Hardening Ingredient Containing Patents (Class 430/621)
  • Patent number: 4450223
    Abstract: A photographic silver halide material comprising a compound which is capable of being reduced by a silver halide developing agent at a rate slower than that of image-wise developable silver halide and in reduced state is capable of releasing a photographically useful group, characterized in that said compound corresponds to the following formula: ##STR1## wherein: R.sup.10 and R.sup.20 (same or different)(1) represent an alkyl group, a cycloalkyl group, an alkenyl group, a cycloalkenyl group or an aralkyl group including said groups in substituted form,(2) represent an aryl group including a substituted aryl group, or(3) represent a heterocyclic ring residue including such residue in substituted form, orR.sup.10 and R.sup.20 are ringclosed, either R.sup.10 or R.sup.20 containing a ballasting group conferring diffusion resistance to the compound in hydrophilic colloid media when penetrated by an aqueous alkaline liquid;L.sup.1 and L.sup.2 (same or different) represent a ##STR2## --SO.sub.
    Type: Grant
    Filed: February 14, 1983
    Date of Patent: May 22, 1984
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Raphael K. Van Poucke, Christian C. Van de Sande, Andree Verhecken
  • Patent number: 4444926
    Abstract: A method of hardening gelatin is described which uses (1) a polymer containing at least 0.01 mol % of a repeating unit represented by formula (I) ##STR1## wherein R represents a hydrogen atom, an alkyl group having from 1 to 6 carbon atoms, or a halogen atom, M represents a hydrogen atom, an alkali metal atom, an alkaline earth metal atom, or an organic base, X represents an alkyl group having from 1 to 6 carbon atoms, an alkoxy group having from 1 to 6 carbon atoms, an alkylamino group having from 1 to 6 carbon atoms, or a halogen atom, m represents 0, 1 or 2, and n represents 1 or 2, (2) a polyvalent alcohol having at least two hydroxy groups, and (3) a hardener having an active vinyl group.The method has advantages in that the rate of hardening the gelatin is fast, the so-called post hardening property is small, and the gelatin composition is hardely influenced by the conditions of temperature and humidity during storage.
    Type: Grant
    Filed: November 10, 1981
    Date of Patent: April 24, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masasi Ogawa, Kunio Ishigaki, Kiyotaka Hori
  • Patent number: 4427768
    Abstract: A method of hardening gelatin is described comprising treating gelatin with a compound of the formula (I) ##STR1## wherein R.sup.1 and R.sup.2 can each represent a monovalent group including a carbon atom or a nitrogen atom forming a bond together with the nitrogen atom N forming an acid ester in the formula (I); or R.sup.1 and R.sup.
    Type: Grant
    Filed: July 2, 1982
    Date of Patent: January 24, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Katuji Kitatani, Hidefumi Sera, Atsuaki Arai, Masasi Ogawa, Kunio Ishigaki, Haruo Ogura
  • Patent number: 4421846
    Abstract: A photographic element containing a nondiffusible metal complex capable of releasing a diffusible photographically useful group. The complex contains at least one poly-dentate ligand which contains the photographically useful group. The complex may be activated when reduced under alkaline conditions to release the photographically useful group.
    Type: Grant
    Filed: December 23, 1981
    Date of Patent: December 20, 1983
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Satoru Ikeuchi, Masaru Kanbe, Jiro Takahashi, Ryuichiro Kobayashi, Shunji Suginaka, Noboru Mizukura
  • Patent number: 4421847
    Abstract: In a process for the chain-lengthening of gelatine the gelatine is brought into contact with a hardening agent which can activate the carboxyl groups of the gelatine. The result is a partially hardened gelatine which has advantageous properties as for the production of photographic layers.
    Type: Grant
    Filed: December 11, 1981
    Date of Patent: December 20, 1983
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Heinrich Jung, Ulrich Biskup
  • Patent number: 4414304
    Abstract: Forehardened photographic elements, particularly radiographic elements, intended to produce silver images are disclosed including among hydrophilic colloid layers at least one emulsion layer containing thin tabular silver halide grains. When developed in less than 1 minute to produce a viewable silver image, these photographic elements exhibit increased covering power.
    Type: Grant
    Filed: September 30, 1982
    Date of Patent: November 8, 1983
    Assignee: Eastman Kodak Company
    Inventor: Robert E. Dickerson
  • Patent number: 4399214
    Abstract: In a process for hardening gelatine containing layers of color photographic multi-layered materials which have a paper laminated with a polyolefin layer arranged on both sides a substrate 1,3,5-triacrylohexahydro-1,3,5-triazine and a polyhydric aliphatic alcohol with 3 to 10 carbon atoms are added to the casting solutions and the casting solutions are then applied to a corona irradiated surface of the substrate.
    Type: Grant
    Filed: October 21, 1980
    Date of Patent: August 16, 1983
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventor: Karl Lohmer
  • Patent number: 4396709
    Abstract: The adhesion resistance of a silver halide photographic light-sensitive medium comprising a support, at least one emulsion layer provided on one side of the support and a backing layer provided on the other side can be improved by incorporating an acid-treated gelatin and a gelatin hardener containing therein a vinyl sulfone group into the backing layer.
    Type: Grant
    Filed: June 2, 1981
    Date of Patent: August 2, 1983
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kimitaka Kameoka, Yoshimi Ishigami
  • Patent number: 4383030
    Abstract: The sensitivity of a gelatino-silver halide emulsion is improved by adding glutaraldehyde bisulfite in combination with benzene sulfinic acid during the preparation of the silver halide, viz. when a silver salt is mixed with a halide to precipitate a silver halide.
    Type: Grant
    Filed: April 27, 1981
    Date of Patent: May 10, 1983
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Allan R. Schoenberg
  • Patent number: 4376818
    Abstract: Compounds represented by the following general formula are used as hardeners for gelatin, in particular gelatin layers of photographic light sensitive materials ##STR1## (wherein R and X are the same as defined in the specification).
    Type: Grant
    Filed: August 20, 1980
    Date of Patent: March 15, 1983
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Minoru Ohashi, Katsuaki Iwaosa
  • Patent number: 4358532
    Abstract: A photographic element containing a compound represented by formula (I) ##STR1## wherein G represents --OR.sup.1 or --NHR.sup.2, R.sup.1 represents hydrogen or a hydrolyzable moiety, R.sup.2 represents hydrogen or an alkyl group containing from 1 to 50 carbon atoms, Z represents a photographically useful group, A represents an atomic group forming an aromatic ring, Ball represents an organic immobilizing group on the aromatic ring, which cntains from 8 to 50 carbon atoms, m represents an integer of 1 or 2, X represents a divalent organic group, Nu represents a nucleophilic group, and n represents an integer of 1 or 2, and X with the nucleophilic group Nu is capable of forming a 5- to 12-membered ring by oxidation having an electrophilic center at the carbon atom substituted by the --NHSO.sub.2 Z group.
    Type: Grant
    Filed: July 15, 1981
    Date of Patent: November 9, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Koichi Koyama, Shinsaku Fujita
  • Patent number: 4338394
    Abstract: Gelatin-containing layers of photographic materials are hardened by adding a compound containing from 2 to 6 sulfonyl ethyl sulfate groups in the form of its salts and activating the compound by adjusting a pH-value in the range from 6.5 to 11.
    Type: Grant
    Filed: December 29, 1980
    Date of Patent: July 6, 1982
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Wolfgang Himmelmann, Peter Bergthaller, Johannes Sobel
  • Patent number: 4323644
    Abstract: A photographic material having at least one layer containing a polymer having a repeating unit of the formula (I): ##STR1## wherein A is a monomer unit copolymerized with a copolymerizable ethylenically unsaturated monomer; R is a hydrogen atom or a lower alkyl group having 1 to about 6 carbon atoms; L is a bivalent linking group having 1 to about 20 carbon atoms; X is an active ester group; x and y each represents molar percent, x being between 0 and 95 and y being between 5 and 100; m is 0 or 1.
    Type: Grant
    Filed: November 5, 1980
    Date of Patent: April 6, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Taku Nakamura, Masasi Ogawa, Kunio Ishigaki
  • Patent number: 4315072
    Abstract: Artificial gelatins containing higher proportions of methionine than are found in natural gelatin are made by thermal polymerization of methionine with various proportions of other .alpha.-amino acids, including some proportion of aspartic acid, glutamic acid or lysine. Artificial gelatins containing as much as 40 mole percent methionine can be obtained. Proportions in the polymer can be adjusted by control of proportions in the reaction mixture. Photographic silver halide emulsions containing these artificial gelatins and photographic films employing the emulsions are also disclosed.
    Type: Grant
    Filed: March 11, 1980
    Date of Patent: February 9, 1982
    Assignee: Polymicro
    Inventors: Sidney W. Fox, Arthur I. Holden
  • Patent number: 4294921
    Abstract: A method of hardening gelatin which uses both a gelatin hardener and a polymer having a repeating unit of the formula (I): ##STR1## wherein R represents a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, and a halogen atom; M represents a hydrogen atom, an alkali metal atom, an alkali earth metal atom, or an organic base; X represents an alkyl group having 1 to 6 carbon atoms, an alkoxy group, an alkylamino group, or a halogen atom; m represents 0, 1 or 2; and n represents 1 or 2.
    Type: Grant
    Filed: June 23, 1980
    Date of Patent: October 13, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Jun Yamaguchi, Takashi Naoi, Hidefumi Sera, Kunio Ishigaki, Masasi Ogawa
  • Patent number: 4278757
    Abstract: A silver halide photographic light-sensitive material having a hydrophilic organic colloid layer containing a dispersion of a substantially water-insoluble photographic additive dissolved in a phosphoric acid ester represented by the following general formula (I): ##STR1## wherein R.sub.1 represents a saturated alicyclic group; and R.sub.2 and R.sub.3, which may be the same or different, each represents a saturated alicyclic group, an alkyl group or an aryl group.
    Type: Grant
    Filed: August 10, 1979
    Date of Patent: July 14, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yasuo Mukunoki, Masakazu Yoneyama, Jiro Yamaguchi, Hideki Naito, Jun Sasaki
  • Patent number: 4268627
    Abstract: A photographic light-sensitive material is described comprising at least one hydrophilic colloidal layer containing a hardener and further containing as an acid-captor at least one compound represented by formula (I) or (II): ##STR1## wherein R.sub.1 represents hydrogen, a lower alkyl group containing 5 or less carbon atoms, an alkoxy group containing 5 or less carbon atoms, or a halogen atom, and R.sub.2 and R.sub.3 each independently represents hydrogen, an alkyl group containing 10 or less carbon atoms, an aryl group containing from 6 to 12 carbon atoms, or an alkoxycarbonyl group containing 5 or less carbon atoms.
    Type: Grant
    Filed: June 13, 1980
    Date of Patent: May 19, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hidefumi Sera, Katuzi Kitatani, Masasi Ogawa, Kunio Ishigaki, Hisashi Shiraishi
  • Patent number: 4243748
    Abstract: A light-sensitive silver halide reproduction material of high gradation stability which contains a disulfide compound substituted by two heterocyclic radicals, and a thiazolidine compound.
    Type: Grant
    Filed: May 29, 1979
    Date of Patent: January 6, 1981
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Gotz Elsner, Rudolf F. Legler, Margarete Popovici
  • Patent number: 4241171
    Abstract: A process for making a photographic product in which a plurality of liquid layers are coated on a base, comprising the steps of coating as the first layer adjacent the base a carrier layer containing a photographic hardener and coating as the second layer adjacent the first layer an isolation layer. The product is completed by coating a plurality of conventional photographic compositions over the first two layers and drying.
    Type: Grant
    Filed: February 21, 1979
    Date of Patent: December 23, 1980
    Assignee: Polaroid Corporation
    Inventors: Roger C. Clapp, Edward J. Choinski
  • Patent number: 4233398
    Abstract: Protein containing photographic layers are hardened by coating with a hardening solution which contains at least one quick-acting hardener which activates carboxyl groups and at least one polysaccharide.
    Type: Grant
    Filed: February 24, 1978
    Date of Patent: November 11, 1980
    Assignee: AGFA-Gevaert, A.G.
    Inventors: Fritz Nittel, Karl Czernik, Wolfgang Sauerteig, Wolfgang Himmelmann, Peter Bergthaller
  • Patent number: 4232107
    Abstract: Said material contains a quinone-type compound which corresponds to one of the formulae (A) or (B) and which is capable in reduced state and under alkaline conditions of releasing a photographically useful group e.g. a dye: ##STR1## wherein: each of (Nuox).sup.1 and (Nuox).sup.2 represents an oxidized nucleophilic group,Z represents a bivalent atomic group which is electronegative,Q together with the Z group represents a releasable photographically useful group,each of R.sup.1, R.sup.2 and R.sup.3 is hydrogen, halogen, alkyl, alkoxy, or an acylamino group or R.sup.1 and R.sup.2 in adjacent positions on the ring form a ring fused with the remainder of the molecule, or R.sup.2 and R.sup.3 together are fused with the remainder of the molecule.each of R.sup.4 and R.sup.5 represents hydrogen or a hydrocarbon group.At least one of the substituents R.sup.1, R.sup.2, R.sup.3, R.sup.4 or R.sup.5 is a ballasting group X.
    Type: Grant
    Filed: March 15, 1979
    Date of Patent: November 4, 1980
    Assignee: AGFA-GEVAERT N.V.
    Inventor: Wilhelmus Janssens
  • Patent number: 4218533
    Abstract: In the production of a photographic material by applying a coating composition to a continuously moving support, cold-setting the coating and drying the coating, an additive in the coating composition (e.g., a hardening agent or an antistatic agent), either partly or completely, is atomized by ultrasonic vibration, and supplied to the coating formed on the continuously moving support. Alternatively, the atomized additive is first supplied to the surface of a continuously moving support, and before the coating is completely dried, the coating composition is applied thereto.
    Type: Grant
    Filed: June 3, 1977
    Date of Patent: August 19, 1980
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shuzo Fuchigami, Toshio Miyashiro
  • Patent number: 4201586
    Abstract: A photographic light-sensitive material having improved anti-adhesive properties comprising an uppermost layer containing acid-processed gelatin and a surface active organic fluoro-compound.
    Type: Grant
    Filed: November 4, 1977
    Date of Patent: May 6, 1980
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kiyotaka Hori, Shigeru Nagatomo
  • Patent number: 4199355
    Abstract: Photographic elements, processes for forming images in photographic elements and new compounds are disclosed. Generally, the invention relates to improved immobile compounds which can be used to provide positive images from negative recording-developing photographic materials such as negative silver halide emulsions. The compounds contain a photographically useful group such as a dye or dye precursor and are capable of releasing said photographically useful group under alkaline conditions, and are also capable of reaction with an oxidized silver halide developing agent before substantial release of said photographically useful group occurs, to provide a reaction product having a substantially lower rate of release of said photographically useful group.
    Type: Grant
    Filed: June 24, 1975
    Date of Patent: April 22, 1980
    Assignee: Eastman Kodak Company
    Inventors: Jerald C. Hinshaw, Paul B. Condit
  • Patent number: 4199363
    Abstract: An improved process is disclosed for uniformly dispersing hydrophobic materials through a hydrophilic colloid layer such as, for example, a photographically useful layer containing gelatin. The process over which the present invention is a valuable improvement comprises the steps:(a) forming an aqueous dispersion by intermixing the hydrophobic material and an aqueous polymeric latex, optionally including gelatin in the dispersion;(b) forming a wet layer by coating onto a suitable support the aqueous dispersion from step (a); and(c) thereafter removing a substantial proportion of the water from the wet layer through which the hydrophobic material is dispersed.The present process relates particularly to improvements in step (a), wherein the "aqueous dispersion" is formed by blending a loadable polymeric latex into a solution of the hydrophobic material dissolved in a water-miscible solvent using techniques which avoid coagulation of the hydrophobic material or the particles of the latex.
    Type: Grant
    Filed: November 3, 1978
    Date of Patent: April 22, 1980
    Assignee: Eastman Kodak Company
    Inventor: Tsang J. Chen
  • Patent number: 4193795
    Abstract: A photographic element comprising a support, a layer containing certain photographically useful and/or active fragments and a layer containing a dye mordant composition comprising a polymer having recurring units of the formula selected from the group consisting of: ##STR1## wherein: R.sup.2 is hydrogen or alkyl;R.sup.1 is hydrogen, alkyl or aryl;L is a linking group;W is an electron-withdrawing group;X is a leaving group; andn is 0 or 1.The polymeric mordants covalently bond with dyes or dye precursors and are especially useful in diffusion transfer processes.
    Type: Grant
    Filed: May 15, 1978
    Date of Patent: March 18, 1980
    Assignee: Eastman Kodak Company
    Inventors: Gerald A. Campbell, Hyman Cohen, Lewis R. Hamilton, George Villard
  • Patent number: 4193802
    Abstract: A silver halide photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer, with the photographic light-sensitive material having a hydrophilic organic colloid layer containing a dispersion of a scarcely water-soluble photographic additive dissolved in an aromatic ester represented by the following general formula (I): ##STR1## wherein R.sub.1 represents an alkyl group, an alkoxy group, an acyloxy group, an aryloxy group, an alkoxycarbonyl group or a halogen atom; R.sub.2 represents a cyclic saturated hydrocarbon group; m represents an integer of 0 to 5; n represents an integer of 1 to 6; and when m and n each represents an integer of 2 or more, the substituents represented by R.sub.1 or R.sub.2 can be the same or different.
    Type: Grant
    Filed: August 15, 1978
    Date of Patent: March 18, 1980
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yasuo Mukunoki, Hideki Naito, Akio Mitsui
  • Patent number: 4175970
    Abstract: A process for sensitizing photographic gelatino-silver halide emulsions with glutaraldehyde bisulfite in combination with benzene sulfinic acid.
    Type: Grant
    Filed: July 24, 1978
    Date of Patent: November 27, 1979
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Raymond J. LeStrange
  • Patent number: 4173481
    Abstract: A photographic silver halide light-sensitive material having at least one hydrophilic colloid layer containing gelatin and/or a gelatin derivative hardened with a compound represented by the following general formula (I): ##STR1## wherein a and d each represents 1 or 2; b and c each represents 0, 1 or 2 with the proviso that both b and c are not simultaneously 0; R represents a divalent group; and n is 0 or 1, which compound provides a preferred hardening rate and does not adversely affect the photographic properties of photographic light-sensitive materials, and a method of hardening gelatin and/or a gelatin derivative comprising treating the gelatin and/or the gelatin derivative with a compound represented by the general formula (I) above.
    Type: Grant
    Filed: November 1, 1977
    Date of Patent: November 6, 1979
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hidefumi Sera, Tsumoru Ishii, June Yamaguchi, Hisashi Shiraishi