With Processing Ingredient In Element Patents (Class 430/415)
  • Patent number: 7147996
    Abstract: Photographic silver halide materials containing an incorporated black-and-white developing agent can be quickly and simply processed using unique processing compositions and methods. In a “two-step” method, the exposed material is contacted with an alkaline activator solution followed by a fixing composition. In a “one-step” method, activation and fixing are combined using a single alkaline activator-fixing composition containing the fixing agent. None of the processing solutions include black-and-white developing agents. The photographic silver halide materials are preferably radiographic silver halide materials that have a reflective support and provide black-and-white images that can be viewed without a light box.
    Type: Grant
    Filed: March 28, 2005
    Date of Patent: December 12, 2006
    Assignee: Eastman Kodak Company
    Inventors: Alan S. Fitterman, Robert E. Dickerson, Kenneth A. Duke
  • Patent number: 6649330
    Abstract: In accordance with one embodiment of the invention, a photographic element is described comprising a support bearing one or more hydrophilic colloid layers including at least one photographic silver halide emulsion layer, wherein sequestered silver ions are incorporated into at least one hydrophilic colloid layer in the form of a silver ion containing material which sequesters silver ions prior to photographic processing and releases silver ions upon exposure to photographic processing solutions. Method for preparing and processing such photographic element are also described. In accordance with particular embodiments of the invention, the silver ion containing material comprises a silver ion-exchanged zeolite material or an intercalation composition comprising a layered host material having silver ions inserted as guest ions between the layers of the host material.
    Type: Grant
    Filed: December 28, 2001
    Date of Patent: November 18, 2003
    Assignee: Eastman Kodak Company
    Inventors: Joseph F. Bringley, Kenneth J. Lushington, Tiecheng A. Qiao, James S. Honan
  • Patent number: 6506546
    Abstract: This invention comprises an imaging element comprising an imaging layer having associated therewith a compound of Structure I: wherein PUG is a photographically useful group; LINK 1 and LINK 2 are linking groups; TIME is a timing group; T represents t independently selected substituted or unsubstituted alkyl or aryl groups, t is 0, 1, or 2 and if t is 2, the T groups can form a ring; HET is a heterocyclic group which optionally can form a ring with a T group; R12 is hydrogen, substituted or unsubstituted alkyl or substituted or unsubstituted aryl, or R12 can form a ring with a T group or with HET; 1 is 0 or 1; m is 0, 1, or 2; and n is 0 or 1.
    Type: Grant
    Filed: December 30, 1999
    Date of Patent: January 14, 2003
    Assignee: Eastman Kodak Company
    Inventors: Zbyslaw R. Owozarczyk, Xiqiang Yang, David T. Southby
  • Publication number: 20020055069
    Abstract: An image information recording method is disclosed.
    Type: Application
    Filed: March 7, 2001
    Publication date: May 9, 2002
    Inventors: Yoshiko Iwai, Shigeto Hirabayashi
  • Patent number: 6312879
    Abstract: This invention relates to an imaging element, such as a photographic or photothermographic element comprising a silver halide emulsion layer, wherein the element also comprises a compound of Structure I: wherein the substituents are as defined in the specification.
    Type: Grant
    Filed: December 30, 1999
    Date of Patent: November 6, 2001
    Assignee: Eastman Kodak Company
    Inventors: Wojciech K. Slusarek, Xiqiang Yang, Mark E. Irving, James H. Reynolds, David H. Levy, Lyn M. Irving
  • Patent number: 6218088
    Abstract: An image formation method for forming a color image by imagewise exposing a color negative type silver halide photographic material comprising a transparent support having provided thereon at least three kinds of light-sensitive layers, followed by development processing at a temperature of 50° C. or more, which comprises the steps of reading with an imaging apparatus an image obtained from the color negative type silver halide photographic material whose sensitivity and gradient satisfy the following relationship, applying digital image processing thereto, and then, obtaining output signals of three or more colors: 1.0≦(log10S)·&ggr;≦2.5 S≧800 wherein S represents an ISO sensitivity, and &ggr; represents an average gradient of the three kinds of light-sensitive layers, thereby inviting no failure in shooting due to insufficient exposure in a compact camera or a film with lens, and forming a color image of high quality.
    Type: Grant
    Filed: September 10, 1999
    Date of Patent: April 17, 2001
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Jun Arakawa
  • Patent number: 6159668
    Abstract: There is disclosed a method for forming a color-image, which method comprises 1 containing, in a light-sensitive material, a dye-forming coupler, and a compound or its precursor, that is oxidized by a silver halide, to form an oxidation product thereof, that is coupled with the coupler, to form a dye having an absorption in a visible wavelength region; 2 having a given coating silver amount; and 3 applying a peroxide-containing solution onto the light-sensitive material, by a coating method by droplet-spraying. The method can achieve both "a lowered amount of a waste solution" and "reduction in a change of the processing.
    Type: Grant
    Filed: January 6, 2000
    Date of Patent: December 12, 2000
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Toshiyuki Makuta
  • Patent number: 6074810
    Abstract: There is disclosed a silver halide color light-sensitive material, which comprises a coupler of the formula (1), (2), or (3) in at least one layer on a base: ##STR1## wherein R.sub.1 is a hydrogen atom, a halogen atom, or a substituent, R.sub.2 is a group of formula (4), R.sub.3 and R.sub.4 each are a hydrogen atom, a halogen atom, or a substituent, with the proviso that at least one of R.sub.3 and R.sub.4 is a group of the formula (4), R.sub.5 and R.sub.6 each are an alkyl group, an amino group, a carbonamido group, an alkoxycarbonylamino group, a sulfonamido group, and the like, R.sub.7 represents a group capable of substitution on a benzene ring; n is an integer of 0 to 3. This light-sensitive material can give a magenta image excellent in discrimination, and it is excellent in preservability before and after processing.
    Type: Grant
    Filed: October 8, 1998
    Date of Patent: June 13, 2000
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshio Kawagishi, Hideaki Naruse
  • Patent number: 6060225
    Abstract: There is disclosed a method for forming a color-image, which method comprises 1 containing, in a light-sensitive material, a dye-forming coupler, and a compound or its precursor, that is oxidized by a silver halide, to form an oxidation product thereof, that is coupled with the coupler, to form a dye having an absorption in a visible wavelength region; 2 having a given coating silver amount; and 3 applying a peroxide-containing solution onto the light-sensitive material, by a coating method by droplet-spraying. The method can achieve both "a lowered amount of a waste solution" and "reduction in a change of the processing.
    Type: Grant
    Filed: March 4, 1999
    Date of Patent: May 9, 2000
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Toshiyuki Makuta
  • Patent number: 5985509
    Abstract: A high contrast photographic material comprises a support bearing a silver halide emulsion layer. This material is free from nucleating agents and has a silver:gelatin ratio greater than 1. The emulsion layer comprises silver halide grains that are spectrally sensitized. Moreover, the material contains a density enhancing amine compound in the emulsion layer or in an adjacent hydrophilic colloid layer. The spectrally sensitized silver halide grains comprise one grain population sensitized to radiation of a particular wavelength region, and one or more additional grain populations sensitized to radiation of a different wavelength region.
    Type: Grant
    Filed: December 18, 1997
    Date of Patent: November 16, 1999
    Assignee: Eastman Kodak Company
    Inventors: Allison Hazel C. Dale, Roger H. Piggin
  • Patent number: 5976771
    Abstract: A heat-developable light-sensitive material including a support and at least one light-sensitive silver halide emulsion layer provided on the support, the light-sensitive silver halide emulsion layer containing light-sensitive silver halide grains, a compound to form a dye through coupling reaction with an oxidized product of a developing agent, and a binder, characterized in that the light-sensitive silver halide emulsion layer includes an emulsion containing a developing agent and tabular silver halide grains having a mean grain thickness of 0.01-0.07 .mu.m. The light-sensitive material enables to provide a convenient and quick method of forming color images.
    Type: Grant
    Filed: August 22, 1997
    Date of Patent: November 2, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takuji Kosugi, Kazuki Uehara, Makoto Kikuchi
  • Patent number: 5965332
    Abstract: A silver halide color photosensitive material comprises a support provided thereon with a photosensitive silver halide, a developing agent, a coupler, and a binder. After exposure, the photosensitive material is placed, onto a processing material comprising a support provided with a processing layer thereon which contains a base and/or a precursor of a base, with water being present between the photosensitive material and the processing material in an amount of 1/10through 1 times that required to maximally swell the layers of the materials. The resultant assembly is heated to form an image on the photosensitive material. The photosensitive material includes an emulsion in which tabular silver halide grains having an aspect ratio of 2 to 30 account for 50% to 100% of the total projected area of all silver halide grains and in which 50% to 100% of all silver halide grains in number include 10 or more dislocation lines per grain. A method of forming images using this photosensitive material is also disclosed.
    Type: Grant
    Filed: August 19, 1997
    Date of Patent: October 12, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Makoto Kikuchi
  • Patent number: 5945264
    Abstract: A silver halide color photographic light-sensitive material is disclosed, capable of forming an image by, after exposure of a light-sensitive material, supplying water corresponding to from 1/10 to 1 times the water necessary for giving maximum swelling of all coated layers of a light-sensitive material and a processing material to the light-sensitive material or the processing material, laminating these materials to each other and then heating them, the light-sensitive material comprising a support having thereon at least one photographic light-sensitive layer comprising a light-sensitive silver halide, a developing agent, a compound capable of forming a dye upon coupling reaction with an oxidation product of the developing agent and a binder, and the processing material comprising a support having thereon a processing layer containing a base and/or a base precursor, wherein at least two kinds of silver halide emulsions having spectral sensitivity in the same wavelength region and different in the average gr
    Type: Grant
    Filed: February 10, 1997
    Date of Patent: August 31, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masahiro Asami, Kazuhiko Matsumoto, Toshiki Taguchi
  • Patent number: 5935773
    Abstract: A colour photographic silver halide material with a support, at last one silver halide emulsion layer containing at least one yellow coupler and at least one silver halide emulsion layer containing a cyan coupler applied thereon, in which material the silver halide emulsion layer, of which there is at least one, containing at least one yellow coupler and/or the silver halide emulsion layer, of which there is at least one, containing at least one cyan coupler contains a compound of the formula (I) ##STR1## in which R.sub.1, R.sub.2, R.sub.3 mean alkyl, alkenyl or acyl andn means 6, 7 or 8,is distinguished by improved stability of the image dyes produced by processing.
    Type: Grant
    Filed: April 29, 1996
    Date of Patent: August 10, 1999
    Assignee: Agfa-Gevaert AG
    Inventors: Jorg Hagemann, Gunter Helling
  • Patent number: 5804359
    Abstract: Photographic elements are disclosed in which exposure to at least one portion of the spectrum is recorded by a silver halide emulsion layer unit as an image having its optical density provided by silver. The layer unit is comprised of a plurality of radiation sensitive silver halide emulsion layers that are responsive to the same region of the spectrum, but differ in sensitivity, including a non-wandering silver halide reducing agent. A molar ratio of reducing agent to silver halide in one of the emulsion layers is less than that stoichiometrically required for complete silver halide reduction to silver. A higher molar ratio of reducing agent to silver halide is contained in a remaining of the two emulsion layers.
    Type: Grant
    Filed: May 17, 1996
    Date of Patent: September 8, 1998
    Assignee: Eastman Kodak Company
    Inventor: Michael John Simons
  • Patent number: 5736295
    Abstract: A density enhancing amine compound is incorporated into a silver halide element containing both spectrally sensitized and non-spectrally sensitized silver halide grains in the emulsion layer.
    Type: Grant
    Filed: August 8, 1996
    Date of Patent: April 7, 1998
    Assignee: Eastman Kodak Company
    Inventors: Allison Hazel Caroline Dale, Roger Hugh Piggin
  • Patent number: 5695913
    Abstract: A process for the formation of a color image which comprises the steps of: exposing to light a silver halide light-sensitive material comprising a support having thereon at least one light-sensitive emulsion layer, and developing said light-sensitive material to form a color image, wherein said light-sensitive material comprises at least one dye-forming coupler and at least one coloring reducing agent represented by formula (I) and is intensified with a solution containing hydrogen peroxide or a compound releasing hydrogen peroxide to form an intensified image:R.sup.11 --NH--NH--X--R.sup.12 (I)wherein R.sup.11 represents an aryl group or a heterocyclic group; R.sup.12 represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group, or a heterocyclic group; and X represents --SO.sub.2 --, --CO--, --COCO--, --CO--O--, --CO--N(R.sup.13)--, --COCO--O--, --COCO--N(R.sup.13)--, or --SO.sub.2 --N(R.sup.13)--, in which R.sup.
    Type: Grant
    Filed: February 28, 1996
    Date of Patent: December 9, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Koichi Nakamura, Koki Nakamura, Kiyoshi Takeuchi
  • Patent number: 5645971
    Abstract: The present invention provides a method for making a lithographic printing plate according to the silver salt diffusion transfer process comprising the steps of image-wise exposing an imaging element comprising on a support a photosensitive layer comprising a silver halide emulsion and an image receiving layer containing physical development nuclei and developing said imaging element in the presence of developing agent(s) and silver halide solvent(s) using an alkaline processing liquid characterized in that said development is carried out in the presence of a meso-ionic compound. The present invention further provides an imaging element and alkaline processing liquid for use in said method.
    Type: Grant
    Filed: June 20, 1996
    Date of Patent: July 8, 1997
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Ludo Van Rompuy, Rene De Keyzer, Jean-Marie Dewanckele, Marcel Monbaliu, Jos Vaes
  • Patent number: 5637439
    Abstract: Negative images of super-high contrast can be formed by developing an exposed silver halide photographic photosensitive material in the presence of at least one compound selected from the compound of formula (1): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 independently represent a hydrogen atom, an alkyl group, an aryl group or a heterocyclic group, R.sup.1 and R.sup.2, R.sup.3 and R.sup.4, R.sup.5 and R.sup.6, or R.sup.1 and R.sup.3, together with nitrogen atom to which they are attached, may form a ring; L.sup.1 and L.sup.2 independently represent an alkylene group, an arylene group or a repeated alkyleneoxy group having at least two repeated alkyleneoxy units, which groups may be optionally substituted; A represents an atom selected from hydrogen, carbon, nitrogen, oxygen and sulfur or a divalent linkage group constituted from these atoms; and m and n represent 0 or 1, and the compound of formula (2) ##STR2## wherein R.sup.7, R.sup.8 and R.sup.
    Type: Grant
    Filed: November 2, 1995
    Date of Patent: June 10, 1997
    Assignees: Mitsubishi Paper Mills Ltd., E. I. Du Pont de Nemours and Company
    Inventors: Satoshi Kaneko, Kenji Hirata, Akira Tanaka, Reinhold Ruger
  • Patent number: 5578411
    Abstract: A medical X-ray film comprising a transparent base coated on at least one side with (a) a laminar grain silver halide emulsion and (b) a separate hydrophillic colloid layer containing a developing agent for silver halide in an amount corresponding to at least 0.5 moles per mole of the silver coated on that side of the base.
    Type: Grant
    Filed: February 10, 1994
    Date of Patent: November 26, 1996
    Assignee: Imation Corp.
    Inventors: Sean D. Slater, Julian M. Wallis
  • Patent number: 5478696
    Abstract: A silver halide photographic light-sensitive material is disclosed. the light-sensitive material comprises a support bearing on the same side thereof a silver halide emulsion layer and optionally a hydrophilic colloid layer, and at least one of the silver halide emulsion layer or the hydrophilic colloid layer contains a hydrazine derivative in a form of dispersion of solid particles and at least one of the silver halide emulsion layer or the hydrophilic colloid layer contains a nucleation accelerator represented by the following formula 1; ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are each independently a hydrogen atom, a substituted or unsubstituted alkyl group, an substituted or unsubstituted alkenyl group or a substituted or unsubstituted aryl group, provided that R.sub.1, R.sub.2 and R.sub.3 are not a hydrogen atom at the same time and two of R.sub.1, R.sub.2 and R.sub.3 may link to form a ring.
    Type: Grant
    Filed: November 21, 1994
    Date of Patent: December 26, 1995
    Assignee: Konica Corporation
    Inventor: Takeo Arai
  • Patent number: 5447817
    Abstract: To eliminate the "pi-line" artefact after processing a method of image formation in a silver halide industrial X-ray photographic material is disclosed wherein said material comprises on at least one side of a support, at least one gelatino silver halide emulsion layer and a total amount of silver halide, corresponding to from 6 to 20 g of silver nitrate per square meter and per side, and at least one non-sensitive protective antistress coating and wherein said method proceeds by the steps of exposing said material to direct X-rays and processing the material in an automatic processing machine by development, fixing, rinsing and drying, characterized in that said material further comprises at least one vinyl sulphone compound as a hardening agent in at least one of its hydrophilic layers, that development occurs in a developer comprising as a surfactant at least one anionic alkylphenoxy and/or alkoxy polyalkyleneoxy phosphate ester, sulphate ester, alkyl carboxylic, sulphonic or phosphonic acid and/or a salt
    Type: Grant
    Filed: April 5, 1994
    Date of Patent: September 5, 1995
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Raymond Florens, Pieter Perdieus, Peter Willems, Freddy Henderickx
  • Patent number: 5283156
    Abstract: The present invention provides a method for making a lithographic printing plate according to the silver salt diffusion transfer process comprising the steps of image-wise exposing an imaging element comprising on a support a photosensitive layer comprising a silver halide emulsion and an image receiving layer containing physical development nuclei and developing said imaging element in the presence of developing agent(s) and silver halide solvent(s) using an alkaline processing liquid characterized in that said development is carried out in the presence of a regulator according to one of the formulas as specified in the claims. The present invention further provides an imaging element and alkaline processing liquid for use in said method.
    Type: Grant
    Filed: December 4, 1992
    Date of Patent: February 1, 1994
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Marcel Monbaliu, Rene De Keyzer, Jean-Marie Dewanckele, Jos Vaes, Ludo Van Rompuy
  • Patent number: 5262271
    Abstract: According to the present invention a method for producing a negative image is provided, comprising the following steps:image-wise exposing an imaging element comprising on a support, a light-sensitive silver halide emulsion layer comprising silver halide grains having an average volume of not more than 0.02 .mu.m.sup.3 and a layer containing non-light-sensitive water insoluble silver salt, to produce a latent image in said layer of light-sensitive silver halidedeveloping said latent image to produce physical development nuclei of silverdissolving the non-light-sensitive silver salts using a silver salt complexing agent andallowing the thus formed silver salt complexes to diffuse to the layer containing said image-wise formed physical development nuclei of silver to image-wise deposit and develop said silver salt complexes on said image-wise formed physical development nuclei of silver in the presence of (a) developing agent(s).
    Type: Grant
    Filed: October 10, 1991
    Date of Patent: November 16, 1993
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Jean-Pierre D. Tahon, Wilhelmus Janssens
  • Patent number: 5155014
    Abstract: Method for the production of direct-positive images by image-wise exposing a light-sensitive silver halide material comprising a support and an internal latent image-type silver halide emulsion layer and developing said exposed material in the presence of at least one development nucleator and density-increasing amounts of a compound chosen from the class consisting of formic acid, oxalic acid, glyoxylic acid, or salts of these and/or of a compound chosen from the class consisting of polyethylene glycols, with a hydroquinone-type developing solution having a pH not higher than 12.0 and comprising less than 25 g per liter of a hydroquinone and 5 to 100 g per liter of at least one alkanolamine.
    Type: Grant
    Filed: August 14, 1991
    Date of Patent: October 13, 1992
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Jozef P. De Prijcker, Fernand I. Ketels, Jean-Marie O. Dewanckele, Piet Kok
  • Patent number: 4975354
    Abstract: Silver halide photographic elements which are capable of high contrast development, when processed in the presence of a hydrazine compound that functions as a nucleating agent, include certain secondary or tertiary amino compounds which function as incorporated boosters. Such elements are particularly useful in the field of graphic arts.
    Type: Grant
    Filed: May 30, 1989
    Date of Patent: December 4, 1990
    Assignee: Eastman Kodak Company
    Inventors: Harold I. Machonkin, Donald L. Kerr
  • Patent number: 4840888
    Abstract: There is disclosed a light-sensitive silver halide photographic material having at least one silver halide emulsion layer on a support, which comprises the light-sensitive photographic material contains light-sensitive silver halide grains, metal salt grains having internal fog and a polyhydric alcohol having at least two hydroxyl groups having a melting point of 40.degree. C. or higher.
    Type: Grant
    Filed: October 27, 1988
    Date of Patent: June 20, 1989
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Mikio Kawasaki, Hiroaki Shiozawa, Kakujulo Fukuouji, Kouji Ono
  • Patent number: 4693955
    Abstract: Disclosed is a light-sensitive photographic element for negative type lithographic printing plates high in sensitivity and contrast which comprises a support having thereon a light-sensitive silver halide, a metal salt particle having substantially no light-sensitivity, a compound which reacts with an oxidized developing agent produced by development to release a compond which acts as a solvent or a solution physical development accelerator for said metal salt particle and physical development nuclei.
    Type: Grant
    Filed: March 18, 1985
    Date of Patent: September 15, 1987
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Koichi Torizuka, Kiyoshi Futaki
  • Patent number: 4579804
    Abstract: An image forming material comprises an image forming layer disposed on a support and comprising (a) aqueous composition comprising a hydrophilic binder layer containing metal developing nuclei or their precursor compound, and water and (b) an organic composition comprising an oil-soluble development inhibitor which is a compound having a diazo group or azide group and a water-miscible organic solvent. An image is formed by exposing the image forming layer to patternized light and then contacting it with a developer containing reducible metal ions and a reducing agent thereby to form an image constituted by metal particles grown at the light-exposed parts.
    Type: Grant
    Filed: February 22, 1983
    Date of Patent: April 1, 1986
    Assignee: Dai Nippon Insatsu Kabushiki Kaisha
    Inventors: Satoshi Takeuchi, Masanori Akada, Ryohei Takiguchi, Yoshiaki Hida, Hideki Takematsu
  • Patent number: 4400462
    Abstract: Photographic materials and photographic processes employing light sensitive silver halide particles, silver halide particles which are substantially non-light sensitive having been modified with a silver halide solubility reducing agent and internally fogged silver halide particles which are substantially non-light sensitive provide negative silver images of high contrast and high maximum density.
    Type: Grant
    Filed: June 1, 1981
    Date of Patent: August 23, 1983
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Kouzi Ono, Mikio Kawasaki, Mariko Natori, Eiichi Sakamoto
  • Patent number: 4363870
    Abstract: A method for making a laser recording and data storage medium by first exposing a Lippman emulsion to light in order to form a depthwise nuclei gradient, then physically developing the emulsion until a reflective surface layer of spheroid silver particles, having the desired degree of reflectivity, is attained and then chemically developing the remaining nuclei to form a dark underlayer of filamentary silver particles.
    Type: Grant
    Filed: September 11, 1981
    Date of Patent: December 14, 1982
    Assignee: Drexler Technology Corporation
    Inventor: Eric W. Bouldin
  • Patent number: 4312938
    Abstract: A broadband laser recording and data storage medium for direct read after writing, formed from a photosensitive silver-halide emulsion in four steps. First, a non-saturating actinic radiation exposure is used to create latent images. A normal photographic development is used to produce a medium of gray neutral density. The surface of the remaining silver halide is fogged in a water or alcohol based solution to create a very thin layer of silver precipitating nuclei on the surface. Finally, a single-step, negative silver diffusion transfer process is used to dissolve the unexposed and undeveloped silver halide, forming silver ion complexes.
    Type: Grant
    Filed: October 17, 1980
    Date of Patent: January 26, 1982
    Assignee: Drexler Technology Corporation
    Inventors: Jerome Drexler, Eric W. Bouldin
  • Patent number: 4286045
    Abstract: An image forming material comprising a support having thereon a layer composed of a Ge-S composition or a Ge-S-X composition wherein X represents at least one element selected from the group consisting of Al, Si, Mg, Ti, V, Mn, Co, Ni, Sn, Zn, Pd, In, Se, Te, Fe, I, P and O which undergoes a structural change capable of being detected optically, electrically or chemically upon exposure imagewise to light wherein the Ge-S or Ge-S-X composition layer has a thickness of at least about 300 A and contains therein at least one element selected from the group consisting of Ag, Cu and Pb in an amount of more than 2 atoms of Ag, Cu and/or Pb based on 100 atoms of the Ge-S composition or the Ge-S-X composition.
    Type: Grant
    Filed: November 15, 1979
    Date of Patent: August 25, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Akira Nahara, Yoshihiro Ono, Tomizo Namiki, Shigeo Harada, Yuzo Mizobuchi, Tomoaki Ikeda
  • Patent number: 4268617
    Abstract: A silver halide color photographic light-sensitive material comprising a support and at least one silver halide emulsion layer, at least one of the layers of said photographic sensitive material containing at least one compound selected from the group consisting of those compounds represented by the formulae (I), (II), (III) and (IV):[Co(NH.sub.3).sub.6 ][R.sup.1 COO].sub.3 (I)[Co(NH.sub.3).sub.6 ][R.sup.2 OOCR.sup.3 COO].sub.3 (II)[Co(NH.sub.3).sub.5 (R.sup.4 COO)]X.sub.2 (III)[Co(NH.sub.3).sub.5 (R.sup.5 NH.sub.2)]X.sub.3 (IV)wherein R.sup.1, R.sup.2 and R.sup.4 each represent an alkyl group having at least 3 carbon atoms or a fluorine-substituted alkyl group having at least 1 carbon atom; R.sup.3 is an alkylene group; R.sup.5 is an alkyl group having at least 1 carbon atom; X is a halogen atom, a nitrate ion, a sulfate ion, or a carboxylate ion is disclosed.
    Type: Grant
    Filed: September 27, 1979
    Date of Patent: May 19, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Akio Mitsui, Yoshiaki Suzuki
  • Patent number: 4258128
    Abstract: Nonpolar, organic solvent-soluble tellurium compounds and complexes are disclosed. The compounds are tellurium(II) compounds and are represented by the formula:Te----CH.sub.2).sub.n SiRR'R"].sub.2wherein:n is an integer from 1 to 10 andR, R' and R" are independently selected from the group consisting of alkyl, aryl and neterocyclic radicals. Photosensitive complexes of these compounds with transition metals, as well as photographic elements having layers comprising these complexes, are also disclosed.
    Type: Grant
    Filed: December 1, 1978
    Date of Patent: March 24, 1981
    Assignee: Eastman Kodak Company
    Inventor: Henry J. Gysling
  • Patent number: 4254214
    Abstract: A photographic material for recording non-silver images at high sensitivity using a small amount of silver halide, comprising a support, a layer, formed thereon, of a monovalent or divalent copper salt or complex and a hydrophilic binder, and a layer of silver halide formed on the layer containing the copper salt or complex either by vacuum-deposition or sputtering, or by coating a silver halide emulsion. Non-silver images are formed by exposing the photographic material imagewise, and developing the silver halide layer and the copper compound layer either successively with different developer solutions, or continuously in one developer solution. The silver developed acts as a catalyst for the development of the copper compound.
    Type: Grant
    Filed: May 30, 1978
    Date of Patent: March 3, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keizi Takeda, Kenji Matsumoto, Masayoshi Nagata
  • Patent number: 4251623
    Abstract: Tellurium images are formed by the decomposition of tellurium (II) coordination complexes in the presence of a catalyst. The complexes are characterized in that at least one of the four coordination positions of the tellurium (II) is occupied by a sulfur containing ligand. Preferred ligands that can be coordinated with tellurium are sulfur containing bidentate anionic ligands. Complexes formed using these preferred ligands are more hydrolytically stable than other tellurium (II) complexes having sulfur containing ligands and yet are still capable of providing catalytic amplification.
    Type: Grant
    Filed: June 21, 1979
    Date of Patent: February 17, 1981
    Assignee: Eastman Kodak Company
    Inventor: Henry J. Gysling
  • Patent number: 4250250
    Abstract: A photographic process comprising exposing imagewise a photosensitive layer containing a divalent tin basic salt to actinic rays to form a pattern consisting of non-reducing exposed areas and reducing non-exposed areas and contacting the exposed photo-sensitive layer with a developer capable of forming or erasing color by reduction to thereby form a visible image corresponding to said non-exposed areas or said exposed areas.
    Type: Grant
    Filed: August 10, 1979
    Date of Patent: February 10, 1981
    Assignee: Mita Industrial Company Limited
    Inventors: Nobuhiro Miyakawa, Hiroshi Kokado, Eiichi Inoue
  • Patent number: 4198237
    Abstract: An image forming material comprising a support having thereon a layer composed of a Ge--S composition or a Ge--S--X composition wherein X represents at least one element selected from the group consisting of Al, Si, Mg, Ti, V, Mn, Co, Ni, Sn, Zn, Pd, In, Se, Te, Fe, I, P and O which undergoes a structural change capable of being detected optically, electrically or chemically upon exposure imagewise to light wherein the Ge--S or Ge--S--X composition layer has a thickness of at least about 300A and contains therein at least one element selected from the group consisting of Ag, Cu and Pb in an amount of more than 2 atoms of Ag, Cu and/or Pb based on 100 atoms of the Ge--S composition or the Ge--S--X composition.
    Type: Grant
    Filed: April 3, 1979
    Date of Patent: April 15, 1980
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Akira Nahara, Yoshihiro Ono, Tomizo Namiki, Shigeo Harada, Yuzo Mizobuchi, Tomoaki Ikeda
  • Patent number: 4188218
    Abstract: Tellurium images are formed by the decomposition of tellurium (II) coordination complexes in the presence of a catalyst. The complexes are characterized in that at least one of the four coordination positions of the tellurium (II) is occupied by a sulfur containing ligand. Preferred ligands that can be coordinated with tellurium are sulfur containing bidentate anionic ligands. Complexes formed using these preferred ligands are more hydrolytically stable than other tellurium (II) complexes having sulfur containing ligands and yet are still capable of providing catalytic amplification.
    Type: Grant
    Filed: December 22, 1977
    Date of Patent: February 12, 1980
    Assignee: Eastman Kodak Company
    Inventor: Henry J. Gysling