Ammonium Salt Patents (Class 430/528)
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Patent number: 5674671Abstract: The invention relates to the use of a fluoropolymer and a fluorochemical surface active agent in combination for improving the antistatic behaviour of surfaces. In one embodiment, the invention provides a light-sensitive material possessing good initial antistatic properties and retaining good properties even after aqueous processing.Type: GrantFiled: June 27, 1995Date of Patent: October 7, 1997Assignee: Minnesota Mining and Manufacturing CompanyInventors: Marc Brandon, Dirk H. C. Arren, Rudolph J. Dams
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Patent number: 5604083Abstract: The invention is directed to an antistatic polymeric film base comprising a polymeric film having coated on at least one side thereof an antistatic layer comprising the reaction product of (1) a water-soluble, electrically conductive polymer containing carboxylic groups and (2) a water-soluble polymer containing oxazoline groups, and to a photographic element comprising at least one silver halide emulsion layer on said antistatic polymeric film base. This antistatic layer may be present as a backing layer on the side of the film base opposite the silver halide emulsion layer, as a subbing layer between the film base and the emulsion layer in a single or double side coated photographic element, and/or as a subbing layer between the film base and a different backing layer.Type: GrantFiled: December 5, 1995Date of Patent: February 18, 1997Assignee: Minnesota Mining and Manufacturing CompanyInventors: Alberto Valsecchi, Giorgio Spazzapan, Renzo Torterolo, Soonkun Kang
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Patent number: 5451495Abstract: A recording element having at least one layer comprising a crosslinked polymer having polymeric backbone moieties and crosslinking moieties, the polymeric backbone moieties containing tertiary nitrogen atoms, the crosslinking moieties connecting polymeric backbone moieties at the teritary nitrogen atoms by conversion of the tertiary nitrogen atoms to quaternary amine, the crosslinking moiety having the structure ##STR1## where R' is independently alkyl or aryl and m is an integer of from 1 to 10.Type: GrantFiled: August 15, 1994Date of Patent: September 19, 1995Assignee: Eastman Kodak CompanyInventors: Catherine A. Falkner, John J. Fitzgerald, Dennis J. Savage, Paul D. Yacobucci
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Patent number: 5411844Abstract: A coating composition for applying a layer to a photographic element and the resulting photographic element comprising gelatin, water and from 0.3 to 1 gm/100 gms of the composition of a surfactant mixture of 15 to 70 percent by weight of a dioctyl sulfosuccinate, sodium salt or di-fluoroalkylsulfosuccinate, sodium salt, from 35 to 75 percent by weight of a nonylphenoxy polyglycidyl alcohol, and from 3 to 14 percent by weight of perfluoro-octyl sulfonamido, N-hydrogen, N-propylene trimethylammonium iodide based on the total weight of the surfactant mixture; when a dioctyl sulfosuccinate, sodium salt is used, the minimum amount thereof is 0.15 gm/100 gm of coating composition.Type: GrantFiled: March 31, 1994Date of Patent: May 2, 1995Assignee: Eastman Kodak CompanyInventor: Michael W. Orem
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Patent number: 5362613Abstract: A cationic high-molecular weight compound is represented by formula (I): ##STR1## wherein R.sup.1 and R.sup.2 may be the same or different and each represents a hydrogen atom or C.sub.1-6 lower alkyl group; L.sup.1 represents --COO-- or --CONH-- and L.sup.2 represents a divalent group; J represents a C.sub.1-20 alkylene group or C.sub.7-20 aralkylene group; R.sup.3, R.sup.4 and R.sup.5 may be the same or different and each represents a C.sub.1-20 alkyl group or C.sub.7-20 aralkyl group; X.sup.Type: GrantFiled: January 15, 1993Date of Patent: November 8, 1994Assignee: Fuji Photo Film Co., Ltd.Inventors: Kentaro Shiratsuchi, Fumio Kawamoto
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Patent number: 5326688Abstract: A solvent mixture of 8 to 30 weight percent of n-propyl acetate 1-methoxy-2-propanol or cyclohexane, 50 to 55 weight percent of acetone and the balance methanol is employed in a coating composition for applying a polymeric antistatic layer.Type: GrantFiled: May 27, 1993Date of Patent: July 5, 1994Assignee: Eastman Kodak CompanyInventors: Ronald M. Stimson, James Skoronski, Thomas M. Smith, Jack J. Holt
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Patent number: 5306606Abstract: Disclosed is a biaxially stretched polyester film which comprises a polyester film and a coating layer composed of a resin composition comprising (A) an acrylic polymer and/or (B) a polyester copolymer and at least (C) a polymer containing a monomer having a sulfonic acid group neutralized with an organic amine in its recurring unit or (D) a polymer containing a monomer having a sulfonic acid group neutralized with ammonium on at least one surface of the polyester film.Type: GrantFiled: December 23, 1991Date of Patent: April 26, 1994Assignee: Konica CorporationInventors: Noriki Tachibana, Yoshihiro Wada, Tohru Kobayashi
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Patent number: 5258276Abstract: A ternary surfactant system useful in reducing the propensity of silver halide elements to generate unwanted static is described. This ternary system comprises a mixture of a specific anionic and two specific nonionic surfactants and produces a surprising synergistic result. A solution of this ternary system is also useful in reducing static produced on the surface of an X-ray intensifying screen.Type: GrantFiled: May 15, 1992Date of Patent: November 2, 1993Assignee: E. I. Du Pont de Nemours and CompanyInventors: Allan R. Schoenberg, Ming-tsai Shu
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Patent number: 5254445Abstract: A method of manufacturing silver halide photographic light-sensitive material with little habitual curling is disclosed. The material, after being coated with a silver halide emulsion layer and antistatic layer on the polyester support, is rolled around a core with its emulsion side facing outside, and then heated at the temperature not less than 30.degree. C. After the heat-treatment, the material is cut and re-rolled on a commercial size core with its emulsion side facing inside.Type: GrantFiled: March 20, 1992Date of Patent: October 19, 1993Assignee: Konica CorporationInventors: Yasuhiko Takamuki, Takeshi Sampei
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Patent number: 5244773Abstract: A silver halide photographic light sensitive material having high contrast photographic characteristics and excellent antistatic properties is provided by incorporating a hydrazine compound represented by formula 1 or 2 and a nucleation-promoting compound selected from the group consisting of amine compounds and quaternary onium salts; and by coating an electrically conductive layer on a support.Type: GrantFiled: January 24, 1992Date of Patent: September 14, 1993Assignee: Konica CorporationInventors: Yasuhiko Muramatsu, Takeshi Sampei
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Patent number: 5135843Abstract: The improved silver halide photographic material comprises a support having an antistatic coating thereon that contains a water-soluble conductive polymer, hydrophobic polymer particles and a curing agent which is a bifunctional ethylene oxide type curing agent that is to be cured by exposure to electron beams or X-rays. This silver halide photographic material may contain a tetrazolium compound or a hydrazine compound in order to prevent desensitization due to aging. At least one hydrophilic colloidal layer may be provided on the antistatic coating, which colloidal layer contains an epoxy curing agent having a hydroxy group.Type: GrantFiled: July 27, 1990Date of Patent: August 4, 1992Assignee: Konica CorporationInventors: Yasuhiko Takamuki, Takatoshi Yamada, Takeshi Habu, Toshiharu Nagashima
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Patent number: 5128233Abstract: A film support having an auxiliary layer coated over an antistatic layer coated on one side thereof is described. This element, which is particularly useful for the application of subsequently applied photosensitive layers on side opposite said auxiliary layer, comprises gelatin, a crosslinking agent, optionally a conductive polymer and an adhesion promoting amount of an adhesion agent, said adhesion agent selected from the group consisting of: compounds containing at least one --NH.sub.2 group and compounds containing at least two --NH groups, wherein said adhesion agent is sufficiently soluble in water that said adhesion promoting amount of adhesion agent may be dissolved in the dispersion used to coat said auxiliary layer, with the proviso that said adhesion agent is not malonamide. Preferred adhesion agents are urea, thiourea and 2-imidazolidone. Improved adhesion of the auxiliary layer to the antistatic layer is achieved.Type: GrantFiled: January 7, 1992Date of Patent: July 7, 1992Assignee: E. I. Du Pont de Nemours and CompanyInventors: Rudolf W. Beisswenger, Kurt B. Gundlach
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Patent number: 5108885Abstract: A silver halide photographic material comprising a support having thereon at least one silver halide emulsion layer, wherein at least one of the layers of the photographic material is a layer which is crosslinked after coating a coating liquid comprising a polymeric compound which has at least repeating units represented by formula (I) or formula (II): ##STR1## wherein, L.sub.1, L.sub.2, L.sub.3, L.sub.4, L.sub.5, L.sub.6, L.sub.7, L.sub.8 and L.sub.9, which may be the same or different, each represents a divalent linking group; X.sub.1 and X.sub.2, which may be the same or different, each represents a crosslinkable groups which contain an activated vinyl component; Y.sub.1, Y.sub.2, Y.sub.3 and Y.sub.4, which may be the same or different, each represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, an aralkyl group or a crosslinkable group which contains an activated vinyl component; Z.sub.1 and Z.sub.Type: GrantFiled: July 3, 1990Date of Patent: April 28, 1992Assignee: Fuji Photo Film Co., Ltd.Inventors: Shoichiro Yasunami, Yasuo Mukunoki
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Patent number: 5102488Abstract: The present invention provides a method for forming a cured-resin layer having a surface with antistatic properties. An ultraviolet-curable resin having antistatic properties is laminated on an ultraviolet-curable resin for forming an electrostatic cured surface by curing and the two layers then being simultaneously cured by ultraviolet irradiation thereon. A cured-resin layer is thereby obtained where the surface layer of the cured resin is provided with antistatic properties, and is strongly held by chemical bonding.Type: GrantFiled: October 1, 1990Date of Patent: April 7, 1992Assignee: Mitsubishi Petrochemical Co., Ltd.Inventors: Kazuhide Hayama, Noritaka Hosokawa, Takao Yazaki, Masataka Noro
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Patent number: 5098822Abstract: Disclosed is an antistatic layer for a plastic film having an antistatic layer comprising a reaction product of a water-soluble conductive polymer, a hydrophobic latex and an epoxy type hardener, characterized in that said hydrophobic latex comprises a hydrophobic polymer having at least one of an alkylene oxide chain and an amide group.Type: GrantFiled: December 6, 1990Date of Patent: March 24, 1992Assignee: Konica CorporationInventors: Noriki Tachibana, Yoichi Saito
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Patent number: 5082730Abstract: Disclosed herein are a stretched antistatic laminate film comprising at least one coating layer containing a polymer having pyrrolidium rings in the main molecular chain, and a polyester film layer, a magnetic recording medium using the same, and a recording material for heat sensitive transfer printing using the same.Type: GrantFiled: December 2, 1988Date of Patent: January 21, 1992Assignee: Diafoil Company, LimitedInventors: Naohiro Takeda, Yuzo Otani, Nariaki Okajima, Masahiro Kita
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Patent number: 5077185Abstract: An element comprising a support having an antistatic layer applied to one side thereof and wherein said antistatic layer also contains antihalation dyes absorbing light at 440 nm and below and with matte particles therein, is described. A photosensitive layer, e.g., photographic silver halide layer can be coated on the opposite side of the support. The element exhibits excellent antistatic and antihalation properties as well as low dye stain and improved dimensional stability, compared to elements wherein the antihalation dyes are coated in a separate layer. These products are especially useful as so-called "bright-light films" that are designed for contact printing and the like.Type: GrantFiled: March 28, 1991Date of Patent: December 31, 1991Assignee: E. I. Du Pont de Nemours and CompanyInventors: Thomas B. Cho, Ray B. Myers
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Patent number: 4968599Abstract: Fluoroalkyl surface active agents are provided as effective coating aids for hydrophilic colloid coating compositions for photographic materials. These coating aids are of the formula: ##STR1## where M is a cation,x and y are each independently 0 or an integer of from 1 to 6 such that the sum of x and y is an integer of from 2 to 6, andp and q are each independently 1 or 2, with the proviso that when the sum of x and y is 6, p and q are each 1, and when the sum of x and y is 2, p and q are each 2.Type: GrantFiled: June 29, 1989Date of Patent: November 6, 1990Assignee: Eastman Kodak CompanyInventors: Alan R. Pitt, Trevor J. Wear
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Patent number: 4914018Abstract: An improved antistatic base comprises a polymeric support film having coated thereon in sequence a first antistatic layer comprising a quaternary polyelectrolyte compound and a polymeric hydrophobic binder and a second protective layer comprising a polymeric hydrophobic binder, wherein said quaternary polyelectrolyte compound is a homopolymer or a copolymer of a diallyldialkylammonium salt compound.The antistatic base is particularly useful as a support for light-sensitive silver halide photographic elements.Type: GrantFiled: December 1, 1988Date of Patent: April 3, 1990Assignee: Minnesota Mining and Manufacturing CompanyInventors: Mauro Besio, Alberto Valsecchi
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Patent number: 4908155Abstract: A surface-active block copolymer which comprises chemically linked polymeric blocks (A) and (B), block (A) of said copolymer consisting of at least one homo- or copolymerized non-polar alpha,beta-ethylenically unsaturated monomer and block (B) of said copolymer is derived by polymerizing an alpha-beta ethylenically unsaturated monomer containing an epoxy group and transforming the epoxy group into an hydroxy-substituted ionic group, preferably an anionic group. These block copolymers are used as dispersing agents in aqueous dispersions, including polymeric latex dispersions, and as plasticizing agent in hydrophilic colloid layers, including colloid layers containing a dispersed light-sensitive silver halide emulsion or other auxiliary substances for photographic materials.Type: GrantFiled: November 13, 1987Date of Patent: March 13, 1990Assignee: Agfa-Gevaert, N.V.Inventors: Luc E. Leemans, Herman J. Uytterhoeven, Philippe J. Teyssie, Roger M. Fayt, Nikolaas C. de Jaeger
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Patent number: 4898808Abstract: An antistatic silver halide photographic light-sensitive material having a support, provided thereon, at least one light-sensitive layer and at least one non-light-sensitive layer is disclosed. Said at least one non-light-sensitive layer comprises a polymer compound consisting essentially of a repeated structural unit represented by Formula [I], and a formamide compound represented by Formula [II]; ##STR1## wherein Z, and Z.sub.2 represent the group of the atoms necessary to form a six-membered ring with--N.sup..sym. --; R represents a divalent group; R.sub.1 and R.sub.2 represent independently one selected from the group consisting of an alkyl group and an aryl group; R.sub.3 represents a hydrocarbon group; R.sub.5 and R.sub.6 represent independently a hydrogen atom or an alkyl group; X.sub.1.sup..crclbar. and X.sub.2.sup..crclbar. represent an anion; a and l represent an integer of 0 and 1.Type: GrantFiled: January 17, 1989Date of Patent: February 6, 1990Assignee: Konica CorporationInventors: Noriki Tachibana, Masato Nishizeki, Nobuaki Kagawa
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Patent number: 4897329Abstract: A method for preparing a lithographic printing plate and a light-sensitive material for a lithographic printing plate are disclosed. The method comprises providing a light-sensitive material comprising an electroconductive support having a hydrophilic surface. Provided on the surface is a light-sensitive layer which contains an electroconductive agent as well as a photoconductive insulating layer. The material is imagewise exposed and then electrophotographically processed to form an electrostatic latent image on the photoconductive insulating layer. The exposed material is developed with developer particles which are opaque to the light which the light-sensitive layer is sensitive. The light-sensitive layer of the developed material is exposed through the image. The exposed or unexposed areas of the light-sensitive layer are then removed together with the photoconductive insulating layer. The lithographic printing plate produced has excellent resolving power and does not cause printing stains.Type: GrantFiled: January 16, 1987Date of Patent: January 30, 1990Assignee: Fuji Photo Film Co., Ltd.Inventor: Takao Nakayama
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Patent number: 4891306Abstract: A static-inhibited photographic light-sensitive material is provided by incorporating a fluorine-containing block polymer derived from a polymerizable hydrophobic monomer containing at least one fluorine atom and a polymerizable hydrophilic monomer, as an antistatic agent in at least one layer thereof. Unlike known antistatic agents and methods, the use of the above antistatic agent does not adversely affect the photographic characteristics, antitack property, marring resistance, etc., of the photographic light-sensitive material.Type: GrantFiled: November 14, 1988Date of Patent: January 2, 1990Assignee: Fuji Photo Film Co., Ltd.Inventors: Shigeki Yokoyama, Yukio Maekawa
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Patent number: 4886735Abstract: Photopolymerizable recording materials suitable for producing photoresist layers and lithographic printing plates are composed of one or more photopolymerizable olefinically unsaturated organic compounds, optionally a polymeric binder, one or more photopolymerization initiators, a color-forming system which on irradiation with actinic light causes an increase in the color intensity of the recording material, a sensitizer and optionally further additive and/or auxiliary substances, and contain as the color-forming system(a) one or more colorless or virtually colorless organic compounds which are oxidizable to colored compounds, and(b) a photooxidant for the colorless or virtually colorless organic compound(s) (a),wherein photooxidant (b) comprises an organic salt with a substituted or unsubstituted hetaromatic system, this hetaromatic system having one or more built-in groups of the general formula (I) ##STR1## where R is substituted or unsubstituted alkenyl, alkynyl, hetaryl, alkoxycarbonyl, carbamoyl, alkylsType: GrantFiled: May 17, 1988Date of Patent: December 12, 1989Assignee: BASF AktiengesellschaftInventors: Andreas Boettcher, Martin Fischer, Reinhard Aldag, Thomas Bluemel
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Patent number: 4847187Abstract: Disclosed is a light-sensitive silver halide photographic material comprising at least one silver halide emulsion layer on at least one side of a support and at least auxiliary layer adjacent to the silver halide emulsion layer, the silver halide emulsion layer containing a surface latent type silver halide emulsion and a silver halide emulsion having fog internally of the grains, and the auxiliary layer containing a compound represented by the formula (I) shown below:RfSO.sub.3 M Formula (I)wherein Rf is a substituted or unsubstituted alkyl group or a substituted or unsubstituted aralkyl group, containing at least 3 fluorine atoms, and M represents hydrogen atom, an alkali metal or ammonium group.According to the present invention, a light-sensitive silver halide photographic material improved in antistatic performance and also improved in storability without accomplaniment of lowering in sensitivity, which can give images with sensitivity, high contrast as well as high covering power is provided.Type: GrantFiled: August 28, 1987Date of Patent: July 11, 1989Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Kouzi Ono, Mikio Kawasaki
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Patent number: 4810624Abstract: To protect photographic films from imaging by static discharges during manufacturing and customer use, copolymers of sulfonated monomers and primary amine monomers are coated on a film base and crosslinked with an aldehyde such as glutaraldehyde, or other colloid hardener giving a water-resistant, permanent, conductive (i.e., antistatic) layer.Type: GrantFiled: September 2, 1987Date of Patent: March 7, 1989Assignee: E. I. DuPont de Nemours and CompanyInventors: William M. Hardam, Frank L. Schadt, III, Arthur J. Taggi
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Patent number: 4756991Abstract: Fluorescent dry nonelectroscopic toner comprising fluorescent pigmented organic resin particles having a size distribution of 0.2 to 50 micrometers, surface coated with at least 0.1% by weight of silicone oil or fluorocarbon compound, in combination with at least 0.5% by weight of a water soluble, polymeric quaternary ammonium compound as defined. The fluorescent toner is useful in color developing positive- and negative-working photosensitive elements. The toners provide good toning quality and excellent lack of background color, together with stability on aging.Type: GrantFiled: March 11, 1987Date of Patent: July 12, 1988Assignee: E. I. Du Pont de Nemours and CompanyInventor: Eugene L. Grubb
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Patent number: 4703000Abstract: Provided herewith is an anti-brick/anti-static composition useful for treating film surfaces. The composition comprises (i) an anionic or cationic surfactant exhibiting anti-static properties, and (ii) a similar charged inorganic particle, e.g., a negatively charged silica or positively charged alumina coated silica, having an average particle size of less than 0.1 micron. Upon coating a film surface with the composition, good anti-static properties are realized without experiencing problems with bricking or blocking of the film. The composition is particularly useful in coating microfilm since it also provides the anti-brick/anti-static properties without deleteriously effecting the viewing capabilities of the film over a wide range of magnifications.Type: GrantFiled: September 30, 1985Date of Patent: October 27, 1987Assignee: James River Graphics, Inc.Inventor: George R. Hodgins
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Patent number: 4649102Abstract: A silver halide photographic light-sensitive material is described, comprising a support having provided thereon at least one silver halide emulsion layer, wherein there is at least one hydrophilic colloidal layer containing at least one nonionic surface active agent and at least one anionic surface active agent having a polyoxyethylene group therein.Type: GrantFiled: January 10, 1986Date of Patent: March 10, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Yasuo Mukunoki, Shigeki Yokoyama, Hiroshi Kawasaki, Ryoichi Nemori, Tetsuo Takeuchi
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Patent number: 4628025Abstract: A support for photographic use comprising a polyester film is disclosed which contains at least one compound of the following formula (I) and at least one quaternary ammonium salt of the following formula (II): ##STR1## a hydroxyl group, a nitro group, an amino group or a hydrogen atom; R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are each a hydrogen atom, a halogen atom, an alkoxy group, an alkyl group, an aryloxy group, an aralkoxy group, a hydroxyalkyl group, --(OCH.sub.2).sub.m OH (m is an integer or 1 to 4) or ##STR2## B, C and D are not simultaneously at least one member selected from the group consisting of a hydrogen atom, a nitro group and an amino group); ##STR3## (wherein R.sub.6, R.sub.7, R.sub.8 and R.sub.9 are each an alkyl group, an aralkyl group or an allyl group; X is an anion; and n represents the number of charges on X).Type: GrantFiled: July 12, 1985Date of Patent: December 9, 1986Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Toshiki Komaita, Takanori Nakadate, Yoshiyuki Funabashi, Kazuto Kiyohara
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Patent number: 4610955Abstract: Antistatic compositions are disclosed comprising a hydrophilic binder, surface-active polymer having polymerized oxyalkylene monomers and an inorganic salt characterized in that the salt is selected from the group consisting of inorganic tetrafluoroborates, perfluoroalkyl carboxylates, hexafluorophosphates and perfluoroalkyl sulfonates.Type: GrantFiled: December 24, 1985Date of Patent: September 9, 1986Assignee: Eastman Kodak CompanyInventors: Janglin Chen, James E. Kelly, James Plakunov
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Patent number: 4596766Abstract: A silver halide photographic material is disclosed comprising a support having thereon at least one layer containing a nonionic surface active agent having a polyoxyethylene group and a fluorine-containing compound, wherein the element composition of the surface of said layer has a ratio of F.sub.ls peak intensity/C.sub.ls peak intensity in the range of 0.3 to 2.0 when measured by an X-ray photoelectron spectrometry.Type: GrantFiled: October 9, 1984Date of Patent: June 24, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Ryoichi Nemori, Hiroshi Kawasaki, Yasuo Mukunoki
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Patent number: 4585730Abstract: As part of a photographic film, a backing layer is coated with an auxiliary layer designed to conduct antistatic properties from an antistatic underlayer to the surface of the backing.Type: GrantFiled: January 16, 1985Date of Patent: April 29, 1986Assignee: E. I. Du Pont de Nemours and CompanyInventor: Thomas B. Cho
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Patent number: 4562120Abstract: An optically-black coating that is adherent to metal surfaces, has a low reflectance of light in the range of about 2000 to 7500 Angstroms, and is chemically stable up to at least 750.degree. C., consists essentially of a minor proportion of an inorganic silicate binder and a major proportion of a particulate mixture of cobaltic oxide and zinc oxide in the weight ratio range of 4/1 to 1/1.Type: GrantFiled: August 10, 1984Date of Patent: December 31, 1985Assignee: RCA CorporationInventors: Randolph H. Axelrod, Joseph J. Piascinski
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Patent number: 4474873Abstract: A silver halide photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer wherein the photographic light-sensitive material contains a compound represented by the following general formula (I): ##STR1## wherein Rf represents a saturated or unsaturated hydrocarbon group having from 3 to 20 carbon atoms wherein all or a part of the hydrogen atoms are substituted with fluorine atoms; A and B each represents a divalent linking group; R.sub.1 represents a hydrogen atom or an alkyl group; R.sub.2, R.sub.3 and R.sub.4 each represents an alkyl group and at least one of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represents an alkyl group substituted with a monovalent group, and X represents an anion.Type: GrantFiled: May 18, 1983Date of Patent: October 2, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Yukio Maekawa, Yasuo Mukunoki, Naohiko Sugimoto
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Patent number: 4464462Abstract: A silver halide photographic light-sensitive material having improved antistatic properties is disclosed. The material is comprised of a support having thereon a light-senstive silver halide emulsion layer and a light-insensitive layer. The material includes (A) a flourine containing cationic surface active agent and (B) an ultraviolet ray absorbing polymer latex which comprises a polymer or a copolymer having a repeating unit derived from a monomer represented by the following general formula (I): ##STR1## within the formula (I) the Q is an ultraviolet ray absorbing group represented by the following general formula (II) or (III): ##STR2## the substituents within the formulae shown are defined within the specification. The ultraviolet ray absorbing polymer latex is present in the material in an amount in the range of 10 to 2,000 mg/m.sup.2 of the material.Type: GrantFiled: July 29, 1983Date of Patent: August 7, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Naohiko Sugimoto, Tetsuro Kojima, Yasuo Mukunoki
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Patent number: 4444876Abstract: A silver halide photographic light-sensitive material containing an anionic surface active agent which comprises a support having thereon at least one constituting layer containing a compound represented by the following general formula (I): ##STR1## wherein R represents a saturated or unsaturated hydrocarbon group having from 3 to 20 carbon atoms; L.sub.1 and L.sub.2 each represents a divalent connecting group; R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7, R.sub.8 and R.sub.9, which may be the same or different, each represents a hydrogen atom, a methyl group, an ethyl group or a propyl group; A represents --COO or --SO.sub.3 ; and a, b, d and e each represents 0, 1 or 2.Type: GrantFiled: July 22, 1982Date of Patent: April 24, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Yukio Maekawa, Tetsuo Takeuchi
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Patent number: 4431727Abstract: Protective layers for photographic elements comprise a compatible blend of:(a) cellulose nitrate and(b) a hydrophobic polymerwherein the blend has a sufficient amount of the hydrophobic polymer so as to have a glass transition temperature of at least about 50.degree. C. and a sufficient amount of cellulose nitrate so as to be resistant to chlorinated hydrocarbon solvents and photographic processing compositions. The overcoat is particularly useful with motion-picture elements containing silver halide which are subjected to chlorinated hydrocarbon solvents during a cleaning process or during wet gate printing.Type: GrantFiled: June 14, 1982Date of Patent: February 14, 1984Assignee: Eastman Kodak CompanyInventor: David J. Steklenski
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Patent number: 4415646Abstract: This invention is directed to positively charged developer compositions and toner compositions, the toner composition being comprised of resin particles, pigment particles, and from about 0.1 to about 10 percent by weight of the toner particles of a polymeric charge enhancing additive selected from the group consisting of those additives of the following formulas: ##STR1## wherein a and b are percentage numbers equaling 100, a being from about 20 weight percent to about 99 weight percent, and b being from about 80 weight percent to about 1 weight percent, n is a repeating number ranging from about 3 to about 300, Z is an oxygen atom, c is the number zero or 1, Y is an alkyl or aromatic radical, Z' is selected from the group consisting of aliphatic, aromatic, and heterocyclic radicals, R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are independently selected from alkyl radicals containing from about 1 to about 22 carbon atoms, X is an anion, a' is a number of from about 50 to about 500, R.sub.Type: GrantFiled: March 3, 1982Date of Patent: November 15, 1983Assignee: Xerox CorporationInventors: Robert J. Gruber, Steven B. Bolte, Doretta Agostine
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Patent number: 4389455Abstract: A photographic resin coated paper having improved resolving power of print images is disclosed. The paper is comprised of a base paper sheet having coated thereon polyolefin resin containing particles of titanium oxide pigment. The surface of the pigment particles are coated with a polyhydric alcohol containing from 2 to 4 hydroxyl groups. The polyolefin resin is coated on the paper by extrusion coating.Type: GrantFiled: August 21, 1981Date of Patent: June 21, 1983Assignee: Fuji Photo Film Co., Ltd.Inventor: Yasuzi Asao
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Patent number: 4374924Abstract: A silver halide photographic light-sensitive material having at least one antistatic layer, said antistatic layer containing a dispersion of polymer represented by the following formula (I): ##STR1## wherein A represents a monomer unit formed from a copolymerizable monomer having at least two ethylenically unsaturated groups, B represents a monomer unit formed from a copolymerizable and monoethylenically unsaturated monomer, R.sub.1 represents a hydrogen atom or a lower alkyl group having 1 to 6 carbon atoms, Q represents a divalent group containing 1 to 12 carbon atoms, R.sub.2, R.sub.3 and R.sub.4 may be the same or different and each represents an alkyl group containing 1 to 20 carbon atoms, or an aralkyl group containing 7 to 20 carbon atoms, or R.sub.2, R.sub.3 and R.sub.4 may combine to form a ring together with the nitrogen atom, X.sup..crclbar. represents an anion, x is about 0.25 to 10 mol%, y is about 0 to 90 mol%, and z is about 10 to 99 mol%.Type: GrantFiled: February 24, 1982Date of Patent: February 22, 1983Assignee: Fuji Photo Film Co., Ltd.Inventors: Shigeki Yokoyama, Shinzo Kishimoto, Itsuki Toriya, Taku Nakamura
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Patent number: 4367283Abstract: A photographic light-sensitive material with improved antistatic properties comprising a support having thereon at least one hydrophilic colloid layer containing(i) a nonionic surface active agent having a polyoxyethylene group,(ii) an anionic surface active agent represented by the following general formula (I)R--X--SO.sub.3 M (I)wherein R represents an alkyl group, an aryl group, an alkylaryl group or an alkenyl group; X represents --O--CH.sub.2 CH.sub.2 O).sub.m C.sub.n.sbsb.1 H.sub.2n.sbsb.1 +1--, ##STR1## or --O--; M represents a hydrogen atom, an alkali metal atom, an ammonium group or an animo group; m represents 0 or an integer of 1 to 25; n.sub.1 represents an integer of 2 to 5; l represents an integer of 1 to 5; and R.sub.Type: GrantFiled: June 25, 1981Date of Patent: January 4, 1983Assignee: Fuji Photo Film Co., Ltd.Inventors: Yasuhiro Nakayama, Masakazu Yoneyama, Yasuo Mukunoki, Akira Kitada, Shinzo Kishimoto
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Patent number: 4362812Abstract: Static property in a photographic material is effectively prevented by incorporating a specific copolymer formed from, as the copolymerizable components, a betaine-containing polymerizable monomer and a fluorine-containing polymerizable monomer, in the protective layer, backing layer, or an overcoat of the photographic material without exhibiting adverse influences on the photographic properties of the photographic material.Type: GrantFiled: July 10, 1981Date of Patent: December 7, 1982Assignee: Fuji Photo Film Co., Ltd.Inventors: Junji Minamizono, Shinzo Kishimoto, Shigeki Yokoyama, Takayuki Inayama
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Patent number: 4343894Abstract: The antistatic properties of a photographic light-sensitive member is improved by adding to a surface protective layer a polymer or copolymer having a repeating unit represented by the formula (I) ##STR1## wherein R.sub.1 represents hydrogen or a methyl group, A represents a --COO-- or --CONH-- group, and B represents ##STR2## wherein R.sub.2 and R.sub.3 represent an alkyl group containing from 1 to 6 carbon atoms; R.sub.4 represents hydrogen or a methyl group; R.sub.5 represents an alkyl group containing from 1 to 3 carbon atoms; p is an integer of 2 to 6, q, when R.sub.4 is hydrogen, is an integer of from 1 to 4, and when R.sub.4 is a methyl group, is 1; and D represents a --COO or --SO.sub.3 group.Type: GrantFiled: October 15, 1980Date of Patent: August 10, 1982Assignee: Fuji Photo Film Co., Ltd.Inventors: Junji Minamizono, Shinzo Kishimoto, Masakazu Yoneyama
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Patent number: 4338390Abstract: This invention is directed to a dry electrostatic toner composition containing a resin, a colorant or pigment, and an organic sulfate or sulfonate charge control additive of the following formula: ##STR1## wherein R.sub.1 is an alkyl radical containing from about 12 carbon atoms to about 22 carbon atoms, and preferably from about 14 carbon atoms to 18 carbon atoms, R.sub.2 and R.sub.3 are independently selected from alkyl groups containing from about 1 carbon atom to about 5 carbon atoms, R.sub.4 is an alkylene group containing from about 1 carbon atom to about 5 carbon atoms, R.sub.5 is a tolyl group or an alkyl group containing from about 1 carbon atom to about 3 carbon atoms and n is the number 3 or 4. Such toners, especially when combined with carrier materials, are useful for causing the development of images in an electrophotographic system.Type: GrantFiled: December 4, 1980Date of Patent: July 6, 1982Assignee: Xerox CorporationInventor: Chin H. Lu
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Patent number: 4335201Abstract: Photographic base elements and radiation-sensitive elements are protected against the adverse effects resulting from accumulation of static electrical charges by incorporating therein an antistatic layer. Such layer is prepared from a coating composition comprising a hydrophilic binder, an anionic fluorinated surfactant and an inorganic nitrate.Type: GrantFiled: November 24, 1980Date of Patent: June 15, 1982Assignee: Eastman Kodak CompanyInventors: Donald N. Miller, Richard A. Kydd
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Patent number: 4330618Abstract: A photographic light-sensitive material containing a copolymer comprising a betaine group-containing monomer and a fluorine atom-containing monomer in at least one photographic layer thereof, whereby the material is improved in the antistatic properties without adversely affecting its photographic properties.Type: GrantFiled: December 3, 1980Date of Patent: May 18, 1982Assignee: Fuji Photo Film Co., Ltd.Inventors: Junji Minamizono, Shinzo Kishimoto, Takayuki Inayama
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Patent number: 4323634Abstract: The present invention relates to the use of low levels of quaternary ammonium salt surfactants as charge control agents for an electrostatic toner contained in dry electrographic developer compositions. Particularly useful such charge control agents are those which contain at least one amido group having 10 or more carbon atoms attached to the ammonium cation and an anion selected from a halide ion or an organosulfur-containing anion.Type: GrantFiled: November 10, 1977Date of Patent: April 6, 1982Assignee: Eastman Kodak CompanyInventor: Thomas A. Jadwin
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Patent number: 4323644Abstract: A photographic material having at least one layer containing a polymer having a repeating unit of the formula (I): ##STR1## wherein A is a monomer unit copolymerized with a copolymerizable ethylenically unsaturated monomer; R is a hydrogen atom or a lower alkyl group having 1 to about 6 carbon atoms; L is a bivalent linking group having 1 to about 20 carbon atoms; X is an active ester group; x and y each represents molar percent, x being between 0 and 95 and y being between 5 and 100; m is 0 or 1.Type: GrantFiled: November 5, 1980Date of Patent: April 6, 1982Assignee: Fuji Photo Film Co., Ltd.Inventors: Taku Nakamura, Masasi Ogawa, Kunio Ishigaki
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Patent number: 4308332Abstract: A coating composition useful in forming conductive layers comprises a latex having water as a continuous phase and, as a dispersed phase, hydrophobic polymer particles having associated therewith a polyaniline salt semiconductor. The coating composition can be coated on a variety of supports to produce conductive elements. The coating compositions are particularly useful in forming antistatic layers for photographic elements or conducting layers for electrophotographic and electrographic elements. Also disclosed is a preferred process for preparing a latex coating composition comprising the steps of loading polymer particles with the polyaniline component of the polyaniline acid addition salt semiconductor and then acidifying the latex to form a polyaniline salt coating composition.Type: GrantFiled: May 1, 1980Date of Patent: December 29, 1981Assignee: Eastman Kodak CompanyInventors: Donald A. Upson, David J. Steklenski