Layers Sensitive To Different Spectral Regions Patents (Class 430/503)
  • Patent number: 5212052
    Abstract: A novel silver halide color photographic material is provided comprising on a support at least one blue-sensitive layer, one green-sensitive layer and one red-sensitive layer, wherein said blue-sensitive layer comprises at least one yellow dye-forming coupler represented by the following general formula (1) and/or (2) and said green-sensitive layer comprises at least one magenta dye-forming coupler represented by the following general formula (M): ##STR1## wherein X.sub.1 and X.sub.2 each represents an alkyl group, an aryl group or a heterocyclic group; X.sub.3 represents an organic residue which forms a nitrogen-containing heterocyclic group together with >N--; Y represents an aryl group or a heterocyclic group; and Z represents a group which separates from the remainder of the molecule when the coupler undergoes a reaction with an oxidation product of a developing agent; ##STR2## wherein R.sub.1 and R.sub.
    Type: Grant
    Filed: March 9, 1992
    Date of Patent: May 18, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kei Sakanoue, Akira Ogawa
  • Patent number: 5206124
    Abstract: A silver halide color photographic light-sensitive material is disclosed. The light-sensitive material is excellent in reproducibility of blue-green or green colored photographic subject. The light-sensitive material has a blue-sensitive layer, green-sensitive layer and a red-sensitive layer. The blue-sensitive layer has the maximum spectral sensitivity at a wavelength within the range of 415 to 470 nm and the spectral sensitivity at 480 nm of the blue-sensitive layer is not more than 35% of the maximum sensitivity. The green-sensitive layer has the maximum spectral sensitivity at a wavelength within the range of 530 nm to 560 nm and the spectral sensitivity at 500 nm of the green-sensitive layer is not less than 25% of the maximum sensitivity.
    Type: Grant
    Filed: February 11, 1992
    Date of Patent: April 27, 1993
    Assignee: Konica Corporation
    Inventors: Hiroshi Shimazaki, Yasushi Irie, Katuya Yabuuchi
  • Patent number: 5206126
    Abstract: A silver halide color photographic light-sensitive material is provided which comprises a support having thereon a blue-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer and a red-sensitive silver halide emulsion layer, having a spectral sensitivity distribution such that a wavelength weight-averaged in spectral sensitivity distribution of the red-sensitive silver halide emulsion layer is within a range of 595 to 625 nm; a maximum sensitivity wavelength in spectral sensitivity distribution of the blue-sensitive silver halide emulsion layer is within a range of 415 to 470 nm; and a sensitivity of the blue-sensitive silver halide emulsion layer at 480 nm does not exceed 35% of the sensitivity at the maximum sensitivity wavelength. The color photographic material makes it possible to faithfully reproduce the hues such as purple colors and green colors.
    Type: Grant
    Filed: February 3, 1992
    Date of Patent: April 27, 1993
    Assignee: Konica Corporation
    Inventors: Hiroshi Shimazaki, Yasushi Irie, Fumie Fukazawa
  • Patent number: 5206125
    Abstract: A silver halide color photographic material comprising a reflective support and coated thereon at least one each of a cyan dye-forming silver halide emulsion layer, a magenta dye-forming silver halide emulsion layer and a yellow dye-forming silver halide emulsion layer, each of the emulsion layers containing substantially silver iodide-free silver chloride or silver chlorobromide and respectively having spectral sensitivity peaks in different wavelength regions, at least one of the emulsion layers containing silver halide grains having an average grain size of 0.35 .mu.m to 0.65 .mu.m and a silver halide content of 0.19 g Ag/m.sup.2 or less, the total silver amount in all the silver halide emulsion layers being 0.78 g/m.sup.
    Type: Grant
    Filed: November 13, 1990
    Date of Patent: April 27, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Tadashi Ogawa
  • Patent number: 5200301
    Abstract: A color photographic recording material comprising at least one blue-sensitive silver halide emulsion layer containing at least one yellow coupler, at least one green-sensitive silver halide emulsion layer containing at least one magenta coupler, at least one red-sensitive silver halide emulsion layer containing at least one cyan coupler and, optionally, a silver halide emulsion layer with no color coupler, of which the silver halide coatings together, expressed as AgNO.sub.3, amount to no more than 0.8 g/m.sup.2 and of which the silver halides have a silver chloride component of at least 95 mol-%, characterized in that the silver halide coating of a silver halide emulsion layer containing a color coupler together with the silver halide coating of the silver halide emulsion layer with no color coupler, expressed as AgNO.sub.3, is from 0.2 to 0.6 g/m.sup.2 and the silver halide coating of all the other silver halide emulsion layers, expressed as AgNO.sub.3, amounts to no more than 0.2 g/m.sup.
    Type: Grant
    Filed: November 20, 1991
    Date of Patent: April 6, 1993
    Assignee: Agfa Gevaert Aktiengesellschaft
    Inventors: Kaspar Wingender, Wolfgang Schmidt
  • Patent number: 5190850
    Abstract: A silver halide photographic material having on a support a first light-sensitive layer containing a light-sensitive silver halide emulsion and a second light-sensitive layer containing a light-sensitive silver halide emulsion, wherein the first light-sensitive layer and/or a hydrophilic colloid layer contains a hydrazine compound, the second light-sensitive layer contains a redox compound capable of releasing a development inhibitor by oxidation, and the sensitivity of the first light-sensitive layer is higher by 0.2 to 1.0 than that of the second light-sensitive layer.
    Type: Grant
    Filed: May 14, 1991
    Date of Patent: March 2, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Minoru Sakai, Kazunobu Katoh
  • Patent number: 5185237
    Abstract: A novel silver halide color photographic material is provided which comprises a support having coated thereon at least three silver halide emulsion layers having maximum spectral sensitivities in at least three sensitive wavelength ranges of 400 nm to 500 nm, 500 nm to 570 nm and 650 nm to 730 nm and is sensitive to said three sensitive wavelength ranges to form yellow, magenta and cyan dye images, respectively, characterized in that said silver halide color photographic material has additionally at least one function to provide a maximum spectral sensitivity in wavelength range other than said three sensitive wavelength ranges and to form any of yellow, magenta or cyan dye image by an exposure to the light of said other wavelength range. A color image formation method is also disclosed which comprises exposing said silver halide color photographic material to light in a print exposure process in combination with a scanning exposure process, and then developing said silver halide color photographic material.
    Type: Grant
    Filed: March 30, 1992
    Date of Patent: February 9, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Kiyoshi Kawai
  • Patent number: 5183730
    Abstract: A silver halide photographic light-sensitive material improved in gradation and processing stability is disclosed. The material has a support and provided thereon a blue-sensitive emulsion layer, a green-sensitive emulsion layer and red-sensitive emulsion layer, wherein at least one of said color-sensitive emulsion layers contains; tabular silver halide grains having an aspect ratio of not less than 1.2; and core/shell type regular crystal silver halide grains of which the average projection area accounts for not more than 40% of that of the tabular grains.
    Type: Grant
    Filed: October 2, 1990
    Date of Patent: February 2, 1993
    Assignee: Konica Corporation
    Inventor: Toshihiko Yagi
  • Patent number: 5180657
    Abstract: A silver halide color photographic light-sensitive material which offers high chroma and excellent hue reproduction comprises a support having thereon a blue-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer and a red-sensitive silver halide emulsion layer, wherein the maximum sensitivity wavelength .lambda..sub.B of a spectral sensitivity distribution of said blue-sensitive silver halide emulsion layer is in the range of 410 nm.ltoreq..lambda..sub.B .ltoreq.470 nm; and the sensitivity of said blue-sensitive silver halide emulsion layer at 480 nm is not more than half of the sensitivity at said wavelength .lambda..sub.B. Preferably, the maximum sensitivity wavelength .lambda..sub.G of said green-sensitive layer is in the range of 530 nm.ltoreq..lambda..sub.G .ltoreq.560 nm and the sensitivity of said green-sensitive layer at the wavelength of 500 nm is not less than one-fourth of the sensitivity at SG.sub.max ; the maximum sensitivity wavelength .lambda..sub.
    Type: Grant
    Filed: December 18, 1990
    Date of Patent: January 19, 1993
    Assignee: Konica Corporation
    Inventors: Fumie Fukazawa, Yasushi Irie, Hiroshi Shimazaki, Katuya Yabuuchi, Satoru Shimba
  • Patent number: 5169746
    Abstract: A silver halide color photographic photo-sensitive material comprises a support, and a layer arrangement formed on the support. The layer arrangement includes a red-sensitive silver halide emulsion layer containing a color coupler capable of forming cyan dye upon reacting with an oxidation product of a developing agent, a green-sensitive silver halide emulsion layer containing a color coupler capable of forming magenta dye upon reacting with the oxidation product of the developing agent, and a blue-sensitive silver halide emulsion layer containing a color coupler capable of forming yellow dye upon reacting with the oxidation product of the developing agent. The red-sensitive layer has a sensitivity at 650 nm of 50% or less of its maximum sensitivity, and contains substantially no magenta-colored couplers.
    Type: Grant
    Filed: December 24, 1990
    Date of Patent: December 8, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Noboru Sasaki
  • Patent number: 5154995
    Abstract: A novel silver halide color photographic material is provided which comprises a support having coated thereon at least three silver halide emulsion layers having maximum spectral sensitivities in at least three sensitive wavelength ranges of 400 nm to 500 nm, 500 nm to 570 nm and 650 nm to 730 nm and is sensitive to said three sensitive wavelength ranges to form yellow, magenta and cyan dye images, respectively, characterized in that said silver halide color photographic material has additionally at least one function to provide a maximum spectral sensitvity in wavelength range other than said three sensitive wavelength ranges and to form any of yellow, magenta or cyan dye image by an exposure to the light of said other range. A color image formation method is also disclosed which comprises exposing said silver halide color photographic material to light in a print exposure process in combination with a scanning exposure process, and then developing said silver halide color photographic material.
    Type: Grant
    Filed: June 13, 1990
    Date of Patent: October 13, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Kiyoshi Kawai
  • Patent number: 5108882
    Abstract: A photographic element is described comprising a support having thereon(a) a silver halide emulsion layer where the silver halide is sensitized with a dye having the formula: ##STR1## Z.sub.1 and Z.sub.2 each independently represents the atoms necessary to complete a substituted or unsubstituted 5- or 6-membered heterocyclic nucleus,R.sub.1 and R.sub.2 each independently represents substituted or unsubstituted alkyl or substituted or unsubstituted aryl, andR.sub.3, R.sub.4, R.sub.5, and R.sub.6 each independently represents hydrogen, substituted or unsubstituted alkyl, substituted or unsubstituted aryl,X represents a counterion, and(b) at least one other red- or infrared-sensitive silver halide emulsion layer having a maximum sensitivity at a wavelength different from that of the (a) layer.
    Type: Grant
    Filed: September 26, 1989
    Date of Patent: April 28, 1992
    Assignee: Eastman Kodak Company
    Inventors: Richard L. Parton, Annabel A. Muenter, Anthony Adin
  • Patent number: 5096804
    Abstract: A silver halide color photographic material excellent in stability, which comprises at least one red-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer and at least one blue-sensitive silver halide emulsion layer on a support and having a specific photographic sensitivity of 320 or more, wherein the total silver content in said silver halide color photographic material is in the range of from 3.0 to 9.0 g/m.sup.2 and the weight ratio of the amount of gold per unit area to the amount of silver incorporated per unit area is in the range of from 1.times.10.sup.-8 to 6.0.times.10.sup.-6.
    Type: Grant
    Filed: January 29, 1991
    Date of Patent: March 17, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinpei Ikenoue, Norihiko Sakata
  • Patent number: 5091293
    Abstract: A high-speed color negative photographic material which comprises, a support having provided thereon, at least one red-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer and at least one blue-sensitive emulsion layer, and is designated so as to acquire a specific photographic sensitivity (defined in detailed description of the invention) of 800 or above, and has a combined total of silver coverages ranging from 3.0 g/m.sup.2 to 9.0 g/m.sup.2 so as to minimize an increase in fog, a decrease in photographic speed and deterioration in granularity, which heretofore have occurred in high-speed photographic materials during long-range storage before used. In addition, the present photographic material enables enhancement of pressure resistance and processing efficiency.
    Type: Grant
    Filed: June 25, 1990
    Date of Patent: February 25, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yasushi Nozawa, Hideto Ikoma, Keiji Mihayashi, Yoshihiko Shibahara
  • Patent number: 5075204
    Abstract: A silver halide color photosensitive material comprising a support having a metal surface with secondary diffuse reflection and a total reflectance of 0.5 or more in the visible wavelength region of 420 to 680 nm, said support having provided thereon a photosensitive silver halide emulsion layer containing a yellow coupler, a photosensitive silver halide emulsion layer containin a magenta coupler, and a photosensitive silver halide emulsion layer containing a cyan coupler and at least one non-photosensitive hydrophilic colloid layer, wherein the volume ratio R of the hydrophilic constituents in each photosensitive silver halide emulsion layer with respect to the non-hydrophilic constituents therein is 1.30 or less, and the photosensitive silver halide emulsion layer containing a color coupler which is arranged nearest the support has an R value of 1.20 or less.
    Type: Grant
    Filed: March 13, 1990
    Date of Patent: December 24, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keisuke Shiba, Tadashi Ogawa
  • Patent number: 5066572
    Abstract: This invention describes a substantially less pressure sensitive photographic film comprising a support, at least one light sensitive silver halide element, and an overlaying element comprising gelatin-grafted or case-hardened gelatin-grafted soft polymer particle composite element. The incorporation of such an overlaying composite particle cushioning layer does not compromise either the physical properties or physical integrity of the film unit. This invention is particularly suitable for highly pressure sensitive tabular grain emulsions.
    Type: Grant
    Filed: March 22, 1990
    Date of Patent: November 19, 1991
    Assignee: Eastman Kodak Company
    Inventors: Kevin M. O'Connor, Richard P. Szajewski, Pranab Bagchi
  • Patent number: 5061618
    Abstract: A photographic element is described comprising a support having thereon a silver halide emulsion layer where the silver halide is sensitized with a dye having the formula: ##STR1## wherein where Z.sub.1, Z.sub.2, Z.sub.3, R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, and X are as defined herein.
    Type: Grant
    Filed: March 28, 1990
    Date of Patent: October 29, 1991
    Assignee: Eastman Kodak Company
    Inventors: Richard L. Parton, Annabel A. Muenter, David A. Stegman
  • Patent number: 5057404
    Abstract: A silver halide color photographic material is disclosed having blue-sensitive, green-sensitive, and red-sensitive silver halide emulsion layers on a support, wherein said red-sensitive silver halide emulsion layer contains a dispersion of fine oleophilic grains formed by dispersing by emulsification a mixture comprising a water-insoluble and organic solvent-soluble homopolymer or copolymer and at least one coupler represented by formula (I) or formula (II), and the silver halide emulsion layer or non-light-sensitive layer of the material contains a dye represented by formula (III);wherein formula (I) is represented by ##STR1## wherein R.sub.11 represents an alkyl group, a cycloalkyl group, an aryl group or a heterocyclic group; R.sub.12 represents an acylamino group or an alkyl group; R.sub.13 represents a hydrogen atom, a halogen atom, an alkyl group or an alkoxy group, or R.sub.12 and R.sub.13 are bonded together to form a nitrogen-containing heterocyclic ring; Z.sub.
    Type: Grant
    Filed: January 12, 1989
    Date of Patent: October 15, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kokichi Waki, Tsumoru Hirano
  • Patent number: 5041359
    Abstract: The invention relates to a method of forming of a patterned photopolymer coating on a printing roller in which a photopolymer coating, present on said roller, and covered by a light-sensitive intermediate layer is exposed in a first stage to form an image of opaque and translucent parts in said intermediate layer.Subsequently the photopolymer layer is exposed via the image formed in the intermediate layer, after which the photopolymer layer is developed.Between abovementioned exposures, in case of a relatively thick, flexible, photopolymer, a period is waited to ensure that depressed parts of the photopolymer layer have returned to their original state.The invention also relates to a printing roller thus obtained.
    Type: Grant
    Filed: August 3, 1987
    Date of Patent: August 20, 1991
    Assignee: Stork Screens B.V.
    Inventor: Kooi, Johannes
  • Patent number: 5024925
    Abstract: A method of forming a color image which comprises subjecting a silver halide color reversal photographic material to imagewise exposure and then to color reversal processing, said color reversal photographic material comprising a support having provided thereon at least one red-sensitive emulsion layer, at least one green-sensitive emulsion layer and at least one blue-sensitive emulsion layer wherein the emulsion layers have an average silver iodide content of up to 5 mol %, and wherein the peak sensitivity of the red layer is in a range between 615 and 640 nm, wherein on the shorter wavelength side, 80% of the peak is in a range between 600 and 633 nm, 50% of the peak is in a range between 585 and 625 nm and 25% of the peak is in a range between 570 and 615 nm, and wherein on the longer wavelength side, 80% of the peak is in a range between 620 and 648 nm, 50% of the peak is in a range between 625 and 655 nm and 25% of the peak is in a range between 630 and 665 nm, wherein the wavelength difference between t
    Type: Grant
    Filed: July 21, 1989
    Date of Patent: June 18, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Naoyasu Deguchi
  • Patent number: 5021336
    Abstract: Color photographic recording material containing, on a reflective layer support, at least one blue sensitive, at least one green sensitive and at least one red sensitive layer of binder containing silver halide and optionally other light insensitive layers of binder, which binder has been hardened with an instant hardener, said recording material containing either from 100 to 900 mMol of soluble chloride and from 0 to 50 mMol of soluble bromide per mole of Ag or from 0 to 600 mMol of soluble chloride and from 5 to 50 mMol of soluble bromide per mol of Ag is distinguished by an exceptionally slight storage fog.
    Type: Grant
    Filed: July 13, 1990
    Date of Patent: June 4, 1991
    Assignee: Agfa Gevaert Aktiengesellschaft
    Inventors: Helmut Reuss, Bruno Mucke, Helmut Mader, Dieter Rockser
  • Patent number: 5019490
    Abstract: Silver halide photographic materials are disclosed, comprising a support carrying at elast one hydrophilic organic colloid layer in which at least one photographically useful reagent is dispersed with at least one of ethylenic addition polymerized polymer which contains at least 50% by weight of trifluorochloroethylene units.
    Type: Grant
    Filed: October 17, 1988
    Date of Patent: May 28, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hidetoshi Kobayashi, Osamu Takahashi
  • Patent number: 5019489
    Abstract: A combination in a color photographic silver halide element and process of at least one red-sensitive silver halide emulsion layer comprising a particular phenolic cyan dye-forming coupler with at least one green-sensitive silver halide emulsion layer comprising a particular pyrazolo[3,2-c]-s-triazole coupler and at least one blue-sensitive silver halide emulsion layer comprising a particular pivaloylacetanilide yellow dye-forming coupler enables improved color saturation of dye images, better relation of speed to grain characteristics and reduced unwanted spectral absorption of dye images formed. This combination is particularly useful in color photographic silver halide materials and processes for forming improved reversal dye images.
    Type: Grant
    Filed: July 26, 1989
    Date of Patent: May 28, 1991
    Assignee: Eastman Kodak Company
    Inventor: Arlyce T. Bowne
  • Patent number: 5015553
    Abstract: A CAD driven photoplotter selectively exposes a photographic imaging layer without affecting the underlying UV sensitive resist on a substrate to make a printed wiring board, for example. The image layer is developed on the board and used as an in situ mask for the underlying UV resist during exposure to UV. After UV exposure, the image layer is peeled off to allow conventional processing of the resist. The in situ mask is preferably applied in the form of a baseless, high contrast, high gamma emulsion layer bonded to the protective cover sheet over the uncured resist. To facilitate application, the emulsion layer is carried by a release paper which is removed before photoplotting. After UV exposure, the cover sheet and emulsion layer are integrally peeled from the resist.
    Type: Grant
    Filed: March 5, 1990
    Date of Patent: May 14, 1991
    Assignee: The Foxboro Company
    Inventors: Paul E. Grandmont, Harold Lake
  • Patent number: 5006457
    Abstract: The invention relates to a photographic recording material comprising a layer support and, arranged thereon, at least one photosensitive silver halide emulsion layer which contains an antifogging agent corresponding to formula (I) ##STR1## in which A, R.sub.1 and R.sub.2 are as defined in the specification. The antifogging agents according to the invention reduce fogging without significantly affecting gradation and improve the staility of the photographic material in storage.
    Type: Grant
    Filed: November 9, 1989
    Date of Patent: April 9, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hans Vetter, Hans hlschlager, Heinrich Odenwalder, Bernhard Morcher, Friedhelm Sommer, Lothar Rosenhahn
  • Patent number: 4978599
    Abstract: Combination of photosensitive elements for use in radiography consisting of a pair of radiographic fluorescent screens and a double-side coated silver halide radiographic element. Each screen is arranged adjacent to each silver halide layer and each screen is capable of imagewise emitting radiation to which the adjacent silver halide layer is sensitive when imagewise exposed to X radiation. The combination is characterized in that one fluorescent screen emits a first radiation in a first wavelength region of the electromagnetic spectrum and the other fluorescent screen emits a second radiation in a second wavelength region of the electromagnetic spectrum, and each silver halide layer is substantially insensitive to the radiation emitted by the opposite screen.
    Type: Grant
    Filed: July 11, 1989
    Date of Patent: December 18, 1990
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Sergio Pesce
  • Patent number: 4963465
    Abstract: Using a color photographic negative recording material which contains a most sensitive, a medium-sensitive and a least sensitive silver halide part layer for recording light from at least one of the spectral ranges of red, green and blue, at least one of the two more sensitive part layers containing a DIR coupler and the most sensitive partial layer and the least sensitive part layer containing a color coupler which couples faster than the color coupler in the medium-sensitive part layer by a factor of at least 1.5, the sharpness can be improved without impairing the color grain.
    Type: Grant
    Filed: December 28, 1989
    Date of Patent: October 16, 1990
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Reinhart Matejec, Ralf Buscher, Hans Langen
  • Patent number: 4954429
    Abstract: A color photographic material composed of a support having thereon at least one red-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer and at least one blue-sensitive silver halide emulsion layer, whereinwith respect to helium-cadmium laser light having a wavelength of 441.6 nm, the ratio of the sensitivity of the green-sensitive emulsion layer to that of the blue-sensitive emulsion layer and the ratio of the sensitivity of the red-sensitive emulsion layer to that of the blue-sensitive emulsion layer are not more than 0.10;with respect to argon laser light having a wavelength of 514.5 nm, the ratio of the sensitivity of the blue-sensitive emulsion layer to that of the green-sensitive emulsion layer and the ratio of the sensitivity of the red-sensitive emulsion layer to that of the green-sensitive emulsion layer are not more than 0.10; andwith respect to helium-neon laser light having a wavelength of 632.
    Type: Grant
    Filed: October 27, 1988
    Date of Patent: September 4, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yukihide Urata
  • Patent number: 4946767
    Abstract: A silver halide color photographic material composed of a support having thereon at least one light-sensitive silver halide emulsion layer, the material having a specific photographic sensitivity of at least 320 and a surface spectral reflectance of from 20% to less than 35% at a wavelength of 600 nm on the emulsion side film surface. The high sensitivity color photographic light-sensitive material provides superior exposure when used in an automatic exposure camera.
    Type: Grant
    Filed: September 23, 1988
    Date of Patent: August 7, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Hiroyuki Yamagami
  • Patent number: 4939078
    Abstract: A direct positive type silver halide photographic material and developing method therefor are disclosed. The photographic material have blue-, green- and red-sensitive emulsion layers and each of these emulsion layer contains at least two kinds of silver halide emulsion being different from each other in average grain size. The average grain diameter S of the emulsion having the smallest average grain size and the average grain diameter of the emulsion having the largest average grain size in each emulsion layer have a proportional relation of 1.6.ltoreq.L/S. The emulsion having the smallest average grain size is contained in a ratio of from 2 to 50% in the blue-sensitive layer and 2 to 40% in green- and red-sensitive emulsion layer.
    Type: Grant
    Filed: September 21, 1988
    Date of Patent: July 3, 1990
    Assignee: Konica Corporation
    Inventors: Kazuya Kuramoto, Bunzo Ueda, Yasuo Tosaka
  • Patent number: 4908300
    Abstract: A method of a processing of a silver halide color photographic material is disclosed. The process comprises a step of developing the exposed color photographic material and a step of treating the developed color photographic material with a bleach-fixing solution. The bleach-fixing solution contains an organic acid ferric complex. At least one layer of the emulsion layers of the photographic material contains silver halide grains containing from 0.5 to 25 mol % of silver iodide. The total dry-thickness of the photographic component layers contained in the photographic material is from 8 to 25 .mu.m and the swelling rate T1/2 of the photographic component layers is not more than 25 sec. The method is suitable for rapid processing of the fine grain-type high-speed silver iodide-containing color photographic material. The method uses a bleach-fixing bath enabling the rapid processing of the high-speed color photographic material.
    Type: Grant
    Filed: October 14, 1988
    Date of Patent: March 13, 1990
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Shigeharu Koboshi, Moeko Higuchi, Shinji Kadota
  • Patent number: 4853322
    Abstract: A light-sensitive silver halide emulsion is disclosed, which comprises light-sensitive silver halide grains in a binder, wherein tabular grains having a diameter of at least 0.15 .mu.m account for at least 70% of the total projected area of said silver halide grains, said tubular grains have a mean aspect ratio of not more than 8.0, and at least 50% (by number) of all of said tabular grains are tabular grains in which the ratio (b/a) of the thickness (b) of said tabular grain to the longest spacing (a) between two or more parallel twinning planes of said tabular grain is at least 5. A color photographic material using the light-sensitive silver halide emulsion for at least one of the silver halide emulsion layers other than the outermost silver halide emulsion layer is also disclosed.
    Type: Grant
    Filed: December 28, 1987
    Date of Patent: August 1, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Katsumi Makino, Yuichi Ohashi, Hiroshi Takehara, Yoichi Suga, Takekimi Shiozawa
  • Patent number: 4851327
    Abstract: The present invention relates to a photographic support having a secondary diffuse-reflective surface, and a color photosensitive material comprising at least one silver halide emulsion layer formed on the secondary diffuse-reflective surface of a photographic support. A photographic support of the present invention provides an image having remarkably improved brightness, saturation, tone reproducibility in shadow areas and sharpness. A color photosensitive material of the present invention provides an image having remakably improved brightness, saturation, tone reproducibility in shades and sharpness and also capable of rapid development.
    Type: Grant
    Filed: July 15, 1987
    Date of Patent: July 25, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tetsuro Fuchizawa, Masaru Sano, Seiichi Taguchi, Keisuke Shiba, Tadashi Ogawa
  • Patent number: 4839268
    Abstract: A silver halide color reversal pohotosensitive material is disclosed, comprising a plurality of silver halide emulsion layers on a substrate, wherein 50% or more of the total projected area of silver halide grains contained in at least one of said silver halide emulsion layers is occupied by tabular silver iodobromide grains having an average thickness of 0.5 micron or less, an average diameter of 0.5 micron or more, an average aspect ratio of at least 5/1, and a silver iodide content of 4.0 mol % or less, and said tabular silver iodobromide grains are negative-type silver halide grains forming a latent image mainly inside the grains.
    Type: Grant
    Filed: December 22, 1987
    Date of Patent: June 13, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Shinsuki Bando
  • Patent number: 4837392
    Abstract: New electrostatographic developers are provided, containing dual function polymeric binder/charge agents. The new developers contain toner particles comprising a vinyl addition binder polymer containing a quaternary phosphonium salt, wherein the phosphonium salt has a cationic portion comprising a phosphorus atom covalently bonded to the binder polymer.
    Type: Grant
    Filed: August 5, 1988
    Date of Patent: June 6, 1989
    Assignee: Eastman Kodak Company
    Inventors: James H. Anderson, Douglas E. Bugner, Lawrence P. DeMejo, Richard C. Sutton, John C. Wilson
  • Patent number: 4837393
    Abstract: New electrostatographic toners and developers are provided, containing dual function polyester binder/charge agents. The new toner particle has an average diameter in the range of 0.01 to 100 micrometers and comprises a binder polyester and a charge-control agent comprising a quaternary phosphonium salt, wherein the phosphonium salt has an anionic portion comprising a sulfonate group covalently bonded to a moiety containing at least one ester linkage to the binder polyester.
    Type: Grant
    Filed: August 5, 1988
    Date of Patent: June 6, 1989
    Assignee: Eastman Kodak Company
    Inventors: Peter S. Alexandrovich, Lawrence P. DeMejo, John C. Wilson
  • Patent number: 4830954
    Abstract: The sensitivity of color photographic negative films may be increased without loss of color quality or sharpness by applying at least one panchromatically sensitized, highly sensitive and black-coupling layer as uppermost, additional light sensitive and dye-forming layer on the side of the film facing the object and including in the negative material sufficient DIR-Coupler to produce an interimage effect of .gtoreq.10% in the yellow region, .gtoreq.25% in the magenta region and .gtoreq.15% in the cyan region.
    Type: Grant
    Filed: February 21, 1987
    Date of Patent: May 16, 1989
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventor: Reinhart Matejec
  • Patent number: 4824770
    Abstract: A process for producing a continuous tone color image comprising providing a light sensitive photographic element comprising a substrate bearing three imaging media coated thereon, said imaging media comprising:(1) an imaging medium capable of forming a yellow image upon imagewise exposure and processing,(2) an imaging medium capable of forming a magenta image upon imagewise exposure and processing,(3) an imaging medium capable of forming a cyan image upon imagewise exposure and processing,each imaging medium having a maximum spectral sensitivity at a wavelength different from that of the maximum spectral sensitivity of the other imaging media within the range 550 to 900 nm, the sensitivities at the wavelength of maximum spectral sensitivity of the media decreasing in order from the medium of shortest wavelength maximum spectral sensitivity to the medium of longest wavelength maximum spectral sensitivity, the difference in said sensitivities between the media of shortest and longest wavelength maximum spectra
    Type: Grant
    Filed: April 9, 1987
    Date of Patent: April 25, 1989
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Jonathan P. Kitchin, Stephen R. Powers, Keith A. Penfound, Peter J. Finn
  • Patent number: 4822728
    Abstract: A color image, wherein granularity is reduced under conditions allowing any sharpness loss to be kept under control, is obtained by image-wise exposing and developing in an alkaline water solution containing a color developer a silver halide color photographic element comprising a support base and at least a silver halide emulsion layer containing dispersed a non-diffusing hydrophobic coupler which upon reactiong with an oxidized developing agent forms a non-diffusing dye, characterized by the fact that said emulsion contains dispersed therein oil droplets, said droplets containing said non-diffusing coupler dissolved therein, and furthermore polymer particles in a quantity sufficient to obtain controlled smearing of the image-forming dye.
    Type: Grant
    Filed: December 11, 1987
    Date of Patent: April 18, 1989
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Marco Loiacono, Angelo Vallarino
  • Patent number: 4818664
    Abstract: A process for processing a silver halide color photographic material which comprises processing, after color development, a silver halide color photographic material with a processing solution having a bleaching faculty using an aminopolycarboxylic acid ferric complex salt as an oxidizing agent, said color photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer and at least one compound releasing by the reaction with an oxidation product of a developing agent a group releasing or forming development inhibitor by the reaction with another molecule of an oxidation product of a developing agent.
    Type: Grant
    Filed: May 20, 1987
    Date of Patent: April 4, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinji Ueda, Keiji Mihayashi, Seiji Ichijima
  • Patent number: 4818673
    Abstract: A method for processing a silver halide color photographic material is disclosed, which comprises processing an imagewise exposed silver halide color photographic material comprising a support having thereon at least one silver halide emulsion layer comprising silver chloride or silver chlorobromide containing at least 80 mol % of silver chloride with a color developing solution and thereafter processing the material with a bleach-fixing solution, wherein the bleach-fixing solution contains a ferric complex salt of an organic acid and from about 1.times.10.sup.-2 to about 2 mol of bromide ions and/or from about 5.times.10.sup.-4 to about 5.times.10.sup.-2 mol of iodide ions per liter.The method for processing a silver halide color photographic material according to the present invention is excellent in desilvering ability, and enables rapid processing to be conducted.
    Type: Grant
    Filed: August 5, 1987
    Date of Patent: April 4, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinji Ueda, Kazunori Hasebe, Junya Nakajima
  • Patent number: 4816378
    Abstract: An imaging process which comprises the steps of:(i) providing a first radiation sensitive element comprising a transparent base having coated thereon at least three imaging media each capable of forming a color image upon imagewise exposure and processing, each media having a maximum sensitivity at a wavelength different from of the other imaging media and the wavelength of the maximum absorption of the color image formed by each imaging medium differing from the other imaging media by at least 40 nm;(ii) obtaining color separation information representative of the cyan, magenta and yellow and optionally black content of a color original, or electronically generated image,(iii) exposing said first radiation sensitive element of step (i) to at least three independently modulated sources of radiation, such that a latent image representative of at least the cyan, magenta and yellow information of step (ii) is formed in individual color forming media;(iv) processing said exposed radiation sensitive element to pro
    Type: Grant
    Filed: April 13, 1987
    Date of Patent: March 28, 1989
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Stephen R. Powers, Peter J. Finn, Michael G. Fisher
  • Patent number: 4804619
    Abstract: A silver halide color photographic material improved in image quality such as sharpness and graininess is disclosed. The silver halide color photographic material is comprises support having thereon photographic component layers comprising at least two silver halide emulsion layers, adjacently arranged to each other, having the same color sensitivity and different speed from each other. In this photographic material the highest speed layer among these emulsion layers contains a DIR compound capable of releasing a diffusible development inhibitor or a diffusible compound capable of releasing a development inhibitor, and the total thickness of the silver halide emulsion layers is within the range of from 1.5 .mu.m to 5 .mu.m, and the silver halide emulsion layers are allowed to have the interposition of a non-light-sensitive intermediate layer.
    Type: Grant
    Filed: October 23, 1987
    Date of Patent: February 14, 1989
    Assignee: Konica Corporation
    Inventors: Yoshitaka Yamada, Masao Iwamura
  • Patent number: 4792518
    Abstract: A silver halide color reversal reflection print photosensitive material comprises at least one blue-sensitive layer, at least one green-sensitive layer and at least one red-sensitive layer on a support. In the characteristic curves of the color sensitive layers, a fluctuation width of point-gammas and absolute values of point-gammas are defined. The distribution of the grain size of the silver halide grains in silver halide emulsions contained in the color sensitive layer can be controlled by forming the grains in the presence of a silver halide solvent.
    Type: Grant
    Filed: April 22, 1988
    Date of Patent: December 20, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shigeru Kuwashima, Akio Mitsui, Masaru Sano
  • Patent number: 4791049
    Abstract: A silver halide photographic material comprising a support having thereon at least one silver halide emulsion layer, wherein the silver halide photographic material contains at least one compound represented by the following general formula (I):A--Time).sub.t X (I)wherein A represents an oxidation reduction moiety comprising an atomic group which does not enable --Time).sub.t X to be released until the oxidation reduction moiety is oxidized during photographic development processing; Time represents a timing group which is connected to A through a sulfur atom, a nitrogen atom or an oxygen atom; t represents an integer of 0 or 1; and X represents a group represented by the following general formula (II): ##STR1## wherein R represents a straight chain or branched chain alkylene group, a straight chain or branched chain alkenylene group, a straight chain or branched chain aralkylene group or an arylene group; Z represents a polar substituent; Y represents ##STR2## R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.
    Type: Grant
    Filed: April 23, 1987
    Date of Patent: December 13, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tetsuro Kojima, Shigeo Hirano, Hideo Usui
  • Patent number: 4780399
    Abstract: A color photographic material having at least one red-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer and at least one blue-sensitive silver halide emulsion layer, characterized in that a blue-sensitive silver halide emulsion which is used in at least one of the blue-sensitive silver halide emulsion layer or layers contains silver halide grains of an average size of 0.4.mu. or less and at least one sensitizing dye represented by formula I or II: ##STR1## wherein Z.sup.1, Z.sup.2 and Z.sup.3 each represent an atomic group necessary for completing an oxazole, benzoxazole, naphthoxazole, thiazole, benzothiazole, naphthothiazole, imidazole, benzimidazole or naphthoimidazole ring; R.sup.1, R.sup.2, R.sup.3 and R.sup.4 each represent a substituted or unsubstituted alkyl or aryl group; (X.sup.-) represents an acid anion; and n represents zero or 1.
    Type: Grant
    Filed: June 17, 1986
    Date of Patent: October 25, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yukihide Urata
  • Patent number: 4777122
    Abstract: A high sensitivity multilayer color photographic material is disclosed. The material is comprised of a support base having coated thereon red-sensitive, green-sensitive and blue-sensitive silver halide emulsion layers associated with non-diffusing image-forming couplers. The red-sensitive silver halide emulsion layer comprises an upper, an intermediate and a lower silver halide emulsion layer, sensitive to visible light in the same or substantially the same spectral wavelength range, with the sensitivity of the layers decreasing in order from the upper layer to the lower layer. The green-sensitive silver halide emulsion layer comprises an upper and a lower silver halide emulsion layer, sensitive to visible light in about the same spectral wavelength range, with the sensitivity of the layers decreasing in order from the upper layer to the lower layer.
    Type: Grant
    Filed: February 24, 1987
    Date of Patent: October 11, 1988
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Walter Beltramini
  • Patent number: 4775617
    Abstract: A silver halide color photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer containing monodispersed silver halide grains wherein at least 50% of the total projected area of the monodispersed silver halide grains are tabular silver halide grains which have an aspect ratio of not less than 5.The silver halide color photographic material has improved image sharpness, graininess and tone reproducibility.
    Type: Grant
    Filed: July 17, 1986
    Date of Patent: October 4, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Kensuke Goda
  • Patent number: 4772546
    Abstract: A silver halide photographic material is described, having at least one light-sensitive silver halide emulsion layer containing an iodine-containing silver halide on a support and having one or more auxiliary layers on the outermost surface of a light-sensitive silver halide emulsion layer positioned farthest from the support, wherein at least one of the auxiliary layers contains a substantially non-light-sensitive silver halide emulsion or a silver halide emulsion containing grains whose inner part or surface part is fogged, and the material contains at least one compound represented by formula (I) ##STR1## wherein R, X, Y, Z, and n are described in the specification.
    Type: Grant
    Filed: October 10, 1986
    Date of Patent: September 20, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naoyasu Deguchi, Tetsuro Kojima, Hideo Miyazaki, Shigeru Ohno, Koki Nakamura
  • Patent number: 4766057
    Abstract: A method of forming a color image which comprises processing, after imagewise exposure, with a color developing solution which contains not more than 0.
    Type: Grant
    Filed: September 4, 1987
    Date of Patent: August 23, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Nobuo Sakai