Chalcogen Or Halogen Attached Indirectly To The Phosphorus By Acyclic Nonionic Bonding Patents (Class 44/379)
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Patent number: 11958875Abstract: A mixture including a thiophosphoric acid product suitable for preparing organometallic and/or ashless antiwear additives having improved copper corrosion performance. The thiophosphoric acid product is distilled and recovered as a condensate of the distillation and having a low level of active sulfur.Type: GrantFiled: March 31, 2023Date of Patent: April 16, 2024Assignee: Afton Chemical CorporationInventors: Brandon Knouse, David Edwards, Magdalena Makowska, Gregory James
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Patent number: 11884893Abstract: An oil-soluble ashless antiwear additive and a lubricating composition including the ashless antiwear additive having improved copper corrosion performance obtained by reacting an organic hydroxy compound with phosphorus pentasulfide to form a reaction product, distilling the reaction product and recovering a condensate, and reacting the condensate with an unsaturated carboxylic acid to form an oil-soluble phosphorus antiwear additive.Type: GrantFiled: March 31, 2023Date of Patent: January 30, 2024Assignee: Afton Chemical CorporationInventors: Brandon Knouse, David Edwards, Magdalena Makowska, Gregory James, Robert Mccovick
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Patent number: 10808194Abstract: High temperature antioxidant additives and methods that improve a liquid fuel composition's thermal oxidative stability are disclosed. A liquid fuel composition may comprise a liquid fuel and a high temperature antioxidant additive. The high temperature antioxidant additive may comprise an indoline compound with a bicyclic ring structure, wherein the indoline compound comprises a six-membered aromatic ring and a five-membered aliphatic ring that share a carbon-carbon aromatic bond. The five-membered aliphatic ring may be heterocyclic and may comprise a nitrogen positioned in an alpha position to the six-membered aromatic ring.Type: GrantFiled: November 25, 2019Date of Patent: October 20, 2020Assignee: ExxonMobil Research and Engineering CompanyInventors: David J. Abdallah, Zsolt Lengyel
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Patent number: 10294435Abstract: Aviation gasolines and additives may have manganese-containing anti-knock components. The scavengers herein mitigate the possible deleterious effects from using the manganese-containing anti-knock. The scavengers include molecules with a central atom of a Group 15 element other than nitrogen. Entities that are attached to the central atom are electron withdrawing entities including electron deficient atoms and electron deficient functional groups.Type: GrantFiled: November 1, 2016Date of Patent: May 21, 2019Assignee: Afton Chemical CorporationInventors: Joseph Anthony Calderone, III, Zachary John McAfee
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Patent number: 8790423Abstract: Described herein are modified fuels with improved properties. The modified fuels are more efficient when compared to conventional fuels such as gasoline. Additionally, the modified fuels burn more efficiently and produce fewer emissions. Finally, the modified fuels also do not require any modifications to existing engines.Type: GrantFiled: August 4, 2009Date of Patent: July 29, 2014Assignee: Spirit of the 21st Century Group, LLCInventors: David Henry Goss, Thomas Oscar Goss, Jr.
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Publication number: 20120317875Abstract: Systems and methods for processing glycerol into one or more products are provided. In at least one specific embodiment, the method can include decreasing a pH of a mixture comprising glycerol and fatty acids to produce an emulsion comprising a glycerol-rich portion and a fatty acids-rich portion. At least a portion of the glycerol-rich portion can be reacted with an acid comprising phosphorus at conditions sufficient to produce a reacted product comprising glycerophosphoric acid, glycerol, and a portion of the acid.Type: ApplicationFiled: August 20, 2012Publication date: December 20, 2012Applicant: Envirosource, Inc.Inventors: Spencer S. Awbrey, John Deloach, Tony Alexander, Don Darbonne, Marilyn Darbonne
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Publication number: 20110179696Abstract: Systems and methods for processing glycerol into one or more products are provided. In at least one specific embodiment, the method can include decreasing a pH of a mixture comprising glycerol and fatty acids to produce an emulsion comprising a glycerol-rich portion and a fatty acids-rich portion. At least a portion of the glycerol-rich portion can be reacted with an acid comprising phosphorus at conditions sufficient to produce a reacted product comprising glycerophosphoric acid, glycerol, and a portion of the acid.Type: ApplicationFiled: April 1, 2011Publication date: July 28, 2011Applicant: Envirosource, Inc.Inventors: Spencer S. Awbrey, John Deloach, Tony Alexander, Don Darbonne, Marilyn Darbonne
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Publication number: 20110091408Abstract: Fluoroalkyl phosphates containing a tertiary carbon and a nonfluorinated chain are useful as surfactants and additives. The f can be used to alter a surface property of a medium and to provide resistance to blocking, open time extension, or oil repellency to a substrate.Type: ApplicationFiled: October 20, 2009Publication date: April 21, 2011Applicant: E. I. DU PONT DE NEMOURS AND COMPANYInventor: Anilkumar Raghavanpillai
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Publication number: 20100031558Abstract: Described herein are modified fuels with improved properties. The modified fuels are more efficient when compared to conventional fuels such as gasoline. Additionally, the modified fuels burn more efficiently and produce fewer emissions. Finally, the modified fuels also do not require any modifications to existing engines.Type: ApplicationFiled: August 4, 2009Publication date: February 11, 2010Applicant: SPIRIT OF THE 21ST CENTURY GROUP, LLCInventors: David Henry GOSS, Thomas Oscar GOSS, JR.
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Patent number: 7645305Abstract: Improved highly stable formulation for aqueous fuel emulsion compositions with a water continuous phase, having reduced NOx emissions. The fuel emulsion formulation includes diesel fuel, purified water, and an additive package that includes one or more surfactants, lubricity additive, cetane improver, anti-corrosion additive, and an alcohol or other suitable antifreeze, the emulsion having an average droplet size of less than 10 microns.Type: GrantFiled: July 1, 1998Date of Patent: January 12, 2010Assignee: Clean Fuels Technology, Inc.Inventors: Gerald N. Coleman, Dennis L. Endicott, Edward A. Jakush
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Patent number: 5630852Abstract: The lubricity (anti-wear properties) of hydrocarbon fuels, oxygenate fuels or mixtures thereof, particularly diesel or aviation fuels having reduced sulphur and/or aromatic content for compliance with regulatory requirements, is improved by the addition of a phosphorus ester or esters (phosphates and/or phosphites), or a concentrate containing the ester or esters, having a total acid number at least 1.0 mg KOH/g. The additives also improve corrosion inhibition.Type: GrantFiled: November 23, 1994Date of Patent: May 20, 1997Assignee: FMC CorporationInventor: Douglas G. Placek
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Patent number: 5490864Abstract: A diesel fuel composition which is comprised of:(a) a major portion of a low-sulfur content diesel fuel; and(b) a minor amount, as an anti-wear lubricity additive, of a dithiophosphoric diester-dialcohol.Type: GrantFiled: June 22, 1994Date of Patent: February 13, 1996Assignee: Texaco Inc.Inventors: Sheldon Herbstman, Doris Love, Michael P. Petrus, Cyril A. Migdal
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Patent number: 5437694Abstract: Vinyl pyrrolidinone capped phosphorodithioates have been found to be effective multifunctional antiwear/antioxidant additives for fuel compositions.Type: GrantFiled: June 24, 1994Date of Patent: August 1, 1995Assignee: Mobil Oil CorporationInventors: Liehpao O. Farng, Andrew G. Horodysky, Ronald J. Poole
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Patent number: 5344468Abstract: Compositions comprising a hydrocarbonaceous middle distillate fuel and a minor wear-inhibiting amount of a combination of (i) at least one fuel-soluble aryl phosphate of the formula(RO).sub.3 POwherein each R is, independently, phenyl or an alkyl-substituted phenyl group; and (ii) at least one fuel-soluble aryl polyphosphate of the formula ##STR1## wherein each R is, independently, phenyl or an alkyl-substituted phenyl group, Ar is m-phenylene or an alkyl-substituted m-phenylene group, and n is from 1 to 4. The combination contains from 2 to 30% by weight of component (i). These compositions are made by (a) reacting about 1.9 to about 2.1 equivalents of phenol or alkyl-substituted phenol with one equivalent of phosphoryl trihalide, and (b) reacting the intermediate product formed in (a) with from about 0.9 to about 1.1 equivalents of resorcinol or alkyl-substituted resorcinol per equivalent of phosphoryl trihalide employed in (a). Alternatively, the compositions are made by (a) reacting about 0.9 to about 1.Type: GrantFiled: September 23, 1992Date of Patent: September 6, 1994Assignee: Ethyl Petroleum Additives, Inc.Inventors: J. Vincent Hanlon, John G. Bostick, Charles H. Kolich
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Patent number: 5084069Abstract: A lubricant or fuel composition contains a multifunctional antioxidant and antiwear amount of an O,O-diorgano-S-(2-hydroxyalkyl) phosphorodithioate derived hydrogen phosphonate which can be made by reacting a diorganophosphorodithioic acid with an epoxide and a dialkyl phosphite, such as dimethyl phosphite.Type: GrantFiled: October 22, 1990Date of Patent: January 28, 1992Assignee: Mobil Oil CorporationInventors: Liehpao O. Farng, Andrew G. Horodysky