Ammonium Salt Patents (Class 430/528)
  • Patent number: 5674671
    Abstract: The invention relates to the use of a fluoropolymer and a fluorochemical surface active agent in combination for improving the antistatic behaviour of surfaces. In one embodiment, the invention provides a light-sensitive material possessing good initial antistatic properties and retaining good properties even after aqueous processing.
    Type: Grant
    Filed: June 27, 1995
    Date of Patent: October 7, 1997
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Marc Brandon, Dirk H. C. Arren, Rudolph J. Dams
  • Patent number: 5604083
    Abstract: The invention is directed to an antistatic polymeric film base comprising a polymeric film having coated on at least one side thereof an antistatic layer comprising the reaction product of (1) a water-soluble, electrically conductive polymer containing carboxylic groups and (2) a water-soluble polymer containing oxazoline groups, and to a photographic element comprising at least one silver halide emulsion layer on said antistatic polymeric film base. This antistatic layer may be present as a backing layer on the side of the film base opposite the silver halide emulsion layer, as a subbing layer between the film base and the emulsion layer in a single or double side coated photographic element, and/or as a subbing layer between the film base and a different backing layer.
    Type: Grant
    Filed: December 5, 1995
    Date of Patent: February 18, 1997
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Alberto Valsecchi, Giorgio Spazzapan, Renzo Torterolo, Soonkun Kang
  • Patent number: 5451495
    Abstract: A recording element having at least one layer comprising a crosslinked polymer having polymeric backbone moieties and crosslinking moieties, the polymeric backbone moieties containing tertiary nitrogen atoms, the crosslinking moieties connecting polymeric backbone moieties at the teritary nitrogen atoms by conversion of the tertiary nitrogen atoms to quaternary amine, the crosslinking moiety having the structure ##STR1## where R' is independently alkyl or aryl and m is an integer of from 1 to 10.
    Type: Grant
    Filed: August 15, 1994
    Date of Patent: September 19, 1995
    Assignee: Eastman Kodak Company
    Inventors: Catherine A. Falkner, John J. Fitzgerald, Dennis J. Savage, Paul D. Yacobucci
  • Patent number: 5411844
    Abstract: A coating composition for applying a layer to a photographic element and the resulting photographic element comprising gelatin, water and from 0.3 to 1 gm/100 gms of the composition of a surfactant mixture of 15 to 70 percent by weight of a dioctyl sulfosuccinate, sodium salt or di-fluoroalkylsulfosuccinate, sodium salt, from 35 to 75 percent by weight of a nonylphenoxy polyglycidyl alcohol, and from 3 to 14 percent by weight of perfluoro-octyl sulfonamido, N-hydrogen, N-propylene trimethylammonium iodide based on the total weight of the surfactant mixture; when a dioctyl sulfosuccinate, sodium salt is used, the minimum amount thereof is 0.15 gm/100 gm of coating composition.
    Type: Grant
    Filed: March 31, 1994
    Date of Patent: May 2, 1995
    Assignee: Eastman Kodak Company
    Inventor: Michael W. Orem
  • Patent number: 5362613
    Abstract: A cationic high-molecular weight compound is represented by formula (I): ##STR1## wherein R.sup.1 and R.sup.2 may be the same or different and each represents a hydrogen atom or C.sub.1-6 lower alkyl group; L.sup.1 represents --COO-- or --CONH-- and L.sup.2 represents a divalent group; J represents a C.sub.1-20 alkylene group or C.sub.7-20 aralkylene group; R.sup.3, R.sup.4 and R.sup.5 may be the same or different and each represents a C.sub.1-20 alkyl group or C.sub.7-20 aralkyl group; X.sup.
    Type: Grant
    Filed: January 15, 1993
    Date of Patent: November 8, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kentaro Shiratsuchi, Fumio Kawamoto
  • Patent number: 5326688
    Abstract: A solvent mixture of 8 to 30 weight percent of n-propyl acetate 1-methoxy-2-propanol or cyclohexane, 50 to 55 weight percent of acetone and the balance methanol is employed in a coating composition for applying a polymeric antistatic layer.
    Type: Grant
    Filed: May 27, 1993
    Date of Patent: July 5, 1994
    Assignee: Eastman Kodak Company
    Inventors: Ronald M. Stimson, James Skoronski, Thomas M. Smith, Jack J. Holt
  • Patent number: 5306606
    Abstract: Disclosed is a biaxially stretched polyester film which comprises a polyester film and a coating layer composed of a resin composition comprising (A) an acrylic polymer and/or (B) a polyester copolymer and at least (C) a polymer containing a monomer having a sulfonic acid group neutralized with an organic amine in its recurring unit or (D) a polymer containing a monomer having a sulfonic acid group neutralized with ammonium on at least one surface of the polyester film.
    Type: Grant
    Filed: December 23, 1991
    Date of Patent: April 26, 1994
    Assignee: Konica Corporation
    Inventors: Noriki Tachibana, Yoshihiro Wada, Tohru Kobayashi
  • Patent number: 5258276
    Abstract: A ternary surfactant system useful in reducing the propensity of silver halide elements to generate unwanted static is described. This ternary system comprises a mixture of a specific anionic and two specific nonionic surfactants and produces a surprising synergistic result. A solution of this ternary system is also useful in reducing static produced on the surface of an X-ray intensifying screen.
    Type: Grant
    Filed: May 15, 1992
    Date of Patent: November 2, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Allan R. Schoenberg, Ming-tsai Shu
  • Patent number: 5254445
    Abstract: A method of manufacturing silver halide photographic light-sensitive material with little habitual curling is disclosed. The material, after being coated with a silver halide emulsion layer and antistatic layer on the polyester support, is rolled around a core with its emulsion side facing outside, and then heated at the temperature not less than 30.degree. C. After the heat-treatment, the material is cut and re-rolled on a commercial size core with its emulsion side facing inside.
    Type: Grant
    Filed: March 20, 1992
    Date of Patent: October 19, 1993
    Assignee: Konica Corporation
    Inventors: Yasuhiko Takamuki, Takeshi Sampei
  • Patent number: 5244773
    Abstract: A silver halide photographic light sensitive material having high contrast photographic characteristics and excellent antistatic properties is provided by incorporating a hydrazine compound represented by formula 1 or 2 and a nucleation-promoting compound selected from the group consisting of amine compounds and quaternary onium salts; and by coating an electrically conductive layer on a support.
    Type: Grant
    Filed: January 24, 1992
    Date of Patent: September 14, 1993
    Assignee: Konica Corporation
    Inventors: Yasuhiko Muramatsu, Takeshi Sampei
  • Patent number: 5135843
    Abstract: The improved silver halide photographic material comprises a support having an antistatic coating thereon that contains a water-soluble conductive polymer, hydrophobic polymer particles and a curing agent which is a bifunctional ethylene oxide type curing agent that is to be cured by exposure to electron beams or X-rays. This silver halide photographic material may contain a tetrazolium compound or a hydrazine compound in order to prevent desensitization due to aging. At least one hydrophilic colloidal layer may be provided on the antistatic coating, which colloidal layer contains an epoxy curing agent having a hydroxy group.
    Type: Grant
    Filed: July 27, 1990
    Date of Patent: August 4, 1992
    Assignee: Konica Corporation
    Inventors: Yasuhiko Takamuki, Takatoshi Yamada, Takeshi Habu, Toshiharu Nagashima
  • Patent number: 5128233
    Abstract: A film support having an auxiliary layer coated over an antistatic layer coated on one side thereof is described. This element, which is particularly useful for the application of subsequently applied photosensitive layers on side opposite said auxiliary layer, comprises gelatin, a crosslinking agent, optionally a conductive polymer and an adhesion promoting amount of an adhesion agent, said adhesion agent selected from the group consisting of: compounds containing at least one --NH.sub.2 group and compounds containing at least two --NH groups, wherein said adhesion agent is sufficiently soluble in water that said adhesion promoting amount of adhesion agent may be dissolved in the dispersion used to coat said auxiliary layer, with the proviso that said adhesion agent is not malonamide. Preferred adhesion agents are urea, thiourea and 2-imidazolidone. Improved adhesion of the auxiliary layer to the antistatic layer is achieved.
    Type: Grant
    Filed: January 7, 1992
    Date of Patent: July 7, 1992
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Rudolf W. Beisswenger, Kurt B. Gundlach
  • Patent number: 5108885
    Abstract: A silver halide photographic material comprising a support having thereon at least one silver halide emulsion layer, wherein at least one of the layers of the photographic material is a layer which is crosslinked after coating a coating liquid comprising a polymeric compound which has at least repeating units represented by formula (I) or formula (II): ##STR1## wherein, L.sub.1, L.sub.2, L.sub.3, L.sub.4, L.sub.5, L.sub.6, L.sub.7, L.sub.8 and L.sub.9, which may be the same or different, each represents a divalent linking group; X.sub.1 and X.sub.2, which may be the same or different, each represents a crosslinkable groups which contain an activated vinyl component; Y.sub.1, Y.sub.2, Y.sub.3 and Y.sub.4, which may be the same or different, each represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, an aralkyl group or a crosslinkable group which contains an activated vinyl component; Z.sub.1 and Z.sub.
    Type: Grant
    Filed: July 3, 1990
    Date of Patent: April 28, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shoichiro Yasunami, Yasuo Mukunoki
  • Patent number: 5102488
    Abstract: The present invention provides a method for forming a cured-resin layer having a surface with antistatic properties. An ultraviolet-curable resin having antistatic properties is laminated on an ultraviolet-curable resin for forming an electrostatic cured surface by curing and the two layers then being simultaneously cured by ultraviolet irradiation thereon. A cured-resin layer is thereby obtained where the surface layer of the cured resin is provided with antistatic properties, and is strongly held by chemical bonding.
    Type: Grant
    Filed: October 1, 1990
    Date of Patent: April 7, 1992
    Assignee: Mitsubishi Petrochemical Co., Ltd.
    Inventors: Kazuhide Hayama, Noritaka Hosokawa, Takao Yazaki, Masataka Noro
  • Patent number: 5098822
    Abstract: Disclosed is an antistatic layer for a plastic film having an antistatic layer comprising a reaction product of a water-soluble conductive polymer, a hydrophobic latex and an epoxy type hardener, characterized in that said hydrophobic latex comprises a hydrophobic polymer having at least one of an alkylene oxide chain and an amide group.
    Type: Grant
    Filed: December 6, 1990
    Date of Patent: March 24, 1992
    Assignee: Konica Corporation
    Inventors: Noriki Tachibana, Yoichi Saito
  • Patent number: 5082730
    Abstract: Disclosed herein are a stretched antistatic laminate film comprising at least one coating layer containing a polymer having pyrrolidium rings in the main molecular chain, and a polyester film layer, a magnetic recording medium using the same, and a recording material for heat sensitive transfer printing using the same.
    Type: Grant
    Filed: December 2, 1988
    Date of Patent: January 21, 1992
    Assignee: Diafoil Company, Limited
    Inventors: Naohiro Takeda, Yuzo Otani, Nariaki Okajima, Masahiro Kita
  • Patent number: 5077185
    Abstract: An element comprising a support having an antistatic layer applied to one side thereof and wherein said antistatic layer also contains antihalation dyes absorbing light at 440 nm and below and with matte particles therein, is described. A photosensitive layer, e.g., photographic silver halide layer can be coated on the opposite side of the support. The element exhibits excellent antistatic and antihalation properties as well as low dye stain and improved dimensional stability, compared to elements wherein the antihalation dyes are coated in a separate layer. These products are especially useful as so-called "bright-light films" that are designed for contact printing and the like.
    Type: Grant
    Filed: March 28, 1991
    Date of Patent: December 31, 1991
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Thomas B. Cho, Ray B. Myers
  • Patent number: 4968599
    Abstract: Fluoroalkyl surface active agents are provided as effective coating aids for hydrophilic colloid coating compositions for photographic materials. These coating aids are of the formula: ##STR1## where M is a cation,x and y are each independently 0 or an integer of from 1 to 6 such that the sum of x and y is an integer of from 2 to 6, andp and q are each independently 1 or 2, with the proviso that when the sum of x and y is 6, p and q are each 1, and when the sum of x and y is 2, p and q are each 2.
    Type: Grant
    Filed: June 29, 1989
    Date of Patent: November 6, 1990
    Assignee: Eastman Kodak Company
    Inventors: Alan R. Pitt, Trevor J. Wear
  • Patent number: 4914018
    Abstract: An improved antistatic base comprises a polymeric support film having coated thereon in sequence a first antistatic layer comprising a quaternary polyelectrolyte compound and a polymeric hydrophobic binder and a second protective layer comprising a polymeric hydrophobic binder, wherein said quaternary polyelectrolyte compound is a homopolymer or a copolymer of a diallyldialkylammonium salt compound.The antistatic base is particularly useful as a support for light-sensitive silver halide photographic elements.
    Type: Grant
    Filed: December 1, 1988
    Date of Patent: April 3, 1990
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Mauro Besio, Alberto Valsecchi
  • Patent number: 4908155
    Abstract: A surface-active block copolymer which comprises chemically linked polymeric blocks (A) and (B), block (A) of said copolymer consisting of at least one homo- or copolymerized non-polar alpha,beta-ethylenically unsaturated monomer and block (B) of said copolymer is derived by polymerizing an alpha-beta ethylenically unsaturated monomer containing an epoxy group and transforming the epoxy group into an hydroxy-substituted ionic group, preferably an anionic group. These block copolymers are used as dispersing agents in aqueous dispersions, including polymeric latex dispersions, and as plasticizing agent in hydrophilic colloid layers, including colloid layers containing a dispersed light-sensitive silver halide emulsion or other auxiliary substances for photographic materials.
    Type: Grant
    Filed: November 13, 1987
    Date of Patent: March 13, 1990
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Luc E. Leemans, Herman J. Uytterhoeven, Philippe J. Teyssie, Roger M. Fayt, Nikolaas C. de Jaeger
  • Patent number: 4898808
    Abstract: An antistatic silver halide photographic light-sensitive material having a support, provided thereon, at least one light-sensitive layer and at least one non-light-sensitive layer is disclosed. Said at least one non-light-sensitive layer comprises a polymer compound consisting essentially of a repeated structural unit represented by Formula [I], and a formamide compound represented by Formula [II]; ##STR1## wherein Z, and Z.sub.2 represent the group of the atoms necessary to form a six-membered ring with--N.sup..sym. --; R represents a divalent group; R.sub.1 and R.sub.2 represent independently one selected from the group consisting of an alkyl group and an aryl group; R.sub.3 represents a hydrocarbon group; R.sub.5 and R.sub.6 represent independently a hydrogen atom or an alkyl group; X.sub.1.sup..crclbar. and X.sub.2.sup..crclbar. represent an anion; a and l represent an integer of 0 and 1.
    Type: Grant
    Filed: January 17, 1989
    Date of Patent: February 6, 1990
    Assignee: Konica Corporation
    Inventors: Noriki Tachibana, Masato Nishizeki, Nobuaki Kagawa
  • Patent number: 4897329
    Abstract: A method for preparing a lithographic printing plate and a light-sensitive material for a lithographic printing plate are disclosed. The method comprises providing a light-sensitive material comprising an electroconductive support having a hydrophilic surface. Provided on the surface is a light-sensitive layer which contains an electroconductive agent as well as a photoconductive insulating layer. The material is imagewise exposed and then electrophotographically processed to form an electrostatic latent image on the photoconductive insulating layer. The exposed material is developed with developer particles which are opaque to the light which the light-sensitive layer is sensitive. The light-sensitive layer of the developed material is exposed through the image. The exposed or unexposed areas of the light-sensitive layer are then removed together with the photoconductive insulating layer. The lithographic printing plate produced has excellent resolving power and does not cause printing stains.
    Type: Grant
    Filed: January 16, 1987
    Date of Patent: January 30, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Takao Nakayama
  • Patent number: 4891306
    Abstract: A static-inhibited photographic light-sensitive material is provided by incorporating a fluorine-containing block polymer derived from a polymerizable hydrophobic monomer containing at least one fluorine atom and a polymerizable hydrophilic monomer, as an antistatic agent in at least one layer thereof. Unlike known antistatic agents and methods, the use of the above antistatic agent does not adversely affect the photographic characteristics, antitack property, marring resistance, etc., of the photographic light-sensitive material.
    Type: Grant
    Filed: November 14, 1988
    Date of Patent: January 2, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shigeki Yokoyama, Yukio Maekawa
  • Patent number: 4886735
    Abstract: Photopolymerizable recording materials suitable for producing photoresist layers and lithographic printing plates are composed of one or more photopolymerizable olefinically unsaturated organic compounds, optionally a polymeric binder, one or more photopolymerization initiators, a color-forming system which on irradiation with actinic light causes an increase in the color intensity of the recording material, a sensitizer and optionally further additive and/or auxiliary substances, and contain as the color-forming system(a) one or more colorless or virtually colorless organic compounds which are oxidizable to colored compounds, and(b) a photooxidant for the colorless or virtually colorless organic compound(s) (a),wherein photooxidant (b) comprises an organic salt with a substituted or unsubstituted hetaromatic system, this hetaromatic system having one or more built-in groups of the general formula (I) ##STR1## where R is substituted or unsubstituted alkenyl, alkynyl, hetaryl, alkoxycarbonyl, carbamoyl, alkyls
    Type: Grant
    Filed: May 17, 1988
    Date of Patent: December 12, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Andreas Boettcher, Martin Fischer, Reinhard Aldag, Thomas Bluemel
  • Patent number: 4847187
    Abstract: Disclosed is a light-sensitive silver halide photographic material comprising at least one silver halide emulsion layer on at least one side of a support and at least auxiliary layer adjacent to the silver halide emulsion layer, the silver halide emulsion layer containing a surface latent type silver halide emulsion and a silver halide emulsion having fog internally of the grains, and the auxiliary layer containing a compound represented by the formula (I) shown below:RfSO.sub.3 M Formula (I)wherein Rf is a substituted or unsubstituted alkyl group or a substituted or unsubstituted aralkyl group, containing at least 3 fluorine atoms, and M represents hydrogen atom, an alkali metal or ammonium group.According to the present invention, a light-sensitive silver halide photographic material improved in antistatic performance and also improved in storability without accomplaniment of lowering in sensitivity, which can give images with sensitivity, high contrast as well as high covering power is provided.
    Type: Grant
    Filed: August 28, 1987
    Date of Patent: July 11, 1989
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Kouzi Ono, Mikio Kawasaki
  • Patent number: 4810624
    Abstract: To protect photographic films from imaging by static discharges during manufacturing and customer use, copolymers of sulfonated monomers and primary amine monomers are coated on a film base and crosslinked with an aldehyde such as glutaraldehyde, or other colloid hardener giving a water-resistant, permanent, conductive (i.e., antistatic) layer.
    Type: Grant
    Filed: September 2, 1987
    Date of Patent: March 7, 1989
    Assignee: E. I. DuPont de Nemours and Company
    Inventors: William M. Hardam, Frank L. Schadt, III, Arthur J. Taggi
  • Patent number: 4756991
    Abstract: Fluorescent dry nonelectroscopic toner comprising fluorescent pigmented organic resin particles having a size distribution of 0.2 to 50 micrometers, surface coated with at least 0.1% by weight of silicone oil or fluorocarbon compound, in combination with at least 0.5% by weight of a water soluble, polymeric quaternary ammonium compound as defined. The fluorescent toner is useful in color developing positive- and negative-working photosensitive elements. The toners provide good toning quality and excellent lack of background color, together with stability on aging.
    Type: Grant
    Filed: March 11, 1987
    Date of Patent: July 12, 1988
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Eugene L. Grubb
  • Patent number: 4703000
    Abstract: Provided herewith is an anti-brick/anti-static composition useful for treating film surfaces. The composition comprises (i) an anionic or cationic surfactant exhibiting anti-static properties, and (ii) a similar charged inorganic particle, e.g., a negatively charged silica or positively charged alumina coated silica, having an average particle size of less than 0.1 micron. Upon coating a film surface with the composition, good anti-static properties are realized without experiencing problems with bricking or blocking of the film. The composition is particularly useful in coating microfilm since it also provides the anti-brick/anti-static properties without deleteriously effecting the viewing capabilities of the film over a wide range of magnifications.
    Type: Grant
    Filed: September 30, 1985
    Date of Patent: October 27, 1987
    Assignee: James River Graphics, Inc.
    Inventor: George R. Hodgins
  • Patent number: 4649102
    Abstract: A silver halide photographic light-sensitive material is described, comprising a support having provided thereon at least one silver halide emulsion layer, wherein there is at least one hydrophilic colloidal layer containing at least one nonionic surface active agent and at least one anionic surface active agent having a polyoxyethylene group therein.
    Type: Grant
    Filed: January 10, 1986
    Date of Patent: March 10, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yasuo Mukunoki, Shigeki Yokoyama, Hiroshi Kawasaki, Ryoichi Nemori, Tetsuo Takeuchi
  • Patent number: 4628025
    Abstract: A support for photographic use comprising a polyester film is disclosed which contains at least one compound of the following formula (I) and at least one quaternary ammonium salt of the following formula (II): ##STR1## a hydroxyl group, a nitro group, an amino group or a hydrogen atom; R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are each a hydrogen atom, a halogen atom, an alkoxy group, an alkyl group, an aryloxy group, an aralkoxy group, a hydroxyalkyl group, --(OCH.sub.2).sub.m OH (m is an integer or 1 to 4) or ##STR2## B, C and D are not simultaneously at least one member selected from the group consisting of a hydrogen atom, a nitro group and an amino group); ##STR3## (wherein R.sub.6, R.sub.7, R.sub.8 and R.sub.9 are each an alkyl group, an aralkyl group or an allyl group; X is an anion; and n represents the number of charges on X).
    Type: Grant
    Filed: July 12, 1985
    Date of Patent: December 9, 1986
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Toshiki Komaita, Takanori Nakadate, Yoshiyuki Funabashi, Kazuto Kiyohara
  • Patent number: 4610955
    Abstract: Antistatic compositions are disclosed comprising a hydrophilic binder, surface-active polymer having polymerized oxyalkylene monomers and an inorganic salt characterized in that the salt is selected from the group consisting of inorganic tetrafluoroborates, perfluoroalkyl carboxylates, hexafluorophosphates and perfluoroalkyl sulfonates.
    Type: Grant
    Filed: December 24, 1985
    Date of Patent: September 9, 1986
    Assignee: Eastman Kodak Company
    Inventors: Janglin Chen, James E. Kelly, James Plakunov
  • Patent number: 4596766
    Abstract: A silver halide photographic material is disclosed comprising a support having thereon at least one layer containing a nonionic surface active agent having a polyoxyethylene group and a fluorine-containing compound, wherein the element composition of the surface of said layer has a ratio of F.sub.ls peak intensity/C.sub.ls peak intensity in the range of 0.3 to 2.0 when measured by an X-ray photoelectron spectrometry.
    Type: Grant
    Filed: October 9, 1984
    Date of Patent: June 24, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Ryoichi Nemori, Hiroshi Kawasaki, Yasuo Mukunoki
  • Patent number: 4585730
    Abstract: As part of a photographic film, a backing layer is coated with an auxiliary layer designed to conduct antistatic properties from an antistatic underlayer to the surface of the backing.
    Type: Grant
    Filed: January 16, 1985
    Date of Patent: April 29, 1986
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Thomas B. Cho
  • Patent number: 4562120
    Abstract: An optically-black coating that is adherent to metal surfaces, has a low reflectance of light in the range of about 2000 to 7500 Angstroms, and is chemically stable up to at least 750.degree. C., consists essentially of a minor proportion of an inorganic silicate binder and a major proportion of a particulate mixture of cobaltic oxide and zinc oxide in the weight ratio range of 4/1 to 1/1.
    Type: Grant
    Filed: August 10, 1984
    Date of Patent: December 31, 1985
    Assignee: RCA Corporation
    Inventors: Randolph H. Axelrod, Joseph J. Piascinski
  • Patent number: 4474873
    Abstract: A silver halide photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer wherein the photographic light-sensitive material contains a compound represented by the following general formula (I): ##STR1## wherein Rf represents a saturated or unsaturated hydrocarbon group having from 3 to 20 carbon atoms wherein all or a part of the hydrogen atoms are substituted with fluorine atoms; A and B each represents a divalent linking group; R.sub.1 represents a hydrogen atom or an alkyl group; R.sub.2, R.sub.3 and R.sub.4 each represents an alkyl group and at least one of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represents an alkyl group substituted with a monovalent group, and X represents an anion.
    Type: Grant
    Filed: May 18, 1983
    Date of Patent: October 2, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yukio Maekawa, Yasuo Mukunoki, Naohiko Sugimoto
  • Patent number: 4464462
    Abstract: A silver halide photographic light-sensitive material having improved antistatic properties is disclosed. The material is comprised of a support having thereon a light-senstive silver halide emulsion layer and a light-insensitive layer. The material includes (A) a flourine containing cationic surface active agent and (B) an ultraviolet ray absorbing polymer latex which comprises a polymer or a copolymer having a repeating unit derived from a monomer represented by the following general formula (I): ##STR1## within the formula (I) the Q is an ultraviolet ray absorbing group represented by the following general formula (II) or (III): ##STR2## the substituents within the formulae shown are defined within the specification. The ultraviolet ray absorbing polymer latex is present in the material in an amount in the range of 10 to 2,000 mg/m.sup.2 of the material.
    Type: Grant
    Filed: July 29, 1983
    Date of Patent: August 7, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naohiko Sugimoto, Tetsuro Kojima, Yasuo Mukunoki
  • Patent number: 4444876
    Abstract: A silver halide photographic light-sensitive material containing an anionic surface active agent which comprises a support having thereon at least one constituting layer containing a compound represented by the following general formula (I): ##STR1## wherein R represents a saturated or unsaturated hydrocarbon group having from 3 to 20 carbon atoms; L.sub.1 and L.sub.2 each represents a divalent connecting group; R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7, R.sub.8 and R.sub.9, which may be the same or different, each represents a hydrogen atom, a methyl group, an ethyl group or a propyl group; A represents --COO or --SO.sub.3 ; and a, b, d and e each represents 0, 1 or 2.
    Type: Grant
    Filed: July 22, 1982
    Date of Patent: April 24, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yukio Maekawa, Tetsuo Takeuchi
  • Patent number: 4431727
    Abstract: Protective layers for photographic elements comprise a compatible blend of:(a) cellulose nitrate and(b) a hydrophobic polymerwherein the blend has a sufficient amount of the hydrophobic polymer so as to have a glass transition temperature of at least about 50.degree. C. and a sufficient amount of cellulose nitrate so as to be resistant to chlorinated hydrocarbon solvents and photographic processing compositions. The overcoat is particularly useful with motion-picture elements containing silver halide which are subjected to chlorinated hydrocarbon solvents during a cleaning process or during wet gate printing.
    Type: Grant
    Filed: June 14, 1982
    Date of Patent: February 14, 1984
    Assignee: Eastman Kodak Company
    Inventor: David J. Steklenski
  • Patent number: 4415646
    Abstract: This invention is directed to positively charged developer compositions and toner compositions, the toner composition being comprised of resin particles, pigment particles, and from about 0.1 to about 10 percent by weight of the toner particles of a polymeric charge enhancing additive selected from the group consisting of those additives of the following formulas: ##STR1## wherein a and b are percentage numbers equaling 100, a being from about 20 weight percent to about 99 weight percent, and b being from about 80 weight percent to about 1 weight percent, n is a repeating number ranging from about 3 to about 300, Z is an oxygen atom, c is the number zero or 1, Y is an alkyl or aromatic radical, Z' is selected from the group consisting of aliphatic, aromatic, and heterocyclic radicals, R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are independently selected from alkyl radicals containing from about 1 to about 22 carbon atoms, X is an anion, a' is a number of from about 50 to about 500, R.sub.
    Type: Grant
    Filed: March 3, 1982
    Date of Patent: November 15, 1983
    Assignee: Xerox Corporation
    Inventors: Robert J. Gruber, Steven B. Bolte, Doretta Agostine
  • Patent number: 4389455
    Abstract: A photographic resin coated paper having improved resolving power of print images is disclosed. The paper is comprised of a base paper sheet having coated thereon polyolefin resin containing particles of titanium oxide pigment. The surface of the pigment particles are coated with a polyhydric alcohol containing from 2 to 4 hydroxyl groups. The polyolefin resin is coated on the paper by extrusion coating.
    Type: Grant
    Filed: August 21, 1981
    Date of Patent: June 21, 1983
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yasuzi Asao
  • Patent number: 4374924
    Abstract: A silver halide photographic light-sensitive material having at least one antistatic layer, said antistatic layer containing a dispersion of polymer represented by the following formula (I): ##STR1## wherein A represents a monomer unit formed from a copolymerizable monomer having at least two ethylenically unsaturated groups, B represents a monomer unit formed from a copolymerizable and monoethylenically unsaturated monomer, R.sub.1 represents a hydrogen atom or a lower alkyl group having 1 to 6 carbon atoms, Q represents a divalent group containing 1 to 12 carbon atoms, R.sub.2, R.sub.3 and R.sub.4 may be the same or different and each represents an alkyl group containing 1 to 20 carbon atoms, or an aralkyl group containing 7 to 20 carbon atoms, or R.sub.2, R.sub.3 and R.sub.4 may combine to form a ring together with the nitrogen atom, X.sup..crclbar. represents an anion, x is about 0.25 to 10 mol%, y is about 0 to 90 mol%, and z is about 10 to 99 mol%.
    Type: Grant
    Filed: February 24, 1982
    Date of Patent: February 22, 1983
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shigeki Yokoyama, Shinzo Kishimoto, Itsuki Toriya, Taku Nakamura
  • Patent number: 4367283
    Abstract: A photographic light-sensitive material with improved antistatic properties comprising a support having thereon at least one hydrophilic colloid layer containing(i) a nonionic surface active agent having a polyoxyethylene group,(ii) an anionic surface active agent represented by the following general formula (I)R--X--SO.sub.3 M (I)wherein R represents an alkyl group, an aryl group, an alkylaryl group or an alkenyl group; X represents --O--CH.sub.2 CH.sub.2 O).sub.m C.sub.n.sbsb.1 H.sub.2n.sbsb.1 +1--, ##STR1## or --O--; M represents a hydrogen atom, an alkali metal atom, an ammonium group or an animo group; m represents 0 or an integer of 1 to 25; n.sub.1 represents an integer of 2 to 5; l represents an integer of 1 to 5; and R.sub.
    Type: Grant
    Filed: June 25, 1981
    Date of Patent: January 4, 1983
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yasuhiro Nakayama, Masakazu Yoneyama, Yasuo Mukunoki, Akira Kitada, Shinzo Kishimoto
  • Patent number: 4362812
    Abstract: Static property in a photographic material is effectively prevented by incorporating a specific copolymer formed from, as the copolymerizable components, a betaine-containing polymerizable monomer and a fluorine-containing polymerizable monomer, in the protective layer, backing layer, or an overcoat of the photographic material without exhibiting adverse influences on the photographic properties of the photographic material.
    Type: Grant
    Filed: July 10, 1981
    Date of Patent: December 7, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Junji Minamizono, Shinzo Kishimoto, Shigeki Yokoyama, Takayuki Inayama
  • Patent number: 4343894
    Abstract: The antistatic properties of a photographic light-sensitive member is improved by adding to a surface protective layer a polymer or copolymer having a repeating unit represented by the formula (I) ##STR1## wherein R.sub.1 represents hydrogen or a methyl group, A represents a --COO-- or --CONH-- group, and B represents ##STR2## wherein R.sub.2 and R.sub.3 represent an alkyl group containing from 1 to 6 carbon atoms; R.sub.4 represents hydrogen or a methyl group; R.sub.5 represents an alkyl group containing from 1 to 3 carbon atoms; p is an integer of 2 to 6, q, when R.sub.4 is hydrogen, is an integer of from 1 to 4, and when R.sub.4 is a methyl group, is 1; and D represents a --COO or --SO.sub.3 group.
    Type: Grant
    Filed: October 15, 1980
    Date of Patent: August 10, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Junji Minamizono, Shinzo Kishimoto, Masakazu Yoneyama
  • Patent number: 4338390
    Abstract: This invention is directed to a dry electrostatic toner composition containing a resin, a colorant or pigment, and an organic sulfate or sulfonate charge control additive of the following formula: ##STR1## wherein R.sub.1 is an alkyl radical containing from about 12 carbon atoms to about 22 carbon atoms, and preferably from about 14 carbon atoms to 18 carbon atoms, R.sub.2 and R.sub.3 are independently selected from alkyl groups containing from about 1 carbon atom to about 5 carbon atoms, R.sub.4 is an alkylene group containing from about 1 carbon atom to about 5 carbon atoms, R.sub.5 is a tolyl group or an alkyl group containing from about 1 carbon atom to about 3 carbon atoms and n is the number 3 or 4. Such toners, especially when combined with carrier materials, are useful for causing the development of images in an electrophotographic system.
    Type: Grant
    Filed: December 4, 1980
    Date of Patent: July 6, 1982
    Assignee: Xerox Corporation
    Inventor: Chin H. Lu
  • Patent number: 4335201
    Abstract: Photographic base elements and radiation-sensitive elements are protected against the adverse effects resulting from accumulation of static electrical charges by incorporating therein an antistatic layer. Such layer is prepared from a coating composition comprising a hydrophilic binder, an anionic fluorinated surfactant and an inorganic nitrate.
    Type: Grant
    Filed: November 24, 1980
    Date of Patent: June 15, 1982
    Assignee: Eastman Kodak Company
    Inventors: Donald N. Miller, Richard A. Kydd
  • Patent number: 4330618
    Abstract: A photographic light-sensitive material containing a copolymer comprising a betaine group-containing monomer and a fluorine atom-containing monomer in at least one photographic layer thereof, whereby the material is improved in the antistatic properties without adversely affecting its photographic properties.
    Type: Grant
    Filed: December 3, 1980
    Date of Patent: May 18, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Junji Minamizono, Shinzo Kishimoto, Takayuki Inayama
  • Patent number: 4323634
    Abstract: The present invention relates to the use of low levels of quaternary ammonium salt surfactants as charge control agents for an electrostatic toner contained in dry electrographic developer compositions. Particularly useful such charge control agents are those which contain at least one amido group having 10 or more carbon atoms attached to the ammonium cation and an anion selected from a halide ion or an organosulfur-containing anion.
    Type: Grant
    Filed: November 10, 1977
    Date of Patent: April 6, 1982
    Assignee: Eastman Kodak Company
    Inventor: Thomas A. Jadwin
  • Patent number: 4323644
    Abstract: A photographic material having at least one layer containing a polymer having a repeating unit of the formula (I): ##STR1## wherein A is a monomer unit copolymerized with a copolymerizable ethylenically unsaturated monomer; R is a hydrogen atom or a lower alkyl group having 1 to about 6 carbon atoms; L is a bivalent linking group having 1 to about 20 carbon atoms; X is an active ester group; x and y each represents molar percent, x being between 0 and 95 and y being between 5 and 100; m is 0 or 1.
    Type: Grant
    Filed: November 5, 1980
    Date of Patent: April 6, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Taku Nakamura, Masasi Ogawa, Kunio Ishigaki
  • Patent number: 4308332
    Abstract: A coating composition useful in forming conductive layers comprises a latex having water as a continuous phase and, as a dispersed phase, hydrophobic polymer particles having associated therewith a polyaniline salt semiconductor. The coating composition can be coated on a variety of supports to produce conductive elements. The coating compositions are particularly useful in forming antistatic layers for photographic elements or conducting layers for electrophotographic and electrographic elements. Also disclosed is a preferred process for preparing a latex coating composition comprising the steps of loading polymer particles with the polyaniline component of the polyaniline acid addition salt semiconductor and then acidifying the latex to form a polyaniline salt coating composition.
    Type: Grant
    Filed: May 1, 1980
    Date of Patent: December 29, 1981
    Assignee: Eastman Kodak Company
    Inventors: Donald A. Upson, David J. Steklenski