Removing And Testing Solid Samples Patents (Class 436/31)
  • Patent number: 10970620
    Abstract: Historical information about a significant input parameter is stored in a data analytics model of a hydrocarbon reservoir. A historical deep recursive neural network (RNN) model is built based on time-series production data from the hydrocarbon reservoir as a function of the significant input parameter in the data analytics model. The historical deep RNN neural network model is stored on a data storage device. An experiment using the historical deep neural network model is designed to predict the significant input parameter. The experiment is run to produce a significant experimental input parameter. The significant experimental input parameter is compared to the significant input parameter stored in the data analytics model to determine a difference. The data analytics model is adjusted to reduce the difference.
    Type: Grant
    Filed: September 8, 2017
    Date of Patent: April 6, 2021
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Srinath Madasu, Ronald Glen Dusterhoft, Vladimir Nikolayevich Martysevich, Yucel Akkutlu, Brice Y. Kim
  • Patent number: 10088406
    Abstract: The invention relates to a method for measuring permeation of gases through a material comprising the following steps: a) Supplying gas to a permeation enclosure (10) during which a first chamber (11) is supplied with a target gas flow comprising at least one target gas corresponding to a gas for which one tries to determine the permeation through the material (M), and simultaneous supplying gas to a measurement enclosure (20) with at least one calibrated flow comprising at least one reference gas different from the target gas; b) during the gas supply step, measuring in the measurement enclosure (20) the reference gas present at instant (t) and the target gas present at the same instant (t) after having crossed the material (M) by permeation; c) calculating a correction factor at instant (t) by comparing the measurement of the reference gas present at instant (t) with the reference gas supply calibrated flow; and d) determining the permeation of the material (M) to said gas, from the measurement of the ta
    Type: Grant
    Filed: November 23, 2015
    Date of Patent: October 2, 2018
    Assignee: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
    Inventors: Stéphane Cros, Fabien Jaubert, Arnaud Leroy, Christine Walsh
  • Patent number: 9939361
    Abstract: Automated calcimeter systems and methods of using the same are described. An automated calcimeter system may comprise a reaction chamber; a pressure sensor coupled to the reaction chamber and configured to measure pressure in the reaction chamber; a pump coupled to the reaction chamber; piping coupled to the pump, wherein the piping is of sufficient length to store a preselected volume of acid; and a processor configured to instruct the pump to deliver the preselected volume of acid to the reaction chamber while also drawing a volume of gas from the reaction chamber, wherein the volume of gas is equivalent to the preselected volume of acid.
    Type: Grant
    Filed: September 23, 2014
    Date of Patent: April 10, 2018
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Bhargav Gajji, Ketan Chimanlal Bhaidasna, Shawn Lynn Broussard, Vyacheslav Chernin
  • Patent number: 9746576
    Abstract: A method of estimating a wettability characteristic of a formation includes: disposing a magnetic resonance (MR) measurement apparatus in a borehole; generating a low gradient static magnetic field and an oscillating magnetic field in a region of the formation; detecting a MR signal generated in the region; calculating relaxation parameters for at least one fluid in the region; and estimating the wettability characteristic of the region based on the relaxation parameters.
    Type: Grant
    Filed: May 27, 2014
    Date of Patent: August 29, 2017
    Assignee: BAKER HUGHES INCORPORATED
    Inventors: Segun A. Jebutu, Weidong Li
  • Patent number: 9587490
    Abstract: A well fluid test device includes a cell body having a first end port disposed on an upper end of the cell body, a second end port disposed on a lower end of the cell body, a first lateral port disposed on a side of the cell body, and a second lateral port disposed on a side of the cell body, and a filter medium disposed in the cell body, wherein the first and second lateral ports are disposed above the filter medium. A method of evaluating a fluid includes injecting a fluid into a well fluid test device, the well fluid test device having a filter medium, heating the fluid in the well fluid test device, establishing a pressure differential across the filter medium, establishing a filter cake on the filter medium, and maintaining at least one of a temperature and a pressure in the well fluid test device.
    Type: Grant
    Filed: November 23, 2012
    Date of Patent: March 7, 2017
    Assignee: SCHLUMBERGER NORGE AS
    Inventors: Håvard Kaarigstad, Christine Mo
  • Patent number: 9047700
    Abstract: Technologies are generally described for systems and methods effective to implement virtual and augmented reality. In an example, a first device may send data to a second device. The first device may include a processor and a memory. The processor may receive first image data based on a first real image from a third device. The first real image may include a fourth device image that relates to a fourth device. The processor may receive second image data based on a second real image from the fourth device. The processor may send the first image data to the second device. The processor may receive a first request from the second device to receive the second image data. The processor may send a second request to the fourth device for the second image data, receive the second image data, and send the second image data to the second device.
    Type: Grant
    Filed: November 9, 2011
    Date of Patent: June 2, 2015
    Assignee: EMPIRE TECHNOLOGY DEVELOPMENT LLC
    Inventor: Shmuel Ur
  • Patent number: 9029156
    Abstract: The subject matter of the present disclosure is directed to developing a method of measuring the amount of producible oil and the producible oil saturation in shale-oil reservoirs using sample source rock. Further, the physical and chemical properties and amounts of producible oil in shale-oil reservoir samples may be determined. First and second solvents are applied to a sample source rock to extract petroleum from the sample source rock. The extracted source rock, the twice-extracted source rock, and the first and second extracted petroleum may be analyzed to determine the characteristics and properties of the reservoir rock.
    Type: Grant
    Filed: May 9, 2013
    Date of Patent: May 12, 2015
    Assignee: Weatherford Technology Holdings, LLC
    Inventors: Alan S. Kornacki, Patricia M. O'Neal, Kathryn E. Washburn, Kevin L. Kmiec
  • Patent number: 8906690
    Abstract: A method for estimating characteristics of a formation including collecting a formation sample, preparing the sample, and analyzing the sample using FTIR comprising identifying the kerogen lineshape and intensity. The method includes using the lineshape to obtain kerogen maturity, using the maturity to obtain the kerogen spectrum, and using the kerogen spectrum to obtain the mineralogy and kerogen content.
    Type: Grant
    Filed: April 13, 2012
    Date of Patent: December 9, 2014
    Assignee: Schlumberger Technology Corporation
    Inventor: Andrew E. Pomerantz
  • Patent number: 8796035
    Abstract: The invention relates to a method and to a device for sulfur characterization and quantification in a sample of sedimentary rocks or of petroleum products wherein the following stages are carried out: heating said sample in a pyrolysis oven (1) in a non-oxidizing atmosphere, oxidizing part of the pyrolysis effluents and continuously measuring the amount of SO2 generated by said part after oxidation, then transferring the pyrolysis residue of said sample into an oxidation oven (1?) and continuously measuring the amount of SO2 contained in the effluents resulting from said oxidation heating.
    Type: Grant
    Filed: October 27, 2009
    Date of Patent: August 5, 2014
    Assignees: IFP Energies Nouvelles, Vinci Technologies
    Inventors: Jean Espitalie, Roland Antonas, Violaine Lamoureux-Var, Gérémie Letort, Daniel Pillot, Valérie Beaumont, Frank Haeseler
  • Patent number: 8678933
    Abstract: A server device according to an embodiment is connected to a plurality of player terminals to communicate information with the player terminals. The server device includes: a storage unit configured to store game content information, the game content information being configured to have special numbers at a predetermined interval in serial number order; a providing unit configured to select the same number of pieces of game content as the number of the predetermined interval, and to provide the selected pieces of game content at a time; a provision notice information generating unit configured to generate provision notice information for notifying in advance of whether a piece of game content with a special number is to be provided; and an image data generating unit configured to generate image data for displaying a game screen on a display unit of the player terminal before providing the pieces of game content.
    Type: Grant
    Filed: July 24, 2013
    Date of Patent: March 25, 2014
    Assignee: DeNA Co., Ltd.
    Inventor: Shigenori Kobayashi
  • Patent number: 8556001
    Abstract: The present invention relates to a process and related apparatus for determining the presence and/or quantity of H2S in the drilling debris of a subsoil layer comprising the following working steps: recovering the drilling debris of a layer; degassing the drilling debris from the previous recovery step, and separating a gaseous phase from said debris; clearing the gas released in the step of degassing, and conveying towards an H2S detector; determining the possible presence and/or quantity of H2S in the gaseous phase from the steps of degassing and clearing by means of a suitable means of detection; possible repetition of the previous phases at two layers, at least of the subsoil at different levels of depth in relation to the surface, with consequent determination of a distribution profile of H2S in the subsoil.
    Type: Grant
    Filed: October 18, 2010
    Date of Patent: October 15, 2013
    Assignee: Geolog S.r.l.
    Inventor: Antonio Calleri
  • Patent number: 8492153
    Abstract: A method for calculating the volume of various predetermined organic end-members in samples of rock at various depths in oil reservoir rock is utilized to produce one or more graphic displays that are use to interpret the data to identify, e.g., tar mats, in order to improve the efficient production of hydrocarbons from the well. Data is collected from the samples by known pyrolysis and compositional modeling methods; additional data is obtained by elemental analysis to determine weight percentages of C, H, N, S and O in the selected end-members and characterization of physical properties of representative samples of the reservoir rock, e.g., from core samples; the data is then processed in accordance with the method to provide a series of data points used to produce the graphic displays for visual interpretation.
    Type: Grant
    Filed: February 15, 2008
    Date of Patent: July 23, 2013
    Assignee: Saudi Arabian Oil Company
    Inventors: Peter J. Jones, Henry I. Halpern
  • Patent number: 8486702
    Abstract: A traceable treatment composition for treating a subterranean formation having multiple zones penetrated by a well bore comprising a homogenous blend of a tracking composition and a resin composition. The tracking composition comprises a substantially non-radioactive tracking material selected from the group consisting of a metal salt. The metal portion of the metal salt may be selected from the group consisting of gold, silver, lithium, molybdenum, and vanadium.
    Type: Grant
    Filed: June 27, 2012
    Date of Patent: July 16, 2013
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Philip D. Nguyen, Jimmie D. Weaver, Johnny A. Barton
  • Patent number: 8388435
    Abstract: A method of playing a wagering game comprises receiving a wager, and generating a randomly selected first outcome of a first wagering game, the first outcome comprising a first plurality of symbols arranged in a first matrix. The method further comprises generating a randomly selected second outcome of a second wagering game, the second outcome comprising a second plurality of symbols arranged in a second matrix, and simultaneously displaying the first outcome and the second outcome on at least one display. The method further comprises detecting an occurrence of a triggering event, in response to the triggering event, copying a first special symbol occurring in the first outcome into the second outcome to yield a modified second outcome, and evaluating the first outcome and the modified second outcome for winning combinations of symbols.
    Type: Grant
    Filed: May 28, 2009
    Date of Patent: March 5, 2013
    Assignee: WMS Gaming Inc.
    Inventors: Peter R. Anderson, Allon G. Englman, Benjamin T. Gomez, Joel R. Jaffe, Daniel P. Louie
  • Patent number: 8354279
    Abstract: Compositions and methods for determining the source of treatment fluids being produced from a production formation having multiple zones by introducing a treatment composition having a tracking material into a zone in the subterranean formation, and detecting the tracking material in treatment composition that flows back from the subterranean formation.
    Type: Grant
    Filed: February 12, 2004
    Date of Patent: January 15, 2013
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Philip D. Nguyen, Jimmie D. Weaver, Johnny A. Barton
  • Patent number: 7772004
    Abstract: The invention relates to a method allowing to determine at least one petroleum characteristic of a geologic sediment sample, wherein the sample is heated in an oxidizing atmosphere, its temperature being successively raised to a first, then to a second value, said first value below 200° C. being reached very quickly, then maintained substantially constant for a certain time, said second value ranging between 600° C. and 850° C. being reached with a temperature gradient ranging between 1 and 30° C./min, from said first value. According to the invention, the amount of SO2 contained by the effluent resulting from said oxidizing heating is measured continuously, every moment of the heating period of said sample.
    Type: Grant
    Filed: April 15, 2005
    Date of Patent: August 10, 2010
    Assignee: Institut Francais du Petrole
    Inventor: François Lorant
  • Patent number: 7435597
    Abstract: The present invention is directed to novel assays for zero-valent transition metals. The novel assays of the present invention are generally methods or processes for quantitatively and/or qualitatively evaluating the presence of zero-valent transition metals on and/or within samples. Such assays generally involve a digestion process whereby the sample is exposed to carbon monoxide. Transition metals, if present in or on the sample and if contacted by the carbon monoxide, are extracted by the carbon monoxide as metal carbonyl species, the presence of which confirms the presence of transition metals. Such novel assays have enormous predictive power in oil and gas exploration.
    Type: Grant
    Filed: April 21, 2004
    Date of Patent: October 14, 2008
    Assignee: Petroleum Habitats, L.L.C.
    Inventor: Frank D. Mango
  • Patent number: 7393689
    Abstract: The present invention provides a method and apparatus or system for determining an amount of coal tar that can enter, and subsequently be displaced from, a given type of soil for a range of depths of the soil. The method and apparatus also provide verification of the pressure at which coal tar can be displaced from a given type of soil. In particular, the method and apparatus simulate the hydrostatic pressure that a soil sample encounters in the subsurface of the ground. Accordingly, the method and apparatus provide a relationship between the concentration of coal tar in the soil and the pressure required to displace the coal tar from the soil, which allows for an estimation of the amount of coal tar that may be displaced at a particular location or site. Further, the method and apparatus are adaptable for use in the laboratory or the field.
    Type: Grant
    Filed: January 27, 2004
    Date of Patent: July 1, 2008
    Assignee: Lehigh University
    Inventors: Horace Keith Moo-Young, Derick Gerdts Brown, Andrew J. Coleman
  • Patent number: 7253005
    Abstract: A method and apparatus are provided for obtaining a reproducible sample of solid particles. The reproducible sample is obtained by receiving solid particles into a collection system that includes a sheltered volume. Solid particles that settle outside of the sheltered volume are purged from the collection system. The remaining solid particles inside the sheltered volume correspond to the reproducible sample.
    Type: Grant
    Filed: August 29, 2003
    Date of Patent: August 7, 2007
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Nicolas P. Coute, James R. Lattner, Jeffrey Scott Smith, Carl Edward Manning
  • Patent number: 7201874
    Abstract: A system for quickly and automatically extracting and analysing residual solvents is realised for operating directly in the premises where the packing materials are being manufactured, printed and/or laminated. The system provides for a single unit equipped with a display and a keyboard, and comprises an extraction (desorption) chamber (1), an analysis chamber with valves and separating columns, a detection system (17), and a data processing system (19). The extracting or desorption chamber comprises a desorption cell (1) for receiving a vial (36; 37) containing said sample, and means are provided to keep the inside of said cell (1) at a pressure higher that that of the surrounding environment until a new sample has been introduced into the cell, thus accomplishing a “washing” of cell for eliminating polluting solvents coming from the desorption of a preceding sample and/or solvents present in the surrounding environment.
    Type: Grant
    Filed: March 14, 2001
    Date of Patent: April 10, 2007
    Inventor: Carlo Squicciarini
  • Patent number: 7153688
    Abstract: The present invention relates to assays for ascribing catalytic activity to rock samples by virtue of zero-valent transition metals potentially being present within the sample. Embodiments of the present invention are generally directed to novel assays for measuring intrinsic paleocatalytic activities (k) of sedimentary rocks for converting oil to gas and projecting the activities to the subsurface based on the measured linear relationship between ln(k) and temperature (T).
    Type: Grant
    Filed: December 7, 2004
    Date of Patent: December 26, 2006
    Assignee: Petroleum Habitats, L.L.C
    Inventor: Frank D. Mango
  • Patent number: 7008793
    Abstract: The present invention is intended to take a sample of an emulsion circulating in a line. The emulsion is momentarily diverted from the main circulation line 1 thereof to a bypass line 2. By restoring circulation of the emulsion in main line 1, an emulsion sample still present in bypass line 2 is confined under pressure. The emulsion sample is then stabilized according to a well-known method. Since the size and the distribution of the drops no longer evolve with time, the sample can be observed and analyzed after sampling. The invention more particularly applies to the field of petroleum industry and it is notably intended to take a sample of a petroleum effluent in form of an emulsion at wellheads.
    Type: Grant
    Filed: October 9, 2001
    Date of Patent: March 7, 2006
    Assignee: Institut Francais du Petrole
    Inventors: Gilbert Duriez, Aurélie Mouret, Christine Noïk, Gérard Papon
  • Patent number: 6950750
    Abstract: A method of evaluating the volume ratio of gas to oil (GOR) in the fluids of a well during drilling by direct or indirect measurement of the volumes of gas and oil in the cuttings. The method includes determining the volume of gas (Vg) contained in the drilling fluids by measuring a ratio between a volume of gas produced and a corresponding volume of drilled rock, determining the volume of oil (Vo) by measuring the total organic carbon (TOC) in the drilled rock while taking account of physical characteristics of the drilled rock and of the oil under the surface conditions, and determining said volume ratio (GOR) by calculating the ratio of the previously determined volumes of gas and of oil. The method can be implemented in the field, even on a drilling site, using a Rock-Eval type equipment for example.
    Type: Grant
    Filed: August 25, 2003
    Date of Patent: September 27, 2005
    Assignee: Institut Francais du Petrole
    Inventor: Bernard Carpentier
  • Patent number: 6852286
    Abstract: A device is provided for extraction of samples of an aqueous solution in a substratum. A probe made up of a pyrometric capsule of porous porcelain has one end of lesser diameter to which is attached a tube of inert material. The tube is sealed hermetically by a rubber cap with two drilled holes. An adapted pipe is fitted into one of the drilled holes for connection to a vacuum pump, and a suction capillary is placed in the other drilled hole.
    Type: Grant
    Filed: March 22, 2001
    Date of Patent: February 8, 2005
    Inventor: Estanislao Martinez Martinez
  • Patent number: 6773921
    Abstract: Indicia of stability or thresholds of instability may be used to assess the proximity of hydrocarbon materials such as petroleum residua to deposition of carbon rich materials. The invention may be used to evaluate suitability of such hydrocarbon materials to various types of processing methodologies, or to determine processing parameters, either prior to processing or during processing. Prediction of proximity to deposition of carbon rich materials may result in continuous process parameters or increased output, decreased energy use or decreased amount of emissions per unit of such hydrocarbon materials compared to conventional processing technology. Products produced or products processed with this technology may also have a higher level of purity.
    Type: Grant
    Filed: December 10, 2001
    Date of Patent: August 10, 2004
    Assignee: The University of Wyoming Research Corporation
    Inventors: John F. Schabron, Joseph F. Rovani, Jr.
  • Patent number: 6630357
    Abstract: A method of determining the composition of a sample including heavy oil or bitumen and water using low-field NMR. The NMR spectrum of the sample is taken at relatively low and high temperatures and the oil or water content is determined from the spectra and differential spectrum.
    Type: Grant
    Filed: February 2, 2001
    Date of Patent: October 7, 2003
    Assignee: University Technologies International Inc.
    Inventors: Konstantin Mirotchnik, Kevin Allsopp, Apostolos Kantzas, Daniel Marentette
  • Patent number: 6599747
    Abstract: A test for determining the bioavailable fraction of an organic pollutant present in soil comprises determining the fraction of the organic pollutant present in the soil which may be extracted by a cyclodextrin or derivative thereof.
    Type: Grant
    Filed: June 22, 2000
    Date of Patent: July 29, 2003
    Assignee: University of Lancaster
    Inventors: Brian John Reid, Kirk Taylor Semple, Kevin Christopher Jones
  • Patent number: 5976883
    Abstract: Provided is a method for testing earth samples for contamination by organic contaminants, and particularly for aromatic compounds such as those found in diesel fuel and other heavy fuel oils, kerosene, creosote, coal oil, tars and asphalts. A drying step is provided in which a drying agent is contacted with either the earth sample or a liquid extract phase to reduce to possibility of false indications of contamination that could occur when humic material is present in the earth sample. This is particularly a problem when using relatively safe, non-toxic and inexpensive polar solvents such as isopropyl alcohol since the humic material tends to be very soluble in those solvents when water is present. Also provided is an ultraviolet spectroscopic measuring technique for obtaining an indication as to whether a liquid extract phase contains aromatic organic contaminants.
    Type: Grant
    Filed: September 30, 1996
    Date of Patent: November 2, 1999
    Assignee: The University of Wyoming Research Corporation
    Inventor: John F. Schabron
  • Patent number: 5969240
    Abstract: A method for determining the resistivity of water in an oil well site that includes rock that is capable of water entrapment, includes the steps of:(a) retrieving a sample of the rock;(b) identifying any entrapped water in the sample; and(c) determining the resistivity of the entrapped water. The so determined resistivity then enables oil reserves to be calculated in the well site.
    Type: Grant
    Filed: April 29, 1998
    Date of Patent: October 19, 1999
    Assignee: Commonwealth Scientific and Industrial Research Organisation
    Inventors: Peter John Eadington, Mark Lisk, Francis William Krieger
  • Patent number: 5958777
    Abstract: A device for determining at least one petroleum characteristic of a geologic sediment sample placed in a boat, said device including a first heater heating said sample in a non-oxidizing atmosphere, a measuring component determining hydrocarbon-containing products released after feeding the sample into said first heater, a second subsequent heater heating said sample in an oxidizing atmosphere, a measuring component determining the amount of CO.sub.2 contained in effluents discharged from the two heaters, said CO.sub.2 measuring means include a cell for measuring continuously CO.sub.2 throughout heating of the first and second heaters and a measuring component determining the amount of CO contained in the effluents discharged from the two heaters, and thereby allowing determination of said petroleum characteristic.
    Type: Grant
    Filed: February 5, 1998
    Date of Patent: September 28, 1999
    Assignee: Institut Francais du Petrole
    Inventors: Jean Espitalie, Francois Marquis
  • Patent number: 5928948
    Abstract: A porous material (10) is contaminated with soil (14). Optionally, the porous material is partially shielded by an impermeable layer. The contaminated porous material is packaged and shipped to a user site. The contaminated porous material is removed from the package and placed in an automated processor containing medical equipment (22). The medical equipment and porous material are subjected to a cleaning, disinfecting, or sterilizing cycle in the processor. The cleaning process is evaluated by examining the porous material with an infrared or other electronic reader (24) to determine the presence of remaining soil which has not be removed during the cleaning, disinfecting, or sterilizing cycle.
    Type: Grant
    Filed: March 10, 1997
    Date of Patent: July 27, 1999
    Assignee: Steris Corporation
    Inventor: Paul S. Malchesky
  • Patent number: 5922611
    Abstract: A method of determining a parameter of a physical model representing the electrical behavior of a composition is provided. The method comprises defining said model by a relationship between the electrical properties of the composition, a plurality of physical variables of the composition and said parameter, and measuring an electrical property of the composition. A sample which is representative for said composition is selected, and an electrical property of the sample is measured for various magnitudes of at least one of said physical variables. An incoherence function is selected, defining a difference between the measured electrical properties and the electrical properties as calculated from said relationship, said incoherence function being such that independent measurements are weighted in dependence of their accuracy. The parameter is determined by minimization of the incoherence function.
    Type: Grant
    Filed: April 28, 1997
    Date of Patent: July 13, 1999
    Assignee: Shell Oil Company
    Inventors: Johannes Maria Vianney Antonius Koelman, Andre De Kuijper, Robert Karl Josef Sandor
  • Patent number: 5876671
    Abstract: A standard laboratory module for automatically producing a solution of cominants from a soil sample. A sonication tip agitates a solution containing the soil sample in a beaker while a stepper motor rotates the sample. An aspirator tube, connected to a vacuum, draws the upper layer of solution from the beaker through a filter and into another beaker. This beaker can thereafter be removed for analysis of the solution. The standard laboratory module encloses an embedded controller providing process control, status feedback information and maintenance procedures for the equipment and operations within the standard laboratory module.
    Type: Grant
    Filed: May 30, 1995
    Date of Patent: March 2, 1999
    Assignee: The Regents of the University of California office of Technology Transfer
    Inventors: Tony Beugelsdijk, Robert M. Hollen, Tracy H. Erkkila, Lawrence E. Bronisz, Jeffrey E. Roybal, Michael Leon Clark
  • Patent number: 5858791
    Abstract: Saturation variations are obtained by displacing a first fluid (for example water) that initially saturates a sample (1) coated with resin (2) by injecting therein, through a first end plate or cap (3) and by means of a pump (7), a second fluid (for example oil). The mixture flowing out through an opposite end plate (4) is collected in an initially filled two-phase separator (9) placed on an electronic balance (10). The first excess fluid flows towards a vessel (13), and the progressive accumulation of the second fluid in separator (9) leads to a variation in the total weight. A programmed processor (14) computes permanently the saturation values of the sample with respect to the first and to the second fluid, from the measured weight variations of separator (9). The method and device can be used for laboratory measurements of rock samples for example.
    Type: Grant
    Filed: September 17, 1997
    Date of Patent: January 12, 1999
    Assignee: Institute Francais du Petrole
    Inventor: Christian Lemaire
  • Patent number: 5843787
    Abstract: A method allowing fast assessment of at least one petroleum characteristic of geologic sediments from a sample of these sediments, said method comprising heating the sample in a non-oxidizing atmosphere, and which method comprises different temperature rise stages; determining at least three magnitudes S.sub.1r, S.sub.2a and S.sub.b representative of the quantity of hydrocarbons contained in said sample, and deducing at least one petroleum characteristic of the geologic sediment from these three magnitudes.
    Type: Grant
    Filed: September 16, 1996
    Date of Patent: December 1, 1998
    Assignee: Institut Francais du Petrole
    Inventors: Khomsi Trabelsi, Jean Espitalie
  • Patent number: 5811308
    Abstract: The present invention relates to a method for determining at least one petroleum characteristic of a geologic sediment sample heated in a non-oxidizing atmosphere and an oxidizing atmosphere. The sample is heated to a first temperature value below 200.degree. C. for a predetermined period of time and then to a second temperature value ranging between 600 and 850.degree. C. according to a temperature gradient between 0.2.degree. C. and 50.degree. C./min. Carbon dioxide and carbon monoxide are continuously measured during the temperature stages in order to determine at least one petroleum characteristic, wherein said petroleum characteristic comprises a quantity of organic oxygen, inorganic oxygen, total organic carbon, or inorganic carbon.
    Type: Grant
    Filed: October 7, 1996
    Date of Patent: September 22, 1998
    Assignee: Institut Francais Du Petrole
    Inventors: Jean Espitalie, Francois Marquis
  • Patent number: 5786225
    Abstract: A method of evaluating at least on type of pollution characteristic in a soil sample contaminated by hydrocarbon compounds, a method wherein the soil sample is first heated in a non-oxidizing atmosphere, then in an oxidizing atmosphere. The method comprises several temperature rise stages from which at least five quantities Q.sub.0, Q.sub.1, Q.sub.2, Q.sub.3 and Q.sub.4 are measured, wherein the quantities represent concentrations of hydrocarbon compounds in the soil sample. At least one type of pollution characteristic of the sample is determined from quantities Q.sub.0, Q.sub.1, Q.sub.2, Q.sub.3 and Q.sub.4.
    Type: Grant
    Filed: November 13, 1996
    Date of Patent: July 28, 1998
    Assignee: Institut Francais du Petrole
    Inventors: Eric Lafargue, Jean Ducreux, Fran.cedilla.ois Marquis, Daniel Pillot
  • Patent number: 5766953
    Abstract: Methods to determine the geographic sources of soil samples are described. A biological fingerprint profile of the sample is determined. The profile is compared to a library which is constructed of datasets which relate biological profiles and geographic locations of soil samples. The invention provides a tool for identification of pollution sources of soil origin.
    Type: Grant
    Filed: April 17, 1997
    Date of Patent: June 16, 1998
    Assignee: The United States of America as represented by the Secretary of the Agriculture
    Inventor: Ann C. Kennedy
  • Patent number: 5741707
    Abstract: A method and apparatus for analyzing a sample to determine its mineral composition. The invention combines X-ray diffraction with Fourier transform infrared spectroscopy to provide a complete spectrum including molecular vibrations, probed by FTIR scans and lattice spacing measured by X-ray diffraction in a single representation. This FX spectrum provides a more complete and accurate mineralogy than either of the techniques alone. In addition, new techniques for independent X-ray diffraction analysis and FTIR analysis are described.
    Type: Grant
    Filed: June 24, 1994
    Date of Patent: April 21, 1998
    Assignee: Schlumberger Technology Corporation
    Inventors: Michael M. Herron, Abigail Matteson, Michael Supp
  • Patent number: 5595914
    Abstract: Precise and accurate determination of gypsum in soils has been difficult, laborious and time consuming by currently available methods. The present invention solves such problems by: 1) Direct removal of nongypsic sulfate from 2-g soil sample with 25-mL portion of 50-% (v/v) ethanol, thus, eliminating positive errors in gypsum measurement from sulfate analysis while causing essentially no loss in gypsum content of the sample, and 2) stoichiometric conversion of soil gypsum to Na.sub.2 SO.sub.4 and CaCO.sub.3 (s) by two equlibrations of the soil sediment with 25-mL increments of 0.5M Na.sub.2 CO.sub.3 solution plus 30-s sonification. The SO.sub.4 in the supernatent solution is centrifuge separated, analyzed by the standard BaSO.sub.4 gravimetric and turbidimetric methods, and gypsum content is computed from equation [8]:gypsum(g)/soil(kg)=[SO.sub.4 (g) /soil(kg)(172/96.
    Type: Grant
    Filed: October 23, 1995
    Date of Patent: January 21, 1997
    Inventor: Mohammed S. Berigari
  • Patent number: 5561065
    Abstract: Provided is a method for testing earth samples for contamination by organic contaminants, and particularly for aromatic compounds such as those found in diesel fuel and other heavy fuel oils, kerosene, creosote, coal oil, tars and asphalts. A drying step is provided in which a drying agent is contacted with either the earth sample or a liquid extract phase to reduce to possibility of false indications of contamination that could occur when humic material is present in the earth sample. This is particularly a problem when using relatively safe, non-toxic and inexpensive polar solvents such as isopropyl alcohol since the humic material tends to be very soluble in those solvents when water is present. Also provided is an ultraviolet spectroscopic measuring technique for obtaining an indication as to whether a liquid extract phase contains aromatic organic contaminants.
    Type: Grant
    Filed: November 14, 1994
    Date of Patent: October 1, 1996
    Assignee: University of Wyoming Research Corporation
    Inventor: John F. Schabron
  • Patent number: 5526705
    Abstract: An apparatus analyzes a plurality of soil samples to determine characteristics of the soil samples. An input portion sequentially provides a plurality of soil samples each having a known solid content. A plurality of vessels are supported for movement with a continuous conveyor relative to the input portion to receive the soil samples. A plurality of testing stations are arranged relative to the continuous conveyor to sequentially access the samples carried by the vessels. The testing stations each test the samples to determine at least one of the characteristics of the samples.
    Type: Grant
    Filed: August 5, 1994
    Date of Patent: June 18, 1996
    Assignee: Tyler Limited Partnership
    Inventors: Andrey V. Skotnikov, Vladimier A. Bobrov
  • Patent number: 5416024
    Abstract: A collective fluid inclusions volatiles sample is released from each of a plurality of sedimentary rock samples and analyzed as it is being released to determine composition thereof. Compositions are used for mapping the earth's subsurface.
    Type: Grant
    Filed: July 2, 1993
    Date of Patent: May 16, 1995
    Assignee: Amoco Corporation
    Inventor: Michael P. Smith
  • Patent number: 5395768
    Abstract: A method is described to evaluate the R.sub.wb parameter, which can be applied to the Dual Water log interpretation model by measuring the resistivity of initial brines and of filtrates from muds prepared with shales. The method allows a more precise evaluation of the R.sub.wb parameter and eventually the reservoir porosity as well as the hydrocarbon storage capacity of a given reservoir.
    Type: Grant
    Filed: January 29, 1991
    Date of Patent: March 7, 1995
    Assignee: Petroleo Brasileiro S.A. - Petrobras
    Inventor: Geraldo G. Nery
  • Patent number: 5385827
    Abstract: A method of geochemical prospecting where samples of soil, sediment and rock in a geological area are collected and each sample is contacted with a leach solution of water, glucose and glucose oxidase. The oxidase acts upon the glucose to produce gluconic acid and hydrogen peroxide. The leach solution reacts with manganese dioxide carrying trace metal elements and compounds in the samples to produce a leach reaction solution. The leach reaction solution and the residue of the said sample are separated, and the leach reaction solution is analyzed to determine the trace metal content present. From the analysis, the mineral content of the geological area is predicted.
    Type: Grant
    Filed: October 16, 1992
    Date of Patent: January 31, 1995
    Inventor: John R. Clark
  • Patent number: 5344781
    Abstract: Methods and apparatuses for detecting leakage of hydrocarbons from and preventing corrosion of underground storage tanks. Soil samples near an underground storage tank are taken and analyzed in the field, preferably using hexane as a solvent to detect the presence of hydrocarbons such as heating and waste oil. The soil-to-tank potential of the tank and the presence of water within the tank are measured and, if warranted, cathodic protection provided to the tank to prevent corrosion or further corrosion.
    Type: Grant
    Filed: April 17, 1991
    Date of Patent: September 6, 1994
    Assignee: International Lubrication and Fuel Consultants
    Inventors: Nancy E. Kitchen, Edward F. Kitchen, George H. Kitchen, III
  • Patent number: 5328849
    Abstract: A collective fluid inclusions volatiles sample is released from each of a plurality of sedimentary rock samples and analyzed as it is being released to determine composition thereof. Compositions are used for mapping the earth's subsurface.
    Type: Grant
    Filed: May 19, 1992
    Date of Patent: July 12, 1994
    Assignee: Amoco Corporation
    Inventor: Michael P. Smith
  • Patent number: 5306640
    Abstract: Methods are provided for using Nuclear Magnetic Resonance (NMR) spectroscopy to measure the bulk volume of oil and water in the polyurethane liner of sponge core. The method is accurate, rapid, and non-destructive. It provides information simultaneously in oil composition and viscosity.
    Type: Grant
    Filed: October 28, 1987
    Date of Patent: April 26, 1994
    Assignee: Shell Oil Company
    Inventors: Harold J. Vinegar, Pierre N. Tutunjian
  • Patent number: 5299453
    Abstract: A method and apparatus is provided to determine the amount of oil and water or brine in a representative core sample of reservoir rock at an overburden stress which approximates reservoir stress conditions. The core sample is initially saturated with reservoir hydrocarbon (crude oil) and aqueous fluids (water or brine). The core sample is surrounded with an elastic jacket, or sleeve, and placed in a confining pressure vessel that simulates reservoir overburden stress on the core sample. The hydrocarbon (oil) fluids and aqueous fluids (water or brine) are than extracted from the core sample with a solvent capable of dissolving both aqueous and hydrocarbon fluids. The solvent and aqueous fluids are separated from the hydrocarbon fluids by evaporation. Thereafter the aqueous fluids are separated from the solvent by extraction. The amounts of oil and aqueous fluids from the sample may be separately determined.
    Type: Grant
    Filed: January 28, 1993
    Date of Patent: April 5, 1994
    Assignee: Mobil Oil Corporation
    Inventors: Eve S. Sprunt, Nizar F. Djabbarah
  • Patent number: 5288695
    Abstract: A process for determining an end member age of an illite component in an earth sample which contains a diagenetic illite component and a detrital illite component. As a first step, the sample is separated into a plurality of fractions so that the fractions will have different mean ages of illite. Next, the relative percentage of one of the illite components is determined for each fraction. The mean age of total illite in each fraction is determined using potassium-argon age analysis. The determined relative percentages are then correlated with the determined mean ages to generate a linear relationship. The end member age for each illite component can then be determined by using the linear relationship since zero percent of one of the illite components corresponds to the end member age of the other illite component.
    Type: Grant
    Filed: October 2, 1992
    Date of Patent: February 22, 1994
    Assignee: Exxon Production Research Company
    Inventor: David R. Pevear