One Or Both Methine Linked Rings Carbocyclic Patents (Class 430/594)
  • Patent number: 8460858
    Abstract: A near-infrared-ray absorbing material containing a cyanine compound per formula (I) exhibits a sharp light absorption in wavelength range 800-1000 nm, with excellent light resistance. R1 - R4, Y1, Y2 represents hydrogen atom, a group of formula (II) or (II?), etc., and Anq? represents a q-valent anion, provided that at least R1 is a group of formula (II) or (II?) or Anq? is an ion of formula (III); R11 - R13 each represents a hydrogen atom, hydroxyl group, etc.; Z1, Z2 represents a C1-10 alkyl group, etc. In formula (II?), the bond between G? and T? is a double bond or a conjugated double bond; G? represents a carbon atom; T? represents a carbon atom or a nitrogen atom; the ring including G? and T? represents a 6-membered ring, etc.; w? is 0-4; and R01? represents a hydrogen atom, hydroxy, etc. In formula (III), R5 and R6 represents a halogen-substituted C1-8 alkyl group.
    Type: Grant
    Filed: November 18, 2009
    Date of Patent: June 11, 2013
    Assignee: Adeka Corporation
    Inventors: Yosuke Maeda, Ryoya Otsuki, Koichi Shigeno
  • Patent number: 7291449
    Abstract: Disclosed is a silver halide photographic material which comprises at least one methine dye represented by the following formula (I): wherein Y represents a furan ring or a pyrrole ring, and Y may further be condensed with other 5- or 6-membered carbocyclic ring or heterocyclic ring, or may have a substituent; the bond between two carbon atoms in which Y is condensed may be a single bond or a double bond; Z represents an atomic group necessary to form a 5- or 6-membered nitrogen-containing heterocyclic ring, and Z may further be condensed with other 5- or 6-membered carbocyclic ring or heterocyclic ring; R represents a substituted or unsubstituted alkyl group, aryl group, or heterocyclic group; D represents a group necessary to form a methine dye; L1 and L2 each represents a methine group; p represents 0 or 1; M represents a counter ion; and m represents a number of 0 or higher necessary to neutralize the charge in the molecule.
    Type: Grant
    Filed: August 17, 2001
    Date of Patent: November 6, 2007
    Assignee: Fujifilm Corporation
    Inventors: Tetsuo Nakamura, Takanori Hioki, Katsuhisa Ohzeki, Naoyuki Hanaki
  • Patent number: 7172856
    Abstract: A silver halide photographic light-sensitive material having high sensitivity and having a desired spectral sensitivity distribution. A silver halide photographic light-sensitive material comprising at least one multichromophore dye compound having at least two dye chromophores connected by covalent bonding or coordinate bonding, at least two of the dye chromophores forming a dye chromophore group and the light absorption of the dye chromophore group differing from the sum of individual light absorptions of respective dye chromophores constituting said dye chromophore group.
    Type: Grant
    Filed: July 22, 2002
    Date of Patent: February 6, 2007
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takanori Hioki, Hiroo Takizawa, Katsuhiro Yamashita
  • Patent number: 6649337
    Abstract: A heat-developable photosensitive material comprises: a support; a photosensitive silver halide; a non-photosensitive organic silver salt; a reducing agent for a silver ion; a binder; and a compound having specified structure.
    Type: Grant
    Filed: November 15, 2001
    Date of Patent: November 18, 2003
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takanori Hioki, Katsumi Kobayashi
  • Publication number: 20030091943
    Abstract: A black-and-white photothermographic material that is sensitive at a wavelength greater than 700 nm, and comprises a support having thereon one or more thermally-developable imaging layers comprising a binder and in reactive association, a photosensitive silver halide, a non-photosensitive source of reducible silver ions, and a reducing composition for the non-photosensitive source reducible silver ions. The thermally-developable layers further comprises one or more indolenine dyes as post-processing stabilizing compounds and one or more merocyanine dyes or cyanine spectral sensitizing dyes that comprise one or more thioalkyl, thioaryl, or thioether groups.
    Type: Application
    Filed: June 29, 2001
    Publication date: May 15, 2003
    Applicant: Eastman Kodak Company
    Inventors: Steven H. Kong, Bryan V. Hunt, Wiliam D. Ramsden
  • Patent number: 6365335
    Abstract: A Silver halide photographic material high in sensitivity and decreased in residual color is disclosed, which comprises at least one compound represented by the following formula (I): wherein Z1 represents an oxygen atom, a sulfur atom, a selenium atom, a tellurium atom, a carbon atom or a nitrogen atom; Q represents a group necessary for forming a methine dye; M1 represents a charge equilibrium counter ion; m1 represents the number necessary for neutralizing a charge of the molecule; Vp represents a group having a log P value lower than that of Cl; q1 represents 1, 2, 3 or 4; and R1 is represented by following: R1=(La)k1CONHSO2R11, R1=(Lb)k2SO2NHCOR12, R1=(Lc)k3CONHCOR13, R1=(Ld)k4SO2NHSO2R14 wherein R11, R12, R13 and R14 each represents an alkyl group, an aryl group, a heterocyclic group, an alkoxyl group, an aryloxy group, a heterocyclyloxy group or an amino group; La, Lb, Lc and Ld each represents a methylene group; and k1, k2, k3 a nd k4 each represents a
    Type: Grant
    Filed: August 13, 1999
    Date of Patent: April 2, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takanori Hioki, Kiyoshi Morimoto
  • Patent number: 6333146
    Abstract: Disclosed is a compound represented by the following formula (I): wherein Z1 represents an atomic group necessary to form a 5- or 6-membered nitrogen-containing heterocyclic ring; Z2 represents an atomic group necessary to form a 5- or 6-membered heterocyclic ring, Z2 may further be substituted, or may be condensed with a hetero ring or a benzene ring; R1 represents a hydrogen atom, a halogen atom, a mercapto group, an alkyl group, an alkenyl group, an aryl group, an alkylthio group, an alkenylthio group, or an arylthio group; L1 and L2 each represents a methine group; p1 represents 0 or 1; V1 represents a substituent; and n represents 0, 1 or 2, and when n represents 2, a plurality of V1 may be the same or different.
    Type: Grant
    Filed: March 10, 2000
    Date of Patent: December 25, 2001
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Katsumi Kobayashi, Takashi Katoh, Junji Nishigaki
  • Patent number: 6329133
    Abstract: This invention comprises a silver halide photographic material comprising at least one silver halide emulsion comprising silver halide grains having associated therewith a combination of two or more dyes wherein (b) (a) a dye having at least one substituent that has a negative charge is present, a dye having at least one substituent that has a positive charge is present, wherein at least one of the dyes is further substituted with at least one hydrogen bonding donor substituent. In a preferred embodiment, at least one of the dyes is substituted with at least two hydrogen bonding donor substituents. In another preferred embodiment a silver halide photographic material comprises at least one silver halide emulsion comprising silver halide grains having associated therewith a dye substituted with at least one guanidinium, amidinium, or imine of urea substituent.
    Type: Grant
    Filed: September 13, 1999
    Date of Patent: December 11, 2001
    Assignee: Eastman Kodak Company
    Inventors: Andrei Andrievsky, Richard L. Parton, Thomas L. Penner, William J. Harrison
  • Patent number: 6306570
    Abstract: A photographic element comprising at least one silver halide emulsion layer in which the silver halide is sensitized with a compound of the formula: wherein A is a silver halide adsorptive group that contains at least one atom of N, S, Se, or Te that promotes adsorption to silver halide, and Z is a light absorbing group including for example cyanine dyes, complex cyanine dyes, merocyanine dyes, complex merocyanine dyes, homopolar cyanine dyes, styryl dyes, oxonol dyes, hemioxonol dyes, and hemicyanine dyes, and XY is an fragmentable electron donor moiety in which X is an electron donor group and Y is a leaving group other than hydrogen, and wherein: 1) XY has an oxidation potential between 0 and about 1.4 V; and 2) the oxidized form of XY undergoes a bond cleavage reaction to give the radical X• and the leaving fragment Y. In a preferred embodiment of the invention, the radical X• has an oxidation potential ≦−0.7 V.
    Type: Grant
    Filed: March 27, 2000
    Date of Patent: October 23, 2001
    Assignee: Eastman Kodak Company
    Inventors: Anthony Adin, Jerome J. Looker, Samir Y. Farid, Ian R. Gould, Stephen A. Godleski, Jerome R. Lenhard, Annabel A. Muenter, Lal C. Vishwakarma, Paul A. Zielinski
  • Patent number: 6245499
    Abstract: In a photothermographic material comprising an organic silver salt, a silver halide, and a reducing agent, a hydrazine compound of a special structure and a sensitizing dye of a special structure are contained. The photothermographic material shows high Dmax and ultrahigh contrast.
    Type: Grant
    Filed: August 21, 1998
    Date of Patent: June 12, 2001
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keiichi Suzuki, Toshiaki Kubo, Yoshio Inagaki, Tsutomu Arai
  • Patent number: 6144825
    Abstract: An image forming apparatus using an electrophotographic processor with a transfer roller, a charge roller and a photosensitive drum for image formation. The photosensitive drum is comprised of a cylindrical elastic body exhibiting a predetermined level of elasticity; a conductive film formed on an outer surface of said cylindrical elastic body; an image carrier generation layer of a first photoconductive material formed on the conductive film; and an image carrier transfer layer of a second photoconductive material formed on said image carrier generation layer.
    Type: Grant
    Filed: April 7, 1998
    Date of Patent: November 7, 2000
    Assignee: SamSung Electronics Co., Ltd.
    Inventor: Ki-Ju Park
  • Patent number: 6136483
    Abstract: An electrophotographic photoconductor including an electroconductive substrate, and a charge generating layer including a charge generating material and a charge transporting layer including a charge transporting material, which are overlaid and which are formed overlying one side of the electroconductive substrate, wherein the charge generating material includes an asymmetric disazo pigment and a metal-free phthalocyanine pigment, and wherein a ratio of the asymmetric disazo pigment to the metal-free phthalocyanine pigment is from 1.5:1 to 5:1 by weight and the asymmetric disazo pigment has the following formula (I):Cp1--N.dbd.N--A--N.dbd.N--Cp2 (I)wherein A represents a divalent group which is connected to each nitrogen atom of the adjacent azo groups through a carbon atom of said A group; and Cp1 and Cp2 independently represents a residual group of a coupler, wherein Cp1 is different from Cp2.
    Type: Grant
    Filed: August 26, 1999
    Date of Patent: October 24, 2000
    Assignee: Ricoh Company, Ltd.
    Inventors: Yasuo Suzuki, Jun Aoto, Takehiko Kinoshita
  • Patent number: 6132911
    Abstract: A method of manufacturing an organic pigment including the steps of providing an organic pigment wet cake which includes at least an organic pigment and a solvent and drying the organic pigment wet cake while the wet cake is heated at a temperature higher than room temperature to prepare a powder of the organic pigment, wherein the organic pigment is present in the organic pigment wet cake in an amount of not greater than about 70% by weight.
    Type: Grant
    Filed: July 22, 1999
    Date of Patent: October 17, 2000
    Assignee: Ricoh Company, Ltd.
    Inventor: Tatsuya Niimi
  • Patent number: 6106985
    Abstract: A layered-form electrophotographic photoreceptor which is composed of a conductive substrate, a charge generating layer (CGL) laid on the conductive substrate, and a charge transporting layer (CTL) laid on the CGL, wherein the CGL includes .mu.-oxo-aluminum phthalocyanine dimer as a charge generating material (CGM), and the CTL comprises a specific hydrazone compound as a charge transporting material (CTM). The electrophotographic photoreceptor shows good stability and electric property (for example, good chargeability, low dark decay, and low residual potential), even if it is employed as a high-gamma photoreceptor which corresponds to a short wavelength light sauce such as LD ray and LED ray.
    Type: Grant
    Filed: March 3, 1999
    Date of Patent: August 22, 2000
    Assignee: Orient Chemical Industries, Ltd.
    Inventors: Yasuhiro Yamasaki, Kazuyoshi Kuroda
  • Patent number: 6093514
    Abstract: The present invention provides novel .mu.-Oxo-aluminum/gallium phthalocyanine dimer having a structure of the formula (A): ##STR1## The .mu.-oxo-aluminum/gallium phthalocyanine dimer, and the mixed crystals comprising the .mu.-oxo-aluminum/gallium phthalocyanine dimer are suitable as a charge generating material for an organic photoconductive material, such as an electrophotographic photoreceptor.
    Type: Grant
    Filed: November 24, 1999
    Date of Patent: July 25, 2000
    Assignee: Orient Chemical Industries, Ltd.
    Inventors: Yasuhiro Yamasaki, Kenji Takaki, Kazuyoshi Kuroda
  • Patent number: 6080518
    Abstract: A photoconductor for use in electrophotographic reproduction devices is disclosed. The photoconductor provides simultaneous improvement in both photoreceptor sensitivity and fatigue, while also providing higher charge voltage, lower residual voltage and lower dark decay. The photoconductor of the present invention includes simple quinone additives in either the charge generation layer, the charge transport layer, or both layers. Quinone additives are preferably selected from o-quinone, duroquinone, diphenoquinone, naphthaquinone, and mixtures of those materials, with duroquinone and the mixture E+Z 3, 3'-di-t-butyl-5, 5'-dimethyl diphenoquinones being preferred.
    Type: Grant
    Filed: June 8, 1999
    Date of Patent: June 27, 2000
    Assignee: Lexmark International, Inc.
    Inventors: Ronald Harold Levin, Scott Thomas Mosier
  • Patent number: 6074791
    Abstract: A photoconductive imaging member comprised of a supporting substrate, a hole blocking layer thereover, a photogenerating layer and a charge transport layer, and wherein the hole blocking layer is comprised of a metal oxide prepared by a sol-gel process.
    Type: Grant
    Filed: February 26, 1999
    Date of Patent: June 13, 2000
    Assignee: Xerox Corporation
    Inventors: Carol A. Jennings, Dasarao K. Murti, Paul F. Smith, Gwynne E. McAneney, Ah-Mee Hor, Sandra J. Gardner, Beng S. Ong
  • Patent number: 6054237
    Abstract: An object of the invention is to provide a highly characteristic image using an electrophotographic photoreceptor of which a charge-generating layer can be produced with a better coating property and which is highly sensitive and electrostatically highly stable in repeated use. The charge-generating layer of a function-separated type photoreceptor contains a n-type non-metallic phthalocyanine and a copolymer of vinyl chloride-vinyl acetate type. Particularly, the ratio of the .tau.-type non-metallic phthalocyanine to the copolymer of vinyl chloride-vinyl acetate type is fixed at 1/3-3/1 by weight. The thickness of the charge-generating layer is fixed at 0.1-0.6 .mu.m. As the copolymer of vinyl chloride-vinyl acetate type, copolymers of vinyl chloride-vinyl acetate, vinyl chloride-vinyl acetate-maleic acid, or vinyl chloride-vinyl acetate-vinyl alcohol are selected. Particularly, it is favorable to select those containing at least 10% by weight of the vinyl alcohol component.
    Type: Grant
    Filed: December 15, 1998
    Date of Patent: April 25, 2000
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Kazuya Ishida, Kiyofumi Morimoto, Satoshi Katayama, Takahiro Teramoto, Akihiko Kawahara, Kazushige Morita
  • Patent number: 6030735
    Abstract: A photoconductive imaging member comprised of a supporting substrate, a hole blocking layer thereover, a photogenerating layer and a charge transport layer, and wherein the hole blocking layer is comprised of a polymetallosiloxane.
    Type: Grant
    Filed: October 12, 1999
    Date of Patent: February 29, 2000
    Assignee: Xerox Corporation
    Inventor: Brian E. Springett
  • Patent number: 6017666
    Abstract: A charge generating composition comprising: a hydroxygallium phthalocyanine an alkoxy-bridged metallophthalocyanine dimer, and a polymer matrix comprised of a reaction product copolymerized from reactants including a vinyl chloride monomer, a vinyl acetate monomer, and a hydroxyalkyl acrylate monomer.
    Type: Grant
    Filed: October 14, 1998
    Date of Patent: January 25, 2000
    Assignee: Xerox Corporation
    Inventors: Richard H. Nealey, Kenny T. T. Dinh, John G. Matta
  • Patent number: 5994013
    Abstract: Photoconductors comprise a substrate, a charge transport layer and a charge generation layer, wherein the charge transport layer comprises binder and a first charge transport compound and the charge generation layer comprises binder, a charge generation compound and a second charge transport compound. The first and second charge transport compounds may be the same or different. In a first embodiment, the second charge transport compound is effective as a dopant in the charge generation layer and the weight ratio of the charge generation compound to the second charge transport compound in the charge generation layer is not less than about 1:3. In a second embodiment, the charge generation layer is formed on the substrate and the charge transport layer is formed on the charge generation layer. In a third embodiment, the charge generation layer comprises at least about 15 weight percent, based on the weight of the charge generation layer, of the charge generation compound.
    Type: Grant
    Filed: April 24, 1998
    Date of Patent: November 30, 1999
    Assignee: Lexmark International, Inc.
    Inventors: Ronald Harold Levin, Scott Thomas Mosier, Jennifer Kaye Neely, Catherine Mailhe Randolph
  • Patent number: 5985500
    Abstract: A photoreceptor composed of: (a) a substrate; (b) a blocking layer including a fluoroelastomer; (c) a charge generating layer including a binder material and a phthalocyanine; and (d) a charge transport layer.
    Type: Grant
    Filed: August 13, 1998
    Date of Patent: November 16, 1999
    Assignee: Xerox Corporation
    Inventors: Timothy J. Fuller, Markus R. Silvestri, Damodar M. Pai, John F. Yanus, Huoy-Jen Yuh, John S. Chambers, Ihor W. Tarnawskyj, Kock-Yee Law
  • Patent number: 5783377
    Abstract: A photographic element having a light sensitive layer and containing a dye of the formula (I): ##STR1## wherein: X.sub.1 and X.sub.2 each independently represents the atoms necessary to complete a 5- or 6-membered heterocyclic nucleus;X.sub.3 represents the atoms necessary to form a 5- or 6-membered ring structure, which may be substituted;R.sub.1 and R.sub.2 each independently represents a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group;R.sub.3 represents H, a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group;r and s independently are 0 or 1; andW represents one or more counterions as needed to balance the charge of the molecule.
    Type: Grant
    Filed: September 4, 1996
    Date of Patent: July 21, 1998
    Assignee: Eastman Kodak Company
    Inventors: John David Mee, Colin James Gray
  • Patent number: 5763152
    Abstract: A silver halide photographic light-sensitive material is disclosed. The material comprises a substrate provided thereon with at least one silver halide emulsion layer comprising at least one compound represented by the following Formula (I): ##STR1## wherein Ra and Rb each represents a hydrogen atom, an alkyl group having at least two carbon atoms or an aryl or heterocyclic group, provided that Ra and Rb do not simultaneously represent hydrogen atoms; La and Lb each represents a methylene group; L.sub.1 and L.sub.2 each represents a methine group; p.sub.1 represents 0 or 1; Z.sub.1 represents an atomic group required for forming a 5- or 6-membered nitrogen atom-containing heterocyclic ring; M.sub.1 represents a counterion required for balancing the electrical charge; m.sub.1 represents a numerical value of not less than 0 required for neutralizing the molecule; and Q represents a methine or polymethine group required for forming a methine dye.
    Type: Grant
    Filed: March 29, 1996
    Date of Patent: June 9, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takanori Hioki, Mikio Ihama
  • Patent number: 5707794
    Abstract: Improved spectral sensitization with a synergistic combination of dyes is described. The two dyes include a first sensitizing dye is represented by Formula 1. ##STR1## and a second dye represented by Formula 2. ##STR2## The substituents of are defined in the description.
    Type: Grant
    Filed: November 22, 1996
    Date of Patent: January 13, 1998
    Assignee: Sterling Diagnostic Imaging, Inc.
    Inventor: Dietrich Max Fabricius
  • Patent number: 5691126
    Abstract: A new class of dyes useful in photographic materials as antihalation dyes, filter dyes or acutance dyes is disclosed. The dyes absorb in the spectral region 450-500 nm and are especially useful in photographic materials designed for recording by means of an Ar ion laser.
    Type: Grant
    Filed: August 29, 1996
    Date of Patent: November 25, 1997
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Eric Kiekens, Antonius Van Gils, Roland Claes
  • Patent number: 5610005
    Abstract: A color photographic light-sensitive material which has a high storage stability and a high sensitivity and in which photographic properties vary little with the passage of time from photography to development is provided. At least one light-sensitive silver halide emulsion layer constituting a silver halide color photographic light-sensitive material is spectrally sensitized with at least one type of a spectral sensitizing dye represented by Formula (I) below, and at least one silver halide emulsion contained in this light-sensitive silver halide emulsion layer is subjected to reduction sensitization in the manufacturing process of the emulsion. (In Formula (I), each of R.sub.11 and R.sub.12 represents an alkyl group, Z.sub.11 represents a group of atoms required to form a benzene ring, Z.sub.12 represents a group of atoms required to form a benzothiazole nucleus, a benzoselenazole nucleus, a benzoxazole nucleus, or a naphthoxazole nucleus, and X.sub.11 represents a charge-balancing counter anion.
    Type: Grant
    Filed: June 12, 1996
    Date of Patent: March 11, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Kawakami, Junji Nishigaki
  • Patent number: 5464736
    Abstract: A photographic element having a silver halide emulsion sensitized by dye of the formula I: ##STR1## wherein: R.sup.1 represents a substituted or unsubstituted aromatic or heteroaromatic group, a substituted or unsubstituted alkyl or H;R.sup.2 represents a substituted or unsubstituted alkyl, alkenyl, aryl, aralkyl, or H;E.sup.1 represents an electron withdrawing group;Z represents the non-metallic atoms required to complete a substituted or unsubstituted ring system containing at least one 5- or 6-membered heterocyclic nucleus;L.sup.1, L.sup.2, L.sup.5 and L.sup.6 independently represent a substituted or unsubstituted methine;m may be 0, 1, 2 or 3;n may be 0 or 1.
    Type: Grant
    Filed: April 28, 1994
    Date of Patent: November 7, 1995
    Assignee: Eastman Kodak Company
    Inventors: Margaret J. Helber, Thomas R. Dobles, Donald R. Diehl, Heidi E. Dankosh, John D. Mee
  • Patent number: 5441866
    Abstract: Photothermographic elements of the photothermographic type may be sensitized to the infrared with sensitizing dyes of the formula: ##STR1## wherein: R.sup.1 represents a (CH.sub.2).sub.n --COO.sup.- group of from 1-20 carbon atoms, or an alkyl group of from 1 to 20 carbon atoms; andn is an integer from 1 to 20.
    Type: Grant
    Filed: January 26, 1995
    Date of Patent: August 15, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: James R. Miller, Sam Kalousdian, Brian C. Willett, John M. Winslow, Pu Zhou, Chaofeng Zou
  • Patent number: 5382497
    Abstract: An optical recording medium comprising a substrate and a thin organic film containing at least one kind of dye selected from polymethine family dyes, perylium family dyes, and cyanine family dyes, and a recording process comprising scanning the optical recording medium with a high intensity light beam such as a laser beam to form optically detectable pits on the recording medium.
    Type: Grant
    Filed: April 1, 1994
    Date of Patent: January 17, 1995
    Assignee: Canon Kabushiki Kaisha
    Inventors: Kazuharu Katagiri, Yoshihiro Oguchi, Yoshio Takasu
  • Patent number: 5320930
    Abstract: An optical recording medium comprising a substrate and a thin organic film containing at least one kind of dye selected from polymethine family dyes, perylium family dyes, and cyanine family dyes, and a recording process comprising scanning the optical recording medium with a high intensity light beam such as a laser beam to form optically detectable pits on the recording medium.
    Type: Grant
    Filed: July 6, 1993
    Date of Patent: June 14, 1994
    Assignee: Canon Kabushiki Kaisha
    Inventors: Kazuharu Katagiri, Yoshihiro Oguchi, Yoshio Takasu
  • Patent number: 5312722
    Abstract: Disclosed is a silver halide photographic material containing at least one dye of formula (Ia), (Ib), (Ic), or (Id): ##STR1## wherein R.sup.1, R.sup.2, R.sup.9 and R.sup.10 may be the same or different and each represents an alkyl group; Z.sup.1, Z.sup.2, Z.sup.3 and Z.sup.4 each represents a non-metallic atomic group necessary for forming a nitrogen-containing hetero ring; R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.11, R.sup.12, R.sup.13 and R.sup.14 may be the same or different and each represents a hydrogen atom, an alkyl group, an aryl group or an aralkyl group; R.sup.7, R.sup.8, R.sup.15 and R.sup.16 may be the same or different and each represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an amino group or a hydroxyl group; R.sup.3 and R.sup.4, R.sup.5 and R.sup.6, R.sup.11 and R.sup.12, R.sup.13 and R.sup.14, R.sup.3 and R.sup.7, R.sup.5 and R.sup.8, R.sup.11 and R.sup.15, or R.sup.13 and R.sup.
    Type: Grant
    Filed: May 3, 1993
    Date of Patent: May 17, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Toru Harada
  • Patent number: 5290670
    Abstract: An infrared sensitive silver halide photographic element which contains an infrared-absorbing dye represented by the following formula ##STR1## wherein: R.sub.1 and R.sub.2 each independently represents a sulfoalkyl or a sulfatoalkyl group,Q represents the atoms necessary to complete a 5- to 6- membered carbocyclic ring,Z.sub.3 represents the atoms necessary to complete a 5-membered N-containing aromatic ring,X.sup.- represents an anion,n is an integer of 1 or 2, provided that n is 1 when the dye forms an intramolecular salt, andZ.sub.1 and Z.sub.2 each independently represents the atoms necessary to complete a substituted or unsubstituted indole nucleus.
    Type: Grant
    Filed: July 9, 1992
    Date of Patent: March 1, 1994
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Ivano Delprato, Stefano Mana, Antonio Luzzi
  • Patent number: 5278026
    Abstract: An optical recording medium comprising a substrate and a thin organic film containing at least one kind of dye selected from polymethine family dyes, perylium family dyes, and cyanine family dyes, and a recording process comprising scanning the optical recording medium with a high intensity light beam such as a laser beam to form optically detectable pits on the recording medium.
    Type: Grant
    Filed: October 1, 1991
    Date of Patent: January 11, 1994
    Assignee: Canon Kabushiki Kaisha
    Inventors: Kazuharu Katagiri, Yoshihiro Oguchi, Yoshio Takasu
  • Patent number: 5275928
    Abstract: A photographic element is described with improved speed in the blue and ultra-violet region of the electromagnetic spectrum. The spectral response of the photographic element is enhanced with at least one dye represented by ##STR1## wherein A.sub.1 and A.sub.2 are hydrogen or taken together represent X--CH.dbd., wherein X is hydrogen, alkyl or substituted alkyl, substituted or unsubstituted five-member heterocyclic ring, substituted or unsubstituted six-member heterocyclic ring, aryl or an aryl substituted by at least one element chosen from the group consisting of alkyl, halogen, aryl, carbonyl, alkoxy, sulfonate, carboxy or triflouralkyl; Y is alkyl, aryl or COR wherein R is OH, NR.sup.2 or OM.sup.+, wherein R2 is hydrogen, alkyl, substituted alkyl, aryl or substituted aryl; wherein M+ is HNR.sup.3.sub.3.sup.+ or a metal cation, wherein R3 is hydrogen, alkyl or substituted alkyl, aryl or substituted aryl; Z is hydrogen, alkyl, substituted alkyl, aryl or substituted aryl.
    Type: Grant
    Filed: November 27, 1991
    Date of Patent: January 4, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Dietrich M. Fabricius
  • Patent number: 5246814
    Abstract: An optical recording medium comprising a substrate and a thin organic film containing at least one kind of dye selected from polymethine family dyes, perylium family dyes, and cyanine family dyes, and a recording process comprising scanning the optical recording medium with a high intensity light beam such as a laser beam to form optically detectable pits on the recording medium.
    Type: Grant
    Filed: October 1, 1991
    Date of Patent: September 21, 1993
    Assignee: Canon Kabushiki Kaisha
    Inventors: Kazuharu Katagiri, Yoshihiro Oguchi, Toshio Takasu
  • Patent number: 5166046
    Abstract: The present invention relates to a silver halide photographic material having one or more light-sensitive silver halide emulsion layers on a support, which said photographic material is characterized in that at least one of said light-sensitive emulsion layers contains silver halide grains that are spectrally sensitized with at least one of the spectral sensitizers represented by the following general formula (I) and further contains at least one of the compounds represented by the following general formulas (II) and (III): ##STR1## wherein the variables are as defined in the specification.
    Type: Grant
    Filed: January 10, 1991
    Date of Patent: November 24, 1992
    Assignee: Konica Corporation
    Inventors: Hiroshi Okusa, Nobuaki Kagawa, Shinri Tanaka
  • Patent number: 5147769
    Abstract: An X-ray photographic material having:(1) at least one sensitive silver halide photographic emulsion layer provided on both sides of a support; and(2) at least one layer provided on at least one side of the support for fixing a dye which can be decolorized during development and which absorbs light in the sensitive region of the photographic material and wherein:(3) the dye contributes to the reduction of cross-over to less than 10%; and(4) the dye is a compound selected from the group consisting of compounds represented by the following general formula (I) and is dissolved in an oil which is a solvent substantially insoluble in water and having a boiling point of not lower than 160.degree. C. and which is dispersed as oil droplets or is loaded and dispersed in a polymer latex: ##STR1## wherein X and Y each represents a substituent group, or X and Y may be combined together to form a heterocyclic ring L.sup.1, L.sup.2 and L.sup.
    Type: Grant
    Filed: June 5, 1990
    Date of Patent: September 15, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Ichizo Toya, Yoshihiro Jimbo
  • Patent number: 5132201
    Abstract: A silver halide photographic material composed of a support having thereon at least one light-sensitive silver halide emulsion layer, at least one layer of the material containing a compound represented by formula (I): ##STR1## wherein X represents hydrogen or a group capable of providing hydrogen upon hydrolysis; Time represents a divalent linking group; t is 0 or 1; PUG represents a photographically useful group; V represents a carbonyl group, a sulfonyl group, a sulfoxy group, an iminomethylene group, ##STR2## wherein W represents an electrophilic group, or V represents ##STR3## wherein R.sub.0 represents an alkoxy group or an aryloxy group; and R represents hydrogen, an aliphatic group, an aromatic group or ##STR4## wherein PUG, Time, t, and W are as defined above. The redox compound is capable of releasing a photographically useful reagent using any conventional developing agent, has excellent storage stability, and provides rapid release of the photographically useful reagent.
    Type: Grant
    Filed: November 12, 1991
    Date of Patent: July 21, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Morio Yagihara, Hisashi Okada
  • Patent number: 5108882
    Abstract: A photographic element is described comprising a support having thereon(a) a silver halide emulsion layer where the silver halide is sensitized with a dye having the formula: ##STR1## Z.sub.1 and Z.sub.2 each independently represents the atoms necessary to complete a substituted or unsubstituted 5- or 6-membered heterocyclic nucleus,R.sub.1 and R.sub.2 each independently represents substituted or unsubstituted alkyl or substituted or unsubstituted aryl, andR.sub.3, R.sub.4, R.sub.5, and R.sub.6 each independently represents hydrogen, substituted or unsubstituted alkyl, substituted or unsubstituted aryl,X represents a counterion, and(b) at least one other red- or infrared-sensitive silver halide emulsion layer having a maximum sensitivity at a wavelength different from that of the (a) layer.
    Type: Grant
    Filed: September 26, 1989
    Date of Patent: April 28, 1992
    Assignee: Eastman Kodak Company
    Inventors: Richard L. Parton, Annabel A. Muenter, Anthony Adin
  • Patent number: 5091298
    Abstract: Dyes according to formulas (I), (II), (III), (IV), and (V) below are described. The dyes are useful as low-staining sensitizing dyes for photographic materials. ##STR1## Z.sub.1, Z.sub.2, Z.sub.3, R.sub.1, R.sub.2, L, D, G, X, n, P, and q are defined herein.
    Type: Grant
    Filed: July 19, 1990
    Date of Patent: February 25, 1992
    Assignee: Eastman Kodak Company
    Inventors: Richard L. Parton, Steven G. Link, David A. Stegman, John D. Mee
  • Patent number: 5079127
    Abstract: An optical recording medium comprising a substrate and a thin organic film containing at least one kind of dye selected from polymethine family dyes, perylium family dyes, and cyanine family dyes, and a recording process comprising scanning the optical recording medium with a high intensity light beam such as a laser beam to form optically detectable pits on the recording medium.
    Type: Grant
    Filed: April 24, 1989
    Date of Patent: January 7, 1992
    Assignee: Canon Kabushiki Kaisha
    Inventors: Kazuharu Katagiri, Yoshihiro Oguchi, Yoshio Takasu
  • Patent number: 5079128
    Abstract: An optical recording medium comprising a substrate and a thin organic film containing at least one kind of dye selected from polymethine family dyes, perylium family dyes, and cyanine family dyes, and a recording process comprising scanning the optical recording medium with a high intensity light beam such as a laser beam to form optically detectable pits on the recording medium.
    Type: Grant
    Filed: April 24, 1990
    Date of Patent: January 7, 1992
    Assignee: Canon Kabushiki Kaisha
    Inventors: Kazuharu Katagiri, Yoshihiro Oguchi, Yoshio Takasu
  • Patent number: 5032500
    Abstract: A process or the preparation of a silver halide photographic emulsion is provided which comprises the addition of at least one pendant type spectral sensitizing dye containing as a substituent a compound having the effect of inhibiting fog at any time after the formation of silver halide grains, but before the completion of the chemical ripening process. In a preferred embodiment, the addition of said pendant type spectral sensitizing dyes is effected at any time after the formation of silver halide grains, but before former one second of the total time of the chemical ripening process. The pendant type spectral sensitizing dyes are compounds represented by the general formula (III) or (IV): ##STR1## wherein SSD represents a sensitizing dye portion; AF represents a compound portion containing a saturated or unsaturated 5- to 7-membered ring containing at least one nitrogen atom; L.sup.1 represents a divalent connecting group containing at least one of C, N, S and O; L.sup.2 has the same meaning at L.sup.
    Type: Grant
    Filed: January 14, 1990
    Date of Patent: July 16, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tadashi Ikeda, Mitsuo Saitou, Yoshio Inagaki, Toshinao Ukai
  • Patent number: 4994356
    Abstract: Solid particle dispersions of dyes according to the formula: ##STR1## are disclosed as filter dyes for photographic elements. In this formula, n is 0 or 1.R.sub.1 is CO.sub.2 H or NHSO.sub.2 R.sub.2 where R.sub.2 is substituted or unsubstituted alkyl or substituted or unsubstituted aryl.R.sub.3 is substituted or unsubstituted alkyl or substituted or unsubstituted aryl.Z represents the atoms necessary to complete a substituted or unsubstituted heterocyclic nucleus.
    Type: Grant
    Filed: April 4, 1990
    Date of Patent: February 19, 1991
    Assignee: Eastman Kodak Company
    Inventors: Donald R. Diehl, Glenn M. Brown
  • Patent number: 4987064
    Abstract: A silver halide photographic material is disclosed, comprising a support having thereon an emulsion layer comprising a dispersion medium, silver halide grains, and a pendant type sensitizing dye, wherein said pendant type sensitizing dye is a compound comprising a sensitizing dye and an antifoggant, each of which may have substituent groups and wherein said sensitizing dye and antifoggant are organochemically bonded.
    Type: Grant
    Filed: December 8, 1989
    Date of Patent: January 22, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Mitsuo Saitou, Toshinao Ukai, Tadashi Ikeda
  • Patent number: 4830958
    Abstract: A photographic material having an excellent rapid processability, a high sensitivity and a less sensitivity variation due to a change of standing of the silver halide emulsion in the course of preparation of the light-sensitive material, and its preparation process are disclosed. The silver halide photographic light-sensitive material comprises a support bearing at least one silver halide emulsion layer thereon, and at least one silver halide emulsion layer contains highly chloride-containing silver halide grains having a silver chloride content of not less than 90 mol %, a water-soluble bromide of from 0.05 mol % to 2 mol % per mol of silver halide and a high boiling organic solvent having a dielectric constant of not higher than 6.0.
    Type: Grant
    Filed: January 25, 1988
    Date of Patent: May 16, 1989
    Assignee: Konica Corporation
    Inventors: Mitsuhiro Okumura, Keiji Ohbayashi, Shigeo Tanaka
  • Patent number: 4814265
    Abstract: A silver halide photographic light-sensitive material containing at least one methine dye which consists of an azulene nucleus, at least one of 10 carbon atoms of which is replaced by chalcogen atom(s) or nitrogen atom(s), and further whose 7-membered ring part is substituted with a methine bond having at the terminal an auxochrome which forms a conjugated resonance chromophore together with 10.pi. electron system of the nucleus is provided.Silver halide photographic light-sensitive materials of the invention are spectrally sensitized in long wavelength region, and have improved photographic performances such as sharpness and color resolution.
    Type: Grant
    Filed: February 26, 1988
    Date of Patent: March 21, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takanori Hioki, Haruo Takei
  • Patent number: 4804599
    Abstract: Dyes of the formula ##STR1## wherein Y completes a benzothiazole or benzoselenazole nucleus, R.sub.1 is alkyl, R.sub.2 and R.sub.3 are hydrogen, alkyl or phenyl and Z is alkylene, are suitable for sensitizing fine grain silver halide emulsions.
    Type: Grant
    Filed: May 24, 1988
    Date of Patent: February 14, 1989
    Assignee: Ciba-Geigy AG
    Inventor: Geoffrey E. Ficken
  • Patent number: 4800154
    Abstract: A silver halide photographic emulsion comprising at least one spectral sensitizing dye having the following general formula (I):Dye--J.sup.1 --CONH--J.sup.2 --NHNHG--R (I)wherein Dye represents a dye residue capable of becoming a spectral sensitizing dye; J.sup.1 represents a substituted or unsubstituted alkylene group, a substituted or unsubstituted arylene group, a substituted or unsubstituted aralkylene group, or a substituted or unsubstituted alkarylene group; J.sup.2 represents a substituted or unsubstituted arylene group; R represents hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxy group, or a substituted or unsubstituted aryloxy group; and G represents a carbonyl group, a sulfonyl group, a sulfoxy group, a phosphoryl group, or a substituted or unsubstituted iminomethylene group.
    Type: Grant
    Filed: October 16, 1986
    Date of Patent: January 24, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masaki Okazaki, Haruo Takei