inventors: Krishnan Chari, Wendell F. Smith, Sundaram Krishnamurthy
  • Patent number: 5420000
    Abstract: Described is a radiation sensitive imaging film containing a heat fixable radiation sensitive element, e.g., a diacetylene, of the formula: R--C.tbd.C--C.tbd.C--R', where R and R' are, e.g., both --CH.sub.2 --O--CONH--(CH.sub.2).sub.5 CH.sub.3. After exposure to X-radiation during diagnostic or X-ray therapy, the resulting image can be permanently dry fixed by a short heating step and then stored for a long period. Processes for making the film, new binder-convertor systems, and a device incorporating the film are described as well as other imaging, diagnostic and therapeutic methods utilizing the film in high energy radiation applications in the health care field.
    Type: Grant
    Filed: August 12, 1993
    Date of Patent: May 30, 1995
    Assignee: JP Laboratories, Inc.
    Inventors: Gordhanbhai N. Patel, Yao-Ming Cheng, Subhash H. Patel
  • Patent number: 5415980
    Abstract: A method of forming a photographic image comprising imagewise exposing a silver halide color photographic material comprising a support having thereon a cyan color image forming layer, a magenta color image forming layer and an yellow color image forming layer, wherein the cyan color image forming layer in the photographic material contains silver halide emulsion grains having a silver chloride content of 95 mol % or more and containing substantially no silver iodide and contains a color sensitizing dye of the following general formula (I), ##STR1## wherein the terms are as defined in the specification and color developing the exposed material with a color developer, wherein the color developer has a chloride ion content of from 3.5.times.10.sup.-2 to 1.5.times.10.sup.-1 mol/liter and a bromide ion content of from 1.5.times.10.sup.-5 to 1.0.times.10.sup.-3 mol/liter.
    Type: Grant
    Filed: March 25, 1994
    Date of Patent: May 16, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Naoto Ohshima
  • Patent number: 5374496
    Abstract: An image forming method is conducted by subjecting a dry silver salt image forming medium to imagewise exposure and heating to form a light-absorbing organic compound. Thereafter, the medium is subjected to polymerization exposure to imagewise polymerize the medium based on the formation pattern of the light-absorbing compound. The light-absorbing organic compound has specific sensitivities to light in order to maximize contrast.
    Type: Grant
    Filed: September 10, 1993
    Date of Patent: December 20, 1994
    Assignee: Canon Kabushiki Kaisha
    Inventors: Kenji Kagami, Akihiro Mouri, Masato Katayama, Kazuo Isaka, Tetsuro Fukui, Susumu Nakamura, Masao Suzuki
  • Patent number: 5298361
    Abstract: A light-sensitive article comprising (a) at least one layer of photopolymerizable material containing a polymerizable compound having at least one ethylenically unsaturated group, and a chromophore-substituted halomethyl-1,3,5-triazine photopolymerization initiator; (b) at least one layer of thermoplastic resin in contact with the layer of photopolymerizable material, said chromophore-substituted 1,3,5-triazine photopolymerization initiator capable of resisting migration to said layer of thermoplastic resin. The invention eliminates the problem of discoloration of the background resulting from excessive migration of the photoinitiator from the layer of photopolymerizable material to the contiguous layer of resin. The invention is especially useful in the preparation of surprint color proofs.
    Type: Grant
    Filed: August 30, 1991
    Date of Patent: March 29, 1994
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: James A. Bonham
  • Patent number: 5219715
    Abstract: A color negative photographic recording material is described in which low emulsion coverage tabular grain silver halide emulsion imaging units are employed. The silver halide emulsion in at least one of the units comprises grains having a tabularity of between about 50 and 25,000. The imaging unit thickness is less than about 4.0 .mu.m, using a total of no more than 2.0 parts by weight of silver per part of coupler. The imaging unit yields a density of at least 2.0 when exposed and processed.
    Type: Grant
    Filed: January 30, 1992
    Date of Patent: June 15, 1993
    Assignee: Eastman Kodak Company
    Inventors: Allan F. Sowinski, George F. Wu, Thomas B. Brust, James T. Kofron, Gary L. House