Four Or More Distinct Heterocyclic Nuclei Patents (Class 430/579)
  • Patent number: 8445857
    Abstract: A flame sensor is provided with a focusing member. Ultraviolet light emitted from a light source is reflected by an inner surface of the focusing member to be focused on an electrode of an electrode pair, to increase the sensitivity.
    Type: Grant
    Filed: March 11, 2011
    Date of Patent: May 21, 2013
    Assignee: Azbil Corporation
    Inventors: Yoshihide Sugino, Keisuke Sumiyoshi, Nanako Yanada, Yuuichi Nakajima
  • Patent number: 7291449
    Abstract: Disclosed is a silver halide photographic material which comprises at least one methine dye represented by the following formula (I): wherein Y represents a furan ring or a pyrrole ring, and Y may further be condensed with other 5- or 6-membered carbocyclic ring or heterocyclic ring, or may have a substituent; the bond between two carbon atoms in which Y is condensed may be a single bond or a double bond; Z represents an atomic group necessary to form a 5- or 6-membered nitrogen-containing heterocyclic ring, and Z may further be condensed with other 5- or 6-membered carbocyclic ring or heterocyclic ring; R represents a substituted or unsubstituted alkyl group, aryl group, or heterocyclic group; D represents a group necessary to form a methine dye; L1 and L2 each represents a methine group; p represents 0 or 1; M represents a counter ion; and m represents a number of 0 or higher necessary to neutralize the charge in the molecule.
    Type: Grant
    Filed: August 17, 2001
    Date of Patent: November 6, 2007
    Assignee: Fujifilm Corporation
    Inventors: Tetsuo Nakamura, Takanori Hioki, Katsuhisa Ohzeki, Naoyuki Hanaki
  • Patent number: 7052827
    Abstract: A silver halide photographic material including at least one methine dye represented by the following general formula (I) and at least one coupler represented by the following general formula (XX): wherein X1 and X2 each represents an oxygen atom, a sulfur atom, a selenium atom, a tellurium atom, or a nitrogen atom; Y1 represents a furan, pyrrole or thiophene ring which may be condensed with another 5- or 6-membered carbon ring or heterocycle or may have a substituent group; Y2 represents an atomic group necessary for forming a benzene ring or a 5- or 6-membered unsaturated heterocycle, which may be further condensed with another 5- or 6-membered carbon ring or heterocycle or may have a substituent group; a bond between two carbon atoms by which Y1 and Y2 are each condensed with the carbon ring or the heterocycle may be a single bond or a double bond; R1 and R2 each represents a substituted or unsubstituted alkyl, aryl or heterocyclic group; L1, L2 and L3 each represents a methine group; n1 represents 0 o
    Type: Grant
    Filed: August 27, 2004
    Date of Patent: May 30, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Tetsuo Nakamura
  • Patent number: 6828087
    Abstract: A silver halide photographic material comprising at least one methine dye of formula (I) and at least one coupler of formula (X): wherein X1 and X2 each represents O, S, Se, Te, N or C; Y1 represents a furan, pyrrole or thiophene ring which may be condensed and substituted with the specific ring; Y2 represents an atomic group necessary for forming a benzene ring or a 5- or 6-membered unsaturated heterocycle; R1 and R2 each represents a substituted or unsubstituted alkyl, aryl or heterocyclic group; L1, L2 and L3 each represents a methine group; n1 represents 0 or 1; M1 represents a counter ion; and m1 represents a number of 0 or more necessary for neutralizing a charge in a molecule; wherein Z1 and Z2 each represents —C(Q3)═ or —N═; Q1 and Q3 each represents a hydrogen atom or a monovalent substituent group; Q2 represents a hydrogen atom or a coupling release group.
    Type: Grant
    Filed: September 23, 2002
    Date of Patent: December 7, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Tetsuo Nakamura
  • Patent number: 6649337
    Abstract: A heat-developable photosensitive material comprises: a support; a photosensitive silver halide; a non-photosensitive organic silver salt; a reducing agent for a silver ion; a binder; and a compound having specified structure.
    Type: Grant
    Filed: November 15, 2001
    Date of Patent: November 18, 2003
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takanori Hioki, Katsumi Kobayashi
  • Patent number: 6333146
    Abstract: Disclosed is a compound represented by the following formula (I): wherein Z1 represents an atomic group necessary to form a 5- or 6-membered nitrogen-containing heterocyclic ring; Z2 represents an atomic group necessary to form a 5- or 6-membered heterocyclic ring, Z2 may further be substituted, or may be condensed with a hetero ring or a benzene ring; R1 represents a hydrogen atom, a halogen atom, a mercapto group, an alkyl group, an alkenyl group, an aryl group, an alkylthio group, an alkenylthio group, or an arylthio group; L1 and L2 each represents a methine group; p1 represents 0 or 1; V1 represents a substituent; and n represents 0, 1 or 2, and when n represents 2, a plurality of V1 may be the same or different.
    Type: Grant
    Filed: March 10, 2000
    Date of Patent: December 25, 2001
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Katsumi Kobayashi, Takashi Katoh, Junji Nishigaki
  • Patent number: 6329133
    Abstract: This invention comprises a silver halide photographic material comprising at least one silver halide emulsion comprising silver halide grains having associated therewith a combination of two or more dyes wherein (b) (a) a dye having at least one substituent that has a negative charge is present, a dye having at least one substituent that has a positive charge is present, wherein at least one of the dyes is further substituted with at least one hydrogen bonding donor substituent. In a preferred embodiment, at least one of the dyes is substituted with at least two hydrogen bonding donor substituents. In another preferred embodiment a silver halide photographic material comprises at least one silver halide emulsion comprising silver halide grains having associated therewith a dye substituted with at least one guanidinium, amidinium, or imine of urea substituent.
    Type: Grant
    Filed: September 13, 1999
    Date of Patent: December 11, 2001
    Assignee: Eastman Kodak Company
    Inventors: Andrei Andrievsky, Richard L. Parton, Thomas L. Penner, William J. Harrison
  • Patent number: 6153371
    Abstract: This invention comprises a photographic element comprising a support and at least one silver halide emulsion layer in which the silver halide is sensitized with a compound of the formula:Q-XYwherein Q represents the atoms necessary to form a chromophore comprising an amidinium-ion, a carboxyl-ion or dipolar-amidic chromophoric system when conjugated with XY, and XY is a fragmentable electron donor moiety in which X is an electron donor group and Y is a leaving group other than hydrogen, and wherein:1) XY has an oxidation potential between 0 and about 1.4 V;2) the oxidized form of XY undergoes a bond cleavage reaction to give the radical X.sup..cndot. and the leaving fragment Y.In a preferred embodiment of the invention, the radical X.cndot. has an oxidation potential <-0.7V.
    Type: Grant
    Filed: July 17, 1998
    Date of Patent: November 28, 2000
    Assignee: Eastman Kodak Company
    Inventors: Samir Y. Farid, Ian R. Gould, Stephen A. Godleski, Jerome R. Lenhard, Annabel A. Muenter, Paul A. Zielinski
  • Patent number: 6054259
    Abstract: A silver halide photographic material which contains at least one methine compound represented by the following formula (I) or (II): wherein Z.sub.1, Z.sub.2 and Z.sub.3 each represents an atomic group necessary to form a 5- or 6-membered nitrogen-containing heterocyclic ring; R.sub.1 and R.sub.3 each represents an alkyl group; R.sub.2 represents a hydrogen atom, an alkyl group, an aryl group or a heterocyclic group; L.sub.1, L.sub.2, L.sub.3, L.sub.4, L.sub.5, L.sub.6, L.sub.7, L.sub.8 and L.sub.9 each represents a methine group; p.sub.1 and p.sub.2 each represents 0 or 1; n.sub.1 and n.sub.2 each represents 0, 1, 2, 3 or 4; M.sub.1 represents a counter ion to balance a charge; and m.sub.1 represents a number of 0 or more necessary for to neutralize a charge in the molecule; provided that at least one of R.sub.1, R.sub.2, R.sub.3, Z.sub.1, Z.sub.2, Z.sub.3, L.sub.1, L.sub.2, L.sub.3, L.sub.4, L.sub.5, L.sub.6, L.sub.7, L.sub.8 and L.sub.9 has a thioether group; ##STR1## wherein Z.sub.4, Z.sub.5 and Z.sub.
    Type: Grant
    Filed: March 18, 1998
    Date of Patent: April 25, 2000
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Takanori Hioki
  • Patent number: 5863714
    Abstract: There is disclosed a silver halide light-sensitive material which contains a methine compound represented by general formula (1):General formula (1) ##STR1## wherein A1, A2, and A3 each represent a streptocyanine dye; L1, L2, L3, and L4 each represent a divalent linking group, and n1 represents an integer of not less than 0. The light-sensitive material exhibits high absorptivity.
    Type: Grant
    Filed: April 15, 1997
    Date of Patent: January 26, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takashi Kato, Takayoshi Oyamada
  • Patent number: 5578439
    Abstract: A silver halide photographic material is described, which contains the methine compound represented by the following formula (I): ##STR1## wherein Z.sup.1 represents a nonmetal atomic group necessary for completing a 5- or 6-membered heterocyclic ring which may be condensed; R.sup.1 represents an aliphatic or aromatic group which may be substituted; G.sup.1 represents a hydroxyl group, an amino group, an aliphatic or aromatic primary amino group, a hydroxyamino group, an alkoxyamino group, an acylamino group, or an aliphatic or aromatic sulfonamido group; G.sup.2 is a group substituted at the position adjacent to G and is a group represented by T.sup.2 --C(.dbd.T.sup.1)--; .dbd.T.sup.1 represents .dbd.O, .dbd.NH, .dbd.NOH, an alkoxyimino group, an aliphatic or aromatic imino group, an acylimino group, or an aliphatic or aromatic sulfonylimino group; T.sup.
    Type: Grant
    Filed: July 26, 1995
    Date of Patent: November 26, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yoshio Inagaki
  • Patent number: 5514533
    Abstract: A silver halide photographic photosensitive material comprises a silver halide photographic emulsion layer and a compound represented by general formula (I): ##STR1## wherein V.sub.1 and V.sub.2 each represents a hydrogen atom, an alkyl group or an alkoxy group; at least one of V.sub.1 and V.sub.2 is an alkyl group or an alkoxy group; Z.sub.1 represents a group of atoms which is required to form a five- or six-membered nitrogen-containing heterocyclic ring; Z.sub.2 represents a group of atoms which is required to form a five- or six-membered nitrogen-containing heterocyclic ring; Z.sub.3 represents an oxygen atom, a sulfur atom or a selenium atom; R.sub.1 and R.sub.3 each represents an alkyl group; R.sub.2 represents an alkyl group, an aryl group or a heterocyclic group; L.sub.1, L.sub.2 and L.sub.3 each represents a methine group; M.sub.1 represents a charge neutralizing counter-ion; and m.sub.1 is a number having a value zero or above which is required to neutralize the charge within the molecule.
    Type: Grant
    Filed: October 4, 1994
    Date of Patent: May 7, 1996
    Assignee: Fuji Photo Film Co., LTD.
    Inventors: Takanori Hioki, Tetsuo Yoshida
  • Patent number: 5491057
    Abstract: Disclosed is a silver halide emulsion having at least one methine compound of formula (I) (MET).sub.k1 --[(Q) --Ar].sub.k2, wherein MET represents an atomic group having a methine compound structure; Q represents a divalent linking group composed of atom(s) or atomic group(s) containing at least one carbon, nitrogen, sulfur or oxygen atom; Ar represents an aromatic group containing monocyclic compound(s) each composed of 5 or more atoms; k1 represents an integer of 1 or more; and k2 represents an integer of 2 or more. A photographic material containing the emulsion has high sensitivity and high storage stability.
    Type: Grant
    Filed: December 2, 1994
    Date of Patent: February 13, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Takanori Hioki
  • Patent number: 5478719
    Abstract: The present invention provides a high sensitivity silver halide photographic material which minimizes the formation of fog and exhibits a small sensitivity drop during storage. A silver halide photographic material is provided comprising a compound having a methine dye and a styryl base covalently connected to each other.
    Type: Grant
    Filed: September 15, 1994
    Date of Patent: December 26, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takanori Hioki, Hiroshi Kawakami
  • Patent number: 5348850
    Abstract: A silver halide photographic material has on a support at least one light-sensitive silver halide emulsion layer which comprises silver halide emulsion grains having a chloride content: of at least 50 mol % and containing a metal selected from rhodium, ruthenium and rhenium in an amount of at least 10.sup.-8 mole per mole of silver, said silver halide emulsion being spectrally sensitized with a compound of general formula (I) and being chemically sensitized with a selenium or tellurium compound: ##STR1## wherein Z and Z.sub.1 each represents a group of nonmetallic atoms necessary to complete a 5- or 6-membered nitrogen-containing heterocyclic nucleus; R and R.sub.1 each represents an unsubstituted or substituted alkyl group, or an unsubstituted aryl group; Q and Q.sub.1 each represents a group of atoms necessary to complete a 4-thiazolidinone, 5-thiazolidinone or 4-imidazolidinone nucleus; L, L.sub.1 and L.sub.2 each represents an unsubstituted or substituted methine group; n.sub.1 and n.sub.
    Type: Grant
    Filed: August 27, 1993
    Date of Patent: September 20, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Tetsuo Yoshida
  • Patent number: 5288738
    Abstract: A novel red-sensitizing dye compound has a structure which contains a pentamethine oxonol chromophore linked to one or two cyanine chromophores. A photographic element comprises a support upon which is coated a silver halide emulsion layer comprising cubic silver halide crystals and said red-sensitizing dye compound.
    Type: Grant
    Filed: April 8, 1992
    Date of Patent: February 22, 1994
    Assignee: Eastman Kodak Company
    Inventors: Lal C. Vishwakarma, Thomas R. Dobles
  • Patent number: 5234806
    Abstract: The present invention provides dyes markedly excellent as sensitizing dyes for silver halide photographic light-sensitive materials. Said dyes are represented by the following formula (I): ##STR1## wherein R.sub.1 and R.sub.2 may be identical or different and each represents an alkyl group, an aralkyl group, an alkenyl group or an aryl group, R.sub.3 represents a heterocyclic group, Z.sub.1 and Z.sub.2 may be identical or different and each represents a group of atoms necessary to form a 5- or 6-membered nitrogen-containing heterocyclic ring, X represents a counter ion, L.sub.1 to L.sub.5 each represents a methine group, and m and n each represents 0, 1 or 2.
    Type: Grant
    Filed: December 4, 1991
    Date of Patent: August 10, 1993
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Satoshi Kaneko, Akira Tanaka
  • Patent number: 5204236
    Abstract: The improved silver halide photographic material is provided which contains a compound of the general formula (I): ##STR1## wherein R.sub.1 and R.sub.2 each represents a hydrogen atom, an alkyl group, an aryl group, an alkenyl group or a heterocyclic group; Z.sub.1 and Z.sub.2 each represents a non-metallic atomic group necessary for forming a 5- to 7-membered ring; X.sub.1 and X.sub.2 each represents an oxygen atom, a sulfur atom or .dbd.N-R.sub.3 ; R.sub.3 is a hydrogen atom, an alkyl group, an aryl group, an alkenyl group, a heterocyclic group or --OR.sub.4 ; R.sub.4 represents a hydrogen atom, an alkyl group, an aryl group, an alkenyl group or a heterocyclic group; L.sub.1 to L.sub.5 each represents a methine group; and n.sub.1 and n.sub.2 each represents an integer of 0, 1 or 2.
    Type: Grant
    Filed: February 27, 1992
    Date of Patent: April 20, 1993
    Assignee: Konica Corporation
    Inventors: Yasuhiko Kawashima, Reiko Yamauchi
  • Patent number: 5032500
    Abstract: A process or the preparation of a silver halide photographic emulsion is provided which comprises the addition of at least one pendant type spectral sensitizing dye containing as a substituent a compound having the effect of inhibiting fog at any time after the formation of silver halide grains, but before the completion of the chemical ripening process. In a preferred embodiment, the addition of said pendant type spectral sensitizing dyes is effected at any time after the formation of silver halide grains, but before former one second of the total time of the chemical ripening process. The pendant type spectral sensitizing dyes are compounds represented by the general formula (III) or (IV): ##STR1## wherein SSD represents a sensitizing dye portion; AF represents a compound portion containing a saturated or unsaturated 5- to 7-membered ring containing at least one nitrogen atom; L.sup.1 represents a divalent connecting group containing at least one of C, N, S and O; L.sup.2 has the same meaning at L.sup.
    Type: Grant
    Filed: January 14, 1990
    Date of Patent: July 16, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tadashi Ikeda, Mitsuo Saitou, Yoshio Inagaki, Toshinao Ukai
  • Patent number: 4987064
    Abstract: A silver halide photographic material is disclosed, comprising a support having thereon an emulsion layer comprising a dispersion medium, silver halide grains, and a pendant type sensitizing dye, wherein said pendant type sensitizing dye is a compound comprising a sensitizing dye and an antifoggant, each of which may have substituent groups and wherein said sensitizing dye and antifoggant are organochemically bonded.
    Type: Grant
    Filed: December 8, 1989
    Date of Patent: January 22, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Mitsuo Saitou, Toshinao Ukai, Tadashi Ikeda
  • Patent number: 4933273
    Abstract: A photographic element and emulsion are described which comprise a negative working silver halide emulsion layer, a hydrazine compound nucleating agent and an electron accepting antifogging dye. Enhanced sensitometric properties are obtained. A process for developing such element or emulsion is also described.
    Type: Grant
    Filed: December 2, 1988
    Date of Patent: June 12, 1990
    Assignee: Eastman Kodak Company
    Inventors: Paul B. Gilman, Jr., Thaddeus D. Koszelak, Anthony Adin, Roland G. Willis
  • Patent number: 4283488
    Abstract: Photo-sensitive silver halide compositions and elements are spectrally sensitized with new mathine dyes having a trialkylsilylalkyl group attached to a nitrogen atom in a heterocyclic nucleus of the dye.
    Type: Grant
    Filed: August 22, 1980
    Date of Patent: August 11, 1981
    Assignee: Eastman Kodak Company
    Inventor: Earl J. VanLare