Substituted At Coupling Position With Other Than Hydrogen Patents (Class 430/555)
  • Patent number: 4310623
    Abstract: A color photographic light-sensitive material is described, comprising a support having thereon a silver halide emulsion layer containing at least one coupler represented by formula (I) ##STR1## wherein R.sub.1 represents an anilino group, an acylamino group or a ureido group, R.sub.2 represents an aralkyl group, an alkyl group, or an alkenyl group, X.sub.1, X.sub.2, and X.sub.3 each represents hydrogen, an alkyl group, a halogen atom, an alkoxy group, an aryloxy group, an acylamino group, a carbamoyl group, a sulfamoyl group, a sulfonyl group or a cyano group and X.sub.1, X.sub.2, and X.sub.3 may be the same or different, and at least one of said silver halide emulsion layer and a hydrophilic colloid layer adjacent thereto containing a 1-phenyl-3-pyrazolidone compound having a diffusion resistant group in the presence of an organic solvent having a high boiling point for a photographic additive.The photographic light-sensitive material provides a magenta color image having a high sensitivity.
    Type: Grant
    Filed: December 15, 1980
    Date of Patent: January 12, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshiyuki Watanabe, Masakazu Morigaki
  • Patent number: 4301235
    Abstract: A process for forming a color photographic image is described comprising processing a silver halide color phototgraphic light-sensitive material in the presence of a 5-pyrazolone magenta coupler represented by the formula (I) ##STR1## wherein R represents an acylamino group, an anilino group or a ureido group; R.sub.
    Type: Grant
    Filed: September 5, 1980
    Date of Patent: November 17, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiji Ichijima, Nobuo Furutachi
  • Patent number: 4297440
    Abstract: A color photographic light-sensitive element is described comprising a support having thereon a silver halide emulsion layer containing therein a 3-anilino-5-pyrazolone magenta color-forming coupler represented by formula (I) ##STR1## wherein X represents a halogen atom or an alkoxy group; Ar represents an aryl group; R.sub.1 represents hydrogen, a halogen atom, an alkyl group, an alkoxy group or an alkylthio group; Y represents a non-metallic atomic group forming a 5-membered or 6-membered ring together with the ##STR2## group, except that Y does not include a carbonyl group; and Z represents hydrogen or a coupling-off group.The magenta color images obtained after color development processing of the color photographic light-sensitive element have an excellent light-fastness, and the formation of yellow stain in the unexposed areas thereof is prevented.
    Type: Grant
    Filed: November 25, 1980
    Date of Patent: October 27, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kozo Aoki, Satoru Sawada, Yoshiharu Yabuki, Nobuo Furutachi
  • Patent number: 4286054
    Abstract: A light-sensitive, color photographic silver halide multilayer material contains for the improvement of definition, grain and color rendition DIR-couplers which are substituted in coupling position by mercapto-azole-, mercaptobenz-azole- or mercapto-azine moieties, which themselves carry hydrophilic substituents. The DIR-couplers according to the invention may be used together with other couplers and additives or as sole color forming element and are noteworthy for their high color yields, inter- and intra-image effects. They may be added as well in hydrophobic state (in dispersed form) as in hydrophilic state (as alkaline solutions) and they may be used in single layers or as associated layers with a maximum three layers of a color forming unit and the layers may be arranged in any desired order within the whole combination of layers.
    Type: Grant
    Filed: May 29, 1980
    Date of Patent: August 25, 1981
    Assignee: VEB Filmfabrik Wolfen
    Inventors: Horst Englemann, Rainer Redmann, Monika Bethke, Christa Melz, Gerd West, Jurgen Mistol, Udo Sydow
  • Patent number: 4283472
    Abstract: Novel 5-pyrazolone magenta dye-forming couplers are blocked with a coupler moiety which yields an alkali-soluble or colorless reaction product. The coupler moiety is joined via its coupling position to the enol oxygen of the 5-pyrazolone and is displaced therefrom during processing as a result of reaction by means of oxidized color developing agent to thereby activate the 5-pyrazolone coupler. These couplers have good reactivity and good resistance to aerial contaminants, such a formaldehyde, and can be incorporated in photographic emulsions and elements.
    Type: Grant
    Filed: February 26, 1980
    Date of Patent: August 11, 1981
    Assignee: Eastman Kodak Company
    Inventors: Thomas E. Gompf, Howell A. Hammond, Jared B. Mooberry
  • Patent number: 4277559
    Abstract: Photographic color elements are described wherein one of the emulsion layers comprise a 4-phenylazo-2-pyrazolin-5-one coupler, the phenylazo group of which carries a p-alkoxy group of the formula:--O--Alk--X--Rwherein:Alk represents a straight-chain or branched-chain alkylene group, which may carry an aryl substituent,X represents a linking group, andR represents an aryl group.
    Type: Grant
    Filed: February 14, 1977
    Date of Patent: July 7, 1981
    Assignee: AGFA-Gevaert N.V.
    Inventors: Jan Jaeken, Andre Verhecken
  • Patent number: 4277398
    Abstract: Orange colored magenta color couplers of the general formula ##STR1## are provided, in which R is optionally substituted alkyl, aralkyl, aryl or a heterocyclic group, X is optionally substituted aryl, Y is optionally substituted acyl-amino, aroyl amino or aryl amino and Z represents further optional substituents of the phenyl ring. Preferably Y also contains a ballasting group, which is a long claim alkyl group having 10 to 24 carbon atoms in the chain.
    Type: Grant
    Filed: August 8, 1979
    Date of Patent: July 7, 1981
    Assignee: Ciba-Geigy AG
    Inventor: Brian R. D. Whitear
  • Patent number: 4273861
    Abstract: A multilayer color photographic material with improved color reproduction comprising a support having thereon at least two photosensitive silver halide emulsion layers which provide color images having different colors from each other, the multilayer color photographic material containing at least one interlayer color correction coupler as defined hereinafter.
    Type: Grant
    Filed: February 23, 1976
    Date of Patent: June 16, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keisuke Shiba, Takeshi Hirose, Jun Hayashi, Atsuaki Arai, Nobuo Furutachi, Harumi Katsuyama
  • Patent number: 4273864
    Abstract: A color photographic light-sensitive material comprising a support having thereon a silver halide emulsion layer containing a 3-anilino-5-pyrazolone type magenta coupler and at least one of the compounds represented by the formula (I) ##STR1## wherein R.sub.1 and R.sub.2 represent each a tertiary alkyl group having 4 to 20 carbon atoms.
    Type: Grant
    Filed: December 20, 1979
    Date of Patent: June 16, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tsutomu Hamaoka, Masakazu Morigaki, Satoru Sawada, Takayoshi Kamio, Kotaro Nakamura
  • Patent number: 4268592
    Abstract: Light-sensitive recording material for color photography, which contains, in at least one silver halide emulsion layer, at least one magenta coupler of the formula ##STR1## in which A is a 5-membered, heterocyclic, unsaturated ring system which contains 2 or 3 hetero-atoms, at least one of which is a nitrogen atom, and can be fused with a benzene ring and which is substituted by at least one ballast group, R is a substituted or unsubstituted aryl radical, R.sub.1 is hydrogen, halogen, alkyl, alkoxy, halogenoalkyl, alkylsulfonyl or aryloxy and X is a radical detachable during the coupling reaction.The magenta couplers show high reactivity (high maximum density), which facilitates accelerated processing of the photographic materials, and minimal fogging. The couplers also have good fastness to light.
    Type: Grant
    Filed: August 28, 1979
    Date of Patent: May 19, 1981
    Assignee: Ciba-Geigy AG
    Inventor: Paul Tschopp
  • Patent number: 4264720
    Abstract: A silver halide color photographic light-sensitive material which contains a 3-anilino-5-pyrazolone type of magenta coupler and a novel dye image-stabilizing agent of the general formula (I) as hereinafter defined.
    Type: Grant
    Filed: December 28, 1979
    Date of Patent: April 28, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tsutomu Hamaoka, Masakazu Morigaki, Satoru Sawada, Nobutaka Ohki, Kotaro Nakamura
  • Patent number: 4264723
    Abstract: Silver halide color photographic sensitive materials which comprise photographic layers containing at least one of the couplers represented by the following general formula (I): ##STR1## wherein R.sub.1 represents an anilino group, an acylamino group or a ureido group, R.sub.2 represents an alkyl group, an aralkyl group or an alkenyl group, X.sub.1, X.sub.2 and X.sub.3 each represents a hydrogen atom, an alkyl group, a halogen atom, an alkoxy group, an aryloxy group, an acylamino group, a carbamoyl group, a sulfamoyl group, a sulfonyl group, a cyano group or an alkoxycarbonyl group and X.sub.1, X.sub.2 and X.sub.3 may be the same or different, are disclosed.
    Type: Grant
    Filed: November 5, 1979
    Date of Patent: April 28, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiji Ichijima, Nobuo Seto, Toshiyuki Watanabe, Nobuo Furutachi
  • Patent number: 4254213
    Abstract: A process for forming a dye image is disclosed which comprises processing an image-wise exposed silver halide photographic emulsion with an aromatic primary amine color developing agent in the presence of bis pyrazolines obtained by reacting 3-acylamino-5-pyrazolones with para-hydroxybenzaldehydes having at least one of the ortho positions to the hydroxy group substituted with a member selected from halogen, alkyl, aryl, amino or amido groups. The invention includes the present dye forming coupler alone and combined with the silver halide emulsion layer.
    Type: Grant
    Filed: January 28, 1980
    Date of Patent: March 3, 1981
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Kosaku Masuda, Hajime Wada, Kiyoshi Yamashita
  • Patent number: 4248962
    Abstract: Photographic couplers which release a photographically useful group by an intramolecular nucleophilic displacement reaction can be used in photographic emulsions, elements and processes to provide a photographically useful group in a controlled manner.
    Type: Grant
    Filed: December 22, 1978
    Date of Patent: February 3, 1981
    Assignee: Eastman Kodak Company
    Inventor: Philip T. S. Lau
  • Patent number: 4241168
    Abstract: A photographic two-equivalent magenta coupler represented by the following general formula (I): ##STR1## wherein [A] represents a magenta color image-forming coupler residue, and the ##STR2## moiety represents a group replacing a hydrogen atom of an active methylene group in coupler [A] wherein Z.sub.a Z.sub.b, Z.sub.c and Z.sub.d, which can be the same or different, each represents a methine group or an --N.dbd. group, and the nitrogen-containing ring formed by Z.sub.a to Z.sub.d may further be substituted with a fused ring, with the proviso that the ##STR3## moiety does not represent a benzotriazolyl-1, benzotriazolyl-2, benzimidazolyl-1 or indazolyl-1 group; a photographic light sensitive material containing the photographic coupler; and a method of forming images using the photographic coupler.
    Type: Grant
    Filed: September 21, 1977
    Date of Patent: December 23, 1980
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Atsuaki Arai, Keisuke Shiba, Minoru Yamada, Nobuo Furutachi
  • Patent number: 4241172
    Abstract: A silver halide color photographic material comprising a coupler represented by the following general formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 individually represent a substituted or unsubstituted alkyl, alkenyl, aryl, cycloalkyl group, or,-A-X).sub.n ].sub.m Cp in which Cp represents a cyan coupler, magenta coupler or yellow coupler, A represents a substituted or unsubstituted divalent aliphatic group, X represents a divalent group, and m and n individually represent a value of 0 or 1, provided that at least one of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 is -A-X).sub.n ].sub.m Cp.
    Type: Grant
    Filed: May 24, 1979
    Date of Patent: December 23, 1980
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Kenichiro Okaniwa, Takashi Uchida, Morio Kobayashi, Hiroshi Sugita, Takashi Sasaki
  • Patent number: 4237217
    Abstract: A two-equivalent magenta coupler in which the coupling position is substituted with a sulfonamido group, and capable of forming a magenta color image on coupling with an oxidation product of an aromatic primary amine developing agent, and a silver halide color photographic light-sensitive material having at least one silver halide emulsion layer on a support and containing the two-equivalent magenta coupler.
    Type: Grant
    Filed: November 17, 1977
    Date of Patent: December 2, 1980
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Atsuaki Arai, Keisuke Shiba, Minoru Yamada, Nobuo Furutachi, Kotaro Nakamura
  • Patent number: 4191574
    Abstract: A process for forming a photographic magenta dye image is disclosed which requires contacting exposed silver halide with a color developing agent in the presence of a particular class of 2-equivalent magenta couplers.
    Type: Grant
    Filed: August 2, 1978
    Date of Patent: March 4, 1980
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Takaya Endo, Shui Sato, Shoji Kikuchi, Tamotsu Kozima, Tugumoto Usui, Hiroyuki Imamura, Koichi Takabe