Subjected To Radiation, Flame, Or Corona Discharge Patents (Class 430/532)
  • Patent number: 4293642
    Abstract: Adhesion of a hydrophilic photographic emulsion to a hydrophobic polyester substrate is achieved by providing the substrate with a surface layer containing free carboxy groups and incorporating in the emulsion a cross-linking agent which can cross-link the emulsion and the carboxy containing surface layer. Carbodiimides are a class of cross-linking agents having this capability.
    Type: Grant
    Filed: May 13, 1980
    Date of Patent: October 6, 1981
    Assignee: GAF Corporation
    Inventors: Elton L. Beavan, E. Bradley Moynahan
  • Patent number: 4267202
    Abstract: A method for modifying the surface properties of polymer substrates which is expedient and effective to give printability, adhesiveness and other desirable properties to the surfaces of polymer substrates is set forth. The method comprises the steps of: subjecting the surfaces to electric discharge treatment, then applying a photopolymerizable composition to the surfaces and irradiating the layer of photopolymerizable composition on the substrate surfaces with actinic rays, thereby photo-grafting the radically polymerizable compound contained in the photopolymerizable composition to the surfaces of the polymer substrates.
    Type: Grant
    Filed: May 21, 1979
    Date of Patent: May 12, 1981
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Hiroyuki Nakayama, Tsuguo Nezu
  • Patent number: 4264706
    Abstract: The properties of a dichromated hydrophilic colloid photosensitive composition are improved by the incorporation of certain copolymer latices. More particularly, the copolymer particles in the latex conform to the structure:--A).sub. (B --.phi.-awherein A is a polymerized monomer or monomers having the structure: ##STR1## and B is a polymerized monomer or monomers having the structure: ##STR2## wherein each R.sup.1 is independently hydrogen or methyl;R.sup.2 is phenyl, substituted phenyl or a straight- or branched-chain alkoxycarbonyl group of about 2-8 carbon atoms;R.sup.3 is --NR.sup.4 R.sup.5 or --OR.sup.6 wherein R.sup.4 and R.sup.5 are independently selected from hydrogen, alkyl of about 1-8 carbon atoms including substituted alkyl, and alkyl containing hetero atoms in the alkyl chain, and R.sup.6 is hydroxyalkyl of about 1-8 carbon atoms; anda represents a weight percent of about 75-95.
    Type: Grant
    Filed: March 12, 1980
    Date of Patent: April 28, 1981
    Assignee: Eastman Kodak Company
    Inventors: Richard C. Sutton, Thomas W. Martin
  • Patent number: 4252885
    Abstract: Light-sensitive photographic films are produced by coating polyester films with aqueous dispersions of polyesters or copolyesters containing free-functional acid groups. Corona discharge treatment of the polyester or copolyester layers is disclosed for direct adhesion to photographic emulsions or indirect adhesion via a polymeric sub and/or gelatin sub.
    Type: Grant
    Filed: March 22, 1978
    Date of Patent: February 24, 1981
    Assignee: Bexford Limited
    Inventors: Patrick T. McGrail, David R. Mann
  • Patent number: 4241169
    Abstract: To improve adhesion of a hydrophilic photographic emulsion to a hydrophobic polyester film base the latter is pretreated by electrical discharge, flame or chemical treatment, and then given a sub-coating composed of an aqueous dispersion of gelatin, a water-soluble polyester, and a polyfunctional aziridine crosslinking agent, and this coating is then thermally cured.
    Type: Grant
    Filed: May 21, 1979
    Date of Patent: December 23, 1980
    Assignee: E. I. Du Pont de Nemours & Company
    Inventors: Ray A. Work, III, Richard P. Pankratz
  • Patent number: 4229523
    Abstract: A method of undercoating a polyester film of a light sensitive photographic material is disclosed in which one side of the film is pretreated such that the contact angle with water is below 58.degree.. Additionally, a layer of an aqueous dispersion containing no organic solvent is applied to said side of said film, said dispersion containing a copolymer containing up to 60% by weight of glycidyl methacrylate and 25-60% by weight of ethyl acrylate.
    Type: Grant
    Filed: March 30, 1979
    Date of Patent: October 21, 1980
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Hideyasu Ohta, Jun Shirasaki, Masaru Kanbe, Naoto Abe, Takahiro Uozumi, Masayoshi Mayama
  • Patent number: 4220471
    Abstract: A photographic material comprising a support having on the surface a polypropylene resin component and a hydrophilic colloidal layer on the top surface which are firmly adhered together, is produced by subjecting the support having on the surface a polypropylene resin component to corona discharge, applying thereto a subbing layer comprising (a) at least one water-dispersed polymer latex selected from butadiene-acrylic ester copolymers, polyvinyl chloride and polystyrene, (b) a compound having an ethyleneimino group such as that capable of hardening a colloidal gelatin or casein, and (c) a water-soluble polymer, and providing a hydrophilic protective colloidal layer on said subbing layer.
    Type: Grant
    Filed: October 4, 1978
    Date of Patent: September 2, 1980
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Sukeaki Date, Seigo Ebato
  • Patent number: 4186018
    Abstract: A method for surface treating a support for a photographic light-sensitive material, said support having a polyolefinic surface, which comprises flame treating said surface using a flame supported by a combustion gas consisting of a paraffinic or an olefinic hydrocarbon gas and oxygen gas, said combustion gas having the composition within the area ABCDE of FIG. 2, is disclosed.
    Type: Grant
    Filed: October 29, 1975
    Date of Patent: January 29, 1980
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobuhiko Minagawa, Hiroyuki Kurabayashi
  • Patent number: 4181528
    Abstract: To improve adhesion of a hydrophilic photographic emulsion to a hydrophobic polyester film base the latter is pretreated by electrical discharge, flame or chemical treatment, and then given a sub-coating composed of an aqueous dispersion of gelatin, a water-soluble polyester, and a polyfunctional aziridine crosslinking agent, and this coating is then thermally cured.
    Type: Grant
    Filed: March 20, 1978
    Date of Patent: January 1, 1980
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Ray A. Work, III, Richard P. Pankratz