Process Including Removal Of Undesirable Patents (Class 44/505)
  • Patent number: 11319603
    Abstract: A method for processing lignocellulose materials comprising the steps of hydrothermal treatment of the material with saturated or superheated steam in a hydrothermal pressure vessel, wherein the steam is provided by means of a steam boiler. The treatment is performed at a pressure of 5-30 bars, and at a temperature of 160-240° C. for a duration of 1-20 minutes. The method further comprises discharging hydrothermally treated lignocellulose material and steam from the pressure vessel by means of rapid pressure reduction, separating the steam and vapours released from the lignocellulose material, and burning the vapours together with additional fuel and combustion air in the furnace of said steam boiler. Furthermore, a corresponding system is provided.
    Type: Grant
    Filed: September 21, 2018
    Date of Patent: May 3, 2022
    Assignee: VALMET AB
    Inventors: Peter Björklund, Mattias Erixon, Francois Lambert, Andreas Averheim
  • Patent number: 10538716
    Abstract: A process and system for producing an engineered fuel product that meets customer specifications for composition and combustion characteristics is provided. The engineered fuel product is preferably a high-BTU, alternative fuel that burns cleaner than coal or petroleum coke (petcoke) and has significantly reduced NOx, SO2 and GHG emissions.
    Type: Grant
    Filed: September 4, 2015
    Date of Patent: January 21, 2020
    Assignee: WM INTELLECTUAL PROPERTY HOLDINGS, L.L.C.
    Inventors: Robert A. Toberman, Thomas F. Perry
  • Patent number: 10358351
    Abstract: Methods, apparatuses, and systems to collect fine particle coal are provided herein. For example, these methods, apparatuses, and systems may be incorporated into a coal processing plant to collect a portion of the fine particle coal that is normally lost in the system. A fine particle coal also is provided. The fine particle coal may have a particle size of 1000 ?m or smaller and a water content of from about 5% to about 20%, by weight.
    Type: Grant
    Filed: May 28, 2015
    Date of Patent: July 23, 2019
    Assignee: Somerset Coal International, Inc.
    Inventor: Richard Troiano
  • Patent number: 9879287
    Abstract: The process for the dry fractionation of lignocellulosic biomass of at least 50% by weight of lignins, cellulose and hemicelluloses. The biomass is fragmented to obtain an ultrafine powder. The process includes at least one step of separating a fraction enriched with cellulose and a fraction enriched with lignin, hemicelluloses and minerals by electrostatic sorting of the ultrafine particles. Preferably, the fraction separation step includes a step of triboelectrostatic charging of ultrafine particles and at least one step of deviating a path in the electric field of the charged particles to sort the particles.
    Type: Grant
    Filed: December 24, 2014
    Date of Patent: January 30, 2018
    Assignees: INSTITUT NATIONAL DE LA RECHERCHE AGRONOMIQUE, CIRAD
    Inventors: Bruno Piriou, Abdellatif Barakat, Xavier Rouau, Gilles Vaitilingom
  • Patent number: 9441175
    Abstract: A process to produce low ash clean coal from high ash coal with substantially complete solvent recovery, the process including: forming a slurry of coal fines in a N-Methyl-2-pyrrolidone (NMP) and Ethylenediamine (EDA) solution; maintaining said slurry in a reactor at a temperature range of 100° C. to 240° C. and a pressure range of 1 to 4 gauge (kg/cm2) for a period of about 15 minutes to 4 hours; separating the produced sample withdrawn from the reactor, one part being a filtrate and the other a reject; feeding the filtrate into an evaporator to recover 80-85% solvent; precipitating the concentrated filtrate material in an anti-solvent tank to separate coal from solvent; separating the coal by filtration, said separated coal having a reduced ash content; feeding the anti-solvent and solvent mixture into a distillation column to separate remaining solvent from the anti-solvent for reuse in the process.
    Type: Grant
    Filed: September 4, 2012
    Date of Patent: September 13, 2016
    Assignee: Tata Steel Limited
    Inventors: Vimal Kumar Chandaliya, Pinakpani Biswas, Pradip Kumar Banerjee
  • Publication number: 20150047253
    Abstract: To provide less expensive and non-polluting coals of which calorific values are increased by improving composition of coals having high moisture content and low fire power, such as peat and lignite, to thereby increase combustion calorie. Materials of coals are heated in a predetermined temperature range in an oxygen-free atmosphere while injecting inactive gas, and elements except for carbon in the atmosphere and in the coals are individually separated by thermal decomposition in the order from an element having a lower decomposition temperature at a temperature of 450 degrees C. or lower so as to obtain upgraded coals. Since the carbon composing the upgraded coals has strong activity, the upgraded coals have quality equivalent or greater than that of the coal of ordinary quality and demonstrate combustion efficiency that has been significantly improved from those of the materials before upgrading.
    Type: Application
    Filed: August 16, 2013
    Publication date: February 19, 2015
    Inventor: Kunimichi SATO
  • Publication number: 20150007492
    Abstract: The present invention relates to a solid fuel in the form of a powder, including at least one lignocellulosic component in the form of a powder. The present invention also relates to the method for preparing said lignocellulosic component in the form of a powder, as well as to the use thereof in the production of a solid fuel intended for an internal combustion engine or a burner. The invention further relates to a method for generating energy using the solid fuel according to the invention.
    Type: Application
    Filed: January 15, 2013
    Publication date: January 8, 2015
    Inventors: Bruno Piriou, Gilles Vaitilingom, Xavier Rouau
  • Patent number: 8906336
    Abstract: A carbonaceous material substitute product for blast furnace metallurgical coal and method of making the carbonaceous material is disclosed. A metallurgical coal substitute material is made from non-metallurgical grade coal or other carbon sources.
    Type: Grant
    Filed: April 29, 2009
    Date of Patent: December 9, 2014
    Inventors: Siddhartha Gaur, Vibha Bansal
  • Publication number: 20140283439
    Abstract: A process for optimizing a biomass feedstock for gasification for the production of syngas. The biomass feed, which is preferably a lignocellulosic material, is subjected to controlled torrefaction so that the biomass only undergoes a weight loss of about 10% to 15% on a dry ash free basis. This increases the energy density and friability of the so treated biomass and results in higher efficiency on subsequent gasification.
    Type: Application
    Filed: March 21, 2013
    Publication date: September 25, 2014
    Applicant: SynGas Technology, LLC
    Inventors: Jacqueline R Hitchingham, Lloyd R. White, Christian T. Goralski, JR.
  • Patent number: 8703081
    Abstract: Sorbent compositions containing halogen and calcium are added to coal to mitigate the release of sulfur and/or other harmful elements, including mercury, into the environment during combustion of coal containing natural levels of mercury.
    Type: Grant
    Filed: September 25, 2013
    Date of Patent: April 22, 2014
    Assignee: NOx II, Ltd.
    Inventor: Douglas C. Comrie
  • Patent number: 8673030
    Abstract: The invention provides a method by which high moisture low rank coal or other carbonaceous material may be transformed into a high-energy, water resistant product. The raw feed is comminuted then mechanically compacted by a roller press with rolls of a specified profile to mobilize the inherent moisture and collapse most of the interstitial pore space. The mobilized moisture is then removed by low-temperature drying and the material is sized and shaped to form a product that is resistant to re-absorption of water or other liquids. The present invention will promote the use of low rank coal for liquefaction and gasification.
    Type: Grant
    Filed: August 1, 2008
    Date of Patent: March 18, 2014
    Assignee: GTL Energy Holdings Pty Limited
    Inventors: Robert R. French, Robert A. Reeves, Patrick B. Auell
  • Publication number: 20130340328
    Abstract: A process for cleaning and dewatering hydrophobic particulate materials is presented. The process is performed in two steps: 1) agglomeration of the hydrophobic particles in a first hydrophobic liquid/aqueous mixture; followed by 2) dispersion of the agglomerates in a second hydrophobic liquid to release the water trapped within the agglomerates along with the entrained hydrophilic particles.
    Type: Application
    Filed: June 11, 2013
    Publication date: December 26, 2013
    Applicant: VIRGINIA TECH INTELLECTUAL PROPERTIES, INC.
    Inventor: Roe-Hoan YOON
  • Publication number: 20130337131
    Abstract: A process of treating biomass such as sugar cane bagasse utilizing practically all components of the biomass to produce livestock feed and fuel biomass. Raw bagasse is ensiled for 50-60 days, dried, mechanically separated from soil particles and ground together with plant-derived lignocellulosic materials, pelletized feed material, agricultural processing residues, or by-products at a ratio of 2:1. The resultant ground material is used as cattle feed, feed additives, fuel pellets and for other purposes.
    Type: Application
    Filed: June 18, 2012
    Publication date: December 19, 2013
    Inventor: RANDAL MYERS
  • Patent number: 8545778
    Abstract: Sorbent compositions containing halogen and calcium are added to coal to mitigate the release of sulfur and/or other harmful elements, including mercury, into the environment during combustion of coal containing natural levels of mercury.
    Type: Grant
    Filed: November 16, 2012
    Date of Patent: October 1, 2013
    Assignee: NOx II, Ltd.
    Inventor: Douglas C. Comrie
  • Publication number: 20130111808
    Abstract: Fine coal is cleaned of its mineral matter impurities and dewatered by mixing the aqueous slurry containing both with a hydrophobic liquid, subjecting the mixture to a phase separation. The resulting hydrophobic liquid phase contains coal particles free of surface moisture and droplets of water stabilized by coal particles, while the aqueous phase contains the mineral matter. By separating the entrained water droplets from the coal particles mechanically, a clean coal product of substantially reduced mineral matter and moisture contents is obtained. The spent hydrophobic liquid is separated from the clean coal product and recycled. The process can also be used to separate one type of hydrophilic particles from another by selectively hydrophobizing one.
    Type: Application
    Filed: January 31, 2011
    Publication date: May 9, 2013
    Applicant: Virginia Tech Intellectual Properties ,Inc.
    Inventors: Roe-Hoan Yoon, Mert K. Eraydin, Chad Freeland
  • Patent number: 8435314
    Abstract: The present application relates to a method for the preparation, by torrefaction, of a solid fuel wherein a starting composition is heated indirectly. The present invention also relates to a solid fuel to be obtained by such method. The present application further relates to a method for the removal of one or more metals from or the reduction of the “total chlorine content”, the sulphur content and the trace element content of a solid fuel thus obtained. In addition to that, the present invention relates to a solid fuel, which can be obtained by the carrying out of such a method. Finally, the present invention relates to the uses of such solid fuels.
    Type: Grant
    Filed: July 6, 2012
    Date of Patent: May 7, 2013
    Assignee: Torr-Coal Technology, B.V.
    Inventor: Gerard Hubert Joseph Ruiters
  • Patent number: 8313323
    Abstract: Sorbent compositions containing halogen and calcium are added to coal to mitigate the release of sulfur and/or other harmful elements, including mercury, into the environment during combustion of coal containing natural levels of mercury.
    Type: Grant
    Filed: January 4, 2012
    Date of Patent: November 20, 2012
    Assignee: NOx II, Ltd.
    Inventor: Douglas C. Comrie
  • Publication number: 20120279115
    Abstract: The present application relates to a method for the preparation, by torrefaction, of a solid fuel wherein a starting composition is heated indirectly. The present invention also relates to a solid fuel to be obtained by such method. The present application further relates to a method for the removal of one or more metals from or the reduction of the “total chlorine content”, the sulphur content and the trace element content of a solid fuel thus obtained. In addition to that, the present invention relates to a solid fuel, which can be obtained by the carrying out of such a method. Finally, the present invention relates to the uses of such solid fuels.
    Type: Application
    Filed: July 6, 2012
    Publication date: November 8, 2012
    Inventor: GERARD HUBERT JOSEPH RUITERS
  • Patent number: 8298304
    Abstract: A coal treatment process containing a coal-beneficiation process module. The module is implemented into the conventional coal treatment process of a coal-fired power plant after a first step of grinding the coal in a coal mill. The process module sequentially extracts chemical substances of non-combustible ash, water, mercury and oil that are found in coal before the coal is fired, so that present invention can produce valuable products and achieve a high quality cleaned powdered coal-char to burn in a furnace to thereby reduce pollution and increase the efficiency of energy production from the coal.
    Type: Grant
    Filed: February 20, 2009
    Date of Patent: October 30, 2012
    Assignee: Castle Light Corporation
    Inventor: Keith A. Moore
  • Publication number: 20120266531
    Abstract: A process for pretreating a biomass feedstock for gasification for the production of syngas.
    Type: Application
    Filed: June 7, 2012
    Publication date: October 25, 2012
    Applicant: SYNGAS TECHNOLOGY INC.
    Inventors: Jacqueline R. Hitchingham, Lloyd R. White
  • Patent number: 8266821
    Abstract: A method for torrefaction of water containing cellulosic materials is performed in an inert atmosphere. The cellulosic material is cascaded through the apparatus between a plurality of rotatable trays vertically stacked within multiple processing zones. Steam being generated from heating of the cellulosic material is recycled back to the apparatus to provide an inert atmosphere. The steam may be superheated in a heat exchanger. Exhaust from the torrefaction zone of the apparatus has some moisture and other volatiles removed prior to being reheated in a burner. The heated exhaust is used in the heat exchanger to superheat the recycled steam.
    Type: Grant
    Filed: December 6, 2011
    Date of Patent: September 18, 2012
    Assignee: Wyssmont Company Inc.
    Inventors: Edward Weisselberg, Joseph Bevacqua, Robert Borre
  • Patent number: 8262751
    Abstract: An improved organo-refining process to produce low ash clean coal from high ash coal, comprising: mixing coal, solvent and a co-solvent to produce a slurry; feeding the slurry to a reactor by pumping; extracting a coal-solvent mixture from the reactor; feeding the extracted mixture to a flasher unit; recovering about 30% of the solvent from the flashing unit; feeding the remaining heavy material to an evaporator; extracting about 60% of solvent from the evaporator; discharging the residue from the evaporator to a precipitator having water which produces a coal slurry; filtering the slurry in a rotary drum; collecting the super clean coal as a residue and feeding the filtrate into a distillation unit; and separating the water and the organic material in the filtrate to recover at least 7 to 8% of the remaining solvent.
    Type: Grant
    Filed: June 5, 2009
    Date of Patent: September 11, 2012
    Assignee: Tata Steel Limited
    Inventors: Pinakpani Biswas, Vimal Kumar Chandaliya, Pradip Kumar Banerjee
  • Patent number: 8231696
    Abstract: The present application relates to a method for the preparation, by torrefaction, of a solid fuel wherein a starting composition is heated indirectly. The present invention also relates to a solid fuel to be obtained by such method. The present application further relates to a method for the removal of one or more metals from or the reduction of the “total chlorine content”, the sulphur content and the trace element content of a solid fuel thus obtained. In addition to that, the present invention relates to a solid fuel, which can be obtained by the carrying out of such a method. Finally, the present invention relates to the uses of such solid fuels.
    Type: Grant
    Filed: June 14, 2007
    Date of Patent: July 31, 2012
    Assignee: Torr-Coal Technology, B.V.
    Inventor: Gerard Hubert Joseph Ruiters
  • Publication number: 20120167457
    Abstract: The present disclosure provides methods, compositions and systems for drying coal fines.
    Type: Application
    Filed: March 8, 2012
    Publication date: July 5, 2012
    Inventors: Philip Harsh, Michael Hurley, Andrew K. Jones, Vinod K. Sikka
  • Patent number: 8114368
    Abstract: Sorbent compositions containing halogen and calcium are added to coal to mitigate the release of sulfur and/or other harmful elements, including mercury, into the environment during combustion of coal containing natural levels of mercury.
    Type: Grant
    Filed: June 27, 2011
    Date of Patent: February 14, 2012
    Assignee: NOx II, Ltd.
    Inventor: Douglas C. Comrie
  • Publication number: 20110283606
    Abstract: The invention relates to a process for processing brown coal for combustion and/or gasification for the purpose of power generation, wherein the brown coal moist from the pit is firstly subjected to preliminary crushing and is subsequently comminuted. The milled coal is then fed to drying in a fluidized-bed dryer. The process is characterized in that the milling apparatus is followed by a control sieving facility, with the sieve opening being selected so that essentially 100% of the brown coal passes the sieve.
    Type: Application
    Filed: November 24, 2008
    Publication date: November 24, 2011
    Applicant: RWE POWER AKTIENGESELLSCHAFT
    Inventor: Hans-Joachim Klutz
  • Publication number: 20110277380
    Abstract: A process for treating coal in which coal, in the form of particles in an aqueous slurry, is heated under pressure to at least partially release bound water from the coal particles, the bound water being released as liquid water. In one aspect, the coal particles of the slurry are hydraulically milled by means of the slurry water as the slurry pressure is reduced through the milling. In a second aspect, mineral and/or inorganic content is separated from the slurry by a flotation procedure that utilizes bubbling of released gases following reduction of the slurry pressure. Also disclosed is corresponding apparatus.
    Type: Application
    Filed: January 13, 2010
    Publication date: November 17, 2011
    Applicant: COMMONWEALTH SCIENTIFIC AND INDUSTRIAL RESEARCH ORGANISATION
    Inventor: Louis Wibberley
  • Publication number: 20110271587
    Abstract: A method for producing pulverized coal including the steps of providing a drying gas heated to a predefined temperature in a hot gas generator; feeding the heated drying gas into a pulverizer; introducing raw coal into the pulverizer, the pulverizer grinding the raw coal into pulverized coal; collecting a mixture of drying gas and pulverized coal from the pulverizer and feeding the mixture to a filter, the filter separating the dried pulverized coal from the drying gas; collecting the dried pulverized coal for further use and feeding the drying gas from the filter to an exhaust line; and collecting the drying gas exiting the filter and feeding part of the collected drying gas to a recirculation line for feeding recirculation drying gas to the hot gas generator.
    Type: Application
    Filed: January 21, 2010
    Publication date: November 10, 2011
    Applicant: PAUL WURTH S.A.
    Inventors: Paul Goedert, Markus Mayer, Georges Stamatakis, Bernard Cauwenberghs
  • Publication number: 20110258914
    Abstract: Methods, process, apparatus, equipment, and systems are disclosed for converting biomass into bio-oil fractions for chemicals, materials, feedstocks and fuels using a low-cost, integrated fast pyrolysis system. The system improves upon prior art by creating stable, bio-oil fractions which have unique properties that make them individually superior to conventional bio-oil. The invention enables water and low-molecular weight compounds to be separated into a final value-added fraction suitable for upgrading or extracting into value-added chemicals, fuels and water. Initial bio-oil fractions from the process are chemically distinct, have low-water content and acidity which reduces processing costs normally associated with conventional bio-oil post-production upgrading since fewer separation steps, milder processing conditions and lower auxiliary inputs are required. Biochar is stabilized so that it can be handled safely.
    Type: Application
    Filed: July 1, 2011
    Publication date: October 27, 2011
    Applicant: AVELLO BIOENERGY, INC.
    Inventors: Dennis S. BANASIAK, Anthony J.S. POLLARD, Cody J. ELLENS, Jared N. BROWN
  • Publication number: 20110214341
    Abstract: The invention relates to a method for processing a mixture of cellulose/plastic waste particles comprising cellulose and thermoplastic materials. The thermoplastic material constitutes at least 10 weight% of the total weight of the waste mixture The cellu-lose/plastic waste mixture is first dried by treatment with a medium with a temperature in the range of 50 to 150 ° C., wherein the exit temperature of the drying medium has a temperature of 115 ° C. or less. The dried cellulose/plastic waste mixture is then fed to a purification stage, and subjected to the operation of the purification stage. The purification stage comprises at least one separator selected from the group of: wind separator, sieve, metal separator, separator for separating out chlorine- containing components, or a combination thereof.
    Type: Application
    Filed: July 28, 2009
    Publication date: September 8, 2011
    Applicant: QLYTE TECHNOLOGIES B.V.
    Inventors: Mohammed Nafid, Ralph Koekkoek
  • Patent number: 7988939
    Abstract: Sorbent compositions containing halogen and calcium are added to coal to mitigate the release of sulfur and/or other harmful elements, including mercury, into the environment during combustion of coal containing natural levels of mercury.
    Type: Grant
    Filed: July 19, 2010
    Date of Patent: August 2, 2011
    Assignee: NOx II Ltd.
    Inventor: Douglas C. Comrie
  • Publication number: 20110099894
    Abstract: Methods and systems are disclosed for direct conversion of a used healthcare material into a burnable fuel and to burnable fuels derived therefrom.
    Type: Application
    Filed: November 1, 2009
    Publication date: May 5, 2011
    Applicant: SHARPS COMPLIANCE, INC.
    Inventors: Burton J. Kunik, James C. Berns
  • Publication number: 20100263269
    Abstract: A process for drying coal is provided in which coal is passed into a fluidized bed reactor and heated to a predetermined temperature. The dried coal is then fed to a cooler where the temperature of the product is reduced to approximately 200 degrees Fahrenheit and water is added to further passivate the coal.
    Type: Application
    Filed: September 24, 2009
    Publication date: October 21, 2010
    Applicant: River Basin Energy, Inc.
    Inventors: Donald D. Dunlop, Clinton B. Camper, Vijay Sethi, Leon C. Kenyon, JR.
  • Publication number: 20100242351
    Abstract: Methods and systems for preparing a torrefied biomass fuel are disclosed. Moisture is initially extracted from relatively wet biomass fuel to produce a relatively dry biomass fuel. Remaining moisture is then extracted from the relatively dry biomass fuel in a final drying stage, using steam at a temperature of about 900° F. The resulting dried biomass fuel is conveyed downward using gravity and undergoes torrefaction, which produces torrefied biomass fuel and torrefaction gases. A gaseous mixture of steam and torrefaction gases is vented to a heat exchanger, where the gaseous mixture is heated by a flue gas, and the heated gaseous mixture is used to support the extraction of the remaining moisture in the final drying stage and to support the torrefaction of the dried biomass fuel. Embodiments disclosed herein efficiently use available energy resources to the benefit of manufacturers, consumers, and the environment.
    Type: Application
    Filed: March 25, 2010
    Publication date: September 30, 2010
    Applicant: TERRA GREEN ENERGY, LLC
    Inventor: Thomas P. Causer
  • Publication number: 20090272027
    Abstract: The present application relates to a method for the preparation, by torrefaction, of a solid fuel wherein a starting composition is heated indirectly. The present invention also relates to a solid fuel to be obtained by such method. The present application further relates to a method for the removal of one or more metals from or the reduction of the “total chlorine content”, the sulphur content and the trace element content of a solid fuel thus obtained. In addition to that, the present invention relates to a solid fuel, which can be obtained by the carrying out of such a method. Finally, the present invention relates to the uses of such solid fuels.
    Type: Application
    Filed: June 14, 2007
    Publication date: November 5, 2009
    Applicant: TORR-COAL TECHNOLOGY B.V.
    Inventor: Gerard Hubert Joseph Ruiters
  • Publication number: 20090183424
    Abstract: This invention discloses systems and methods for conversion of high moisture waste materials to dry or low moisture products for recycle or reuse. The equipment systems comprise a gas turbine generator unit (preferred heat source), a dryer vessel and a processing unit, wherein the connection between the gas turbine and the dryer vessel directs substantially all the gas turbine exhaust into the dryer vessel and substantially precludes the introduction of air into the dryer vessel and wherein the processing unit forms the dried material from the dryer vessel into granules, pellets or other desired form for the final product. Optionally, the systems and methods further provide for processing ventilation air from manufacturing facilities to reduce emissions therefrom.
    Type: Application
    Filed: March 27, 2009
    Publication date: July 23, 2009
    Applicant: EARTHRENEW, INC.
    Inventors: Brian N. Gorbell, Christianne Carin, Alvin W. Fedkenheuer, John S. Jonasson, Alexander Starosud
  • Publication number: 20090158645
    Abstract: The invention provides a method by which high moisture low rank coal or other carbonaceous material may be transformed into a high-energy, water resistant product. The raw feed is comminuted then mechanically compacted by a roller press with rolls of a specified profile to mobilize the inherent moisture and collapse most of the interstitial pore space. The mobilized moisture is then removed by low-temperature drying and the material is sized and shaped to form a product that is resistant to re-absorption of water or other liquids. The present invention will promote the use of low rank coal for liquefaction and gasification.
    Type: Application
    Filed: August 1, 2008
    Publication date: June 25, 2009
    Inventors: Robert R. French, Robert A. Reeves, Patrick B. Auell
  • Patent number: 7507083
    Abstract: Processes and compositions are provided for decreasing emissions of mercury upon combustion of fuels such as coal. Various sorbent compositions are provided that contain components that reduce the level of mercury and/or sulfur emitted into the atmosphere upon burning of coal. In various embodiments, the sorbent compositions are added directly to the fuel before combustion; are added partially to the fuel before combustion and partially into the flue gas post combustion zone; or are added completely into the flue gas post combustion zone. In preferred embodiments, the sorbent compositions comprise a source of halogen and preferably a source of calcium. Among the halogens, iodine and bromine are preferred. In various embodiments, inorganic bromides make up a part of the sorbent compositions.
    Type: Grant
    Filed: March 16, 2006
    Date of Patent: March 24, 2009
    Inventor: Douglas C Comrie
  • Publication number: 20040111958
    Abstract: Coal ash, which also consists of fly ash, is a very fine granular solid residue obtained as a by-product of coal combustion. The invention relates to the surprising result that a fuel can be obtained from coal ash. The process involves a pneumatic separation of the coal ash at relatively low temperatures. The coal ash is separated into at least two size fractions. The size fractions obtained by the process of this invention include at least one with lower carbon and another containing increased levels of carbon in the range of 50% by weight and a heating value in the range of 4000 to 6000 Btu/lb.
    Type: Application
    Filed: December 16, 2002
    Publication date: June 17, 2004
    Inventors: David Bridson Oates, Alan Van Sloten, Jeffrey Fair, Trent Renfro, Craig Plunk
  • Publication number: 20010047614
    Abstract: A process and an installation for treating solid carbonaceous material comprises heating the material to a temperature of about 1800° C. or higher, by means of a non-transfer arc generated plasma flame. This causes components of, or present in, the carbonaceous material to be gasified and thus to be separated or removed from any residual solid material as a hot gas phase, with residual solid material being obtained as a product. The installation comprises a vertical shaft non-transfer arc plasma reactor comprising an upper preheating zone (14) an intermediate reaction zone (16) in which at least one non-transfer arc plasma generator or reactor (40) is located and a lower cooling zone (18).
    Type: Application
    Filed: February 27, 2001
    Publication date: December 6, 2001
    Inventors: Jacobus Swanepoel, Ruan Lombaard, Julian Charles Mast-Ingle
  • Patent number: 6193768
    Abstract: A particulate waste wood fuel comprising wood particles comprising less than 20% water by weight and having a particle size distribution suitable for combustion of the particulate wood fuel in a particulate fossil fuel suspension furnace. A method for making the particulate wood fuel includes shredding of waste wood and drying the shredded waste wood to obtain the desired particle size distribution and water content. A method for producing energy comprises injecting the particulate wood fuel into the combustion chamber of a particulate fuel suspension furnace separately from a particulate fossil fuel which is also injected into the combustion chamber. The particulate fossil fuel and particulate wood fuel are combusted in the combustion chamber in a gas flow through the combustion chamber to form a flame in the gas flow. The wood particles are substantially completely combusted within the combustion chamber while suspended in the gas flow and are not combusted at the furnace wall.
    Type: Grant
    Filed: September 27, 1994
    Date of Patent: February 27, 2001
    Assignee: MCX Environmental Energy Corp.
    Inventors: Claude Joseph Galipeault, Lawrence Edward Staab
  • Patent number: 6068671
    Abstract: In drying coal to be used as fuel for a coal-fired boiler, the coal is dried at a temperature of 80 to 150.degree. C. by using combustion exhaust gas having passed through an air heater for the coal-fired boiler. Moreover, after medium-quality or low-quality coal is heated to a temperature of 300 to 500.degree. C. at a heating rate of not less than 100.degree. C. per minute and then cooled to a temperature of 250.degree. C. or below at a cooling rate of not less than 50.degree. C. per minute, the resulting reformed coal is cooled to a temperature of 70.degree. C. or below and stored for 1 month or more in a state of isolation from the atmosphere. In producing the aforesaid reformed coal, the medium-quality or low-quality coal is heated by using combustion exhaust gas obtained at the outlet of an economizer included in the coal-fired boiler equipment or at the outlet of a denitrator included therein.
    Type: Grant
    Filed: March 23, 1998
    Date of Patent: May 30, 2000
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Masaki Iijima, Kiyomichi Taoda
  • Patent number: 5795484
    Abstract: An ultra-fine coal particle fraction forms a coal product with particles that are dilatant due to the mechanical stripping of the clay contaminates from the coal surface and the subdividing of the clay to clay platelets which are peptized to maintain discreetness in an aqueous slurry. The coal particles are unflocculated and can produce an aqueously permeable barrier on a sieve. The ultrafine coal product has an increase of 100-150 BTU per pound and when combusted reduced Nox production of 20-40% is realized. In a 15.times.0 micron coal fraction, the sulphur content is significantly reduced.
    Type: Grant
    Filed: May 8, 1995
    Date of Patent: August 18, 1998
    Inventor: Edward H. Greenwald, Sr.
  • Patent number: 5637122
    Abstract: The invention relates to electrostatic separation of coal from toxic and pyritic elements and ash compounds. More particularly this invention relates to separation of coal from refuse material by imparting opposite electrostatic charges to coal and refuse particles, passing them between oppositely charged electrodes and mechanically separating the electrostatically attracted diverging coal and refuse particles. The electrostatic attraction and divergent separation process is maximized by performing the charging and separation functions within a continuously vacuum reduced atmosphere. The use of a vacuum exhaust to continuously remove water and water vapor can prevent charge dissipation of the coal particles through charge transfer to water and water vapor. Additionally, the vacuum reduced atmosphere can prevent impairment of electrostatic influence due to gas turbulence.
    Type: Grant
    Filed: August 28, 1995
    Date of Patent: June 10, 1997
    Inventor: David K. Brown
  • Patent number: 5575824
    Abstract: The present invention provides for a fuel coal processing system having a centrifugal type coal pulverizer and an electrostatic type coal purifier and an optional fuel coal size classifier all combined into one integral, cooperatively acting fuel coal preparation device in one embodiment, and a centrifugal type coal pulverizer and fuel coal size classifier combined in a second embodiment. The centrifugal type coal pulverizer may be a counter rotating cup and ring assembly for breaking apart the coal particles and impurities. The coal particles and impurities leave the pulverizer in flat, radiating, sheet pattern which passes through the electrostatic purifier or separator. The electrostatic separator has a pair of plates which are oppositely charged and arranged next to the pulverizer. The top plate is negatively charged to attract the positively charged pure coal particles and repel the negatively charged pyritic particles.
    Type: Grant
    Filed: January 3, 1995
    Date of Patent: November 19, 1996
    Inventors: Charles K. Brown, David K. Brown
  • Patent number: 5468265
    Abstract: A method of treating coal. The method comprises passing the coal through a retort having a shell temperature of about 500.degree.-1000.degree. F. and shock heating the coal to a maximum surface temperature of about 500.degree.-1000.degree. F. without allowing the coal to become exothermic. The coal is prevented from going exothermic by a combination of factors, including the evaporation of moisture from the shock heated coal, the tendency of coal to absorb heat and maintain a temperature of about 390.degree.-570.degree. F. until the coal undergoes molecular transformation of complex hydrocarbons contained in the coal to simpler forms, and the effects of a cooling blanket gas passed through the shock heated coal. The blanket gas preferably comprises an oxygen lean blanket gas stream containing about 2-8% oxygen by volume. The treated coal exhibits extremely low moisture content and increased BTU value and other improved combustion characteristics.
    Type: Grant
    Filed: August 12, 1993
    Date of Patent: November 21, 1995
    Assignee: RJA Associates
    Inventor: Robert J. Adams
  • Patent number: 5350431
    Abstract: A process for chemical desulfurization of coal, in which coal is brought into contact with a desulfurizing agent after or while the coal is irradiated with ultraviolet light, thereby to give remarkably high desulfurization ratios and remarkably high yields of low sulfur coal.
    Type: Grant
    Filed: April 22, 1993
    Date of Patent: September 27, 1994
    Assignee: Idemitsu Kosan Company Limited
    Inventor: Toru Yamashita
  • Patent number: 5332407
    Abstract: A diesel fuel composition comprising a major portion of a middle distillate fuel oil and a minor portion, effective to clean deposits from diesel fuel injectors, of a diesel fuel detergent comprising the reaction product of:(a) a 4-alkyl-2-morpholinone represented by the formula: ##STR1## in which R represents a monovalent aliphatic radical having from 1 to 10 carbon atoms, and(b) an alkylphenoxypolyoxyalkylene amine represented by the formula: ##STR2## in which R' represents a hydrocarbyl radical having from 4 to 30 carbon atoms, x has a value from 5 to 50, and R" represents a methyl radical or a mixture of hydrogen and methyl radicals.A method of cleaning diesel fuel injectors is also provided.
    Type: Grant
    Filed: October 19, 1992
    Date of Patent: July 26, 1994
    Assignee: Texaco Inc.
    Inventor: Sheldon Herbstman
  • Patent number: 5275631
    Abstract: A fuel coal processing system is provided which consists of a centrifugal type pulverizer, a coal purifier and an optional fuel coal size classifier, all combined into one integral, cooperatively acting, fuel coal preparation device. The pulverizer consists of a pair of opposed multicup concentric ring rotors, mounted on a common axis, counter rotating at relatively high speed, an axially located feed tube through which material is fed into the center of the rotor system and then is thrown tangentially, progressively and outwardly from ring to ring on each of the counter rotating rotors thereby being reduced in size by the repeated high speed impacts and skidding abrasion associated with the process.
    Type: Grant
    Filed: August 17, 1992
    Date of Patent: January 4, 1994
    Inventors: Charles K. Brown, David K. Brown
  • Patent number: 5254139
    Abstract: A method of treating coal. The method comprises passing the coal through a retort having a shell temperature of about 500.degree.-1000.degree. F. and shock heating the coal to a maximum surface temperature of about 500.degree.-1000.degree. F. without allowing the coal to become exothermic. The coal is prevented from going exothermic by a combination of factors, including the evaporation of moisture from the shock heated coal, the tendency of coal to absorb heat and maintain a temperature of about 390.degree.-570.degree. F. until the coal undergoes molecular transformation of complex hydrocarbons contained in the coal to simpler forms, and the effects of a cooling blanket gas passed through the shock heated coal. The blanket gas preferably comprises an oxygen lean blanket gas stream containing about 2-8% oxygen by volume. The treated coal exhibits extremely low moisture content and increased BTU value and other improved combustion characteristics.
    Type: Grant
    Filed: August 5, 1991
    Date of Patent: October 19, 1993
    Inventor: Robert J. Adams