Substituted At Coupling Position With Other Than Hydrogen Patents (Class 430/555)
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Patent number: 4310623Abstract: A color photographic light-sensitive material is described, comprising a support having thereon a silver halide emulsion layer containing at least one coupler represented by formula (I) ##STR1## wherein R.sub.1 represents an anilino group, an acylamino group or a ureido group, R.sub.2 represents an aralkyl group, an alkyl group, or an alkenyl group, X.sub.1, X.sub.2, and X.sub.3 each represents hydrogen, an alkyl group, a halogen atom, an alkoxy group, an aryloxy group, an acylamino group, a carbamoyl group, a sulfamoyl group, a sulfonyl group or a cyano group and X.sub.1, X.sub.2, and X.sub.3 may be the same or different, and at least one of said silver halide emulsion layer and a hydrophilic colloid layer adjacent thereto containing a 1-phenyl-3-pyrazolidone compound having a diffusion resistant group in the presence of an organic solvent having a high boiling point for a photographic additive.The photographic light-sensitive material provides a magenta color image having a high sensitivity.Type: GrantFiled: December 15, 1980Date of Patent: January 12, 1982Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshiyuki Watanabe, Masakazu Morigaki
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Patent number: 4301235Abstract: A process for forming a color photographic image is described comprising processing a silver halide color phototgraphic light-sensitive material in the presence of a 5-pyrazolone magenta coupler represented by the formula (I) ##STR1## wherein R represents an acylamino group, an anilino group or a ureido group; R.sub.Type: GrantFiled: September 5, 1980Date of Patent: November 17, 1981Assignee: Fuji Photo Film Co., Ltd.Inventors: Seiji Ichijima, Nobuo Furutachi
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Patent number: 4297440Abstract: A color photographic light-sensitive element is described comprising a support having thereon a silver halide emulsion layer containing therein a 3-anilino-5-pyrazolone magenta color-forming coupler represented by formula (I) ##STR1## wherein X represents a halogen atom or an alkoxy group; Ar represents an aryl group; R.sub.1 represents hydrogen, a halogen atom, an alkyl group, an alkoxy group or an alkylthio group; Y represents a non-metallic atomic group forming a 5-membered or 6-membered ring together with the ##STR2## group, except that Y does not include a carbonyl group; and Z represents hydrogen or a coupling-off group.The magenta color images obtained after color development processing of the color photographic light-sensitive element have an excellent light-fastness, and the formation of yellow stain in the unexposed areas thereof is prevented.Type: GrantFiled: November 25, 1980Date of Patent: October 27, 1981Assignee: Fuji Photo Film Co., Ltd.Inventors: Kozo Aoki, Satoru Sawada, Yoshiharu Yabuki, Nobuo Furutachi
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Patent number: 4286054Abstract: A light-sensitive, color photographic silver halide multilayer material contains for the improvement of definition, grain and color rendition DIR-couplers which are substituted in coupling position by mercapto-azole-, mercaptobenz-azole- or mercapto-azine moieties, which themselves carry hydrophilic substituents. The DIR-couplers according to the invention may be used together with other couplers and additives or as sole color forming element and are noteworthy for their high color yields, inter- and intra-image effects. They may be added as well in hydrophobic state (in dispersed form) as in hydrophilic state (as alkaline solutions) and they may be used in single layers or as associated layers with a maximum three layers of a color forming unit and the layers may be arranged in any desired order within the whole combination of layers.Type: GrantFiled: May 29, 1980Date of Patent: August 25, 1981Assignee: VEB Filmfabrik WolfenInventors: Horst Englemann, Rainer Redmann, Monika Bethke, Christa Melz, Gerd West, Jurgen Mistol, Udo Sydow
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Patent number: 4283472Abstract: Novel 5-pyrazolone magenta dye-forming couplers are blocked with a coupler moiety which yields an alkali-soluble or colorless reaction product. The coupler moiety is joined via its coupling position to the enol oxygen of the 5-pyrazolone and is displaced therefrom during processing as a result of reaction by means of oxidized color developing agent to thereby activate the 5-pyrazolone coupler. These couplers have good reactivity and good resistance to aerial contaminants, such a formaldehyde, and can be incorporated in photographic emulsions and elements.Type: GrantFiled: February 26, 1980Date of Patent: August 11, 1981Assignee: Eastman Kodak CompanyInventors: Thomas E. Gompf, Howell A. Hammond, Jared B. Mooberry
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Patent number: 4277559Abstract: Photographic color elements are described wherein one of the emulsion layers comprise a 4-phenylazo-2-pyrazolin-5-one coupler, the phenylazo group of which carries a p-alkoxy group of the formula:--O--Alk--X--Rwherein:Alk represents a straight-chain or branched-chain alkylene group, which may carry an aryl substituent,X represents a linking group, andR represents an aryl group.Type: GrantFiled: February 14, 1977Date of Patent: July 7, 1981Assignee: AGFA-Gevaert N.V.Inventors: Jan Jaeken, Andre Verhecken
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Patent number: 4277398Abstract: Orange colored magenta color couplers of the general formula ##STR1## are provided, in which R is optionally substituted alkyl, aralkyl, aryl or a heterocyclic group, X is optionally substituted aryl, Y is optionally substituted acyl-amino, aroyl amino or aryl amino and Z represents further optional substituents of the phenyl ring. Preferably Y also contains a ballasting group, which is a long claim alkyl group having 10 to 24 carbon atoms in the chain.Type: GrantFiled: August 8, 1979Date of Patent: July 7, 1981Assignee: Ciba-Geigy AGInventor: Brian R. D. Whitear
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Patent number: 4273861Abstract: A multilayer color photographic material with improved color reproduction comprising a support having thereon at least two photosensitive silver halide emulsion layers which provide color images having different colors from each other, the multilayer color photographic material containing at least one interlayer color correction coupler as defined hereinafter.Type: GrantFiled: February 23, 1976Date of Patent: June 16, 1981Assignee: Fuji Photo Film Co., Ltd.Inventors: Keisuke Shiba, Takeshi Hirose, Jun Hayashi, Atsuaki Arai, Nobuo Furutachi, Harumi Katsuyama
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Patent number: 4273864Abstract: A color photographic light-sensitive material comprising a support having thereon a silver halide emulsion layer containing a 3-anilino-5-pyrazolone type magenta coupler and at least one of the compounds represented by the formula (I) ##STR1## wherein R.sub.1 and R.sub.2 represent each a tertiary alkyl group having 4 to 20 carbon atoms.Type: GrantFiled: December 20, 1979Date of Patent: June 16, 1981Assignee: Fuji Photo Film Co., Ltd.Inventors: Tsutomu Hamaoka, Masakazu Morigaki, Satoru Sawada, Takayoshi Kamio, Kotaro Nakamura
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Patent number: 4268592Abstract: Light-sensitive recording material for color photography, which contains, in at least one silver halide emulsion layer, at least one magenta coupler of the formula ##STR1## in which A is a 5-membered, heterocyclic, unsaturated ring system which contains 2 or 3 hetero-atoms, at least one of which is a nitrogen atom, and can be fused with a benzene ring and which is substituted by at least one ballast group, R is a substituted or unsubstituted aryl radical, R.sub.1 is hydrogen, halogen, alkyl, alkoxy, halogenoalkyl, alkylsulfonyl or aryloxy and X is a radical detachable during the coupling reaction.The magenta couplers show high reactivity (high maximum density), which facilitates accelerated processing of the photographic materials, and minimal fogging. The couplers also have good fastness to light.Type: GrantFiled: August 28, 1979Date of Patent: May 19, 1981Assignee: Ciba-Geigy AGInventor: Paul Tschopp
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Patent number: 4264720Abstract: A silver halide color photographic light-sensitive material which contains a 3-anilino-5-pyrazolone type of magenta coupler and a novel dye image-stabilizing agent of the general formula (I) as hereinafter defined.Type: GrantFiled: December 28, 1979Date of Patent: April 28, 1981Assignee: Fuji Photo Film Co., Ltd.Inventors: Tsutomu Hamaoka, Masakazu Morigaki, Satoru Sawada, Nobutaka Ohki, Kotaro Nakamura
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Patent number: 4264723Abstract: Silver halide color photographic sensitive materials which comprise photographic layers containing at least one of the couplers represented by the following general formula (I): ##STR1## wherein R.sub.1 represents an anilino group, an acylamino group or a ureido group, R.sub.2 represents an alkyl group, an aralkyl group or an alkenyl group, X.sub.1, X.sub.2 and X.sub.3 each represents a hydrogen atom, an alkyl group, a halogen atom, an alkoxy group, an aryloxy group, an acylamino group, a carbamoyl group, a sulfamoyl group, a sulfonyl group, a cyano group or an alkoxycarbonyl group and X.sub.1, X.sub.2 and X.sub.3 may be the same or different, are disclosed.Type: GrantFiled: November 5, 1979Date of Patent: April 28, 1981Assignee: Fuji Photo Film Co., Ltd.Inventors: Seiji Ichijima, Nobuo Seto, Toshiyuki Watanabe, Nobuo Furutachi
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Patent number: 4254213Abstract: A process for forming a dye image is disclosed which comprises processing an image-wise exposed silver halide photographic emulsion with an aromatic primary amine color developing agent in the presence of bis pyrazolines obtained by reacting 3-acylamino-5-pyrazolones with para-hydroxybenzaldehydes having at least one of the ortho positions to the hydroxy group substituted with a member selected from halogen, alkyl, aryl, amino or amido groups. The invention includes the present dye forming coupler alone and combined with the silver halide emulsion layer.Type: GrantFiled: January 28, 1980Date of Patent: March 3, 1981Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Kosaku Masuda, Hajime Wada, Kiyoshi Yamashita
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Patent number: 4248962Abstract: Photographic couplers which release a photographically useful group by an intramolecular nucleophilic displacement reaction can be used in photographic emulsions, elements and processes to provide a photographically useful group in a controlled manner.Type: GrantFiled: December 22, 1978Date of Patent: February 3, 1981Assignee: Eastman Kodak CompanyInventor: Philip T. S. Lau
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Patent number: 4241168Abstract: A photographic two-equivalent magenta coupler represented by the following general formula (I): ##STR1## wherein [A] represents a magenta color image-forming coupler residue, and the ##STR2## moiety represents a group replacing a hydrogen atom of an active methylene group in coupler [A] wherein Z.sub.a Z.sub.b, Z.sub.c and Z.sub.d, which can be the same or different, each represents a methine group or an --N.dbd. group, and the nitrogen-containing ring formed by Z.sub.a to Z.sub.d may further be substituted with a fused ring, with the proviso that the ##STR3## moiety does not represent a benzotriazolyl-1, benzotriazolyl-2, benzimidazolyl-1 or indazolyl-1 group; a photographic light sensitive material containing the photographic coupler; and a method of forming images using the photographic coupler.Type: GrantFiled: September 21, 1977Date of Patent: December 23, 1980Assignee: Fuji Photo Film Co., Ltd.Inventors: Atsuaki Arai, Keisuke Shiba, Minoru Yamada, Nobuo Furutachi
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Patent number: 4241172Abstract: A silver halide color photographic material comprising a coupler represented by the following general formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 individually represent a substituted or unsubstituted alkyl, alkenyl, aryl, cycloalkyl group, or,-A-X).sub.n ].sub.m Cp in which Cp represents a cyan coupler, magenta coupler or yellow coupler, A represents a substituted or unsubstituted divalent aliphatic group, X represents a divalent group, and m and n individually represent a value of 0 or 1, provided that at least one of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 is -A-X).sub.n ].sub.m Cp.Type: GrantFiled: May 24, 1979Date of Patent: December 23, 1980Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Kenichiro Okaniwa, Takashi Uchida, Morio Kobayashi, Hiroshi Sugita, Takashi Sasaki
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Patent number: 4237217Abstract: A two-equivalent magenta coupler in which the coupling position is substituted with a sulfonamido group, and capable of forming a magenta color image on coupling with an oxidation product of an aromatic primary amine developing agent, and a silver halide color photographic light-sensitive material having at least one silver halide emulsion layer on a support and containing the two-equivalent magenta coupler.Type: GrantFiled: November 17, 1977Date of Patent: December 2, 1980Assignee: Fuji Photo Film Co., Ltd.Inventors: Atsuaki Arai, Keisuke Shiba, Minoru Yamada, Nobuo Furutachi, Kotaro Nakamura
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Patent number: 4191574Abstract: A process for forming a photographic magenta dye image is disclosed which requires contacting exposed silver halide with a color developing agent in the presence of a particular class of 2-equivalent magenta couplers.Type: GrantFiled: August 2, 1978Date of Patent: March 4, 1980Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Takaya Endo, Shui Sato, Shoji Kikuchi, Tamotsu Kozima, Tugumoto Usui, Hiroyuki Imamura, Koichi Takabe