Using Heterocyclic Compound Patents (Class 430/446)
  • Patent number: 6740478
    Abstract: A method for processing a silver halide photographic light-sensitive material which comprises a support, a silver halide emulsion layer provided on the support and a hydrophilic colloid layer adjacent to the silver halide emulsion layer, comprising a step of developing the photographic light-sensitive material with a developing solution containing an ascorbic acid compound as a developing agent, wherein the photographic material contains an amine compound in at least one of the silver halide emulsion layer and the hydrophilic colloid layer and an nucleating agent within a range of 0 to 20 mg per 1 m2 of the photographic light-sensitive material, and wherein the amine compound has a distribution coefficient (log P) of 1 or more in a n-octanol/water system.
    Type: Grant
    Filed: February 7, 2003
    Date of Patent: May 25, 2004
    Assignee: Konica Corporation
    Inventor: Shoji Nishio
  • Publication number: 20040067457
    Abstract: A method of chemically marking photosensitive material that needs to be digitally scanned and adjusted rather than optically printed to produce a satisfactory hardcopy.
    Type: Application
    Filed: September 30, 2003
    Publication date: April 8, 2004
    Inventors: John R. Fyson, Peter J. Twist
  • Publication number: 20040018453
    Abstract: A composition and method to reduce photolithographic residue and scum formation on a substrate or in a solution, and to reduce or prevent foam formation. The composition contains a diphenyl oxide compound in combination with an antifoam agent. The composition may be added to developer solutions and stripper solutions used in manufacturing printed wiring boards.
    Type: Application
    Filed: April 7, 2003
    Publication date: January 29, 2004
    Applicant: Shipley Company, L.L.C.
    Inventors: Edgardo Anzures, Daniel E. Lundy, Robert K. Barr, Corey O'Connor
  • Publication number: 20040009439
    Abstract: A processing composition for silver halide photographic light-sensitive materials, comprises a bis[2,6-diaminotriazin-4-yl]arylenediamine derivative having at least one of a sulfonic acid group, a carboxylic group and a hydroxyl group within the molecule. This processing composition can be applied to a color developer, a bleaching agent, a fixing agent, a bleach-fixing agent and a stabilizing agent and also to a processing agent in a concentration on use, a concentrated processing agent and a solid processing agent.
    Type: Application
    Filed: April 16, 2003
    Publication date: January 15, 2004
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventors: Yasufumi Nakai, Keizo Kimura, Masashi Ogiyama
  • Publication number: 20030224300
    Abstract: A photographic processing composition for silver halide color photographic lightsensitive material, comprising at least one compound represented by the formula (I):
    Type: Application
    Filed: June 18, 2003
    Publication date: December 4, 2003
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventors: Makoto Suzuki, Yasufumi Nakai, Yoshiharu Yabuki
  • Publication number: 20030165783
    Abstract: A method for processing a silver halide photographic light-sensitive material which comprises a support, a silver halide emulsion layer provided on the support and a hydrophilic colloid layer adjacent to the silver halide emulsion layer, comprising a step of developing the photographic light-sensitive material with a developing solution containing an ascorbic acid compound as a developing agent, wherein the photographic material contains an amine compound in at least one of the silver halide emulsion layer and the hydrophilic colloid layer and an nucleating agent within a range of 0 to 20 mg per 1 m2 of the photographic light-sensitive material, and wherein the amine compound has a distribution coefficient (log P) of 1 or more in a n-octanol/water system.
    Type: Application
    Filed: February 7, 2003
    Publication date: September 4, 2003
    Inventor: Shoji Nishio
  • Publication number: 20030152876
    Abstract: A black-and-white photographic developing composition has improved stability and is more compatible with the environment when discarded. The composition includes one or more ascorbic acid developing agents and is essentially free of hydroquinone and similar developing agents. It comprises a mono- or disaccharide such as ribose, fructose, lactose, glucose or galactose as a stabilizing agent for the developing agent.
    Type: Application
    Filed: January 23, 2003
    Publication date: August 14, 2003
    Inventors: Shirleyanne E. Haye, Janet M. Huston, Jacques Roussilhe
  • Publication number: 20030096203
    Abstract: A silver halide emulsion sheet for detecting track of charged elementary particles, in which emulsion at least one silver halide emulsion layer and at least one hydrophilic protective colloid layer are applied on both surfaces of a transparent support, and a compound selected from benzotriazoles is contained in said at least one silver halide emulsion layer.
    Type: Application
    Filed: September 17, 2002
    Publication date: May 22, 2003
    Inventor: Ken-ichi Kuwabara
  • Patent number: 6440652
    Abstract: A processing method of a silver halide light sensitive photographic material by the use of an automatic processor is disclosed, in which a developing solution contains a developing agent represented by the formula described below and a developer replenishing solution having activity lower than that of a developing solution used at the time of starting processing is replenished within a predetermined amount to be replenished per unit time, and when the replenished amount of the developer replenishing solution has exceeded the predetermined amount to be replenished per unit time, a developer replenishing solution having higher activity is replenished.
    Type: Grant
    Filed: June 2, 2000
    Date of Patent: August 27, 2002
    Assignee: Konica Corporation
    Inventor: Shoji Nishio
  • Patent number: 6372417
    Abstract: A method of forming a photographic image in an imagewise exposed high contrast photographic material free from nucleating agents comprising a support bearing a silver halide emulsion layer comprising silver halide grains wherein at least 10% of the silver halide grains are spectrally sensitized and a hydrophilic colloid having a silver:hydrophilic colloid ratio above 1. The method comprises developing the material in a developer comprising an ascorbic acid developing agent at a pH no greater than 10.5, the developer being free of hydroquinone.
    Type: Grant
    Filed: June 14, 1999
    Date of Patent: April 16, 2002
    Assignee: Eastman Kodak Company
    Inventors: Colin J. Gray, Andrew R. Benoy, Eric Ordia
  • Patent number: 6346570
    Abstract: Provided are a water resistant composition comprising a uniform mixture of (A) at least one of modified polyvinyl alcohol containing either from 1 to 20 mol % of &agr;-olefin units with not more than 4 carbon atoms, from 0.01 to 1 mol % of silyl groups, or from 1 to 20 mol % of &agr;-olefin units with not more than 4 carbon atoms and from 0.01 to 1 mol % of silyl groups and (B) an organotitanium compound having a chelating ligand, in a blend ratio of component (A) to the component (B) between 99.99/0.01 and 60/40 by weight; a coating agent comprising the composition; a thermal recording material having a coat layer of the composition; and an ink-jet recording material having an ink-absorbing layer of the composition.
    Type: Grant
    Filed: August 22, 2000
    Date of Patent: February 12, 2002
    Assignee: Kuraray Co., Ltd.
    Inventors: Somemiya Kazuyuki, Sadahiko Shiraga, Naoki Fujuwara, Atsushi Jikihara, Toshiyuki Akasawa
  • Publication number: 20010026908
    Abstract: A method for processing a silver halide light-sensitive material employing an automatic processing machine is disclosed. A developer comprises compounds represented by the formula (1), and a fixer comprises thiosulfate salts, water-soluble aluminum salts, and at least one type of crystallization retarding agents and substantially comprises no boron compound.
    Type: Application
    Filed: December 6, 2000
    Publication date: October 4, 2001
    Inventor: Shoji Nishio
  • Patent number: 6238853
    Abstract: A method of processing has been described for a light-sensitive black-and-white silver halide photographic material comprising the distinct steps of developing, fixing, rinsing and drying, wherein during said processing said developer comprises, besides one or more developing agent(s), one or more agent(s) preventing oxidation thereof and agent(s) providing pH buffering in running equilibrium conditions during said processing, at least one agent preventing silver dissolution and at least one silver complexing agent, characterized in that said agent preventing silver dissolution, if present in an amount of 50 mg/l of developer, makes silver content of the developer decrease in an amount of more than 50% versus in the absence thereof, without loss in speed in an amount of more than 0.10 log Exposure after processing in said developer composition; said silver complexing agent makes silver content of the said developer increase in an amount of more than 1 mg per liter per mmole of said complexing agent.
    Type: Grant
    Filed: June 6, 2000
    Date of Patent: May 29, 2001
    Assignee: Agfa-Gevaert
    Inventors: Govert De Baecke, Benny Jansen, Frank Michiels, Johan Loccufier, Ton Rutges
  • Patent number: 6218092
    Abstract: A processing method of silver halide light sensitive photographic materials by the use of an automatic processor is disclosed, comprising the steps of developing, fixing and washing, in which a developing bath of the processor comprises a processing tank and a temperature-controlling tank and a ratio by volume of the temperature-controlling tank to the processing tank being 0.4 to 1.
    Type: Grant
    Filed: March 22, 2000
    Date of Patent: April 17, 2001
    Assignee: Konica Corporation
    Inventor: Kazuya Tsukada
  • Patent number: 6117611
    Abstract: An image forming method of a silver halide photographic light-sensitive material is disclosed. The silver halide photographic light-sensitive material is exposed to a laser beam light, while said silver halide photographic light-sensitive material is conveyed with rollers at 15 to 100 mm/sec., and processed with a developer composition containing a developing agent represented by formula (A). The silver halide photographic light-sensitive material contains at least an organic contrast enhancing agent, the impedance of at least one side of said silver halide photographic light-sensitive material is from 4.times.10.sup.5 to 10.sup.20 .OMEGA.
    Type: Grant
    Filed: December 13, 1999
    Date of Patent: September 12, 2000
    Assignee: Konica Corporation
    Inventor: Hirohide Ito
  • Patent number: 6083673
    Abstract: The present invention concerns an organic/inorganic developer composition comprising a regeneratable iron chelate, novel codevelopers of the phenidone type including one or more solubilizing groups that are not directly attached to the phenyl nucleus or to the pyrazolidino nucleus and optionally ascorbic acid. These compositions are particularly useful for the black-and-white development of films or photographic papers, in particular for the fast development of radiographic products.
    Type: Grant
    Filed: March 31, 1998
    Date of Patent: July 4, 2000
    Assignee: Eastman Kodak Company
    Inventors: Jacques Roussilhe, Siu Chung Tsoi
  • Patent number: 6083672
    Abstract: A method of processing an exposed black-and-white silver halide light-sensitive photographic material has been disclosed, said method comprising the steps of developing in a developer solution, followed by fixing in a fixer solution, comprising a hardening agent, preferably a compound providing aluminum ions, and wherein, in running equilibrium conditions, said fixer solution has a pH of at least 4.3, further adding to said fixer a fixer replenisher at a rate of from 0 ml/m.sup.2 up to 300 ml/m.sup.2 ; followed by rinsing and drying, wherein rinsing between developing and fixing is excluded and wherein an .alpha.
    Type: Grant
    Filed: September 23, 1998
    Date of Patent: July 4, 2000
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Andre Roefs, Benedictus Jansen, Frank Michiels
  • Patent number: 6066441
    Abstract: A method is disclosed of processing an exposed black-and-white light-sensitive silver halide photographic material having silver halide, coated in an amount, expressed as an equivalent amount of silver nitrate of less than 6 g/m.sup.2 comprising the steps of developing, fixing, rinsing and drying, making use in the developing step of an ascorbic acid type developer and of an equivalent developer replenisher providing a regeneration amount of less than 150 ml/m.sup.2, characterized in that the said material has a buffering capacity of less than 6 mmole/m.sup.2, wherein said buffering capacity is defined as the amount of alkali, expressed in mmole/square meter, required to bridge across pH differences between the material and the developer.
    Type: Grant
    Filed: May 3, 1999
    Date of Patent: May 23, 2000
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Benedictus Jansen, Freddy Henderickx, Ann Verbeeck, Frank Michiels
  • Patent number: 6048675
    Abstract: A development processing method comprising a step of developing a silver halide photographic material having at least one silver halide emulsion layer with a developing solution containing a hydroquinone developing agent, wherein said developing solution has a pH of from 9.0 to 11.0, and contains a compound represented by formula (I) and a compound represented by formula (II) in a concentration ratio of the compound represented by formula (II)/the hydroquinone developing agent of from 0.03 to 0.12: ##STR1## wherein the symbols in these formulae are defined in the specification.
    Type: Grant
    Filed: November 26, 1997
    Date of Patent: April 11, 2000
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Mitsunori Hirano, Kohzaburoh Yamada
  • Patent number: 6033837
    Abstract: Low silver black-and-white photographic elements, such as radiographic films, can be processed quickly using black-and-white developing and fixing compositions having reduced photoprocessing activity. The entire process is fairly rapid and effective despite the lowered concentrations of photographic developing and fixing agents. The processing compositions are more environmentally friendly because the conventional hydroquinone is replaced with an ascorbic acid developing agent. In addition, the processing compositions are free of ammonium ions.
    Type: Grant
    Filed: May 18, 1999
    Date of Patent: March 7, 2000
    Assignee: Eastman Kodak Company
    Inventors: Alan S. Fitterman, Robert E. Dickerson
  • Patent number: 6017674
    Abstract: A silver halide photographic material comprising a support having thereon at least one photosensitive silver halide emulsion layer, wherein at least one of the silver halide emulsion layer and other hydrophilic colloid layers comprises at least one hydrazine compound represented by the following general formula (II) in the form of fine solid dispersion:A--(B).sub.m (II)wherein A represents a connecting group; B represents a group represented by the following general formula (III); and m represents an integer of from 2 to 6:--(L.sub.2 --Ar.sub.2).sub.n --L.sub.1 --Ar.sub.1 --NHNH--G.sub.1 --R.sub.1(III)wherein Ar.sub.1 and Ar.sub.2 each represents an aromatic group or an aromatic heterocyclic group; L.sub.1 and L.sub.2 each represents a connecting group; n represents an integer of 0 or 1; R.sub.1 represents a hydrogen atom, an alkyl group, an aryl group, a heterocyclic group, an alkoxy group, an aryloxy group, an amino group or a hydrazino group; and G.sub.1 represents a --CO-- group, an --SO.sub.
    Type: Grant
    Filed: January 21, 1997
    Date of Patent: January 25, 2000
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshihide Ezoe, Kohzaburoh Yamada
  • Patent number: 6013421
    Abstract: There is disclosed a silver halide photographic light-sensitive material containing a color-developing agent of formula (I) and a coupler of formula (II), in at least one photographic constitutional layer: ##STR1## In formula (I), Z is a carbamoyl, acyl, alkoxycarbonyl, or aryloxycarbonyl group, and Q is a group of atoms that, together with the C, form an unsaturated ring. In formula (II), Cp is a coupler residue, Time is a group that releases PUG upon released from Cp by coupling reaction, PUG is a photographically useful group, and t is 0, 1, 2, or 3. There is also disclosed a silver halide photographic light-sensitive material containing a color-developing agent of formula (I), a dye-forming coupler, and a non-dye-forming coupler (that is unsubstituted on its active site), in at least one photographic constitutional layer. There is further disclosed methods for forming an image using the light-sensitive materials.
    Type: Grant
    Filed: July 18, 1997
    Date of Patent: January 11, 2000
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Koki Nakamura, Kazuhiko Matsumoto
  • Patent number: 6013423
    Abstract: A developing solution for silver halide photographic material contains a six-membered heterocyclic compound having two nitrogen atoms as the constituent atoms of the six-membered ring and mercapto group, hydroxyl group and at least one substituent group other than hydrogen atom and a five-membered heterocyclic compound having two to three nitrogen atoms as the constituent atoms of the five-membered ring and at least one mercapto group. There is also disclosed a method for processing a silver halide photographic material with said developing solution.
    Type: Grant
    Filed: February 7, 1994
    Date of Patent: January 11, 2000
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Mitsunori Hirano, Kiyoshi Morimoto, Tetsuo Yoshida, Kunio Ishigaki
  • Patent number: 5998110
    Abstract: A black-and-white aqueous alkaline photographic developer composition is described which is free of dihydroxybenzene developing agent and comprises a p-aminophenol primary developing agent and an auxiliary superadditive 3-pyrazolidone developing agent, wherein the p-aminophenol primary developing agent is represented by the following formula: ##STR1## wherein R.sub.1, and R.sub.2, which may be the same or different, each represents a hydrogen atom, an alkyl group, or R.sub.1, and R.sub.2 together represent the carbon atoms required to complete a 5-membered saturated ring, R.sub.3 represents a hydrogen atom, an alkyl group or an alkoxy group, n represents 0 or 1, and HX represents HCl or 1/2 H.sub.2 SO.sub.4.A process for forming a black-and-white photographic silver image comprising developing a silver halide photographic element with the black-and-white aqueous alkaline photographic developer composition is also described.
    Type: Grant
    Filed: November 6, 1997
    Date of Patent: December 7, 1999
    Assignee: Ferrania S.p.A.
    Inventor: Filippo Faranda
  • Patent number: 5994040
    Abstract: A processing composition for silver halide photographic light-sensitive material, which comprises at least one compound represented by the following formula (A), (A-I) or (A-II) and at least one compound represented by the following formula (B): ##STR1## Also disclosed are a developer prepared from the processing composition, and a processing method using the developer.
    Type: Grant
    Filed: March 4, 1997
    Date of Patent: November 30, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinnichi Morishima, Kohzaburoh Yamada, Seiji Yamashita, Minoru Sakai, Kouta Fukui, Eiichi Okutsu
  • Patent number: 5994037
    Abstract: Color photographic elements, especially color photographic papers, can be more rapidly color developed (up to 25 seconds) in the presence of a color developing solution containing a selectively diffusible color development photochemical such as a development inhibitor. Despite the shortened processing time, color balance within the three color records of such elements is maintained. The selectively diffusible color development photochemical has size and structure that enables it to have sufficient solubility in the color developing composition, and to selectively diffuse into the topmost red-sensitive emulsion layers of the processed color papers only.
    Type: Grant
    Filed: October 21, 1998
    Date of Patent: November 30, 1999
    Assignee: Eastman Kodak Company
    Inventors: Peter J. Twist, John D. Goddard
  • Patent number: 5989789
    Abstract: A silver halide color photographic material comprising a transparent support having thereon at least one blue-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer, at least one red-sensitive silver halide emulsion layer and at least one light-insensitive layer, wherein said red-sensitive silver halide emulsion layer contains at least one compound which releases a development inhibitor having a diffusion parameter of 0.3 or more upon reaction with the oxidation product of a color developing agent, and when development processing I and development processing II each defined in the specification are carried out, the gradients of yellow, magenta and cyan obtained by said two kinds of development processing satisfy the following conditions:0.8.ltoreq..gamma..sub.II (Y)/.gamma..sub.I (Y).ltoreq.1.20.8.ltoreq..gamma..sub.II (M)/.gamma..sub.I (M).ltoreq.1.20.8.ltoreq..gamma..sub.II (C)/.gamma..sub.I (C).ltoreq.1.2wherein .gamma..sub.I (Y), .gamma..sub.I (M), .gamma..sub.
    Type: Grant
    Filed: June 27, 1996
    Date of Patent: November 23, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hajime Nakagawa, Akimitsu Haijima
  • Patent number: 5989773
    Abstract: A developing processing method and an image forming method are described, which comprise the steps of (a) exposing a silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer; and (b) developing the exposed silver halide photographic material with a developer containing a developing agent, containing substantially no dihydroxybenzene developing agent, containing an auxiliary developing agent exhibiting a superadditive property, containing a quaternary onium salt compound, and having a pH value of from 9.5 to 11.5, or a developer containing a developing agent, containing substantially no dihydroxybenzene developing agent, and having a pH value of from 10 or less.
    Type: Grant
    Filed: March 31, 1997
    Date of Patent: November 23, 1999
    Assignee: Fuji Photo Film Co., Ltd
    Inventors: Kouta Fukui, Minoru Sakai, Kazunobu Katoh
  • Patent number: 5976758
    Abstract: A development processing method which comprises the steps of: imagewise exposing a silver halide photographic light-sensitive material; and developing the exposed photographic material with a developing solution, wherein the silver halide photographic material comprises a support having thereon at least one light-sensitive silver halide emulsion layer, at least one of the silver halide emulsion layer and other hydrophilic colloidal layers containing at least one hydrazine derivative; and wherein the developing solution is substantially free from a dihydroxybenzene compound, has a pH of from 9.0 to 10.5 and contains (1) at least one ascorbic acid developing agent, (2) at least one 1-phenyl-3-pyrazolidone auxiliary developing agent and (3) a compound represented by the following formula (I): ##STR1## wherein R.sub.1 to R.sub.
    Type: Grant
    Filed: December 19, 1997
    Date of Patent: November 2, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kouta Fukui, Senzo Sasaoka, Kohzaburoh Yamada
  • Patent number: 5972580
    Abstract: A development processing method comprises: exposing a silver halide light-sensitive material comprising a support having thereon at least one light-sensitive silver halide emulsion layer; and developing said exposed light-sensitive material with a developing solution, wherein at least one of said silver halide emulsion layer and other hydrophilic colloidal layers contains at least one hydrazine derivative, and wherein said developing solution is substantially free from a dihydroxybenzene compound, has a pH of from 9.0 to 10.5, and contains (1) at least one ascorbic acid derivative developing agent, (2) at least one aminophenol auxiliary developing agent and (3) a specific mercaptopyrimidine compound. The processing method provides a high-contrast image required in the field of graphic arts using a developing solution having no problem with respect to the ecosystem and working environment, without causing silver stain even at a low replenishment rate.
    Type: Grant
    Filed: November 21, 1997
    Date of Patent: October 26, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kouta Fukui, Kohzaburoh Yamada
  • Patent number: 5968706
    Abstract: A silver halide photographic material enabling very rapid processing and extremely low waste liquid processing, which comprises a transparent film support having provided on each side thereof at least one light-sensitive silver halide emulsion layer and a dye-fixed layer for absorbing the crossover light disposed nearer to the support, wherein a dye used in said dye-fixed layer is a compound which is decolorized in development processing.
    Type: Grant
    Filed: February 26, 1997
    Date of Patent: October 19, 1999
    Assignee: Fuji Photo Co., Ltd.
    Inventors: Seiji Yamashita, Toshiki Fujiwara, Toru Harada
  • Patent number: 5962182
    Abstract: A method for forming an image which comprises imagewise-exposing a silver halide photographic material comprising a support having thereon at least one silver halide emulsion layer, wherein the emulsion layer or other hydrophilic colloid layer contains a hydrazine derivative as a nucleating agent and contains at least one compound represented by formula (A); and then developing the exposed photographic material with a developer having a pH of 9.0 to 11.0 which contains an ascorbic acid type developing agent and does not substantially contain a dihydroxybenzene type developing agent: ##STR1## wherein X represents a hydrogen atom, an aryl group, a heterocyclic group, or a group represented by formula (B): ##STR2## wherein each of R.sub.1, R.sub.2 and R.sub.3 may be the same or different, and each represents a hydrogen atom or a group other than a hydroxyl group.
    Type: Grant
    Filed: March 24, 1997
    Date of Patent: October 5, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazunobu Katoh, Shinnichi Morishima
  • Patent number: 5962202
    Abstract: A method for processing a black-and-white silver halide photographic light-sensitive material. The method comprises the steps of (1) developing the black-and-white photographic light-sensitive material containing a quaternary onium compound with a developer containing ascorbic acid or a derivative thereof and having a pH value of from 8.0 to 10.0, (2) fixing the light-sensitive material, (3) washing the light-sensitive material by an automatic processor having a multi-step counter flow washing system, and (4) drying the light-sensitive material.
    Type: Grant
    Filed: December 1, 1997
    Date of Patent: October 5, 1999
    Assignee: Konica Corporation
    Inventor: Takeshi Sampei
  • Patent number: 5962199
    Abstract: An image forming process of a silver halide photographic material comprising a glass support having thereon a silver halide emulsion layer is disclosed, the process comprising exposing with laser beam spot with a diameter of 0.05 to 5 .mu.m and developing the exposed photographic material with a developer, wherein the silver halide emulsion layer contains silver halide grains having an average grain size of 0.08 to 0.2 .mu.m and a chloride content of at least 50 mol %; the developer containing a developing agent selected from hydroquinone and ascorbic acid, and a developing agent selected from p-methyl-aminophenol, 1-phenyl-3-pyrazolidone and 1-pheny-4-dimethyl-3-pyrazolidone; and the developed photographic material having a contrast of 4.8 to 12.
    Type: Grant
    Filed: February 11, 1998
    Date of Patent: October 5, 1999
    Assignee: Konica Corporation
    Inventor: Tomonobu Moriya
  • Patent number: 5962201
    Abstract: A method of processing a silver halide photographic light-sensitive material by use of an automatic processor is disclosed, comprising the steps of developing an exposed photographic material with a developer, fixing with a fixer, washing and drying, wherein a swell ration of overall hydrophilic colloid layers including a silver halide emulsion layer and a protective layer provided on one side of a support is not more than 150%; and the developer, which contains substantially no dihydroxybenzene compound comprises a compound represented by the following formulas in combination with a 3-pyrazolidone compound or an aminophenol compound, and a carbonate salt in an amount of 0.35 mol/l or more.
    Type: Grant
    Filed: September 19, 1997
    Date of Patent: October 5, 1999
    Assignee: Konica Corporation
    Inventors: Wataru Ishikawa, Shoji Nishio
  • Patent number: 5948602
    Abstract: When a double-sided photographic silver halide photosensitive element having a crossover light quantity of up to 15% is processed through an automatic processor, it is developed with a developer containing an ascorbic acid type developing agent. By restricting the drag-out of the developer to 1.0 ml or less per 10.times.12-inch size sheet, the photosensitive element can be processed and effectively dried so as to produce high-quality images free of residual color.
    Type: Grant
    Filed: April 21, 1998
    Date of Patent: September 7, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiji Yamashita, Eiichi Okutsu
  • Patent number: 5948603
    Abstract: Disclosed is a method of processing an exposed black and white photographic light-sensitive material employing an automatic processor, the method comprising the steps of developing the exposed material with a developer, the developer is replenished with a developer replenisher; fixing the developed material with a fixer; washing the fixed material; and drying the washed material, wherein the developer contains a developing agent, a compound represented by the following formula (III) and at least one of a compound represented by the following formula (I) and a compound represented by the following formula (II): ##STR1##
    Type: Grant
    Filed: November 20, 1997
    Date of Patent: September 7, 1999
    Assignee: Konica Corporation
    Inventors: Shinji Uchihiro, Shoji Nishio
  • Patent number: 5935769
    Abstract: A method for processing a silver halide black-and-white photographic light sensitive material comprising a transparent polyester support having thereon hydrophilic colloid layers including a silver halide emulsion layer, by the use of an automatic processor, the method comprising the steps of developing with a developing solution; fixing with a fixing solution, washing and drying, wherein the polyester support is a biaxially stretched polyester film obtained from a naphthalenedicarboxylic acid and a diol; the developing solution and the fixing solution being prepared by dissolving, in water, a solid developing composition and a solid fixing composition, respectively.
    Type: Grant
    Filed: December 5, 1997
    Date of Patent: August 10, 1999
    Assignee: Konica Corporation
    Inventor: Kazuya Tsukada
  • Patent number: 5932399
    Abstract: A class of pyrazolidone compounds suitable for use as electron transfer agents in photographic development comprises pyrazolidones substituted in the 1-position by an aromatic group that is substituted in the ortho, meta or para position by -O-CO-R, wherein R is a monovalent organic group having up to 24 carbon atoms. This ester group is hydrolyzable in an alkaline developer solution, thereby deactivating the electron transfer agents after a period of time and reducing the contamination effect of seasoning into the developer solution. Photographic recording materials can be developed in reactive association with the electron transfer agent. The electron transfer agent can be present in the photographic recording materials, or in develper solutions.
    Type: Grant
    Filed: November 14, 1997
    Date of Patent: August 3, 1999
    Assignee: Eastman Kodak Company
    Inventors: Siu C. Tsoi, Peter J. Twist
  • Patent number: 5925493
    Abstract: A developing processing method and an image forming method are described, which comprise the steps of (a) exposing a silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer; and (b) developing the exposed silver halide photographic material with a developer containing a developing agent, containing substantially no dihydroxybenzene developing agent, containing an auxiliary developing agent exhibiting a superadditive property, containing a quaternary onium salt compound, and having a pH value of from 9.5 to 11.5, or a developer containing a developing agent, containing substantially no dihydroxybenzene developing agent, and having a pH value of from 10 or less.
    Type: Grant
    Filed: March 4, 1997
    Date of Patent: July 20, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kouta Fukui, Minoru Sakai, Kazunobu Katoh
  • Patent number: 5912108
    Abstract: A method has been disclosed of processing an image-wise exposed light-sensitive black-and-white silver halide photographic material comprising a support coated on one or both sides thereof with hydrophilic layers, wherein at least one of said layers comprises one or more emulsions having tabular silver halide crystals rich in silver chloride, said method comprising the steps of developing, fixing, rinsing and drying, further characterized in that said developing step proceeds in a black-and-white developer comprising one or more organic compounds inhibiting development, more preferably one or more benzotriazole compounds, and in that said developer is substantially free from bromide ions in favor of a low fog level, a high speed and a sufficiently high covering power of the developed tabular grains.
    Type: Grant
    Filed: December 16, 1997
    Date of Patent: June 15, 1999
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Ann Verbeeck, Peter Verrept, Freddy Henderickx
  • Patent number: 5888708
    Abstract: A development processing method comprising developing a silver halide photographic material with a developing solution, (i) wherein the silver halide photographic material comprises a support having thereon at least one light-sensitive silver halide emulsion layer and contains: (a) at least two kinds of light-sensitive silver halide emulsions which are each spectrally sensitized and have sensitivities different from each other with respect to a certain exposure wavelength; and (b) at least one hydrazine derivative in at least one of the silver halide emulsion layer and other hydrophilic colloidal layers, and (ii) wherein the developing solution is substantially free from a dihydroxybenzene compound, has a pH of from 9.0 to 10.5 and contains: (1) at least one ascorbic acid developing agent and (2) at least one auxiliary developing agent represented by the following general formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.
    Type: Grant
    Filed: January 28, 1998
    Date of Patent: March 30, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kouta Fukui, Senzo Sasaoka
  • Patent number: 5882841
    Abstract: A silver halide photographic light-sensitive material comprising a support having thereon at least one light-sensitive silver halide emulsion layer, wherein at least one of the silver halide emulsion layer and other hydrophilic colloid layers comprises fine polymer particles containing at least one hydrazine compound represented by the following general formula (NB):A--(B).sub.m (NB)wherein A represents a connecting group; m represents an integer of from 2 to 6; and B represents a group containing a hydrazine structure. The sliver halide photographic light-sensitive material exhibits an ultrahigh contrast, an excellent storage stability and an excellent processing stability and is prevented from the occurrence of processing unevenness. A method for processing the silver halide photographic light-sensitive material is also disclosed.
    Type: Grant
    Filed: December 24, 1997
    Date of Patent: March 16, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshihide Ezoe, Kouta Fukui, Kohzaburoh Yamada
  • Patent number: 5876907
    Abstract: An image formation method, which comprises the steps of imagewise exposing a silver halide photographic material comprising a support having thereon at least one layer of a silver halide emulsion chemically sensitized with at least one selenium or tellurium compound, and then subjecting the material to development-processing with a developer containing substantially no dihydroxybenzene developing agent but containing a developing agent represented by the following formula (I): ##STR1## wherein R.sub.1 and R.sub.
    Type: Grant
    Filed: October 28, 1997
    Date of Patent: March 2, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Tsutomu Arai
  • Patent number: 5874203
    Abstract: There is disclosed novel color-developing agents of the formula (I). There is also disclosed silver halide photographic light-sensitive materials and image-forming methods, using the color-developing agent. The color-developing agent is excellent in color-forming property, and the image obtained from the color-developing agent is good in hue. ##STR1## wherein R.sub.1 to R.sub.4 each represent a group of nonmetal atoms required to form, together with the carbon atom, a monocyclic 5-membered aromatic ring or a 5-membered aromatic ring condensed with another ring, with the proviso that at least two of R.sub.1 to R.sub.4 are nitrogen atoms; and Z represents an acyl group, a carbamoyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfonyl group, a sulfamoyl group, an amidino group, or an imidoyl group.
    Type: Grant
    Filed: November 26, 1996
    Date of Patent: February 23, 1999
    Assignee: Fuji Photo Film, Co., Ltd.
    Inventors: Kensuke Morita, Hiroo Takizawa, Taiji Katsumata
  • Patent number: 5869225
    Abstract: A method for processing a silver halide photographic light sensitive material, using an automatic processor, the method comprising the steps of developing an exposed silver halide photographic light sensitive material with developer containing a compound represented by the following formula (1); and then fixing the developed material with fixer, formula (1) ##STR1## wherein the average flow velocity of the developer is 20 cm/second or more.
    Type: Grant
    Filed: August 20, 1997
    Date of Patent: February 9, 1999
    Assignee: Konica Corporation
    Inventor: Akiko Yamaya
  • Patent number: 5869218
    Abstract: Disclosed are an image formation process which comprises developing a photographic material comprising a silver halide emulsion layer, and a hydrazine derivative and a specific phosphonium compound of formula (1) with a developer which is substantially free of a dihydroxybenzene developing agent, contains a specific developing agent of formula (2) and at least one p-aminophenol derivative, and has a pH value of not more than 10, and a development process which comprises developing a photographic material comprising a silver halide emulsion layer, and a hydrazine derivative and a nucleation accelerator, with a developer having a pH value of from 9.0 to 10.5 and containing a first developing agent selected from ascorbic acid and a derivative thereof and a second developing agent selected from aminophenol and a derivative thereof, wherein a solution having the same composition as the fresh developer but a higher pH value than the fresh developer is used as a development replenisher.
    Type: Grant
    Filed: July 26, 1996
    Date of Patent: February 9, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Minoru Sakai, Kazunobu Katoh
  • Patent number: 5866309
    Abstract: Black-and-white elements, such as radiographic films, can be handled and processed in roomlight because they include certain light absorbing dyes and desensitizers. Processing is carried out by developing the exposed element using a developing composition having a pH of less than 10. The developed elements are fixed using a fixing composition having a pH of from 10 to 11.5, and comprising specific amounts of fixing agent and sulfite to solubilize silver halide and to bleach or decompose the light absorbing dyes. The processing method is carried out quickly, usually within 120 seconds.
    Type: Grant
    Filed: October 22, 1997
    Date of Patent: February 2, 1999
    Inventors: Alan S. Fitterman, Jeffrey S. Baugher, Robert E. Dickerson
  • Patent number: 5858632
    Abstract: A method for processing a silver halide light sensitive photographic material comprising a support having thereon hydrophilic colloid layers including a silver halide emulsion layer, wherein a dextran and a leuco dye compound each are independently contained in the hydrophilic colloid layer(s), the photographic material being processed with a developer containing a reductone as a developing agent.
    Type: Grant
    Filed: October 17, 1997
    Date of Patent: January 12, 1999
    Assignee: Konica Corporation
    Inventor: Masaaki Taguchi
  • Patent number: RE36384
    Abstract: The invention comprises a process for forming a high contrast photographic image including the steps of imagaewise exposing a silver halide photographic element containing a hydrazine compound which functions as a nucleating agent, wherein the element is free of incorporated amine boosters. The exposed element is developed with a chemically stable aqueous alkaline developing solution that is free of dihydroxybenzene developing agents and has a pH between 9.5 and 11. The developing solution comprises an ascorbic acid developing agent; an auxiliary developing agent; and a combination of an alkali metal carbonate and an alkali metal borate comprising between 0.125 and 0.5 molar concentration of the carbonate and between 0.04 and 0.35 molar concentration of the borate.
    Type: Grant
    Filed: November 17, 1997
    Date of Patent: November 9, 1999
    Assignee: Kodak Polychrome Graphics, LLC
    Inventors: John L. Adkins, Dinesh P. Patel