S, Se, Or Te Or Compound Thereof Patents (Class 430/603)
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Publication number: 20020058217Abstract: An aqueous dispersion comprising a binder or a surfactant, a substantially light-insensitive and substantially water-insoluble organic silver salt and a photosensitive silver halide, wherein the aqueous emulsion further comprises a sensitization agent selected from the group consisting of: tin(II) bromide, aminoiminomethane sulfinic acid, water-soluble salts of H3PO3, water-soluble salts of H3PO2, water-soluble SO32− salts and water-soluble HSO3− salts; and production process for therefor and a photothermographic recording material comprising a support and a photo-addressable thermally developable element, the photo-addressable thermally developable element fulfilling two requirements: (i) the photo-addressable thermally developable element contains a substantially light-insensitive and substantially water-insoluble organic silver salt, a reducing agent for the substantially light-insensitive and substantially water-insoluble organic silver salt and in thermal working relationship therewith, a phoType: ApplicationFiled: August 23, 2001Publication date: May 16, 2002Applicant: AGFA-GEVAERTInventors: Herman Uytterhoeven, Johan Loccufier, Yvan Gilliams
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Patent number: 6383731Abstract: The object of the present invention is to provides a novel polyhalogenomethylsulfonyl compound which can be used for providing a thermally processed image recording material which has a high sensitivity, gives less fog, and has a good stock stability and a good image storage stability of dark and high temperature or light storage. According to the present invention, there is provided a polyhalogenomethylsulfonyl compound represented by the following formula (1), or salts thereof, or hydrates or solvates thereof: wherein Z1 and Z2 each independently represents a halogen atom; A represents a hydrogen atom or a halogen atom; and R1 represents an alkyl group having from 2 to 12 carbon atoms, which may have one or more substituents, an alkenyl group having from 2 to 12 carbon atoms, which may have one or more substituents, or an alkinyl group having from 2 to 12 carbon atoms, which may have one or more substituents.Type: GrantFiled: August 20, 2001Date of Patent: May 7, 2002Assignee: Fuji Photo Film Co., Ltd.Inventors: Masaru Takasaki, Katsuyuki Watanabe, Hisashi Okamura
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Patent number: 6383725Abstract: An emulsion comprising a substantially light-insensitive organic silver salt, photosensitive silver halide in catalytic association with the substantially light-insensitive organic silver salt and a binder, wherein the emulsion further comprises a polyhalide compound selected from the group consisting of quaternary ammonium polyhalides, quaternary phosphonium polyhalides and ternary sulphonium polyhalides, which satisfies a test specified in the description, or a product of a reaction between the polyhalide compound and a reducing species present in said emulsion; a process for producing a photothermographic recording material, capable of image formation without preliminary heating prior to exposure, comprising a photo-addressable thermally developable element incorporating the emulsion; and a photothermographic recording process utilizing the photothermographic recording material.Type: GrantFiled: December 13, 2000Date of Patent: May 7, 2002Assignee: AGFA-GevaertInventors: Johan Loccufier, Ivan Hoogmartens, Hans Strijckers
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Publication number: 20020051950Abstract: A silver halide photographic material having high sensitivity, low fog and good shelf life (i.e.Type: ApplicationFiled: April 10, 2001Publication date: May 2, 2002Inventors: Takashi Katoh, Tomoyuki Ohzeki, Katsutoshi Yamane, Takanori Hioki
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Publication number: 20020042032Abstract: A photothermographica material is disclosed, comprising an organic silver salt and a light sensitive silver halide, wherein the photothermographic material contains a hydrophilic binder of 0.5 to 2 g per mol of the organic silver salt and the organic silver salt having been formed in the presence of the silver halide of 7×1015 to 3×1017 grains per mol of the organic salt.Type: ApplicationFiled: April 18, 2001Publication date: April 11, 2002Applicant: KONICA CORPORATIONInventors: Keiko Maeda, Tetsuo Shima, Kazuyoshi Goan
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Publication number: 20020042030Abstract: Disclosed is a silver halide color photographic light-sensitive material including at least one red-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer, and at least one blue-sensitive silver halide emulsion layer on a support, and having an ISO sensitivity of 640 or more, wherein the material exhibits a color saturation evaluation value &eegr;, represented by equation (I) below, of −15 dB or more.Type: ApplicationFiled: March 29, 2001Publication date: April 11, 2002Inventors: Yoichi Suga, Hideto Ikoma, Jun Okamoto
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Patent number: 6368779Abstract: Photothermographic materials have increased photospeed provided by certain organic solvent-soluble thiourea compounds that can be represented by the following Structure I, II, or III: wherein in Structure I, R1, R2, R3 and R4 are independently alkyl, cycloalkyl, allyl, alkenyl, alkynyl, aryl or heterocyclic groups, or R1 and R2 taken together, R3 and R4 taken together, R1 and R3 taken together or R2 and R4 taken together, can form a 5- to 7-membered heterocyclic ring, in Structure II, R1, R2, R3, R4 and R5 are independently alkyl, cycloalkyl, allyl, alkenyl, alkynyl, aryl or heterocyclic groups, or R3 and R5 taken together, R4 and R5 taken together, R1 and R3 taken together or R2 and R4 taken together, can form a substituted or unsubstituted 5- to 7-membered heterocyclic ring, and in Structure III, R1, R2, R3, R4, R5, and R6 are independently alkyl, cycloalkyl, allyl, alkenyl, alkynyl, aryl or heterocyclic groups, or R3 and R6 taken together, R4 and R5 taken together, R1 and R3 taken togetheType: GrantFiled: September 21, 2000Date of Patent: April 9, 2002Assignee: Eastman Kodak CompanyInventors: Doreen C. Lynch, Sharon M. Simpson, Steven M. Shor, Brian C. Willett, Chaofeng Zou
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Publication number: 20020031731Abstract: A method for processing a silver halide color photographic light-sensitive material. The material has, on a support, at least one light-sensitive silver halide emulsion layer comprising a light-sensitive silver halide emulsion, a compound that forms a dye by a coupling reaction with a developing agent in an oxidized form, and a binder. The method comprises processing the light-sensitive material such that a silver density of the at least one light-sensitive silver halide emulsion layer during development is 4×105 g/m3 or more.Type: ApplicationFiled: June 8, 2001Publication date: March 14, 2002Inventor: Junichiro Hosokawa
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Publication number: 20020028414Abstract: A silver salt photothermographic material is disclosed, comprising at least a light sensitive layer and at least a light insensitive layer, the light sensitive layer comprising organic silver salt grains, a light sensitive emulsion containing light sensitive silver halide grains and medium, a reducing agent and a binder, wherein at least one of the light sensitive layer and the light insensitive layer contains a silver-saving agent and the photothermographic material which has been subjected to thermal development at 123° C. for 13.5 sec. exhibits an average contrast of 2.0 to 6.0 within the density range of 0.25 to 2.0 on a characteristic curve of the photothermographic material.Type: ApplicationFiled: June 21, 2001Publication date: March 7, 2002Inventors: Hiroyuki Yanagisawa, Socmen Ho Kimura
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Patent number: 6350567Abstract: A silver halide photographic element comprising a silver halide emulsion which is greater than 50 mole-% silver chloride, said emulsion containing an isothiazolone compound represented by the formula wherein R1 is a substituent; and Z contains the carbon atoms necessary to form a substituted or unsubstituted non-aromatic ring, wherein the isothiazolone compound was added before or during precipitation of the emulsion.Type: GrantFiled: October 7, 1999Date of Patent: February 26, 2002Assignee: Eastman Kodak CompanyInventors: Benjamin T. Chen, Roger L. Klaus, Jeri L. Mount
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Publication number: 20020022201Abstract: A red sensitive photographic recording material is disclosed having an emulsion layer with low silver halide and low binder content. It further comprises a polyester support having subbing layers on both sides and an anti-halation layer on the back side.Type: ApplicationFiled: June 26, 2001Publication date: February 21, 2002Inventors: Roland Claes, Stefaan Lingier, Etienne Van Thillo
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Patent number: 6346372Abstract: A silver halide photographic light-sensitive material is disclosed, comprising a support having thereon at least one silver halide emulsion layer, which contains at least one compound represented by formula (1) or (A-1).Type: GrantFiled: July 6, 2000Date of Patent: February 12, 2002Assignee: Fuji Photo Film Co., Ltd.Inventors: Masaru Yoshikawa, Hirotomo Sasaki, Atsushi Matsunaga
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Publication number: 20020012891Abstract: A silver halide photographic emulsion which contains at least two sensitizing dyes represented by the following formula (I):Type: ApplicationFiled: May 1, 2001Publication date: January 31, 2002Inventors: Tetsuo Nakamura, Takanori Hioki
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Publication number: 20020009681Abstract: A silver halide photographic lightsensitive material comprises at least one lightsensitive silver halide emulsion layer on a support. The lightsensitive material exhibits a speed at 3×10−9 sec exposure time being lower than a speed at 10−5 sec exposure time by 30 or more in terms of speed unit.Type: ApplicationFiled: March 29, 2001Publication date: January 24, 2002Inventor: Naoharu Kiyoto
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Patent number: 6322961Abstract: A color reversal photographic element is disclosed comprising a support having coated thereon a silver halide emulsion layer comprising a silver halide emulsion chemically sensitized in the presence of an organomercapto Au(I) complex having the formula [L—Au—L]M wherein M is a cationic counter ion and each L is an organomercapto ligand which has antifogging, stabilizing or sensitizing properties, and a rapid sulfiding agent represented by structure SS-1 wherein each of the R1, R2, R3, and R4 groups independently represents an alkylene, cycloalkylene, carbocyclic arylene, heterocyclic arylene, alkarylene or aralkylene group; or taken together with the nitrogen atom to which they are attached, R1 and R2 or R3 and R4 can complete a 5- to 7-membered heterocyclic ring; and each of the B1, B2, B3, and B4 groups independently is hydrogen or represents a carboxylic, sulfinic, sulfonic, hydroxamic, mercapto, sulfonamido or primary or secondary amino nucleophilic group, with thType: GrantFiled: September 21, 2000Date of Patent: November 27, 2001Assignee: Eastman Kodak CompanyInventors: Wai K. Lam, Roger Lok, David W. Sandford
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Publication number: 20010044067Abstract: A silver halide color photographic light-sensitive material comprising, a photographic structural layer coated on a support, which structural layer includes at least one photographic light-sensitive layer containing a light-sensitive silver halide, a compound that forms a dye by a coupling reaction with an oxidized product of a developing agent, and a binder, wherein at least one photographic light-sensitive layer of the light-sensitive material contains a silver halide emulsion comprising a tabular silver halide grain that has principal faces composed of (111) planes, an average equivalent circle diameter of at least 0.70 &mgr;m, and an average thickness of less than 0.20 &mgr;m, and the emulsion is chemically sensitized by a tellurium sensitizer.Type: ApplicationFiled: February 28, 2001Publication date: November 22, 2001Inventor: Tomoyuki Koide
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Publication number: 20010041313Abstract: A photothermographic material disclosed, comprising on a support a light sensitive layer containing an organic silver salt, light sensitive silver halide grains and a solvent, wherein the organic silver salt comprises tabular organic silver salt grains exhibiting an average needle ratio of not less than 1.1 and less than 10.0, the light sensitive silver halide grains having been subjected to chemical sensitization.Type: ApplicationFiled: February 28, 2001Publication date: November 15, 2001Inventor: Hideki Takiguchi
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Patent number: 6316176Abstract: A method has been described of chemically sensitizing a silver halide emulsion having silver halide grains and a binder, comprising the steps of adding thereto, besides a chemically sensitizing agent providing sulphur, an organo-tellurium sensitizing compound providing tellurium in a molar ratio amount versus sulphur of less than 0.30. A light-sensitive silver halide photographic element has also been described which has been made highly sensitive by chemically sensitizing a silver halide emulsion which has been made highly sensitive by the method described hereinbefore.Type: GrantFiled: July 21, 2000Date of Patent: November 13, 2001Assignee: Agfa-GevaertInventors: Kathy Elst, Johan Loccufier
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Patent number: 6316178Abstract: Disclosed is a silver halide emulsion comprising gold-sensitized silver halide grains having a silver chloride content of 95 mole % or more, wherein from 8% to 50% of the amount of gold existing on the part of the silver halide grains is in the state of metal gold. The silver halide emulsion is an emulsion having a high silver chloride content that has high sensitivity and low fogging, and reduced both high illumination intensity reciprocity law failure and regression of latent image in the initial stage after exposure.Type: GrantFiled: November 30, 2000Date of Patent: November 13, 2001Assignee: Fuji Photo Film Co., Ltd.Inventor: Seiji Yamashita
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Publication number: 20010036606Abstract: A silver halide photographic emulsion that comprises silver halide grains.Type: ApplicationFiled: March 1, 2001Publication date: November 1, 2001Inventors: Mamoru Sakurazawa, Takeshi Funakubo, Hirotomo Sasaki, Kiyoshi Morimoto
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Publication number: 20010028996Abstract: An emulsion comprising a substantially light-insensitive organic silver salt, photosensitive silver halide in catalytic association with the substantially light-insensitive organic silver salt and a binder, wherein the emulsion further comprises a polyhalide compound selected from the group consisting of quaternary ammonium polyhalides, quaternary phosphonium polyhalides and ternary sulphonium polyhalides, which satisfies a test specified in the description, or a product of a reaction between the polyhalide compound and a reducing species present in said emulsion; a process for producing a photothermographic recording material, capable of image formation without preliminary heating prior to exposure, comprising a photo-addressable thermally developable element incorporating the emulsion; and a photothermographic recording process utilizing the photothermographic recording material.Type: ApplicationFiled: December 13, 2000Publication date: October 11, 2001Applicant: Agfa GevaertInventors: Johan Loccufier, Ivan Hoogmartens, Hans Strijckers
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Patent number: 6300053Abstract: A photothermographic element has on a support a photo-sensitive layer, and a first non-photosensitive layer containing (1) a base-bleachable dye or a salt thereof and (2) a binder. The first non-photosensitive layer or a second non-photosensitive layer disposed adjacent thereto contains (3) a base precursor and (4) a melting point depressant. The dye (1) becomes more bleachable and the processed image becomes more water resistant.Type: GrantFiled: April 1, 1999Date of Patent: October 9, 2001Assignee: Fuji Photo Film Co., Ltd.Inventors: Itsuo Fujiwara, Ichizo Toya, Masaki Noro
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Patent number: 6296998Abstract: The invention relates to an emulsion comprising bromide grains wherein said grains are chemically sensitized with a water soluble Au(I) complex having the formula [L—Au—L]M wherein the complex is symmetrical; L is an organomercapto ligand which has antifogging, stabilizing, or sensitizing properties, and M is a cationic counter ion and a rapid sulfiding agent represented by structure SS-1: wherein each of the R1, R2, R3, and R4 groups independently represents an alkylene, cycloalkylene, carbocyclic arylene, heterocyclic arylene, alkarylene or aralkylene group; or taken together with the nitrogen atom to which they are attached, R1 and R2 or R3 and R4 can complete a 5- to 7-membered heterocyclic ring; and each of the B1, B2, B3, and B4 groups independently is hydrogen or represents a carboxylic, sulfinic, sulfonic, hydroxamic, mercapto, sulfonamido or primary or secondary amino nucleophilic group, with the proviso that at least one of the B1R1 to B4R4 groups containsType: GrantFiled: September 21, 2000Date of Patent: October 2, 2001Assignee: Eastman Kodak CompanyInventors: Jon N. Eikenberry, Roger Lok, Robert D. Wilson
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Patent number: 6277549Abstract: A photosensitive element comprising a silver halide emulsion having silver halide grains containing an organic hole-trapping dopant. In a preferred embodiment said dopant is represented by formula (I): R—COOM (I) wherein R is hydrogen, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aralkyl group or hetero-aryl group, and M is hydrogen or any metal or organic group which can form a salt or by formula (II): wherein: X and Y are independently selected from O, S, Se, m is 1 and n is 1 or 2, R1 and R2 are hydrogen, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl or aralkyl group or a substituted or unsubstituted heteroaryl group, wherein R1 and R2 may be the same or different and may form a ring, E represents a group linked to the carbon atom by a heteroatom, having at least one free electron pair, M+ is a proton or an organic or inorganic (metal) counterion.Type: GrantFiled: December 11, 1998Date of Patent: August 21, 2001Assignee: Agfa-GevaertInventors: René De Keyzer, Mona Treguer, Jacqueline Belloni, Remita Hynd
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Publication number: 20010014434Abstract: A silver halide color photographic light-sensitive material comprising, a photographic structural layer coated on a support, which structural layer includes at least one photographic light-sensitive layer containing a light-sensitive silver halide, a compound that forms a dye by a coupling reaction with an oxidized product of a developing agent, and a binder, wherein at least one photographic light-sensitive layer of the light-sensitive material contains a silver halide emulsion comprising a tabular silver halide grain that has principal faces composed of (111) planes, an average equivalent circle diameter of at least 0.70 &mgr;m, and an average thickness of less than 0.20 &mgr;m, and the emulsion is chemically sensitized by a tellurium sensitizer is disclosed. The light-sensitive material is a color photographic light-sensitive material improved in the relation of sensitivity and granularity.Type: ApplicationFiled: December 22, 2000Publication date: August 16, 2001Inventor: Tomoyuki Koide
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Patent number: 6245497Abstract: A photographic element comprises a support bearing a cyan dye image-forming unit comprising at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of said emulsion layers comprises a) an emulsion with 3D, core/shell grains of at least 0.Type: GrantFiled: December 20, 1999Date of Patent: June 12, 2001Assignee: Eastman Kodak CompanyInventors: Jon N. Eikenberry, David T. Southby
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Publication number: 20010003037Abstract: Disclosed is a silver halide emulsion comprising gold-sensitized silver halide grains having a silver chloride content of 95 mole % or more, wherein from 8% to 50% of the amount of gold existing on the part of the silver halide grains is in the state of metal gold.Type: ApplicationFiled: November 30, 2000Publication date: June 7, 2001Inventor: Seiji Yamashita
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Patent number: 6242171Abstract: This invention concerns tabular photographic emulsions and their preparation. According to the invention, high bromide tabular emulsion is precipitated and then a non-sensitized fine grain emulsion comprising grains exhibiting {100} crystal faces is added, before sensitization. The resulting emulsion exhibits improved speed/fog performance.Type: GrantFiled: December 9, 1999Date of Patent: June 5, 2001Assignee: Eastman Kodak CompanyInventor: Luc R. Gourlaouen
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Patent number: 6187516Abstract: An emulsion comprising a substantially light-insensitive organic silver salt, photosensitive silver halide in catalytic association with the substantially light-insensitive organic silver salt and a binder, wherein the emulsion further comprises a polyhalide compound selected from the group consisting of quaternary ammonium polyhalides, quaternary phosphonium polyhalides and ternary sulphonium polyhalides, which satisfies a test specified in the description, or a product of a reaction between the polyhalide compound and a reducing species present in said emulsion; a process for producing a photothermographic recording material, capable of image formation without preliminary heating prior to exposure, comprising a photo-addressable thermally developable element incorporating the emulsion; and a photothermographic recording process utilizing the photothermographic recording material.Type: GrantFiled: July 8, 1997Date of Patent: February 13, 2001Assignee: Agfa-GevaertInventors: Johan Loccufier, Ivan Hoogmartens, Hans Strijckers
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Patent number: 6159676Abstract: The invention relates to an emulsion comprising tabular grains of greater than or equal to about 3.7 .mu.m area weighted mean equivalent circular diameter and thiourea sensitizer having the structural formula: ##STR1## wherein each of R.sub.1, R.sub.2, R.sub.3, and R.sub.4 independently can represent an alkylene, cycloalkylene, carbocyclic arylene or heterocyclic arylene, alarylene or aralkylene group; or taken together with the nitrogen atom to which they are attached, R.sub.1 and R.sub.2 or R.sub.3 and R.sub.4 can complete a 5- to 7-member heterocyclic ring; andeach of A.sub.1, A.sub.2, A.sub.3, and A.sub.4 independently is hydrogen or represents a carboxylic, sulfinic, sulfonic, hydroxamic, mercapto, sulfonamido or primary or secondary amino nucleophilic group;with the proviso that at least one of A.sub.1 R.sub.1 to A.sub.4 R.sub.4 contains a nucleophilic group bonded to a urea nitrogen atom through a 2- or 3-member chain.Type: GrantFiled: December 5, 1997Date of Patent: December 12, 2000Assignee: Eastman Kodak CompanyInventors: Ming Jye Lin, Kenneth J. Lushington, Frederick C. Derks, Joseph C. Deaton
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Patent number: 6159677Abstract: A monodispersed silver halide emulsion has an average silver iodide content of 1 to 20 mol %, an average equivalent sphere diameter of 0.1 to 0.6 .mu.m, and 60% or more of the total projected area of all the grains in the emulsion are occupied by tabular silver halide grains each having principal planes composed of {100} faces in an amount of 80% or more based on the total surface area of each grain.Type: GrantFiled: May 29, 1998Date of Patent: December 12, 2000Assignee: Fuji Photo Film, Co., Ltd.Inventor: Nobuyuki Haraguchi
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Patent number: 6143487Abstract: Vinyl sulfone and/or .beta.-halo sulfone compounds have been found to improve fog stability on shelf aging of photothermographic imaging elements. These elements comprise a photosensitive silver halide, silver salt oxidizing agent and reducing agent for silver ion in a binder.Type: GrantFiled: November 30, 1992Date of Patent: November 7, 2000Assignee: Eastman Kodak CompanyInventors: James B. Philip, Ivan H. Skoog, Gary L. Featherstone, Thomas J. Kub
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Patent number: 6127109Abstract: A silver halide light sensitive photographic material is disclosed, comprising a support having thereon hydrophilic colloid layers including a silver halide emulsion layer, wherein (i) at least 50% of the total projected area of silver halide grains contained in the emulsion layer is accounted for by tabular grains having an aspect ratio of 3 to 15, (ii) the tabular grains each comprising an inner region which accounts for 70% by volume of the grain and a residual outer region, the outer region containing at least 75% of total iodide contained in the grain, and (iii) the tabular grains each having an outermost layer, a halide content distribution among the tabular grains with respect to the outermost layer being not more than 20%; and wherein at least one of the hydrophilic colloid layers contains a sulfur containing compound, which has a water-solubilizing group.Type: GrantFiled: September 10, 1998Date of Patent: October 3, 2000Assignee: Konica CorporationInventor: Kazuyoshi Goan
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Patent number: 6120983Abstract: A photothermographic material contains an organic silver salt, a photosensitive silver halide, a reducing agent, a binder, and a compound of the formula: X--L.sub.1 --D wherein D is an electron donative group of atoms, X is an adsorption promoting group to silver halide, and L.sub.1 is a valence bond or a linking group. It has high sensitivity in the red to infrared region and experiences a minimal change of photographic properties under different developing conditions.Type: GrantFiled: October 22, 1997Date of Patent: September 19, 2000Assignee: Fuji Photo Film Co., LtdInventors: Hisashi Okada, Ryo Suzuki, Naoki Asanuma, Tadashi Ikeda, Shigeo Hirano
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Patent number: 6114105Abstract: A high bromide {111} tabular grain emulsion is disclosed in which most of the tabular grains exhibit silver salt epitaxy at a single site. Most of the silver halide epitaxy sites contact an edge region of the tabular grains. These emulsions exhibit chemical sensitization by the epitaxy and surprising lower levels of desensitization by spectral sensitizing dyes.Type: GrantFiled: April 13, 1999Date of Patent: September 5, 2000Assignee: Eastman Kodak CompanyInventors: Thomas B. Brust, Bernard D. Stich
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Patent number: 6100021Abstract: Provided is an improved sensitization method for photographic element. The photographic element comprises a support with at least one hydrophilic colloid layer coated thereon. The hydrophilic colloid layer comprises silver halide grains which are chemically sensitized with at least one compound represented by Formula 1:(OCH).sub.2 R.sup.1 (LHSO.sub.3).sub.2 Formula 1and at least one selenium compound.In formula 1, R.sup.1 represents an alkyl of 1-8 carbons; and L represents and alkali metal. The selenium compound is chosen from a group consisting of R.sup.2 SeCN, (R.sup.3).sub.3 PSe and ((R.sup.4).sub.2 NCO).sub.2 Se wherein R.sup.2 represents an alkyl of 1 to 8 carbons, or an alkali metal atom; R.sup.3 independently represents an aryl of 6 to 10 carbons or an alkyl of 1 to 8 carbons; and R.sup.4 independently represents an aryl of 6 to 10 carbons or an alkyl of 1 to 8 carbons.Type: GrantFiled: December 15, 1998Date of Patent: August 8, 2000Assignee: Agfa-Gevaert N.V.Inventors: Dietrich Max Fabricius, Allan R. Schoenberg
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Patent number: 6090536Abstract: A photographic emulsion is disclosed containing for enhanced imaging speed high bromide {111} tabular grain emulsion peptizer with a cationic starch and sensitized with a fragmentable electron donating sensitizer. The photographic emulsion is disclosed for use in black-and-white and color photographic elements.Type: GrantFiled: December 17, 1998Date of Patent: July 18, 2000Assignee: Eastman Kodak CompanyInventors: Joe E. Maskasky, Kenneth J. Reed, Victor P. Scaccia, James A. Friday
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Patent number: 6083681Abstract: Compounds having general structure (I) have been found to be useful as stabilizers in photothermographic elements. The photothermographic elements comprise a support bearing an imaging coating (specifically, a photosensitive, image-forming, photothermographic coating) comprising:(a) a photosensitive silver halide;(b) a non-photosensitive, reducible source of silver;(c) a reducing agent for the non-photosensitive, reducible source of silver;(d) a binder; and(e) a compound having general structure (I) ##STR1## wherein X is O or S; and Y is NH.sub.2, OH, or O.sup.- M.sup.+ wherein M.sup.+ is a metal atom.The photothermographic elements may be used in medical imaging films or as a photomask in a process where there is a subsequent exposure of an ultraviolet or short wavelength visible radiation-sensitive imageable medium.Type: GrantFiled: June 10, 1999Date of Patent: July 4, 2000Assignee: Eastman Kodak CompanyInventors: Doreen C. Lynch, Paul G. Skoug, Steven H. Kong
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Patent number: 6083680Abstract: A photothermographic material for a photomechanical process which is high in sensitivity and high in contrast and can provide an image low in Dmin by UV light, comprising a support having provided thereon a light-insensitive organic silver salt, a light-sensitive silver halide formed independently of the light-insensitive organic silver salt, and a binder, wherein the main binder of an image formation layer containing the light-sensitive silver halide is a polymer latex having a glass transition-temperature of 40.degree. C. or less, said image formation layer is formed by applying a coating solution in which 60% by weight or more of a solvent is water, and the light-sensitive silver halide is gold-sensitized silver halide grains having a silver chloride content of 80 mol % or more per silver halide.Type: GrantFiled: August 14, 1998Date of Patent: July 4, 2000Assignee: Fuji Photo Film Co., Ltd.Inventors: Tadashi Ito, Kazuki Yamazaki
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Patent number: 6080537Abstract: A silver halide emulsion is disclosed, comprising a dispersing medium and silver halide grains having a variation coefficient of grain size distribution of not more than 20%, at least 50% of total grain projected area of the emulsion being accounted for by tabular grains an aspect ratio of at least 5, the tabular grains each having a surface region having an iodide content more than an average iodide content of the grains, the tabular grains having dislocation lines in a central region and a peripheral region of the major faces, the peripheral region having a silver chalcogenide nucleus-containing phase, the central region having silver nucleus-containing phase, and the peripheral region having at least 10 dislocation lines per grain.Type: GrantFiled: April 26, 1999Date of Patent: June 27, 2000Assignee: Konica CorporationInventors: Hideo Sugimoto, Sadayasu Ishikawa
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Patent number: 6074811Abstract: A silver halide emulsion is described, which comprises at least a dispersion medium and silver halide grains, wherein from 40 to 100% of the total projected area of the entire silver halide grains are occupied by tabular grains having a thickness of from 0.01 to 0.50 .mu.m, an aspect ratio (diameter/thickness) of from 1.6 to 500, and main planes of {100} faces, and the aspect ratio of a right angled parallelogram surrounded by edge sides of {100} face of the tabular grains or a right angled parallelogram formed by extending the edge sides (long side length/short side length) is from 1 to 8, and the tabular grains are tabular grains formed by the adsorption of compound A.sup.0 represented by formula (Z.sup.1), (Z.sup.2), (Z.sup.3) or (Z.sup.4) onto silver halide grains:B.sup.1 --S--B.sup.2 (Z.sup.1)B.sup.1 --S(O)--B.sup.2 (Z.sup.2)B.sup.1 --S(O.sub.2)--B.sup.2 (Z.sup.3)B.sup.1 --S.sup.+ (R.sup.0)--B.sup.2 .multidot.Y.sub.0.sup.-(Z.sup.4)wherein B.sup.Type: GrantFiled: January 19, 1999Date of Patent: June 13, 2000Assignee: Fuji Photo Film Co., Ltd.Inventor: Mitsuo Saitou
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Patent number: 6063558Abstract: A photosensitive element which comprises on a support at least one photosensitive silver halide emulsion layer and at least a non-light sensitive layer, wherein the silver halide emulsion layer comprises a chalcogenic compound satisfying formula (1): ##STR1## wherein: X represents Se or Te, forming a double bond with its neighbouring C-atom,Nu represents a nucleophilic group which brings an electron pair in heterolytic bond formation; Nu has a pK.sub.a -value of at least 2.0 if Nu is an acidic group,L represents a divalent linking group representing each group which can position an electron donating atom in any of the 5th to the 8th position vis-a-vis the carbon atom of the carbon-chalcogen double bond,AQB represents the necessary atoms to form a heterocyclic 5- or 6-membered ring, provided that when A is a Nitrogen-atom, B is an atom selected from the group consisting of NR.sup.1, O, S, Se and Te,R.sup.Type: GrantFiled: May 25, 1999Date of Patent: May 16, 2000Assignee: Agfa-Gevaert, N.V.Inventors: Johan Loccufier, Rene De Keyzer, Antonius Rutges
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Patent number: 6048683Abstract: A method is disclosed of manufacturing radiation-sensitive emulsions by a pulsed flow double-jet process in which high chloride silver halide grains are grown in the presence of a thioether ripening agent in the dispersing medium in the reaction vessel the silver halide grains exhibiting an average grain roundness coefficient n in the range of from 2 to less than 15.Type: GrantFiled: December 22, 1998Date of Patent: April 11, 2000Assignee: Eastman Kodak CompanyInventors: Rajesh V. Mehta, Ramesh Jagannathan, Y. Chea Chang
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Patent number: 6030763Abstract: A process for reduction-sensitizing a silver halide photographic emulsion is disclosed, comprising reduction-sensitizing a silver halide basis grain having a silver bromide content of 75 mol % or more and thereafter or at the same time, depositing silver halide having a silver chloride content of 50 mol % or more on the surface of said basis grain not to have a distinct epitaxial form. Further disclosed is a silver halide photographic light-sensitive material containing a silver halide emulsion prepared by the process.Type: GrantFiled: April 14, 1998Date of Patent: February 29, 2000Assignee: Fuji Photo Film Co., Ltd.Inventor: Hiroyuki Mifune
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Patent number: 6031237Abstract: A radiation image storage panel has a phosphor layer comprising a stimulable phosphor and a binder, in which the binder is composed of a resin containing a thermo-plastic polyurethane elastomer and a radical scavenger. The panel shows excellent durability against both light and repeated conveying.Type: GrantFiled: December 16, 1997Date of Patent: February 29, 2000Assignee: Fuji Photo Film Co., Ltd.Inventors: Shinichiro Fukui, Hideki Suzuki
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Patent number: 6030744Abstract: Photographic silver-halide materials for producing negatives with ultrahard-gradation gamma contrast, which contain a hydrazine compound and a contrast-boosting amino compound and/or phosphonium compound, demonstrate an undesirable increase in fog during storage. By adding a sulphite salt to the emulsion, storage-stable materials are obtained in which sensitivity and contrast are increased. The invention can be used to produce images during reproduction in the pre-printing stage.Type: GrantFiled: October 29, 1998Date of Patent: February 29, 2000Assignee: Agfa-Gevaert NVInventors: Reinhold Ruger, Fran.cedilla.ois Varescon
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Patent number: 6027872Abstract: A photothermographic element comprising a photosensitive silver halide, an organic silver salt, a reducing agent, and a compound of formula (I) on a support has a high sensitivity and storage stability.Z.sup.1 --(W.sup.1).sub.m1 --L.sup.1 --S--S--L.sup.2 --(W.sup.2).sub.m2 --Z.sup.2 (I)L.sup.1 and L.sup.2 are divalent aliphatic hydrocarbon groups, W.sup.1 and W.sup.2 are divalent linking groups containing 0, S or N, Z.sup.1 is hydrogen, halogen, aliphatic hydrocarbon, aromatic or heterocyclic group, Z.sup.2 is an aromatic or heterocyclic group, m.sub.1 =0, 1, 2 or 3, and m.sub.2 =0, 1, 2 or 3.Type: GrantFiled: May 20, 1998Date of Patent: February 22, 2000Assignee: Fuji Photo Film Co., Ltd.Inventors: Ryo Suzuki, Tsutomu Arai, Katsuyuki Watanabe, Shigeo Hirano, Minoru Sakai
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Patent number: 6027869Abstract: A photographic element is disclosed having at least one emulsion layer comprised of (a) radiation-sensitive silver halide grains, (b) sensitizer for the radiation-sensitive silver halide grains, (c) hydrophilic colloid vehicle, including peptizer for the radiation-sensitive silver halide grains, and (d) light scattering particles, wherein (a) the radiation-sensitive silver halide grains include tabular grains (1) having an aspect ratio of at least 2.0, (2) having {111} major faces, (3) containing greater than 50 mole percent bromide, based on silver, and (4) accounting for greater than 50 percent total grain projected area, (b) the sensitizer includes a fragmentable electron donating sensitizer, (c) the peptizer is a water dispersible cationic starch, and (d) the light scattering particles have aspect ratios of less than 1.5 and can be dissolved for removal from the emulsion layer. The photographic elements exhibit enhanced imaging speed and can be employed for color or black-and-white photographic imaging.Type: GrantFiled: December 17, 1998Date of Patent: February 22, 2000Assignee: Eastman Kodak CompanyInventors: Joe E. Maskasky, Kenneth J. Reed, Victor P. Scaccia, James A. Friday
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Patent number: 6010841Abstract: A photographic element comprises at least one silver halide emulsion layer in which the silver halide is sensitized with a compound of formulaZ-(L-XY).sub.kwherein:Z is a light absorbing group;L is a linking group containing a least one C, N, S, or O atom; andk is 1 or 2; andXY represents a fragmentable electron donor moiety wherein:1) XY has a an oxidation potential between 0 and about 1.4 V;2) X is an electron donor group;3) Y is a leaving group other than hydrogen; and4) the oxidized form of XY undergoes a bond cleavage reaction to give the radical X.sup..cndot. and the leaving fragment Y.In a preferred embodiment the radical X.sup..cndot. has an oxidation potential of .ltoreq.-0.7 V.Type: GrantFiled: October 30, 1996Date of Patent: January 4, 2000Assignee: Eastman Kodak CompanyInventors: Samir Y. Farid, Jerome R. Lenhard, Chin H. Chen, Annabel A. Muenter, Ian R. Gould, Stephen A. Godleski, Paul A. Zielinski
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Patent number: 5989797Abstract: A light-sensitive silver halide photographic material and a method for preparing said material is provided, wherein said material comprises a support and on one or both sides thereof at least one silver halide emulsion layer and a protective antistress layer as an outermost layer, characterized in that said silver halide emulsion layer(s) and/or said protective antistress layer comprise(s) at least one zeolite loaded with a photographically useful group. Said photographically useful group is a soluble salt, an organic compound releasing chloride, bromide or iodide, a sulfur salt, a selenium salt, a tellurium salt and/or a metal salt of group VIII.Type: GrantFiled: October 7, 1998Date of Patent: November 23, 1999Assignee: Agfa-Gevaert, N.V.Inventor: Hubert Vandenabeele