Plural Nitrogens In The Organic Nitrogen Compound (e.g., Diamines, Aminoamides, Guanidines, Etc.) Patents (Class 44/409)
  • Patent number: 10577556
    Abstract: A lubricating composition suited to use in a marine diesel engine includes an oil of lubricating viscosity and an amino carboxylate compound of formula (I): NR1R2—((CHR3)xNR4)n—(CHR5)2—COY, where R1 and R2 are independently selected from —(CHR6)2—COY?, H, and C1C3 alkyl and wherein at least one of R1 and R2 is —(CHR6)2—COY?; or wherein NR1R2 is a cyclic structure; Y and Y? are independently selected from —OR7, NHR7, and —N(R7)2; each R7 is independently selected from C6-C12 alkyl and C6-C12 alkenyl; R3, R5 and R6 are independently selected from H and C1-C4 alkyl; R4 is selected from H, C1-C4 alkyl, and (CHR3)xNH2; x is from 2 to 4; and n is at least 1, except where NR1R2 is a cyclic structure, where n is at least 0.
    Type: Grant
    Filed: June 10, 2016
    Date of Patent: March 3, 2020
    Assignee: The Lubrizol Corporation
    Inventors: Daniel J. Saccomando, Natasha K. Horn, Ewan E. Delbridge, Stephen J. Cook, John K. Pudelski, Mark C. Davies
  • Patent number: 8863700
    Abstract: In accordance with the disclosure, exemplary embodiments provide a fuel additive concentrate, a method for cleaning fuel injectors, a method for restoring power to a diesel fuel injected engine, a fuel composition, and a method of operating a fuel injected diesel engine. The additive concentrate includes (a) a hydrocarbyl substituted quaternary ammonium internal salt; and (b) a reaction product of (i) a hydrocarbyl substituted dicarboxylic acid, anhydride, or ester and (ii) an amine compound or salt thereof of the formula wherein R is selected from hydrogen and a hydrocarbyl group containing from about 1 to about 15 carbon atoms, and R1 is selected from hydrogen and a hydrocarbyl group containing from about 1 to about 20 carbon atoms. The reaction product (b) on average has less than 2 amino-triazole groups per molecule. A weight ratio of (a) to (b) in the additive concentrate ranges from about 10:1 to about 1:10.
    Type: Grant
    Filed: November 1, 2012
    Date of Patent: October 21, 2014
    Assignee: Afton Chemical Corporation
    Inventors: Xinggao Fang, Scott D. Schwab
  • Publication number: 20100139153
    Abstract: A method of improving the low temperature properties of an oil comprising fatty acid alkyl esters derived from plant or animal materials, wherein at least 5% by weight of the fatty acid alkyl esters are derived from C16-C22 saturated fatty acids. The method comprising reacting at least a portion of the oil with a polyalkylene polyamine or an imidazoline compound carrying both a poly-alkylene imine substituent and at least one primary amine group.
    Type: Application
    Filed: December 3, 2009
    Publication date: June 10, 2010
    Inventors: Robert D. Tack, Diana Riano-Gordo
  • Patent number: 6858046
    Abstract: This invention relates to an emulsified water-blended fuel composition comprising: (A) a hydrocarbon boiling in the gasoline or diesel range; (B) water; (C) a minor emulsifying amount of at least one fuel-soluble salt made by reacting (C)(I) at least one acylating agent having about 16 to 500 carbon atoms with (C)(II) ammonia and/or at least one amine; and (D) about 0.001 to about 15% by weight of the water-blended fuel composition of a water soluble, ashless, halogen-, boron-, and phosphorus-free, amine salt, distinct from component (C). In one embodiment, the composition further comprises (E) at least one cosurfactant distinct from component (C); in one embodiment, (F) at least one organic cetane improver; and in one embodiment, (G) at least one antifreeze. The invention also relates to a method for fueling an internal combustion engine comprising fueling said engine with the composition of the present invention.
    Type: Grant
    Filed: February 5, 2002
    Date of Patent: February 22, 2005
    Assignee: The Lubrizol Corporation
    Inventors: Daniel T. Daly, John J. Mullay, Elizabeth A. Schiferl
  • Publication number: 20040093790
    Abstract: Fuel compositions comprising a major amount of a normally liquid fuel and a minor amount of a hydroxylamine or a salt thereof, more often wherein each hydroxylamino group of the hydroxylamine or salt thereof contains no more than one tertiary alkyl substituent. The hydroxylamine or salt thereof provide improved combustion properties to a wide variety of normally liquid fuels, including hydrocarbon based fuels, oxygenates and synthetic fuels.
    Type: Application
    Filed: August 22, 2003
    Publication date: May 20, 2004
    Inventors: Mark R. Baker, Douglas M. Barr, Daniel T. Daly
  • Publication number: 20040010967
    Abstract: A friction modifier for combustible fuels is provided that is prepared by combining a saturated carboxylic acid and an alkoxylated amine or etheramine. Furthermore, there also is an additive concentrate for use in fuels, especially in gasoline for internal combustion engines, comprising (a) a friction modifier comprising of a branched saturated carboxylic acid salt of an alkoxylated amine, such as isohexyloxypropylamine isostearate; (b) a detergent package, as well as the combustible fuels containing this additive concentrate. The particular selection of friction modifier (a) enables a stable additive concentrate to be formulated providing a significant benefit in friction loss when incorporated in gasoline used to fuel an internal combustion engine, and hence an improvement in fuel economy.
    Type: Application
    Filed: April 22, 2003
    Publication date: January 22, 2004
    Inventors: Allen A. Aradi, Dennis J. Malfer, Scott D. Schwab, William J. Colucci
  • Publication number: 20040010966
    Abstract: A method for reducing the formation of combustion chamber deposits in an engine using a friction modifier for combustible fuels is provided. The friction modifier is prepared by combining a saturated carboxylic acid and an alkylated or alkoxylated amine. The particular selection of friction modifier enables a stable additive concentrate to be formulated providing a significant decrease in CCD without increasing the incidence of IVD deposits in combustion engines running on a fuel modified with the additive concentrate.
    Type: Application
    Filed: March 26, 2003
    Publication date: January 22, 2004
    Inventors: Allen A. Aradi, Dennis J. Malfer, Scott D. Schwab, William J. Colucci
  • Patent number: 6648929
    Abstract: This invention relates to an emulsified water-blended fuel composition comprising: (A) a hydrocarbon boiling in the gasoline or diesel range; (B) water; (C) a minor emulsifying amount of at least one fuel-soluble salt made by reacting (C)(I) at least one acylating agent having about 16 to 500 carbon atoms with (C)(II) ammonia and/or at least one amine; and (D) about 0.001 to about 15% by weight of the water-blended fuel composition of a water soluble, ashless, halogen-, boron-, and phosphorus-free, amine salt, distinct from component (C). In one embodiment, the composition further comprises (E) at least one cosurfactant distinct from component (C); in one embodiment, (F) at least one organic cetane improver; and in one embodiment, (G) at least one antifreeze. The invention also relates to a method for fueling an internal combustion engine comprising fueling said engine with the composition of the present invention.
    Type: Grant
    Filed: September 14, 1998
    Date of Patent: November 18, 2003
    Assignee: The Lubrizol Corporation
    Inventors: Daniel T. Daly, John J. Mullay, Elizabeth A. Schiferl
  • Publication number: 20030200697
    Abstract: A friction modifier for combustible fuels is provided that is prepared by combining a saturated carboxylic acid and an alkylated amine. Furthermore, there also is an additive concentrate for use in fuels, especially in gasoline for internal combustion engines, comprising (a) a friction modifier comprising of a branched saturated carboxylic acid salt of an alkylated amine, such as n-butylamine isostearate; (b) a detergent package, as well as the combustible fuels containing this additive concentrate. The particular selection of friction modifier (a) enables a stable additive concentrate to be formulated providing a significant benefit in friction loss when incorporated in gasoline used to fuel an internal combustion engine, and hence an improvement in fuel economy.
    Type: Application
    Filed: April 24, 2002
    Publication date: October 30, 2003
    Inventors: Allen A. Aradi, Dennis J. Malfer, Scott D. Schwab
  • Publication number: 20020129541
    Abstract: This invention relates to an emulsified water-blended fuel composition comprising: (A) a hydrocarbon boiling in the gasoline or diesel range; (B) water; (C) a minor emulsifying amount of at least one fuel-soluble salt made by reacting (C)(I) at least one acylating agent having about 16 to 500 carbon atoms with (C)(II) ammonia and/or at least one amine; and (D) about 0.001 to about 15% by weight of the water-blended fuel composition of a water soluble, ashless, halogen-, boron-, and phosphorus-free, amine salt, distinct from component (C). In one embodiment, the composition further comprises (E) at least one cosurfactant distinct from component (C); in one embodiment, (F) at least one organic cetane improver; and in one embodiment, (G) at least one antifreeze. The invention also relates to a method for fueling an internal combustion engine comprising fueling said engine with the composition of the present invention.
    Type: Application
    Filed: February 5, 2002
    Publication date: September 19, 2002
    Inventors: Daniel T. Daly, John J. Mullay, Elizabeth A. Schiferl
  • Patent number: 6051039
    Abstract: This invention relates to a diesel fuel composition containing an additive composition made by admixing at least two components: A) at least one dicarboxylic acid having about 8 to about 500 carbon atoms or a reactive equivalent thereof; and B) at least one amine having about 6 to about 80 carbon atoms. In one embodiment, the additive composition also contains: C) at least one monocarboxylic acid of about 8 to about 28 carbon atoms or a reactive equivalent thereof. The additive composition is useful as a lubricity additive for diesel fuel, especially low sulfur diesel fuel and provide excellent storage stability, rust-inhibiting and anti-wear performance to diesel fuel.
    Type: Grant
    Filed: September 14, 1998
    Date of Patent: April 18, 2000
    Assignee: The Lubrizol Corporation
    Inventor: Shigeru Sugimoto
  • Patent number: 5264005
    Abstract: This invention relates to a two-cycle engine lubricant composition, comprising (A) at least one dispersant, (B) at least one reaction product of a fatty acid and a polyamine, and (C) at least about 25% by weight of the composition of at least one varnish dissolver selected from (a) keto-alcohols, (b) carboxylic esters having up to a total of 24 carbon atoms and (c) alkoxy alcohols, and (D) at least about 15% by weight of the composition of at least one fluidizing oil, and a method, comprising the steps of introducing into a two-cycle internal combustion engine a fuel-lubricant mixture comprising a major amount of a fuel and a minor amount sufficient to increase compression or release stuck piston rings, of the two-cycle engine lubricant composition.
    Type: Grant
    Filed: August 9, 1991
    Date of Patent: November 23, 1993
    Assignee: The Lubrizol Corporation
    Inventor: Glen H. Blythe
  • Patent number: 5160350
    Abstract: This invention describes a water fix for an alcohol containing gasoline which has been formulated with a lead replacement.
    Type: Grant
    Filed: December 6, 1991
    Date of Patent: November 3, 1992
    Assignee: The Lubrizol Corporation
    Inventor: Stephen H. Stoldt
  • Patent number: 5152807
    Abstract: Sediment and color formation in diesel and heating fuel oils, especially those comprising a cracked fraction, may be reduced by incorporating in the fuel oil a guanidinium or substituted guanidinium salt.
    Type: Grant
    Filed: March 15, 1990
    Date of Patent: October 6, 1992
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Michael D. Sexton, Rosalind H. Strange