Abstract: An electromagnetic shielding film for plasma display which is excellent in electromagnetic shielding characteristics for effectively shielding electromagnetic waves, near infrared rays, stray light, external light, and the like and even when stored under a wet heat condition, is small in change of color tint and good in adhesion, with a blackening layer hardly peeled away, is provided by a transparent electromagnetic shielding film including a transparent support having thereon a conductive metal layer in a pattern-like state having an electromagnetic shielding ability and having a surface covered by a blackening layer, with the blackening layer made of an alloy of nickel and zinc in a nickel/zinc mass ratio of from 0.5 to 50.

Abstract: There are provided a conductive pattern material and a pattern-forming method by which a fine pattern having a high resolution and no wire breakage is obtained. The conductive pattern material is such that on a support surface a pattern-forming layer is formed which allows the formation of a hydrophilic/hydrophobic region directly bonded to the support surface due to energy imparted. Energy is imparted to the pattern-forming material in an imagewise manner to form the conductive material layer.

Abstract: A method of making a printing plate from a heat-sensitive PS plate of a positive-working mode for lithographic printing includes the steps of exposing the heat-sensitive PS plate to light and developing the PS plate using an alkaline developing solution containing at least one surfactant selected from the group consisting of anionic surfactants and ampholytic surfactants, and a salt selected from the group consisting of alkali metal salts and ammonium cation salts. The PS plate has a substrate and an image forming layer formed thereon, the image forming layer including a lower layer which is formed on the substrate and contains a water-insoluble and alkali-soluble resin and an upper heat-sensitive layer which is overlaid on the lower layer and contains a water-insoluble and alkali-soluble resin and an infrared absorption dye and exhibits an elevated solubility with respect to alkaline aqueous solutions when heated.

Abstract: A method is provided for selectively metallizing one or more three-dimensional materials in an electronic circuit package comprising the steps of forming a layer of seeding solution on a surface of the three-dimensional material of interest, exposing this layer to light of appropriate wavelength, resulting in the formation of metal seed on regions of the three-dimensional material corresponding to the regions of the layer of seeding solution exposed to light; removing the unexposed regions of the layer of seeding solution by subjecting the exposed and unexposed regions of the layer of seeding solution to an alkaline solution. Thereafter, additional metal is deposited, e.g., plated, onto the metal seed using conventional techniques. Significantly, this method does not involve the use of a photoresist, or of a corresponding chemical developer or photoresist stripper.

Abstract: The method for the aptitude testing of protein fractions containing factor VIII the further processing of which comprises a pasteurizing step is performed in such a way that the starting material is examined for fragments within a range of from 20 to 50 kD. Fragments of factor VIII within this range evidently cause inhibitor formations in patients pretreated with factor VIII. Batches contaminated with such fragments can also be utilized, i.e., for the preparation of a high purity virus-free factor VIII by size exclusion chromatography on hydrophilic materials.

Abstract: A method is provided for selectively metallizing one or more three-dimensional materials in an electronic circuit package comprising the steps of forming a layer of seeding solution on a surface of the three-dimensional material of interest, exposing this layer to light of appropriate wavelength, resulting in the formation of metal seed on regions of the three-dimensional material corresponding to the regions of the layer of seeding solution exposed to light; removing the unexposed regions of the layer of seeding solution by subjecting the exposed and unexposed regions of the layer of seeding solution to an alkaline solution. Thereafter, additional metal is deposited, e.g., plated, onto the metal seed using conventional techniques. Significantly, this method does not involve the use of a photoresist, or of a corresponding chemical developer or photoresist stripper.

Abstract: A hydrophilic activating catalytic solution for electroless plating is a mixture of lactate, palladium and alkaline medium. The solution enables depositing palladium catalyst in a short time radiation exposure and removing unwanted photo-sensitive film more effectively by water or the like. The lactate preferably comprises copper lactate and/or zinc lactate and the palladium salt is preferably palladium chloride.

Abstract: Disclosed is a process for processing a lithographic printing plate having a physical development nuclei layer between an aluminum support and a silver halide emulsion layer, which comprises processing the lithographic printing plate in the presence of a monocyclic azole compound having no mercapto group or a derivative thereof.

Abstract: An optical recording material comprising: a thin film or membrane of a hydrophobic binding agent; and metallic particles having a diameter of 0.003 .mu.m to 3 .mu.m dispersed in said film or membrane wherein the density of said metallic particles is higher near at least one surface of said film or membrane as compared with another portion of said film or membrane, each metallic particle having a nucleus and an outer coating, said outer coating consisting of at least one metal having a melting point of 250.degree. C. to 1800.degree. C. and a thermal conductivity at 0.degree. C. of 5 W.multidot.m.sup.-1 .multidot.K.sup.-1 to 450 W.multidot.m.sup.-1 .multidot.K.sup.-1 wherein the reflectivity of the surface of said film or membrane where the density of said metallic particle is higher is 10 to 90%., a method for preparing the optical recording material and an optical card containing the optical recording material.

Abstract: A method of making a photographic color print using a photographic color material containing low levels of silver halide characterized in that,(a) after image formation and washing and/or stop bath treatment and(b) before non-uniform exposure to adventitious light,the print is uniformly exposed to a light source so that undeveloped silver halide is caused to print out uniformly. Such a uniform density is much more acceptable than a non-uniform density caused by uneven light in normal conditions.

Abstract: A light-stable physical developer comprising a solution of silver ions, a desensitizing agent and a reducing agent. A method for the detection of one or more components of an aggregate formed between at least one specific binding agent and its corresponding bindable substance by labelling at least one component of said aggregate with a marker and contacting said aggregate with said light-stable physical developer, whereby under influence of the marker a metal particle is formed which can be detected. Further the invention also relates to products, e.g. a test-kit adapted for carrying out the above mentioned method.

Abstract: Metal is photolytically deposited from solution onto a substrate in contact with the solution by irradiating with light a solution containing a solubilized metal source and an organic compound containing a plurality of proximal Lewis base substituent groups so as to be capable of promoting the photoreduction of the metal onto the substrate.

Abstract: A method of manufacturing printed circuit boards. An environmentally safe method for manufactured printed circuit boards using additive technology provides a simple and exact transfer of conductor patterns. The novel method provides a selective ablation of a nucleation, B, applied to a substrate either by itself or together with a thin base layer, G, applied by chemical metal deposition. This ablation is done by electromagnetic radiation preferably with an excimer laser in those regions of the substrate that do not correspond to the conductor tracks and/or interlayer connections or through-connections to be formed later. Conductor material is subsequently built up by chemical and/or galvanic metal deposition.

Abstract: A method of locally providing metal on a surface of a substrate, in which the substrate is provided at the surface with an electrocatalythic image. The surface is then brought into contact with an electroless metal-plating solution. The electrocatalythic image is capable of binding metal to it from the metal-plating solution. Due to the fact that the image is brought into contact with the metal-plating solutin, the image is gradually strengthened with metal from the solution. With images smaller than 10 .mu.m, this strengthening is prevented, however, due to the fact that oxygen is present in the solution. Because oxygen is reduced, a reduction of metal ions in the solution cannot occur, as a result of which no metal deposition takes place on the image. According to the invention, the reduction of oxygen in the solution is counteracted at least relatively so that also in the case of images smaller than 10 .mu.m metal ions are reduced without hindrance to the metal, which is then deposited on the image.

Abstract: Novel photosensitive polymers having an intrinsic viscosity [.eta.] of not less than 0.10 dl/g, measured at 25.degree. C. in N,N-dimethylformamide, and consisting of 1 to 40 mol % of recurring structural elements of the formula I ##STR1## and 60 to 99 mol % of recurring structural elements of the formula II ##STR2## in which R, R', R", X, Z and Z.sub.1 are as defined in patent claim 1, are described. The polymers according to the invention can be partially complexed with metal ions of a metal of group VIII or Ib of the periodic table. In not less than 20% of the structural elements of the formula II, Z.sub.1 is --COO--C.sub.2-12 -alkylene-OH, --COO(CH.sub.2 CH.sub.2 O).sub.p H, --COO[CH.sub.2 CH(CH.sub.3)O].sub.p H, hydroxymethylphenyl, --CONH--C.sub.1-4 -alkylene-OH or --COO--C.sub.1-4 -alkylene-N(Q')(Q"), where p=2-4. The polymers according to the invention can be used, inter alia, for producing images, in particular for the construction of electrically conductive coatings or patterns.

Abstract: A process for generating a capacitive servo pattern on a magnetic storage disk, comprising the steps of: (1) coating the disk with a solution of noble metal compound to form a film of the compound on the disk, (2) exposing said film to radiation through a mask to generate an image on the film, and (3) plating the disk on the areas exposed to radiation.

Abstract: A process suitable for the fully additive technique for the electroless partial metallization of substrate surfaces consists in treating the surface with photosensitive silver(I) compounds (e.g. carboxylic acid salts), partially exposing the silver(I) compounds left behind on the surfaces, if necessary intensifying the exposure effect and/or exchanging the silver produced during the exposure for nobler metals, and detaching the unexposed silver(I) compounds.

Abstract: A multilayered composite product useful as an electrical circuit is produced by coating a base with a photoimagable resin free of catalyst or catalyst activator for electroless metal deposition. The resin is patterned by exposure to a desired light, through a mask followed by development. The patterned cured resin is selectively chemically modified while avoiding chemical modification of the base to render the cured resin receptive to a metal catalyst. The metal catalyst which promotes subsequent electroless metal deposition is selectively absorbed on the patterned cured resin and is converted to a catalytically active form. A conductive metal then is deposited selectively on the catalyst-containing patterned cured resin.

Abstract: The present invention relates to a chemical metallization process, particularly for the spatially selective metallization of electrically insulating surfaces. This process employs a chemically stable, radiation sensitive sensitizer layer which contains chromium complex compounds and noble metal ions.

Abstract: A thin film device for recording information in readable form that decreases its light absorbancy in response to increased temperature. The film includes two elements from column IVa of the Periodic Table, such as silicon, germanium, tin and lead, bound with one of or a mixture of sulfur and selenium.The as-deposited inventive materials contain tetrahedral units, some ethane-like units and some rings and chains. Upon heating the ethane-like units are converted to rings and chains and tetrahedral units producing a dramatically decreased light absorbancy. The materials are stable at relatively high operating temperatures.

Abstract: An image forming material comprises an image forming layer disposed on a support and comprising (a) aqueous composition comprising a hydrophilic binder layer containing metal developing nuclei or their precursor compound, and water and (b) an organic composition comprising an oil-soluble development inhibitor which is a compound having a diazo group or azide group and a water-miscible organic solvent. An image is formed by exposing the image forming layer to patternized light and then contacting it with a developer containing reducible metal ions and a reducing agent thereby to form an image constituted by metal particles grown at the light-exposed parts.

Abstract: The use of photosensitive compositions of matter for electroless deposition of metals, containing(a) 0.1 to 20 percent by weight of a compound of the formula I ##STR1## in which Y and R.sub.1 to R.sub.6 are as defined in patent claim 1, (b) 70 to 99.8% by weight of a polymer with H donor groups and an average molecular weight of at least 2,000 Daltons, or of a polymer mixture of a polymer component with H donor groups and an average molecular weight of at least 2,000 Daltons and a second polymer component with an average molecular weight of at least 3,000 Daltons, and(c) 0.1 to 10% by weight of one or more salts of a metal of group Ib or VIII of the periodic table.Images, in particular electrically conductive coatings or patterns, can be produced with the above compositions of matter by exposing the compositions of matter to light and then depositing a metal on the zero-valent, non-conductive metal nuclei thereby formed.

Abstract: A multilayered composite product including a base, a patterned cured resin bonded to the base and an applied metal layer selectively bonded to the patterned cured resin. The product is useful as an electrical circuit.

Abstract: A photographic material comprises acid esters of cellulose or copolymers of acid esters of cellulose and synthetic comonomers.The invention may be used in the photographic industry for producing line and half-tone images on paper, films and cloth. Moreover, the proposed photographic material may be used for direct recording of ultraviolet radiation.

Abstract: An improved method for making conductive metal patterns involving the steps of treating a substrate with a solution comprising a reducible salt of a non-noble metal and a light radiation sensitive reducing compound, exposing said substrate to light radiant energy, fixing with a solution comprised of a complexing agent followed by electroless deposition, the improvement comprising extending the bath life of said fixing solution by maintaining the concentration of the light sensitive reducing compound on the fixing solution so that it does not exceed 0.4 m moles/liter.

Abstract: There is disclosed an improved integral optical device of the type produced by creating optical patterns in porous glass bodies, especially patterns involving gradient refractive index distributions. The optical strength of an element, such as a lens, in such an optical pattern is increased by treatment with a polymerizable, organo functional silicone fluid while the matrix glass is sealed.

Abstract: An image-forming method wherein a photosensitive material comprising a support having a photosensitive copper (I) halide emulsion that contains silver halide and which has grains of copper (I) halide crystal dispersed in a binder is subjected to imagewise exposure and development with an alkaline solution is disclosed. The imagewise exposure is effected either in a dry or wet state. The alkaline solution contains compounds selected from at least two of the following three groups: (A) a group consisting of .alpha.-amino acids, .alpha.

Abstract: Producing metal images or patterns on and/or below the surface of a substrate material comprising a semiconducting light-sensitive compound, such as titanium dioxide or zinc oxide which after exposure of a metal compound releases this metal in the form of nuclei. Exposure takes place in the solution of the metal compound by means of a moving beam of laser light whereby the nuclei pattern is directly "written". Thereafter, the nuclei image is intensified in known manner to produce a visible image or a conductive pattern, for example by means of an electroless plating solution. Use: the recording of information as well as the production of printed circuit boards.

Abstract: Optical patterns formed by localized optical density or refractive index variations in glass are produced by impregnating a porous glass support with a photolyzable organometallic compound and selectively exposing the glass to a photolyzing light source to cause the photolytic decomposition of the organometallic compound in exposed portions of the glass. The patterns are fixed, if desired, by removing unreacted organometallic compound from the pores.

Abstract: In an electrically activatable recording element improvements are provided by an electrically conductive interlayer (ECI layer) separating (a) an electrically activatable recording layer from (b) a photoconductive layer or electrical activating means. The ECI layer comprises electrically conductive particles uniformly dispersed in an electrically insulating binder. The interlayer enables imaging with a minimized air gap between (a) and (b). The recording element is room light handleable. The element provides an image by dry development processing or by means of processing solutions.

Abstract: A photosensitive element comprising a support carrying photosensitive silver halide grains in a substantially predetermined spaced array and methods for forming such photosensitive elements.

Abstract: A black-and-white negative image forming process is disclosed using a diffusion transfer type film unit. An exposed silver halide emulsion comprising internal latent image type silver halide grains which have substantially no fogging centers at their surface is processed with a composition comprising a silver halide solvent, a developing agent, a foggant, alkali and a fog promoting agent. The solvent for the silver halide characteristically possesses a solubilizing power for AgBr of from about 2.times.10.sup.-5 to 5.times.10.sup.-3 mol/l in a 0.002 molar aqueous solution.

Abstract: Disclosed are tellurium (IV) compounds represented by the formula: ##STR1## wherein: D is a Lewis base function containing a group VA or VIA donor atom;Q represents the atoms necessary to complete a 5- or 6-membered ring, when taken together with C, D and Te, when m is 1 and represents the atoms linking C and D when m is greater than 1;R.sub.1 and R.sub.2 are independently selected from the group consisting of hydrogen, alkyl and aryl;X is an anion;n is 1 or 2; andm is an integer from 1 to 500.These compounds are useful in an image-forming combination comprising the described Te(IV) compound and a reducing agent. The image-forming combination is useful in a variety of materials, including a dry amplification element.

Abstract: Methods for making photosensitive thin film structures comprising one or more metal-dielectric layers, produced by the sequential deposition of discontinuous metal island films and transparent covering films containing selected dielectric acceptor materials, and the use of the photosensitive thin film structures to record full-color and/or dichroic images, are described.

Abstract: In an improved method for depositing a metal on a substrate of the type in which a dielectric coated substrate is coated with a sensitizing solution containing a reductible metal salt, a primary reducing agent comprising 2,7 anthraquinone disulfonic acid and a secondary reducing agent, the substrate is exposed to ultraviolet light in an atmosphere having a temperature of at least 117.degree. F. (42.degree. C.) and a mass of water vapor of at least 3.8 mg of water per liter of dry air for at least 15 seconds. In an embodiment of the method the substrate is aerated in a moisture controlled atmosphere at room temperature for at least 30 minutes prior to exposing the substrate to ultraviolet light.

Abstract: Plastic surfaces are activated for the reception of adherent metal coatings by depositing noble metal nuclei thereon, the noble metal nuclei being deposited by a multistep process including the steps of mechanically roughening the surface, treating the roughened surface with a complex-former solution, thereafter treating the surface with a solution of a noble metal complex salt so as to exchange the noble metal complex for the complex deposited by the initial complex-former solution, and converting the noble metal complex to form metal nuclei.

Abstract: A composition for catalyzing a substrate prior to electroless metal deposition. The catalyst formulation comprises the admixture of a principal catalytic agent and a catalytic promoting agent. The principal catalytic agent is selected preferably from the metals of Period 4 and Groups IB and VIII of the Periodic Table of the Elements while the catalytic promoting agents are selected from metals of Period 4, 5, 6 and Groups IVB, VB, VIB, and VIIB of the Periodic Table of the Elements.

Abstract: An image forming material comprising a support having thereon a layer composed of a Ge-S composition or a Ge-S-X composition wherein X represents at least one element selected from the group consisting of Al, Si, Mg, Ti, V, Mn, Co, Ni, Sn, Zn, Pd, In, Se, Te, Fe, I, P and O which undergoes a structural change capable of being detected optically, electrically or chemically upon exposure imagewise to light wherein the Ge-S or Ge-S-X composition layer has a thickness of at least about 300 A and contains therein at least one element selected from the group consisting of Ag, Cu and Pb in an amount of more than 2 atoms of Ag, Cu and/or Pb based on 100 atoms of the Ge-S composition or the Ge-S-X composition.

Abstract: The method of depositing a metal on a surface especially suitable for the manufacture of printed circuit boards includes coating the surface with a sensitizing solution comprising an inaqueous solvent solution, a reducible salt of a non-noble metal, a salt of 2,7 anthraquinone disulfonic acid and a polyol type secondary reducing agent such as sorbitol. The coated surface is then dried and the dried surface may be stored for extended periods of time before further processing which consists of imaging the sensitized surface with ultraviolet light and electrolessly plating a metal over the imaged surface.

Abstract: A process for the preparation of metal patterns on insulating carriers by photochemical means, in particular for the preparation of printed circuits, is described, in which the carrier is treated with a photo-sensitizer in the absence of wetting agents; the carrier is irradiated in a manner corresponding to the desired pattern with a radiation source; the metal seeds formed on the surface are augmented with an aqueous palladium-salt solution; a nickel layer is deposited with a nickel or nickel-cobalt bath; the metal layer is treated with an aqueous solution containing a complex-forming agent for copper-(I) ions; and a copper layer is deposited with a currentless coppering bath.

Abstract: A composition for catalyzing a substrate prior to electroless metal deposition. The catalyst formulation comprises the admixture of a principal catalytic agent and a catalytic promoting agent. The principal catalytic agent is selected preferably from the metals of Period 4 and Groups IB and VIII of the Periodic Table of the Elements while the catalytic promoting agents are selected from metals of Period 4, 5, 6 and Groups IVB, VB, VIB, and VIIB of the Periodic Table of the Elements.

Abstract: Nonpolar, organic solvent-soluble tellurium compounds and complexes are disclosed. The compounds are tellurium(II) compounds and are represented by the formula:Te----CH.sub.2).sub.n SiRR'R"].sub.2wherein:n is an integer from 1 to 10 andR, R' and R" are independently selected from the group consisting of alkyl, aryl and neterocyclic radicals. Photosensitive complexes of these compounds with transition metals, as well as photographic elements having layers comprising these complexes, are also disclosed.

Abstract: Tellurium images are formed by the decomposition of tellurium (II) coordination complexes in the presence of a catalyst. The complexes are characterized in that at least one of the four coordination positions of the tellurium (II) is occupied by a sulfur containing ligand. Preferred ligands that can be coordinated with tellurium are sulfur containing bidentate anionic ligands. Complexes formed using these preferred ligands are more hydrolytically stable than other tellurium (II) complexes having sulfur containing ligands and yet are still capable of providing catalytic amplification.

Abstract: A method for producing visible images in certain charge sensitive, dry processable recording elements. Image recording is accomplished by flowing, in a resistive recording element containing a reducible metal compound, an imagewise pattern of electrical current of sufficient magnitude to produce therein a storable latent image. The metal compound in the latent image areas is subsequently reduced by a dry development technique to produce a visible image.

Abstract: An image forming material comprising a support having thereon a layer composed of a Ge--S composition or a Ge--S--X composition wherein X represents at least one element selected from the group consisting of Al, Si, Mg, Ti, V, Mn, Co, Ni, Sn, Zn, Pd, In, Se, Te, Fe, I, P and O which undergoes a structural change capable of being detected optically, electrically or chemically upon exposure imagewise to light wherein the Ge--S or Ge--S--X composition layer has a thickness of at least about 300A and contains therein at least one element selected from the group consisting of Ag, Cu and Pb in an amount of more than 2 atoms of Ag, Cu and/or Pb based on 100 atoms of the Ge--S composition or the Ge--S--X composition.

Abstract: Tellurium images are formed by the decomposition of tellurium (II) coordination complexes in the presence of a catalyst. The complexes are characterized in that at least one of the four coordination positions of the tellurium (II) is occupied by a sulfur containing ligand. Preferred ligands that can be coordinated with tellurium are sulfur containing bidentate anionic ligands. Complexes formed using these preferred ligands are more hydrolytically stable than other tellurium (II) complexes having sulfur containing ligands and yet are still capable of providing catalytic amplification.

Abstract: A method of depositing a metal on a surface is disclosed. The method comprises coating the surface with a sensitizing solution comprising at least a reducible salt of a non-noble metal. The coated surface is selectively treated to reduce the metal salt to metallic nuclei to form a catalytic pattern thereon capable of directly catalyzing the deposition of a metal on the nuclei from an electroless metal deposition solution. The selectively treated surface is then exposed to a stripping solution comprising an organic acid selected from (a) a carboxylic acid having a structural formula of ##STR1## where R is a member selected from the hydrogen radical, H, and an alkyl group having 1 to 3 carbon atoms, (b) citric acid and (c) a mixture of any of the foregoing acids, to essentially remove portions of the coated surface which have not been selectively treated.

Abstract: Copper physical development using certain heterocyclic ligand copper(I) complexes which are resistant to aerial oxidation is disclosed. The copper(I) complexes can be represented by the formulaL(CuX).sub.mwherein L is a monodentate or bidentate heterocyclic ligand, X is an anion and m is the integer 1 or 2. The described physical development compositions can operate in either the disproportionation mode, in which case the composition further comprises, in addition to the copper(I) complex, a ligand for copper(II); or in the reduction mode, in which case the composition further comprises a reducing agent and preferably a base. Generally, nuclei of metals from group VIII and IB of the periodic table are catalytic for the deposition of copper from these compositions. The nuclei can be imagewise formed by exposing an electromagnetic radiation sensitive compound. Physical development formulations, processes and elements are disclosed.