Product Polymerized Through An Olefinic Double Bond Patents (Class 44/392)
  • Patent number: 10767128
    Abstract: A copolymer obtained by copolymerization of at least: an apolar monomer (ma) with the following formula (I), where u=0 or I, w=0 or I, E=-0- or —NH(Z)—, or —O—CO—, or —NH—CO— or —CO—NH—, wherein Z is H or an alkyl group, and G is a group selected among an alkyl, an aromatic ring and an arylalkyl; and a polar monomer (mb) selected among those of the following formula (II), wherein t=0 or I, Q is selected among the oxygen atom and the —NR?— group, wherein R? is selected among a hydrogen atom and hydrocarbon chains, and R is a hydrocarbon chain substituted by at least one quaternary ammonium group and optionally one or more hydroxyl groups. The invention also relates to the use of such a copolymer as a detergent additive in a liquid fuel of an internal combustion engine.
    Type: Grant
    Filed: July 20, 2017
    Date of Patent: September 8, 2020
    Assignee: TOTAL MARKETING SERVICES
    Inventor: Julie Prevost
  • Publication number: 20150059238
    Abstract: The present invention relates to the use of polyalkyl(meth)acrylates as an additive to fuels, especially middle distillate fuels and blends thereof. The present invention further relates to the use of a composition comprising polyalkyl(meth)acrylates as dispersing species susceptible to disperse waxes and sludgy material at low temperatures and a hydrocarbon solvent/an oil for improving the cold flow properties of fuel oil and fuel oil compositions. The present invention further relates to the use of these compositions as an additive to fuels, especially in the function of paraffin dispersant, to such fuels themselves and to fuel additive concentrates which comprise this composition dissolved in a hydrocarbon solvent or an oil.
    Type: Application
    Filed: April 22, 2013
    Publication date: March 5, 2015
    Applicant: EVONIK OIL ADDITIVES GMBH
    Inventors: Julien Couet, Frank-Olaf Maehling, Rene Koschabek, Sandra Kuenzel
  • Patent number: 8721744
    Abstract: A copolymer with high chemical homogeneity, consisting of (A) 50 to 30% by weight of ethylene, (B) 50 to 70% by weight of C4- to C24-hydrocarbyl ester of (meth)acrylic acid, (C) 0 to 5% by weight of (meth)acrylic acid and (D) 0 to 10% by weight of copolymerizable monomers, obtainable by polymerizing a mixture of 80 to 60% by weight of ethylene, 20 to 40% by weight of (meth)acrylic acid and 0 to 10% by weight of copolymerizable monomers in a backmixing, continuous polymerization apparatus, and subsequently polymer-analogously esterifying the resulting copolymer with C4- to C24-hydrocarbinols. The inventive copolymer is suitable for improving the cold flow properties of fuel oils, for lowering the lower mixing temperature of cold flow improver additives into fuel oils, and for improving the filterability of fuel oils comprising cold flow improver additives.
    Type: Grant
    Filed: July 5, 2011
    Date of Patent: May 13, 2014
    Assignee: BASF SE
    Inventors: Frank-Olaf Maehling, Jan Strittmatter, Irene Troetsch-Schaller, Ivette Garcia Castro, Michael Schroers, Uwe Rebholz
  • Publication number: 20120277133
    Abstract: This invention relates to functionalized polymers derived from functionalized monomers. The functionalized polymer may be reacted with an enophilic reagent (e.g., maleic anhydride) to form an enophilic reagent modified functionalized polymer. The functionalized polymer may be further reacted with one or more additional reagents, e.g., an oxygen-containing reagent (e.g., alcohol, polyol), a nitrogen-containing reagent (e.g., amine, polyamine, aminoalcohol), a metal, a metal compound, or a mixture of two or more thereof. The invention relates to lubricants, functional fluids, fuels, dispersants, detergents and polymer compositions.
    Type: Application
    Filed: March 23, 2012
    Publication date: November 1, 2012
    Inventors: Stephen A. DiBiase, Syed Q.A. Rizvi, Georgeta Hategan
  • Publication number: 20110308145
    Abstract: A method of inhibiting deposit formation in a jet fuel at temperatures above 150° C., whilst not substantially adversely affecting the water separability of the jet fuel. The method includes the step of adding at least one copolymer, terpolymer or polymer of an ester of acrylic acid or methacrylic acid or a derivative thereof to the jet fuel; wherein the copolymer, terpolymer or polymer of an ester of acrylic acid or methacrylic acid or derivative thereof is copolymerized with a nitrogen-containing, amine-containing or amide-containing monomer; or the copolymer, terpolymer or polymer of an ester of acrylic acid or methacrylic acid or derivative thereof includes nitrogen-containing, amine-containing or amide-containing branches.
    Type: Application
    Filed: August 31, 2011
    Publication date: December 22, 2011
    Inventors: Andrew C. Sutkowski, Roger W. Glyde
  • Patent number: 8034131
    Abstract: A method of inhibiting deposit formation in a jet fuel at temperatures above 150° C., whilst not substantially adversely affecting the water separability of the jet fuel. The method includes the step of adding at least one copolymer, terpolymer or polymer of an ester of acrylic acid or methacrylic acid or a derivative thereof to the jet fuel; wherein the copolymer, terpolymer or polymer of an ester of acrylic acid or methacrylic acid or derivative thereof is copolymerized with a nitrogen-containing, amine-containing or amide-containing monomer; or the copolymer, terpolymer or polymer of an ester of acrylic acid or methacrylic acid or derivative thereof includes nitrogen-containing, amine-containing or amide-containing branches.
    Type: Grant
    Filed: November 12, 2004
    Date of Patent: October 11, 2011
    Assignee: Infineum International Limited
    Inventors: Andrew C. Sutkowski, Roger W. Glyde
  • Patent number: 7942941
    Abstract: The present invention generally relates to oil compositions, primarily to fuel oil and petroleum compositions produced there from susceptible to wax formation at low temperatures, to polymeric amides for use with such fuel oil compositions, and to methods for their manufacture.
    Type: Grant
    Filed: April 5, 2005
    Date of Patent: May 17, 2011
    Assignee: Akzo Nobel N.V.
    Inventors: Rodney Lee Cravey, Stephen L. Mead
  • Publication number: 20100287822
    Abstract: Polymeric mist control materials, methods of forming polymeric mist control materials, and methods of using such materials for mist control are provided. The polymeric mist control additives are formed of molecules comprised predominantly of monomers that confer high solubility in fuel and include associative groups that attract each other in donor-acceptor manner, and are incorporated such that multiple associative groups are in close proximity (“clusters”), such that the clusters are separated by very long non-associative sequences.
    Type: Application
    Filed: April 19, 2010
    Publication date: November 18, 2010
    Applicant: California Institute of Technology
    Inventors: Ming-Hsin Wei, Julie A. Kornfield, R.L. Ameri David
  • Patent number: 7815697
    Abstract: The invention provides a fuel oil composition comprising a fuel oil of mineral origin and a fuel oil of vegetable and/or animal origin and as a cold additive, the constituents, at least one copolymer composed of ethylene and 8-21 mol % of at least one acrylic and vinyl ester having a C1-C18 alkyl radical and at least one comb polymer containing structural units composed of at least one olefin as monomer 1 which bears at least one C8-C18 alkyl radical on the olefinic double bond, and at least one ethylenically unsaturated dicarboxylic acid as monomer 2 which bears at least one C8-C16 alkyl radical bonded via an amide and/or imide moiety.
    Type: Grant
    Filed: December 10, 2004
    Date of Patent: October 19, 2010
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Matthias Krull, Bettina Siggelkow, Martina Hess
  • Publication number: 20040231235
    Abstract: The present invention provides a polymeric compound comprising at least one monomer unit of Formula I 1
    Type: Application
    Filed: September 26, 2003
    Publication date: November 25, 2004
    Inventors: Cyrus Pershing Henry, David Leonard Pinch, Andrea Sneddon, Derek Richard Green
  • Publication number: 20010022046
    Abstract: A novel crosslinked emulsifier is employed to produce a stable aqueous hydrocarbon fuel emulsion.
    Type: Application
    Filed: January 16, 2001
    Publication date: September 20, 2001
    Inventors: Claire L. Thompson, Douglas M. Barr
  • Patent number: 5976202
    Abstract: Reaction products of polyolefins having predominantly a terminal double bond and a number average molecular weight of from 250 to 10,000, which possess an aliphatic hydrocarbon skeleton which is straight-chain or carries C.sub.1 -C.sub.4 -alkyl side chains, with from 1 to 10 mol, per equivalent of double bond, of one or more vinyl esters I ##STR1## are obtainable by reacting the stated polyolefins with the vinyl esters I in the presence of a free radical initiator at from 80 to 200.degree. C., it being possible for these reaction products subsequently to have been hydrolyzed to the corresponding alcohols or converted into the corresponding amines by reductive amination with amines II ##STR2## .
    Type: Grant
    Filed: July 20, 1995
    Date of Patent: November 2, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Hans Peter Rath, Helmut Mach, Harald Schwahn, Hans-Joachim Muller, Wolfgang Reif, Thomas Ruhl
  • Patent number: 5906970
    Abstract: A dendrimer-based cold flow additive material.
    Type: Grant
    Filed: March 20, 1997
    Date of Patent: May 25, 1999
    Assignee: Exxon Chemical Patents Inc.
    Inventor: Robert Dryden Tack
  • Patent number: 5466267
    Abstract: Additives which improve the low-temperature properties of distillate fuels are the oligomeric/polymeric reaction products of aromatic anhydrides and epoxides (or their corresponding acid/diol equivalents), with optional termonomers.
    Type: Grant
    Filed: September 17, 1992
    Date of Patent: November 14, 1995
    Assignee: Mobil Oil Corporation
    Inventors: David J. Baillargeon, Angeline B. Cardis, Dale B. Heck, Susan W. Johnson
  • Patent number: 5284495
    Abstract: Additives which improve the low-temperature properties of distillate fuels are the oligomeric/polymeric reaction products of anhydrides and one or more of the following long-chain diols: aminodiols, diaminodiols, amidodiols, with optional termonomers.
    Type: Grant
    Filed: September 17, 1992
    Date of Patent: February 8, 1994
    Assignee: Mobil Oil Corporation
    Inventors: David J. Baillargeon, Angeline B. Cardis, Dale B. Heck, Susan W. Johnson
  • Patent number: 5284494
    Abstract: Additives which improve the low-temperature properties of distillate fuels are oligomeric/polymeric reaction products consisting of cross-linked anhydride and cross-linked epoxide (or their corresponding acid/diol equivalents), with optional termonomers.
    Type: Grant
    Filed: September 17, 1992
    Date of Patent: February 8, 1994
    Assignee: Mobil Oil Corporation
    Inventors: David J. Baillargeon, Angeline B. Cardis, Dale B. Heck, Susan W. Johnson
  • Patent number: 5240469
    Abstract: A method for preventing fouling of ethylene dichloride distillation units which comprises treating the feed to such units with a fouling preventing amount of a composition comprising:______________________________________ INGREDIENTS WEIGHT % ______________________________________ a) An oil soluble polymethacrylate 2-15 ester which contains from between .1-25 mole % of amino alcohol ester groups with the balance of the alcohol radical of the ester group containing from C.sub.4 -C.sub.22 carbon atoms, b) a phenylene diamine compound 20-40 having the formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are the same or different and are hydrogen, C.sub.1 -C.sub.20 alkyl, C.sub.1 -C.sub.20 aryl, C.sub.1 -C.sub.20 alkaryl or C.sub.1 -C.sub.20 aralkyl, with the proviso that at least one of R.sub.1, R.sub.2, R.sub.3 or R.sub.
    Type: Grant
    Filed: April 27, 1992
    Date of Patent: August 31, 1993
    Assignee: Nalco Chemical Company
    Inventor: Michael K. Poindexter
  • Patent number: 5178641
    Abstract: Crude oil middle distillates with improved cold flow properties, containing small amounts ofA. conventional flow improver on an ethylene base, andB. copolymers which consist of 10 to 95 mol-% of one or more acrylacrylates or alkylmethacrylates with C.sub.1 - to C.sub.26 -alkyl chains, and of 5 to 90 mol-% of one or more ethylenically unsaturated dicarboxylic acids or their anhydrides, where the copolymer is reacted to a large extent with one or several primary or secondary amines into the monoamide or amide/ammonia salt of dicarboxylic acid, and the quantitative proportion of A to B is from 40 to 60 up to 95 to 5.
    Type: Grant
    Filed: November 13, 1991
    Date of Patent: January 12, 1993
    Assignee: BASF Corporation
    Inventors: Gerd Konrad, Bernd Wenderoth, Klaus Barthold, Erich Schwartz, Hans-Juergen Raubenheimer, Heinrich Hartmann
  • Patent number: 5080690
    Abstract: Products of reaction between 1-alkyl-N,N-dialkyl ethanolamines and copolymers of maleic anhydride are new additives which are effective in lowering the cloud point of distillate fuels.
    Type: Grant
    Filed: December 29, 1989
    Date of Patent: January 14, 1992
    Assignee: Mobil Oil Corp.
    Inventors: David J. Baillargeon, Angeline B. Cardis, Susan W. Johnson, Carl E. Shanholtz
  • Patent number: 5011504
    Abstract: AB and ABA block copolymers of acrylics and acrylic amines are useful as oil additives to diminish sediment and color formation. The copolymers are preferably formed by group transfer polymerization.
    Type: Grant
    Filed: July 27, 1990
    Date of Patent: April 30, 1991
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Cyrus P. Henry, Michael W. J. West