Toner Containing Patents (Class 430/965)
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Patent number: 4965172Abstract: This invention concerns a method for color development of a surface having imagewise tacky and nontacky image areas which comprises(a) applying a dry nonelectroscopic toner to the image-bearing surface;(b) distributing the toner particles over the image surface whereby the distributed toner particles become embedded solely in the tacky image areas; and(c) physically removing toner particles from the nontacky areas which are left substantially free of the toner particles, the improvement wherein high resolution images having higher toned optical density with improved color purity are obtained using a dry nonelectroscopic humidity resistant toner having a size distribution within the range from about 0.2 micron to about 10 microns, not more than 10% of the toner being below 0.Type: GrantFiled: December 22, 1988Date of Patent: October 23, 1990Assignee: E. I. du Pont de Nemours and CompanyInventor: Howard Matrick
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Patent number: 4917995Abstract: A silver halide photographic material for obtaining silver images is described, comprising at least one silver halide emulsion layer on a support having a white reflection layer, wherein at least one compound represented by formula (I) is contained in at least one of the constituent layers: ##STR1## wherein X.sup.1 represents a divalent bonding group bonded by way of a hetero atom to a carbon atom; A represents a group capable of controlling the tone of silver images, which is bonded to X.sup.1 by way of the hetero atom of A; R.sup.1, R.sup.2 and R.sup.3 each represents a hydrogen atom or a group that can be substituted, in which R.sup.1 and R.sup.2, or R.sup.1 and R.sup.3 may further be bonded together to form a carbocyclic ring or a heterocyclic ring; Y represents: ##STR2## a cyano group or a nitro group, in which R.sup.4, R.sup.5, R.sup.6, R.sup.7 R.sup.Type: GrantFiled: June 28, 1988Date of Patent: April 17, 1990Assignee: Fuji Photo Film Co., Ltd.Inventors: Tetsuro Kojima, Tetsunori Matsushita, Ichizo Toya, Kazuhiko Takeuchi
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Patent number: 4886737Abstract: Photographically produced black and white images (silver images) are stabilized against subsequent destruction of the image silver, in particular due to discoloration, by treating the finished silver image with an aqueous after treatment bath containing aminotetrazole or a mercaptotetrahydrotriazine.Type: GrantFiled: September 19, 1988Date of Patent: December 12, 1989Assignee: Agfa-Gevaert AktiengesellschaftInventors: Werner Berthold, Paul Marx, hlschlager
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Patent number: 4869996Abstract: An improved process for preparing negative images from a photohardenable tonable element, wherein the unexposed photohardenable tonable element is tacky in a preselected temperature range, T.sub.1 -T.sub.2, in which temperature range the exposed photosensitive tonable element is nontacky but wherein the exposed element is retackifiable at elevated temperatures above T.sub.2. After imagewise exposure the unexposed areas have a colorless toning material applied to them at a temperature within the range T.sub.1 -T.sub.2 to make them nontacky at temperatures of at least up to T.sub.3, which is greater than T.sub.2. After heating to an elevated temperature above T.sub.2 but less than T.sub.3 the exposed areas have a contrasting toning material applied to them to give a negative or reverse image.Type: GrantFiled: December 18, 1987Date of Patent: September 26, 1989Assignee: E. I. Du Pont De Nemours and CompanyInventors: Peter J. McCartin, Eugene L. Grubb, Robert P. Held, Howard Matrick, Bohdan Rakoczy
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Patent number: 4865958Abstract: A photographic recording material is described which comprises a leuco dye which is capable of generating a blue tone in a developed silver image.Type: GrantFiled: August 18, 1988Date of Patent: September 12, 1989Assignee: Eastman Kodak CompanyInventors: Thomas I. Abbott, Robert E. Dickerson, Michael P. Youngblood
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Patent number: 4859565Abstract: Method for making images by image-wise exposing a silver halide emulsion layer, developing it with an alkaline processing solution in the presence of a silver halide solvent, development nuclei, and a density- and tone-controlling compound, transferring silver complexes from the emulsion layer to a non-light-sensitive image-receiving layer and forming an image therein, said density- and tone-controlling compound being contained in said image-receiving layer and/or in said processing solution and corresponding to the general formula: ##STR1## wherein R.sup.1, R.sup.2, and R.sup.3 (same or different) represent hydrogen, C.sub.1 -C.sub.8 alkyl, or Alk.sub.1 --X--Alk.sub.2 --Y--; Alk.sub.1 is (substituted) C.sub.1 -C.sub.8 alkyl; X is --O-- or --S--; Alk.sub.2 is (substituted) C.sub.1 -C.sub.8 alkylene; Y is a single bond, --O--, --S--, --CONH--, --SO.sub.2 NH--, or --NHCONH--; R.sup.3 can alternatively represent (substituted) C.sub.1 -C.sub.8 alkylthio; at least one of R.sup.1, R.sup.2, and R.sup.Type: GrantFiled: April 26, 1988Date of Patent: August 22, 1989Assignee: Agfa-Gevaert, N.V.Inventors: Rene M. De Keyzer, Robert J. Pollet, Leon L. Vermeulen
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Patent number: 4760015Abstract: Photographically produced black-and-white images (silver images) are stabilized against subsequent destruction of the silver image, in particular against the occurrence of so-called microspot defects, by treatment of the finished silver image with an aqueous after-treatment bath containing an amino-1,2,4-triazole.Type: GrantFiled: April 13, 1987Date of Patent: July 26, 1988Assignee: Agfa Gevaert AktiengesellschaftInventors: Werner Berthold, Gunther Mahlberg, Paul Marx, Hans hlschlager
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Patent number: 4756991Abstract: Fluorescent dry nonelectroscopic toner comprising fluorescent pigmented organic resin particles having a size distribution of 0.2 to 50 micrometers, surface coated with at least 0.1% by weight of silicone oil or fluorocarbon compound, in combination with at least 0.5% by weight of a water soluble, polymeric quaternary ammonium compound as defined. The fluorescent toner is useful in color developing positive- and negative-working photosensitive elements. The toners provide good toning quality and excellent lack of background color, together with stability on aging.Type: GrantFiled: March 11, 1987Date of Patent: July 12, 1988Assignee: E. I. Du Pont de Nemours and CompanyInventor: Eugene L. Grubb
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Patent number: 4728601Abstract: Tetra-aza indene compounds of the formula ##STR1## wherein R.sub.1 is alkyl or a ring system and R.sub.2 and R.sub.3 are hydrogen or alkyl.These compounds are of use as image toners in photographic materials.Type: GrantFiled: April 1, 1986Date of Patent: March 1, 1988Assignee: Ciba-Geigy AGInventors: David Rowland, Michael E. Dale, Geoffrey E. Ficken, William E. Long, Andrew W. Yates
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Patent number: 4711832Abstract: A colored, transparent electroscopic toner is provided comprising:(a) a polymeric binder,(b) a rhodamine dye having a non-lactonizing ester-containing phenyl group in the 9-position, and(c) a quencher dye.Type: GrantFiled: May 5, 1986Date of Patent: December 8, 1987Assignee: Eastman Kodak CompanyInventors: William T. Gruenbaum, Julie P. Harmon, Luther C. Roberts
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Patent number: 4698289Abstract: A process for making a ferrite spherical particulate toner carrier core from a raw fly ash comprising recovering the magnetic particles from the non-magnetic particles of the raw fly ash; selecting a desired size for the particles of the raw fly ash and screening the fly ash to obtain the desired sized particles; and purifying the resultant raw fly ash to obtain a ferrite composition having a particle size from 20-300 microns, in which the particles are essentially spherical, having an apparent density of at least 1.8 g/cm.sup.3, a saturation magnetization of 43-70 emu/g, a remanence of 5 emu/g or less, a Hall Flow of 20 sec. or greater/50 g.Type: GrantFiled: February 27, 1986Date of Patent: October 6, 1987Assignee: Halomet Inc.Inventors: Robert G. Aldrich, Geoffrey H. Earl, David W. Trunko
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Patent number: 4683189Abstract: A method of forming a silver salt diffusion transfer image comprises developing an imagewise exposed photosensitive silver halide emulsion layer with a developing agent and a silver halide solvent in the presence of an alkali to thereby convert at least a portion of unexpected silver halide in said emulsion layer to a diffusible silver complex salt and transferring at least a portion of said silver complex salt into a silver precipitating agent-containing image receivin- layer to form an image in said image receiving layer.Type: GrantFiled: April 21, 1986Date of Patent: July 28, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Yoshio Idota, Morio Yagihara
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Patent number: 4661439Abstract: Efficient, lower cost process for preparing dry, nonelectroscopic toners surface coated with antistatic agent and liquid slip agent, utilizing a pressure filter and a planetary mixer. The toners are useful for developing positive- or negative-working photosensitive elements and having imagewise tacky and nontacky surfaces.Type: GrantFiled: December 6, 1985Date of Patent: April 28, 1987Assignee: E.I. De Pont de Nemours and CompanyInventor: Maureen K. Ruskin
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Patent number: 4608329Abstract: An imageable toner powder comprising a solid material capable of existing as a supercooled liquid after being heated above its melting temperature and subsequently cooled and a colorant.Type: GrantFiled: January 8, 1985Date of Patent: August 26, 1986Assignee: Minnesota Mining and Manufacturing CompanyInventor: Thomas C. Geisler
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Patent number: 4592988Abstract: A ferrite toner carrier core composition derived from flyash comprising a mixture of spherical particulates of the general formula ##EQU1## wherein iron is the principal metallic element and i,j,k denote the number of atoms of monovalent, divalent and trivalent atoms present in one mole of the compound, andM.sub.x denotes monovalent atoms from Group IA of the Periodic Table, the alkali metals, usually sodium or potassium, alone or together.M.sub.y denotes divalent atoms from Group IIA of the Periodic Table, the alkali earth metals, usually magnesium or calcium, alone or together.M.sub.z denotes trivalent atoms from Group IVB, usually titanium, Group IVA, usually silicon and Group IIIA, usually aluminum. All permutations and combinations may be present.Type: GrantFiled: August 15, 1984Date of Patent: June 3, 1986Assignee: Halomet, Inc.Inventors: Robert G. Aldrich, Geoffrey H. Earl, David W. Trunko
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Patent number: 4585734Abstract: Certain effective toning systems for silver halide/silver salt/reducing agent photothermographic imaging materials tend to bleach the final image. The presently disclosed toning system of phthalazine and an active-hydrogen containing heterocyclic compound is more stable than some previous toners.Type: GrantFiled: February 1, 1985Date of Patent: April 29, 1986Assignee: Minnesota Mining and Manufacturing CompanyInventor: David C. Weigel
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Patent number: 4569899Abstract: In a photographic element for a silver salt diffusion transfer process comprising a silver halide light-sensitive element, an image receiving element and a processing element, the improvement wherein the photographic element contains a compound represented by the following general formula (I) or (II) ##STR1## wherein all the symbols are defined in the appended claims. A photographic element for a silver salt diffusion transfer process containing the novel image stabilizing agent has good stability during storage thereof before development processing and provides stable silver images free from discoloration or fading.Type: GrantFiled: December 6, 1984Date of Patent: February 11, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Yoshio Inagaki, Katsusuke Endo
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Patent number: 4565773Abstract: Dry nonelectroscopic toners comprising pigmented organic resin particles having a size distribution of 0.2 to 30 micrometers, not more than 50 percent of the particles being less than 1 micrometer, surface coated with nonionic siloxane polyoxyalkylene copolymer with a polar end as defined having a hydrophilic lipophilic balance in the range of 7 to 15. The toners are useful in color developing positive- and negative-working photosensitive elements, particularly in automatic toning machine. Good clean-up and low stain propensity are achieved.Type: GrantFiled: November 22, 1983Date of Patent: January 21, 1986Assignee: E. I. Du Pont de Nemours and CompanyInventor: Howard Matrick
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Patent number: 4547457Abstract: Process of preparing dry nonelectroscopic toner comprising pigmented organic resin particles having a size distribution of 0.2 to 30 micrometers, surface coated with at least 0.1% by weight of silicone oil or fluorocarbon compound, in combination with at least 0.5% by weight of a water soluble, polymeric quaternary ammonium compound as defined. The toner is useful in color developing positive- and negative-working photosensitive elements. The toners, particularly magenta and cyan, exhibit high density and excellent stability.Type: GrantFiled: March 30, 1984Date of Patent: October 15, 1985Assignee: E. I. Du Pont de Nemours and CompanyInventors: Eugene L. Grubb, Howard Matrick
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Patent number: 4546072Abstract: Dry nonelectroscopic toner comprising pigmented organic resin particles having a size distribution of 0.2 to 30 micrometers, surface coated with at least 0.1% by weight of silicone oil or fluorocarbon compound, in combination with at least 0.5% by weight of a water soluble, polymeric quaternary ammonium compound as defined. The toner is useful in color developing positive- and negative-working photosensitive elements. The toners, particularly magenta and cyan, exhibit high density and excellent stability.Type: GrantFiled: March 30, 1984Date of Patent: October 8, 1985Assignee: E. I. Du Pont de Nemours and CompanyInventor: Howard Matrick
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Patent number: 4520096Abstract: A photographic element for a silver salt diffusion transfer process is described, comprising a silver halide light-sensitive element, an image receiving element and a processing element, the improvement wherein said photographic element contains a compound represented by formula (I) or (II) ##STR1## wherein the R.sub.Type: GrantFiled: June 13, 1984Date of Patent: May 28, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Katsusuke Endo, Yoshio Inagaki
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Patent number: 4436805Abstract: Disclosed are a developer for silver complex diffusion transfer process which contains a nitrogen-containing heterocyclic compound having a mercapto or thione group and, as substituent, an alkyl group of 4 or more carbon atoms, an aryl group, or a group having both the alkyl and aryl groups and further contains an alkali-soluble iodide in an amount such that the molar ratio of the iodide in terms of iodine to the heterocyclic compound is in the range of from 1:5 to 5:1 and a silver complex diffusion transfer process using said developer, according to which transferred silver images of improved color tone, maximum density, contrast and sharpness can be obtained.Type: GrantFiled: September 27, 1982Date of Patent: March 13, 1984Assignee: Mitsubishi Paper Mills, Ltd.Inventors: Shigeru Iguchi, Seigo Ebato
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Patent number: 4397941Abstract: Dry nonelectroscopic toners comprising pigmented organic resin particles having a size distribution of 0.2 to 30 micrometers, not more than 50 percent of the particles being less than 1 micrometer surface treated with a combination of at least 1% by weight of an antistatic agent and at least 0.5% of a slip agent as described. The preparation of the toners is described. The toners are useful in color developing positive and negative-working photosensitive elements particularly in an automatic toning machine. Improved clean-up and low stain propensity are achieved.Type: GrantFiled: December 29, 1981Date of Patent: August 9, 1983Assignee: E. I. Du Pont de Nemours and CompanyInventor: Michael G. Fickes
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Patent number: 4330613Abstract: Dry nonelectroscopic toners comprising pigmented organic resin particles having a size distribution of 0.2 to 30 micrometers, not more than 50 percent of the particles being less than 1 micrometer surface treated with a combination of at least 1% by weight of an antistatic agent and at least 0.5% of a slip agent as described. The preparation of the toners is described. The toners are useful in color developing positive and negative-working photosensitive elements particularly in an automatic toning machine. Improved clean-up and low stain propensity are achieved.Type: GrantFiled: November 7, 1980Date of Patent: May 18, 1982Assignee: E. I. Du Pont de Nemours and CompanyInventor: Michael G. Fickes
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Patent number: 4275104Abstract: A dry transfer system for transferring indicia to a receiving surface comprises a flexible but dimensionally stable carrier substrate with a film of cohesive, pliable and plastically deformable, indicium-forming material not more than 10 micrometers thick defining a preformed image and adhering to the front surface of the substrate. This surface is composed of a smooth material with adhesive properties such that without relying on adhesive the film can be released and transferred to a receiving surface in close contact, by a pressure transmitted through the substrate, but the film is retained on the carrier substrate in the absence of such pressure, in spite of close contact with the receiving surface.Type: GrantFiled: May 23, 1979Date of Patent: June 23, 1981Assignee: International Hona NVInventor: Erno N. de Nagybaczon
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Patent number: 4242436Abstract: A photographic material suited for use in the silver complex diffusion transfer process and comprising at least one water-permeable layer and including a hydrophilic colloid silver halide emulsion layer in which the silver halide comprises a mixture of silver chloride and silver iodide and/or silver bromide, at least 90 mole % based on the total molar weight of the silver halide being silver chloride, and the ratio by weight of hydrophilic colloid to silver halide expressed as silver nitrate is between about 3:1 and about 10:1, wherein said at least one of the water-permeable layers contains a mixture of developing agents comprising an o-dihydroxybenzene and a 3-pyrazolidinone, the molar amount of the o-dihydroxybenzene in the mixture being larger than the molar amount of the 3-pyrazolidinone.Type: GrantFiled: November 7, 1978Date of Patent: December 30, 1980Assignee: AGFA-GEVAERT N.V.Inventors: Ludovicus M. Mertens, Leon L. Vermeulen
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Patent number: 4242440Abstract: Certain polyacetylenes exhibit reversible color changes at transition temperatures in the range -180.degree. to 220.degree. C., wherein the thermochromic cycles can be repeated many times with no apparent degradation and little change in spectroscopic properties.These thermochromic polyacetylenes are useful in temperature-indicator and indicia-display device applications.A process for laser-beam recording of images is described employing a thermochromic polyacetylene, in which the hysteresis properties of the polyacetylene can be suitably altered allowing for selectively storing or erasing the formed image.Type: GrantFiled: April 30, 1979Date of Patent: December 30, 1980Assignee: Allied Chemical CorporationInventors: Kwok C. Yee, Anthony F. Preziosi, Gordhanbhai N. Patel, Ronald R. Chance, Granville G. Miller, Ray H. Baughman
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Patent number: 4232107Abstract: Said material contains a quinone-type compound which corresponds to one of the formulae (A) or (B) and which is capable in reduced state and under alkaline conditions of releasing a photographically useful group e.g. a dye: ##STR1## wherein: each of (Nuox).sup.1 and (Nuox).sup.2 represents an oxidized nucleophilic group,Z represents a bivalent atomic group which is electronegative,Q together with the Z group represents a releasable photographically useful group,each of R.sup.1, R.sup.2 and R.sup.3 is hydrogen, halogen, alkyl, alkoxy, or an acylamino group or R.sup.1 and R.sup.2 in adjacent positions on the ring form a ring fused with the remainder of the molecule, or R.sup.2 and R.sup.3 together are fused with the remainder of the molecule.each of R.sup.4 and R.sup.5 represents hydrogen or a hydrocarbon group.At least one of the substituents R.sup.1, R.sup.2, R.sup.3, R.sup.4 or R.sup.5 is a ballasting group X.Type: GrantFiled: March 15, 1979Date of Patent: November 4, 1980Assignee: AGFA-GEVAERT N.V.Inventor: Wilhelmus Janssens
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Patent number: 4201582Abstract: Certain mercapto heterocyclic compounds in certain photothermographic and thermographic elements and compositions containing silver salts of certain heterocyclic thione compounds and an organic reducing agent for the silver salts provide improved developed image tone. In the photothermographic element comprising photographic silver halide in association with the silver salt of heterocyclic thione, a developed and stabilized image, in the absence of a separate stabilizer or stabilizer precursor, with improved tone, is provided by heating the element. The photothermographic element and composition can contain a binder.Type: GrantFiled: December 22, 1975Date of Patent: May 6, 1980Assignee: Eastman Kodak CompanyInventor: Richard L. White