And Aluminum Compound (e.g., Clay, Aluminum Oxide, Etc.) Patents (Class 501/105)
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Publication number: 20090011920Abstract: A gasifier comprising an interior wall on which a layer is applied or an interior wall protected by an assembly of blocks, said layer or said blocks having at least one region of a sintered material containing: i) at least 25% by weight of chromium oxide Cr2O3; and ii) at least 1% by weight of zirconium oxide, wherein at least 20% by weight of said zirconium oxide ZrO2 is stabilized in the cubic and/or quadratic form.Type: ApplicationFiled: July 2, 2008Publication date: January 8, 2009Applicant: SAINT-GOBAIN CENTRE DE RECHERCHES ET D'ETUDES EUROPEENInventors: THIBAULT PIERRE PAUL CHAMPION, CHRISTIAN CLAUDE HIS, FRANCELINE MARGUERITE VILLERMAUX
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Publication number: 20080314085Abstract: A refractory composition includes a first set of components and a colloidal silica binder. The first set of components includes alumina and zirconia. The colloidal silica binder is provided at 5 wt % to 20 wt % of the dry weight of the first set of components. The refractory composition includes 45 wt % to 75 wt % alumina, 15 wt % to 30 wt % zirconia, and 10 wt % to 30 wt % silica.Type: ApplicationFiled: June 19, 2007Publication date: December 25, 2008Inventors: Charles W. Connors, SR., Michael W. Anderson, Shirish Shah
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Publication number: 20080314084Abstract: A refractory system includes a first set of components and a colloidal silica binder. The first set of components includes alumina and zirconia. The colloidal silica binder is at 5 wt % to 20 wt % of the dry weight of the first set of components. The refractory composition comprises 10 wt % to 45 wt % alumina, at least 35 wt % zirconia, and at least 20 wt % silica.Type: ApplicationFiled: June 19, 2007Publication date: December 25, 2008Inventors: Charles W. Connors, SR., Michael W. Anderson, Shirish Shah
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Publication number: 20080274871Abstract: A jig for calcining an electronic component including a substrate 11 and a zirconia layer 12 coated on a surface of the substrate characterized in that the zirconia layer including one or more metal oxides forming a liquid phase is calcined for improving peel-off resistance and wear resistance to crystallize the liquid phase after the calcination. In the jig for calcining the electronic component, when the zirconia layer is formed by using an inexpensive method such as an application method, the zirconia layer is not peeled off from the substrate, and grains are not detached.Type: ApplicationFiled: July 2, 2008Publication date: November 6, 2008Applicant: MITSUI MINING & SMELTING CO., LTD.Inventors: Kazutomo HOSHINO, Hitoshi Kajino, Yasuhisa Idutsu, Koushi Horiuchi
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Publication number: 20080220209Abstract: This invention relates to thermally sprayed coatings of a high purity yttria or ytterbia stabilized zirconia powder, said high purity yttria or ytterbia stabilized zirconia powder comprising from about 0 to about 0.15 weight percent impurity oxides, from about 0 to about 2 weight percent hafnium oxide (hafnia), from about 6 to about 25 weight percent yttrium oxide (yttria) or from about 10 to about 36 weight percent ytterbium oxide (ytterbia), and the balance zirconium oxide (zirconia). Thermal barrier coatings for protecting a component such as blades, vanes and seal surfaces of gas turbine engines, made from the high purity yttria or ytterbia stabilized zirconia powders, have a density greater than 88% of the theoretical density with a plurality of vertical macrocracks homogeneously dispersed throughout the coating to improve its thermal fatigue resistance.Type: ApplicationFiled: April 27, 2007Publication date: September 11, 2008Inventors: Thomas Alan Taylor, Danny Lee Appleby, Albert Feuerstein, Ann Bolcavage, Neil Hitchman
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Patent number: 7414002Abstract: The present invention provides an aluminum oxide-titanium nitride sintered body having good resistance to electrostatic damage and small variation in volume resistivity. The aluminum oxide-titanium nitride sintered body is mainly composed of 65 to 85% by weight of aluminum oxide and titanium nitride constituting the rest. The average of the sum of the crystal grain sizes of the aluminum oxide and the titanium nitride is 0.4 to 2.0 ?m. The aluminum oxide has a mean crystal grain size of 0.5 to 2.2 ?m and the titanium nitride has a mean crystal grain size of 0.2 to 1.6 ?m.Type: GrantFiled: November 29, 2005Date of Patent: August 19, 2008Assignee: Kyocera CorporationInventors: Minoru Nakasuga, Kazuhide Kusano
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Patent number: 7405173Abstract: An alumina-titanium oxide-zirconia fused grain presenting, for a total of 100%, the following chemical composition: Al2O3: more than 10% and less than 50%; TiO2: more than 10% and less than 40%; ZrO2: more than 50%; and impurities: less than 2%; the percentages being percentages by weight on the basis of the oxides. The invention is applicable to slide gates for continuous casting of steel.Type: GrantFiled: January 31, 2007Date of Patent: July 29, 2008Assignee: Saint-Gobain Centre de Recherches et d'Etudes EuropeenInventors: Samuel Marlin, Jerome Latournerie
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Patent number: 7399722Abstract: Composite ceramics having a high strength, a high toughness and an excellent abrasion resistance, and a method of producing the same. The composite ceramics comprises 10 to 30 mass % of a zirconia crystal phase including Ce-stabilized zirconia crystal particles which contain CeO2 in an amount of 9 to 12 mol % and Y-stabilized zirconia crystal particles which contain Y2O3 in an amount of 2.8 to 4.5 mol %; and 70 to 90 mass % of an alumina crystal phase, the zirconia crystal phase having an average crystal particle size of not larger than 1 ?m.Type: GrantFiled: March 2, 2006Date of Patent: July 15, 2008Assignee: Kyocera CorporationInventors: Kunihide Shikata, Shugo Onitsuka, Wang Yucong
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Patent number: 7396792Abstract: The present invention relates to highly dense translucent and transparent aluminium oxide components for applications, e.g. in the lighting industry, where a fine crystal size has to be obtained and stabilized for use at temperatures of 800° C. or more. Disclosed are high-strength polycrystalline alumina products which include 0.001-0.5 weight-% ZrO2 stabilizing a fine crystal size <2 ?m or, preferably, <1 ?m if used at temperatures of 800° C. or more. The microstructure exhibits an extremely high relative density enabling a high real in-line transmission >30% measured over an angular aperture of at most 0.5° at a sample thickness of 0.8 mm and with a monochromatic wavelength of light ?, preferably, of 645 nm.Type: GrantFiled: July 2, 2003Date of Patent: July 8, 2008Assignees: Koninklijke Philips Electronics, N.V., Fraunhofer-Gesellschaft zur Forderung der Angewandten Forschung e.V.Inventors: Michel Paul Barbara Van Bruggen, Rolf Theo Anton Apetz, Theo Arnold Kop, Andreas Krell, Thomas Hutzler
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Patent number: 7396789Abstract: A gasifier internal refractory coating has at least one region of a sintered material containing at least 45% by weight of chromium oxide (Cr2O3) and at least 1% by weight of zirconium oxide, at least 20% by weight of the zirconium oxide (ZrO2) being stabilized in the cubic and/or quadratic form.Type: GrantFiled: June 27, 2005Date of Patent: July 8, 2008Assignee: Saint-Gobain centre de Recherches et d'Etudes EuropeenInventors: Thibault Pierre Paul Champion, Christian Claude His, Franceline Marguerite Louise Villermaux
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Publication number: 20080124515Abstract: The present invention provides a cordierite ceramic containing at least either of zirconium oxide and hafnium oxide and also containing titanium oxide, wherein the molar ratio of zirconium (Zr), hafnium (Hf) and titanium (Ti) in terms of the moles in the form of the dioxides, respectively which is given by the formula [(ZrO2+HfO2)/TiO2] is in a range of 0.1 to 5; and a honeycomb structure made of the cordierite ceramic. In this cordierite ceramic, the phases of the above components are contained mainly as zirconium titanate or hafnium titanate, and there occurs no heterogeneity in appearance, caused by change in color and generation of spots or the like.Type: ApplicationFiled: November 27, 2007Publication date: May 29, 2008Applicant: NGK Insulators, Ltd.Inventors: Yohei ONO, Satoshi YAMAZAKI, Yuji KATSUDA, Shuji UEDA
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Patent number: 7335617Abstract: The invention relates to a melted and cast refractory product which is intended, for example, for a checker work element of a glass furnace regenerator, having the following average chemical weight composition, expressed in weight percent based on oxide content: 0.4%<MgO<2.5%; 0.2%<SIO2<2%; CaO<0.4%; impurities<0.5% AL2O3: complement.Type: GrantFiled: April 15, 2004Date of Patent: February 26, 2008Assignee: Saint-Gobain Centre de Recherches et d'Etudes EuropeenInventors: Yves Boussant-Roux, Michel Gaubil, Olivier Citti
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Publication number: 20070270304Abstract: A zirconia-containing powder including 2 to 6 weight % of a pigment which has a spinel structure represented by the chemical formula (Co1-xZnx)(Fe1-yAly)2O4(0?x?0.5, 0<y?0.5) or which is a coprecipitated material containing Co, Zn, Fe, and Al and has the same spinel structure after calcination, 0.05 to 6 weight % of Al2O3, and 3.60 to 7.10 weight % of Y2O3; and a black zirconia sintered body obtained by sintering the zirconia-containing powder within a temperature range of 1300 to 1500° C.Type: ApplicationFiled: May 14, 2007Publication date: November 22, 2007Applicant: TOSOH CORPORATIONInventor: Hiroyuki FUJISAKI
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Patent number: 7291574Abstract: A zirconia sintered body having high strength and high toughness is provided, and a method for producing the same is also provided. The zirconia sintered body comprising tetragonal zirconia, wherein a full width at half maximum at (111) plane of the tetragonal zirconia obtained by X-ray diffraction pattern is from 0.38 to 4 degree. A method for producing the zirconia sintered body, wherein the method comprises steps of; molding zirconia powder having an average particle diameter of from 0.1 to 0.6 ?m, a maximum particle diameter of 5 ?m or less and a substantially polyhedral shape, and then sintering the molded green body under the temperature of from 1200 to 1400° C.Type: GrantFiled: February 25, 2004Date of Patent: November 6, 2007Assignee: Sumitomo Chemical Company, LimitedInventors: Ichiro Tanaka, Yoshio Uchida
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Publication number: 20070225153Abstract: The invention provides composite materials comprising eucryptite particles distributed in a matrix material other than eucryptite. The matrix material may be a ceramic material such as an oxide ceramic. In an embodiment, the eucryptite particles are transformed from the ?-phase to the ?-phase during fabrication of the composite. This phase transformation can enable a eucryptite-based transformation toughening mechanism.Type: ApplicationFiled: March 21, 2007Publication date: September 27, 2007Inventors: Ivar Reimanis, Chris Seick, Kyle Fitzpatrick
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Publication number: 20070213199Abstract: A refractory brick, comprised of a refractory material having about 55% to about 96% by weight magnesia particles or magnesia particles containing spinel precipitates, about 3% to about 20% by weight fine zirconia particles having a particle size less than 35 Tyler mesh (less than 425 ?m), and about 1% to about 25% of a material selected from the group consisting of coarse zirconia, coarse spinel, coarse alumina-zirconia, and combinations thereof.Type: ApplicationFiled: September 15, 2006Publication date: September 13, 2007Inventor: David J. Michael
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Patent number: 7247588Abstract: ESD safe ceramic component is provided which includes a sintered composition which is formed of a base material and a resistivity modifier. The base material includes a primary component and a secondary component, the primary component including Al2O3 and the secondary component including tetragonal-ZrO2.Type: GrantFiled: November 24, 2003Date of Patent: July 24, 2007Assignee: Saint-Gobain Ceramics & Plastics, Inc.Inventors: Oh-Hun Kwon, Christophe Coureau, Richard A. Gorski, Matthew A. Simpson
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Patent number: 7176153Abstract: A refractory system for glass melting furnaces includes alumina, zirconia, and silica mixed with a silica binder. The refractory may be formed as refractory blocks or directly onto the wear portion of a glass melting furnace. The refractory may be formed using casting, pumping, or shotcreting methods.Type: GrantFiled: December 9, 2003Date of Patent: February 13, 2007Assignee: Magneco/Metrel, Inc.Inventor: Michael W. Anderson
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Patent number: 7169723Abstract: A ceramic includes alumina in an amount between about 90 and about 99% by weight, a zirconium containing compound in an amount between about 0 and about 1% by weight, and an oxide mixture in an amount between about 1 and about 10% by weight. The oxide mixture includes a glass former and a network modifier, wherein the molar ratio of the glass former to the network modifier ranges between about 0.8:1 and 1.2:1. The ceramic insulator is particularly adapted for use as an insulator in a spark plug to provide improved dielectric strength and shunt resistance of greater than one 1000 megaohms at 1000 degrees Fahrenheit, so as to reduce the shunting of the spark plug and thereby improve the quality of the spark generated by the spark plug.Type: GrantFiled: November 9, 2004Date of Patent: January 30, 2007Assignee: Federal-Mogul World Wide, Inc.Inventor: William J. Walker, Jr.
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Patent number: 7148167Abstract: Alumina/zirconia ceramics containing Al2O3 in an amount of not less than 65 mass % and ZrO2 in an amount of 4 to 34 mass %, and further containing TiO2, MgO and SiO2. The ceramics effectively suppresses the growth of shape isotropic particles of alumina, suppresses the growth of zirconia particles, and has a high strength and a high hardness. Besides, the ceramics containing SrO features a high fracture toughness.Type: GrantFiled: August 26, 2004Date of Patent: December 12, 2006Assignee: Kyocera CorporationInventors: Kunihide Shikata, Shugo Onitsuka, Yucong Wang, Hiroaki Seno
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Patent number: 7129192Abstract: The invention concerns a refractory product comprising more than 85% of zirconia (ZrO2), characterized in that it comprises in wt. % with respect to oxides: ZrO2>92%, SiO2: 2 to 8%, Na2O: 0.12 to 1%, Al2O3: 0.2 to 2%, 0.5%?Y2O3+CaO?2.6%, with the proviso that Y2O3: 0.3 to 2% and that CaO: 0.5 to 1.93%.Type: GrantFiled: February 28, 2003Date of Patent: October 31, 2006Assignee: Saint-Gobain Centre de Recherches et D'Etudes EuropeenInventors: Yves Marcel Leon Boussant-Roux, Michel Marc Gaubil
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Patent number: 7122064Abstract: An Al2O3 and ZrO2 based abrasive grain containing titanium compounds in a reduced form, especially in the form of oxides and/or suboxides and/or carbides and/or oxycarbides and/or oxycarbonitrides and/or suicides, corresponding to a proportion of 0.510 wt. %, expressed as TiO2, containing 20–50 wt. % ZrO2, wherein more than 75 wt. % of the ZrO2 is present in a tetragonal crystal form, having an overall carbon content of 0.03–0.5 wt. %, a proportion of impurities caused by raw materials of less than 3.0 wt. %, wherein the rare earth content calculated in the form of oxides is less than 0.1 wt. %, having an Si-compound content of 0.05–1.0 wt. %, expressed as SiO2, and an Al2O3 content of 50–80 wt.Type: GrantFiled: November 29, 2001Date of Patent: October 17, 2006Assignee: Treibacher Schleifmittel GmbHInventors: Alessandro Dazza, Hans Zeiringer, Wolfgang Bucar, Paul Moeltgen
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Patent number: 7094719Abstract: Aspects of the present invention may be found in an electrostatic dissipative ceramic component having a stabilized zirconia base, a surface resistivity between 1×105 and 1×1012 ohms per square and at least 2 percent by volume scattering material. The stabilized zirconia may be present in amounts between 60 and 95 weight percent. Further aspects of the invention may be found in an electrostatic dissipative ceramic material having stabilized zirconia, a resistivity modifier, and a scattering material. The stabilized zirconia may be present in amounts between 60 and 95 weight percent of the ceramic material. The resistivity modifier may be present in amounts between 5 and 30 weight percent. The scattering material may comprise at least 2 volume percent of the electrostatic dissipative ceramic material. The component may be used in the manufacturing of electronic component such as hard drives.Type: GrantFiled: June 27, 2005Date of Patent: August 22, 2006Assignee: Saint-Gobain Ceramics & Plastics, Inc.Inventor: Matthew Simpson
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Patent number: 7074733Abstract: An unwrought refractory composition, in particular for producing glass furnace hearths, includes a base mixture comprising in wt. %: 1 to 6% of a hydraulic cement, and 94 to 99% of particles of at least a refractory material mainly consisting of alumina (Al2O3), zirconia (ZrO2) and silica (SiO2), the fraction of the particles of the base mixture having a size less than 40 ?m being distributed in wt. % relative to the weight of the base mixture, as follows: fraction<0.5 ?m: ?4%; fraction<2 ?m: ?5%; fraction<10 ?m: ?16%; fraction<40 ?m: 29–45%, the refractory composition further comprising, in wt. % relative to the weight of the base mixture: 0.02 to 0.08% of organic fibers, and 0.075 to 1% of a surfactant.Type: GrantFiled: November 19, 2002Date of Patent: July 11, 2006Assignee: Saint-Gobain Centre de Recherches Et d'Etudes EuropeenInventors: Jacques Marius Louis Guigonis, Thierry Claude Consales
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Patent number: 7067446Abstract: A material having a negative or low thermal expansion coefficient and composed substantially of a single crystal system is provided. The material is an oxide represented by the chemical formula ((R4+M2+)1-xA3+2x)(QO4)3 (where R stands for at least one tetravalent metal element selected from Zr and Hf; M stands for at least one divalent metal element selected from Mg, Ca, Sr, Ba, and Ra; Q stands for at least one hexavalent metal element selected from W and Mo; and A stands for at least one trivalent metal element selected from Al, Sc, Y, Lu, Ga, and In; 0<x<1) and composed substantially of a single crystal system.Type: GrantFiled: August 5, 2005Date of Patent: June 27, 2006Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Tomoko Suzuki, Atsushi Omote, Masa-aki Suzuki
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Patent number: 7056851Abstract: A ZrO2—Al2O3 composite ceramic material is provided, which is excellent in mechanical strength and toughness, and has the capability of preventing low temperature degradation. This ceramic material includes a first phase of ZrO2 grains having an average grain size of 0.1 to 0.8 ?m, and containing 10 to 12 mol % of CeO2 and 0.005 mol % to less than 0.5 mol % of Y2O3, and a second phase of Al2O3 grains having an average grain size of 0.1 to 0.5 ?m. The ZrO2 grains is composed of 90 vol % or more of tetragonal ZrO2, and a content of the second phase in the composite ceramic material is in a range of 20 to 60 vol %, and preferably 30 to 50 vol %.Type: GrantFiled: August 20, 2004Date of Patent: June 6, 2006Assignee: Matsushita Electric Works, Ltd.Inventor: Masahiro Nawa
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Patent number: 7012036Abstract: A ZrO2—Al2O3 composite ceramic material having high mechanical strength and toughness as well as excellent wear resistance and hardness is provided. This ceramic material includes a first phase of ZrO2 grains containing 10 to 12 mol % of CeO2 as a stabilizer and having an average grain size of 0.1 ?m to 1 ?m, and a second phase of Al2O3 grains having an average grain size of 0.1 to 0.5 ?m.Type: GrantFiled: July 18, 2003Date of Patent: March 14, 2006Assignee: Matsushita Electric Works, Ltd.Inventors: Masahiro Nawa, Kouichi Yamaguchi, Motoyuki Toki
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Patent number: 6984261Abstract: The invention relates to uses of glasses and glass-ceramics in dental and orthodontic applications.Type: GrantFiled: February 5, 2003Date of Patent: January 10, 2006Assignee: 3M Innovative Properties CompanyInventors: Kevin M. Cummings, Jacqueline C. Rolf, Anatoly Z. Rosenflanz, Richard P. Rusin, Jerome E. Swanson
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Patent number: 6982233Abstract: The invention relates to a fired refractory ceramic molded piece with a spinel matrix based on (Mg)2+ (Al, Cr)23+O4, in which coarser particles based on chromium corundum and/or corundum and coarser particles based on ZrO2 are present.Type: GrantFiled: November 8, 2002Date of Patent: January 3, 2006Assignee: Refractory Intellectual Property GmbH & Co.Inventors: Bernd Buchberger, Markus Horn, Roland Nilica
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Patent number: 6960395Abstract: Ceramic compositions comprising at least about 91 mole % zirconia and up to about 9 mole % of a stabilizer component comprising a first metal oxide having selected from the group consisting of yttria, calcia, ceria, scandia, magnesia, india and mixtures thereof. This stabilizer component further comprises a second metal oxide of a trivalent metal atom selected from the group consisting of lanthana, gadolinia, neodymia, samaria, dysprosium, and mixtures thereof and a third metal oxide of a trivalent metal atom selected from the group consisting of erbia, ytterbia and mixtures thereof. These ceramic compositions are useful in preparing thermal barrier coatings having reduced thermal conductivity for the metal substrate of articles that operate at, or are exposed to, high temperatures.Type: GrantFiled: December 30, 2003Date of Patent: November 1, 2005Assignee: General Electric CompanyInventors: Irene Spitsberg, Venkat Subramanian Venkataramani, Brett Allen Boutwell, Mark Daniel Gorman
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Patent number: 6958303Abstract: The invention provides partially stabilised zirconia and alumina based electro-static dissipative or ESD ceramic compositions. The proposed ceramic compositions include specific amounts of dopants comprising one or more metal oxides selected from iron oxide, chromium oxide and titanium oxide. The proposed ESD ceramic materials are made into useful industrial products by injection moulding and sintering technology. A novel binder system may optionally be used to make injection mouldable feedstock. Useful products produced by the invention include, for example, ESD ceramic tweezers tips, ESD ceramic dispensing needles, ESD ceramic scissors and blades and ESD ceramic wire bonding capillaries which retain their ESD properties at relatively low temperatures, for example, service temperatures from 25 to 500° C.Type: GrantFiled: May 30, 2003Date of Patent: October 25, 2005Assignee: Dou Yee Technologies Pte Ltd.Inventors: Jian Guo Zhang, Hwey Eng Liow, Bo Zhang
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Patent number: 6946417Abstract: Aspects of the present invention may be found in an electrostatic dissipative ceramic component having a stabilized zirconia base, a surface resistivity between 1×105 and 1×1012 ohms per square and at least 2 percent by volume scattering material. The stabilized zirconia may be present in amounts between 60 and 95 weight percent. Further aspects of the invention may be found in an electrostatic dissipative ceramic material having stabilized zirconia, a resistivity modifier, and a scattering material. The stabilized zirconia may be present in amounts between 60 and 95 weight percent of the ceramic material. The resistivity modifier may be present in amounts between 5 and 30 weight percent. The scattering material may comprise at least 2 volume percent of the electrostatic dissipative ceramic material. The component may be used in the manufacturing of electronic component such as hard drives.Type: GrantFiled: May 21, 2003Date of Patent: September 20, 2005Assignee: Saint-Gobain Ceramics & Plastics, Inc.Inventor: Matthew Simpson
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Patent number: 6905993Abstract: The present invention relates to a zirconia based sintered body excellent in durability, characterized in that in Y2O3-toughened zirconia based sintered body, (a) ZrO2 contained therein is mainly composed of tetragonal ZrO2, and the sintered body contains Y2O3 as a secondary component and further SiO2 and Al2O3 as a third component; (b) the sintered body has a molar ratio of Y2O3/ZrO2 in the range of 1.5/98.5 to 4/96; (c) the sintered body has a SiO2 content of 0.05 to 2.5 wt %; (d) the sintered body has a Al2O3 content of 0.05 to 3.0 wt %; (e) the sintered body has an average crystal grain diameter of 0.7 ?m or less; (f) SiO2 (wt %)×average crystal grain diameter (?m) takes a value ranging from 0.03 to 0.5; (g) the sintered body contains at least one oxide of Na2O, K2O, CaO and Fe2O3 as an impurity and a weight ratio of SiO2/(total amount of the impurity) is 5 or more; and (h) the sintered body has a bulk density of 5.Type: GrantFiled: August 2, 2002Date of Patent: June 14, 2005Assignee: Nikkato CorporationInventors: Miyuki Sakuta, Hiroshi Onishi, Toshio Kawanami
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Patent number: 6872676Abstract: The present invention provides a semiconductive zirconia sintering material comprising more than 2% by weight of aluminum oxide and sintered zirconia material derived therefrom as well as a method of producing the sintered material. The sintered semiconductive zirconia materials of the present invention have a better physical and mechanical properties than conventional sintered semiconductive zirconia materials.Type: GrantFiled: April 25, 2003Date of Patent: March 29, 2005Assignee: CoorsTek, Inc.Inventors: Matthew W. Schaefer, Frank E. Anderson, Brian Seegmiller
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Patent number: 6862166Abstract: The invention provides a ceramic capacitor including a ceramic dielectric body at least two spaced-part electrodes in contact with the body wherein at least 80 weight percent of the body consists of alumina, the body further including at least 0.5 BaTiO3 w/w %, at least 0.5 w/w % MgO, <0.05 w/w % SiO2, at least 4.5 w/w % ZrO2 and at least 0.07 w/w % HfO2.Type: GrantFiled: February 17, 2004Date of Patent: March 1, 2005Inventors: Michael Cohen, Shalom Itzhak Cohen
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Publication number: 20040266604Abstract: An unwrought refractory composition, in particular for producing glass furnace hearths, includes a base mixture comprising in wt. %: 1 to 6% of a hydraulic cement, and 94 to 99% of particles of at least a refractory material mainly consisting of alumina (Al2O3), zirconia (ZrO2) and silica (SiO2), the fraction of the particles of the base mixture having a size less than 40 &mgr;m being distributed in wt. % relative to the weight of the base mixture, as follows: fraction<0.5 &mgr;m: ≧4%; fraction<2 &mgr;m: ≧5%; fraction<10 &mgr;m: ≧16%; fraction<40 &mgr;m: 29-45%, the refractory composition further comprising, in wt. % relative to the weight of the base mixture: 0.02 to 0.08% of organic fibers, and 0.075 to 1% of a surfactant.Type: ApplicationFiled: May 19, 2004Publication date: December 30, 2004Inventors: Jacques Marius Louis Guigonis, Thierry Claude Consales
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Publication number: 20040242401Abstract: The invention provides partially stabilised zirconia and alumina based electro-static dissipative or ESD ceramic compositions. The proposed ceramic compositions include specific amounts of dopants comprising one or more metal oxides selected from iron oxide, chromium oxide and titanium oxide. The proposed ESD ceramic materials are made into useful industrial products by injection moulding and sintering technology. A novel binder system may optionally be used to make injection mouldable feedstock. Useful products produced by the invention include, for example, ESD ceramic tweezers tips, ESD ceramic dispensing needles, ESD ceramic scissors and blades and ESD ceramic wire bonding capillaries which retain their ESD properties at relatively low temperatures, for example, service temperatures from 25 to 500° C.Type: ApplicationFiled: May 30, 2003Publication date: December 2, 2004Applicant: Dou Yee Technologies PTE, LTD.Inventors: Jian Guo Zhang, Hwey Eng Liow, Bo Zhang
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Patent number: 6815386Abstract: A high-chromium refractory material that provides improved resistance to coal slag penetration is presented. The refractory mixture comprises a blend of chromium oxide, aluminum oxide and phosphates. The refractory mixture may be blended with an aggregate and cured. In addition a phosphorous oxide may be blended with chromium oxide and aluminum oxide and additionally an aggregate. The refractory mixture reduces the rate of coal slag penetration into the surface of the cured refractory.Type: GrantFiled: October 23, 2002Date of Patent: November 9, 2004Inventors: Kyei-Sing Kwong, Cynthia P. Dogan, James P. Bennett, Richard E. Chinn, Arthur V. Petty
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Patent number: 6811868Abstract: The object of the present invention is to provide a ceramic body that can support a required amount of a catalyst component, without lowering the characteristics such as strength, being manufactured without forming a coating layer and providing a high performance ceramic catalyst that is excellent in practical utility and durability. A noble metal catalyst is supported directly on the surface of the ceramic body and the second component, consisting of compound or composite compound of element having d or f orbit in the electron orbits thereof such as W, Co, Ti, Fe, Ga and Nb, is dispersed in the first component made of cordierite or the like that constitutes the substrate ceramic. The noble metal catalyst can be directly supported by bonding strength generated by sharing the d or f orbits of the second component, or through interaction with the dangling bond that is generated in the interface between the first component and the second component.Type: GrantFiled: June 6, 2003Date of Patent: November 2, 2004Assignee: Denso CorporationInventors: Jun Hasegawa, Tomomi Hase, Kazuhiko Koike, Miho Ito
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Patent number: 6800158Abstract: A conductive co-fired body for an electrochemical cell for an exhaust sensor comprises zirconia, yttrium oxide, and alumina. The body comprises about 15 to about 30 weight % monoclinic phase zirconia. This produces an electrochemical cell having low impedance wherein the zirconia body and alumina body are co-fired. One method for manufacturing the electrochemical cell comprises combining zirconia, yttria, and alumina with solvent and dispersant to form a mixture. After, binder is added to the mixture which is then de-aired and cast onto a tape surface. The tape is dried, metallized, and laminated to an unfired alumina surface. The structure is then co-fired to form a body for said electrochemical cell.Type: GrantFiled: January 23, 2001Date of Patent: October 5, 2004Assignee: Delphi Technologies, Inc.Inventors: Kaius Kiiren Polikarpus, Walter Thomas Symons, Kerry J. Gross
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Publication number: 20040162214Abstract: The present invention relates to a zirconia based sintered body excellent in durability, characterized in that in Y2O3-toughened zirconia based sintered body,Type: ApplicationFiled: September 2, 2003Publication date: August 19, 2004Inventors: Miyuki Sakuta, Hiroshi Onishi, Toshio Kawanami
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Publication number: 20040142812Abstract: The invention relates to a fired refractory ceramic molded piece with a spinel matrix based on (Mg)2+ (Al, Cr)23+O4, in which coarser particles based on chromium corundum and/or corundum and coarser particles based on ZrO2 are present.Type: ApplicationFiled: November 12, 2003Publication date: July 22, 2004Inventors: Bernd Buchberger, Markus Horn, Roland Nilica
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Publication number: 20040138047Abstract: An object of the present invention is to provide an integrated sintered body having a first phase and a second phase containing yttrium-aluminum garnet as a main component, in which the incidence of peeling of the first phase from the second phase is reduced to improve the production yield. A sintered body 1 has at least first phase 3 and second phase 2. The first phase 3 has, as a main component, alumina containing a total amount of 12 weight percent or more and 50 weight percent or less of one or more of stabilized zirconia and partially stabilized zirconia. The second phase 2 contains yttrium-aluminum garnet as a main component.Type: ApplicationFiled: December 24, 2003Publication date: July 15, 2004Applicant: NGK Insulators, Ltd.Inventors: Hirotake Yamada, Tsutomu Naito
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Publication number: 20040138048Abstract: A refractory system for glass melting furnaces includes alumina, zirconia, and silica mixed with a silica binder. The refractory may be formed as refractory blocks or directly onto the wear portion of a glass melting furnace. The refractory may be formed using casting, pumping, or shotcreting methods.Type: ApplicationFiled: December 9, 2003Publication date: July 15, 2004Inventor: Michael W. Anderson
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Patent number: 6723674Abstract: A microstructured or nanostructured multi-component ceramic comprises (a) a major ceramic phase comprising a ceramic oxide composite; (b) a ceramic oxide additive; and (c) a rare earth ceramic oxide additive, wherein the total of the additives (b) and (c) comprise from about 0.1 weight percent to less than 50 weight percent based on the total weight the multi-component ceramic composite. In another embodiment, a microstructured or nanostructured multi-component ceramic comprises (a) a major ceramic oxide phase comprising a ceramic oxide composite; and either (b) a ceramic oxide additive or (c) a rare earth ceramic oxide additive, wherein amount of the additive (b) or (c) comprises from about 0.1 weight percent to less than 50 weight percent based on the total weight the multi-component ceramic composite. Such ceramics are useful as bulk materials or as feedstocks for thermal spray.Type: GrantFiled: September 21, 2001Date of Patent: April 20, 2004Assignee: Inframat CorporationInventors: Donald M. Wang, You Wang, Tongsan D. Xiao
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Patent number: 6723672Abstract: A high strength ceramic body and a method of making same are disclosed. The ceramic body is formed of ceramic composition containing 2.8-5.0% by weight MgO, an effective amount of grain growth inhibiting material, and the balance being essentially zirconia. The crystalline microstructure of the ceramic body comprises grains of cubic zirconia having an average grain size of less than about 30 microns in major dimension, 0.1-8.7% by volume of discrete particles of the grain growth inhibiting material, and precipitates of tetragonal zirconia having a substantially ellipsoidal shape with a long dimension of about 0.1-0.4 microns.Type: GrantFiled: July 17, 2001Date of Patent: April 20, 2004Assignee: Carpenter Advanced Ceramics, Inc.Inventors: Martin D. Stuart, Wilson H. Ta
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Publication number: 20040067839Abstract: A ZrO2—Al2O3 composite ceramic material having high mechanical strength and toughness as well as excellent wear resistance and hardness is provided. This ceramic material includes a first phase of ZrO2 grains containing 10 to 12 mol % of CeO2 as a stabilizer and having an average grain size of 0.1 &mgr;m to 1 &mgr;m, and a second phase of Al2O3 grains having an average grain size of 0.1 to 0.5 &mgr;m.Type: ApplicationFiled: July 18, 2003Publication date: April 8, 2004Applicant: MATSUSHITA ELECTIC WORKS, LTD.Inventors: Masahiro Nawa, Kouichi Yamaguchi, Motoyuki Toki
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Patent number: 6713421Abstract: The invention relates to blanks comprising zirconium oxide-based ceramic with an addition of 0.1 to 0.50 wt.-% of at least one of the oxides of the elements aluminium, gallium, germanium, indium and their use.Type: GrantFiled: April 11, 2002Date of Patent: March 30, 2004Assignee: 3M ESPE AGInventors: Holger Hauptmann, Robert Schnagl, Sybille Frank
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Publication number: 20040040218Abstract: A process for producing fused alumina-zirconia grits includes mixing raw materials suitable to produce grits with the following chemical composition, in % by weight: ZrO2+HfO2: 10-60%, Al2O3: 38-90%, SiO2: <0.8%, and Impurities: <1.2%. The process also includes adding carbon and aluminum metal to the mixture of raw materials to obtain a charged batch containing, in % by weight,: Carbon: 0.4-1% Aluminum metal: 0.5-2.5%. The process further includes melting the charged batch in an electric arc furnace with a voltage of 175-205 V and a delivered specific electrical energy of 2.5 to 4 kWh per kg of charge.Type: ApplicationFiled: June 10, 2003Publication date: March 4, 2004Inventors: Bruno Pascal Albert Aleonard, Alain Paul Bernard Zanoli
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Patent number: 6669749Abstract: Fused abrasive particles comprising eutectic colonies. The fused abrasive particles can be incorporated into abrasive products such as coated abrasives, bonded abrasives, non-woven abrasives, and abrasive brushes.Type: GrantFiled: July 19, 2000Date of Patent: December 30, 2003Assignee: 3M Innovative Properties CompanyInventors: Anatoly Z. Rosenflanz, Ahmet Celikkaya, Donna W. Bange