Abstract: A method for treating refractory ceramic products is described herein. The method includes providing a refractory ceramic product, comprising magnesia and at least one of the following salts: one or more alkali salts and one or more alkaline earth salts. The method also includes providing a water-based liquid, combining the refractory ceramic product with the liquid, and separating the refractory ceramic product and the liquid.

Abstract: There is a process for creating graphite free non-fired refractory products, which are molded using presses and which includes using a plurality of different binders. The binders comprise a first binder for binding grains of granulation between room temperature and 400° C., a second binder binding the grains of granulation between 300 and 900° C.; and a third binder binding granulations of the refractory materials that enter into ceramic binding at temperatures above 900° C. This process is for producing at least one of magnesia chromite bricks, magnesia spinel and spinel bricks, magnesia zirconia and magnesia zircon bricks, magnesia hercynite and magnesia galaxite bricks, dolomite, dolomite-magnesia, and lime bricks, forsterite and olivine bricks, magnesia forsterite bricks, magnesia pleonast bricks, magnesia bricks.

Abstract: The composition applied to the refractory structure has a magnesia-based refractory material, calcia source and a binder. After application of the refractory material to a refractory structure and upon application of heat to the applied refractory material a matrix is formed which protects against penetration of the slag into the refractory material. The resulting refractory material has improved hot strength, slag resistance and durability.

Abstract: The composition applied to the refractory structure has a magnesia-based refractory material, calcia source and a binder. After application of the refractory material to a refractory structure and upon application of heat to the applied refractory material a matrix is formed which protects against penetration of the slag into the refractory material. The resulting refractory material has improved hot strength, slag resistance and durability.

Abstract: A method of reducing the defects in ceramic articles and precursors, particularly ceramic articles and precursors made using a batch composition containing an oil phase material. The method includes increasing the concentration of a water insoluble soap in the batch composition, which can increase the cohesive strength of the oil phase, leading to a reduction in the incidence of defects in the ceramic articles and precursors.

Abstract: In a carbon-containing refractory composed of a refractory aggregate, a carbon based raw material, and a carbon bond connecting between the refractory aggregate or the carbon based raw material, transition metal-containing nanoparticles having particle diameters of 1,000 nm or less and containing a transition metal are contained in the above-described carbon bond while being dispersed. When the carbon-containing refractory is heat-treated, flexible structures of carbon fiber-shaped textures having diameters of 50 nm or less are formed in the inside of a carbon bond and, thereby, an increase in strength, a reduction in modulus of elasticity, and a reduction in thermal expansion coefficient are facilitated. Therefore, a carbon-containing refractory exhibiting high thermal shock resistance, high abrasion resistance, and high corrosion resistance are provided.

Abstract: Mix which comprises a) one or more very finely divided silicon dioxide powders having an average particle diameter of from 2 to 100 nm and a BET surface area of at least 30 m2/g, b) one or more particulate components selected from the group consisting of oxides, carbides and nitrides, in each case having an average particle diameter of from >0.5 ?m to 30 mm, c) one or more synthetic resins as binders and d) one or more metallic antioxidants having an average particle diameter of from >0.5 to 250 ?m. Process for producing a shaped body, in which to the mix is introduced into a mould, pressed if appropriate and heated to a temperature at which the synthetic resin crosslinks thermally. Shaped body which can be obtained therefrom. Process for producing a refractory shaped body, in which the shaped body is carbonized. Refractory shaped body which can be obtained therefrom.

Abstract: The composition applied to the refractory structure has a magnesia-based refractory material, calcium carbonate and a binder. After application of the refractory material to a refractory structure and upon application of heat to the applied refractory material a matrix is formed which protects against penetration of the slag into the refractory material. The resulting refractory material has improved hot strength, slag resistance and durability.

Abstract: The invention relates to an unshaped refractory material comprising a refractory base component and a binder component, the binder component comprising, related to the refractory material, an acidic component of the group comprising an acid, salt of an acid, ester of an acid, salt and ester of an acid as phosphate, sulfate or carbonate, in an amount of ?1.5 wt.-% and ?6 wt.-%, and a basic component of the group comprising: base, urotropin, calcium oxide, calcium hydroxide, magnesium oxide, caustic MgO, sodium hydroxide, potassium hydroxide, magnesium hydroxide, in an amount of ?1 wt.-% and ?4 wt.-%, wherein said material receives an earth-moist, crumbly consistency by addition of 1 to 5 wt.-% of water and which solidifies after an exothermic reaction of the binder component.

Abstract: The invention relates to a refractory, ceramically fired, carbon-bonded magnesia brick whose matrix is more than 70% by weight, in particular from 80 to 98% by weight, of MgO grains and also a carbon framework binder matrix resulting from carbonization, and pores, wherein the MgO grains are fixed by means of carbon bonding of the carbon framework and at least 30%, in particular from 50 to 100%, of the MgO grains have at least one sintering bridge resulting from the ceramic firing.

Abstract: Disclosed is a magnesia-carbon based sleeve brick for steelmaking converters, which is obtained by adding, to a refractory raw material mix containing 60 to 95 mass % of a magnesia raw material and 5 to 20 mass % of graphite, a metal powder of one or more selected from the group consisting of Al, Si, Mg, Ca, Cr and an alloy thereof, in an amount of greater than 3 to 6 mass %, and an organic binder, in addition to 100 mass % of the refractory raw material mix, and subjecting the resulting mixture to kneading, forming and heat treatment, wherein the sleeve brick is used under a condition that a thickness thereof is set at 70 mm or less. This makes it possible to prevent cracking which would otherwise occur in the sleeve brick itself, to allow the sleeve brick to have enhanced durability. One or more selected from the group consisting of B, B4C, MgB2, CaB6, and CrB may be further added in an amount of 0.

Abstract: The present invention provides a carbon-containing refractory composition comprising a carbon-containing refractory matrix material, and a binder selected from molasses, lignosulphonate, magnesium sulfate, magnesium chloride, and a mixture thereof. The inventive composition having satisfactory good thermal and physical properties causes no environmental hazard.

Abstract: A refractory mortar cured material is formed in the surface or joint portions of a ceramic refractory material, such as fire bricks used in the lining of melting furnace or firing furnace used at high temperature, and includes ceramic particles with an inorganic binder having silanol group that are kneaded together with water. The kneaded mortar is applied on the surface of a ceramic base material. The average particle size of ceramic particles in the refractory mortar is 10 to 50 ?m, and the difference between the 90% particle size and the 10% particle size is 10 ?m or more to 60 ?m or less. The average pore size of the refractory mortar cured material is 5 to 25 ?m, and the width of pore size distribution is 20 to 80 ?m, so that the cracks are suppressed. In addition, the bulk density is 0.9 to 1.5 g/cm3.

Abstract: A high-temperature, heat-resistant fill material is disclosed. The high-temperature, heat-resistant fill material includes an alumina refractory waste material having one or more of a used alumina-magnesium-carbon material, a used high-alumina material and a used fused-grain alumina material is disclosed. A method for method for manufacturing a material is also disclosed.

Abstract: The composition applied to the refractory structure has a magnesia-based refractory material, calcia source and a binder. After application of the refractory material to a refractory structure and upon application of heat to the applied refractory material a matrix is formed which protects against penetration of the slag into the refractory material. The resulting refractory material has improved hot strength, slag resistance and durability.

Abstract: An in-situ method for nanomixing magnesium aluminate spinel nanoparticles with a uniformly distributed controlled concentration of nanoparticles of an inorganic sintering aid, such as LiF, to produce ready-to-sinter spinel powder. The spinel-sintering aid nanomixture is formed by induced precipitation of the sintering aid nanoparticles from a dispersion of the spinel nanoparticles in an aqueous solution of the sintering aid, followed by separation, drying and deagglomeration of the spinel-sintering aid nanomixed product.

Abstract: Disclosed is a continuous casting nozzle having a refractory portion formed to contain a dolomite clinker and arranged to define a surface region adapted to be in contact with molten steel, which is capable of protecting a working surface of the nozzle from alumina build-up due to alumina in molten steel, while improving corrosion resistance, even during long-term continuous casting of molten steel. The refractory portion is prepared by adding a binder to a mixed material and subjecting the obtained mixture to kneading, forming and heat treatment. The mixed material comprises a dolomite clinker which has an average particle size of 0.8 mm or less and a CaO content of 50 mass % or less. The mixed material has a ratio W1/W2 of 0.33 or more, wherein W1 is a content by mass of CaO, and W2 is a content by mass of MgO. The mixed material comprises a dolomite clinker and a magnesia clinker. Alternatively, the mixed material comprises a dolomite clinker and a magnesia clinker.

Abstract: This invention relates to refractory mixes produced by mixing a refractory material with an organic binder and heating to a temperature of typically from about 50° C. to about 100° C. to form a stable composite granulate. The refractor mixes comprise a major amount of a refractory material and a minor amount of a binder composition comprising (a) condensed tannin and (b) furfuryl alcohol. The refractory mixes are used to prepare shaped (e.g. bricks) and unshaped (e.g. blast furnace tap holes, troughs, and tundish liners) refractory products. The invention also relates to a process for preparing the refractory products using the refractory mixes.

Abstract: A high temperature hot strength magnesia-based refractory composition having high durability at elevated temperatures wherein a sulfamic acid in combination with an independent calcia source is added to a magnesia-based refractory material. The invention also provides for a refractory gunning composition for use in the production or repair of metallurgical furnace linings.

Abstract: A refractory repair batch material includes a refractory, in particular a basic resistor component in granule form and a binder system. The binder system contains at least one hard bitumen component in granule form, at least one ignitable metal powder and at least one combustible mineral oil.

Abstract: A batch, in particular for the production of a refractory shaped body, includes at least one refractory metal oxide component and a synthetic resin component as a binder, and a graphitizing auxiliary for producing crystalline graphite carbon from the resin. The graphitizing auxiliary originates from a group consisting of reducible organic compounds of transition elements and/or a group of active organic or inorganic metal compounds or metals, such as resin-soluble metal salts, chemically precipitated or micronized metal oxides or metals. The graphitizing auxiliary is available in molecular form over the time and/or temperature range of conversion of the synthetic resin into carbon (carbonization).

Abstract: The invention relates to a fire resistant substance and to a method for producing a fire-resistant lining. The fire-resistant substance contains MgO sinter and up to 5 wt. % of a reducing agent selected from the group consisting of substances that contain carbon. The lining has several layers with decreasing quantities of reducing agents.

Abstract: The invention relates to free-flowing refractory castable material and castings produced therefrom. Refractory nonbasic and basic refractory castable materials have been known for a long time. The traditional refractory castable materials have thixotropic properties and must be lined sing vibration technology. In the past, free-flowing refractory castable materials were solely based on alumina raw materials. Attempts to produce an aqueous, highly concentrated basic suspension which would Coma the basis of free-flowing refractory castable materials failed to meet the requirements in terms of theological properties and a low degree of to hydration of the MgO-based materials. It is the aim of the invention to provide the above-mentioned refractory castable material for the monolithic lining or repair of high-temperature equipment and for the production of refractory castings. This is achieved by providing a fine-grained and a mixed fine and coarse-grained alternative.

Abstract: A dry refractory composition having superior insulating value. The dry refractory composition also may have excellent resistance to molten metals and slags. The composition includes filler lightweight material, which may be selected from perlite, vermiculite, expanded shale, expanded fireclay, expanded alumina silica hollow spheres, bubble alumina, sintered porous alumina, alumina spinel insulating aggregate, calcium alumina insulating aggregate, expanded mulllite, cordierite, and anorthite, and matrix material, which may be selected from calcined alumina, fused alumina, sintered magnesia, fused magnesia, silica fume, fused silica, silicon carbide, boron carbide, titanium diboride, zirconium boride, boron nitride, aluminum nitride, silicon nitride, Sialon, titanium oxide, barium sulfate, zircon, a sillimanite group mineral, pyrophyllite, fireclay, carbon, and calcium fluoride.

Abstract: A binder system for use in the formation of ceramic or other powder-formed greenware comprising a binder, a solvent for the binder, a surfactant, and a component that is non-solvent with respect to the binder and solvent. The non-solvent component exhibits a lower viscosity than the solvent when containing the binder and comprises a low molecular weight oil having a 90% recovered distillation temperature range of between about 220 to 400° C. Also disclosed is a process of forming and shaping plasticized powder mixtures and a process for forming ceramic articles utilizing the binder system.

Abstract: The present invention includes a method for producing high-alumina bodies with superior chemical properties at reduced sintering temperatures. One form of the method includes the steps of providing an alumina powder precursor, adding about 2 wt. % magnesia powder precursor and about 2 wt. % titania powder precursor, mixing the resultant green powder precursor, pressing a green body from the green powder precursor, removing residual moisture and organic material from the green body, and firing the green body to about cone 13.

Abstract: A binder system for use in the formation of ceramic or other powder-formed greenware comprising a binder, a solvent for the binder, a surfactant, and a component that is non-solvent with respect to the binder and solvent. The non-solvent component exhibits a lower viscosity than the solvent when containing the binder and comprises at least a portion of an organic liquid having a 90% recovered distillation temperature of no greater than about 225° C. and more preferably less than 220° C. Also disclosed is a process of forming and shaping plasticized powder mixtures and a process for forming ceramic articles utilizing the binder system.

Abstract: An essentially non-slumping sprayable refractory castable composition that is applied without forms is disclosed comprising (a) a tempered, pumpable first component comprising (i) one hundred weight percent of a refractory composition comprising from about 60 to 90 weight percent of a refractory aggregate, from about 2 to 25 weight percent of an ultrafine refractory material having an average particle diameter size less than or equal to about 3 microns, from about 0.5 to 15 weight percent of a binder, and from about 0.05 to 2.

Abstract: A binder system for use in the formation of ceramic or other powder-formed greenware comprising a binder, a solvent for the binder, a surfactant, and a component that is non-solvent with respect to the binder and solvent. The non-solvent component exhibits a lower viscosity than the solvent when containing the binder and comprises at least a portion of a branched chain paraffin exhibiting a 90% recovered distillation temperature ranging between 205° C. to about 225° C. and a carbon chain length comprised predominantly of carbon chain distributions ranging from 12 to 14. Also disclosed is a process of forming and shaping plasticized powder mixtures and a process for forming ceramic articles utilizing the binder system.

Abstract: A pumpable ceramic composition is provided comprising an inorganic oxide, potassium phosphate, and an oxide coating material. Also provided is a method for preparing pumpable ceramic-based waste forms comprising selecting inorganic oxides based on solubility, surface area and morphology criteria; mixing the selected oxides with phosphate solution and waste to form a first mixture; combining an additive to the first mixture to create a second mixture; adding water to the second mixture to create a reactive mixture; homogenizing the reactive mixture; and allowing the reactive mixture to cure.

Abstract: This invention is directed to ceramic metal composite useful as a refractory and having improved abrasion, corrosion, and oxidation resistance. The ceramic metal composite of the present invention is comprised of ceramic refractory aggregate, metal particulate, and a nonaqueous binder wherein the ceramic refractory aggregate, metal particulate, and binder residuals react to form a three-dimensional ceramic-metal matrix. The ceramic-metal matrix is further stabilized by bonds between the metal particulate, reaction products of the metal particulate, and the ceramic refractory aggregate.

Abstract: Disclosed is an alumina-based sintered material comprising a magnesium component, a calcium component, a silicon component, and a lithium component, wherein the content of the lithium component in terms of oxide amount is from 0.002 to 0.04% by weight based on the alumina-based sintered material.

Abstract: Phosphates can be removed from a hydrocarbon stream by contacting said stream with a ceramic formed of a basic material which is insoluble in the hydrocarbon stream. A ceramic as used in this patent document is a solid solution formed by calcination of a compound. The removal of the organic acid is accomplished at temperatures ranging from 20.degree. C. to 400.degree. C., a preferred temperature is between 200.degree. C. and 370.degree. C. A hydrocarbon stream consists of C.sub.5 + hydrocarbons. The basic material can be made up of one or more alkaline earth oxides, alkaline earth compounds, alkaline metal compounds, group IIIA element compounds, group IVA element compounds, group VIA element compounds. Preferred alkaline earth oxides are sodium, magnesium, potassium, calcium, aluminum and silicon. The support for the basic material can be made from any inorganic oxide.

Abstract: Castable refractory for a slide gate plate is mainly formed of alumina raw material and amorphous carbon raw material of 2 to 15 wt %, and contains silicon carbide and/or boron carbide, the total content thereof being equal to 0.5 to 10 wt % (the content of boron carbide is equal to or less than 3 wt %, and when the content of boron carbide is less than 0.5 wt %, silicon carbide is set to 3 wt % or more), 2 to 10 wt % magnesia of 1 mm or less in particle size, 0.2 to 3 wt % silica fine powder of 5 micrometers or less in particle size, and 0.1 to 5 wt % salt of condensate of formalin and aromatic sulfonate.

Abstract: Plasticized inorganic powder batches comprising a cellulosic binder, water, and at least one inorganic powder exhibiting relatively high water affinity are compounded by combining the inorganic powder, prior to any contact with the water or cellulosic binder, with an organic surface treatment agent to decrease the water affinity thereof; subsequent mixing of the treated powder with the water and the cellulosic binder forms a plasticized inorganic powder batch with improved extrusion, molding, or other shaping characteristics.

Abstract: A pulverulent fiber-reinforced spray mix is disclosed in which about 0.02 to 0.3 wt. % of flexible, thermoset polymer fibers resistant to decomposition at a temperature up to about 400.degree. F. are added for each 100 wt. % of other solids in the mix to form a mix which both avoids formation of mat-like structures in the dry hopper of refractory spray apparatus and provides a sprayed lining that is resistant to cracking and peeling during dry-out and preheat. The invention also comprises sprayable compositions formed by admixing water with the mix.

Abstract: A colored refractory material for lining an instrument/apparatus used at a high temperature is formed by mixing a powder of a raw material containing ceramics with a coloring agent and kneading with a liquid using a binder. The refractory material is put in lining for a portion being in contact with a high temperature molten substance or being exposed to a high temperature atmosphere, and is dried by heating while adjusting a temperature and a heating time on the basis of color change on the surface of the refractory material.

Abstract: The disclosed invention provides a method of forming refractory linings for maintaining refractory linings against attack by corrosive materials such as those present in steel manufacture. The method entails spraying an aqueous mixture of a refractory composition that includes at least one refractory material onto the working surface of a refractory lining. Spraying is performed to provide one or more layers of the refractory composition on the refractory lining after each exposure of the lining to corrosive materials such as those incurred in steel manufacture.

Abstract: A grain-spacer for an abrasive bond containing abrasive grain comprising particles of interlocked and bonded plant fibers.

Abstract: The present invention discloses a low density basic refractory lining material with improved resistance to corrosion by molten slag and metal that is especially adapted for use as a disposable liner in molten metal containing vessels. This material incorporates hollow ceramic microspheres of alumina, silica or mixtures thereof, having diameters of between about 5 and 500 microns as a density reducing material. This material may also include a stiffening agent, a set retarding agent, a foaming agent to further reduce the density, a plasticizer, and a low temperature binder. The addition of the ceramic microspheres has been found to provide reduced open porosity, improving resistance to corrosion. Also, the invention relates to methods for applying the disposable lining and vessels which include the lining applied thereon.

Abstract: A method for dispersing ceramic materials in aqueous media is disclosed. The method uses water-soluble polymers as dispersants and may be used for dispersing various classes of ceramic materials, including oxide, carbide, and nitride ceramics. The method is useful for dispersing ceramic materials known to present difficulties in forming aqueous dispersions. The polymeric dispersant may be made using conventional polymerization techniques such as solution polymerization.

Abstract: The present invention pertains to the use of a finely divided magnesium oxide micropowder for preparing ceramic masses and moldings.

Abstract: A pelletizable gunning composition is provided which exhibits excellent flow characteristics, minimal release of dust, and excellent adhesion and resistance to slag. The gunning composition includes high density magnesium oxide as the primary component, and lesser quantities of powdered metal, refractory clay, binder and, preferably, graphite. The dry components are mixed together, and the binder is added and mixed, resulting in a composition that can be pelletized. After pelletizing, the composition can be coated with a dusting material to facilitate pellet flow and prevent pellet agglomeration.

Abstract: A method for improving the properties of ceramic green bodies is provided. In particular, ceramic green bodies having improved green strength are provided. Incorporating certain acid-containing polymers as binders at a level of at least about 1 to about 15, preferably at least about 3 to about 10 percent by weight based on the weight of ceramic particles improves the green strength of the resulting ceramic green bodies.

Abstract: A process for obtaining a synthetic refractory sand for use in steelmaking, said synthetic refractory sand being free-flowing, comprising at least 50% forsterite, having semi-angular and irregularly shaped grains, lenses and flat grains, a specific gravity of approximately 3 g/cm.sup.3, a void volume of less than approximately 50%, a coefficient of thermal expansion of approximately 1.09.times.10.sup.-5 and a fusion point of at least 1610.degree. C. including the steps of: (a) agglomerating a mixture comprising a particulate starting material selected from the group consisting of serpentine-containing asbestos tailings and an enstatite-containing product produced by calcining serpentine-containing asbestos tailings and from 10% to 25%, based on the total weight of mixture, of magnesium oxides or precursors of magnesium oxides with an aqueous binder solution to obtain agglomerates of said mixture; (b) calcining said agglomerates at a temperature of from 1200.degree. C. to 1500.degree. C.

Abstract: A dry vibratable substantially alkali free refractory composition is disclosed for use as a disposable liner wherein the combination of a powdered metal utilized as a high temperature binder and an organic material utilized as a low temperature binder obviates the use of alkali oxides which previously caused degradation of the permanent refractory liner materials upon which the disposable lining was placed. Low density materials such as expanded inorganic materials can be added to the disclosed compositions to decrease the density. The invention also relates to a method of providing a disposable lining in a vessel having a permanent refractory lining, and to the resulting vessel thereof.

Abstract: A composite socket of a joint endoprosthesis may be fashioned in which the inorganic component of the socket has apatite and/or wollastonite crystalline phases and additionally secondary crystalline phases providing improved hydrolysis stability. The inorganic mixture consists (in mass % proportions) of 31-34% CaO, 10-12% P.sub.2 O.sub.5, 43-46% SiO.sub.2, 3-5% Na.sub.2 O, 2-3% CaF.sub.2 and, beyond the 100% of the above components, also 0.5-11% Al.sub.2 O.sub.3 and/or Zr.sub.2 and Al.sub.2 O.sub.3 or TiO.sub.2 and ZrO.sub.2 or TiO.sub.2 and ZrO.sub.2 and Al.sub.2 O.sub.3, whereby the proportion of TiO.sub.2 lies between 0.5 and 5%. Essential to the invention, too, is a certain grain size distribution and radius of aperture between the ball and the socket. The result is non-wearing operation of the endoprosthesis.

Abstract: Carbon-containing carbon bonded refractory mixes and products made therefrom in which the refractory is a magnesite or high alumina aggregate and containing a silica-free elemental boron containing B-Mg-O alloy powder containing at least 95% B-Mg-O. and shapes made therefrom. The invention also involves the method of increasing the lining life of a metallurgical vessel utilizing unburned brick made from the above-noted mixes.

Abstract: The present invention discloses an alkali oxide free low density refractory material especially adapted for use as a disposable liner material for molten metal containing vessels. This material includes about 0.1 to about 2 weight percent of a stiffening agent, about 0.1 to about 2 weight percent of a set retarding agent, about 0.1 to 6 weight percent of density reducing materials, about 0.1 to about 5 weight percent of a plasticizer, up to about 2 weight percent of a secondary binder, and the balance of a refractory aggregate which is preferably MgO. The stiffening agent and set retarding agent are used in substantially the same amounts to provide the disclosed refractory material with increased resistance to slumping while, at the same time, allowing spraying apparatus residence times of up to 30-40 minutes without clogging. The composition includes less than about 0.

Abstract: Sprayable aqueous insulating liner compositions for metal casting vessels such as permanent refractory lined tundishes are disclosed that contain a water insoluble and hydration resistant particulate refractory grain containing MgO, organic binder and fibers, with the composition being substantially free of water soluble alkali and alkaline earth metal oxides that would migrate during drying with the water to degrade the permanent refractory lining.