Stabilizing Patents (Class 430/428)
  • Patent number: 4546070
    Abstract: A method for processing a color photographic light-sensitive material comprising subjecting an exposed silver halide color photographic light-sensitive material to color development processing then to bleach processing and fixing processing separately, wherein a bath of the bleach processing contains (a) at least one bleach accelerating agent selected from a compound having a mercapto group or a disulfide bond, a thiazolidine derivative and an isothiourea derivative and (b) at least one compound represented by the following general formula (I-a) or (I-b): ##STR1## wherein M represents a hydrogen atom, an alkali metal atom or an ammonium ion; R represents a hydrogen atom, a substituted or unsubstituted alkyl group, --SO.sub.3 M.sup.1 or --COOM.sup.1 ; R.sup.1 represents --SO.sub.3 M.sup.1 or --COOM.sup.1 ; M.sup.1 represents a hydrogen atom, an alkali metal atom or an ammonium ion; and n represents an integer of 1 to 6 and when n is 2 or more, R's may be the same or different.
    Type: Grant
    Filed: December 10, 1984
    Date of Patent: October 8, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinzo Kishimoto, Shigeru Ohno, Akira Abe
  • Patent number: 4546071
    Abstract: A photographic image was produced by storing a geranium leaf in darkness and then projecting a light image on the leaf for a sufficient time to produce a suitable latent starch image, the leaf then being treated to extract the chlorophyll and then flooded with an iodine solution to stain the starch and develop the photographed image. Alternatively, instead of the leaf, a photographic medium may be employed including a film of a starch free, water, carbon dioxide and light permeable matrix, such as gelatin, having dispersed therein chloroplast containing algae or photosynthetic bacteria.
    Type: Grant
    Filed: June 30, 1983
    Date of Patent: October 8, 1985
    Inventor: David Fox
  • Patent number: 4543317
    Abstract: There is described a photographic system wherein development of an exposed photosensitive element with an aqueous alkaline processing composition is effected in the presence of a compound which is a salt of a radical of a substituted phenylmercaptoazole complexed with a radical of a quaternary. The salts are either insoluble or have extremely low solubility in water and become soluble, and photographically active, in alkaline environment.
    Type: Grant
    Filed: December 19, 1984
    Date of Patent: September 24, 1985
    Assignee: Polaroid Corporation
    Inventors: Avinash C. Mehta, Lloyd D. Taylor
  • Patent number: 4530898
    Abstract: Photographic film units and processes are disclosed which provide a negative image, wherein exposed silver is developed to high covering power silver and unexposed silver halide is reduced to low covering power silver.
    Type: Grant
    Filed: February 29, 1984
    Date of Patent: July 23, 1985
    Assignee: Polaroid Corporation
    Inventor: Arnold Spiegal
  • Patent number: 4520096
    Abstract: A photographic element for a silver salt diffusion transfer process is described, comprising a silver halide light-sensitive element, an image receiving element and a processing element, the improvement wherein said photographic element contains a compound represented by formula (I) or (II) ##STR1## wherein the R.sub.
    Type: Grant
    Filed: June 13, 1984
    Date of Patent: May 28, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Katsusuke Endo, Yoshio Inagaki
  • Patent number: 4510221
    Abstract: A method for producing a phase hologram having a high diffraction efficiency which includes treating a developed photographic material with a stop bath containing sodium sulfate, bleaching with a tanning bleach having a low pH value and fixing the bleached material in a bath containing sodium thiosulfate.
    Type: Grant
    Filed: August 1, 1983
    Date of Patent: April 9, 1985
    Assignee: NCR Corporation
    Inventors: Brian A. Gorin, Ping-Pei Ho
  • Patent number: 4500632
    Abstract: A process for stabilizing a silver image is disclosed. The process is utilized in connection with a photographic material which is comprised of a water impermeable support having one or more light-sensitive silver halide emulsion layers thereon. After the photographic material is exposed and developed it is subjected to further processing by conventional means. However, within the further processing an aqueous solution is utilized which includes any compounds represented by the general formula (I), (II) or (III) as defined within the specification. The compound(s) represented by the general formula is/are generally present within the processing solution in a total amount of about 0.1 to 10 g/l of processing solution. By utilizing the aqueous solution containing the compound represented by the general formula within the processing, it is possible to greatly increase the stability of the silver image formed.
    Type: Grant
    Filed: March 5, 1984
    Date of Patent: February 19, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kunioki Ohmura, Masaaki Torigoe, Isamu Itoh, Katsumi Hayashi
  • Patent number: 4481290
    Abstract: A color photographic silver halide light-sensitive material is described, containing at least one member of the compounds represented by the general formula (I-a) and (I-b) in at least one layer thereof: ##STR1## (wherein all the symbols are defined in the appended claims). This color light-sensitive material can be subjected to rapid photographic processing; i.e., the compounds of the general formula (I-a) and (I-b) act as bleach accelerators, making it possible to perform rapid photographic processing without exerting adverse influences on photographic characteristics.
    Type: Grant
    Filed: March 29, 1983
    Date of Patent: November 6, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinzo Kishimoto, Kiyohiko Yamamuro
  • Patent number: 4467027
    Abstract: A developer composition of an alkaline aqueous solution containing a reducing inorganic salt, typically an alkali metal salt of sulfurous acid such as sodium sulfite, is found to be applicable for development of a lithographic printing plate material containing a photosensitive o-quinonediazide compound and an organic polymer, with reduced deterioration in developing capacity caused by the air and enhanced stability with lapse of time. In particular, a developer composition composed of an alkaline aqueous solution of pH 11 or higher containing a water-soluble sulfurous acid salt is effective for developing both of a lithographic printing plate material having a nega-type photosensitive layer containing a photosensitive diazo compound and an organic polymer, and a lithographic printing plate material having a posi-type photosensitive layer containing an o-quinonediazide compound and an organic polymer.
    Type: Grant
    Filed: May 20, 1982
    Date of Patent: August 21, 1984
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Takeshi Yamamoto, Kiyoshi Goto, Yoshio Kurita, Noriyasu Kita, Naoshi Kunieda
  • Patent number: 4410618
    Abstract: .alpha.-Ketoimidomethyl blocked photographic reagents are useful in photographic elements, film units and processes. The blocked photographic reagents have the structure: ##STR1## wherein J represents ##STR2## X represents the atoms to complete a 5- or 6-membered ring or ring system; R represents alkyl of 1 to 30 carbon atoms or aryl of 6 to 30 carbon atoms; andPR represents the residue of an organic photographic reagent containing a heteroatom through which it is joined to the blocking group.
    Type: Grant
    Filed: June 11, 1982
    Date of Patent: October 18, 1983
    Assignee: Eastman Kodak Company
    Inventors: James P. Vanmeter, Chin H. Chen
  • Patent number: 4404390
    Abstract: Mesoionic 1,2,4-triazolium-3-thiolate silver halide stabilizer precursors are novel compounds useful in a heat developable and heat stabilizable photographic silver halide materials and processes. After imagewise exposure of the photographic material, a developed and stabilized silver image is produced by heating the element. Mesoionic stabilizer precursors are also useful in photographic silver halide processing compositions.
    Type: Grant
    Filed: November 9, 1981
    Date of Patent: September 13, 1983
    Assignee: Eastman Kodak Company
    Inventors: Henry W. Altland, Daniel D. Shiao
  • Patent number: 4388398
    Abstract: This invention relates to photographic products and processes employing silver halide solvent precursors of the formula ##STR1## wherein R.sup.1 is a monovalent organic radical; R.sup.2 is hydrogen or a monovalent organic radical; Z is a moiety that undergoes .beta.-elimination in aqueous alkaline solution and preferably is a moiety that undergoes .beta.-elimination in aqueous alkaline solution to release a photographically useful reagent; and n is an integer 3, 4 or 5.
    Type: Grant
    Filed: March 23, 1982
    Date of Patent: June 14, 1983
    Assignee: Polaroid Corporation
    Inventors: Alan L. Borror, Ernest W. Ellis
  • Patent number: 4382119
    Abstract: This invention relates to photographic products and processes employing silver halide solvent precursors of the formulae ##STR1## wherein R.sup.1 and R.sup.2, the same or different, each are hydrogen, alkyl, phenalkyl, phenyl or phenyl substituted with an electron-donating or electron-withdrawing group; R.sup.3 is alkyl, phenalkyl, phenyl or substituted phenyl; Z is --CN or --SO.sub.2 R.sup.4 wherein R.sup.4 is branched-chain alkyl, phenalkyl, phenyl or substituted phenyl; and n is an integer 3, 4 or 5.
    Type: Grant
    Filed: May 27, 1982
    Date of Patent: May 3, 1983
    Assignee: Polaroid Corporation
    Inventors: Alan L. Borror, Ernest W. Ellis
  • Patent number: 4367279
    Abstract: Certain organic, carbon acid silver halide complexing agents in a photographic diffusion transfer system provide suitable replacement for conventional silver halide complexing agents. Such organic, silver halide complexing agents include certain sulfones, nitriles and onium salts. These are especially useful in a silver salt diffusion transfer system. They can be employed with silver halide developing agents, such as in a monobath, and are especially suitable with a hydroxylamine silver halide developing agent. Other addenda commonly employed in photographic diffusion transfer systems can be employed in combination with these silver halide complexing agents.
    Type: Grant
    Filed: September 6, 1974
    Date of Patent: January 4, 1983
    Assignee: Eastman Kodak Company
    Inventors: Arthur H. Herz, Daniel S. Daniel
  • Patent number: 4353976
    Abstract: There are described photographic products, processes and compositions wherein cyclic crown ether ligands are utilized as silver halide solvents. Also disclosed are novel cyclic crown ether ligands.
    Type: Grant
    Filed: October 30, 1980
    Date of Patent: October 12, 1982
    Assignee: Polaroid Corporation
    Inventors: Stanley M. Bloom, deceased, Krishna G. Sachdev
  • Patent number: 4351896
    Abstract: Mesoionic 1,2,4-triazolium-3-thiolate silver halide stabilizer precursors are novel compounds useful in a heat developable and heat stabilizable photographic silver halide materials and processes. After imagewise exposure of the photographic material, a developed and stabilized silver image is produced by heating the element. Mesoionic stabilizer precursors are also useful in photographic silver halide processing compositions.
    Type: Grant
    Filed: November 9, 1981
    Date of Patent: September 28, 1982
    Assignee: Eastman Kodak Company
    Inventors: Henry W. Altland, Daniel D. Shiao
  • Patent number: 4346154
    Abstract: A stain retarding concentration of a phosphine antistain agent or phosphine antistain agent precursor in the undercoat layer of a photographic silver halide element comprising a support having thereon (a) a photographic silver halide gelatino emulsion layer, and (b) an undercoat layer between the emulsion layer and the support, provides reduced stain in the element upon exposure and processing. The photographic element preferably comprises a silver halide developing agent. The photographic element, after exposure, is preferably processed by means of an aqueous alkaline activator bath and then an aqueous thiosulfate stabilizer bath.
    Type: Grant
    Filed: June 22, 1981
    Date of Patent: August 24, 1982
    Assignee: Eastman Kodak Company
    Inventors: Donald F. McLaen, Arthur H. Herz
  • Patent number: 4345018
    Abstract: Alkanes containing an intralinear sulfonyl group and a cyano group separated by a single carbon substituted with at least one hydrogen atom are employed as silver halide solvents in photographic processes and compositions.
    Type: Grant
    Filed: November 1, 1976
    Date of Patent: August 17, 1982
    Assignee: Polaroid Corporation
    Inventors: Alan L. Borror, Richard B. Greenwald
  • Patent number: 4343893
    Abstract: Novel nitrobenzyl compounds are incorporated into a photographic emulsion or developer for controlled release of development/image modifier compounds. This occurs imagewise only after developer oxidation products have been formed in the course of the development process. For example, nitrobenzyl-masked phenylmercaptotetrazole (PMT), incorporated into a silver halide emulsion, reacts with developer oxidation products via an electron transfer mechanism to release the potent development restrainer PMT.
    Type: Grant
    Filed: July 25, 1980
    Date of Patent: August 10, 1982
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Dennis S. Donald, Ross A. Lee
  • Patent number: 4326021
    Abstract: Photographic negative material which has at least one layer which contains a desensitized silver halide emulsion, the desensitizer used being a trinuclear heptamethinecyanine or a halogenated trinuclear tetramethinecyanine which has three identical heterocyclic ring systems, which can have different substituents and are linked to one another by three identical methine systems, which can be mesomeric, is suitable for processing in subdued daylight but nevertheless has an adequate sensitivity on exposure to intense light.
    Type: Grant
    Filed: February 11, 1981
    Date of Patent: April 20, 1982
    Assignee: Ciba Geigy AG
    Inventors: Rolf Steiger, Jean-Francois Reber
  • Patent number: 4310613
    Abstract: A liquid processing composition for silver complex diffusion transfer process which contains the specific quaternary ammonium salts as defined in the specification prevents formation of colored sludge for a long time without damaging characteristics of silver complex diffusion transfer development and improves color tone of silver images obtained.
    Type: Grant
    Filed: May 14, 1980
    Date of Patent: January 12, 1982
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Shigeru Iguchi, Kazuhiro Emoto
  • Patent number: 4279983
    Abstract: A novel photographic film unit, preferably a diffusion transfer film unit adapted to provide silver images of enhanced image stability which comprises photosensitive silver halide, silver precipitating nuclei and a stabilizing compound consisting of a noble metal complexed with a ligand, said ligand being adapted to hydrolyze in aqueous alkali to provide a diffusible complex of said noble metal.
    Type: Grant
    Filed: April 24, 1980
    Date of Patent: July 21, 1981
    Assignee: Polaroid Corporation
    Inventors: Ruth C. Bilofsky, Mara O. Nestle
  • Patent number: 4272632
    Abstract: There are described novel acyclic silver complexing agents which are useful as silver halide solvents in photographic products, processes and compositions. Also disclosed are photographic compositions, products and processes in which the complexing agents are utilized.
    Type: Grant
    Filed: June 16, 1980
    Date of Patent: June 9, 1981
    Assignee: Polaroid Corporation
    Inventors: Krishna G. Sachdev, Stanley M. Bloom, deceased
  • Patent number: 4267254
    Abstract: There is described a photograhic method employing a positive-negative diffusion transfer film unit wherein there is formed a positive silver transfer image which may be viewed as a positive transparency without being separated from the developed negative silver image, including an embodiment wherein additive color projection positive images are formed. According to the method, the exposed film unit is developed by contacting the silver halide emulsion layer with a photographic processing composition which comprises an aqueous alkaline solution containing a silver halide developing agent and a silver complexing agent. The silver complexing agent is stable in an alkaline environment, has a melting point less than about 50.degree. C. preferably about 25.degree. C. or less, and the log of the stability constant (.beta.) for a 1:1 complex of the complexing agent with silver is at least about 10.5. The film unit is not washed during the method.
    Type: Grant
    Filed: October 1, 1979
    Date of Patent: May 12, 1981
    Assignee: Polaroid Corporation
    Inventors: Stanley M. Bloom, deceased, Krishna G. Sachdev
  • Patent number: 4267256
    Abstract: There are described photographic products, processes and compositions wherein cyclic crown ether ligands are utilized as silver halide solvents. Also disclosed are novel cyclic crown ether ligands.
    Type: Grant
    Filed: October 1, 1979
    Date of Patent: May 12, 1981
    Assignee: Polaroid Corporation
    Inventors: Stanley M. Bloom, deceased, Krishna G. Sachdev
  • Patent number: 4260674
    Abstract: A photographic material for the production of an image in a dry process by forming a vesicle image upon the decomposition of a peroxide compound at image nuclei of silver by providing a layer containing a silver salt which forms upon exposure to light, in imagewise distribution, image nuclei. The silver salt has a grain size of less than 0.3 .mu.m and is present in the layer in an amount of from 1-500 mg/m.sup.2.
    Type: Grant
    Filed: December 14, 1979
    Date of Patent: April 7, 1981
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Edith Weyde, Anita von Konig, Werner Liebe
  • Patent number: 4251617
    Abstract: There are described novel acyclic silver complexing agents which are useful as silver halide solvents in photographic products, processes and compositions. Also disclosed are photographic compositions, products and processes in which the complexing agents are utilized.
    Type: Grant
    Filed: October 1, 1979
    Date of Patent: February 17, 1981
    Assignee: Polaroid Corporation
    Inventors: Stanley M. Bloom, deceased, Krishna G. Sachdev
  • Patent number: 4237212
    Abstract: An image-forming agent selected from polyacids of molybdenum and tungsten and salts and complexes of these polyacids and disposed as a layer on at least one surface of a support substrate is reduced thereby being caused to undergo coloring in the form of an image and is then irradiated over its entire surface including thus colored parts and yet uncolored parts with long wavelength light rays which are absorbable by only the colored parts thereby to produce a colored image wherein the optical density of only the colored parts is selectively increased to a remarkable degree.
    Type: Grant
    Filed: February 13, 1979
    Date of Patent: December 2, 1980
    Assignee: Dai Nippon Insatu Kabushiki Kaisha
    Inventors: Eiichi Inoue, Misturu Takeda, Fumio Shimada
  • Patent number: 4235957
    Abstract: In a dry physical development photothermographic element for a dry thermal silver-dye bleach process wherein the element comprises a silver halide complexing concentration of a silver halide complexing agent improvements are provided when the complexing agent is an organic ammonium chloride, bromide or iodide. After imagewise exposure of the element, a dye image can be produced by uniformly heating the element. Improvements are also produced by providing a dry activator element for producing a dye image in a separate photographic element by means of a dry physical development thermal dye-bleach process, wherein the activator element comprises a support having thereon a layer comprising a synthetic hydrophobic polymeric binder, a silver halide complexing concentration of a silver halide complexing agent, as described, a bleachable dye and a thermal solvent.
    Type: Grant
    Filed: January 25, 1979
    Date of Patent: November 25, 1980
    Assignee: Eastman Kodak Company
    Inventors: Carl F. Kohrt, Roland G. Willis
  • Patent number: 4217405
    Abstract: Volume dielectric holograms are prepared by methods which have in common the intra-emulsion diffusion transfer of silver atoms within the emulsion by a process of dissolving undeveloped silver halide, and diffusing and precipitating said dissolved silver on precipitation sites provided by the development of the exposed silver halide. The resulting metallic silver is then rehalogenated to substantially reconstitute the original silver halide volume of the emulsion.
    Type: Grant
    Filed: October 14, 1975
    Date of Patent: August 12, 1980
    Assignee: Polaroid Corporation
    Inventor: Stephen A. Benton
  • Patent number: 4211559
    Abstract: Difunctional compounds wherein one of said functions is a hard or soft atom that ionizes to the corresponding anion in alkaline solution to combine with silver cation and the other of said functions is a non-ionizable soft base that additionally combines with said silver cation are employed as silver halide complexing agents in photography. In a preferred embodiment, the difunctional compounds possess (a) an O, N or C atom that ionizes to the corresponding O.crclbar., N.crclbar. or C.crclbar. anion in basic solution and (b) an --S-- containing moiety excluding --SH and moieties that form --S.crclbar. in basic solution wherein the --S-- of said moiety is positioned alpha, beta, gamma, delta, epsilon or zeta to said anion.
    Type: Grant
    Filed: August 4, 1978
    Date of Patent: July 8, 1980
    Assignee: Texas Instruments Incorporated
    Inventor: Richard B. Greenwald