Stabilizing Or Fog Inhibiting Ingredient Containing Patents (Class 430/607)
-
Publication number: 20030148233Abstract: A radiation sensitive imaging element is described comprising a support bearing one or more hydrophilic colloid layers, wherein a photographically useful compound is incorporated into at least one hydrophilic colloid layer in the form of a self-assembled composition comprising a substantially homogeneous and ordered array of the photographically useful compound and silver and halide atoms, wherein the average minimum distance from each Ag atom in the composition to an atom of the photographically useful compound in the composition is less than 50 Å.Type: ApplicationFiled: December 21, 2001Publication date: August 7, 2003Applicant: Eastman Kodak CompanyInventors: Joseph F. Bringley, Manju Rajeswaran
-
Patent number: 6593075Abstract: A silver halide photographic light-sensitive material having at least one emulsion layer comprising silver halide grains, with the emulsion layer further comprising at least one compound represented by the following formula (I) and at least one compound represented by the following formula (II), (III), (IV-1), (IV-2), (V-1), (V-2), (V-3) or (VI): (X&Parenclosest;1&Parenopenst;L&Parenclosest;m&Parenopenst;A—B)n (I) (Het&Parenclosest;k1&Brketopenst;&Parenopenst;Q1&Parenclosest;k2&Parenopenst;Hy)]k3 (III) wherein the substituents as defined herein the specification.Type: GrantFiled: July 24, 2000Date of Patent: July 15, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Shinichi Ichikawa, Takeshi Suzumoto, Kohzaburoh Yamada, Tadashi Inaba
-
Patent number: 6593073Abstract: A silver halide photographic element comprises at least one silver halide emulsion layer comprising a silver halide emulsion comprising core/shell silver halide grains wherein the core region comprises silver bromide with from about 5 to about 20% silver iodide and the shell region comprises silver bromide with about 0.1 to about 10% silver iodide and said layer contains a fragmentable electron donor compound of the formula X—Y′ or a compound which contains a moiety of the formula —X—Y′; wherein X is an electron donor moiety, Y′ is a leaving proton H or a leaving group Y, with the proviso that if Y′ is a proton, a base, &bgr;−, is covalently linked directly or indirectly to X, and wherein: 1) X—Y′ has an oxidation potential between 0 and about 1.Type: GrantFiled: December 20, 1999Date of Patent: July 15, 2003Assignee: Eastman Kodak CompanyInventors: Jon N. Eikenberry, Yun C. Chang
-
Patent number: 6582897Abstract: A heat developable light-sensitive material high in heat development activity, excellent in image keeping quality, high in sensitivity and rapidly developable, comprising a support having provided on one side thereof a light-sensitive silver halide, a light-insensitive organic silver salt, a reducing agent for a silver ion and a binder, wherein the reducing agent is a compound represented by the formula (I), and an aromatic carboxylic acid compound represented by the formula (A) and a hydrogen bonding compound are further provided on the same side where the light-sensitive silver halide is provided.Type: GrantFiled: June 21, 2001Date of Patent: June 24, 2003Assignee: Fuji Photo Film Co., Ltd.Inventor: Yasuhiro Yoshioka
-
Patent number: 6582892Abstract: A black-and-white photothermographic material that is sensitive at a wavelength greater than 700 nm, and comprises a support having thereon one or more thermally-developable imaging layers comprising a binder and in reactive association, a photosensitive silver halide, a non-photosensitive source of reducible silver ions, and a reducing composition for the non-photosensitive source reducible silver ions. The thermally-developable layers further comprises one or more indolenine dyes as post-processing stabilizing compounds and one or more merocyanine dyes or cyanine spectral sensitizing dyes that comprise one or more thioalkyl, thioaryl, or thioether groups.Type: GrantFiled: June 29, 2001Date of Patent: June 24, 2003Assignee: Eastman Kodak CompanyInventors: Steven H. Kong, Bryan V. Hunt, William D. Ramsden
-
Patent number: 6576411Abstract: The invention is directed to a color photothermographic film in which particles comprising an organic silver salt is treated with a dye that functions as a passivating agent. In particular, the present invention involves passivating the organic silver salts with a dye that blocks the surface of the organic silver salt or ligand, resulting in a reduction of speed loss. The invention is also directed to a method of making a photothermographic element to improve raw stock keeping.Type: GrantFiled: November 21, 2001Date of Patent: June 10, 2003Assignee: Eastman Kodak CompanyInventors: Mark E. Irving, Gregg P. Bryant, JoAnn D. Hanna, Mark R. Mis, Nancy B. Liebert
-
Publication number: 20030096203Abstract: A silver halide emulsion sheet for detecting track of charged elementary particles, in which emulsion at least one silver halide emulsion layer and at least one hydrophilic protective colloid layer are applied on both surfaces of a transparent support, and a compound selected from benzotriazoles is contained in said at least one silver halide emulsion layer.Type: ApplicationFiled: September 17, 2002Publication date: May 22, 2003Inventor: Ken-ichi Kuwabara
-
Patent number: 6566034Abstract: A high contrast photographic material is disclosed containing a new type of hydrazine compound characterized in that said hydrazine compound comprises a redox moiety capable of developing an exposed silver halide crystal. Preferably the photographic material is a graphic arts material for pre-press applications. The developed photographic material shows high gradation, and excellent dot quality and exposure latitude.Type: GrantFiled: September 7, 2001Date of Patent: May 20, 2003Assignee: AGFA-GevaertInventors: Johan Loccufier, Stefaan Lingier
-
Patent number: 6566042Abstract: A method for producing an image comprising a step for heat-developing after light exposure a photothermographic material containing elsewhere on a support a non-photosensitive organic acid silver salt, a photosensitive silver halide, a nucleation aid, a binder and at least one compound expressed by the formula (A) below, at a line speed of 140 cm/min or faster: [where R1, R2, R3, X1 and X2 independently represent a hydrogen atom, halogen atom or the like; at least either one of X1 and X2 is a group expressed as —NR4R5, where R4 and R5 independently represents a hydrogen atom, alkyl group or the like] is provided. The method for producing an image of the present invention is successful in raising Dmax (maximum density), suppressing increase in fog during a long-term storage, and suppressing dimensional instability of line width affected by the energy of exposure.Type: GrantFiled: November 22, 2000Date of Patent: May 20, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Takahiro Goto, Minoru Sakai, Katsuyuki Watanabe
-
Patent number: 6558894Abstract: A photothermographic material comprising, on one surface of a support, at least one kind of photosensitive silver halide, a silver salt of an organic acid, a reducing agent for silver ions, and a binder, wherein (1) said material further comprises two or more kinds of organic polyhalogenated compounds, and (2) a melting point of a mixture which consists of the organic polyhalogenated compounds in the same content ratio as the content ratio of said compounds in the photothermographic material is in the range of from −10° C. to 50° C. relative to a heat development temperature for the photothermographic material. The photothermographic material of the present invention shows high sensitivity and superior storability before heat development, and the material can be used for medical images, photoengraving and the like.Type: GrantFiled: January 11, 2001Date of Patent: May 6, 2003Assignee: Fuji Photo Film Co., Ltd.Inventor: Kouta Fukui
-
Patent number: 6558896Abstract: A silver salt photothermographic material is disclosed, comprising on a support (a) a light-insensitive organic silver salt, (b) light-sensitive silver halide and (c) a reducing agent capable of reducing a silver ion of the organic silver salt to silver upon heating, wherein when the exposed and thermally processed photothermographic material having a density of 3.0 have been kept at 50° C. and 50% RH for 120 hr., the photothermographic material exhibits a variation of density from 3.0 being within ±0.2.Type: GrantFiled: October 16, 2001Date of Patent: May 6, 2003Assignee: Konica CorporationInventor: Hideki Komatsu
-
Patent number: 6548233Abstract: Aqueous-based thermally sensitive emulsions and imaging materials include two or more hindered phenol silver ion reducing agents in a non-crystalline reducing agent composition. Such compositions can be provided as evaporated dispersions and can be formulated in aqueous coating compositions to provide thermally developable materials such as thermographic and photothermographic materials.Type: GrantFiled: March 28, 2002Date of Patent: April 15, 2003Assignee: Eastman Kodak CompanyInventors: John W. Boettcher, Paul L. Zengerle, Roger L. Klaus
-
Patent number: 6544725Abstract: A lightsensitive silver halide photographic emulsion comprises silver halide grains, a sensitizing dye having a given maximum absorption wavelength and an organic compound exhibiting no absorption in a visible light region. The addition amount of the organic compound is in the range of 1 to 50 mol % based on the sensitizing dye, and a maximum absorption wavelength of the photographic emulsion exhibited by the sensitizing dye in the presence of the organic compound is at least 2 nm shorter than the maximum absorption wavelength exhibited by the sensitizing dye in the absence of the organic compound.Type: GrantFiled: August 8, 2001Date of Patent: April 8, 2003Assignee: Fuji Photo Film Co., Ltd.Inventor: Kiyoshi Morimoto
-
Publication number: 20030064328Abstract: A photothermographic recording material comprising a support and a photo-addressable thermally developable element, the photo-addressable thermally developable element containing a mixture of a substantially light-insensitive silver salt of a monocarboxylic acid and a substantially light-insensitive compound exclusive of silver succinate represented by formula (I): 1Type: ApplicationFiled: March 19, 2002Publication date: April 3, 2003Applicant: AGFA-GEVAERTInventor: Horst Friedel
-
Patent number: 6534226Abstract: This invention comprises an imaging element comprising an imaging layer having associated therewith a compound of Structure I: In the above Structure I, the substituents are as defined in the application. Such compounds have good reactivity and can by used to block photographically useful compounds such as developing agents until thermally activated under preselected conditions. Compounds according to the present invention are especially useful in color photothermographic imaging elements.Type: GrantFiled: November 20, 2000Date of Patent: March 18, 2003Assignee: Eastman Kodak CompanyInventors: Zbyslaw R. Owczarczyk, David T. Southby, Xiqiang Yang
-
Patent number: 6518007Abstract: This invention relates to a multicolor silver halide photographic element comprising a support and at least one high bromide silver halide emulsion layer comprising low fogging tabular silver halide grains, said element further comprising an antifoggant represented by the following Structure I: R1—SO2—C(R2)R3—(CO)m—(L)n—SG I wherein R1 is an aliphatic or cyclic group, R2 and R3 are independently hydrogen or bromine as long as at least one of them is bromine, L is a divalent linking group, m and n are independently 0 or 1, and SG is a solubilizing group that has a pKa of 8 or less.Type: GrantFiled: December 11, 2001Date of Patent: February 11, 2003Assignee: Eastman Kodak CompanyInventors: Kenneth J. Reed, George J. Burgmaier, John E. Keevert, Roger L. Klaus
-
Patent number: 6514683Abstract: This invention comprises a photographic element comprising at least one light-sensitive silver halide emulsion layer containing a fragmentable electron donating compound of the formula: X—Y′ or a compound which contains a moiety of the formula —X—Y′; wherein X is an electron donor moiety, Y′ is a leaving proton H or a leaving group Y, with the proviso that if Y′ is a proton, a base, &bgr;−, is present in the emulsion layer, and wherein: 1) X—Y′ has an oxidation potential between 0 and about 1.4 V; and 2) the oxidized form of X—Y′ undergoes a bond cleavage reaction to give the radical X• and the leaving fragment Y′; and 3) the radical X• has an oxidation potential ≦−0.Type: GrantFiled: January 5, 2001Date of Patent: February 4, 2003Assignee: Eastman Kodak CompanyInventors: Annabel A. Muenter, Steven P. Szatynski, Sharon G. Johnston
-
Patent number: 6514678Abstract: Aqueous-based photothermographic materials have improved stability to increase in Dmin during aging by including certain water-soluble or water-dispersible antifoggants that have a pKa of 8 or less. These antifoggants are represented by Structure I: R1—SO2—C(R2)R3—(CO)m—(L)n—SG I wherein R1 is an aliphatic or cyclic group, R2 and R3 are independently hydrogen or bromine as long as at least one of them is bromine, L is an aliphatic divalent linking group, m and n are independently 0 or 1, and SG is a solubilizing group having a pKa of 8 or less.Type: GrantFiled: December 11, 2001Date of Patent: February 4, 2003Assignee: Eastman Kodak CompanyInventors: George J. Burgmaier, Roger L. Klaus
-
Patent number: 6511797Abstract: Provided is a photothermographic material having, on one surface of its support, at least one type of photosensitive silver halide grains, a non-photosensitive silver salt of an organic acid, a reducing agent for silver ions, and a binder; which contains an organic polyhalogen compound of the following general formula (I) and in which the silver halide grains have a hexacyano-metal complex of the following general formula (II) in their outermost surfaces: wherein Q represents an alkyl group optionally having one or more substituents, an aryl group optionally having one or more substituents, or a heterocyclic group optionally having one or more substituents; X1 and X2 each independently represent a halogen atom; Z represents a hydrogen atom or an electron-attracting group; Y represents —C(═O)—, —SO— or —SO2—; and n indicates 0 or 1; [M(CN)6]n− (II) wherein M represents Fe, Ru, Os, Co, Rh, Ir, Cr or Re; and n indicates 3 orType: GrantFiled: August 3, 2000Date of Patent: January 28, 2003Assignee: Fuji Photo Film Co., Ltd.Inventor: Shinji Ikari
-
Patent number: 6506546Abstract: This invention comprises an imaging element comprising an imaging layer having associated therewith a compound of Structure I: wherein PUG is a photographically useful group; LINK 1 and LINK 2 are linking groups; TIME is a timing group; T represents t independently selected substituted or unsubstituted alkyl or aryl groups, t is 0, 1, or 2 and if t is 2, the T groups can form a ring; HET is a heterocyclic group which optionally can form a ring with a T group; R12 is hydrogen, substituted or unsubstituted alkyl or substituted or unsubstituted aryl, or R12 can form a ring with a T group or with HET; 1 is 0 or 1; m is 0, 1, or 2; and n is 0 or 1.Type: GrantFiled: December 30, 1999Date of Patent: January 14, 2003Assignee: Eastman Kodak CompanyInventors: Zbyslaw R. Owozarczyk, Xiqiang Yang, David T. Southby
-
Patent number: 6506548Abstract: This invention relates to a silver halide photographic element comprising at least one silver halide emulsion layer and further comprising an antifoggant represented by the following Structure I: wherein R1 is an aliphatic or cyclic group, R2 and R3 are independently hydrogen or bromine as long as at least one of them is bromine, L is a divalent linking group, m and n are independently 0 or 1, and SG is a solubilizing group that has a pKa of 8 or less.Type: GrantFiled: December 11, 2001Date of Patent: January 14, 2003Assignee: Eastman Kodak CompanyInventors: Roger L. Klaus, George J. Burgmaier, Jon N. Eikenberry, Jerzy Z. Mydlarz, Nicholas E. Grzeskowiak
-
Publication number: 20030008248Abstract: This invention comprises a photographic element comprising at least one light-sensitive silver halide emulsion layer containing a fragmentable electron donating compound of the formula: X—Y′ or a compound which contains a moiety of the formula —X—Y′; whereinType: ApplicationFiled: January 5, 2001Publication date: January 9, 2003Applicant: Eastman Kodak CompanyInventors: Annabel A. Muenter, Steven P. Szatynski, Sharon G. Johnston
-
Patent number: 6498003Abstract: A photographic material comprising a support and at least one layer which comprises at least one spectrally sensitised silver halide emulsion, characterised in that the material contains at least one compound of formula and/or wherein R1 denotes H, alkyl, aryl, aralkyl, alkenyl, heterocyclyl, R2 denotes OH, NH2, NHR7, NR8R9 or R1 together with R2, denotes the atoms necessary for the completion of a heteroaliphatic ring, R3 denotes OH, NH2, NHR7, NR8R9, R4 denotes H, alkyl, aryl, aralkyl, alkenyl, heterocyclyl, R5, R6 independently of each other, denote OH, NH2, NHR10, NR11R12, or R4 together with R5, or R4 together with R6, denote the atoms necessary for the completion of a heteroaliphatic ring, and the R5 or R6 radical, which is not part of a ring, denotes OH, NH2, NHR10 or NR11R12, R7, R10 denote alkyl, aryl, aralkyl, heterocyclyl, R8, R9 independently of each other, denote alkyl, aryl, aralkyl, heterocyclyl, or R8 together with R9, denotes the atoms necessary fType: GrantFiled: July 26, 2001Date of Patent: December 24, 2002Assignee: Agfa-GevaertInventors: Peter Bergthaller, Jörg Siegel, Hans-Ulrich Borst
-
Patent number: 6498001Abstract: A spectrally sensitized photographic silver halide emulsion, characterized in that after precipitation at least one compound of formula is added to the emulsion, wherein R1 denotes alkyl, aryl, aralkyl, alkenyl or heterocyclyl; R2 denotes H, alkyl, aryl, heterocyclyl, amino or alkoxy; R3 denotes H, alkyl, aryl, aralkyl or heterocyclyl; D denotes —OH or —NR4R5; X denotes O or N—R6; R4 denotes H, alkyl, aryl, aralkyl, alkenyl or heterocyclyl; R5: denotes H, alkyl, aryl, aralkyl, alkenyl or heterocyclyl; R6: denotes H, alkyl, aryl, aralkyl, alkenyl, acyl, alkoxycarbonyl, carbamoyl or heterocyclyl, the aforementioned alkyl, aryl, aralkyl, alkenyl, heterocyclyl, amino, alkoxy, acyl, alkoxycarbonyl and carbamoyl groups can be substituted, and any two of the radicals R1 to R6 can together form a heterocyclic ring, such as a pyrrolidine, piperidine, perhydroazepine, piperazine, morpholine or thiomorpholine ring, for example; as well as a photographic material comprising aType: GrantFiled: July 24, 2001Date of Patent: December 24, 2002Assignee: AGFA-GevaertInventors: Peter Bergthaller, Jörg Siegel, Hans-Ulrich Borst, Ralf Büscher, Ulrich Nickel
-
Patent number: 6498004Abstract: This invention provides a photographic element comprising at least one silver halide emulsion layer in which the silver halide is sensitized with a compound of the formula (a): &Dgr;−(t)m−XY′ (a) XY′−(t)m−&Dgr; (b) &Dgr;−(t)m−XY′−(t)m−&Dgr; (c) wherein &Dgr; is protective group that is eliminated during development of the photographic element, t is a timing group, m is an integer from 0 to 3, and XY′ is a fragmentable electron donor moiety in which X is an electron donor group and Y′ is a leaving proton H or a leaving group Y, with the proviso that if Y′ is a proton, a base, &bgr;−, is present in the emulsion or is covalently linked directly or indirectly to X, and wherein: 1) X—Y′ has an oxidation potential between 0 and about 1.Type: GrantFiled: December 28, 2000Date of Patent: December 24, 2002Assignee: Eastman Kodak CompanyInventors: Jerome R. Lenhard, Annabel A. Muenter, Stephen A. Godleski, Paul A. Zielinski, Deepak Shukla, Donald R. Diehl
-
Patent number: 6497999Abstract: The invention is directed to a color photothermographic film in which particles comprising an organic silver salt is treated with a passivating agent. In particular, the present invention involves passivating the organic silver salts with an organic adsorbate that blocks the surface of the organic silver salt or ligand, resulting in a reduction of speed loss. The invention is also directed to a method of making a photothermographic element to improve raw stock keeping.Type: GrantFiled: November 21, 2001Date of Patent: December 24, 2002Assignee: Eastman Kodak CompanyInventors: Gregg P. Bryant, JoAnn D. Hanna, Nancy B. Liebert, Mark E. Irving
-
Patent number: 6498002Abstract: A photographic material comprising a support and at least one at least one layer which comprises at least one spectrally sensitized silver halide emulsion, characterized in that the material contains at least one compound of formula wherein X denotes sulphur or selenium, R1 denotes aryl or heterocyclyl, R2 denotes alkyl, alkenyl, alkynyl, aralkyl or hetarylalkyl, R3 denotes alkyl, alkenyl, aryl, aralkyl, hetaryl or hetarylalkyl, and R4 denotes H, alkyl, alkenyl, aryl, aralkyl, hetaryl or hetaralkyl, or R3, together with R4, denotes the remaining atoms of a carbocyclic or heterocyclic ring, is distinguished by increased spectral sensitivity, a high sensitivity/fogging ratio and a good shelf life under humid conditions.Type: GrantFiled: July 25, 2001Date of Patent: December 24, 2002Assignee: AGFA-GevaertInventors: Peter Bergthaller, Jörg Siegel, Hans-Ulrich Borst
-
Patent number: 6492102Abstract: A red or infrared sensitive silver halide emulsion is disclosed, comprising at least a compound represented by the following formula. A photographic material containing the emulsion is also disclosed.Type: GrantFiled: August 11, 2000Date of Patent: December 10, 2002Assignee: Konica CorporationInventors: Nobuaki Kagawa, Noriyasu Kita
-
Publication number: 20020177084Abstract: The present invention relates to a silver halide color photographic light-sensitive material wherein at least one of light-sensitive silver halide emulsion layers includes a silver halide emulsion having a silver chloride content of at least 95 mol % and a silver iodide content of 0.05 mol % to 0.75 mol % and/or a silver bromide content of 0.05 mol % to 4.Type: ApplicationFiled: February 26, 2002Publication date: November 28, 2002Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Atsushi Matsunaga, Tadashi Inaba, Shinichi Ichikawa
-
Patent number: 6485898Abstract: A photothermographic material comprising a defined amount of a compound represented by the following general formula as a reducing agent is disclosed. In the following general formula, R1 and R1′ each independently represent an alkyl group, at least one of which is a secondary or tertiary alkyl group; R2 and R2′ each independently represent hydrogen atom or a group that can be a substituent on benzene ring; L represents —S— group or a —CH(R3)— group where R3 represents hydrogen atom or an alkyl group; and X and X′ each independently represent hydrogen atom or a group that can be a substituent on benzene ring. The photothermographic material is characterized by providing sufficient image density by heat development, and showing good silver color tone and little change with time after the development.Type: GrantFiled: January 5, 2001Date of Patent: November 26, 2002Assignee: Fuji Photo Film Co., Ltd.Inventors: Yasuhiro Yoshioka, Kouta Fukui, Makoto Suzuki
-
Patent number: 6482582Abstract: Disclosed in an image recording material comprising, on a support, a photosensitive silver halide, a reducing agent, a binder and a compound represented by the following Formula (1): wherein, in Formula (1), R1 and R2 each independently represent a substituent, R1 and R2 may be bonded to each other to form a ring, X represents a halogen atom, L represents a methylene group, m represents an integer of 0-7, Y represents a divalent bridging group, n represents 0 or 1 and Z represents a residue derived from a photographically useful compound. This image recording material exhibits high sensitivity, low fog and good storage stability, and is stable against fluctuation of development conditions.Type: GrantFiled: July 24, 2001Date of Patent: November 19, 2002Assignee: Fuji Photo Film Co., Ltd.Inventors: Katsuyuki Watanabe, Masaru Takasaki
-
Patent number: 6482583Abstract: Provided is a photothermographic material having, on one surface of its support, at least one type of photosensitive silver halide grains, a non-photosensitive silver salt of an organic acid, a reducing agent for silver ions, and a binder; which contains a compound of the following general formula (I) and in which the silver halide grains have a hexacyano-metal complex of the following general formula (II) in their outermost surfaces: wherein R11, R12, R13 and R14 may be the same or different, and each independently represents a hydrogen atom, a halogen atom, a hydroxyl group, an amino group, a nitro group, a cyano group, a carboxyl group or its salt, a sulfo group or its salt, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, or a group of R15—D—; where R15 represents a hydrogen atom, a halogen atom, a hydroxyl group, an amino group, a nitro group, a cyano group a carboxyl group or its salt, a sulfo group or its salt, an alkyl group, an alkType: GrantFiled: August 3, 2000Date of Patent: November 19, 2002Assignee: Fuji Photo Film Co., Ltd.Inventor: Shinji Ikari
-
Patent number: 6475710Abstract: A photothermographic material is disclosed, comprising a light-sensitive silver halide, an organic silver salt, a reducing agent, a thiuronium salt and a binder, wherein the photothermographic material further contains at least one of compounds represented by formulas such asType: GrantFiled: January 17, 2001Date of Patent: November 5, 2002Assignee: Konica CorporationInventors: Shinji Kudo, Keiko Chigusa, Hiroshi Kashiwagi
-
Patent number: 6475715Abstract: A photothermographic material is disclosed, comprising on a support an organic silver salt, a light-sensitive silver halide, a reducing agent, and a compound represented by the following formula, 6-aryl-2,4-bis(tribromomethyl)-s-triazine or a 6-heteroaryl-2,4-bis(tribromomethyl)-s-triazine.Type: GrantFiled: February 13, 2001Date of Patent: November 5, 2002Assignee: Konica CorporationInventors: Katsura Hirai, Kiyoshi Fukusaka
-
Patent number: 6472132Abstract: There is disclosed a silver halide photographic light-sensitive material comprising at least one compound selected from the group consisting of the compounds represented by the following formula (1), (2) or (3): wherein R1 represents a phenyl, aromatic heterocyclic or aliphatic group, having at least one electron-withdrawing group as a substituent, PUG represents a residue of a development inhibitor, Y1 and Z1 respectively represent a substituent which is substitutable on a benzene ring, and n1 and p1 denote integers from 0 to 4, Ar represents an aryl group or an aromatic heterocyclic group, PUG represents a residue of a development inhibitor, TIME represents a timing group and t denotes 0 or 1, A represents a connecting group, m denotes an integer from 2 to 6.Type: GrantFiled: September 18, 2000Date of Patent: October 29, 2002Assignee: Fuji Photo Film Co., Ltd.Inventors: Kohzaburoh Yamada, Hirokazu Kyota, Masahiko Taniguchi, Takashi Hoshimiya, Tetsuo Yamaguchi, Ken-ichi Kuwabara, Toshihide Ezoe
-
Patent number: 6472135Abstract: This invention relates to a silver halide photographic element comprising at least one silver halide emulsion, said silver halide element further comprising an amido compound represented by Formula 1 wherein INH is a development inhibitor; LINK is a linking or timing group and m is 0, 1 or 2; and R1 and R2 independently represents an aliphatic, aromatic or heterocyclic group, or R1 and R2 together with the nitrogen to which they are attached represent the atoms necessary to form a 5 or 6 membered ring or multiple ring system, or R1 and R2 are independently a —C(═O)(LINK)m—INH group, or are substituted with an —NR3aC(═O)—(LINK)m—INH group, with R3a being defined the same as R1 or R2; and wherein the compound of Formula 1 does not substantially react with oxidized developer to release INH; and a reductone compound represented by Formula 2 wherein R7 and R8 are the same or different, and may represent H, alkyl, cycloalkyl, aryl, or anType: GrantFiled: June 13, 2000Date of Patent: October 29, 2002Assignee: Eastman Kodak CompanyInventors: Steven P. Szatynski, James H. Reynolds, Lillian M. Kellogg, George J. Burgmaier
-
Patent number: 6472133Abstract: This invention relates to a silver halide photographic element comprising at least one silver halide emulsion layer containing a dye-forming coupler which reacts with an oxidized color developing agent to form dye, said silver halide element further comprising an amido compound of Formula I wherein INH is a development inhibitor; LINK is a linking or timing group and m is 0, 1 or 2; and wherein INH is a development inhibitor; R1 and R2 independently represent an aliphatic, aromatic or heterocyclic group, or R1 and R2 together with the nitrogen to which they are attached represent the atoms necessary to form a 5 or 6 membered ring or multiple ring system, or R1 and R2 are independently a —C(═O)(LINK)m—INH group, or are substituted with an —NR3aC(═O)—(LINK)m—INH group, with R3a being defined the same as R1 or R2, and wherein the compound of Formula I does not substantially react with oxidized developer to release INH.Type: GrantFiled: June 13, 2000Date of Patent: October 29, 2002Assignee: Eastman Kodak CompanyInventors: James H. Reynolds, Steven P. Szatynski, Stephen P. Singer, George J. Burgmaier, Janet N. Younathan, Lillian M. Kellogg
-
Patent number: 6472134Abstract: A silver halide photographic element comprising at least one silver halide emulsion, said silver halide element further comprising an amido compound represented by Formula 1 wherein INH is a development inhibitor; LINK is a linking or timing group and m is 0, 1 or 2; and R1 and R2 independently represents an aliphatic, aromatic or heterocyclic group, or R1 and R2 together with the nitrogen to which they are attached represent the atoms necessary to form a 5 or 6 membered ring or multiple ring system; or R1 and R2 are independently a —C(═O)(LINK)m—INH group, or are substituted with an —NR3aC(═O)—(LINK)m—INH group, with R3a being defined the same as R1 or R2, and wherein the compound of Formula I does not substantially react with oxidized developer to release INH; and a fragmentable electron donor compound of the formula X—Y′ or a compound which contains a moiety of the formula —X—Y′; wherein X is an electron donorType: GrantFiled: June 13, 2000Date of Patent: October 29, 2002Assignee: Eastman Kodak CompanyInventors: Steven P. Szatynski, James H. Reynolds, Annabel A. Muenter, George J. Burgmaier
-
Patent number: 6468730Abstract: Image recording materials, especially photothermographic light-sensitive image recording materials, that comprise a compound of formula (1) to acquire excellent image storage stability: wherein X1 and X2 each represent a halogen atom; X3 represents a hydrogen atom, a halogen atom or a univalent substituent group; L represents a divalent organic group; Y represents a divalent organic group containing a hetero atom, or a single bond; and Z represents an acidic functional group or a salt thereof.Type: GrantFiled: June 11, 1999Date of Patent: October 22, 2002Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshiki Fujiwara, Rikio Inoue
-
Patent number: 6465162Abstract: Photothermographic materials provide images having improved stability from browning. The improved image stability is achieved by including an image stabilizing compound in the support, a backside layer on the support or in a layer associated with a backside layer. The most useful backside layer for this purpose is an antihalation layer. These compounds are present in the backside layer in an amount sufficient to provide an increase in blocking power of at least 0.01.Type: GrantFiled: August 15, 2000Date of Patent: October 15, 2002Assignee: Eastman Kodak CompanyInventors: Steven H. Kong, Kumars Sakizadeh
-
Patent number: 6458525Abstract: A method for preparing a photothermographic material comprising an organic silver salt is disclosed, comprising a step of treating the organic silver salt under a gas atmosphere containing an inert gas having a volume fraction of not less than 85% or under a gas atmosphere containing oxygen gas having a volume fraction of not more than 15%. Packaging the photothermographic material under the inert gas atmosphere is also disclosed.Type: GrantFiled: November 3, 2000Date of Patent: October 1, 2002Assignee: Konica CorporationInventors: Hideki Takiguchi, Hitoshi Adachi, Hideki Hoshino, Shu Nishiwaki
-
Patent number: 6458505Abstract: A photothermographic material having, on a support, an image-forming layer that contains at least a non-photosensitive silver salt of an organic acid, a photosensitive silver halide, a nucleating agent and a binder, and at least one protective layer outer than the image-forming layer on the support, wherein the protective layer contains at least one compound selected from the group consisting of the compounds represented by the following formula (1) and the compounds represented by the following formula (2) as emulsion dispersion or solid dispersion: C—(Y)n—CZ1Z2X Formula (1) wherein, in the formula (1), Q represents an alkyl group, an aryl group or a heterocyclic group, which groups may have one or more substituents, Y represents a divalent bridging group, n represents 0 or 1, Z1 and Z2 represents a halogen atom, and X represents hydrogen atom or an electron-withdrawing group, wherein, in the formula (2), M represents hydrogen atom or a k-valent cation; k representsType: GrantFiled: March 22, 2001Date of Patent: October 1, 2002Assignee: Fuji Photo Film Co., Ltd.Inventor: Tadashi Ito
-
Patent number: 6458522Abstract: A silver halide photographic light-sensitive material includes a compound selected from: (1) a quaternary nitrogen or phosphorus salt compound, having 20 or more of total recurring units consisting of an ethyleneoxy group and/or a propyleneoxy group; (2) a quaternary salt compound represented by formula (A): wherein Q represents nitrogen or phosphorus, R1, R2 and R3 represent an alkyl, aryl, alkenyl, alkynyl, or heterocyclic group, L1 represents an alkylene group, Y represents —C(═O) or —SO2—, L2 represents a divalent connecting group having at least one hydrophilic group, Xn− represents an n-valent counter anion, n being an integer of 1 to 3; and (3) a quaternary salt compound represented by formula (B): wherein A represents an organic moiety necessary to complete a nitrogen-containing aromatic heterocyclic ring. L2 represents a divalent connecting group having at least one hydrophilic group that divides L2.Type: GrantFiled: September 18, 2000Date of Patent: October 1, 2002Assignee: Fuji Photo Film Co., Ltd.Inventors: Masahiko Taniguchi, Kohzaburoh Yamada, Ken-ichi Kuwabara, Tetsuo Yamaguchi
-
Patent number: 6451520Abstract: A colour photographic silver halide material comprising a support and at least one silver halide emulsion layer which is deposited thereon and which contains at least one colour coupler, characterised in that said layer also contains a compound of formula (I) wherein R1 denotes alkyl, aryl, aralkyl or hetaryl, R2 denotes H or R1, or R1 and R2 together denote the remaining members of a heterocyclic ring, R3, R4, independently of each other, denote aryl or hetaryl or together denote the remaining members of a phenanthrene ring which is condensed-on in the 9,10-position, wherein R1 can also be H if R3 and R4 together form a phenanthrene ring, is distinguished by improved granularity.Type: GrantFiled: July 27, 2001Date of Patent: September 17, 2002Assignee: Agfa-GevaertInventors: Heinrich Odenwälder, Hans Langen, Uwe Dahlhaus
-
Patent number: 6444392Abstract: A black and white graphic arts film comprising a support having thereon at least one emulsion layer, said emulsion layer comprising: a trinuclear merocyanine spectral sensitising dye; 2-methylthio-4-hydroxy-6-methyl-1,3,3a,7-tetraazaindene (SMe-TAI); and a photosensitive silver halide.Type: GrantFiled: August 10, 2001Date of Patent: September 3, 2002Assignee: Eastman Kodak CompanyInventor: Julie Baker
-
Patent number: 6440655Abstract: A silver halide photographic element comprising at least one silver halide emulsion layer containing a dye-forming coupler which reacts with an oxidized color developing agent to form dye, said silver halide element further comprising a polyester support and an amido compound of Formula I wherein INH is a development inhibitor; LINK is a linking or timing group and m is 0, 1 or 2; R1 and R2 independently represent an aliphatic, aromatic or heterocyclic group, or R1 and R2 together with the nitrogen to which they are attached represent the atoms necessary to form a 5 or 6 membered ring or multiple ring system, or R1 and R2 are independently a —C(═O)(LINK)m—INH group, or are substituted with an —NR3aC(═O)—(LINK)m—INH group, with R3a being defined the same as R1 or R2, and wherein the compound of Formula I does not substantially react with oxidized developer to release INH.Type: GrantFiled: June 13, 2000Date of Patent: August 27, 2002Assignee: Eastman Kodak CompanyInventors: Steven P. Szatynski, James H. Reynolds, Janet N. Younathan, George J. Burgmaier
-
Patent number: 6440618Abstract: This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of Structure I: In the above Structure I, the substituents are as defined in the application, wherein B is a six-membered heteroaromatic ring. Such compounds have good reactivity and can by used to block photographically useful compounds such as developing agents until thermally activated under preselected conditions. Compounds according to the present invention are especially useful in color photothermographic imaging elements.Type: GrantFiled: November 13, 2000Date of Patent: August 27, 2002Assignee: Eastman Kodak CompanyInventors: Wojciech K. Slusarek, Xiqiang Yang, David H. Levy
-
Patent number: 6432627Abstract: A photothermographic element has on a support a photosensitive layer containing an emulsion of silver halide fine grains having a mean equivalent spherical diameter of 10-50 nm. (1) The silver halide emulsion has been formed independent of an organic fatty acid silver salt rather than by partial halogen conversion of a non-photosensitive organic silver salt, and mixed with the organic silver salt before coating. (2) A reducing agent for silver ion is contained. (3) The silver halide fine grains have been chemically sensitized in the presence of a spectral sensitizing dye. The element is improved in sensitivity and restrained from fog increase during storage in daylight after processing.Type: GrantFiled: April 7, 1999Date of Patent: August 13, 2002Assignee: Fuji Photo Film Co., Ltd.Inventor: Seiji Yamashita
-
Patent number: 6428947Abstract: This invention comprises multicolor photographic element comprising a support bearing a cyan dye image-forming unit comprising at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of said red-sensitive or green-sensitive layers comprises a fragmentable electron donating compound of the formula: X—Y′ or a compound which contains a moiety of the formula —X—Y′; wherein the speed gain deriving from addition of said compound to said layer is less than or equal to 0.Type: GrantFiled: January 5, 2001Date of Patent: August 6, 2002Assignee: Eastman Kodak CompanyInventors: Sharon G. Johnston, Annabel A. Muenter, Steven P. Szatynski, Jerome R. Lenhard
-
Patent number: 6426179Abstract: This invention relates to an imaging element, such as a photographic or photothermographic element comprising a silver halide emulsion layer, wherein the element also comprises a compound of Structure I: wherein the substituents are as defined in the specification.Type: GrantFiled: December 30, 1999Date of Patent: July 30, 2002Assignee: Eastman Kodak CompanyInventors: Wojciech K. Slusarek, Xiqiang Yang, Mark E. Irving, David H. Levy