Fluorocarbon Containing Patents (Class 442/92)
  • Patent number: 9194078
    Abstract: A soil repellency aqueous dispersion for treating various fibers, yarns, and textiles is disclosed. The dispersion provides superior soil resistance when compared to known fluorochemical and silicone fiber treatments. The dispersion comprises clay nanoparticle components and fluorochemicals that can be applied to the fibers, yarns, and textiles using known methods.
    Type: Grant
    Filed: December 10, 2010
    Date of Patent: November 24, 2015
    Assignee: INVISTA North America S.a.r.l.
    Inventors: Isaac Keene Iverson, Martin August Rudat
  • Publication number: 20150079865
    Abstract: Expanded polytetrafluoroethylene (ePTFE) monofilament fibers and woven fabrics formed from the ePTFE fibers are provided. The ePTFE fibers have a substantially rectangular configuration, a density less than about 1.0 g/cc, and an aspect ratio greater than 15. Additionally, the ePTFE fibers are microporous and have a node and fibril structure. The ePTFE fiber may be woven into a fabric without first twisting the fiber. A polymer membrane and/or a textile may be laminated to the woven fabric to produce a laminated article. The ePTFE woven fabric simultaneously possesses high moisture vapor transmission (highly breathable) and high water entry pressure (water resistant). The woven fabric is quiet, soft, and drapable, making it especially suitable for use in garments, gloves and footwear applications. Treatments may be provided to the surface of the ePTFE fiber and/or the woven fabric to impart one or more desired functionality, such as, for example, oleophobicity.
    Type: Application
    Filed: September 17, 2013
    Publication date: March 19, 2015
    Applicant: W.L. Gore & Associates, Inc.
    Inventors: David J. Minor, Raymond B. Minor
  • Patent number: 8803115
    Abstract: The present invention relates to a coated microfibrous web, a process for producing the same, use thereof as a covering of a radiation protection material as well as a radiation protection device. The coated microfibrous web comprises: (i) a microfibrous web impregnated with a fluoropolymer; and (ii) a layer comprising polyurethane, which is present only on one side of the microfibrous web.
    Type: Grant
    Filed: August 10, 2010
    Date of Patent: August 12, 2014
    Assignee: Mavig GmbH
    Inventors: Thomas Leucht, Barbara Ballsieper
  • Patent number: 8735306
    Abstract: An article comprising a microporous membrane. A first porous fabric is laminated to a first side of the microporous membrane. A second porous fabric is laminated to a second opposite side of the microporous membrane to form a laminate with the membrane and the first porous fabric. The laminate has two fabric sides separated by the microporous membrane. A treatment material is applied to the laminate to form a treated laminate. The treated laminate has an oil resistance of at least a number 7 determined by AATCC 118 testing on both fabric sides and has an air permeability through the treated laminate of at least 0.01 CFM per square foot determined by ASTM D737 testing.
    Type: Grant
    Filed: November 1, 2010
    Date of Patent: May 27, 2014
    Assignee: BHA Altair, LLC
    Inventors: Martin Gregory Hatfield, Nusrat Farzana
  • Publication number: 20140038483
    Abstract: An object is to provide a cloth containing an organic fiber, which is excellent in the oil repellency, dirt-removal property by washing and water-absorbing property, and a textile product produced using the cloth. A means for solution is attaching a specific fluorine-containing polymer to a cloth containing an organic fiber, with a quaternary ammonium salt if desired, and thus making the water-absorbing property in accordance with JIS L1018A method (the instillation method) 60 seconds or less and the oil repellency in accordance with AATCC118-1992 grade 4 or higher.
    Type: Application
    Filed: April 18, 2012
    Publication date: February 6, 2014
    Applicant: TEIJIN FRONTIER CO., LTD.
    Inventor: Ryo Yasumitsu
  • Patent number: 8551895
    Abstract: A laminate is generally provided having alcohol repellency properties. In one particular embodiment, the laminate includes a meltblown web bonded to a spunbond web (e.g., a SM laminate, a SMS laminate, a SMMS laminate, etc.). A fluorinated polymeric coating is attached to the surface of the spunbond web (e.g., grafted). The fluorinated polymeric coating comprises a perfluoroalkyl(alkyl) (meth)acrylate monomer polymerized on the surface of the spunbond web via exposure to a low frequency energy source. The perfluoroalkyl(alkyl) (meth)acrylate monomer has a perfluoroalkyl side groups comprising —(CF2)z—F, where z is an integer from 1 to 6. The laminate has an alcohol repellency of greater than 80%.
    Type: Grant
    Filed: December 22, 2010
    Date of Patent: October 8, 2013
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Ali Yahiaoui, Anthony S. Spencer, Linda Connor Sledge, John Joseph Lassig, Eric Edward Lennon
  • Patent number: 8507601
    Abstract: A method of providing oil repellency, water repellency, and dynamic water repellency to a substrate comprising contacting the substrate with a polymer composition comprising A) a first polymer comprising (a) hydrophobized nanoparticle; (b) C1 to C18, straight, branched, or cyclic alkyl (meth)acrylate; (c) N-methylol (meth)acrylamide or a monomer of formula (I) R—(OCH2CH2)a—O—C(O)—C(R1)?CH2??(I) wherein R is hydrogen, C1-C4 alkyl, or —C(O)—C(R1)?CH2, and R1 is H or —CH3; said first polymer in contact with B) a second polymer comprising (d) a fluorinated monomer of formula (II) Rf1-L-X—C(O)—C(R)?CH2??(II) wherein Rf1 is a monovalent, partially or fully fluorinated, linear or branched, alkyl radical having 2 to about 100 carbon atoms; optionally interrupted by 1 to about 50 oxygen atoms; wherein the ratio of carbon atoms to oxygen atoms is at least 2:1 and no oxygen atoms are bonded to each other; L is a bond or a linear or branched divalent linking group having 1 to about 20 carbon atoms, said linkin
    Type: Grant
    Filed: November 9, 2009
    Date of Patent: August 13, 2013
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Gerald Oronde Brown, Victoria A. Helinski
  • Patent number: 8324314
    Abstract: A composition for imparting surface properties to substrates comprising a polymer of at least one polyurethane having at least one urea linkage prepared by: (i) reacting (a) at least one diisocyanate, polyisocyanate, or mixture thereof, having isocyanate groups, and (b) at least one fluorinated compound selected from the formula (I): Rf1-L-X??(I) wherein Rf1 is a monovalent, partially or fully fluorinated, linear or branched, alkyl radical having 2 to 100 carbon atoms; optionally interrupted by 1 to 50 oxygen atoms; wherein the ratio of carbon atoms to oxygen atoms is at least 2:1 and no oxygen atoms are bonded to each other; L is a bond or a linear or branched divalent linking group having 1 to about 20 carbon atoms, said linking group optionally interrupted by 1 to about 4 hetero-radicals selected from the group consisting of —O—, —NR1—, —S—, —SO—, —SO2—, and —N(R1)C(O)— wherein R1 is H or C1 to C6 alkyl, and said linking group optionally substituted with CH2Cl; X is an isocyanate-reactive group selec
    Type: Grant
    Filed: October 12, 2009
    Date of Patent: December 4, 2012
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Gerald Oronde Brown, Michael Henry Ober
  • Publication number: 20110263367
    Abstract: Described herein is a belt comprising a body made of elastomeric material, embedded in which is a plurality of longitudinal filiform resistant inserts, and a working surface covered with a covering fabric; advantageously the working surface is constituted by a toothing. The covering fabric is treated with a coating treatment. The coating treatment comprises a fluorinated elastomer. Advantageously, the coating treatment moreover comprises an antifriction agent and an elastomer formed by at least one copolymer obtained starting from a diene monomer and a monomer containing nitrile groups, more advantageously modified with a salt of an unsaturated carboxylic acid.
    Type: Application
    Filed: January 10, 2008
    Publication date: October 27, 2011
    Inventors: Carlo Baldovino, Marco Di Meco
  • Publication number: 20110111659
    Abstract: A method of providing oil repellency, water repellency, and dynamic water repellency to a substrate comprising contacting the substrate with a polymer composition comprising A) a first polymer comprising (a) hydrophobized nanoparticle; (b) C1 to C18, straight, branched, or cyclic alkyl (meth)acrylate; (c) N-methylol (meth)acrylamide or a monomer of formula (I) R—(OCH2CH2)a—O—C(O)—C(R1)?CH2??(I) wherein R is hydrogen, C1-C4 alkyl, or —C(O)—C(R1)?CH2, and R1 is H or —CH3; said first polymer in contact with B) a second polymer comprising (d) a fluorinated monomer of formula (II) Rf1-L-X—C(O)—C(R)?CH2??(II) wherein Rf1 is a monovalent, partially or fully fluorinated, linear or branched, alkyl radical having 2 to about 100 carbon atoms; optionally interrupted by 1 to about 50 oxygen atoms; wherein the ratio of carbon atoms to oxygen atoms is at least 2:1 and no oxygen atoms are bonded to each other; L is a bond or a linear or branched divalent linking group having 1 to about 20 carbon atoms,
    Type: Application
    Filed: November 9, 2009
    Publication date: May 12, 2011
    Applicant: E. I. DU PONT DE NEMOURS AND COMPANY
    Inventors: Gerald Oronde Brown, Victoria A. Helinski
  • Patent number: 7494709
    Abstract: The present invention teaches a filament yarn that has low wicking, i.e., less than or equal to about 6 mm; has a contact angle of greater than or equal to about 65° but less than about 90° according to the straw method; and a static voltage of +/?400 volts (between ?400 to +400 volts). Such yarns are traditionally employed in weaving signs, banners, awning, tents and other products where moisture resistant yarn is important. The yarns can be made into fabrics that possess the same features as the yarn, namely low wicking, and water and oil repellency.
    Type: Grant
    Filed: March 18, 2005
    Date of Patent: February 24, 2009
    Assignee: Performance Fibers Operations, Inc.
    Inventor: John Edward Davis
  • Patent number: 7232776
    Abstract: Disclosed is a surface material for an automobile internal trim panel consisting of a fiber sheet, wherein the fiber sheet contains an oil repellent and substantially consists of non-water absorbent fibers; an oil repellency of at least one surface of the surface material is grade 1 or more in an evaluation by an AATCC Test Method 118-1997; and a grade of the oil repellency of one surface of the surface material is different from that of the other surface thereof. Further, an automobile internal trim panel comprising the same is also disclosed.
    Type: Grant
    Filed: April 29, 2003
    Date of Patent: June 19, 2007
    Assignee: Japan Vilene Company, Ltd.
    Inventors: Masaaki Akuzawa, Masami Nakano, Akira Utsumi
  • Patent number: 7015278
    Abstract: Formulations formed by aqueous dispersions of cationic ionomer fluorinated polyurethanes based on (per)fluoropolyethers, having end groups constituted by —NCO groups reacted with hydrogenactive compounds to give covalent bonds stable to water but thermolabile, usable for the surface hydro- and oil-repellent treatment of textiles.
    Type: Grant
    Filed: December 30, 2002
    Date of Patent: March 21, 2006
    Assignee: Solvay Solexis, S.p.A.
    Inventors: Tania Trombetta, Stefano Turri
  • Publication number: 20040202818
    Abstract: Excellent water- and oil-repellency and soil releasability can be obtained by a method of preparing a treated textile, having steps of:
    Type: Application
    Filed: April 8, 2003
    Publication date: October 14, 2004
    Applicant: DAIKIN INDUSTRIES, LTD.
    Inventors: Ikuo Yamamoto, Kayo Kusumi, Mitsuhiro Usugaya, Ryosuke Hara, Takahito Kanbara
  • Patent number: 6780226
    Abstract: An electret filter media includes an additive or mixtures thereof that enhance the charge stability of the media. The filter media achieves acceptable alpha values for a range of filtration challenges without significant decay in alpha values over time. Preferred charge additives include fatty acid amides, oleophobic fluorochemical surfactants, and mixtures thereof.
    Type: Grant
    Filed: April 5, 1996
    Date of Patent: August 24, 2004
    Assignee: Hollingsowrth & Vose Company
    Inventors: Norman Lifshutz, Richard E. Gahan, Graham C. Stevens
  • Patent number: 6627563
    Abstract: A filter that includes a first electret filter layer through which an airstream first passes before encountering a second electret filter layer. The first filter layer exhibits nondecreasing removal efficiency and removes a majority of a challenge aerosol; whereas the second layer exhibits decreasing removal efficiency and has an initial quality factor greater than the first layer. Together, the first and second electret filter layers can provide a filter that exhibits a nondecreasing removal efficiency and a relatively low pressure-drop. The filter can provide nondecreasing removal efficiency and reduced pressure drop even though the second electret filter layer exhibits decreasing removal efficiency in contrast to the desired nondecreasing removal efficiency for the filter as a whole.
    Type: Grant
    Filed: August 19, 1999
    Date of Patent: September 30, 2003
    Assignee: 3M Innovative Properties Company
    Inventor: John S. Huberty
  • Patent number: 6562112
    Abstract: An electret is described that includes a surface modified polymeric article having surface fluorination produced by fluorinating the polymeric article.
    Type: Grant
    Filed: April 19, 2002
    Date of Patent: May 13, 2003
    Assignee: 3M Innovative Properties Company
    Inventors: Marvin E. Jones, Christopher S. Lyons, David B. Redmond, Jeffrey L. Solomon, Seyed Abolhassan Angadjivand
  • Patent number: 6551951
    Abstract: A burn through resistant nonwoven mat and cover film composite for use in a thermal and/or acoustical insulation blanket system, are, preferably, made up of non-respirable and/or biosoluble base fibers and capable of retaining their integrity and dimensional stability during 4 minutes of exposure to a fluctuating high pressure flame front at a temperature of 1100° C. examples of non-respirable base fibers which make up the nonwoven mat are quartz fibers; aluminosilicate, aluminoborosilicate or alumina ceramic oxide fibers; partially oxidized pitch based fibers; and partially oxidized polyacrylonitrile fibers having mean diameters greater than 6 microns. Examples of biosoluble fibers are biosoluble glass fibers. Preferably, the nonwoven mats also include a lubricant sizing with a water repellent additive.
    Type: Grant
    Filed: March 13, 2000
    Date of Patent: April 22, 2003
    Assignee: Johns Manville International, Inc.
    Inventors: Ralph Michael Fay, Rebecca S. Wulliman
  • Patent number: 6541402
    Abstract: An improved fabric for use in applications such as furniture upholstery is provided which possesses desirable flexibility, cleanability, and fluid resistant properties. The fabric includes a textile substrate treated with a fluorochemical stain resist agent. The treated textile substrate is covered substantially on the back with a layer of extrusion coated thermoplastic polymer which is pressed at least partially into the fabric substrate. A process for forming the fluid shield fabric according to the present invention is also provided. Preferably, the fabric is comprised of solution dyed nylon and the polymeric material is ethylene methyl acrylate polymer.
    Type: Grant
    Filed: July 25, 2000
    Date of Patent: April 1, 2003
    Assignee: Milliken & Company
    Inventors: William Carl Kimbrell, Jr., Thomas E. Godfrey
  • Patent number: 6432175
    Abstract: An electret is described that includes a surface modified polymeric article having surface fluorination produced by fluorinating the polymeric article.
    Type: Grant
    Filed: July 2, 1998
    Date of Patent: August 13, 2002
    Assignee: 3M Innovative Properties Company
    Inventors: Marvin E. Jones, Christopher S. Lyons, David B. Redmond, Jeffrey L. Solomon, Seyed Abolhassan Angadjivand
  • Patent number: 6419871
    Abstract: The present invention is drawn to an improved electrostatic filter medium comprising a web of electret fibers which have been treated with fluorine-containing plasmas at a deposition amount of about 0.03 g/m2 to about 1.5 g/m2; electrostatically charged; rinsed; and dried. The present invention is further drawn to a method of producing non-woven webs which have been treated with a fluorine-containing plasma at a deposition amount of about 0.03 g/m2 to about 1.5 g/m2; electrostatically charged; rinsed; and dried.
    Type: Grant
    Filed: May 25, 2000
    Date of Patent: July 16, 2002
    Assignee: Transweb, LLC.
    Inventor: Kumar Ogale
  • Patent number: 6383633
    Abstract: A fluorochemical composition is described comprising a polymer derived from a fluorochemical urethane (meth)acrylate monomer. The fluorochemical composition is useful for imparting stain release properties to a substrate.
    Type: Grant
    Filed: September 24, 1999
    Date of Patent: May 7, 2002
    Assignee: 3M Innovative Properties Company
    Inventors: Kathy E. M. L. A. Allewaert, Pierre J. Vander Elst
  • Publication number: 20020034902
    Abstract: There is provided a woven fabric for use in endovascular grafting, said fabric being biostable, composed of substantially non-elastomeric yarn, and expansible in at least one yarn direction, preferably the weft direction. Expansibility of the fabric is achieved by introducing non-linearity into a yarn (such as polyester or polytetrafluoroethylene) used in weaving the fabric. The non-linear yarn is maintained in that form by an agent which may itself be a yarn. Following fabric formation resilience is advantageously imparted to the non-linear yarn prior to release of the agent. In a preferred embodiment the yarn is polyester and is crimped or twisted around the agent which is a PVA yarn. After weaving, the fabric is washed in hot water to heat-set the water insoluble yarn in its non-linear form and to selectively dissolve the agent. An endovascular graft comprising the fabric of the invention is also described.
    Type: Application
    Filed: January 12, 1999
    Publication date: March 21, 2002
    Inventor: MICHAEL GERVASE LITTON
  • Patent number: 6306781
    Abstract: An expansion joint patch apparatus for repairing failed or torn expansion joint belting having a substantially flat, woven substrate material, and a cured solution of suspended elastomer, coating the substrate material. The substrate material is selected from the group consisting of aramid, fiberglass, corrosion resistant alloy wire, polyester, ceramic and kevlar fabrics. The elastomer material is selected from the group consisting of chloroprene, chlorosulfonated polyethylene, ethylene propylene, chloronated isobutylene isoprene, fluoroelastomers and silicone rubbers. The invention further includes a method for forming a fluoroelastomer patch for repairing fabric expansion joints.
    Type: Grant
    Filed: July 21, 1999
    Date of Patent: October 23, 2001
    Assignee: Senior Investments AG
    Inventor: David F. McGrath
  • Patent number: 6238466
    Abstract: Novel electret articles containing a polymer and a performance-enhancing additive can be identified by their thermally stimulated conductivity characteristics or their filtration properties. Electret articles such as nonwoven filter webs and respirators exhibit superior oily mist loading performance, low penetration and a small pressure drop.
    Type: Grant
    Filed: October 1, 1997
    Date of Patent: May 29, 2001
    Assignee: 3M Innovative Properties Company
    Inventors: Alan D. Rousseau, Marvin E. Jones, Betty Z. Mei
  • Patent number: 6214094
    Abstract: The thermally stimulated discharge current of an electret article can be used to identify electret articles that exhibit superior filtration properties. Electret filters that exhibit superior properties not achieved in similarly constructed filters contain fibers that are made from a blend of a polymer and a performance-enhancing additive. The electret filters exhibit an initial detectable DOP penetration of less than 5% and an average Min@Chl of greater than 200 mg DOP as measured by DOP Filter Web Loading Test Procedure 1. These new electrets are particularly useful in a respirator.
    Type: Grant
    Filed: January 18, 2000
    Date of Patent: April 10, 2001
    Assignee: 3M Innovative Properties Company
    Inventors: Alan D. Rousseau, Marvin E. Jones, Betty Z. Mei
  • Patent number: 6171983
    Abstract: This invention relates to fluorochemical compositions, their preparation and their use as water- and oil-repellents, and substrates treated therewith. The fluorochemical composition comprises a mixture of fluorochemical compounds and/or polymers, each component having at least two fluoroaliphatic groups and a large hydrocarbon moiety such as derived from dimer acids, and the polymer having at least one fluoroaliphatic group and a plurality of said hydrocarbon moiety.
    Type: Grant
    Filed: September 8, 1999
    Date of Patent: January 9, 2001
    Assignee: 3M Innovative Properties Company
    Inventors: Dirk M. Coppens, Richard J. Grant
  • Patent number: 6132838
    Abstract: A functional carpet suitable for use in an automotive vehicle. The functional carpet comprises a nonwoven fabric having piles formed throughout a whole surface of the nonwoven fabric. Each pile projects from the surface of the nonwoven fabric and is formed of at least a part of fibers constituting the nonwoven fabric. Each pile has a length ranging from 1 to 10 mm. The nonwoven fabric has a density ranging from 250 to 800 g/m.sup.2. Additionally, a fluoroplastics is adhered to a surface portion of the nonwoven fabric and extends substantially uniformly throughout the surface of the nonwoven fabric. The fluoroplastics includes linear tetrafluoroethylene telomer as a main body. The tetrafluoroethylene telomer has a number of carbon atoms ranging from 6 to 14. The amount of the fluoroplastics adhered to the surface portion of the nonwoven fabric ranges from 1.5 to 60 g/m.sup.2 in solid state.
    Type: Grant
    Filed: April 24, 1998
    Date of Patent: October 17, 2000
    Assignee: Nissan Motor Co., Ltd.
    Inventors: Hideo Hiratsuka, Kazufumi Shimizu, Hiroki Nagayama, Hiroaki Harata
  • Patent number: 6054399
    Abstract: A textile material whose fibers have been coated, at least in part, with fluorocarbon particles is usable in an electrophotographic printing machine to clean toner particles off a fuser roll, and to supply a toner release agent to the fuser roll. The textile material can include woven goods, as well as non-woven felts and the like. The resultant product has reduced friction and decreased fiber shedding.
    Type: Grant
    Filed: January 27, 1998
    Date of Patent: April 25, 2000
    Assignee: BMP America, Inc.
    Inventors: Alan R. Lebold, Alan Smithies, Edward D. Andrew
  • Patent number: 5899783
    Abstract: A fabric possessing both cleanability and fluid resistant properties is provided which can, if desired, be transfer printed. The fabric includes a textile substrate treated with a fluorochemical stain resist agent. The treated textile substrate is covered substantially on the back with a layer of extrusion coated thermoplastic polymer which is pressed at least partially into the fabric substrate. A process for forming the fluid shield fabric according to the present invention is also provided.
    Type: Grant
    Filed: February 12, 1997
    Date of Patent: May 4, 1999
    Assignee: Milliken & Company
    Inventors: William Carl Kimbrell, Jr., Christopher Todd Usher
  • Patent number: 5856246
    Abstract: The invention concerns a thin film of a permanent hydrophobic and optionally oleophobic finish for polymer surfaces. The film is formed from at least one layer of a water-soluble polycation and cationic synthetic resin. For further improvement of the oleophobic and permanent hydrophobic properties the film can additionally contain a long-chain surfactant or an alkyl-substituted polyanion.
    Type: Grant
    Filed: March 26, 1997
    Date of Patent: January 5, 1999
    Inventors: Richard Witzko, Wolfgang Burger, Gudrun Petzold, Klaus Lunkwitz, Heide-Marie Buchhammer
  • Patent number: 5756407
    Abstract: A treated fibrous polyamide substrate having durable resistance to staining by acid colorants comprising a fibrous polyamide substrate having applied thereto an aqueous solution of a sulfonated, phosphated resol resin; which aqueous solution may include a methacrylic polymer or copolymer and a fluorochemical; and the method of treating said substrate with the solution to render it durable to staining by acid colorants.
    Type: Grant
    Filed: October 9, 1996
    Date of Patent: May 26, 1998
    Assignee: Trichromatic Carpet Inc.
    Inventors: Yassin M. Elgarhy, Barry R. Knowlton
  • Patent number: 5756181
    Abstract: A method for imparting soil resistance to unscoured carpets, and a carpet treated in accordance with the method, are provided. In accordance with the method, a substrate comprising unscoured carpet fibers is treated with the ammonium salt of a polycarboxylic acid, such as an ammonium salt of a hydrolyzed styrene/maleic anhydride copolymer. The treated substrate is found to have enhanced water and oil repellency in both heat cured and room temperature drying conditions.
    Type: Grant
    Filed: July 23, 1996
    Date of Patent: May 26, 1998
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Shou-Lu G. Wang, Irvin F. Dunsmore, Robert F. Kamrath, John C. Chang
  • Patent number: 5753569
    Abstract: Substrates which have been provided with an oil-, water- and soil-repellant treatment from the group consisting of naturally occurring and synthetic textiles and their mixtures, leather, mineral substances, thermoplastic and thermosetting polymers and paper, comprise fluorine-containing compositions which comprise two components A and B.Component A is a fluorine-containing acrylic copolymer with the following comonomers:a) (meth)acrylates containing perfluoroalkyl groupsC.sub.n F.sub.2n+1 --X--O--CO--CR.sup.1 .dbd.CH.sub.2 (I),b) monomers from the group consisting of styrene, acrylonitrile, vinyl acetate, vinyl propionate and monomers,CH.sub.2 .dbd.CR.sup.4 --CO----OR.sup.5 (II),c) monomers ##STR1## and d) monomersCH.sub.2 .dbd.CR.sup.11 COO--CH.sub.2 CH.sub.2 N(R.sup.9, R.sup.10) (IVa)or in quaternized form?CH.sub.2 .dbd.CR.sup.11 --COO--CH.sub.2 CH.sub.2 N(R.sup.9 R.sup.10 R.sup.12)!.sup..sym. Y.sup..crclbar. (IVb)or in N-oxidized form ##STR2## or of the formulaCH.sub.2 .dbd.CR.sup.13 --COO.sup..sym. Z.sup.
    Type: Grant
    Filed: November 17, 1995
    Date of Patent: May 19, 1998
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gisbert Michels, Hans-Albert Ehlert, Uwe Zweering