Gaseous Sample Or With Change Of Physical State Patents (Class 436/181)
  • Patent number: 7390673
    Abstract: The invention relates to a method for fluorimetrically or photometrically identifying gaseous substances or substances, which can be converted into a gaseous state, in samples. Decomposition reactions, optional purification steps, and detection can be carried out in a cell, which comprises one or more ion-permeable membranes, in a user-friendly and selective manner without losing any substances.
    Type: Grant
    Filed: April 8, 2002
    Date of Patent: June 24, 2008
    Assignee: Merck Patent GmbH
    Inventors: Ingo Klimant, Achim Stangelmayer
  • Patent number: 7387764
    Abstract: An apparatus for analyzing the amount of gas in a solid sample such as a contained oxygen analyzing apparatus and method utilizing a preliminary reducing furnace which can be connected to an analyzing furnace by a transfer unit. A sample such as steel can be reduced in the preliminary reducing furnace and transferred to the analyzing furnace, for example, by a magnetic force, a gripping unit or a transporting sample body holder. A controller can control the application of heat and the mixing of a metal flux to provide discharge gas to an analyzer.
    Type: Grant
    Filed: May 28, 2003
    Date of Patent: June 17, 2008
    Assignee: Horiba, Ltd.
    Inventors: Hiroshi Uchihara, Masahiko Ikeda
  • Patent number: 7381373
    Abstract: A preparative mass spectrometer system includes an ionizer which converts the mixture into gas phase ions of the molecules in the mixture, and a separator which separates the ions according to their mass to charge ratio or mobility. The separator is a linear ion trap mass analyzer that accumulates the ions based on their mass to charge ratio. A surface is in cooperative relationship with the separator so that the separated molecules are soft landed onto the surface at different locations such that the collected molecules can be stored or further processed/analyzed.
    Type: Grant
    Filed: September 16, 2005
    Date of Patent: June 3, 2008
    Assignee: Purdue Research Foundation
    Inventors: Thomas Blake, Zheng Ouyang, Robert G. Cooks
  • Patent number: 7374722
    Abstract: The sampling system of the invention includes a column comprising a first separator associated with a first collector so as to extract particles whose diameter is larger than a first diameter, and a second separator associated with a second collector which eliminates the finest particles and concentrates the other particles in the gas flow sucked up by the suction pipe of an analysis device.
    Type: Grant
    Filed: April 8, 2002
    Date of Patent: May 20, 2008
    Assignee: Proengin SA
    Inventors: Henri Lancelin, Gilles Guene, Patrick Bleuse, Pierre Clausin
  • Patent number: 7374942
    Abstract: A process and apparatus for testing material libraries, in particular catalysts, by means of coupled use of at least two analytical methods, preferably IR thermography and mass spectrometry. Owing to the selected arrangement, the disadvantages of the two previously known individual methods are compensated for: the subsequent selectivity determination for selected sections by means of mass spectrometry invalidates the argument against IR thermography, of only being able to determine activities; the rapid integrated determination of potentially “good” materials via IR thermography prevents an excessive loss of time by needing to test all materials of a library successively with the mass spectrometer.
    Type: Grant
    Filed: March 16, 2001
    Date of Patent: May 20, 2008
    Assignee: BASF Aktiengesellschaft
    Inventors: Jens Klein, Wolfram Stichert, Wolfgang Strehlau, Armin Brenner, Stephan Andreas Schunk, Dirk Demuth
  • Patent number: 7364917
    Abstract: For detecting a component of a substance (of liquid or solid) on a front surface of a substrate, the substrate with the substance thereon is transferred into a vaporizing section, the substance is heated in the vaporizing section so that the component is vaporized from the substance in the vaporizing section, the component vaporized is fed from the substance in the vaporizing section to a detecting section, and the vaporized component is detected in the detecting section.
    Type: Grant
    Filed: March 26, 2004
    Date of Patent: April 29, 2008
    Assignee: Hitachi High-Tech Control Systems Corporation
    Inventors: Satoshi Ichimura, Masami Sakamoto, Toshio Iwasaki
  • Patent number: 7361311
    Abstract: A method of separating species in a mixture of molecules, particles or atoms and collecting the separated species is described. The method comprises the steps of converting by ionization the species in the mixture to gas phase ions, separating the gas phase ions according to their mass charge ratio and/or mobility and collecting the separated ions. The system includes ionizing means such as electrospray to form the gas phase ions. The gas phase ions are separated by filtering, or in time or in space and soft-landed for collection such as on a surface.
    Type: Grant
    Filed: December 31, 2002
    Date of Patent: April 22, 2008
    Assignee: Purdue Research Foundation
    Inventors: Robert G. Cooks, Zheng Ouyang
  • Patent number: 7341694
    Abstract: In an ammonia sensor (1), lead portions (7) and (9) are provided on an insulating substrate (5); a pair of comb-shaped electrodes (11) and (13) are connected to the lead portions (7) and (9), respectively; a sensitive layer (15) is provided on the comb-shaped electrodes (11) and (13); and a protective layer (17) is provided on the sensitive layer (15). Particularly, the sensitive layer (15) is formed of a gas-sensitive raw material predominantly containing ZrO2 and containing at least W in an amount of 2 to 40 wt. % as reduced to WO3.
    Type: Grant
    Filed: September 25, 2003
    Date of Patent: March 11, 2008
    Assignee: NGK Spark Plug Co., Ltd.
    Inventors: Hiroyuki Nishiyama, Shiro Kakimoto, Ryuji Inoue, Hitoshi Yokoi, Noboru Ishida, Takafumi Oshima, Satoshi Sugaya, Koichi Imaeda, Tadashi Hattori, Atsushi Satsuma
  • Patent number: 7337616
    Abstract: A system for sampling cryogenic liquids, and an air separation unit provided with at least one such system. The cryogenic liquid is introduced into a vaporizer, through heat exchange with the compressed air. The liquid passes through the vaporizer generally downwards. The walls of the vaporizer that are intended to come into contact with the cryogenic liquid are maintained at a temperature above the sublimation temperature or the boiling point of the least volatile impurity contained in this liquid. Downstream of the vaporizer, a gaseous phase coming from the vaporization of the cryogenic liquid is withdrawn and at least some of the gaseous phase is sent to an analyzer.
    Type: Grant
    Filed: April 25, 2003
    Date of Patent: March 4, 2008
    Assignee: L'Air Liquide, Societe Anonyme A Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: David Meneses, Jean-Yves Thonnelier, Jean-Yves Lehman
  • Patent number: 7335513
    Abstract: A parallel reactor system including a reactor and vessels in the reactor for holding reaction mixtures, and a cannula for introducing fluid reaction material into the vessels. A robot system is operable to insert the cannula into cannula passages in the reactor for delivery of reaction materials, including condensed gases, to respective vessels, and to withdraw the cannula from the cannula passages after delivery. Related methods are also disclosed.
    Type: Grant
    Filed: January 28, 2002
    Date of Patent: February 26, 2008
    Assignee: Symyx Technologies, Inc.
    Inventors: Matthew F. Smith, John F. Varni, G. Cameron Dales, Trevor G. Frank, Rakesh Jain, Lynn Van Erden
  • Patent number: 7323343
    Abstract: An analytical system is provided for determining nitrogen monoxide, nitrogen dioxide and ozone concentrations in air samples. An ultraviolet light source 4 is used to alter the equilibrium between nitrogen dioxide and oxygen on the one hand and nitrogen monoxide and ozone on the other. Dynamic measurement of ozone concentration with time while ultraviolet irradiation is pulsed enables each gas concentration to be calculated without requiring input gases to be scrubbed. An aApparatus 101 is further provided to provide a controlled flow of gas to a sensor 103 attached to a high altitude balloon while sheltering it from the elements and allowing for affects of temperature, said apparatus comprising a shield 104 and a gas conducting means which uses the venturi effect to control air flow or has a hole to allow water to drain without affecting air flow past the sensor.
    Type: Grant
    Filed: July 13, 2004
    Date of Patent: January 29, 2008
    Assignee: Cambridge University Technical Services Limited
    Inventors: Richard Anthony Cox, Roderic Lewis Jones
  • Patent number: 7323344
    Abstract: A method is provided for the quantitative analysis of the contents, in nitrogen, of hydrogen and methane by ionic mobility spectrometry. The method includes the steps of: a) performing a measurement of the apparent hydrogen concentration in the nitrogen to be analyzed; b) performing a measurement of the apparent hydrogen concentration in a flow of the same sample of nitrogen, purified of all impurities but methane; and c) comparing the two measurements. A system of branched lines is also provided for carrying out the method.
    Type: Grant
    Filed: November 6, 2003
    Date of Patent: January 29, 2008
    Assignee: Saes Getters S.p.A.
    Inventors: Luca Pusterla, Marco Succi
  • Patent number: 7318908
    Abstract: Integrated nanotube sensors are adapted for detecting various chemical and biological molecules. In one implementation, nanotube sensor arrays are formed as nano-electronic noses capable of such detection, and can be implemented in devices including carbon nanotube-based electronic noses and biochips. Various implementations of the present invention are also directed to nanoscience and nanotechnology applications, such as medical, military and biological applications. In a more particular implementation, nanotubes are produced on full-scale wafers and functionalized. In another more particular implementation, functionalized nanotubes are integrated into addressable devices. With these approaches, various aspects of the present invention have been found to be useful in sensor applications having small size, high density and extreme sensitivity. Such sensor applications are applicable to many aspects of society, and can be implemented for making human lives more safe, secure and healthy.
    Type: Grant
    Filed: October 31, 2002
    Date of Patent: January 15, 2008
    Assignee: The Board of Trustees of the Leland Stanford Junior University
    Inventor: Hongjie Dai
  • Patent number: 7319039
    Abstract: The presence of an aerosol or cloud (3) of a toxic substance is detected by producing an aerosol (17, 5) of ligands (13) to the target substance in a region of sky that contains the target substance, permitting molecules the target substance to bind to the ligand, directing light (7, 21) of a first frequency into the revised aerosol; and then inspecting (9, 25) the revised aerosol for emissions of light of a second frequency. When light of the second frequency exists an alarm (15, 31) is initiated.
    Type: Grant
    Filed: November 9, 2004
    Date of Patent: January 15, 2008
    Assignee: Northrop Grumman Corporation
    Inventor: Brian M. Sullivan
  • Patent number: 7310992
    Abstract: The present invention provides a device for continuous real-time monitoring of ambient air. The device includes a receptacle, a liquid supply, and a pressure balancing system. The receptacle includes a gas inlet slit located such that the gas inlet slit is covered by liquid within the receptacle during use. The pressure balancing portion of the present device includes communication between a point within the receptacle above the liquid level in the receptacle, as well as a liquid inlet portion at the lowermost end of the receptacle, and an air space above a liquid supply portion and the liquid supply portion itself, respectively.
    Type: Grant
    Filed: September 27, 2005
    Date of Patent: December 25, 2007
    Assignee: Sceptor Industries, Inc.
    Inventors: Freeman Swank, Christopher Tesluk
  • Patent number: 7306953
    Abstract: A method of determining the cause of disease is described, which method uses the detection of “signature” or “fingerprint” volatile compounds in an emission, especially flatus, from a patient.
    Type: Grant
    Filed: January 14, 2005
    Date of Patent: December 11, 2007
    Assignee: The University of the West of England, Bristol
    Inventors: Christopher Simon J. Probert, Norman Mark Ratcliffe
  • Patent number: 7297549
    Abstract: A method of determining bias in a measurement of a constituent concentration level in a sample gas is provided. The method comprises establishing a sample gas flow from an emission stream into a sample gas line of an emissions monitoring system. The method further comprises removing water from the sample gas flow and cooling the sample gas flow to a temperature below about 41° F. to produce a cooled, dried sample gas flow. The constituent concentration level is then determined for the cooled, dried sample gas flow. The method further comprises introducing a span gas having a known span gas constituent concentration level into the sample gas flow to form a combined sample and span gas flow, the span gas being introduced at a desired span gas flow rate. The method still further comprises removing water from the combined sample and span gas and cooling the combined sample and span gas to a temperature below about 41° F. to produce a cooled, dried, combined sample and span gas flow.
    Type: Grant
    Filed: March 6, 2002
    Date of Patent: November 20, 2007
    Assignee: General Electric Company
    Inventors: William Steven Lanier, Glenn England
  • Patent number: 7287391
    Abstract: Modular expandable hyperpolarizers include a central control module and at least one optical pumping module that can be expandable to a plurality of optical pumping modules that can be separately operated depending on the capacity demands at the production site (hospital, clinic and the like). Methods for producing blended polarized gas products include introducing a pre-packaged pre-mixed amount of a polarizer-ready blend of unpolarized gas. Methods for producing the polarized gas can be carried out at the point of use site and the production run according to patient load. Other methods consider the patient load and automatically schedule the hyperpolarizer to yield the desired polarized gas doses to support the patient and/or MRI/NMR equipment schedule.
    Type: Grant
    Filed: October 22, 2002
    Date of Patent: October 30, 2007
    Assignee: Medi-Physics, Inc.
    Inventor: Kenneth Bolam
  • Patent number: 7287390
    Abstract: Hyperpolarizers for producing polarized noble gases can include: (a) a control module configured to direct the operation of a hyperpolarizer to produce polarized noble gas via spin-exchange interactions between a noble gas and an alkali metal; (b) at least one optical pumping module including an optical pumping cell operably associated with the control module; (c) a dispensing system operably associated with the control module and the optical pumping module to dispense meted volumes of polarized gas from the hyperpolarizer; and (d) a fluid distribution system operably associated with the control module, the optical pumping module, and the dispensing system, such that, in response to commands transmitted from the control module, the fluid distribution system operates to automatically direct purge gas into and out of a gas travel path that extends from the control module to the optical pumping cell prior to commencing the spin-exchange interactions in the optical pumping cell, then to receive unpolarized gas an
    Type: Grant
    Filed: October 22, 2002
    Date of Patent: October 30, 2007
    Assignee: Medi-Physics, Inc.
    Inventor: Kenneth Bolam
  • Patent number: 7285246
    Abstract: A hand-held device detects the presence of a preselected substance in the breath. A deformable housing forms a test chamber for interacting an indicator reagent with the breath. An ampoule positioned inside the housing is ruptured by manual pressure through the walls of the housing. The contents of the ruptured ampoule are exposed to the breath introduced into the chamber. The presence of a substance in the breath causes the indicator reagent to undergo a visually ascertainable change. The ampoule is secured within the housing by a pair of filter plugs having inboard concavities to receive the rounded ends of the ampoule to center it within the housing, and plural detents prevent slippage of the filters. Additional embodiments lower the user's risk of being cut by glass shards, prevent reagent inhalation, enhance the visual aspects of the device, and physically indicate the presence of breath flowing through the device.
    Type: Grant
    Filed: August 19, 2003
    Date of Patent: October 23, 2007
    Assignee: Akers Acquisition Sub, Inc.
    Inventor: Lawrence Martin
  • Patent number: 7273588
    Abstract: Methods for determining the amount of at least one metal analyte present in a liquid or gas sample of a halosilane supply (e.g., a chlorosilane supply) are disclosed herein. A sample of a halosilane supply is contacted and reacted with an aqueous hydrofluoric acid solution to produce a liquid reaction mixture. Liquid from the liquid reaction mixture is evaporated under controlled temperature and pressure conditions to near dryness. The nearly-dry residue is prepared for spectral analysis. The presence of a detectable amount of at least one metal analyte is determined for the sample.
    Type: Grant
    Filed: July 17, 2003
    Date of Patent: September 25, 2007
    Assignee: Air Liquide America L.P.
    Inventors: Daniel C. Cowles, David S. Bollinger
  • Patent number: 7267987
    Abstract: A process and an assembly for simultaneously evaluating a plurality of catalysts is provided wherein the flow rate of a reactive fluid to each of a plurality of reactors is automatically adjusted based on the measured amount of catalyst sample in each reactor to concurrently obtain a substantially identical fluid space velocity in each of the reactors.
    Type: Grant
    Filed: January 6, 2003
    Date of Patent: September 11, 2007
    Assignee: UOP LLC
    Inventors: Maureen L. Bricker, J. W. Adriaan Sachtler, Charles P. McGonegal, Mark A. Krawczyk, Ara J. Alexanian, Martin Plassen
  • Patent number: 7255837
    Abstract: An airtight configuration for keeping down the permeation of corrosive gas from silicone adhesive, and for preventing corrosive gas from entering the case. An electronic device mounted on vehicle. The electronic device has at least one of a portion connecting components, and a portion sealing the clearance or hole where exists in the electronic device. The at least one of the connection portion and the seal portion is constituted by using adhesive or sealant which has at least one of a function adsorbing corrosive gas and a function trapping corrosive gas with chemical reaction. A car-mounted electronic device characterized by reduced permeation of corrosive gas into a case and high reliability.
    Type: Grant
    Filed: September 20, 2002
    Date of Patent: August 14, 2007
    Assignees: Hitachi, Ltd., Hitachi Car Engineering Co., Ltd.
    Inventors: Hiroyuki Abe, Shinya Igarashi
  • Patent number: 7256052
    Abstract: This invention is to a microreactor type of reaction and analysis system. The system includes a chemical reaction chamber having internal conduits through which a chemical reactant, such as a reaction gas, can be fed. The conduits for transporting fluids such as reactant, carrier gas and balance gas are in appropriate communication such that the amount of reactant going directly to a catalyst located in the reaction chamber can be optimally controlled. The system is highly useful for studying the kinetics of a chemical reaction.
    Type: Grant
    Filed: October 18, 2002
    Date of Patent: August 14, 2007
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Nicolas P. Coute, John K. Pierce
  • Patent number: 7250138
    Abstract: A system and method for detecting the presence of submicron sized particles in a sample taken from the environment includes a collecting a sample from the environment and purifying and concentrating the submicron particles in a sample based on the size of the particles. The purified and concentrated particles are detected with an apparatus which includes an electrospray assembly having an electrospray capillary, a differential mobility analyzer which receives the output from the capillary, and a condensation particle device for counting the number of particles that pass through the differential mobility analyzer.
    Type: Grant
    Filed: December 9, 2002
    Date of Patent: July 31, 2007
    Assignee: United States of America as respresented by the Secretary of the Army
    Inventor: Charles Harold Wick
  • Patent number: 7247496
    Abstract: The measurement of the particle size distribution of an aerosol is of crucial importance in pharmaceutical development. A prerequisite for this is a valid method, e.g. the cascade impactor method described in the pharmacopoeias. It requires measurement of the active substance concentration in order to determine the particle size distribution. The invention provides a process which makes it possible to measure the size of aerosol droplets containing pharmaceutical substances which are unstable in the event of changes in the pH.
    Type: Grant
    Filed: July 24, 2002
    Date of Patent: July 24, 2007
    Assignee: Boehringer Ingelheim International GmbH
    Inventors: Dieter Hochrainer, Georg Boeck, Hubert Hoelz, Christian Scheffler, Christoph Kreher
  • Patent number: 7247495
    Abstract: The invention provides a mass spectrometric method for analyzing a sample in a solution, including the steps of directing a flow of a solution containing sample compounds to be analyzed towards a supersonic nozzle having an input end and an output end; vaporizing the solution and sample prior to its expansion from the output end of said supersonic nozzle; allowing expansion of the vaporized sample and solution from said supersonic nozzle into a vacuum system, forming a supersonic molecular beam with vibrationally cold sample molecules; ionizing the vaporized sample compounds with electrons while contained as vibrationally cold molecules in said supersonic molecular beam; mass analyzing the ions formed from said sample compounds; detecting said ions formed from said sample compounds after mass analysis, and processing the data obtained from the resulting mass spectral information, for identifying and/or quantifying the chemical content of said sample.
    Type: Grant
    Filed: August 15, 2002
    Date of Patent: July 24, 2007
    Inventor: Aviv Amirav
  • Patent number: 7229832
    Abstract: A process and apparatus for rapidly screening materials using, for example, mass spectrometry has been developed. More specifically, an array of materials on a fluid permeable support contained within a reaction cell having a semipermeable membrane can be rapidly screened for characteristics such as catalytic activity, selectivity, and adsorption and desorption properties.
    Type: Grant
    Filed: September 18, 2003
    Date of Patent: June 12, 2007
    Assignee: UOP LLC
    Inventors: Amit Nayar, Renxuan Liu, Richard R. Willis, Eugene R. Smotkin
  • Patent number: 7229593
    Abstract: An apparatus for measuring the effective vapor diffusion coefficient of a test vapor diffusing through a sample of porous media contained within a test chamber. A chemical sensor measures the time-varying concentration of vapor that has diffused a known distance through the porous media. A data processor contained within the apparatus compares the measured sensor data with analytical predictions of the response curve based on the transient diffusion equation using Fick's Law, iterating on the choice of an effective vapor diffusion coefficient until the difference between the predicted and measured curves is minimized. Optionally, a purge fluid can forced through the porous media, permitting the apparatus to also measure a gas-phase permeability. The apparatus can be made lightweight, self-powered, and portable for use in the field.
    Type: Grant
    Filed: October 25, 2002
    Date of Patent: June 12, 2007
    Assignee: Sandia Corporation
    Inventor: Clifford K. Ho
  • Patent number: 7220388
    Abstract: Apparatus and method for increasing the concentration of a chemical substance in a fluid comprise a micro-fluidic elongated channel formed in a substrate, with the channel being in fluid-flow communication with an ambient region along its elongated dimension. In general, the fluid includes first and second chemical substances having different vapor pressures. The apparatus includes an evaporation controller for increasing the evaporation rate of the fluid from the channel into the ambient region, thereby increasing the concentration of the higher vapor pressure (HVP) substance in the portion of the fluid remaining in the channel and increasing the concentration of the lower vapor pressure (LVP) substance in the portion of the fluid evaporated into the ambient region.
    Type: Grant
    Filed: February 25, 2004
    Date of Patent: May 22, 2007
    Assignee: Lucent Technologies Inc.
    Inventors: David John Bishop, John VanAtta Gates, Marc Scott Hodes, Avinoam Kornblit, Stanley Pau, Brijesh Vyas
  • Patent number: 7220383
    Abstract: An analytical apparatus to monitor fluid systems has at least one extraction module having a raw-sample reservoir connected by input fluid conduit to individual ones of said fluid systems, to extract raw samples for analysis from said fluid systems, one or more modification modules comprising additive materials to modify the extracted raw samples prior to analysis, an analytical device to receive at least a portion of said raw samples in an ordered sequence, and to determine concentration of at least one constituent of said sample portion, fluid-handling apparatus for transferring fluid through the analytical apparatus, and a computerized control and management system to manage operations of component modules and devices, and to report analytical results.
    Type: Grant
    Filed: February 28, 2002
    Date of Patent: May 22, 2007
    Assignee: Metara, Inc.
    Inventors: Marc R. Anderson, Larry N. Stewart, Howard M. Kingston
  • Patent number: 7208123
    Abstract: A flow-through monitor for detecting molecular contamination (MC) within a fluid flow. The monitor has a diffusion chamber having an inlet port and an outlet port, and a structure for supporting a fluid flow from the inlet port to the outlet port. The structure includes a flow gap causing a diffusion of molecular contaminants into the diffusion chamber, while substantially preventing, for a rate of the fluid flow above a predetermined magnitude, particulate contaminants within the fluid from entering the diffusion chamber. A SAW device detects molecular contamination interior to the diffusion chamber. Fluid input to the flow-through monitor may be diluted by a pure fluid for extended monitor life. A system for aggregate sampling connects an ensemble manifold upstream of the flow-through monitor. A system for triggered sampling connects a sample preconcentrator downstream of the flow-through monitor. A chemically selective membrane may be located between the flow gap and the SAW.
    Type: Grant
    Filed: June 24, 2002
    Date of Patent: April 24, 2007
    Assignee: Particle Measuring Systems, Inc.
    Inventors: Brian A. Knollenberg, Daniel Rodier, Scott Waisanen
  • Patent number: 7201874
    Abstract: A system for quickly and automatically extracting and analysing residual solvents is realised for operating directly in the premises where the packing materials are being manufactured, printed and/or laminated. The system provides for a single unit equipped with a display and a keyboard, and comprises an extraction (desorption) chamber (1), an analysis chamber with valves and separating columns, a detection system (17), and a data processing system (19). The extracting or desorption chamber comprises a desorption cell (1) for receiving a vial (36; 37) containing said sample, and means are provided to keep the inside of said cell (1) at a pressure higher that that of the surrounding environment until a new sample has been introduced into the cell, thus accomplishing a “washing” of cell for eliminating polluting solvents coming from the desorption of a preceding sample and/or solvents present in the surrounding environment.
    Type: Grant
    Filed: March 14, 2001
    Date of Patent: April 10, 2007
    Inventor: Carlo Squicciarini
  • Patent number: 7201878
    Abstract: Aerosol particle analyzer (APA) for measuring an analyte in airborne particle is described. Airborne particles are first given an electrical charge and then drawn in air past an oppositely charged volume of an analysis liquid that exposed to the air at a small hole in a container, such as a capillary, that holds that analysis liquid. Electrostatic forces enhance the rate that the airborne particles collide with the small exposed volume of the analysis liquid in the hole. If the particles that collide with the analysis liquid contain the analyte, an optical property of the analysis liquid, such as the fluorescence, varies according to the amount of the analyte in the particles. This optical property is measured and the amount of analyte in the particles is determined from the measured optical property.
    Type: Grant
    Filed: March 26, 2004
    Date of Patent: April 10, 2007
    Assignee: The United States of America as Represented by the Secretary of the Army
    Inventors: Horn-Bond Lin, Steven Clyde Hill
  • Patent number: 7201879
    Abstract: An aerosol-into-liquid collector (ALC) for collecting gas-borne particles from a large volume of gas such as air into a small volume of liquid is described. The ALC uses a linear quadrupole to concentrate particles flowing in a gas and to help direct these concentrated particles toward a small volume of collection liquid so that these particles tend to combine with a small volume of collection liquid that can then be drawn from the ACL for further analysis. The particles in the gas are typically given a charge that is opposite to that of the charge imparted to the volume of collection liquid so that electrostatic forces help draw particles from the flowing gas into the small volume of liquid. The linear quadrupole focuses toward it axis particles that have the charge, mass and mobility to be stable in the linear quadrupole.
    Type: Grant
    Filed: November 19, 2004
    Date of Patent: April 10, 2007
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: Steven Clyde Hill, Horn-Bond Lin
  • Patent number: 7197949
    Abstract: A sampling system for detecting an analyte, comprising a diaphragm pump, a buffer chamber, a sensor head and intake port. The pump includes a chamber for receiving fluids via first and second ports. A buffer chamber is located at the second port for holding a quantity of air, and a sensor head is adapted to identify the presence of a desired analyte and produce a signal in response to the quantity identified. Preferably the diaphragm pump has a volume of gas per stroke capacity slightly larger than the volume of the sensor head such that the pump chamber has a greater volume than the buffer chamber and the buffer chamber has about the same volume as the sensor head. A sensor intake port intakes a sample potentially containing the analyte for contact with the sensor head upon operation of the diaphragm pump and out of the sensor head by jet-action caused by rapid movement of the diaphragm pump. A filter may be used for filtering air drawn through the pump chamber.
    Type: Grant
    Filed: April 2, 2002
    Date of Patent: April 3, 2007
    Assignee: Honeywell International Inc.
    Inventors: J. David Zook, Cleopatra Cabuz
  • Patent number: 7198952
    Abstract: An upstream side catalyst and a downstream side catalyst are disposed in an exhaust passage. A first oxygen sensor is disposed between these two catalysts and a second oxygen sensor is disposed downstream of the downstream side catalyst. The air-fuel ratio is forcibly oscillated and the oxygen storage capacity of the upstream side catalyst is detected. Deterioration of the upstream side catalyst is then detected based on whether this oxygen storage capacity is larger than a predetermined value. The forced oscillation of the air-fuel ratio is performed only when the oxygen storage state of the downstream side catalyst is appropriate.
    Type: Grant
    Filed: July 15, 2002
    Date of Patent: April 3, 2007
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Takahiro Uchida, Hiroshi Sawada, Toshinari Nagai, Akihiro Katayama, Yasuhiro Kuze, Naoto Kato
  • Patent number: 7191670
    Abstract: A method and system for automated remote microbial air sampling includes a sampling enclosure positioned outside an isolator. An infeed sample receiver passes sample containers into the enclosure. An atrium is located within the enclosure and exposes containers to a gas sample. A remote sampling device collects the gas sample from the isolator and passes it to the atrium. A load arm is located within the enclosure. The load arm intermittently permits containers to enter the enclosure and moves containers to the atrium. An outfeed sample receiver passes containers out of the enclosure. The system allows addition and removal of containers from the air sampling system without interrupting the processing of the containers within the enclosure, and allows the first container supplied to the air sampling system to be the first exposed container removed therefrom.
    Type: Grant
    Filed: July 27, 2005
    Date of Patent: March 20, 2007
    Assignee: Hospira. Inc.
    Inventor: Alan H. Aicher
  • Patent number: 7189363
    Abstract: Of a gas detector 100, a chamber 105 formed between a center cover 150 and a cover 160 is a part of an air flow channel AF. A first shielding plate 165 is provided in the chamber 105. Water droplets that have entered the chamber from a chamber entrance 103 with air hit and adhere to an entrance-opposed surface 165E of the first shielding plate 165. The water thus adhering to the surface is pushed by the air flowing along the entrance-opposed surface 165E and by gravity, to thereby advance downward. The water then drips downward and is accumulated on a bottom wall surface 105WD which serves as an upper surface of a bottom wall section 161WD. The water is pushed by the flow of air, to thereby advance toward a chamber exit 104. The water is then drained downward from the chamber exit 104.
    Type: Grant
    Filed: May 23, 2003
    Date of Patent: March 13, 2007
    Assignee: NGK Spark Plug Co., Ltd.
    Inventors: Norimasa Osawa, Kazuto Hirai, Yuichi Koyama
  • Patent number: 7189579
    Abstract: A method and device for measuring release rates of contaminants in at least one of a fast release mode and a slow release mode in which a volatile liquid sample is introduced into a sealed transparent reactor vessel having at least one sorbent contained within the transparent reactor vessel and a separator for preventing direct contact between the at least one adsorbent and the at least one volatile liquid sample in the transparent reactor vessel, whereby substantially zero headspace is maintained within the transparent reactor vessel. At least one solvent soluble constituent present in the at least one volatile liquid sample is passed through the separator, resulting in sorption of the at least one solvent soluble constituent by the at least one sorbent. In accordance with one preferred embodiment, the separator is a dialysis bag contained in the transparent reactor vessel into which the resin is placed.
    Type: Grant
    Filed: February 22, 2002
    Date of Patent: March 13, 2007
    Assignee: Gas Technology Institute
    Inventors: Bhupendra K. Soni, Thomas D. Hayes
  • Patent number: 7179656
    Abstract: Disclosed is an apparatus for rapidly screening chemicals for their ability to sublime. The apparatus consists of a heated well plate, where the chemicals are deposited, and a cooled finger plate, holding fingers that penetrate each well. The two plates touch at only the perimeter in order to facilitate a vacuum seal and to reduce any thermal transfer.
    Type: Grant
    Filed: July 3, 2002
    Date of Patent: February 20, 2007
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Daniel David Lecloux, Steven J. Medwin, Eric Maurice Smith
  • Patent number: 7172730
    Abstract: A thermal sensor has a substrate defining a reaction chamber. The reaction chamber has an inlet for conducting sample into the reaction chamber, a reaction surface and an orifice adjacent the reaction surface defining an outlet from the reaction chamber. The reaction surface is coated with a sorbant for binding agents in the sample. A heat transducer in the substrate and in proximity to the reaction surface is configured for heating the reaction surface.
    Type: Grant
    Filed: December 9, 2002
    Date of Patent: February 6, 2007
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventor: Steven E. Carpenter
  • Patent number: 7153694
    Abstract: A method for quantitative determination of hydrocarbon species in a hydrocarbon sample is disclosed. The method uses Townsend Discharge Nitric Oxide Chemical Ionization Gas Chromatography/Mass Spectrometry.
    Type: Grant
    Filed: November 26, 2002
    Date of Patent: December 26, 2006
    Assignee: Shell Oil Company
    Inventors: Knox Alex Evans, Weijan Mo, Howard Peterson, Ismet Dzidic
  • Patent number: 7153475
    Abstract: Aerosol particle analyzer (APA) for measuring the amount of analyte in airborne particle is described. The APA uses an analysis liquid. In most embodiments, this analysis liquid is chosen so that when it is mixed with the particles, an optical property of the analysis liquid (AL) varies according to the amount of the analyte in the particles. Airborne particles are drawn into the instrument, and detected using optical methods such as light scattering or laser-induced fluorescence. When a particle of interest is detected, a charged droplet of the analysis liquid (CDAL) is ejected so that it collides with the detected particle and moves into a horizontally oriented linear quadrupole that is in an airtight container, except for small orifices to let the CDAL enter and exit.
    Type: Grant
    Filed: May 9, 2005
    Date of Patent: December 26, 2006
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: Steven Clyde Hill, Richard Kounai Chang, Jean-Pierre Wolf
  • Patent number: 7150994
    Abstract: Parallel flow reaction systems comprising four or more reaction channels are disclosed. Distribution systems, and parallel flow reaction systems comprising such distribution systems are also disclosed. Specifically, the distribution systems comprise one or more subsystems, including for example, a flow-partitioning subsystem for providing a different flow rate to each of the four or more reactors, a pressure-partitioning subsystem for providing a different reaction pressure in the reaction cavity of each of the four or more reactors, and a feed-composition subsystem for providing a different feed composition to each of the four or more reactors. In preferred embodiments, the one or more subsystems can comprise at least one set of four or more flow restrictors, each of the four or more flow restrictors having a flow resistance that varies relative to other flow restrictors in the set.
    Type: Grant
    Filed: March 7, 2001
    Date of Patent: December 19, 2006
    Assignee: Symyx Technologies, Inc.
    Inventors: H. Sam Bergh, James R. Engstrom, Shenheng Guan, Daniel Meron Pinkas, Kyle W. Self
  • Patent number: 7144736
    Abstract: A method and an apparatus which continuously separate and measure mercury in an exhaust gas in accordance with each chemical conformation and display a measurement result in real time. According to the method and the apparatus, water-soluble mercury in a gas is absorbed into an absorption solution (7), the gas and the absorption solution (7) are then separated from each other, the water-soluble mercury in the absorption solution (7) is reduced to be converted into gaseous metal mercury and led to an analyzer (20), and metal mercury in the gas which is not absorbed into the absorption solution (7) is led to an analyzer (22) in the form of gas. As a result, the water-soluble mercury and the non-water-soluble mercury contained in the gas can be captured and measured/analyzed in respective measurement systems in accordance with each chemical conformation. In addition, a concentration of the metal mercury and that of the water-soluble mercury in the gas can be continuously monitored in real time.
    Type: Grant
    Filed: June 25, 2001
    Date of Patent: December 5, 2006
    Assignees: Central Research Institute of Electric Power Industry, Nippon Instruments Corporation
    Inventors: Naoki Noda, Shigeo Ito, Koji Marumoto, Koji Tanida, Munehiro Hoshino
  • Patent number: 7129093
    Abstract: A method of determining beryllium or a beryllium compound thereof in a sample, includes providing a sample suspected of comprising beryllium or a compound thereof, extracting beryllium or a compound thereof from the sample by dissolving in a solution, adding a fluorescent indicator to the solution to thereby bind any beryllium or a compound thereof to the fluorescent indicator, and determining the presence or amount of any beryllium or a compound thereof in the sample by measuring fluorescence.
    Type: Grant
    Filed: March 30, 2004
    Date of Patent: October 31, 2006
    Assignee: Los Alamos National Security, LLC
    Inventors: T. Mark McCleskey, Deborah S. Ehler, Kevin D. John, Anthony K. Burrell, Gavin E. Collis, Edel M. Minogue, Benjamin P. Warner
  • Patent number: 7125518
    Abstract: Aerosol particle analyzer (APA) for measuring the amount of analyte in airborne particle is described. The APA uses an analysis liquid. When this analysis liquid is mixed with the particles, an optical property of the analysis liquid (CDAL) varies according to the amount of the analyte in the particles. A charged droplet of the analysis liquid is levitated. Airborne particles are drawn into the instrument and given a charge that is opposite that of the CDAL, and made to flow near the CDAL so that electrostatic forces greatly increase the probability that the CDAL and charged particles will combine. Then the CDAL is ejected into a horizontally oriented linear quadrupole that is in an airtight container, except for a small orifice to let the CDAL enter. The CDAL is levitated in a high humidity environment so that it evaporates slowly, so that there is time for the reaction between the analyte, if any, and the CDAL can take place, and so that the optical property, typically fluorescence, can be measured.
    Type: Grant
    Filed: February 14, 2004
    Date of Patent: October 24, 2006
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventor: Steven Clyde Hill
  • Patent number: 7118920
    Abstract: Multiphasic reactions, especially those reactions using a phase transfer catalyst, are conducted in microchannel apparatus. Advantageously, these reactions can be conducted with two, planar microlayers of reactants in adjacent laminar flow streams. Microchannel apparatus and methods for conducting unit operations such as reactions and separations in microchannel apparatus is also described. Microchannel apparatus can provide advantages for controlling reactions and separating products, solvents or reactants in multiphase reactions.
    Type: Grant
    Filed: October 22, 2002
    Date of Patent: October 10, 2006
    Assignee: Battelle Memorial Institute
    Inventors: John H. Brophy, Bruce F. Monzyk
  • Patent number: RE39353
    Abstract: The system for analyzing multiple samples includes a plurality of portable of sample supports each for accommodating a plurality of samples thereon, and an identification mechanism for identifying each sample location on each of the plurality of sample supports. The mass spectrometer is provided for analyzing each of the plurality of samples when positioned within a sample receiving chamber, and a laser source strikes each sample with a laser pulse to desorb and ionize sample molecules. The support transport mechanism provided provides for automatically inputting and outputting each of the sample supports from the sample receiving chamber of the mass spectrometer. A vacuum lock chamber receives the sample supports and maintains at least one of the sample supports within a controlled environment while samples on another of the plurality of sample supports are being struck with laser pulses.
    Type: Grant
    Filed: January 4, 2001
    Date of Patent: October 17, 2006
    Assignees: Applera Corporation, MDS, Inc.
    Inventor: Marvin L. Vestal