Apparatus For Converting Or Treating Hydrocarbon Gas Patents (Class 48/127.9)
  • Patent number: 8252251
    Abstract: The present subject matter discloses a fluid cooled reformer for gas turbine systems and a method for cooling both a fuel reformer and a heated reformate stream produced by such fuel reformer. The fluid cooled reformer may include a pressure vessel and a reactor assembly disposed within the pressure vessel. The reactor assembly may include a reactor and may be configured to receive and reform an oxygen/fuel mixture to produce a heated reformate stream. Additionally, the fluid cooled reformer may include an inlet configured to direct a fluid stream into the pressure vessel. At least a portion of the fluid stream may be used to cool the reactor assembly. A reformate cooling section may be disposed downstream of the reactor of the reactor assembly and may be configured to cool the heated reformate stream.
    Type: Grant
    Filed: March 30, 2010
    Date of Patent: August 28, 2012
    Assignee: General Electric Company
    Inventors: Jonathan Dwight Berry, Hasan Karim, Abdul Rafey Khan
  • Patent number: 8236071
    Abstract: A quench ring for use with a gasifier system. The quench ring including an annular manifold having a radius, an annular channel coupled in flow communication with said manifold, and at least one inlet coupled in flow communication with said manifold, said at least one inlet having a center line aligned substantially tangentially to said annular manifold.
    Type: Grant
    Filed: August 15, 2007
    Date of Patent: August 7, 2012
    Assignee: General Electric Company
    Inventors: Judeth Helen Brannon Corry, Yulianto Salahuddin Mohsin
  • Patent number: 8236073
    Abstract: A hydrogen supply apparatus includes a hydrogen supply path by which hydrogen released from a hydrogen tank reaches a hydrogen supply target, a branching path from the hydrogen supply path, in which a part of hydrogen released from the hydrogen tank flows, addition means for adding an odorizing agent to the hydrogen flowing in the branching path, a buffer tank storing the hydrogen to which the odorizing agent is added by the addition means, and supplying means for supplying the odorizing agent treated hydrogen in the buffer tank to the hydrogen supply path.
    Type: Grant
    Filed: August 2, 2007
    Date of Patent: August 7, 2012
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventor: Shuji Hirakata
  • Patent number: 8236260
    Abstract: A fuel processor that extracts, from a fuel source, hydrogen gas used for an electricity generation reaction. The fuel processor includes a reformer that generates hydrogen gas by reacting a fuel source with water, a burner that heats the reformer to an appropriate temperature for a hydrogen generation reaction, a CO remover that removes CO generated during the hydrogen generation reaction in the reformer, and a heat exchanger for cooling the CO remover.
    Type: Grant
    Filed: April 24, 2008
    Date of Patent: August 7, 2012
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Kang-hee Lee, Doo-hwan Lee, Hyun-chul Lee
  • Patent number: 8221692
    Abstract: Embodiments are disclosed that relate to increasing radiative heat transfer in a steam reformer from an exterior shell which includes a diffusion burner to an interior reactor via angled fins coupled to the exterior shell. For example, one disclosed embodiment provides a steam reformer, comprising an exterior shell which includes a diffusion burner and angled fins, the angled fins extending away from an inner surface of the exterior shell and downward toward the diffusion burner. The steam reformer further comprises an interior reactor positioned at least partly within the exterior shell.
    Type: Grant
    Filed: December 5, 2011
    Date of Patent: July 17, 2012
    Assignee: ClearEdge Power, Inc.
    Inventors: Bob Sorensen, Craig E. Evans, Brian Sonnichsen
  • Patent number: 8221512
    Abstract: Provided is a hydrogen generator capable of suppressing degradation in capability of a hydrogen generator which is caused by crush of particulate reforming catalyst and of suppressing decrease in reforming efficiency due to decrease in heat transfer efficiency of a catalyzing portion which is caused by the crush of the particulate reforming catalyst. A hydrogen generator comprises a catalyzing portion 50 having particulate reforming catalyst P, and a combusting portion 5 for heating the catalyzing portion 50, the hydrogen generator being configured to generate a reformed gas containing hydrogen while flowing a material gas containing steam in a direction in which the catalyzing portion 50 extends. The catalyzing portion 50 includes a separating member 40. The separating member 40 is disposed on a separating cross-section which is a cross-section of the catalyzing portion 50 in a direction perpendicular to the direction in which the catalyzing portion 50 extends.
    Type: Grant
    Filed: September 28, 2006
    Date of Patent: July 17, 2012
    Assignee: Panasonic Corporation
    Inventors: Hiroki Fujioka, Akira Maenishi, Yoshio Tamura, Yuji Mukai, Kiyoshi Taguchi
  • Patent number: 8216345
    Abstract: A gasification system is disclosed having a combustion or reaction vessel, a scrubber housing, and a filter housing. A carbonaceous fuel is partially combusted in the reaction vessel to generate a combustible gas. An improved ash support and removal system reduces clogging and other problems in the reaction vessel. The combustible gas passes through the scrubber housing to remove matter such as tar and oil, and the scrubbed gas passes through a hybrid blower to the filter housing. Wood chips are used in the filter housing to provide a relatively clean, dry gas. Wastewater and other waste products from the scrubber housing and filter housing are captured and returned to the reaction vessel.
    Type: Grant
    Filed: April 10, 2008
    Date of Patent: July 10, 2012
    Assignee: Verde Reformation, Inc.
    Inventors: Jackie W. Rogers, Michael W. Rogers
  • Patent number: 8216323
    Abstract: A system comprises a mixed reforming zone configured to receive a first fuel steam mixture and an oxidant to produce a first reformate stream comprising hydrogen. The system further comprises at least one steam-reforming zone configured to receive the first reformate stream, a first portion of steam and a second fuel to produce a second reformate stream comprising hydrogen. The first reformate stream is mixed with the first portion of steam and second fuel before entering the steam reforming zone.
    Type: Grant
    Filed: June 30, 2005
    Date of Patent: July 10, 2012
    Inventors: Ke Liu, Parag Prakash Kulkarni, Gregg Anthony Deluga
  • Patent number: 8202331
    Abstract: When odorant injection systems are inactive, they may accumulate unwanted vapors in the pump mechanism and associated tubing. In order to restart the odorant injection system, it is best to purge the unwanted vapors from the odorant pumps. The present pump purge system facilitates purging of unwanted vapors from odorant injection systems in an environmentally friendly fashion. The pump purge system purifies these vapors before they are vented to atmosphere. In addition, the pump purge system accumulates liquid odorant which is a byproduct of the purging process and stores it in a tank to reduce the likelihood of improper disposal. As an option, the pump purge system may also include a liquid odorant recapture system. The liquid odorant recapture system uses high pressure gas to return accumulated liquid odorant to the odorant injection system to be reused. This liquid odorant recovery system ensures environmentally responsible behavior.
    Type: Grant
    Filed: October 6, 2008
    Date of Patent: June 19, 2012
    Assignee: Odoreyes Technologies, Inc.
    Inventors: Kyle Welker, Wade L. Williams
  • Patent number: 8202499
    Abstract: A small cylindrical reformer having at least a combustion reaction unit and a fuel-converting catalytic reaction unit wherein the combustion reaction unit and the fuel-converting catalytic reaction unit are structured as six cylindrical pipes to realize optimal heat exchange efficiently, a route supplying a water gas shift reformate to a preferential oxidation reactor and a route supplying feed and water into reforming reaction parts from the feed/water inlet overlap each other at a lower portion of the reformer so as to increase heat transfer efficiency, and a preferential oxidation reactor provided outside the fuel-converting catalytic reaction unit to decrease the concentration of carbon monoxide in the water gas shift reformate to a predetermined level or lower and increase heat transfer efficiency with an air/fuel preheating passage communicating with the air/fuel inlet.
    Type: Grant
    Filed: December 28, 2010
    Date of Patent: June 19, 2012
    Assignee: SK Energy Co., Ltd.
    Inventors: Tae Woo Woo, Young Seek Yoon, Seong Ho Lee, Il Su Kim, Keun Seob Choi
  • Patent number: 8192514
    Abstract: A fixed bed coal gasifier (300) includes a coal gasification chamber with a coal lock above the chamber. A static coal distribution device inside the gasification chamber includes a hollow coal distributor which flares downwardly outwardly with a skirt depending downwardly from an inside of the coal distributor so that a gas collection zone is defined between the skirt and the coal distributor. The gasifier (300) has an ash discharge outlet (606) and a rotatable grate (600) above the outlet (606). The rotatable grate (600) includes at least one upwardly projecting finger or disturbing formation (500) to disturb the ash bed formed in use above and around the grate (600).
    Type: Grant
    Filed: November 30, 2005
    Date of Patent: June 5, 2012
    Assignee: Sasol Technology (Proprietary) Limited
    Inventors: Jacobus Andreas Stadler, Eric Graham Van De Venter, Paul Smit Baumann
  • Patent number: 8187869
    Abstract: A biogas installation for production of biogas from biomass and methods for starting and shutting down a fermenter are disclosed. When biomass in a fermenter is used up, biogas production must stop, the fermented biomass removed, and the fermenter filled with fresh biomass. Biogas production and utilisation is maintained for as long as possible. When the methane concentration in the biogas outlet falls below an upper limit, the biogas line is disconnected. The biogas/off-gas mixture is fed out via an exhaust chimney until the methane concentration has fallen to a lower limit. The fermenter to be shut down is purged with fresh air, and the off-gas/biogas/fresh air mixture is fed out via the exhaust chimney until the carbon-dioxide concentration in the off-gas/biogas/fresh air mixture has fallen to a first limit. The fermenter is then opened to unload the consumed biomass and load fresh biomass.
    Type: Grant
    Filed: May 23, 2008
    Date of Patent: May 29, 2012
    Assignee: Bekon Energy Technologies GmbH & Co., KG
    Inventor: Peter Lutz
  • Patent number: 8187349
    Abstract: A gasification reactor vessel comprising a combustion chamber in the upper half of the vessel, provided with a product gas outlet at the bottom end of the combustion chamber, at least two burner openings are present in the wall of the combustion chamber, which burner openings are located at the same horizontal level and are positioned diametrical relative to each other and wherein in each burner opening a burner is present, wherein between the wall of the combustion chamber and the wall of vessel an annular space is provided, wherein the wall of the combustion chamber comprises an arrangement of interconnected tubes (vertical arranged or helical coiled), wherein the product gas outlet at the bottom end of the combustion chamber is fluidly connected to a dip-tube, which partly is submerged in a water bath located at the lower end of the reactor vessel, and wherein at the upper end of the dip-tube means are present to add a quenching medium to the, in use, downwardly flowing mixture of hydrogen and carbon monox
    Type: Grant
    Filed: March 14, 2008
    Date of Patent: May 29, 2012
    Assignee: Shell Oil Company
    Inventors: Steffen Jancker, Thomas Paul Von Kossak-Glowczewski, Joachim Wolff
  • Patent number: 8182559
    Abstract: There are provided a fuel reformer housing container and a fuel reforming apparatus, which are capable of maintaining a level of vacuum inside the fuel reformer housing container favorably and which have less power generation loss. A fuel reformer housing container includes a base having a concave portion for housing a fuel reformer in which reformed gas containing hydrogen gas is generated from fuel, a discharge pipe for communicating inside of the concave portion with outside thereof to discharge the reformed gas from the fuel reformer, a supply pipe for communicating inside of the concave portion with outside thereof to supply the fuel to the fuel reformer, and a gas adsorbent housed in the concave portion, for adsorbing gas in the concave portion.
    Type: Grant
    Filed: October 27, 2005
    Date of Patent: May 22, 2012
    Assignee: Kyocera Corporation
    Inventors: Yoshihiro Basho, Toshihiro Hashimoto, Masaaki Miyahara, Ryuji Mori
  • Patent number: 8182771
    Abstract: A system comprising a multi-stage reactor. The multi-stage reactor may include a water gas shift (WGS) reactor and a sour methanation reactor configured to generate methane without prior removal of acid gas. Furthermore, the multistage reactor may be a single unit having both the WGS reactor and the methanation reactor.
    Type: Grant
    Filed: April 22, 2009
    Date of Patent: May 22, 2012
    Assignee: General Electric Company
    Inventors: Arnaldo Frydman, Ke Liu
  • Patent number: 8178062
    Abstract: In a reforming apparatus, for use in a fuel cell, for reforming a raw fuel into a hydrogen-rich reformed gas, a reformer generates the reformed gas from the raw fuel. A shift reactor reduces carbon monoxide contained in the reformed gas through a shift reaction. A selective oxidation unit reduces the carbon monoxide contained in the reformed gas that has passed through the shift reactor by performing selective oxidation on the carbon monoxide. A reforming reaction tube houses linearly the reformer, the shift reactor and the selective oxidation unit in this order. A combustion means produces combustion exhaust gas by combusting the raw fuel. An outer casing is placed around the reforming reaction tube, and the outer casing has a larger diameter than that of the reforming reaction tube. A heated flow passage through which the combustion exhaust gas passes to heat the reforming reaction tube is formed between the reforming reaction tube and the outer casing.
    Type: Grant
    Filed: September 26, 2008
    Date of Patent: May 15, 2012
    Assignees: Sanyo Electric Co., Ltd., Nippon Oil Corporation
    Inventors: Akira Fuju, Masataka Kadowaki, Kazumi Kobayashi, Kazuaki Nakajima, Yasushi Sato, Ken Samura
  • Patent number: 8173083
    Abstract: A compact catalytic reactor defines a multiplicity of first and second flow channels arranged alternately in the reactor, for carrying first and second fluids, respectively, wherein at least the first fluids undergo a chemical reaction. Each first flow channel containing a removable gas-permeable catalyst structure (20) incorporating a metal substrate, the catalyst structure defining flow paths therethrough, with catalytic material on at least some surfaces of each such path. The catalyst structure also incorporates a multiplicity of projecting resilient lugs (22) which support the catalyst structure (20) spaced away from at least one adjacent wall of the channel (17).
    Type: Grant
    Filed: February 15, 2006
    Date of Patent: May 8, 2012
    Assignee: CompactGTL plc
    Inventor: Michael Joseph Bowe
  • Patent number: 8168131
    Abstract: A syngas reforming reactor has a shell-and-tube configuration wherein the shell-side fluid flow path through the tube bundle has a longitudinal configuration. The reactor can include a shell-side inlet fluid distributor plate below the lower end of the tube bundle.
    Type: Grant
    Filed: November 9, 2009
    Date of Patent: May 1, 2012
    Assignee: Kellog Brown & Root LLC
    Inventors: Robert Stevens Burlingame, Lloyd Edward Cizmar, Larry Gene Hackemesser, Laura Beth Aguilar
  • Patent number: 8163047
    Abstract: A method of cooling hot fluid flowing through a chamber is provided. The method includes channeling cooling fluid through at least one cooling tube that extends through a passage of the chamber, and circulating the hot fluid flowing within the passage around the at least one cooling tube using at least one fluid diverter.
    Type: Grant
    Filed: January 10, 2007
    Date of Patent: April 24, 2012
    Assignee: General Electric Company
    Inventors: George Albert Goller, Daniel Anthony Nowak
  • Patent number: 8152872
    Abstract: The thermal reformer system (1) is provided that compromises a planar assembly including a reformer zone (5), a combustion zone (6), and various inlet and outlet manifolds with associated fluid flow passages (11, 20). The reformer system further compromises an inlet combustion fluid flow passage (31) connecting an inlet combustion fluid manifold (30) and the combustion zone (6), and an outlet combustion fluid flow passage (41) connecting the combustion zone (6) and the outlet combustion fluid manifold (40). In the thermal reformer system the heat transfer and recuperation from outlet fluid flows is efficiently transferred to inlet fluid flows, in order to minimize heat loss and insulation requirements.
    Type: Grant
    Filed: March 9, 2005
    Date of Patent: April 10, 2012
    Assignee: Intelligent Energy, Inc.
    Inventors: Richard Root Woods, Brook F. Porter, Rahul Iyer, Leonard M. Weschta
  • Patent number: 8118895
    Abstract: A process of generating power utilizing a low level heat from a raw syngas produced in a quench gasifier is disclosed. The process includes a first stage that includes: producing raw syngas at the quench gasifier, making 150 psi saturated steam from the produced raw syngas, superheating the saturated steam, and using the superheated saturated steam in a low pressure steam turbine to generate power. The process includes a second stage that includes: providing the raw syngas and a process condensate stream to a thermal fluid vaporizer to vaporize an organic thermal fluid, and using the vaporized organic thermal fluid in an expander turbine to generate power via an organic Rankine cycle.
    Type: Grant
    Filed: March 29, 2008
    Date of Patent: February 21, 2012
    Assignee: Bechtel Power Corporation
    Inventors: Harvey Wen, Rattan K. Tawney
  • Patent number: 8118893
    Abstract: A gas-generating apparatus includes a reaction chamber having a first reactant, a reservoir having an optional second reactant, and a self-regulated flow control device. The self-regulated flow control device stops the flow of reactant from the reservoir to the reaction chamber when the pressure of the reaction chamber reaches a predetermined level. Methods of operating the gas-generated apparatus and the self-regulated flow control device, including the cycling of a shut-off valve of the gas-generated apparatus and the cycling of the self-regulated flow control device are also described.
    Type: Grant
    Filed: January 26, 2009
    Date of Patent: February 21, 2012
    Assignee: Societe Bic
    Inventors: Alain Rosenzweig, Paul Adams, Andrew J. Curello, Floyd Fairbanks, Anthony Sgroi, Jr., Constance R. Stepan
  • Patent number: 8114174
    Abstract: A reaction device 10 is used for producing water gas from polyhydric alcohol and water. The reaction device 10 includes a reactor 13 which has a reaction field 14 where a catalyst is provided inside and a reaction fluid flows. The catalyst 17 has a surface extending in a direction of flow of the reaction fluid.
    Type: Grant
    Filed: April 3, 2007
    Date of Patent: February 14, 2012
    Assignee: Kao Corporation
    Inventors: Takeshi Shirasawa, Yasukazu Kumita
  • Patent number: 8110012
    Abstract: In a retrofit system for hot solids combustion and gasification, a chemical looping system includes an endothermic reducer reactor 12 having at least one materials inlet 22 for introducing carbonaceous fuel and CaCO3 therein and a CaS/gas outlet 26. A first CaS inlet 40 and a first CaSO4 inlet 64 are also defined by the reducer reactor 12. An oxidizer reactor 14 is provided and includes an air inlet 68, a CaSO4/gas outlet 46, a second CaS inlet 44, and a second CaSO4 inlet 66. A first separator 30 is in fluid communication with the CaS/gas outlet 26 and includes a product gas and a CaS/gas outlet 32 and 34 from which CaS is introduced into said first and second CaS inlets. A second separator 50 is in fluid communication with the CaSO4/gas outlet 46 and has an outlet 52 for discharging gas therefrom, and a CaSO4 outlet from which CaSO4 is introduced into the first and second CaSO4 inlets 62, 66.
    Type: Grant
    Filed: July 31, 2009
    Date of Patent: February 7, 2012
    Assignee: ALSTOM Technology Ltd
    Inventors: John H. Chiu, Herbert E. Andrus, Gregory N. Liljedahl, Paul R. Thibeault
  • Patent number: 8105401
    Abstract: A method for using a downdraft gasifier comprising a housing and a refractory stack contained within the housing. The refractory stack may comprise various sections. Apertures in the sections may be aligned to form multiple columnar cavities. Each columnar cavity may comprise an individual oxidation zone. The method of use may include the steps of placing a feedstock into an upper portion of the refractory stack, measuring the temperature of each columnar cavity, and adjusting the flow of oxygen to a particular columnar cavity to maintain the temperature of the particular columnar cavity within a particular range.
    Type: Grant
    Filed: July 9, 2008
    Date of Patent: January 31, 2012
    Assignee: Refill Energy, Inc.
    Inventors: Alan M. Neves, Grover R. Brockbank, Morris K. Ebeling, Jr.
  • Patent number: 8101141
    Abstract: A unified fuel processing reactor for a solid oxide fuel cell can reform hydrocarbon-based fuel into hydrogen-rich gas, remove a sulfur component, and convert non-converted fuel and a low carbon (C2˜C5) hydrocarbon compound into hydrogen and methane in a single reactor. The reactor comprises a primary-reformer which reforms a hydrocarbon-base fuel and generates hydrogen-rich reformed gas, a desulfurizer which removes a sulfur component from the reformed gas, and a post-reformer which selectively decomposes a low carbon (C2˜C5) hydrocarbon in the desulfurized reformed gas into hydrogen and methane. The primary-reformer, desulfurizer and post-reformer are in the unified reactor and isolated, except for a fluid passage, from each other by internal partition walls. The primary-reformer is disposed at a center portion of the reactor. The post-reformer and the desulfurizer are concentrically disposed outside of the primary-reformer.
    Type: Grant
    Filed: April 24, 2009
    Date of Patent: January 24, 2012
    Assignee: Korea Advanced Institute of Science and Technology
    Inventors: Joongmyeon Bae, Sangho Yoon, Sunyoung Kim
  • Patent number: 8092558
    Abstract: There is disclosed a microchannel reactor module for the immediate catalytic release of hydrogen from hydrogenated organic molecules along with the recovery of hydrogen gas and the recovery of dehydrogenated organic molecules as a liquid. More specifically, the disclosure provides a polyimide-based microchannel plate that is particularly useful for a process of immediate catalytic release of hydrogen from a hydrogenated organic molecule or formulation of molecules.
    Type: Grant
    Filed: January 20, 2009
    Date of Patent: January 10, 2012
    Assignee: Asemblon, Inc.
    Inventors: David G. O'Connor, Robert B. Nelson
  • Patent number: 8088188
    Abstract: A system and process for gasifying carbonaceous feedstock with staged slurry addition in order to prevent the formation of tar that causes deposition problems. Dry solid carbonaceous material is partially combusted, then pyrolyzed along with a first slurry stream comprising carbonaceous material in two separate reactor sections, thereby producing mixture products comprising synthesis gas. The second slurry stream comprising particulate carbonaceous material is fed to a drying unit downstream of a heat recovery zone along with the mixture product exiting the heat recovery zone The resulting final temperature of the second stage mixture products and dried particulate carbonaceous material is between 450° F. and 550° F., a temperature range that is typically not conducive to the emission of heavy molecular-weight tar species.
    Type: Grant
    Filed: April 1, 2011
    Date of Patent: January 3, 2012
    Assignee: ConocoPhillips Company
    Inventors: David L. Breton, Albert C. Tsang, Max W. Thompson
  • Patent number: 8088185
    Abstract: A system is provided for producing and separating hydrogen and carbon dioxide from a hydrocarbon and steam. A hydrocarbon and steam are steam reformed and the reformed gas is shift reacted to produce a shift gas in the system. Hydrogen is removed from the shift gas, and the hydrogen-depleted gas is reformed and shift reacted again to produce more hydrogen and carbon dioxide in the system. The hydrogen and carbon dioxide are then separated.
    Type: Grant
    Filed: November 3, 2010
    Date of Patent: January 3, 2012
    Assignee: Shell Oil Company
    Inventors: Lloyd Anthony Clomburg, Jr., Andreas Nicholas Matzakos, Peter Veenstra, Scott Lee Wellington
  • Patent number: 8083819
    Abstract: Hydrogen-producing fuel processing assemblies and fuel cell systems with at least one temperature-responsive valve assembly, and methods for feedback regulation of the hydrogen-producing region. The temperature-responsive valve assembly responds automatically to the temperature of a gas stream of interest to regulate the flow of a subject gas stream therethrough. In some embodiments, these streams are the same streams, while in others, they are different streams. The streams may include at least the reformate stream from a hydrogen-producing region of the fuel processing assembly, the byproduct stream from a purification region, and the product gas stream from the purification region. In some embodiments, the subject gas stream may be the byproduct stream, which is in fluid communication for delivery as a combustible fuel stream for a burner or other heating assembly that produces an exhaust stream to heat the hydrogen-producing region of the fuel processing assembly.
    Type: Grant
    Filed: August 27, 2008
    Date of Patent: December 27, 2011
    Assignee: Idatech, LLC
    Inventors: John R. Arnold, James A. Givens, Arne LaVen
  • Patent number: 8083996
    Abstract: Provided are a thermal siphon reactor and a hydrogen generator including the same. The hydrogen generator including the thermal siphon reactor includes: a housing; a reaction source container disposed in the housing; a reactor tube connected to the reaction source container in which a catalytic reaction of a reaction source provided from the reaction source container occurs; a catalyst layer which is porous, facilitates gas generation by being contacted with the reaction source, and is disposed in the reactor tube; and a product container which is connected to the reactor tube and collects a reaction product generated in the reactor tube, wherein in the reactor tube, a convection channel through which the reaction product is discharged passes through the reactor tube in the lengthwise direction of the reactor tube. The thermal siphon reactor and the hydrogen generator including the same have a self-operating ability, operate at low costs, and have small installment volume.
    Type: Grant
    Filed: January 23, 2007
    Date of Patent: December 27, 2011
    Assignee: Samsung Engineering Co., Ltd.
    Inventors: Myong Hoon Lim, Tae Hee Park, Jae Hoi Gu, Yongho Yu
  • Patent number: 8057560
    Abstract: A fuel processor having a movable burner, a method of operating the fuel processor, and a fuel cell system having the fuel processor. The fuel processor includes a combustion chamber, a reformer burner, a portion of which is partially disposed inside the combustion chamber, a reformer which is heated by heat transfer from the combustion chamber, and a burner-moving apparatus that moves the reformer burner with respect to the combustion chamber. The method of operating the fuel processor includes determining the load on and a plurality of temperatures within the fuel processor and moving the reformer burner depending upon such information.
    Type: Grant
    Filed: January 24, 2007
    Date of Patent: November 15, 2011
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Hyun-chul Lee, Soon-ho Kim, Doo-hwan Lee, Kang-hee Lee
  • Patent number: 8057575
    Abstract: Hydrogen-producing fuel processing systems, hydrogen purification membranes, hydrogen purification devices, fuel processing and fuel cell systems that include hydrogen purification devices, and methods for operating the same. In some embodiments, operation of the fuel processing system is initiated by heating at least the reforming region of the fuel processing system to at least a selected hydrogen-producing operating temperature. In some embodiments, an electric heater is utilized to perform this initial heating. In some embodiments, use of the electric heater is discontinued after startup, and a burner or other combustion-based heating assembly combusts a fuel to heat at least the hydrogen producing region, such as due to the reforming region utilizing an endothermic catalytic reaction to produce hydrogen gas.
    Type: Grant
    Filed: October 21, 2010
    Date of Patent: November 15, 2011
    Assignee: Idatech, LLC
    Inventors: David J. Edlund, William A. Pledger, R. Todd Studebaker
  • Patent number: 8057559
    Abstract: The efficiency of dehydrogenation and that of hydrogenation are improved. A hydrogen generator for generating hydrogen by dehydrogenation of organic hydrides in the presence of a catalyst is characterized by comprising a reactor vessel (10) of a multi-tubular structure having a region (12) for supplying fuel to generate heat necessary for dehydrogenation, the region containing a combustion catalyst for combusting fuel, and a region (11) containing a dehydrogenation catalyst necessary for dehydrogenation, the regions being arranged radially side by side with a wall separating them.
    Type: Grant
    Filed: January 9, 2007
    Date of Patent: November 15, 2011
    Assignees: Hrein Energy, Inc.
    Inventors: Masaru Ichikawa, Katsumori Tanabe, Masashi Sakuramoto, Satoru Kikuchi, Yukimitsu Mita
  • Patent number: 8038959
    Abstract: A reacting device includes a base plate, a first reaction unit provided on the base plate, a reaction material being supplied thereto, the first reaction unit being set at a first temperature, a reaction flow channel being formed such that the reaction material flows therein, the first reaction unit causing a reaction of the reaction material and at least one heating unit which sets the first reaction unit at the first temperature. The first reaction unit has a plurality of reactors that communicate with each other, and the heating unit is provided between the adjacent reactors.
    Type: Grant
    Filed: September 6, 2006
    Date of Patent: October 18, 2011
    Assignee: Casio Computer Co., Ltd.
    Inventors: Naotomo Miyamoto, Tadao Yamamoto, Masaharu Shioya
  • Patent number: 8038744
    Abstract: A system and process for maximizing the generation of marketable products from a variety of hydrocarbon feedstocks. The hydrocarbon feedstocks are first gasified and then oxidized in a two-chamber system and process using oxygen gas rather than ambient air. Intermediate gases generated in the system and process are recirculated and recycled to the gasification and oxidation chambers in order to maximize both energy generation and the resulting stoichiometric reaction products. The energy produced through the system and process is used to generate steam and produce power through conventional steam turbine technology. In addition to the release of heat energy, the hydrocarbon feedstocks are oxidized to the pure product compounds of water and carbon dioxide. The carbon dioxide is subsequently purified and marketed. The water recovered from the system and process is collected and electrolyzed to generate oxygen and hydrogen gases.
    Type: Grant
    Filed: October 1, 2007
    Date of Patent: October 18, 2011
    Inventor: Steve L. Clark
  • Patent number: 8038743
    Abstract: A supercritical water reformer (SCWR) and methods for using supercritical water to convert hydrocarbons, particularly hydrocarbon fuels such as diesel fuel or gasoline, into carbonaceous gases and hydrogen. The synthesis gas stream generated by the fuel reforming reaction can then be further refined to increase hydrogen content, and the resultant hydrogen can be utilized to power fuel cells.
    Type: Grant
    Filed: November 26, 2003
    Date of Patent: October 18, 2011
    Assignee: DRS Sustainment Systems, Inc.
    Inventors: John R. Wootton, Sunggyu Lee, Asdrubal Garcia-Ortiz
  • Patent number: 8038746
    Abstract: A system and process are disclosed for the controlled combustion of a wide variety of hydrocarbon feedstocks to produce thermal energy, liquid fuels, and other valuable products with little or no emissions. The hydrocarbon feeds, such as coal and biomass, are first gasified and then oxidized in a two-chamber system/process using pure oxygen rather than ambient air. A portion of the intermediate gases generated in the system/process are sent to a Fischer-Tropsch synthesis process for conversion into diesel fuel and other desired liquid hydrocarbons. The remaining intermediate gases are circulated and recycled through each of the gasification/oxidation chambers in order to maximize energy production. The energy produced through the system/process is used to generate steam and produce power through conventional steam turbine technology.
    Type: Grant
    Filed: May 5, 2008
    Date of Patent: October 18, 2011
    Inventor: Steve L. Clark
  • Patent number: 8038745
    Abstract: A carbonaceous feedstock to alcohol conversion process in which carbon dioxide and a portion of the hydrogen produced are removed from the syngas stream issuing from a feedstock reformer, to yield a reduced hydrogen, carbon monoxide and methane syngas stream. The hydrogen and the carbon dioxide are passed through a Fischer Tropsch reactor which is catalyzed to favor the production of methanol. The methanol produced in the Fischer-Tropsch reactor is passed with the reduced hydrogen syngas through a second Fischer-Tropsch reactor which is catalyzed to favor the production of ethanol. Also disclosed, without limitation, are a unique catalyst, a method for controlling the content of the syngas formed in the feedstock reformer, and a feedstock handling system.
    Type: Grant
    Filed: April 14, 2008
    Date of Patent: October 18, 2011
    Assignee: Pearson Technologies, Inc.
    Inventor: Stanley R. Pearson
  • Patent number: 8038960
    Abstract: A reformer that produces reformed gas from a hydrocarbon material includes a reforming chamber having an inner cylinder and an outer cylinder; a reforming catalyst filled in the reforming chamber; a burner that heats the reforming catalyst and fuel of reformed gas; a combustion gas outer flow channel through which combustion gas of the burner flows along an outer side surface of the reforming chamber; a combustion gas inner flow channel through which the combustion gas of the burner flows along an inner side surface of the reforming chamber; and a plurality of return pipes as a reformed gas flow channel.
    Type: Grant
    Filed: January 24, 2005
    Date of Patent: October 18, 2011
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventor: Kazuyuki Higashino
  • Patent number: 8034135
    Abstract: A fuel modification apparatus is equipped with evaporators for evaporating a raw fuel as a fuel to be modified, a super heater for elevating the temperature of the above evaporated raw fuel to a temperature required for the modification, a modification vessel for modifying the above raw fuel having an elevated temperature to form a modified gas, and a preheater for preheating a heating fluid for evaporating the above raw fuel in the evaporator. The evaporators are arranged on a concentric circle, surrounding the superheater.
    Type: Grant
    Filed: March 7, 2006
    Date of Patent: October 11, 2011
    Assignee: Honda Motor Co., Ltd.
    Inventors: Takashi Arai, Hikaru Okada, Mitsuru Ikeo, Takeshi Yamagami, Nobuyoshi Yoshida, Noriyuki Mizojiri, Satoshi Hanai
  • Patent number: 8021447
    Abstract: Hydrogen-producing fuel processing assemblies for producing hydrogen gas. The assemblies include a catalyst chamber, a heat source adapted to heat the catalyst chamber, a hydrogen-producing region within the catalyst chamber adapted to produce hydrogen gas from a feed stream, and a conductive guide structure within the catalyst chamber adapted to conduct and distribute heat from the heat source within the hydrogen-producing region and to direct fluid through the hydrogen-producing region. In some embodiments, the conductive guide structure includes a helical member. In some embodiments, the assembly further includes a vaporization region within the catalyst chamber. In some embodiments, the fuel processing assembly is adapted to produce hydrogen gas via a steam reforming or other endothermic reaction.
    Type: Grant
    Filed: July 30, 2008
    Date of Patent: September 20, 2011
    Assignee: Idatech, LLC
    Inventors: Vernon Wade Popham, Robert A. Sorensen, Kyle Taylor
  • Patent number: 8021446
    Abstract: Feedstock delivery systems and hydrogen-producing fuel processing assemblies and fuel cell systems containing the same. The feedstock delivery systems include a liquid pump that draws at least one liquid feedstock from a supply and delivers at least one feed stream containing the feedstock(s) to a fuel processor, such as to the hydrogen-producing region thereof. The feedstock delivery system further includes a recycle conduit that establishes a fluid flow path for the liquid feedstock(s) from a location downstream of the pump back to a location upstream of the pump. In some embodiments, the feedstock delivery system further includes a flow restrictor associated with the recycle conduit and a pressure-actuated valve that selectively permits the recycled feedstock to bypass the flow restrictor. In some embodiments, the pump is configured to draw a greater flow rate of the feed stream from the supply than is delivered to the fuel processor.
    Type: Grant
    Filed: September 13, 2006
    Date of Patent: September 20, 2011
    Assignee: Idatech, LLC
    Inventors: Patton M. Adams, David J. Edlund, Vernon Wade Popham, Mesa Scharf, R. Todd Studebaker
  • Patent number: 8016900
    Abstract: Disclosed are a carbon monoxide remover and a fuel cell reformer including the same. In the reformer, a reformed gas produced from a reforming reaction unit when the reformer is initially driven is used as a fuel for a heat source unit supplying heat to a water gas shift reaction unit. The carbon monoxide remover is connected to the reforming reaction unit that changes fuel into reformed gas with hydrogen. The carbon monoxide remover lowers carbon monoxide contained in the reformed gas. The carbon monoxide remover includes a heat source unit employing the reformed gas as a fuel; and a water gas shift reaction unit provided with a shift catalyst using heat from the heat source unit. The shift catalyst lowers the concentration of carbon monoxide in the reformed gas through reaction between water and carbon monoxide.
    Type: Grant
    Filed: July 12, 2007
    Date of Patent: September 13, 2011
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Sung Chul Lee, Ju Yong Kim, Yong Kul Lee, Man Seok Han, Chan Ho Lee, Jin Kwang Kim, Jin Goo Ahn, Dong Uk Lee, Leonid Gorobinskiy
  • Patent number: 8002855
    Abstract: A reactor is proposed for entrained flow gasification for operation with pulverized or liquid fuels, with an externally cooled draft tube protecting the slag discharge outlet. An outlet of the draft tube remains above a water line of a sump of the reactor and is formed from Molybdenum, an alloy featuring molybdenum, Tantalum or an alloy featuring Tantalum.
    Type: Grant
    Filed: July 1, 2008
    Date of Patent: August 23, 2011
    Assignee: Siemens Aktiengesellschaft
    Inventors: Matthias Köhler, Joachim Lamp
  • Patent number: 7998226
    Abstract: An appliance is provided having a waste receptor module and an energy generation module for converting household waste into energy. The receptor module has a rotary drum with an opening for receiving the household waste and a steam reforming means for converting the waste into synthesis gas. A swing arm is attached adjacent to the opening in the rotary drum and a sealing door is mounted on the swing arm for sealing the opening when the waste receptor module is in operation. An outer door is used to cover the sealing door. The steam reforming means includes a tube mounted within the rotary drum for receiving the volatilized organic waste and an internal heater for heating the organic waste to temperatures to convert the waste into the synthesis gas. The energy generation module has an inlet in fluid communication with the waste receptor module for receiving the synthesis gas and a fuel cell for converting the synthesis gas into electrical energy.
    Type: Grant
    Filed: November 2, 2006
    Date of Patent: August 16, 2011
    Inventor: Terry R. Galloway
  • Patent number: 7981373
    Abstract: A reaction device can raise heat use efficiency. The reaction device includes a carbon monoxide remover removing carbon monoxide, and a vaporizer provided inside the carbon monoxide remover to vaporize fuel.
    Type: Grant
    Filed: September 26, 2007
    Date of Patent: July 19, 2011
    Assignee: Casio Computer Co., Ltd.
    Inventors: Kaoru Saito, Naotomo Miyamoto
  • Patent number: 7981372
    Abstract: An oxidative autothermal reformer including a reforming layer at least partially filled with a reforming catalyst for producing a reformed gas composed mainly of hydrogen through a reforming reaction by contacting a mixture of a hydrocarbon or an aliphatic alcohol and steam with the reforming catalyst; and an oxidative exothermic layer at least partially filled with an oxidation catalyst for generating heat by oxidizing a part of the reformed gas, in which the reforming layer is disposed at an upstream side of the oxidative exothermic layer; the reforming layer and the oxidative exothermic layer are in the form of a cylinder and have a triple circular tube structure formed by disposing an inner reforming layer, an oxidative exothermic layer and an outer reforming layer from the inside in a radial direction in this order; and at least a part of the reforming catalyst filled in the inner reforming layer and the outer reforming layer contains Ru metal.
    Type: Grant
    Filed: November 24, 2006
    Date of Patent: July 19, 2011
    Assignees: Japan Energy Corporation, Nippon Chemical Plant Consultant Co., Ltd.
    Inventors: Yoshinori Yamazaki, Saburo Maruko, Shingo Komori
  • Patent number: 7981274
    Abstract: A catalytic element useful for promoting catalytic gas phase reactions is provided, comprising a porous ceramic body comprising a multiplicity of open pores having a coating comprising a basic oxide material and a catalyst material selected from transition metal and noble metal compounds.
    Type: Grant
    Filed: July 21, 2008
    Date of Patent: July 19, 2011
    Assignee: Pall Corporation
    Inventors: Manfred Nacken, Steffen Heidenreich
  • Patent number: 7976787
    Abstract: An improved multiple-tube catalytic reformer comprising a tubular body containing a radiator core having a plurality of longitudinal cells for low-pressure flow-through of combustion gases, the core being formed preferably either by winding of corrugated metal or as an extruded metal monolith. A plurality of reformer tubes, preferably non-cylindrical, containing hydrocarbon catalyst are arrayed in longitudinal openings within the radiator core and preferably are brazed thereto to maximize heat transfer from the radiator core to the reformer tubes. During manufacture, the metal radiator core is economically bored by laser cutting to form the openings to admit the reformer tubes for brazing. Preferably, the reformer tubes are numbered, sized, shaped, and arrayed to minimize the longest conduction path in the radiator core to the center of any reformer tube.
    Type: Grant
    Filed: August 20, 2008
    Date of Patent: July 12, 2011
    Assignee: Delphi Technologies, Inc.
    Inventors: Diane M. England, Sean M. Kelly