Organic Silver Compound Containing Patents (Class 430/618)
  • Patent number: 7144692
    Abstract: The invention provides a photothermographic material having, on both sides of a support, an image forming layer including at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent, and a binder, which is to be exposed with X-rays using a fluorescent intensifying screen, wherein (1) a coating amount of the photosensitive silver halide per one side is from 0.01 g/m2 to 0.45 g/m2 in terms of silver amount; and (2) a crossover (%) is 30% or more, or when parallel light having the same wavelength as a main emission peak wavelength of the fluorescent intensifying screen is incident perpendicular to the surface of the photothermographic material, the parallel light component of transmitted light comprises 5% or more of the incident light. A photothermographic material for medical use having high sensitivity and high image quality is provided.
    Type: Grant
    Filed: June 13, 2005
    Date of Patent: December 5, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Takeshi Funakubo
  • Patent number: 7144693
    Abstract: A photothermographic material comprising a support and an image-forming layer, a non-photosensitive intermediate layer A, and an outermost layer provided in this order on at least one side of the support, wherein the image-forming layer comprises a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent, and a binder, and at least 50 mass % of a binder in the non-photosensitive intermediate layer A is a polymer latex having a film water absorption of 5 % or lower.
    Type: Grant
    Filed: September 21, 2005
    Date of Patent: December 5, 2006
    Assignee: FujiFilm Corporation
    Inventor: Takayoshi Oyamada
  • Patent number: 7144694
    Abstract: A photothermographic imaging material including a support; an image forming layer containing an organic silver salt, a photosensitive silver halide, a binder and a silver ion reducing agent, the image forming layer being provided on the support; and a cyan coloring leuco dye.
    Type: Grant
    Filed: October 28, 2005
    Date of Patent: December 5, 2006
    Assignee: Konica Minolta Holdings, Inc.
    Inventors: Hiroshi Kashiwagi, Narito Goto
  • Patent number: 7141361
    Abstract: Buried backside conductive layers with increased conductive efficiency can be provided for thermally developable materials using a specific organic solvent mixture to coat a protective overcoat directly disposed over the conductive layer. This organic solvent mixture comprises an alcohol in which one or more film-forming polymers used in the formulation are soluble at room temperature. The alcohol is used in an amount of more than 10 and up to 90 weight % of the organic solvent mixture.
    Type: Grant
    Filed: February 8, 2005
    Date of Patent: November 28, 2006
    Assignee: Eastman Kodak Company
    Inventors: Thomas J. Ludemann, Aparna V. Bhave, Gary E. LaBelle, Darlene F. Philip, Samuel Chen
  • Patent number: 7138224
    Abstract: A photothermographic material containing a support having on one side of the support a photosensitive layer containing: photosensitive silver halide grains; and a compound represented by Formula (1) or Formula (2): wherein the symbols in Formulas (1) and (2) are indicated in the specification.
    Type: Grant
    Filed: September 29, 2005
    Date of Patent: November 21, 2006
    Assignee: Konica Minolta Medical & Graphic, Inc.
    Inventors: Kiyoshi Fukusaka, Osamu Ishige, Rie Sakuragi
  • Patent number: 7138225
    Abstract: A silver salt photothermographic dry imaging material wherein said material has photographic speeds (1) and (2) determined based on the predetermined conditions and the photographic speed (2) is not more than 1/10 of the photographic speed (1), and the coefficient of determination value R2 of the linear regression line is 0.998–1.000, which is obtained from the predetermined density points having a* and b* arranged in two-dimensional coordinates in which a* is used as the abscissa and b* is used as the coordinate of the CIE 1076 (L*a*b*) color space, b* of the intersection point of the linear regression line with the ordinate is ?5–5, and gradient (a*/b*) is 0.7–2.5.
    Type: Grant
    Filed: September 2, 2004
    Date of Patent: November 21, 2006
    Assignee: Konica Minolta Medical & Graphic, Inc.
    Inventors: Tetsuya Suzuki, Hideki Takiguchi, Toshiyuki Marui, Kazuhiko Fujikura, Kazuhito Ihara, Yasuo Taima, Kenji Ohnuma, Hiroto Ito
  • Patent number: 7135277
    Abstract: Provided are a photothermographic material which includes, on at least one side of a support, an image forming layer containing at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent, and a binder, and is X-ray exposed with a fluorescent intensifying screen, wherein (1) the photosensitive silver halide includes tabular grains having a mean aspect ratio of 2 to 100 and a mean equivalent spherical diameter of 0.3 ?m to 10 ?m, (2) an exposure value necessary for obtaining an image density of fog+0.
    Type: Grant
    Filed: June 3, 2005
    Date of Patent: November 14, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Tomoyuki Ohzeki
  • Patent number: 7135276
    Abstract: The invention provides a photothermographic material containing a tabular photosensitive silver halide having an average silver iodide content of 40 mol % or higher, 50% or more of a total projected area of the photosensitive silver halide being occupied by tabular grains having an aspect ratio of 2 or more, the photosensitive silver halide grains having a mean equivalent spherical diameter of from 0.2 ?m to 5 ?m and a variation coefficient of an equivalent spherical diameter distribution of 30% or less. Further, a method for preparing the photosensitive silver halide used in the photothermographic material is characterized in that grains are formed in the presence of at least one selected from a silver halide solvent and an amino group-modified gelatin. A high-sensitivity photothermographic material exhibiting a low fog and a high optical density is provided.
    Type: Grant
    Filed: October 6, 2004
    Date of Patent: November 14, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Fumito Nariyuki
  • Patent number: 7132227
    Abstract: A silver salt photothermographic dry imaging material including a support provided thereon a light-sensitive layer containing an organic silver salt, light-sensitive silver halide particles and a reducing agent, wherein the dry imaging material contains organic solid lubricant particles having an average particle diameter of 1 to 30 ?m.
    Type: Grant
    Filed: June 15, 2005
    Date of Patent: November 7, 2006
    Assignee: Konica Minolta Medical & Graphic, Inc.
    Inventors: Kiyokazu Morita, Kenji Ohnuma
  • Patent number: 7132226
    Abstract: A photothermographic material comprising a support, and an image-forming layer and a non-image-forming layer provided on the support, wherein the image-forming layer comprises a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent, and a binder; the non-image-forming layer includes a slipping agent having a melting point of 80° C. to 120° C.; the coefficient (K1) of dynamic friction measured at a velocity of 0.1 cm/sec and the coefficient (K2) of dynamic friction measured at a velocity of 10 cm/sec have a relation represented by formula (1): Formula (1) 1.20>K1/K2>0.90. Also provided is an image-forming method using the photothermographic material.
    Type: Grant
    Filed: September 22, 2005
    Date of Patent: November 7, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Katsutoshi Yamane
  • Patent number: 7132229
    Abstract: A photothermographic material having an image forming layer containing at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent, and a binder, and a non-photosensitive layer on at least one side of a support, in which the binder is a hydrophilic binder, the non-photosensitive layer contains gelatin or a gelatin derivative, the reducing agent is a compound represented by the following formula (R), and at least one compound represented by the following formula (I) or (II) is contained: (wherein in formula (R), R11 and R11? each independently represent an alkyl group and at least one of R11 and R11? is a secondary or tertiary alkyl group); (wherein in the formula (I), Q represents an atomic group necessary for forming a 5 or 6-membered imide ring); and (wherein in the formula (II), R5 independently represents a hydrogen atom or a substituent, r represents 0, 1, 2, 3 or 4, and X represents O, S, Se or N(R6)).
    Type: Grant
    Filed: July 13, 2005
    Date of Patent: November 7, 2006
    Assignee: Fuji Photo Film Co., Ltd
    Inventor: Kouta Fukui
  • Patent number: 7132228
    Abstract: Solid particle dispersions of certain ascorbic acid esters are prepared in the presence of at least 0.5 and less than 50 weight % of a particle growth modifier based on the weight of the ascorbic acid ester. The particle growth modifier is an alkyl carboxylic acid having from 8 to 22 carbon atoms, an alkyl ester of glycerol wherein the alkyl moiety has from 8 to 22 carbon atoms, or a stereoisomer of the ascorbic acid ester. The resulting aqueous solid particle dispersion can be used in various thermally developable materials including thermographic and photothermographic materials.
    Type: Grant
    Filed: September 7, 2004
    Date of Patent: November 7, 2006
    Assignee: Eastman Kodak Company
    Inventors: Mary C. Brick, William D. Ramsden, Doreen C. Lynch
  • Patent number: 7129033
    Abstract: A photothermographic material having, on at least one side of a support, an image forming layer containing at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent, and a binder, and an X-ray image forming method using the same, wherein 50% or more of a total projected area of the photosensitive silver halide is occupied by tabular grains having an aspect ratio of 2 or more, and the grains have at least one epitaxial junction portion having a multifold structure. A photothermographic material with high sensitivity and excellent storage stability, and an image forming method using the material are provided.
    Type: Grant
    Filed: August 4, 2005
    Date of Patent: October 31, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Takayoshi Mori
  • Patent number: 7125656
    Abstract: Organic silver salt particles are manufacture by mixing an aqueous solution containing silver ions with an aqueous solution containing an organic acid alkali salt to form organic silver salt particles, using a mixing device in which plural supply tubes are connected to a discharge tube so that an axis of the discharge tube and axes of the supply tubes coincide at a single point.
    Type: Grant
    Filed: November 24, 2004
    Date of Patent: October 24, 2006
    Assignee: Konica Minolta Medical & Graphic, Inc.
    Inventor: Satoshi Ito
  • Patent number: 7122300
    Abstract: A photothermographic material comprising a support, and an image-forming layer and a non-photosensitive layer provided on a surface of the support, wherein the image-forming layer and the non-photosensitive layer are adjacent to each other; the image-forming layer includes a photosensitive silver halide, a first non-photosensitive organic silver salt, a first reducing agent, a polyhalogen compound and a binder; and the non-photosensitive layer includes a second non-photosensitive organic silver salt.
    Type: Grant
    Filed: March 9, 2005
    Date of Patent: October 17, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yasuhiro Yoshioka
  • Patent number: 7115358
    Abstract: The present invention provides a black and white photothermographic material having, on at least one side of a support, an image forming layer containing at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent for silver ions, and a binder, as well as an image forming method. The black and white photothermographic material is characterized in that 1) the non-photosensitive organic silver salt includes at least one compound selected from the group consisting of a silver salt of an azole compound and a silver salt of a mercapto compound, and 2) the photosensitive silver halide has a spectral sensitizing dye in the form of a multilayer adsorbed on its surface. According to the invention, an improved black and white photothermographic material and image forming method realizing high sensitivity, favorable gradation, and less dependence on developing process conditions are provided.
    Type: Grant
    Filed: May 20, 2005
    Date of Patent: October 3, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takeshi Funakubo, Takeshi Suzumoto
  • Patent number: 7112398
    Abstract: This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of Structure I: wherein: the substituents are as defined in the application.
    Type: Grant
    Filed: January 9, 2004
    Date of Patent: September 26, 2006
    Assignee: Eastman Kodak Company
    Inventors: Wojciech K. Slusarek, Xiqiang Yang, Mark E. Irving, David H. Levy, Jared B. Mooberry, James J. Seifert, James H. Reynolds, Lyn M. Irving
  • Patent number: 7112401
    Abstract: A photothermographic material comprising a support body provided on or above at least one surface thereof with an image forming layer, containing at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and binder, and a non-photosensitive layer, wherein: 1) 50% or more of the binder in the image forming layer is hydrophilic binder; 2) a ratio of the non-photosensitive organic silver salt to the hydrophilic binder is from 0.6 to 1.4 by mass; and 3) 70% or more of binder in the non-photosensitive layer is hydrophilic binder.
    Type: Grant
    Filed: September 8, 2005
    Date of Patent: September 26, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Hajime Nakagawa
  • Patent number: 7108965
    Abstract: A photothermographic material for blue light exposure that has a good coating surface condition and an image forming method for use with the photothermographic material are provided. The photothermographic material includes a support, and an image forming layer provided on at least one side of the support. The image forming layer contains at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder. The photothermographic material is characterized in that: (1) a silver iodide content of the photosensitive silver halide is not less than 40 mole %; (2) the binder is a hydrophilic binder; (3) the image forming layer contains a silver iodide complexing agent; and (4) the image forming layer contains, as a silver carrier, at least one compound represented by the following Formula (I) or (II): (wherein Q represents an atomic group that is necessary to form a 5 or 6-membered imide ring).
    Type: Grant
    Filed: September 12, 2005
    Date of Patent: September 19, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takayoshi Mori, Kazutaka Takahashi
  • Patent number: 7105283
    Abstract: The present invention provides a black and white photothermographic material having, on at least one surface of a support, an image forming layer containing at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent for silver ions, and a binder, wherein 70% or more of a total projected area of the photosensitive silver halide is occupied by tabular grains having an aspect ratio of 2.5 or more, a mean projected area equivalent diameter of 0.5 ?m to 8 ?m, and a mean grain thickness of 0.02 ?m to 0.2 ?m, and a ratio of a number of sites capable of forming a development initiation point on a corner portion or a fringe portion of the photosensitive silver halide grain to all development initiation points is 50% or more. Also disclosed is an image forming method of forming a radiation image by using a fluorescent intensifying screen.
    Type: Grant
    Filed: December 10, 2004
    Date of Patent: September 12, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Tomoyuki Ohzeki
  • Patent number: 7105284
    Abstract: Thermally developable materials including photothermographic and thermographic materials having an outermost backside layer that includes amorphous silica particles having a narrow particle size distribution. The narrower particle size distribution provides reduced haze and increased surface roughness that reduces blocking and machine feeding at comparable weight percent. The materials can also include conductive layers underneath the outermost backside layer.
    Type: Grant
    Filed: March 17, 2005
    Date of Patent: September 12, 2006
    Assignee: Eastman Kodak Company
    Inventors: Darlene F. Philip, Thomas J. Ludemann, Roland J. Koestner, Gary E. LaBelle
  • Patent number: 7097962
    Abstract: A photothermographic imaging material containing a support having thereon light-insensitive organic silver salt grains, photosensitive silver halide grains, a reducing agent for silver ions and a binder, wherein, (i) each of the organic silver salt grains has a structure having different silver ion dissociation constants at a surface portion and at an inner portion of the grain; (ii) each of the silver halide grains produces a larger number of latent images in a surface portion than in an inner portion of the grain by exposure to light; (iii) each of the silver halide grains produces a larger number of latent images in the inner portion than in the surface portion of the grain after being subjected to a thermal development; and (iv) a surface photographic speed of each of the silver halide grains decreases after being subjected to the thermal development.
    Type: Grant
    Filed: October 19, 2004
    Date of Patent: August 29, 2006
    Assignee: Konica Minoltn Medical & Graphic, Inc.
    Inventors: Hideki Komatsu, Hideki Takiguchi
  • Patent number: 7097963
    Abstract: Black-and-white, aqueous-based, silver halide-containing photothermographic materials have increased stability after imaging with the incorporation of at least 0.0002 mol/m2 of a halogen-substituted tetraazaindene compound.
    Type: Grant
    Filed: April 18, 2005
    Date of Patent: August 29, 2006
    Assignee: Eastman Kodak Company
    Inventors: Chaofeng Zou, Kumars Sakizadeh, George J. Burgmaier, Roger L. Klaus
  • Patent number: 7097961
    Abstract: A substantially light-insensitive black and white monosheet thermographic recording material comprising a support and a thermosensitive element, said thermosensitive element containing a substantially light-insensitive organic silver salt, an organic reducing agent therefor in thermal working relationship therewith, at least one binder and at least one stabilizer represented by formula (I): wherein R1, R2, R3 and R4 are independently selected from the group consisting of a hydrogen atom, halogen atoms and aliphatic, alkoxy, nitro, acyl, sulfonyl, nitrile, alkaryl, aryl, amino, thioalkyl, aldehyde, urea, —O—(C?O)-alkyl, —O—(C?O)-aryl, —O—(C?O)—O-alkyl, —O—(C?O)—O-aryl, —NH—(C?O)-alkyl, —NH—(C?O)-aryl, —(C?O)—NH-alkyl, —(C?O)—NH-aryl, —NH—(SO2)-alkyl, —NH—(SO2)-aryl, —(SO2)—NH-alkyl, —(SO2)—NH-aryl groups; X is represented by -A(-M)n or is selected from the group consisting of substituted aliphatic groups, unsubstituted aliphatic groups, substituted cycloaliphatic groups, unsubstituted cycloaliphatic groups
    Type: Grant
    Filed: May 12, 2005
    Date of Patent: August 29, 2006
    Assignee: Agfa Gevaert
    Inventors: Frank Louwet, Johan Loccufier
  • Patent number: 7094526
    Abstract: A photothermographic imaging material containing a support having thereon photosensitive silver halide grains, light-insensitive organic silver salt grains, a reducing agent for silver ions and polymer, wherein and average particle size of the photosensitive silver halide grains is 0.005 to 0.1 ?m, and the polymer dissolves both in water and in an organic solvent.
    Type: Grant
    Filed: October 28, 2004
    Date of Patent: August 22, 2006
    Assignee: Konica Minolta Medical & Graphic, Inc
    Inventors: Hiroaki Ando, Kazuhito Ihara, Shinichi Karakata, Kazuyoshi Shioiri
  • Patent number: 7087368
    Abstract: A silver salt photothermographic dry imaging material including non-photosensitive aliphatic carboxylic acid silver salts; a photosensitive emulsion containing photosensitive silver halide grains; a silver ion reducing agent; a binder; and a cyan coloring leuco dye. A percentage of the photosensitive silver halide grains having a mean particle size of 0.01 or more ?m and 0.04 ?m or less is 5% or more by mass and 50% or less by mass of total photosensitive silver halide grains by conversion into a silver amount.
    Type: Grant
    Filed: October 31, 2005
    Date of Patent: August 8, 2006
    Assignee: Konica Minolta Holdings, Inc.
    Inventors: Hiroshi Kashiwagi, Narito Goto
  • Patent number: 7087367
    Abstract: A photothermographic material is disclosed, comprising on a support a light-sensitive layer comprising a light-insensitive silver salt of an aliphatic carboxylic acid, light-sensitive silver halide grains, a reducing agent for silver ions and a binder, wherein the light-sensitive layer further comprises nonaqueous dispersion particles insoluble in organic solvents.
    Type: Grant
    Filed: January 20, 2005
    Date of Patent: August 8, 2006
    Assignee: Konica Minolta Medical & Graphic, INC
    Inventors: Takayuki Sasaki, Akihisa Nakajima, Kiyokazu Morita
  • Patent number: 7067242
    Abstract: Backside conductive layers with increased conductive efficiency can be provided for thermally developable materials by formulating hydrophilic metal oxide clusters in a hydrophobic environment using low shear mixing conditions. The dry thickness and coating weight of the conductive layer are thereby reduced.
    Type: Grant
    Filed: October 29, 2004
    Date of Patent: June 27, 2006
    Assignee: Eastman Kodak Company
    Inventors: Thomas J. Ludemann, Gary E. LaBelle, Roland J. Koestner, Samuel Chen
  • Patent number: 7056652
    Abstract: A silver salt photothermographic material is disclosed, comprising on a support a light-insensitive silver salt of an aliphatic carboxylic agent, light-sensitive silver halide grains, a reducing agent for silver ions and a binding agent, wherein the silver halide grains are those which are capable being converted from a surface latent image formation type to internal latent image formation type upon thermal development, and the photothermographic material further comprises a dye microcapsule dispersion or a dye compound containing at least two chromophores.
    Type: Grant
    Filed: October 22, 2004
    Date of Patent: June 6, 2006
    Assignee: Konica Minolta Medical & Graphic, Inc.
    Inventor: Hiroshi Kashiwagi
  • Patent number: 7056651
    Abstract: Thermally developable materials for thermography or photothermography have imaging layers on one or both sides of the support. Buried conductive underlayers are disposed under these imaging layers on one or both sides of the support, and these conductive underlayers include conductive metal oxide(s) and optionally a smectite clay or lithium salt.
    Type: Grant
    Filed: April 18, 2005
    Date of Patent: June 6, 2006
    Assignee: Eastman Kodak Company
    Inventors: Sharon M. Simpson, Jon A. Hammerschmidt, Kumars Sakizadeh
  • Patent number: 7052819
    Abstract: The addition of certain aliphatic and non-aromatic carbocyclic polycarboxylic acids provides an improvement in natural age keeping properties of organic-solvent based photothermographic materials. This improvement is particularly useful in organic-based photothermographic materials containing phosphors in the photothermographic emulsion layer. Phosphor-containing materials can be particularly useful for direct radiographic imaging using X-radiation.
    Type: Grant
    Filed: April 16, 2004
    Date of Patent: May 30, 2006
    Assignee: Eastman Kodak Company
    Inventor: Sharon Mary Simpson
  • Patent number: 7052828
    Abstract: The present invention provides a photothermographic material including at least a photosensitive silver halide, a non-photosensitive silver-supplying compound, a reducing agent and a binder on at least one surface of a support. The photothermographic material further includes at least one kind of halogen releasing compound having a water-solubilizing group and at least one kind of halogen releasing compound having no water-solubilizing group, and a gradation of a characteristic curve is 2.5 to 4.0. The photothermographic material of the invention is excellent in storability, and particularly excellent in storability of high quality images used for image recording for medical diagnosis.
    Type: Grant
    Filed: September 14, 2004
    Date of Patent: May 30, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yasuhiro Yoshioka
  • Patent number: 7049054
    Abstract: Thermally developable imaging materials have an outermost protective layer that is composed of one or more hydrophilic film-forming components. Between the outermost protective layer and the underlying thermally developable imaging layers is an interlayer containing a film-forming ionic latex polymer other than a carboxy-containing latex polymer. This ionic polymer can be negatively-charged or positively-charged. The ionic latex polymer is present as latex particles that have been prepared in the presence of a stabilizer in an amount of at least 0.5% (by weight) that has an HLB value of 7 to 20. The stabilizer becomes associated with the latex polymer particles. Both thermographic and photothermographic materials can be prepared with such protective layers.
    Type: Grant
    Filed: September 7, 2004
    Date of Patent: May 23, 2006
    Assignee: Eastman Kodak Company
    Inventors: Jon A. Hammerschmidt, Jeffrey W. Leon
  • Patent number: 7022471
    Abstract: An organic silver salt dispersion containing: light-insensitive organic silver salt grains; photosensitive silver halide grains; a solvent; and a binder for dispersion, wherein the organic silver salt is prepared by using: (i) an alkaline metal salt of an organic acid other than a sodium salt; and (ii) a water soluble silver compound, and the binder is a polyvinyl acetal resin having a polymerization degree of 250 to 1000 and prepared by acetal forming reaction of a polyvinylalcohol with an aldehyde.
    Type: Grant
    Filed: August 19, 2004
    Date of Patent: April 4, 2006
    Assignee: Konica Minolta Medical & Graphic Inc.
    Inventor: Kenji Ohnuma
  • Patent number: 7022467
    Abstract: Backside conductive layers with increased conductive efficiency can be provided for thermally developable materials by providing a buried conductive coating containing a lower molecular weight polyvinyl acetal binder (that is, a molecular weight of at least 8,000 and less than 30,000).
    Type: Grant
    Filed: November 30, 2004
    Date of Patent: April 4, 2006
    Assignee: Eastman Kodak Company
    Inventors: Thomas J. Ludemann, Roland J. Koestner, Gary E. LaBelle, Darlene F. Philip
  • Patent number: 7022470
    Abstract: A photothermographic imaging material having high sensitivity and superior temporal storage stability. The photothermographic imaging material includes silver halide on at least one side of a support, and includes at least one kind of the compounds represented by the following general formula (1).
    Type: Grant
    Filed: March 24, 2004
    Date of Patent: April 4, 2006
    Assignee: Konica Minolta Medical & Graphic, Inc.
    Inventors: Kiyoshi Fukusaka, Kazuaki Nakamura, Ryouhei Iwamoto, Norio Miura, Nobuaki Kagawa, Soc Man Ho Kimura
  • Patent number: 7018770
    Abstract: A reflective radiographic material is useful to provide images that can be viewed without a light box. This reflective radiographic material has a reflective support and a silver halide emulsion on one side of the support only. The material can be used with a single green- or blue-light emitting fluorescent intensifying screen as part of an imaging assembly. The reflective support enables the image in the radiographic material to be viewed without a light box and the speed of the material enables the use of low power X-radiation generating equipment.
    Type: Grant
    Filed: March 28, 2005
    Date of Patent: March 28, 2006
    Inventors: Robert E. Dickerson, Kenneth A. Duke, Phillip C. Bunch, Alan S. Fitterman
  • Patent number: 7018787
    Abstract: Thermally developable materials such as photothermographic and thermographic materials have a backside conductive layer with increased conductive efficiency. This backside conductive layer is a buried conductive coating and is overcoated with a layer that contains a smectite clay modified with a quaternary ammonium compound.
    Type: Grant
    Filed: November 30, 2004
    Date of Patent: March 28, 2006
    Assignee: Eastman Kodak Company
    Inventors: Thomas J. Ludemann, Gary E. LaBelle, Darlene F. Philip, Thomas C. Geisler
  • Patent number: 7018786
    Abstract: A black and white monosheet thermographic recording material comprising a support and a thermosensitive element, the thermosensitive element containing a substantially light-insensitive organic silver salt, an organic reducing agent therefor in thermal working relationship therewith, a binder and at least one toning agent, wherein the at least one toning agent is represented by formula (I): wherein R1 is a hydrogen atom or an alkyl, an alkenyl, an alkynyl, a cycloalkyl, an alkaryl, an aryl, a heterocyclic or a heteroaryl group all of which may be optionally substituted; with the proviso that R1 may not be a hydrogen atom if both R2 and R3 are both hydrogen atoms; R2 and R3 are independently a hydrogen or a halogen atom or an amino, amide, ester, carboxy, carbonate, alkyl, alkenyl, alkynyl, cycloalkyl, alkaryl, aryl, heterocyclic or heteroaryl group all of which may be optionally substituted; R2 and R3 may together represent the atoms necessary to complete a heteroaromatic ring with no more than one nitrog
    Type: Grant
    Filed: December 16, 2003
    Date of Patent: March 28, 2006
    Assignee: AGFA Gevaert
    Inventors: Ingrid Geuens, Johan Loccufier, Vera Drieghe
  • Patent number: 7014989
    Abstract: Black-and-white, aqueous-based, silver halide-containing photothermographic materials have increased stability after imaging with the incorporation of at least 0.00005 mol/m2 of a 4-substituted urazole.
    Type: Grant
    Filed: April 18, 2005
    Date of Patent: March 21, 2006
    Assignee: Eastman Kodak Company
    Inventors: Sharon M. Simpson, Kumars Sakizadeh
  • Patent number: 7014977
    Abstract: A reflective radiographic material (at least 200 system speed) is useful especially to provide images that can be viewed without a light box. This reflective radiographic material has a reflective support, a silver halide emulsion on one side of the support only, and a photographic speed of at least 200. The reflective material also includes an incorporated black-and-white developing agent and a co-developing agent, and can be used with a single fluorescent intensifying screen as part of an imaging assembly. The reflective support enables viewing the resulting image without a light box and the high speed of the material enables the use of low power X-radiation generating equipment. The incorporated black-and-white developing agent and co-developing agent allow the radiographic material to be quickly processed after exposure using simplified processing chemistry.
    Type: Grant
    Filed: March 28, 2005
    Date of Patent: March 21, 2006
    Assignee: Eastman Kodak Company
    Inventors: Robert E. Dickerson, Kenneth A. Duke, Alan S. Fitterman
  • Patent number: 7008748
    Abstract: Thermally developable materials such as thermographic and photothermographic materials include a co-precipitate comprising first and second organic silver salts, the first organic silver salt comprising a silver salt of a nitrogen-containing heterocyclic compound containing an imino group, and the second organic silver salt comprising a silver salt of a mercaptotriazole. The first organic silver salt can be used in the imaging process as a source of reducible silver ions, and the second organic silver salt can be a source of a toning agent. The co-precipitate can be prepared using double-jet precipitation techniques to provide an aqueous dispersion that can be used in imaging formulations.
    Type: Grant
    Filed: September 7, 2004
    Date of Patent: March 7, 2006
    Assignee: Eastman Kodak Company
    Inventors: Dirk J. Hasberg, Doreen C. Lynch, Kui Chen-Ho, Chaofeng Zou
  • Patent number: 6977139
    Abstract: Thermally developable materials such as thermographic and photothermographic materials include a novel non-photosensitive source of reducible silver ions that are predominantly provided as rod-shaped particles of silver salt of a nitrogen-containing heterocyclic compound containing an imino group. The rod-shaped particles have an average aspect ratio of at least 3:1 and a width index for particle diameter of 1.25 or less, and provide improved imaging properties. These particles can be prepared using double jet precipitation procedures in which vAg is kept constant at a value of equal to or greater than ?50 mV.
    Type: Grant
    Filed: April 16, 2004
    Date of Patent: December 20, 2005
    Assignee: Eastman Kodak Company
    Inventors: Dirk J. Hasberg, Chaofeng Zou
  • Patent number: 6939667
    Abstract: A photo sensitive emulsion disclosed, comprising an organic silver salt, a photosensitive silver halide and a dispersing medium, wherein the organic silver salt is comprised of at least a first organic silver salt grains and a second organic silver salt grains which are different in average grain size from each other. A photothermographic material containing is also disclosed.
    Type: Grant
    Filed: June 17, 2004
    Date of Patent: September 6, 2005
    Assignee: Konica Minolta Medical & Graphic, Inc.
    Inventor: Yasuo Taima
  • Patent number: 6908731
    Abstract: A substantially light-insensitive black and white monosheet thermographic recording material comprising a support and a thermosensitive element, the thermosensitive element containing a substantially light-insensitive organic silver salt, an organic reducing agent therefor in thermal working relationship therewith, a binder and at least one stabilizer selected from the group consisting of 1-phenyl-5-mercaptotetrazole compounds in which the phenyl group is substituted with a substituent containing an optionally substituted aryl group; and
    Type: Grant
    Filed: November 13, 2003
    Date of Patent: June 21, 2005
    Assignee: Agfa-Gevaert
    Inventors: Ingrid Geuens, Carlo Uyttendaele, Ivan Hoogmartens, Johan Loccufier
  • Patent number: 6902880
    Abstract: A substantially light-insensitive black and white monosheet thermographic recording material comprising a support and a thermosensitive element, the thermosensitive element containing a substantially light-insensitive organic silver salt, an organic reducing agent therefor in thermal working relationship therewith, a binder and at least one stabilizer selected from the group consisting of 1-(5-mercapto-1-tetrazolyl)-acetyl compounds represented by formula (I): wherein R1 is —NR2R3, —OR4 or an optionally substituted aryl or heteroaryl group; R2 is hydrogen or an optionally substituted alkyl, aryl or heteroaryl group; R3 is an optionally substituted aryl or heteroaryl group; and R4 is an optionally substituted aryl group; and compounds with two or more groups represented by formula (II): where Q comprises the necessary atoms to form a 5- or 6-membered unsaturated heterocyclic ring, A is hydrogen, a counterion to compensate the negative charge of the thiolate group or two or more A groups provide a linki
    Type: Grant
    Filed: November 10, 2003
    Date of Patent: June 7, 2005
    Assignee: AGFA-Gevaert
    Inventors: Ingrid Geuens, Johan Loccufier
  • Publication number: 20040043338
    Abstract: A thermally developable light-sensitive material comprising a support having thereon light-sensitive silver halide grains, an organic silver halide salt and a reducing agent, wherein when a regression line is obtained by plotting color coordinates (u*, v*) of the thermally developable light-sensitive material at optical densities of 0.5, 1.0, 1.5 and the minimum density on a two dimensional coordinates of CIE 1976 (L* u* v*) color space, in which the abscissa is u* and the ordinate is v*, a coefficient of determination R2 of the regression line is from 0.998 to 1.000.
    Type: Application
    Filed: July 31, 2003
    Publication date: March 4, 2004
    Applicant: Konica Corporation
    Inventor: Hiroyuki Yanagisawa
  • Patent number: 6677111
    Abstract: A silver halide emulsion is described, comprising at least a dispersion medium and silver halide grains, wherein said silver halide grains have an average grain size of from 0.005 to 0.1 &mgr;m and a hexacyano metal complex represented by formula (I) is present on the outermost surface of the silver halide grain: [M(CN)6]n−  (I) wherein M represents Fe, Ru, Os, Co, Rh, Ir, Cr or Re, and n represents 3 or 4. Also described are a method for producing the emulsion, and a silver halide light-sensitive material and a photothermographic material using the emulsion.
    Type: Grant
    Filed: March 9, 2000
    Date of Patent: January 13, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Shinji Ikari
  • Publication number: 20030224302
    Abstract: A heat-developable color photosensitive material of single sheet type, which comprises a support having provided thereon at least light-sensitive silver halide, a color developing agent or a precursor thereof, dye-forming couplers capable of forming dyes by reacting with an oxidation product of the color developing agent, a reducible silver salt, a thermal solvent and a binder, wherein a water-insoluble thermoplastic polymer prepared by polymerizing at least one kind of monomer is included in layers containing the dye-forming couplers, thereby preventing the dyes formed from bleeding to ensure high sharpness and making an improvement in raw-stock storability.
    Type: Application
    Filed: April 8, 2003
    Publication date: December 4, 2003
    Inventor: Kazuhiko Matsumoto
  • Publication number: 20030203324
    Abstract: A color image forming method is disclosed, comprising exposing a silver halide color photographic material and developing the exposed photographic material at 43 to 180° C. to form a color image, wherein when the photographic material is exposed so that the light-sensitive layer has a transmission density of a minimum density plus 0.1, the light-sensitive layer comprises dye-clouds having an average diameter of 3.0 to 20.0 &mgr;m. There is also disclosed a digital image forming process, wherein image recording information of the photographic material which was formed by use of the color image forming method is converted to digital image information through an image sensor.
    Type: Application
    Filed: March 26, 2003
    Publication date: October 30, 2003
    Inventors: Noriyuki Kokeguchi, Hiroyuki Hoshino, Hiromoto Ii