Cyanine Sensitizer Patents (Class 430/581)
  • Patent number: 7476495
    Abstract: A silver halide photosensitive material comprising at least one blue-sensitive layer, at least one green-sensitive layer and at least one red-sensitive layer on a transparent support, wherein a peak wavelength of spectral sensitivity of at least one of the green-sensitive layer is in the range of ?10 nm or more and +10 nm or less in comparison with a peak wavelength of a green light source for exposure.
    Type: Grant
    Filed: September 27, 2007
    Date of Patent: January 13, 2009
    Assignee: Fujifilm Corporation
    Inventors: Tetsuo Kikuchi, Yoichi Hosoya, Masaaki Miki, Junichiro Hosokawa, Koichi Yokota, Ryoji Nishimura
  • Patent number: 7419774
    Abstract: Disclosed is a photothermographic material comprising a support having disposed on a surface thereof, a non-photosensitive silver source, a photosensitive silver halide, and a reducing agent, and having disposed another surface thereof at least one non-photosensitive layer, wherein at least one of the non-photosensitive layers contains at least one type of gelatin having an isoelectric point of from 5.0 to 9.5; and a method for processing the photothermographic material.
    Type: Grant
    Filed: December 23, 2002
    Date of Patent: September 2, 2008
    Assignee: FUJILFILM Corporation
    Inventor: Rikio Inoue
  • Patent number: 7402677
    Abstract: A TBET cassette including at least one xanthine- or pyronin-based compound as a donor or acceptor is disclosed. Also, a method of TBET cassette design in which four criteria may be used is provided. TBET cassettes may be used to label biological molecules, in clothing dyes, and in cosmetics.
    Type: Grant
    Filed: June 25, 2004
    Date of Patent: July 22, 2008
    Assignee: The Texas A&M University System
    Inventor: Kevin Burgess
  • Patent number: 7303851
    Abstract: Disclosed is a silver halide photographic light-sensitive material wherein a silver halide emulsion layer and/or a hydrophilic colloid layer contains at least one hydrazine derivative, and a silver halide emulsion is spectrally sensitized with a particular dye, and which contains a benzotriazol compound. There is provided a silver halide photographic light-sensitive material that exhibits superior residual color property and can provide stable photographic performance even after a long term running with a reduced silver amount.
    Type: Grant
    Filed: September 29, 2003
    Date of Patent: December 4, 2007
    Assignee: Fujifilm Corporation
    Inventors: Mitsunori Hirano, Kunio Ishigaki, Tokuju Oikawa
  • Patent number: 7291449
    Abstract: Disclosed is a silver halide photographic material which comprises at least one methine dye represented by the following formula (I): wherein Y represents a furan ring or a pyrrole ring, and Y may further be condensed with other 5- or 6-membered carbocyclic ring or heterocyclic ring, or may have a substituent; the bond between two carbon atoms in which Y is condensed may be a single bond or a double bond; Z represents an atomic group necessary to form a 5- or 6-membered nitrogen-containing heterocyclic ring, and Z may further be condensed with other 5- or 6-membered carbocyclic ring or heterocyclic ring; R represents a substituted or unsubstituted alkyl group, aryl group, or heterocyclic group; D represents a group necessary to form a methine dye; L1 and L2 each represents a methine group; p represents 0 or 1; M represents a counter ion; and m represents a number of 0 or higher necessary to neutralize the charge in the molecule.
    Type: Grant
    Filed: August 17, 2001
    Date of Patent: November 6, 2007
    Assignee: Fujifilm Corporation
    Inventors: Tetsuo Nakamura, Takanori Hioki, Katsuhisa Ohzeki, Naoyuki Hanaki
  • Patent number: 7211373
    Abstract: A photothermographic material comprising a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent for a silver ion and a binder on one surface of a support, wherein a silver behenate-content of the non-photosensitive organic silver salt is 40 to 70 mol %, and the photothermographic material comprises a compound that can be one-electron-oxidized to provide a one-electron oxidation product, which further releases at least 1 electron, one of during and after a subsequent reaction.
    Type: Grant
    Filed: April 1, 2003
    Date of Patent: May 1, 2007
    Assignee: Fujifilm Corporation
    Inventors: Tomoyuki Ohzeki, Kohzaburoh Yamada
  • Patent number: 7172856
    Abstract: A silver halide photographic light-sensitive material having high sensitivity and having a desired spectral sensitivity distribution. A silver halide photographic light-sensitive material comprising at least one multichromophore dye compound having at least two dye chromophores connected by covalent bonding or coordinate bonding, at least two of the dye chromophores forming a dye chromophore group and the light absorption of the dye chromophore group differing from the sum of individual light absorptions of respective dye chromophores constituting said dye chromophore group.
    Type: Grant
    Filed: July 22, 2002
    Date of Patent: February 6, 2007
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takanori Hioki, Hiroo Takizawa, Katsuhiro Yamashita
  • Patent number: 7153644
    Abstract: A silver halide color photosensitive material, which has: at least each one layer of yellow-, magenta- and cyan-color-forming photosensitive silver halide emulsion layers on a reflective support, and at least one non-light-sensitive non-color-forming hydrophilic colloidal layer; wherein at least one of the photosensitive silver halide emulsion layers contains a silver halide emulsion containing 90 mol % or more of silver chloride, and a compound having a repetitive unit of formula (I) is contained: wherein R1 is —OR, —SR or —N—R(—R?), where R and R? are a hydrogen atom, or an alkyl, aryl, aralkyl, cycloalkyl or heterocyclic group, or R and R? may form a saturated carbon ring or a heterocycle; R2 and R3 are a hydrogen atom or an alkyl group; Y1 and Y2 are a polymethylene, arylene or cycloalkylene group; Z is —O—, —SO2— or —CH2—; and m is 0 or 1.
    Type: Grant
    Filed: May 11, 2004
    Date of Patent: December 26, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Akito Yokozawa, Tetsuo Nakamura, Katsuyuki Takada
  • Patent number: 7083906
    Abstract: A heat-developable photosensitive material having on a support at least one light-sensitive layer comprising an organic silver salt, a light-sensitive silver halide and a reducing agent and at least one light-insensitive layer, which comprises an antihalation dye causing no decoloration by heat and provides tone represented by an inequality L*?92 on the CIELAB space in a background after heat development.
    Type: Grant
    Filed: March 7, 2003
    Date of Patent: August 1, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keiichi Suzuki, Hideyasu Ishibashi
  • Patent number: 7052827
    Abstract: A silver halide photographic material including at least one methine dye represented by the following general formula (I) and at least one coupler represented by the following general formula (XX): wherein X1 and X2 each represents an oxygen atom, a sulfur atom, a selenium atom, a tellurium atom, or a nitrogen atom; Y1 represents a furan, pyrrole or thiophene ring which may be condensed with another 5- or 6-membered carbon ring or heterocycle or may have a substituent group; Y2 represents an atomic group necessary for forming a benzene ring or a 5- or 6-membered unsaturated heterocycle, which may be further condensed with another 5- or 6-membered carbon ring or heterocycle or may have a substituent group; a bond between two carbon atoms by which Y1 and Y2 are each condensed with the carbon ring or the heterocycle may be a single bond or a double bond; R1 and R2 each represents a substituted or unsubstituted alkyl, aryl or heterocyclic group; L1, L2 and L3 each represents a methine group; n1 represents 0 o
    Type: Grant
    Filed: August 27, 2004
    Date of Patent: May 30, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Tetsuo Nakamura
  • Patent number: 7022470
    Abstract: A photothermographic imaging material having high sensitivity and superior temporal storage stability. The photothermographic imaging material includes silver halide on at least one side of a support, and includes at least one kind of the compounds represented by the following general formula (1).
    Type: Grant
    Filed: March 24, 2004
    Date of Patent: April 4, 2006
    Assignee: Konica Minolta Medical & Graphic, Inc.
    Inventors: Kiyoshi Fukusaka, Kazuaki Nakamura, Ryouhei Iwamoto, Norio Miura, Nobuaki Kagawa, Soc Man Ho Kimura
  • Patent number: 6979529
    Abstract: A silver halide photographic light-sensitive material is disclosed, comprising a support having thereon at least on light-sensitive halide emulsion layer, wherein the emulsion layer contains a compound represented by formula (1).
    Type: Grant
    Filed: April 26, 2001
    Date of Patent: December 27, 2005
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takashi Katoh, Hiroo Takizawa
  • Patent number: 6908730
    Abstract: This invention relates to a silver halide photographic material comprising at least one silver halide emulsion comprising silver halide grains having associated therewith: (a) a first dye (Dye 1) that is a cyanine dye capable of spectrally sensitizing a silver halide emulsion and that has at least one anionic substituent; and (b) a second dye (Dye 2) that is not a cyanine dye and that has at least one cationic substituent. Dye 2 has a log P, excluding any counterion, of less than 4.00 and greater than 1.00 or Dye 2 is represented by a dye of formula II as described herein.
    Type: Grant
    Filed: January 17, 2003
    Date of Patent: June 21, 2005
    Assignee: Eastman Kodak Company
    Inventors: Richard L. Parton, Thomas L. Penner, David R. Foster, Stephen A. Hershey
  • Patent number: 6844146
    Abstract: A silver halide color photosensitive material has at least one blue-sensitive silver halide emulsion layer containing a yellow coupler, at least one green-sensitive silver halide emulsion layer containing a magenta coupler, at least one red-sensitive silver halide emulsion layer containing a cyan coupler, and at least one non-lightsensitive layer, on a support. The photosensitive material contains, in at least one of the layers, a compound having a reducing group and a compound having at least three hetero atoms capable of increasing a photographic speed of the photosensitive material in comparison with the case where the material does not contain the same.
    Type: Grant
    Filed: November 19, 2002
    Date of Patent: January 18, 2005
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Junichiro Hosokawa, Kohzaburoh Yamada, Yasuhiro Shimada
  • Patent number: 6838231
    Abstract: A process for producing a spectrally sensitized silver halide photographic emulsion having high sensitivity. A process for producing a silver halide photographic emulsion comprising as a sensitizing dye at least one connection dye having two or more chromophores connected through a covalent bond, the process comprising adding said connection dye to a silver halide photographic emulsion and allowing at least one chromophore out of a plurality of chromophores in the molecule of the connection dye to change in the adsorption strength to a silver halide grain; and a process for producing a silver halide photographic emulsion comprising a silver halide grain having adsorbed on the surface thereof a sensitizing dye in multiple layers, the process comprising adding one or a plural of sensitizing dye(s) to said silver halide emulsion and allowing at least one sensitizing dye out of added sensitizing dyes to change in the adsorption strength to a silver halide grain.
    Type: Grant
    Filed: October 15, 2002
    Date of Patent: January 4, 2005
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Katsumi Kobayashi, Takeshi Suzumoto, Takanori Hioki
  • Patent number: 6828087
    Abstract: A silver halide photographic material comprising at least one methine dye of formula (I) and at least one coupler of formula (X): wherein X1 and X2 each represents O, S, Se, Te, N or C; Y1 represents a furan, pyrrole or thiophene ring which may be condensed and substituted with the specific ring; Y2 represents an atomic group necessary for forming a benzene ring or a 5- or 6-membered unsaturated heterocycle; R1 and R2 each represents a substituted or unsubstituted alkyl, aryl or heterocyclic group; L1, L2 and L3 each represents a methine group; n1 represents 0 or 1; M1 represents a counter ion; and m1 represents a number of 0 or more necessary for neutralizing a charge in a molecule; wherein Z1 and Z2 each represents —C(Q3)═ or —N═; Q1 and Q3 each represents a hydrogen atom or a monovalent substituent group; Q2 represents a hydrogen atom or a coupling release group.
    Type: Grant
    Filed: September 23, 2002
    Date of Patent: December 7, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Tetsuo Nakamura
  • Patent number: 6828088
    Abstract: Disclosed is a silver halide photographic light-sensitive material comprising at least one silver halide emulsion layer on a support, wherein 40 mol % or more of silver halide contained in the silver halide emulsion layer is silver bromide and the silver halide contains 1×10−6 mole or more per mole of silver of a metal complex containing one or more cyanide ligands, and the silver halide photographic light-sensitive material has a characteristic curve drawn in orthogonal coordinates of logarithm of light exposure (x-axis) and optical density (y-axis) using equal unit lengths for the both axes, on which gamma is 4.0 or more for the optical density range of 0.1-1.5. There is provided a silver halide photographic light-sensitive material showing high contrast and high sensitivity.
    Type: Grant
    Filed: November 26, 2002
    Date of Patent: December 7, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Tokuju Oikawa
  • Patent number: 6821719
    Abstract: A process for producing a deformed image comprising the steps of: digitally exposing a color photographic silver halide material, said color photographic silver halide material comprising on a deformable plastic support at least one blue-sensitive silver halide emulsion layer containing at least one yellow coupler, at least one green-sensitive silver halide emulsion layer containing at least one magenta coupler and at least one red-sensitive silver halide emulsion layer containing at least one cyan coupler; conventionally processing said exposed color photographic material to produce an image; and deforming said color photographic material.
    Type: Grant
    Filed: November 14, 2003
    Date of Patent: November 23, 2004
    Assignee: AGFA-Gevaert
    Inventors: Ly Cuong, Markus Geiger, Leon Vermeulen, Arno Schmuck
  • Patent number: 6818390
    Abstract: A deformable color photographic silver halide material, said color photographic silver halide material comprising on a deformable plastic support at least one blue-sensitive silver halide emulsion layer containing at least one yellow coupler, at least one green-sensitive silver halide emulsion layer containing at least one magenta coupler and at least one red-sensitive silver halide emulsion layer containing at least one cyan coupler can be deformed without loss in image quality and is suitable for large formats and automatic processing.
    Type: Grant
    Filed: November 14, 2003
    Date of Patent: November 16, 2004
    Assignee: AGFA-Gevaert
    Inventors: Ly Cuong, Markus Geiger, Leon Vermeulen, Arno Schmuck
  • Patent number: 6815153
    Abstract: This invention relates to a silver halide photographic element comprising a support bearing a cyan dye image-forming unit comprised of at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, and a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein said photographic element has an ISO speed rating of 800 or greater and has an integrated RMS green granularity equal to or less than 11.2.
    Type: Grant
    Filed: January 17, 2003
    Date of Patent: November 9, 2004
    Assignee: Eastman Kodak Company
    Inventors: James A. Friday, Roger A. Weiss, Anabisdally I. Bodden
  • Patent number: 6811963
    Abstract: This invention relates to a silver halide photographic element comprising a support bearing a cyan dye image-forming unit comprised of at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, and a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of the dye image forming units contains layers of differing sensitivities, and the layer of highest sensitivity contains a development promoting agent or a specific coupler as described herein, or a combination thereof, and a silver halide emulsion comprising tabular silver halide grains having associated therewith at least two dye layers comprising (a) an inner dye layer adjacent to the silver ha
    Type: Grant
    Filed: January 17, 2003
    Date of Patent: November 2, 2004
    Assignee: Eastman Kodak Company
    Inventors: Sharon G. Johnston, Stephen P. Singer, Drake M. Michno, James A. Friday, David R. Foster
  • Patent number: 6806043
    Abstract: A silver halide photographic light-sensitive material is disclosed, comprising a support having thereon at least one light-sensitive silver halide emulsion layer, wherein said emulsion layer contains a compound represented by the following formula (1): Dye1&Parenopenst;L1&Parenopenst;Dye2)m1)m2  (1) wherein Dye1 represents a cyanine chromophore, Dye2 represents a merocyanine dye having in the acid nucleus thereof at least one dissociative group having a pKa of 5 or less, and L1 represents a linking group represented by -G1-(A1-G2)t1-(wherein G1 and G2 each independently represents an alkylene, alkenylene or arylene group which may be substituted, A1 represents, irrespective of the direction, —O—, —S—, —SO2—, —NR3—, —COO—, —CONR4— or —SO2NR5— (wherein R3 to R5 each independently represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group or a heterocyclic group) and t1 represents an integer of 1 to 1
    Type: Grant
    Filed: March 22, 2002
    Date of Patent: October 19, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Hiroo Takizawa
  • Patent number: 6794121
    Abstract: This invention relates to a method of spectrally sensitizing a silver halide emulsion comprising the following steps in the following order a) providing a silver halide emulsion comprising tabular silver halide grains having an inner dye layer adjacent to the silver halide grain, said dye layer comprising at least one dye (Dye 1) that is capable of spectrally sensitizing silver halide, b) adding to the emulsion at least one dye (Dye 2) capable of providing a second dye layer adjacent to the inner dye layer, and c) adding to the emulsion a non-cationic surfactant or a scavenger for oxidized developer, or a combination of the two, to form a silver halide emulsion comprising silver halide grains having associated therewith two dye layers, wherein the dye layers are held together by non-covalent forces or by in situ bond formation; the outer dye layer adsorbs light at equal or higher energy than the inner dye layer; and the energy emission wavelength of the outer dye layer overlaps with the energy absorption
    Type: Grant
    Filed: January 17, 2003
    Date of Patent: September 21, 2004
    Assignee: Eastman Kodak Company
    Inventors: David R. Foster, Stephen P. Singer, William J. Harrison, Alan R. Pitt
  • Patent number: 6794122
    Abstract: A silver halide photographic material comprising a support having thereon at least one silver halide photographic emulsion layer, wherein the emulsion layer contains at least one compound of formulae (Ia), (Ib) and (Ic) and at least one compound of formula (II): wherein Z1 represents S, O, Se, Te, N or C; R, R31 and R32 each are an alkyl, aryl or heterocyclic group; D is a group necessary for forming a methine dye; V1 to V4 represent H or a monovalent substituent; M and M3 each are a charge-balancing counter ion; m and m3 each are a number or 0 or more necessary for neutralizing the charge of the molecule; Z31 and Z32 each are an atomic group necessary for forming the nitrogen-containing hetero-ring; L31 to L37 each represent a methine group; p31 and p32 each are 0 or 1; n3 is 0, 1, 2, 3 or 4, but the compound of formula (II) does not include the compounds of formulae (Ia), (Ib) and (Ic).
    Type: Grant
    Filed: December 4, 2002
    Date of Patent: September 21, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takanori Hioki, Tetsuo Nakamura
  • Patent number: 6787297
    Abstract: This invention provides a silver halide photographic element comprising at least one silver halide emulsion comprising silver halide grains which have associated therewith at least an inner dye layer and an outer dye layer wherein the outer dye layer comprises a dye having at least one substituent that has a positive charge, said photographic element further comprising a cyanine dye of formula (I) or (II) (as described in the specification) that is capable of spectrally sensitizing a silver halide emulsion.
    Type: Grant
    Filed: May 12, 2003
    Date of Patent: September 7, 2004
    Assignee: Eastman Kodak Company
    Inventors: Steven G. Link, Richard L. Parton, Robert D. Wilson, Roger A. Bryant, William J. Harrison
  • Patent number: 6780577
    Abstract: A silver halide photographic material containing silver halide grains onto which a sensitizing dye in the first layer and a sensitizing dye or dyes in the second or after layers are multilayer-adsorbed, wherein the fluorescence life time of the dye or dyes in the second or after layers on the silver halide grain surface measured at a maximum wavelength of fluorescence spectrum is shorter than the fluorescence life time of the dye or dyes in a gelatin dry film measured at a maximum wavelength of fluorescence spectrum when the sensitizing dyes are multilayer-adsorbed onto the silver halide grain surface.
    Type: Grant
    Filed: October 9, 2002
    Date of Patent: August 24, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Hideo Furuuchi
  • Patent number: 6770433
    Abstract: A high-sensitive silver halide photographic light-sensitive material is provided. A silver halide photographic light-sensitive material comprising a dye having a plurality of dye chromophores, which contains at least one dye where at least one of the dye chromophores is a methine dye chromophore containing a basic nucleus comprising a monocyclic heterocyclic ring.
    Type: Grant
    Filed: January 11, 2002
    Date of Patent: August 3, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Takanori Hioki
  • Publication number: 20040142288
    Abstract: This invention relates to a silver halide photographic element comprising a support bearing a cyan dye image-forming unit comprised of at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, and a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein said photographic element has an ISO speed rating of 800 or greater and has an integrated RMS green granularity equal to or less than 11.2.
    Type: Application
    Filed: January 17, 2003
    Publication date: July 22, 2004
    Inventors: James A. Friday, Roger A. Weiss, Anabisdally I. Bodden
  • Patent number: 6759186
    Abstract: A silver halide photographic material is disclosed, comprising at least one silver halide emulsion layer provided on a support, the emulsion layer comprising a silver halide emulsion containing at least two sensitizing dyes represented by the following general formula (I): wherein X represents an oxygen atom, sulfur atom, selenium atom or NR′; R and R′ each represent a substituted or unsubstituted alkyl, aryl or heterocyclic group; D represents a group required to form a methine dye; M represents a counter ion; and m represents a number of not smaller than 0 required to neutralize the electric charge in the molecule.
    Type: Grant
    Filed: January 30, 2002
    Date of Patent: July 6, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tetsuo Nakamura, Kimiyasu Morimura, Takanori Hioki
  • Publication number: 20040126721
    Abstract: Disclosed is a silver halide photographic light-sensitive material wherein a silver halide emulsion layer and/or a hydrophilic colloid layer contains at least one hydrazine derivative, and a silver halide emulsion is spectrally sensitized with a particular dye, and which contains a benzotriazol compound. There is provided a silver halide photographic light-sensitive material that exhibits superior residual color property and can provide stable photographic performance even after a long term running with a reduced silver amount.
    Type: Application
    Filed: September 29, 2003
    Publication date: July 1, 2004
    Inventors: Mitsunori Hirano, Kunio Ishigaki, Tokuju Oikawa
  • Publication number: 20040115570
    Abstract: An image-forming method comprising:
    Type: Application
    Filed: December 27, 2002
    Publication date: June 17, 2004
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventors: Akito Yokozawa, Tatsuya Ishizaka, Katsuyuki Takada, Yoshiro Ochiai, Tetsuo Nakamura
  • Patent number: 6750002
    Abstract: A process for preparing a concentrated photographic spectral sensitizing dye-water composition which comprises adding an anionic sensitizing dye to an aqueous medium in the substantial absence of organic solvent, and agitating the combined dye and aqueous medium, wherein the anionic dye forms a liquid-crystalline dye phase in the aqueous medium and the agitation is performed in the presence of a nonionic surfactant having an HLB of less than 12 and an aqueous solubility at 25° C. of greater than 10 ppm, which nonionic surfactant is in the aqueous medium at a level of from 10 to 1000 ppm. In a specific embodiment of the invention, where the viscosity (at 0.1 s−1 shear rate) of the dye-water composition in the absence of the nonionic surfactant would be greater than 100 cp and especially where such viscosity would be greater than 500 cp, the surfactant is preferably present at a level sufficient to substantially reduce air entrainment during agitation of the dye-water composition.
    Type: Grant
    Filed: January 28, 2002
    Date of Patent: June 15, 2004
    Assignee: Eastman Kodak Company
    Inventors: James E. Novak, Jeffrey S. Baugher, Dirk J. Hasberg, Lloyd A. Lobo
  • Publication number: 20040106075
    Abstract: A process for producing a deformed image comprising the steps of: digitally exposing a colour photographic silver halide material, said colour photographic silver halide material comprising on a deformable plastic support at least one blue-sensitive silver halide emulsion layer containing at least one yellow coupler, at least one green-sensitive silver halide emulsion layer containing at least one magenta coupler and at least one red-sensitive silver halide emulsion layer containing at least one cyan coupler; conventionally processing said exposed colour photographic material to produce an image; and deforming said colour photographic material.
    Type: Application
    Filed: November 14, 2003
    Publication date: June 3, 2004
    Applicant: Agfa-Gevaert
    Inventors: Ly Cuong, Markus Geiger, Leon Vermeulen, Arno Schmuck
  • Publication number: 20040106076
    Abstract: A deformable colour photographic silver halide material, said colour photographic silver halide material comprising on a deformable plastic support at least one blue-sensitive silver halide emulsion layer containing at least one yellow coupler, at least one green-sensitive silver halide emulsion layer containing at least one magenta coupler and at least one red-sensitive silver halide emulsion layer containing at least one cyan coupler can be deformed without loss in image quality and is suitable for large formats and automatic processing.
    Type: Application
    Filed: November 14, 2003
    Publication date: June 3, 2004
    Applicant: Agfa-Gevaert
    Inventors: Ly Cuong, Markus Geiger, Leon Vermeulen, Arno Schmuck
  • Patent number: 6720134
    Abstract: A silver halide photographic emulsion comprising grains, wherein 70% or more of the total projected area of the grains is occupied by silver halide grains each meeting requirements (a) to (d) below (a) the grain is composed of a tabular silver halide host grain having two mutually parallel main planes and aspect ratio of 2 or more, and a silver halide protrusion portion epitaxially junctioned on the surface of the host grain; (b) the silver bromide contents of both the host grain and the protrusion portion are 70 mol % or more; (c) the percentage of the silver amount in the protrusion is 12% or less of the silver amount in the host grain; and (d) the grain has a shallow electron-trapping zone.
    Type: Grant
    Filed: January 14, 2002
    Date of Patent: April 13, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yasushi Miyamoto, Toshihiro Nishikawa, Nobuyuki Haraguchi, Hideo Ikeda, Takayoshi Mori
  • Patent number: 6716994
    Abstract: The present invention provides a novel class of fluorescent cyanine dye compounds that are modified at one of the hetercyclic ring nitrogen atoms with a mobility-modifying moiety that permits the electrophoretic mobilities of polynucleotides labeled with the mobility-modifying cyanine dyes to be adjusted or tuned in a predictable fashion while retaining enzymatic activity. The ability to predictably tune the relative electrophoretic mobilities of the dyes permits the creation of sets of mobility-matched fluorescent dyes of a variety of structures for a variety of applications, including fluorescence-based 4-color nucleic acid sequencing reactions.
    Type: Grant
    Filed: January 4, 2000
    Date of Patent: April 6, 2004
    Assignee: Applera Corporation
    Inventors: Steven M. Menchen, Scott C. Benson, Barnett B. Rosenblum, Shaheer H. Khan
  • Patent number: 6699652
    Abstract: This invention relates to a silver halide photographic element comprising a support bearing a cyan dye image-forming unit comprised of at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, and a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of the dye image forming units contains layers of differing sensitivities, and the layer of highest sensitivity contains a development promoting agent or a specific coupler as described herein, or a combination thereof, and a silver halide emulsion comprising tabular silver halide grains having associated therewith at least two dye layers comprising (a) an inner dye layer adjacent to the silver ha
    Type: Grant
    Filed: January 17, 2003
    Date of Patent: March 2, 2004
    Assignee: Eastman Kodak Company
    Inventors: Sharon G. Johnston, Stephen P. Singer, Drake M. Michno, James A. Friday, David R. Foster
  • Patent number: 6689554
    Abstract: A silver halide emulsion comprises an electron-releasing compound of Types 1 to 4: (Type 1) a compound capable of undergoing a one-electron oxidation (1-EO) to form a one-electron oxidation product (1-EOP), the 1-EOP capable of releasing further two or more electrons accompanying a subsequent bond cleavage reaction, (Type 2) a compound capable of undergoing 1-EO to form 1-EOP, the 1-EOP capable of releasing further one electron accompanying a subsequent bond cleavage reaction, and having, in its molecule, two or more adsorptive groups acting on silver halides, (Type 3) a compound capable of undergoing 1-EO to thereby form 1-EOP, the 1-EOP capable of releasing further one or more electrons after going through a subsequent bond forming process, and (Type 4) a compound capable of undergoing 1-EO to form 1-EOP, the 1-EOP capable of releasing further one or more electrons after going through a subsequent intramolecular ring cleavage reaction.
    Type: Grant
    Filed: July 30, 2002
    Date of Patent: February 10, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kohzaburoh Yamada, Masahiko Taniguchi, Naoki Asanuma, Takashi Hoshimiya, Hirokazu Kyota, Masafumi Mizuno
  • Patent number: 6689552
    Abstract: A color photographic silver halide material which can be developed to form a negative, at least 95 mol % of the silver halides of which consist of AgCl, and which contains at least one light-sensitive silver halide emulsion layer, the silver halide of which contains at least one compound of formulae (I), (II) and (III): [IrClnF6-n]2−M2+  (I) wherein n denotes 0 or an integer from 1 to 6 and M2+ denotes 1 or 2 cations with a total number of 2 positive charges, [Fe(CN)6]m−Mm+  (II) wherein m denotes 2 or 3 and Mm+ denotes 1 to 3 cations with a total number of m positive charges, wherein o denotes 0, 1 or 2 and R denotes an alkyl, aryl or aralkyl, is distinguished under scanning exposure and on analogue exposure by sharp contrast which is independent of exposure time and by a stable latent image.
    Type: Grant
    Filed: November 5, 2001
    Date of Patent: February 10, 2004
    Assignee: Agfa-Gevaert
    Inventors: Cuong Ly, Edgar Draber, Matthias Feigl, Günter Helling, Thomas Kaluschke, Michael Missfeldt, Maria Nietgen, Heinz-Horst Teitscheid, Ralf Weimann, Heinz Wiesen
  • Patent number: 6689547
    Abstract: A photothermographic material that comprises a support having thereon one or more thermally-developable imaging layers comprising a binder and in reactive association, a photosensitive silver halide, a non-photosensitive source of reducible silver ions, and a reducing composition for the non-photosensitive source reducible silver ions. The thermally-developable layers further comprises one or more radiation absorbing compounds that provide a total absorbance of greater than 0.6 and up to and including 3 in the thermally-developable imaging layer(s). These photothermographic materials exhibit reduced mottle without significant loss in sensitivity.
    Type: Grant
    Filed: December 5, 2001
    Date of Patent: February 10, 2004
    Assignee: Eastman Kodak Company
    Inventors: Bryan V. Hunt, Steven H. Kong, William D. Ramsden, Gary E. Labelle
  • Patent number: 6686142
    Abstract: A chemically and spectrally-sensitized emulsion has been described, wherein said emulsion comprising (100) cubic silver halide grains with an average edge length of from 0.2 up to 1.5 &mgr;m, has been spectrally sensitized by addition at least three trimethine dyes: a main spectral sensitizer added in an amount of at least 85 mole % of all spectral sensitizers added, followed by adding a second spectral sensitizer in an amount of not more than 10 mole % and a third spectral sensitizer in an amount of at most 1 mole % wherein at least said main spectral sensitizer has two benzoxazole rings in its chemical structure, at least said third spectral sensitizer has two benzimidazole rings in its chemical structure and wherein the said second spectral sensitizer has a structure more sterically hindered than the structure of the other spectral sensitizers. A light-sensitive silver halide photographic film material coated with such emulsion and a radiographic screen/film combination has been described.
    Type: Grant
    Filed: March 4, 2002
    Date of Patent: February 3, 2004
    Assignee: Agfa-Gevaert
    Inventors: Kathy Elst, Paul Callant
  • Publication number: 20030228549
    Abstract: To provide a silver halide photographic light-sensitive material having high sensitivity and having a desired spectral sensitivity distribution.
    Type: Application
    Filed: July 22, 2002
    Publication date: December 11, 2003
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventors: Takanori Hioki, Hiroo Takizawa, Katsuhiro Yamashita
  • Publication number: 20030224304
    Abstract: A silver halide color reversal photographic lightsensitive material comprising a support and, superimposed thereon, at least one red-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer and at least one blue-sensitive silver halide emulsion layer, the red-sensitive silver halide emulsion layer having a weight-averaged wavelength (&lgr;ra) of spectral sensitivity distribution satisfying the relationship: 600 nm<&lgr;ra<625 nm, which silver halide color reversal photographic lightsensitive material contains at least one interimage effect intensifying layer substantially not forming any image, the interimage effect intensifying layer containing:
    Type: Application
    Filed: February 20, 2003
    Publication date: December 4, 2003
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventor: Yutaka Maeno
  • Patent number: 6649336
    Abstract: A silver halide photographic light-sensitive material is disclosed, including at least one silver halide emulsion layer, wherein the silver halide grain contained in the emulsion layer is silver chloroiodide or silver chloroiodobromide having a silver chloride content of 90 mol % or more and a silver iodide content of 0.01 to 1.0 mol %, at least one hexacyano complex is doped in an amount of at least 1×10−7 mol % based on the total silver amount, and the emulsion layer contains a methine dye represented by the formula (I) as defined.
    Type: Grant
    Filed: September 25, 2001
    Date of Patent: November 18, 2003
    Assignee: Fuji Photo Film Co., LTD
    Inventors: Katsuhisa Ohzeki, Tetsuo Nakamura
  • Patent number: 6649335
    Abstract: A cyanine dye of formula (II) wherein X1 is C(R5, R6), NR7, O, S or Se, X2 is O, S, Se or NR13, R2 with R3, or R3 with R4, are the remaining members for the completion of a condensed furano ring system, and the other R2 or R4 radical, is H, a halogen, SH, CN, CF3, alkyl, aryl, heterocyclyl, alkoxy, aryloxy, alkylthio or arylthio, R10 to R12, are H, a halogen, SH, CN, CF3, alkyl, aryl, heterocyclyl, alkoxy, aryloxy, alkylthio or arylthio, or R10 with R11, or R11 with R12, are the remaining members for the completion of a ring system, R5 to R7 and R13 are alkyl, alkylene-SO3Z1 or alkylene-CO2Z1, R8 and R9 are alkyl, alkylene-SO3Z1, alkylene-CO2Z1 or alkylene-Y2—N(Z1)—Y3-alkyl, Z1 is H or a negative charge, Y2 and Y3 are —S(═O)2— or —C(═O)—, M1 is a counterion, L1, L2 and L3 are a methine group and n is 0, 1, 2 or 3.
    Type: Grant
    Filed: November 5, 2001
    Date of Patent: November 18, 2003
    Assignee: AGFA-Gevaert
    Inventor: Michael Missfeldt
  • Patent number: 6632597
    Abstract: A compound represented by the following formula (1) and a silver halide photographic material containing the compound: wherein Dye 1 represents a first chromophore; Dye 2 represents a second chromophore; L1 represents a linking chain; R1 represents a dissociable group having pKa of 5 or less; m1 represents an integer of from 1 to 5; m2 represents an integer of from 1 to 5; and m3 represents an integer of from 1 to 4.
    Type: Grant
    Filed: August 31, 2001
    Date of Patent: October 14, 2003
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Hiroo Takizawa
  • Publication number: 20030175629
    Abstract: A process for preparing a concentrated photographic spectral sensitizing dye-water composition which comprises adding an anionic sensitizing dye to an aqueous medium in the substantial absence of organic solvent, and agitating the combined dye and aqueous medium, wherein the anionic dye forms a liquid-crystalline dye phase in the aqueous medium and the agitation is performed in the presence of a nonionic surfactant having an HLB of less than 12 and an aqueous solubility at 25° C. of greater than 10 ppm, which nonionic surfactant is in the aqueous medium at a level of from 10 to 1000 ppm. In a specific embodiment of the invention, where the viscosity (at 0.1 s−1 shear rate) of the dye-water composition in the absence of the nonionic surfactant would be greater than 100 cp and especially where such viscosity would be greater than 500 cp, the surfactant is preferably present at a level sufficient to substantially reduce air entrainment during agitation of the dye-water composition.
    Type: Application
    Filed: January 28, 2002
    Publication date: September 18, 2003
    Applicant: Eastman Kodak Company
    Inventors: James E. Novak, Jeffrey S. Baugher, Dirk J. Hasberg, Lloyd A. Lobo
  • Patent number: 6620581
    Abstract: This invention comprises a silver halide photographic material comprising at least one silver halide emulsion comprising silver halide grains having associated therewith at least two dyes: (a) a first dye that has at least one anionic substituent and that is capable of spectrally sensitizing a silver halide emulsion; and (b) a second dye that absorbs light at an equal or shorter wavelength than the first dye and that has at least one cationic substituent and that is highly fluorescent.
    Type: Grant
    Filed: October 16, 2000
    Date of Patent: September 16, 2003
    Assignee: Eastman Kodak Company
    Inventors: Richard L. Parton, Joseph C. Deaton, William J. Harrison, Margaret J. Helber
  • Patent number: 6611367
    Abstract: A surface plasmon optical modulator element includes a dielectric material block disposed so that light-to-be-modulated travels through the interior of the dielectric material block and impinges upon one surface thereof at an angle of total reflection, a metal film formed on the surface of the dielectric material block, a photo-functional film which is formed on the metal film and whose refractive index is changed upon exposure to light, and a modulating light source which projects modulating light onto the photo-functional film. The photo-functional film is formed of dye which contains an electron donor and an electron acceptor so that a photoelectron can be transferred therebetween.
    Type: Grant
    Filed: February 7, 2000
    Date of Patent: August 26, 2003
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masayuki Naya, Yoshio Inagaki, Yoshihisa Usami
  • Publication number: 20030157447
    Abstract: A silver halide photographic light-sensitive emulsion comprising a silver halide and a compound represented by the following Formula (I): 1
    Type: Application
    Filed: July 19, 2002
    Publication date: August 21, 2003
    Inventors: Tatsuo Tanaka, Nobuaki Kagawa, Yoshiko Iwai, Tomohiro Oshiyama