Gaseous Sample Or With Change Of Physical State Patents (Class 436/181)
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Patent number: 7390673Abstract: The invention relates to a method for fluorimetrically or photometrically identifying gaseous substances or substances, which can be converted into a gaseous state, in samples. Decomposition reactions, optional purification steps, and detection can be carried out in a cell, which comprises one or more ion-permeable membranes, in a user-friendly and selective manner without losing any substances.Type: GrantFiled: April 8, 2002Date of Patent: June 24, 2008Assignee: Merck Patent GmbHInventors: Ingo Klimant, Achim Stangelmayer
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Patent number: 7387764Abstract: An apparatus for analyzing the amount of gas in a solid sample such as a contained oxygen analyzing apparatus and method utilizing a preliminary reducing furnace which can be connected to an analyzing furnace by a transfer unit. A sample such as steel can be reduced in the preliminary reducing furnace and transferred to the analyzing furnace, for example, by a magnetic force, a gripping unit or a transporting sample body holder. A controller can control the application of heat and the mixing of a metal flux to provide discharge gas to an analyzer.Type: GrantFiled: May 28, 2003Date of Patent: June 17, 2008Assignee: Horiba, Ltd.Inventors: Hiroshi Uchihara, Masahiko Ikeda
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Patent number: 7381373Abstract: A preparative mass spectrometer system includes an ionizer which converts the mixture into gas phase ions of the molecules in the mixture, and a separator which separates the ions according to their mass to charge ratio or mobility. The separator is a linear ion trap mass analyzer that accumulates the ions based on their mass to charge ratio. A surface is in cooperative relationship with the separator so that the separated molecules are soft landed onto the surface at different locations such that the collected molecules can be stored or further processed/analyzed.Type: GrantFiled: September 16, 2005Date of Patent: June 3, 2008Assignee: Purdue Research FoundationInventors: Thomas Blake, Zheng Ouyang, Robert G. Cooks
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Patent number: 7374722Abstract: The sampling system of the invention includes a column comprising a first separator associated with a first collector so as to extract particles whose diameter is larger than a first diameter, and a second separator associated with a second collector which eliminates the finest particles and concentrates the other particles in the gas flow sucked up by the suction pipe of an analysis device.Type: GrantFiled: April 8, 2002Date of Patent: May 20, 2008Assignee: Proengin SAInventors: Henri Lancelin, Gilles Guene, Patrick Bleuse, Pierre Clausin
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Patent number: 7374942Abstract: A process and apparatus for testing material libraries, in particular catalysts, by means of coupled use of at least two analytical methods, preferably IR thermography and mass spectrometry. Owing to the selected arrangement, the disadvantages of the two previously known individual methods are compensated for: the subsequent selectivity determination for selected sections by means of mass spectrometry invalidates the argument against IR thermography, of only being able to determine activities; the rapid integrated determination of potentially “good” materials via IR thermography prevents an excessive loss of time by needing to test all materials of a library successively with the mass spectrometer.Type: GrantFiled: March 16, 2001Date of Patent: May 20, 2008Assignee: BASF AktiengesellschaftInventors: Jens Klein, Wolfram Stichert, Wolfgang Strehlau, Armin Brenner, Stephan Andreas Schunk, Dirk Demuth
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Patent number: 7364917Abstract: For detecting a component of a substance (of liquid or solid) on a front surface of a substrate, the substrate with the substance thereon is transferred into a vaporizing section, the substance is heated in the vaporizing section so that the component is vaporized from the substance in the vaporizing section, the component vaporized is fed from the substance in the vaporizing section to a detecting section, and the vaporized component is detected in the detecting section.Type: GrantFiled: March 26, 2004Date of Patent: April 29, 2008Assignee: Hitachi High-Tech Control Systems CorporationInventors: Satoshi Ichimura, Masami Sakamoto, Toshio Iwasaki
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Patent number: 7361311Abstract: A method of separating species in a mixture of molecules, particles or atoms and collecting the separated species is described. The method comprises the steps of converting by ionization the species in the mixture to gas phase ions, separating the gas phase ions according to their mass charge ratio and/or mobility and collecting the separated ions. The system includes ionizing means such as electrospray to form the gas phase ions. The gas phase ions are separated by filtering, or in time or in space and soft-landed for collection such as on a surface.Type: GrantFiled: December 31, 2002Date of Patent: April 22, 2008Assignee: Purdue Research FoundationInventors: Robert G. Cooks, Zheng Ouyang
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Patent number: 7341694Abstract: In an ammonia sensor (1), lead portions (7) and (9) are provided on an insulating substrate (5); a pair of comb-shaped electrodes (11) and (13) are connected to the lead portions (7) and (9), respectively; a sensitive layer (15) is provided on the comb-shaped electrodes (11) and (13); and a protective layer (17) is provided on the sensitive layer (15). Particularly, the sensitive layer (15) is formed of a gas-sensitive raw material predominantly containing ZrO2 and containing at least W in an amount of 2 to 40 wt. % as reduced to WO3.Type: GrantFiled: September 25, 2003Date of Patent: March 11, 2008Assignee: NGK Spark Plug Co., Ltd.Inventors: Hiroyuki Nishiyama, Shiro Kakimoto, Ryuji Inoue, Hitoshi Yokoi, Noboru Ishida, Takafumi Oshima, Satoshi Sugaya, Koichi Imaeda, Tadashi Hattori, Atsushi Satsuma
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Patent number: 7337616Abstract: A system for sampling cryogenic liquids, and an air separation unit provided with at least one such system. The cryogenic liquid is introduced into a vaporizer, through heat exchange with the compressed air. The liquid passes through the vaporizer generally downwards. The walls of the vaporizer that are intended to come into contact with the cryogenic liquid are maintained at a temperature above the sublimation temperature or the boiling point of the least volatile impurity contained in this liquid. Downstream of the vaporizer, a gaseous phase coming from the vaporization of the cryogenic liquid is withdrawn and at least some of the gaseous phase is sent to an analyzer.Type: GrantFiled: April 25, 2003Date of Patent: March 4, 2008Assignee: L'Air Liquide, Societe Anonyme A Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: David Meneses, Jean-Yves Thonnelier, Jean-Yves Lehman
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Patent number: 7335513Abstract: A parallel reactor system including a reactor and vessels in the reactor for holding reaction mixtures, and a cannula for introducing fluid reaction material into the vessels. A robot system is operable to insert the cannula into cannula passages in the reactor for delivery of reaction materials, including condensed gases, to respective vessels, and to withdraw the cannula from the cannula passages after delivery. Related methods are also disclosed.Type: GrantFiled: January 28, 2002Date of Patent: February 26, 2008Assignee: Symyx Technologies, Inc.Inventors: Matthew F. Smith, John F. Varni, G. Cameron Dales, Trevor G. Frank, Rakesh Jain, Lynn Van Erden
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Patent number: 7323343Abstract: An analytical system is provided for determining nitrogen monoxide, nitrogen dioxide and ozone concentrations in air samples. An ultraviolet light source 4 is used to alter the equilibrium between nitrogen dioxide and oxygen on the one hand and nitrogen monoxide and ozone on the other. Dynamic measurement of ozone concentration with time while ultraviolet irradiation is pulsed enables each gas concentration to be calculated without requiring input gases to be scrubbed. An aApparatus 101 is further provided to provide a controlled flow of gas to a sensor 103 attached to a high altitude balloon while sheltering it from the elements and allowing for affects of temperature, said apparatus comprising a shield 104 and a gas conducting means which uses the venturi effect to control air flow or has a hole to allow water to drain without affecting air flow past the sensor.Type: GrantFiled: July 13, 2004Date of Patent: January 29, 2008Assignee: Cambridge University Technical Services LimitedInventors: Richard Anthony Cox, Roderic Lewis Jones
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Patent number: 7323344Abstract: A method is provided for the quantitative analysis of the contents, in nitrogen, of hydrogen and methane by ionic mobility spectrometry. The method includes the steps of: a) performing a measurement of the apparent hydrogen concentration in the nitrogen to be analyzed; b) performing a measurement of the apparent hydrogen concentration in a flow of the same sample of nitrogen, purified of all impurities but methane; and c) comparing the two measurements. A system of branched lines is also provided for carrying out the method.Type: GrantFiled: November 6, 2003Date of Patent: January 29, 2008Assignee: Saes Getters S.p.A.Inventors: Luca Pusterla, Marco Succi
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Patent number: 7318908Abstract: Integrated nanotube sensors are adapted for detecting various chemical and biological molecules. In one implementation, nanotube sensor arrays are formed as nano-electronic noses capable of such detection, and can be implemented in devices including carbon nanotube-based electronic noses and biochips. Various implementations of the present invention are also directed to nanoscience and nanotechnology applications, such as medical, military and biological applications. In a more particular implementation, nanotubes are produced on full-scale wafers and functionalized. In another more particular implementation, functionalized nanotubes are integrated into addressable devices. With these approaches, various aspects of the present invention have been found to be useful in sensor applications having small size, high density and extreme sensitivity. Such sensor applications are applicable to many aspects of society, and can be implemented for making human lives more safe, secure and healthy.Type: GrantFiled: October 31, 2002Date of Patent: January 15, 2008Assignee: The Board of Trustees of the Leland Stanford Junior UniversityInventor: Hongjie Dai
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Patent number: 7319039Abstract: The presence of an aerosol or cloud (3) of a toxic substance is detected by producing an aerosol (17, 5) of ligands (13) to the target substance in a region of sky that contains the target substance, permitting molecules the target substance to bind to the ligand, directing light (7, 21) of a first frequency into the revised aerosol; and then inspecting (9, 25) the revised aerosol for emissions of light of a second frequency. When light of the second frequency exists an alarm (15, 31) is initiated.Type: GrantFiled: November 9, 2004Date of Patent: January 15, 2008Assignee: Northrop Grumman CorporationInventor: Brian M. Sullivan
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Patent number: 7310992Abstract: The present invention provides a device for continuous real-time monitoring of ambient air. The device includes a receptacle, a liquid supply, and a pressure balancing system. The receptacle includes a gas inlet slit located such that the gas inlet slit is covered by liquid within the receptacle during use. The pressure balancing portion of the present device includes communication between a point within the receptacle above the liquid level in the receptacle, as well as a liquid inlet portion at the lowermost end of the receptacle, and an air space above a liquid supply portion and the liquid supply portion itself, respectively.Type: GrantFiled: September 27, 2005Date of Patent: December 25, 2007Assignee: Sceptor Industries, Inc.Inventors: Freeman Swank, Christopher Tesluk
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Patent number: 7306953Abstract: A method of determining the cause of disease is described, which method uses the detection of “signature” or “fingerprint” volatile compounds in an emission, especially flatus, from a patient.Type: GrantFiled: January 14, 2005Date of Patent: December 11, 2007Assignee: The University of the West of England, BristolInventors: Christopher Simon J. Probert, Norman Mark Ratcliffe
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Patent number: 7297549Abstract: A method of determining bias in a measurement of a constituent concentration level in a sample gas is provided. The method comprises establishing a sample gas flow from an emission stream into a sample gas line of an emissions monitoring system. The method further comprises removing water from the sample gas flow and cooling the sample gas flow to a temperature below about 41° F. to produce a cooled, dried sample gas flow. The constituent concentration level is then determined for the cooled, dried sample gas flow. The method further comprises introducing a span gas having a known span gas constituent concentration level into the sample gas flow to form a combined sample and span gas flow, the span gas being introduced at a desired span gas flow rate. The method still further comprises removing water from the combined sample and span gas and cooling the combined sample and span gas to a temperature below about 41° F. to produce a cooled, dried, combined sample and span gas flow.Type: GrantFiled: March 6, 2002Date of Patent: November 20, 2007Assignee: General Electric CompanyInventors: William Steven Lanier, Glenn England
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Patent number: 7287391Abstract: Modular expandable hyperpolarizers include a central control module and at least one optical pumping module that can be expandable to a plurality of optical pumping modules that can be separately operated depending on the capacity demands at the production site (hospital, clinic and the like). Methods for producing blended polarized gas products include introducing a pre-packaged pre-mixed amount of a polarizer-ready blend of unpolarized gas. Methods for producing the polarized gas can be carried out at the point of use site and the production run according to patient load. Other methods consider the patient load and automatically schedule the hyperpolarizer to yield the desired polarized gas doses to support the patient and/or MRI/NMR equipment schedule.Type: GrantFiled: October 22, 2002Date of Patent: October 30, 2007Assignee: Medi-Physics, Inc.Inventor: Kenneth Bolam
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Patent number: 7287390Abstract: Hyperpolarizers for producing polarized noble gases can include: (a) a control module configured to direct the operation of a hyperpolarizer to produce polarized noble gas via spin-exchange interactions between a noble gas and an alkali metal; (b) at least one optical pumping module including an optical pumping cell operably associated with the control module; (c) a dispensing system operably associated with the control module and the optical pumping module to dispense meted volumes of polarized gas from the hyperpolarizer; and (d) a fluid distribution system operably associated with the control module, the optical pumping module, and the dispensing system, such that, in response to commands transmitted from the control module, the fluid distribution system operates to automatically direct purge gas into and out of a gas travel path that extends from the control module to the optical pumping cell prior to commencing the spin-exchange interactions in the optical pumping cell, then to receive unpolarized gas anType: GrantFiled: October 22, 2002Date of Patent: October 30, 2007Assignee: Medi-Physics, Inc.Inventor: Kenneth Bolam
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Patent number: 7285246Abstract: A hand-held device detects the presence of a preselected substance in the breath. A deformable housing forms a test chamber for interacting an indicator reagent with the breath. An ampoule positioned inside the housing is ruptured by manual pressure through the walls of the housing. The contents of the ruptured ampoule are exposed to the breath introduced into the chamber. The presence of a substance in the breath causes the indicator reagent to undergo a visually ascertainable change. The ampoule is secured within the housing by a pair of filter plugs having inboard concavities to receive the rounded ends of the ampoule to center it within the housing, and plural detents prevent slippage of the filters. Additional embodiments lower the user's risk of being cut by glass shards, prevent reagent inhalation, enhance the visual aspects of the device, and physically indicate the presence of breath flowing through the device.Type: GrantFiled: August 19, 2003Date of Patent: October 23, 2007Assignee: Akers Acquisition Sub, Inc.Inventor: Lawrence Martin
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Patent number: 7273588Abstract: Methods for determining the amount of at least one metal analyte present in a liquid or gas sample of a halosilane supply (e.g., a chlorosilane supply) are disclosed herein. A sample of a halosilane supply is contacted and reacted with an aqueous hydrofluoric acid solution to produce a liquid reaction mixture. Liquid from the liquid reaction mixture is evaporated under controlled temperature and pressure conditions to near dryness. The nearly-dry residue is prepared for spectral analysis. The presence of a detectable amount of at least one metal analyte is determined for the sample.Type: GrantFiled: July 17, 2003Date of Patent: September 25, 2007Assignee: Air Liquide America L.P.Inventors: Daniel C. Cowles, David S. Bollinger
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Patent number: 7267987Abstract: A process and an assembly for simultaneously evaluating a plurality of catalysts is provided wherein the flow rate of a reactive fluid to each of a plurality of reactors is automatically adjusted based on the measured amount of catalyst sample in each reactor to concurrently obtain a substantially identical fluid space velocity in each of the reactors.Type: GrantFiled: January 6, 2003Date of Patent: September 11, 2007Assignee: UOP LLCInventors: Maureen L. Bricker, J. W. Adriaan Sachtler, Charles P. McGonegal, Mark A. Krawczyk, Ara J. Alexanian, Martin Plassen
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Patent number: 7255837Abstract: An airtight configuration for keeping down the permeation of corrosive gas from silicone adhesive, and for preventing corrosive gas from entering the case. An electronic device mounted on vehicle. The electronic device has at least one of a portion connecting components, and a portion sealing the clearance or hole where exists in the electronic device. The at least one of the connection portion and the seal portion is constituted by using adhesive or sealant which has at least one of a function adsorbing corrosive gas and a function trapping corrosive gas with chemical reaction. A car-mounted electronic device characterized by reduced permeation of corrosive gas into a case and high reliability.Type: GrantFiled: September 20, 2002Date of Patent: August 14, 2007Assignees: Hitachi, Ltd., Hitachi Car Engineering Co., Ltd.Inventors: Hiroyuki Abe, Shinya Igarashi
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Patent number: 7256052Abstract: This invention is to a microreactor type of reaction and analysis system. The system includes a chemical reaction chamber having internal conduits through which a chemical reactant, such as a reaction gas, can be fed. The conduits for transporting fluids such as reactant, carrier gas and balance gas are in appropriate communication such that the amount of reactant going directly to a catalyst located in the reaction chamber can be optimally controlled. The system is highly useful for studying the kinetics of a chemical reaction.Type: GrantFiled: October 18, 2002Date of Patent: August 14, 2007Assignee: ExxonMobil Chemical Patents Inc.Inventors: Nicolas P. Coute, John K. Pierce
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Patent number: 7250138Abstract: A system and method for detecting the presence of submicron sized particles in a sample taken from the environment includes a collecting a sample from the environment and purifying and concentrating the submicron particles in a sample based on the size of the particles. The purified and concentrated particles are detected with an apparatus which includes an electrospray assembly having an electrospray capillary, a differential mobility analyzer which receives the output from the capillary, and a condensation particle device for counting the number of particles that pass through the differential mobility analyzer.Type: GrantFiled: December 9, 2002Date of Patent: July 31, 2007Assignee: United States of America as respresented by the Secretary of the ArmyInventor: Charles Harold Wick
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Patent number: 7247496Abstract: The measurement of the particle size distribution of an aerosol is of crucial importance in pharmaceutical development. A prerequisite for this is a valid method, e.g. the cascade impactor method described in the pharmacopoeias. It requires measurement of the active substance concentration in order to determine the particle size distribution. The invention provides a process which makes it possible to measure the size of aerosol droplets containing pharmaceutical substances which are unstable in the event of changes in the pH.Type: GrantFiled: July 24, 2002Date of Patent: July 24, 2007Assignee: Boehringer Ingelheim International GmbHInventors: Dieter Hochrainer, Georg Boeck, Hubert Hoelz, Christian Scheffler, Christoph Kreher
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Patent number: 7247495Abstract: The invention provides a mass spectrometric method for analyzing a sample in a solution, including the steps of directing a flow of a solution containing sample compounds to be analyzed towards a supersonic nozzle having an input end and an output end; vaporizing the solution and sample prior to its expansion from the output end of said supersonic nozzle; allowing expansion of the vaporized sample and solution from said supersonic nozzle into a vacuum system, forming a supersonic molecular beam with vibrationally cold sample molecules; ionizing the vaporized sample compounds with electrons while contained as vibrationally cold molecules in said supersonic molecular beam; mass analyzing the ions formed from said sample compounds; detecting said ions formed from said sample compounds after mass analysis, and processing the data obtained from the resulting mass spectral information, for identifying and/or quantifying the chemical content of said sample.Type: GrantFiled: August 15, 2002Date of Patent: July 24, 2007Inventor: Aviv Amirav
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Patent number: 7229832Abstract: A process and apparatus for rapidly screening materials using, for example, mass spectrometry has been developed. More specifically, an array of materials on a fluid permeable support contained within a reaction cell having a semipermeable membrane can be rapidly screened for characteristics such as catalytic activity, selectivity, and adsorption and desorption properties.Type: GrantFiled: September 18, 2003Date of Patent: June 12, 2007Assignee: UOP LLCInventors: Amit Nayar, Renxuan Liu, Richard R. Willis, Eugene R. Smotkin
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Patent number: 7229593Abstract: An apparatus for measuring the effective vapor diffusion coefficient of a test vapor diffusing through a sample of porous media contained within a test chamber. A chemical sensor measures the time-varying concentration of vapor that has diffused a known distance through the porous media. A data processor contained within the apparatus compares the measured sensor data with analytical predictions of the response curve based on the transient diffusion equation using Fick's Law, iterating on the choice of an effective vapor diffusion coefficient until the difference between the predicted and measured curves is minimized. Optionally, a purge fluid can forced through the porous media, permitting the apparatus to also measure a gas-phase permeability. The apparatus can be made lightweight, self-powered, and portable for use in the field.Type: GrantFiled: October 25, 2002Date of Patent: June 12, 2007Assignee: Sandia CorporationInventor: Clifford K. Ho
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Patent number: 7220388Abstract: Apparatus and method for increasing the concentration of a chemical substance in a fluid comprise a micro-fluidic elongated channel formed in a substrate, with the channel being in fluid-flow communication with an ambient region along its elongated dimension. In general, the fluid includes first and second chemical substances having different vapor pressures. The apparatus includes an evaporation controller for increasing the evaporation rate of the fluid from the channel into the ambient region, thereby increasing the concentration of the higher vapor pressure (HVP) substance in the portion of the fluid remaining in the channel and increasing the concentration of the lower vapor pressure (LVP) substance in the portion of the fluid evaporated into the ambient region.Type: GrantFiled: February 25, 2004Date of Patent: May 22, 2007Assignee: Lucent Technologies Inc.Inventors: David John Bishop, John VanAtta Gates, Marc Scott Hodes, Avinoam Kornblit, Stanley Pau, Brijesh Vyas
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Patent number: 7220383Abstract: An analytical apparatus to monitor fluid systems has at least one extraction module having a raw-sample reservoir connected by input fluid conduit to individual ones of said fluid systems, to extract raw samples for analysis from said fluid systems, one or more modification modules comprising additive materials to modify the extracted raw samples prior to analysis, an analytical device to receive at least a portion of said raw samples in an ordered sequence, and to determine concentration of at least one constituent of said sample portion, fluid-handling apparatus for transferring fluid through the analytical apparatus, and a computerized control and management system to manage operations of component modules and devices, and to report analytical results.Type: GrantFiled: February 28, 2002Date of Patent: May 22, 2007Assignee: Metara, Inc.Inventors: Marc R. Anderson, Larry N. Stewart, Howard M. Kingston
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Patent number: 7208123Abstract: A flow-through monitor for detecting molecular contamination (MC) within a fluid flow. The monitor has a diffusion chamber having an inlet port and an outlet port, and a structure for supporting a fluid flow from the inlet port to the outlet port. The structure includes a flow gap causing a diffusion of molecular contaminants into the diffusion chamber, while substantially preventing, for a rate of the fluid flow above a predetermined magnitude, particulate contaminants within the fluid from entering the diffusion chamber. A SAW device detects molecular contamination interior to the diffusion chamber. Fluid input to the flow-through monitor may be diluted by a pure fluid for extended monitor life. A system for aggregate sampling connects an ensemble manifold upstream of the flow-through monitor. A system for triggered sampling connects a sample preconcentrator downstream of the flow-through monitor. A chemically selective membrane may be located between the flow gap and the SAW.Type: GrantFiled: June 24, 2002Date of Patent: April 24, 2007Assignee: Particle Measuring Systems, Inc.Inventors: Brian A. Knollenberg, Daniel Rodier, Scott Waisanen
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Patent number: 7201874Abstract: A system for quickly and automatically extracting and analysing residual solvents is realised for operating directly in the premises where the packing materials are being manufactured, printed and/or laminated. The system provides for a single unit equipped with a display and a keyboard, and comprises an extraction (desorption) chamber (1), an analysis chamber with valves and separating columns, a detection system (17), and a data processing system (19). The extracting or desorption chamber comprises a desorption cell (1) for receiving a vial (36; 37) containing said sample, and means are provided to keep the inside of said cell (1) at a pressure higher that that of the surrounding environment until a new sample has been introduced into the cell, thus accomplishing a “washing” of cell for eliminating polluting solvents coming from the desorption of a preceding sample and/or solvents present in the surrounding environment.Type: GrantFiled: March 14, 2001Date of Patent: April 10, 2007Inventor: Carlo Squicciarini
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Patent number: 7201878Abstract: Aerosol particle analyzer (APA) for measuring an analyte in airborne particle is described. Airborne particles are first given an electrical charge and then drawn in air past an oppositely charged volume of an analysis liquid that exposed to the air at a small hole in a container, such as a capillary, that holds that analysis liquid. Electrostatic forces enhance the rate that the airborne particles collide with the small exposed volume of the analysis liquid in the hole. If the particles that collide with the analysis liquid contain the analyte, an optical property of the analysis liquid, such as the fluorescence, varies according to the amount of the analyte in the particles. This optical property is measured and the amount of analyte in the particles is determined from the measured optical property.Type: GrantFiled: March 26, 2004Date of Patent: April 10, 2007Assignee: The United States of America as Represented by the Secretary of the ArmyInventors: Horn-Bond Lin, Steven Clyde Hill
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Patent number: 7201879Abstract: An aerosol-into-liquid collector (ALC) for collecting gas-borne particles from a large volume of gas such as air into a small volume of liquid is described. The ALC uses a linear quadrupole to concentrate particles flowing in a gas and to help direct these concentrated particles toward a small volume of collection liquid so that these particles tend to combine with a small volume of collection liquid that can then be drawn from the ACL for further analysis. The particles in the gas are typically given a charge that is opposite to that of the charge imparted to the volume of collection liquid so that electrostatic forces help draw particles from the flowing gas into the small volume of liquid. The linear quadrupole focuses toward it axis particles that have the charge, mass and mobility to be stable in the linear quadrupole.Type: GrantFiled: November 19, 2004Date of Patent: April 10, 2007Assignee: The United States of America as represented by the Secretary of the ArmyInventors: Steven Clyde Hill, Horn-Bond Lin
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Patent number: 7197949Abstract: A sampling system for detecting an analyte, comprising a diaphragm pump, a buffer chamber, a sensor head and intake port. The pump includes a chamber for receiving fluids via first and second ports. A buffer chamber is located at the second port for holding a quantity of air, and a sensor head is adapted to identify the presence of a desired analyte and produce a signal in response to the quantity identified. Preferably the diaphragm pump has a volume of gas per stroke capacity slightly larger than the volume of the sensor head such that the pump chamber has a greater volume than the buffer chamber and the buffer chamber has about the same volume as the sensor head. A sensor intake port intakes a sample potentially containing the analyte for contact with the sensor head upon operation of the diaphragm pump and out of the sensor head by jet-action caused by rapid movement of the diaphragm pump. A filter may be used for filtering air drawn through the pump chamber.Type: GrantFiled: April 2, 2002Date of Patent: April 3, 2007Assignee: Honeywell International Inc.Inventors: J. David Zook, Cleopatra Cabuz
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Patent number: 7198952Abstract: An upstream side catalyst and a downstream side catalyst are disposed in an exhaust passage. A first oxygen sensor is disposed between these two catalysts and a second oxygen sensor is disposed downstream of the downstream side catalyst. The air-fuel ratio is forcibly oscillated and the oxygen storage capacity of the upstream side catalyst is detected. Deterioration of the upstream side catalyst is then detected based on whether this oxygen storage capacity is larger than a predetermined value. The forced oscillation of the air-fuel ratio is performed only when the oxygen storage state of the downstream side catalyst is appropriate.Type: GrantFiled: July 15, 2002Date of Patent: April 3, 2007Assignee: Toyota Jidosha Kabushiki KaishaInventors: Takahiro Uchida, Hiroshi Sawada, Toshinari Nagai, Akihiro Katayama, Yasuhiro Kuze, Naoto Kato
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Patent number: 7191670Abstract: A method and system for automated remote microbial air sampling includes a sampling enclosure positioned outside an isolator. An infeed sample receiver passes sample containers into the enclosure. An atrium is located within the enclosure and exposes containers to a gas sample. A remote sampling device collects the gas sample from the isolator and passes it to the atrium. A load arm is located within the enclosure. The load arm intermittently permits containers to enter the enclosure and moves containers to the atrium. An outfeed sample receiver passes containers out of the enclosure. The system allows addition and removal of containers from the air sampling system without interrupting the processing of the containers within the enclosure, and allows the first container supplied to the air sampling system to be the first exposed container removed therefrom.Type: GrantFiled: July 27, 2005Date of Patent: March 20, 2007Assignee: Hospira. Inc.Inventor: Alan H. Aicher
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Patent number: 7189363Abstract: Of a gas detector 100, a chamber 105 formed between a center cover 150 and a cover 160 is a part of an air flow channel AF. A first shielding plate 165 is provided in the chamber 105. Water droplets that have entered the chamber from a chamber entrance 103 with air hit and adhere to an entrance-opposed surface 165E of the first shielding plate 165. The water thus adhering to the surface is pushed by the air flowing along the entrance-opposed surface 165E and by gravity, to thereby advance downward. The water then drips downward and is accumulated on a bottom wall surface 105WD which serves as an upper surface of a bottom wall section 161WD. The water is pushed by the flow of air, to thereby advance toward a chamber exit 104. The water is then drained downward from the chamber exit 104.Type: GrantFiled: May 23, 2003Date of Patent: March 13, 2007Assignee: NGK Spark Plug Co., Ltd.Inventors: Norimasa Osawa, Kazuto Hirai, Yuichi Koyama
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Patent number: 7189579Abstract: A method and device for measuring release rates of contaminants in at least one of a fast release mode and a slow release mode in which a volatile liquid sample is introduced into a sealed transparent reactor vessel having at least one sorbent contained within the transparent reactor vessel and a separator for preventing direct contact between the at least one adsorbent and the at least one volatile liquid sample in the transparent reactor vessel, whereby substantially zero headspace is maintained within the transparent reactor vessel. At least one solvent soluble constituent present in the at least one volatile liquid sample is passed through the separator, resulting in sorption of the at least one solvent soluble constituent by the at least one sorbent. In accordance with one preferred embodiment, the separator is a dialysis bag contained in the transparent reactor vessel into which the resin is placed.Type: GrantFiled: February 22, 2002Date of Patent: March 13, 2007Assignee: Gas Technology InstituteInventors: Bhupendra K. Soni, Thomas D. Hayes
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Patent number: 7179656Abstract: Disclosed is an apparatus for rapidly screening chemicals for their ability to sublime. The apparatus consists of a heated well plate, where the chemicals are deposited, and a cooled finger plate, holding fingers that penetrate each well. The two plates touch at only the perimeter in order to facilitate a vacuum seal and to reduce any thermal transfer.Type: GrantFiled: July 3, 2002Date of Patent: February 20, 2007Assignee: E. I. du Pont de Nemours and CompanyInventors: Daniel David Lecloux, Steven J. Medwin, Eric Maurice Smith
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Patent number: 7172730Abstract: A thermal sensor has a substrate defining a reaction chamber. The reaction chamber has an inlet for conducting sample into the reaction chamber, a reaction surface and an orifice adjacent the reaction surface defining an outlet from the reaction chamber. The reaction surface is coated with a sorbant for binding agents in the sample. A heat transducer in the substrate and in proximity to the reaction surface is configured for heating the reaction surface.Type: GrantFiled: December 9, 2002Date of Patent: February 6, 2007Assignee: Hewlett-Packard Development Company, L.P.Inventor: Steven E. Carpenter
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Patent number: 7153694Abstract: A method for quantitative determination of hydrocarbon species in a hydrocarbon sample is disclosed. The method uses Townsend Discharge Nitric Oxide Chemical Ionization Gas Chromatography/Mass Spectrometry.Type: GrantFiled: November 26, 2002Date of Patent: December 26, 2006Assignee: Shell Oil CompanyInventors: Knox Alex Evans, Weijan Mo, Howard Peterson, Ismet Dzidic
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Patent number: 7153475Abstract: Aerosol particle analyzer (APA) for measuring the amount of analyte in airborne particle is described. The APA uses an analysis liquid. In most embodiments, this analysis liquid is chosen so that when it is mixed with the particles, an optical property of the analysis liquid (AL) varies according to the amount of the analyte in the particles. Airborne particles are drawn into the instrument, and detected using optical methods such as light scattering or laser-induced fluorescence. When a particle of interest is detected, a charged droplet of the analysis liquid (CDAL) is ejected so that it collides with the detected particle and moves into a horizontally oriented linear quadrupole that is in an airtight container, except for small orifices to let the CDAL enter and exit.Type: GrantFiled: May 9, 2005Date of Patent: December 26, 2006Assignee: The United States of America as represented by the Secretary of the ArmyInventors: Steven Clyde Hill, Richard Kounai Chang, Jean-Pierre Wolf
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Patent number: 7150994Abstract: Parallel flow reaction systems comprising four or more reaction channels are disclosed. Distribution systems, and parallel flow reaction systems comprising such distribution systems are also disclosed. Specifically, the distribution systems comprise one or more subsystems, including for example, a flow-partitioning subsystem for providing a different flow rate to each of the four or more reactors, a pressure-partitioning subsystem for providing a different reaction pressure in the reaction cavity of each of the four or more reactors, and a feed-composition subsystem for providing a different feed composition to each of the four or more reactors. In preferred embodiments, the one or more subsystems can comprise at least one set of four or more flow restrictors, each of the four or more flow restrictors having a flow resistance that varies relative to other flow restrictors in the set.Type: GrantFiled: March 7, 2001Date of Patent: December 19, 2006Assignee: Symyx Technologies, Inc.Inventors: H. Sam Bergh, James R. Engstrom, Shenheng Guan, Daniel Meron Pinkas, Kyle W. Self
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Patent number: 7144736Abstract: A method and an apparatus which continuously separate and measure mercury in an exhaust gas in accordance with each chemical conformation and display a measurement result in real time. According to the method and the apparatus, water-soluble mercury in a gas is absorbed into an absorption solution (7), the gas and the absorption solution (7) are then separated from each other, the water-soluble mercury in the absorption solution (7) is reduced to be converted into gaseous metal mercury and led to an analyzer (20), and metal mercury in the gas which is not absorbed into the absorption solution (7) is led to an analyzer (22) in the form of gas. As a result, the water-soluble mercury and the non-water-soluble mercury contained in the gas can be captured and measured/analyzed in respective measurement systems in accordance with each chemical conformation. In addition, a concentration of the metal mercury and that of the water-soluble mercury in the gas can be continuously monitored in real time.Type: GrantFiled: June 25, 2001Date of Patent: December 5, 2006Assignees: Central Research Institute of Electric Power Industry, Nippon Instruments CorporationInventors: Naoki Noda, Shigeo Ito, Koji Marumoto, Koji Tanida, Munehiro Hoshino
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Patent number: 7129093Abstract: A method of determining beryllium or a beryllium compound thereof in a sample, includes providing a sample suspected of comprising beryllium or a compound thereof, extracting beryllium or a compound thereof from the sample by dissolving in a solution, adding a fluorescent indicator to the solution to thereby bind any beryllium or a compound thereof to the fluorescent indicator, and determining the presence or amount of any beryllium or a compound thereof in the sample by measuring fluorescence.Type: GrantFiled: March 30, 2004Date of Patent: October 31, 2006Assignee: Los Alamos National Security, LLCInventors: T. Mark McCleskey, Deborah S. Ehler, Kevin D. John, Anthony K. Burrell, Gavin E. Collis, Edel M. Minogue, Benjamin P. Warner
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Patent number: 7125518Abstract: Aerosol particle analyzer (APA) for measuring the amount of analyte in airborne particle is described. The APA uses an analysis liquid. When this analysis liquid is mixed with the particles, an optical property of the analysis liquid (CDAL) varies according to the amount of the analyte in the particles. A charged droplet of the analysis liquid is levitated. Airborne particles are drawn into the instrument and given a charge that is opposite that of the CDAL, and made to flow near the CDAL so that electrostatic forces greatly increase the probability that the CDAL and charged particles will combine. Then the CDAL is ejected into a horizontally oriented linear quadrupole that is in an airtight container, except for a small orifice to let the CDAL enter. The CDAL is levitated in a high humidity environment so that it evaporates slowly, so that there is time for the reaction between the analyte, if any, and the CDAL can take place, and so that the optical property, typically fluorescence, can be measured.Type: GrantFiled: February 14, 2004Date of Patent: October 24, 2006Assignee: The United States of America as represented by the Secretary of the ArmyInventor: Steven Clyde Hill
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Patent number: 7118920Abstract: Multiphasic reactions, especially those reactions using a phase transfer catalyst, are conducted in microchannel apparatus. Advantageously, these reactions can be conducted with two, planar microlayers of reactants in adjacent laminar flow streams. Microchannel apparatus and methods for conducting unit operations such as reactions and separations in microchannel apparatus is also described. Microchannel apparatus can provide advantages for controlling reactions and separating products, solvents or reactants in multiphase reactions.Type: GrantFiled: October 22, 2002Date of Patent: October 10, 2006Assignee: Battelle Memorial InstituteInventors: John H. Brophy, Bruce F. Monzyk
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Patent number: RE39353Abstract: The system for analyzing multiple samples includes a plurality of portable of sample supports each for accommodating a plurality of samples thereon, and an identification mechanism for identifying each sample location on each of the plurality of sample supports. The mass spectrometer is provided for analyzing each of the plurality of samples when positioned within a sample receiving chamber, and a laser source strikes each sample with a laser pulse to desorb and ionize sample molecules. The support transport mechanism provided provides for automatically inputting and outputting each of the sample supports from the sample receiving chamber of the mass spectrometer. A vacuum lock chamber receives the sample supports and maintains at least one of the sample supports within a controlled environment while samples on another of the plurality of sample supports are being struck with laser pulses.Type: GrantFiled: January 4, 2001Date of Patent: October 17, 2006Assignees: Applera Corporation, MDS, Inc.Inventor: Marvin L. Vestal