Using Polymer Or Condensation Reaction Product Patents (Class 430/444)
  • Patent number: 7566688
    Abstract: The invention provides a soil release agent and a detergent composition blended therewith. The invention relates to a crosslinked product obtained by reacting a compound having 2 to 32 hydroxyl groups, such as triethanol amine, with a compound having at least two functional groups reacting with hydroxyl groups, such as (poly)ethylene glycol diglycidyl ether, a soil release agent containing the crosslinked product, and a detergent composition containing the soil release agent.
    Type: Grant
    Filed: December 9, 2003
    Date of Patent: July 28, 2009
    Assignee: Kao Corporation
    Inventors: Atsushi Tanaka, Satoru Kijima, Makoto Kubo
  • Patent number: 7118836
    Abstract: A substantially transparent conductive layer on a support, the layer comprising an intrinsically conductive polymer e.g. containing an intrinsically conductive polymer optionally containing structural units represented by formula (I): wherein n is larger than 1 and each of R1 and R2 independently represents hydrogen or an optionally substituted C1-4 alkyl group or together represent an optionally substituted C1-4 alkylene group or an optionally substituted cycloalkylene group, preferably an ethylene group, an optionally alkyl-substituted methylene group, an optionally C1-12 alkyl- or phenyl-substituted ethylene group, a 1,3-propylene group or a 1,2-cyclohexylene group; and a conductive metal non-uniformly distributed therein and forming of itself a conductive entity; a process for preparing the transparently conductive layer; and light emitting diodes, photovoltaic devices, transistors and electroluminescent devices comprising the above-described conductive layer.
    Type: Grant
    Filed: August 19, 2003
    Date of Patent: October 10, 2006
    Assignee: Agfa Gevaert
    Inventor: Hieronymus Andriessen
  • Publication number: 20040048205
    Abstract: Concentrated and working strength photographic color developing compositions are stabilized with the inclusion of two specific types of calcium ion sequestering agents. One of the sequestering agents is a polyelectrolyte such as a polycarboxylic acid or salt thereof having a molecular weight of from about 2000 to about 100,000. The other one is a non-polymeric aminocarboxylic acid, polyphosphonic acid, or a salt thereof. The weight ratio of the first calcium ion sequestering agent to the second calcium ion sequestering agent is from about 1:1 to about 20:1. These compositions can be used to process color photographic materials such as color photographic papers.
    Type: Application
    Filed: August 12, 2003
    Publication date: March 11, 2004
    Inventors: Shirleyanne E. Haye, Janet M. Huston
  • Publication number: 20040023169
    Abstract: A silver halide photographic processing solution comprising at least one polymeric compound inhibiting sludge formation and preventing “pi-line” artefact, more particularly in radiographic non-destructive testing applications, wherein said polymeric compound comprises at least one monomer unit having a silver complexing moiety and at least one monomer unit having a solubilizing group, and wherein both said silver ion complexing moiety and said solubilizing group are comprised in same or different monomer units.
    Type: Application
    Filed: July 11, 2003
    Publication date: February 5, 2004
    Inventors: Johan Loccufier, Frank Louwet, Andre Roefs
  • Patent number: 6649331
    Abstract: Rapid development of silver bromoiodide color negative photographic films and formation of high quality negative images suitable for scanning to produce display images of excellent quality is made possible by a novel developer solution composition and method of development. The solution is characterized by containing, in addition to the color developer compound and conventional photographic developer solution components, a water soluble pyrrolidone polymer, a high concentration of sulfite ion and a low concentration, or the absence of, bromide ion. In the novel method the developer composition contacts the exposed film at elevated temperature, e.g., 40 to 66° C., for a short development time, e.g., 20 to 90 seconds. The developed image has image quality suitable for scanning and digital manipulation to produce a digital record for forming a color display image of high quality.
    Type: Grant
    Filed: May 20, 2002
    Date of Patent: November 18, 2003
    Assignee: Eastman Kodak Company
    Inventors: Robert A. Arcus, Peter N. Bacel, John A. Weldy
  • Publication number: 20030108826
    Abstract: An antifoaming agent composition for a silver halide photographic processing solution, which comprises at least one of the specified (polyoxyethylene/polyoxypropylene) copolymer as a surface active agent.
    Type: Application
    Filed: March 14, 2002
    Publication date: June 12, 2003
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventor: Akimitsu Haijima
  • Publication number: 20030082490
    Abstract: Rapid development of silver bromoiodide color negative photographic films and formation of high quality negative images suitable for scanning to produce display images of excellent quality is made possible by a novel developer solution composition and method of development. The solution is characterized by containing, in addition to the color developer compound and conventional photographic developer solution components, a water soluble pyrrolidone polymer, a high concentration of sulfite ion and a low concentration, or the absence of, bromide ion. In the novel method the developer composition contacts the exposed film at elevated temperature, e.g., 40 to 66° C., for a short development time, e.g., 20 to 90 seconds. The developed image has image quality suitable for scanning and digital manipulation to produce a digital record for forming a color display image of high quality.
    Type: Application
    Filed: May 20, 2002
    Publication date: May 1, 2003
    Inventors: Robert A. Arcus, Peter N. Bacel, John A. Weldy
  • Patent number: 6479198
    Abstract: A silver halide light-sensitive material comprises a support and a silver halide gelatin emulsion layer. The silver halide gelatin emulsion layer or an optionally provided hydrophilic layer contains a tanning developing agent. According to the first embodiment of the present invention, the tanning developing agent has a molecular structure in which two to six benzenediol or benzenetriol rings are connected with a linking group. According to the second embodiment of the invention, the tanning developing agent consists of a polymer having side chains containing benzenediol or benzenetriol rings. According to the third embodiment of the invention, the tanning developing agent consists of a benzenediol or benzenetriol ring having an aliphatic substituent group having 5 to 40 carbon atoms or an aromatic substituent group having 7 to 40 carbon atoms. A tanning developing solution and a lithographic printing plate are also disclosed.
    Type: Grant
    Filed: February 1, 2001
    Date of Patent: November 12, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naonori Makino, Kaku Sakata
  • Patent number: 6436617
    Abstract: The present invention relates to photographic elements having a protective overcoat that resists fingerprints, common stains, and spills. The overcoat comprises an epoxy material, an acid polymer, a water-soluble hydrophilic binder and an associative thickener. In one embodiment, a photographic element includes a support, at least one silver halide emulsion layer superposed on the support and a processing-solution-permeable overcoat overlying the silver halide emulsion layer that becomes water-resistant in the final product without requiring lamination or fusing. The present invention is also directed to a method of making a print involving developing the photographic element.
    Type: Grant
    Filed: October 30, 2000
    Date of Patent: August 20, 2002
    Assignee: Eastman Kodak Company
    Inventors: Yongcai Wang, Kevin M. O'Connor, Melvin M. Kestner, James L. Bello
  • Patent number: 6376160
    Abstract: The present invention relates to photographic elements having a protective overcoat that resists fingerprints, common stains, and spills. The overcoat comprises an epoxy material, an acid polymer, and a water-soluble hydrophilic binder. In one embodiment, a photographic element includes a support, at least one silver halide emulsion layer superposed on the support and a processing-solution-permeable overcoat overlying the silver halide emulsion layer that becomes water-resistant in the final product without requiring lamination or fusing. The present invention is also directed to a method of making a print involving developing the photographic element.
    Type: Grant
    Filed: October 30, 2000
    Date of Patent: April 23, 2002
    Assignee: Eastman Kodak Company
    Inventors: Yongcai Wang, Kevin M. O'Connor, Melvin M. Kestner, James L. Bello
  • Patent number: 6190843
    Abstract: The present invention relates to imaging elements, including photographic elements and recording media, having a protective overcoat that resists fingerprints, common stains, and spills. More particularly, the present invention provides a processing-solution-permeable protective overcoat that is water resistant in the final processed product. The overcoat, before formation of the image, comprises hydrophobic polymeric particles in a gelatin matrix. Subsequent treatment of the overcoat, after formation of the image, to remove the gelatin, causes coalescence of the hydrophobic particles, resulting in the formation of a water-resistant continuous protective overcoat.
    Type: Grant
    Filed: April 11, 2000
    Date of Patent: February 20, 2001
    Assignee: Eastman Kodak Company
    Inventors: Hwei-Ling Yau, Thomas H. Whitesides, Elmer C. Flood, Amy E. Jasek
  • Patent number: 6187518
    Abstract: The present invention is a photographic element which includes a support, at least one silver halide emulsion superposed on a front side of the support and an outermost backing layer superposed on a backside of the support. The outermost backing layer is composed of a hydrophobic binder and a hydrophilic binder wherein the backing layer has an advancing water contact angle of 70 or greater and a receding water contact angle of at least 40 less than the advancing water contact angle.
    Type: Grant
    Filed: October 23, 1998
    Date of Patent: February 13, 2001
    Assignee: Eastman Kodak Company
    Inventors: Raymond T. Jones, Ravi Sharma, Alfred B. Fant
  • Patent number: 6100016
    Abstract: The invention relates to a developer for irradiated, radiation-sensitive recording materials, in particular for the production of offset printing plates, which contains water, a compound which is alkaline in aqueous solution and a copolymer which acts as an emulsifier and has units of (I) a hydrophobic vinyl compound which has at least one optionally substituted mono- or bicyclic (C.sub.6 -C.sub.14)aryl radical and (II) a hydrophilic, ethylenically unsaturated carboxylic acid. Some of the carboxyl groups of the copolymer are esterified with reaction products of (A) (C.sub.1 -C.sub.30)alkanols, (C.sub.8 -C.sub.25)alkanoic acids, (C.sub.1 -C.sub.12)-alkylphenols or di(C.sub.1 -C.sub.20)alkylamines with (B) (C.sub.2 -C.sub.4)-alkylene oxides or tetrahydrofuran, the molar ratio (A):(B) being in the range from 1:2 to 1:50. If it is intended to develop recording materials having a negative-working layer, the developer additionally contains a water-miscible organic solvent and a surface-active compound.
    Type: Grant
    Filed: September 14, 1999
    Date of Patent: August 8, 2000
    Assignee: Agfa-Gevaert AG
    Inventors: Steffen Denzinger, Michael Doerr, Klaus-Peter Konrad, Andreas Elsaesser, Paul Eckler
  • Patent number: 6096488
    Abstract: Processing a silver halide color photographic material comprising color developing, desilvering and water washing and/or stabilizing. In this process, a photographic material which has at least one emulsion layer containing a high silver chloride content, and at least one emulsion layer containing a monodisperse emulsion, is continuously processed with a color developing solution containing a water-soluble high polymer compound. The coated amount of silver in the photographic material is preferably 0.75 g/m.sup.2 or less. The color developing solution preferably has a chloride ion content of 0.035 mol/l or more. The water soluble high polymer compound can be a polyester, polyamide, polyurethane, polyether, polycarbonate or a natural high polymer compound, or their derivatives. It is obtained by polymerizing or copolymerizing a monomer containing a copolymerizable ethylene type unsaturated group. The high polymer compound is preferably added in the amount of 0.
    Type: Grant
    Filed: May 5, 1999
    Date of Patent: August 1, 2000
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takatoshi Ishikawa, Kazuaki Yoshida, Hiroshi Fujimoto, Junichi Yamanouchi, Tomokazu Yasuda
  • Patent number: 6096485
    Abstract: A desensitizing solution for lithographic printing is disclosed, which comprises at least one organometallic polymer containing at least two partial structure units represented by the following formula (1): ##STR1## wherein R.sup.0 represents --PO.sub.3 H.sub.2, --OPO.sub.3 H.sub.2 or a salt thereof.
    Type: Grant
    Filed: October 18, 1999
    Date of Patent: August 1, 2000
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seishi Kasai, Ryousuke Itakura, Eiichi Kato
  • Patent number: 5972572
    Abstract: A developer for irradiated, radiation-sensitive recording materials, in particular for the production of offset printing plates, which contains water, a compound which is alkaline in aqueous solution and a copolymer which acts as an emulsifier and has units of (I) a hydrophobic vinyl compound which has alkyl radicals having up to 30 carbon atoms and (II) a hydrophilic, ethylenically unsaturated carboxylic acid. Some of the carboxyl groups of the copolymer are esterified with reaction products of (A) (C.sub.1 -C.sub.30)alkanols, (C.sub.8 -C.sub.25)alkanoic acids, (C.sub.1 -C.sub.12)alkylphenols or di(C.sub.1 -C.sub.20)alkylamines with (B) (C.sub.2 -C.sub.4)alkylene oxides or tetrahydrofuran.
    Type: Grant
    Filed: November 3, 1998
    Date of Patent: October 26, 1999
    Assignee: Agfa-Gevaert AG
    Inventors: Klaus Peter Konrad, Steffen Denzinger, Andreas Elsaesser
  • Patent number: 5853926
    Abstract: The present invention is an imaged photographic element having a protective overcoat thereon. The protective overcoat is formed by providing a photographic element having at least one silver halide light-sensitive emulsion layer; and applying an aqueous coating comprising polymer particles having an average size of 0.1 to 50 microns at a weight percent of 5 to 50 percent, a soft polymer latex binder at a weight percent of 1 to 3 percent, over the at least one silver halide light-sensitive emulsion layer. The silver halide light sensitive emulsion layer is developed to provide an imaged photographic element. The hydrophobic polymer particles is fused to form a protective overcoat.
    Type: Grant
    Filed: July 23, 1997
    Date of Patent: December 29, 1998
    Assignee: Eastman Kodak Company
    Inventors: Anne E. Bohan, Vito A. DePalma, William K. Goebel, Amy E. Jasek, Thomas H. Whitesides
  • Patent number: 5821037
    Abstract: A redox developer-amplifier composition contains a color developing agent and a redox oxidizing agent. The composition also contains a stabilizing amount of Zn.sup.++ or Mg.sup.++ ions, and thus has improved stability.
    Type: Grant
    Filed: March 13, 1997
    Date of Patent: October 13, 1998
    Assignee: Eastman Kodak Company
    Inventors: Peter J. Twist, Christopher J. Winscom
  • Patent number: 5800974
    Abstract: A black and white photographic element comprising as a photosensitive medium a layer of a silver halide emulsion characterised in that the photosensitive medium comprises in the same layer or in an adjacent layer thereto a developer comprising a substantially non-diffusing polymeric compound having as a component part of its structure a plurality of units having a nucleus of general formula (I): ##STR1## wherein; each Z independently is a member selected from the group consisting of --OH and a group which leaves an --OH residue when contacted with an alkali (pH .gtoreq.10) at temperatures of .ltoreq.50.degree. C.
    Type: Grant
    Filed: September 8, 1992
    Date of Patent: September 1, 1998
    Assignee: Imation Corp.
    Inventors: Julian Wallis, Kevin P. Hall, Stephen Newman, Dian Elizabeth Stevenson
  • Patent number: 5789143
    Abstract: This invention relates to a silver halide color photographic element comprising a support, a silver halide emulsion and poly(thioether)s wherein greater than 50 percent of the poly(thioether)s have acidic functional end groups with an aqueous pKa.ltoreq.10, or end groups which will react to form acidic functional end groups with an aqueous pKa.ltoreq.10 during development, on both termini and wherein the poly(thioether)s have a molecular weight greater than 800.
    Type: Grant
    Filed: April 30, 1997
    Date of Patent: August 4, 1998
    Assignee: Eastman Kodak Company
    Inventors: George J. Burgmaier, David A. Dickinson, Robert A. Guistina
  • Patent number: 5763148
    Abstract: A silver halide photographic activation material is disclosed comprising a film support, on one or both sides thereof at least one gelatino silver halide emulsion layer and between said emulsion layer and said support a hydrophilic undercoat layer comprising as a binder at least 50% of a loaded latex polymer, said latex polymer being loaded with at least one developing agent, further characterised in that water absorption during activation processing is not higher than 2.5 g per gram of binder present in said material.
    Type: Grant
    Filed: July 17, 1996
    Date of Patent: June 9, 1998
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Peter Willems, Freddy Henderickx, Marcel Monbaliu
  • Patent number: 5660973
    Abstract: A developing machine having a high durability at a high temperature even in the presence of a high concentration of the developing agent is provided. The developing machine has means for keeping the temperature of a color developer having a concentration of an aromatic primary amine developing agent of 0.15 to 0.50 mol/l in the range of 40.degree. to 50.degree. C., and the material for at least one of the developing tanks and the racks is a resin selected from the group consisting of polyphenylene sulfide resin, polyphenylene oxide resin, polymethylpentene resin, polyether ether ketone resin, polyalkylene terephthalate resin, polyether imide resin, polyether sulfone resin and polysulfone resin.
    Type: Grant
    Filed: March 15, 1995
    Date of Patent: August 26, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takatoshi Ishikawa, Fumio Mogi
  • Patent number: 5518868
    Abstract: To eliminate the "pi-line" artefact after processing a silver halide industrial photographic X-ray material is disclosed comprising on at least one side of a support, at least one gelatino silver halide emulsion layer and a total amount of silver halide, corresponding to from 6 to 20 g of silver nitrate per square meter and per side, and at least one non-sensitive protective antistress coating, wherein said photographic material comprises at least one vinyl sulphone compound as a hardening agent and at least one polyoxyalkylene compound as a surfactant in at least one of its hydrophilic layers.
    Type: Grant
    Filed: August 8, 1995
    Date of Patent: May 21, 1996
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Raymond Florens, Pieter Perdieus, Andre Roefs
  • Patent number: 5466565
    Abstract: Color development composition and process. The compositions of this invention contain a color developer containing poly(N-hydroxyl alkyleneimine) and/or a derivative thereof, which are represented by general formula (I) shown below: ##STR1## wherein: "R" in said formula (I) represents an alkylene group, which may be substituted by a hydroxyl group, a carboxyl group, a sulfo group or other similar groups and may contain carbonyl linkage, ether linkage, double bond or other similar bond or linkage, and may also have a cyclic structure;" and ".sub.n " in said formula (I) represents an integer in the range from 10 to 10,000. These compositions are used for processing silver halide-type color sensitized material. These compositions maintain the usable life of a color developer, do not cause decrease of color density or deterioration of quality of photographs such as fogging, and have no odor or deleterious substance.
    Type: Grant
    Filed: March 18, 1994
    Date of Patent: November 14, 1995
    Assignee: Chugai Phote Chemical Co., Ltd.
    Inventors: Nobuki Shigemori, Hisao Kamo
  • Patent number: 5462831
    Abstract: To eliminate the "pi-line" artifact after processing a method of image formation is disclosed in a silver halide industrial X-ray photographic material, comprising on at least one side of a support, at least one gelatin silver halide emulsion layer and a total amount of silver halide, corresponding to from 6 to 20 g of silver nitrate per square meter and per side, and at least one non-sensitive protective antistress coating, wherein said material further comprises a hardening agent different from a vinyl sulphone compound, preferably formaldehyde, and at least one polyoxyalkylene compound as a surfactant in at least one of its hydrophilic layers, and wherein after exposure to direct X-rays said material is subjected in an automatic processing machine to the steps of developing in a developer comprising at least one anionic alkylphenoxy polyalkyleneoxy phosphate ester surfactant, fixing in a fixer which may comprise at least one alpha-ketocarboxylic acid, rinsing and drying.
    Type: Grant
    Filed: April 5, 1994
    Date of Patent: October 31, 1995
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Benedictus Jansen, Andre Roefs, Francis Sels, Pieter Perdieus, Raymond Florens
  • Patent number: 5411842
    Abstract: A method for making a photographic silver halide developer composition, preferably immediately before use, by electrolysing an aqueous medium containing a developing agent precursor composition which forms or releases a silver halide developing agent at an electrode upon electrolysis.
    Type: Grant
    Filed: April 7, 1994
    Date of Patent: May 2, 1995
    Assignee: Eastman Kodak Company
    Inventors: Michael Ridgway, Nigel E. Milner, Siu C. Tsoi, Paul C. Ward
  • Patent number: 5376509
    Abstract: A processing chemical for light-sensitive silver halide photographic material, comprising a cyclodextrin compound, which can contribute a decrease in packaging materials, transportation cost and storage space, can be free from lateral cracking at the formation of tablets, and can bring about an improvement in storage stability after being formed into processing solutions (i.e., more free from occurrence of stain during developing and scratches in light-sensitive materials having been processed, caused by deposition of crystals).
    Type: Grant
    Filed: November 27, 1992
    Date of Patent: December 27, 1994
    Assignee: Konica Corporation
    Inventors: Hiroshi Yoshimoto, Shoji Nishio, Hideki Komatsu, Satomi Kawasaki
  • Patent number: 5284733
    Abstract: A silver halide photographic material is disclosed. The photographic material comprises a support having coated thereon one or more hydrophilic colloidal layers, at least one of the hydrophilic colloidal layers being a negative working silver halide emulsion layer, wherein said silver halide emulsion layer or another hydrophilic colloidal layer contains a water-soluble polymer or copolymer having a quaternary ammonium salt in a repeating unit. The process for forming a high contrast negative image using the photographic material is also disclosed.
    Type: Grant
    Filed: October 1, 1991
    Date of Patent: February 8, 1994
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Yasuhiko Kojima, Naoki Obi, Yasuo Shigemitsu, Kiyoshi Suematsu
  • Patent number: 5272045
    Abstract: Solid anti-fogging agents such as 5-nitroindazole which are otherwise poorly soluble in water are converted to readily water soluble compositions that are solids at room temperature when they are first dissolved in water soluble polymers or other organic compounds that have a melting point above room temperature and do not chemically react with the anti-fogging agent. The anti-foggants are preferably dissolved in the polymer or organic compound at or near the compounds' melting point below 175.degree.C.
    Type: Grant
    Filed: November 13, 1992
    Date of Patent: December 21, 1993
    Assignee: Sun Chemical Corporation
    Inventors: Dinesh P. Patel, John L. Adkins
  • Patent number: 5256523
    Abstract: A compound (I) having a carrier moiety (CAR) and a releasable development inhibitor moiety (INH) capable of being released during photographic processing by means of at least one timing group (T) bonded to and releasable from the carrier moiety provides improved images in a photographic silver halide element and process when the inhibitor moiety (INH) comprises (R.sup.1) a non-aromatic, sterically hindered substituent group having (a) a tertiary carbon atom bonded directly to the releasable development inhibitor moiety or (b) a secondary carbon atom bonded directly to the releasable development inhibitor moiety and wherein the secondary carbon atom is not part of an unsubstituted carbocyclic ring containing at least 6 carbon atoms. Such compounds, particularly as couplers, are useful in photographic silver halide materials and processes to provide improved acutance and interimage effects.
    Type: Grant
    Filed: June 17, 1991
    Date of Patent: October 26, 1993
    Assignee: Eastman Kodak Company
    Inventors: Richard P. Szajewski, Jerrold N. Poslusny
  • Patent number: 5153111
    Abstract: A composition for color-development of a silver halide color photographic material and a method for processing such using the same wherein the composition comprises an aromatic primary amine color developing agent, a hydroxylamine compound represented by formula (I) or a hydrazine compound represented by formula (II) and at least one polymer selected from the group consisting of a vinyl alcohol homopolymer, a vinyl alcohol copolymer, a vinylpyrrolidone homopolymer, and a vinylpyrrolidone copolymer, being free from sulfite ion, providing a color photographic image high in maximum density and good in whiteness without causing problems by tarry substance in the color developer.
    Type: Grant
    Filed: January 24, 1991
    Date of Patent: October 6, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazuaki Yoshida, Takatoshi Ishikawa, Tadashi Ogawa, Hiroshi Fujimoto, Junichi Yamanouchi, Tomokazu Yasuda
  • Patent number: 5015560
    Abstract: A method of treating a waste solution resulting from the processing of a photographic material with a working solution is disclosed, wherein at least part of said waste solution is absorbed by a resin capable of absorbing at least 50 times its own weight of a liquid.
    Type: Grant
    Filed: January 10, 1989
    Date of Patent: May 14, 1991
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Shigeharu Koboshi, Kazuhiro Kobayashi, Syozo Aoki, Naoki Takabayashi
  • Patent number: 4920040
    Abstract: A silver halide light-sensitive photographic material for a laser light exposure is disclosed. The material comprises a support having thereon at least one light-sensitive silver halide emulsion layer containing silver halide grains therein and a layer adjacent thereto, wherein said silver halide grains are spectrally sensitized with a dye represented by the following formula I, at least one layer of said silver halide emulsion layer and said adjacent layer contains a fluorine-containing ionic surfactant, a non-ionic surfactant and an inorganic salt; ##STR1## The material of the invention excels in each of sensitivity, gradation and maximum density, and exhibits good coloration.
    Type: Grant
    Filed: December 1, 1988
    Date of Patent: April 24, 1990
    Assignee: Konica Corporation
    Inventor: Kouzi Ono
  • Patent number: 4916047
    Abstract: A silver halide light-sensitive material comprising a support having thereon at least one silver halide emulsion layer, and containing a compound containing a repeating unit, said compound containing a repeating unit being connected at the repeating unit to a compound represented by formula (I) at the position of the PWR or Time moiety:PWR--Time.sub.t PUG (I)wherein PWR represents a moiety capable of releasing (Time.sub.t PUG upon reduction, and PUG represents a group which can fulfil a photographically useful function after the release; Time represents a moiety capable of releasing PUG through a reaction subsequent to the release from PWR in the form of --Time.sub.t PUG; and t represents 0 or 1.
    Type: Grant
    Filed: April 29, 1988
    Date of Patent: April 10, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keizo Koya, Junichi Yamanouchi, Masaharu Toriuchi, Yoshisada Nakamura
  • Patent number: 4849319
    Abstract: A negative silver halide photographic material comprising a support and at least one silver halide emulsion layer on the support, the emulsion layer or other hydrophilic colloid layer containing a hydrazine derivative, wherein the photographic material further contains an acid polymer and in which the pH of the surface of the photographic material is not more than 5.8. Also, a method for forming a superhigh contrast negative image using the above photographic material is disclosed.
    Type: Grant
    Filed: November 20, 1987
    Date of Patent: July 18, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobuaki Inoue, Senzo Sasaoka, Hiroshi Hayashi
  • Patent number: 4837133
    Abstract: There is disclosed a photographic four-color material for the silver dye bleach process, which material, in addition to containing the customary yellow, magenta and cyan image dyes, contains a black layer which is sensitive to infra-red light.The material is suitable e.g. for testing dotted or continuous tone color separation positives.
    Type: Grant
    Filed: December 9, 1986
    Date of Patent: June 6, 1989
    Assignee: Ciba-Geigy AG
    Inventor: Jakob Kuhn
  • Patent number: 4822728
    Abstract: A color image, wherein granularity is reduced under conditions allowing any sharpness loss to be kept under control, is obtained by image-wise exposing and developing in an alkaline water solution containing a color developer a silver halide color photographic element comprising a support base and at least a silver halide emulsion layer containing dispersed a non-diffusing hydrophobic coupler which upon reactiong with an oxidized developing agent forms a non-diffusing dye, characterized by the fact that said emulsion contains dispersed therein oil droplets, said droplets containing said non-diffusing coupler dissolved therein, and furthermore polymer particles in a quantity sufficient to obtain controlled smearing of the image-forming dye.
    Type: Grant
    Filed: December 11, 1987
    Date of Patent: April 18, 1989
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Marco Loiacono, Angelo Vallarino
  • Patent number: 4761362
    Abstract: An image forming process capable of providing photographic images having extremely high contrast and high resolution for use in photoengraving is disclosed, which comprises processing an image-wise exposed silver halide light-sensitive material having at least two silver halide emulsion layers on a support, one of said emulsion layers providing a contrasty gradation and the other of said emulsion layers providing a soft tone gradation, with a hydrazine contrast development system, a tetrazolium contrast development system or a lith development system, wherein the gamma (.gamma.) value of the portion having a density (D) from 0.3 to 1.5 on the characteristic curve obtained is less than 10 and the gamma (.gamma.) value of the portion having a density (D) from 1.5 to 3.0 is at least 10.
    Type: Grant
    Filed: December 29, 1986
    Date of Patent: August 2, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Senzo Sasaoka, Shigenori Moriuchi, Kimitaka Kameoka, Kazunobu Katoh, Yoshio Inagaki
  • Patent number: 4755448
    Abstract: A negative type silver halide photographic material and a method for forming a super high contrast negative image using the photographic material are disclosed. The photographic material comprises a support, at least one silver halide emulsion layer on the support, and at least one light-insensitive colloid layer on the support, said emulsion layer or light-insensitive hydrophilic colloid layer containing a hydrazine derivative, and further contains the tertiary amine salt of an acid polymer.
    Type: Grant
    Filed: September 4, 1986
    Date of Patent: July 5, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Kazunobu Katoh
  • Patent number: 4710451
    Abstract: A high contrast silver metal image can be formed in an exposed photographic silver halide emulsion layer material, the silver halide of which is at least 90 mole percent silver bromide, with the balance being silver chloride and/or silver iodide by developing the same in a developing medium in the presence of hydroquinone as sole developing agent, a large amount of sulphite derived from an inorganic sulphite compound, a nitro-indazole anti-fogging agent, and a polyoxyethylene polymer, and an inorganic alkaline compound to impart to the medium a pH of at least 10.5 provided the amounts of these ingredients meets certain requirements.
    Type: Grant
    Filed: March 24, 1986
    Date of Patent: December 1, 1987
    Assignee: AGFA-Gevaert N.V.
    Inventor: Richard A. Ooms
  • Patent number: 4680247
    Abstract: Photographic processing compositions containing a light-reflecting pigment and a styrene-butadiene copolymer are disclosed. The photographic processing compositions are useful in photographic diffusion transfer film units and processes for the provision of permanent photographic laminates. A light-reflecting layer formed in a photographic laminate from such a processing composition exhibits a reduced tendency toward cohesion or adhesion failure and separation.
    Type: Grant
    Filed: March 31, 1986
    Date of Patent: July 14, 1987
    Assignee: Polaroid Corporation, Patent Dept.
    Inventor: Richard J. Murphy
  • Patent number: 4624913
    Abstract: A silver halide photographic light-sensitive material is described, comprising at least one light-sensitive silver halide emulsion layer on a support, wherein the emulsion in said light-sensitive silver halide emulsion layer comprises a silver iodobromide emulsion containing 3 mol % or more of iodide, and at least one of said light-sensitive emulsion layer or another hydrophilic colloid layer contains a polyoxyethylene type surface active agent and at least one of said light-sensitive emulsion layer or another hydrophilic colloid layer contains a meso-ionic triazolium compound represented by formula (I) ##STR1## wherein X represents a sulfur ion or --N--R.sup.4, and R.sup.1, R.sup.2, R.sup.3, and R.sup.4 each represents a hydrogen atom or a substituted or nonsubstituted alkyl group, aryl group, or heterocyclic group, or R.sup.1 and R.sup.2, R.sup.2 and R.sup.3 or R.sup.3 and R.sup.4 can together form a heterocyclic ring.
    Type: Grant
    Filed: February 11, 1985
    Date of Patent: November 25, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobuaki Miyasaka, Koki Nakamura, Shigeki Yokoyama
  • Patent number: 4401751
    Abstract: Silver halide emulsions, which have been precipitated in the presence of polymers having recurring units with a 8-hydroxy quinoline structure are suitable for the preparation of vesicular images.
    Type: Grant
    Filed: September 28, 1981
    Date of Patent: August 30, 1983
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Edith Weyde, Harald von Rintelen, Wilhelm Saleck, Heinz-Horst Teitscheid
  • Patent number: 4323643
    Abstract: A silver halide photographic light-sensitive material is described, comprising at least one silver halide photographic emulsion layer, wherein at least one layer contains a compound represented by formula (I) ##STR1## wherein R.sup.1 and R.sup.2 each represents hydrogen, an aliphatic group, an aromatic group, or a heterocyclic group;R.sup.3 represents hydrogen or an aliphatic group, andX represents a divalent aromatic group.The light-sensitive material provides high-contrast negative images and good dot image quality.
    Type: Grant
    Filed: November 6, 1980
    Date of Patent: April 6, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Mifune, Shigeo Hirano, Yoshitaka Akimura
  • Patent number: 4323642
    Abstract: Lignosulfonates are incorporated in photographic developing compositions containing an indazole antifoggant in order to prevent or retard the precipitation of the indazole. Both black-and-white developing compositions, containing such developing agents as dihydroxybenzenes and/or pyrazolidones, and color developing compositions, containing primary aromatic amino color developing agents, are effectively stabilized against precipitation of indazole antifoggants by the lignosulfonates.
    Type: Grant
    Filed: March 9, 1981
    Date of Patent: April 6, 1982
    Assignee: Eastman Kodak Company
    Inventor: Steven R. Levinson
  • Patent number: 4287296
    Abstract: Direct positive silver halide emulsions are provided which contain fogged silver halide grains the said grains being heterodisperse and containing silver iodide in an amount of more than 10 mole % and at most 20 mole % relative to the total amount of silver halide. The emulsions have increased sensitivity and reduced gradation which is suitable for continuous tone reproduction.
    Type: Grant
    Filed: November 20, 1973
    Date of Patent: September 1, 1981
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Willy J. Vanassche, Herman A. Pattyn, Erik Moisar, Sieghart Klotzer
  • Patent number: 4276370
    Abstract: Novel photographic processing compositions including a polymeric oxime viscosity-increasing reagent for processing an exposed film unit to provide a photographic image. While this photographic image may be in black-and-white or in color and prepared by any of the heretofore known systems, of particular interest are color diffusion transfer systems for preparing a color image viewable without separation of any of the components or layers of the photographic product. The invention also includes a novel class of polymeric oximes which may be employed in such compositions.
    Type: Grant
    Filed: November 5, 1979
    Date of Patent: June 30, 1981
    Assignee: Polaroid Corporation
    Inventor: Lloyd D. Taylor
  • Patent number: 4272614
    Abstract: A silver halide photographic light-sensitive material having at least one silver halide photographic emulsion layer comprising substantially surface latent image type silver halide grains, and containing in said photographic emulsion layer or at least one of other hydrophilic colloid layers a compound represented by the following general formula (I): ##STR1## wherein R.sup.1 represents a hydrogen atom, an aliphatic group which may be substituted or an aromatic group which may be substituted; Ar represents a divalent aromatic group which may be substituted; Y represents a divalent linking group; n represents 0 or 1; R.sup.2 represents a hydrogen atom, an aliphatic group which may be substituted or an aromatic group which may be substituted; and Z represents a nonmetallic atomic group necessary to form a 5-membered or 6-membered heterocyclic ring together with the ##STR2## linkage.
    Type: Grant
    Filed: December 20, 1979
    Date of Patent: June 9, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Mifune, Shigeo Hirano
  • Patent number: 4269925
    Abstract: Polymeric optical filter agents and photographic products and processes using same are disclosed. The polymeric optical filter agents are pH-sensitive optical filter agents comprising polymeric backbone units having the following hydrazone moiety: ##STR1## where R is a group which can provide a double bond for conjugation with the ##STR2## portion of the moiety to provide light-absorbing capability for the agent at a pH above its pKa, and X represents a substituent of R providing at least one electron-withdrawing group. The polymeric pH-sensitive optical filter agents have a highly colored light-absorbing form at a pH above the pKa and are substantially non-absorbing at a pH below the pKa. The polymeric optical filter agents are useful in photographic film units and processes for the protection of photoexposed photosensitive elements against the occurence of fogging during in-light development.
    Type: Grant
    Filed: October 29, 1979
    Date of Patent: May 26, 1981
    Assignee: Polaroid Corporation
    Inventors: Derek H. R. Barton, Irena Y. Bronstein-Bonte, Lloyd D. Taylor
  • Patent number: 4266481
    Abstract: Aqueous solutions are provided for treating image-bearing lithographic plates.
    Type: Grant
    Filed: June 29, 1979
    Date of Patent: May 12, 1981
    Assignee: The Dow Chemical Company
    Inventors: Walter L. Garrett, Ralph G. Czerepinski