And Chromium Compound Patents (Class 501/117)
  • Patent number: 9580768
    Abstract: The invention relates to a synthetic slag forming briquette encased in an aluminum shell. The briquette may include a deoxidizing agent, calcium oxide, calcium fluoride, calcium aluminate, magnesia, or dolomitic lime, or combinations thereof. The deoxidizing agent may include calcium carbide, powdered aluminum or magnesium, or combinations thereof. The aluminum shell may be formed from molten aluminum, or aluminum sheet or foil.
    Type: Grant
    Filed: April 17, 2014
    Date of Patent: February 28, 2017
    Assignee: METCAN INDUSTRIAL CORP.
    Inventor: Dean McCann
  • Patent number: 9174874
    Abstract: A refractory object can include at least 10 wt % Al2O3. Further, the refractory object may contain less than approximately 6 wt % SiO2 or may include a dopant that includes an oxide of Ti, Mg, Ta, Nb, or any combination thereof. In an embodiment, at least approximately 1% of the Al2O3 in the refractory object can be provided as reactive Al2O3. In another embodiment, the refractory object may have a density of at least approximately 3.55 g/cc, a corrosion rate of no greater than approximately 2.69 mm/year, or any combination of the foregoing. In a particular embodiment, the refractory object can be used to form an Al—Si—Mg glass sheet. In an embodiment, the refractory object may be formed by a process using a compound of Ti, Mg, Ta, Nb, or any combination thereof.
    Type: Grant
    Filed: March 30, 2012
    Date of Patent: November 3, 2015
    Assignee: SAINT-GOBAIN CERAMICS & PLASTICS, INC.
    Inventors: Olivier Citti, Andrea Kazmierczak
  • Publication number: 20140349833
    Abstract: The invention relates to a blend for the production of a sintered refractory material containing chromium oxide, a sintered refractory material containing chromium oxide, a method for the manufacture of a sintered refractory material containing chromium oxide and to a use of magnesium titanate.
    Type: Application
    Filed: April 24, 2013
    Publication date: November 27, 2014
    Inventors: Boro Djuricic, Roland Nilica, Klaus Santowski
  • Publication number: 20140171288
    Abstract: A cordierite sintered body and a member for semiconductor manufacturing apparatus are disclosed. The cordierite sintered body includes a crystal phase and an amorphous phase. The crystal phase includes a main crystal phase that essentially consists of cordierite crystal grains; and a sub crystal phase that includes sub crystal grains containing alumina, mullite or sapphirine. The amorphous phase contains calcium and is located at grain boundaries of the cordierite crystal grains and the sub crystal grains. A crystal phase proportion of the main crystal phase to the crystal phase (or total of the main crystal phase and the sub crystal phase) is 95% to 97.5% by mass or less. A crystal phase proportion of the sub crystal phase to the crystal phase is 2.5% to 5% by mass or less. The sintered body contains calcium by 0.4% to 0.6% by mass or less in terms of CaO.
    Type: Application
    Filed: February 22, 2012
    Publication date: June 19, 2014
    Applicant: KYOCERA CORPORATION
    Inventors: Kouki Okayama, Shuichi Iida, Shuichi Iida, Kouki Okayama, Toshiaki Shigecka
  • Publication number: 20120096822
    Abstract: Fused particles containing, by weight percent: more than 15% but less than 55% of Al2O3; more than 20% but less than 45% of TiO2; more than 3% but less than 30% of SiO2; less than 20%, in total, of at least one oxide selected from the group consisting of ZrO2, Ce2O3, and HfO2; less than 1% of MgO; and more than 1% but less than 15%, in total, of at least one selected from the group consisting of CaO, Na2O, K2O, SrO, B2O3, and BaO. Also, a ceramic product or material obtained by sintering the fused particles.
    Type: Application
    Filed: June 25, 2010
    Publication date: April 26, 2012
    Applicant: SAINT-GOBAIN CENTRE DE RECH. ET D'ETUDES EUROPEEN
    Inventor: Stephane Raffy
  • Publication number: 20100065977
    Abstract: In one aspect, the present invention provides a method of providing a filling material for use in connection with an opening in a container used in molten metal processing including: recovering used refractory bricks; crushing the used refractory bricks into particles; and covering the opening with the particles.
    Type: Application
    Filed: September 12, 2008
    Publication date: March 18, 2010
    Inventor: Joseph R. Quigley
  • Publication number: 20100040778
    Abstract: A treated refractory material includes a porous refractory material having one or more protective materials disposed within pores of the refractory material. Methods of preparing the treated refractory material are also provided. The treated refractory material provides protection from the penetration of slag and extends the service life of the refractory material.
    Type: Application
    Filed: August 14, 2008
    Publication date: February 18, 2010
    Applicant: General Electric Company
    Inventors: Roman Shuba, Wei Chen, Anthony Mark Thompson
  • Publication number: 20100004114
    Abstract: The invention relates to a fired refractory ceramic product. According to the invention, this generic term encompasses both shaped and unshaped products. Shaped products are ones which have a defined shape so that they can be manufactured in finished form on the premises of the manufacturer. Shaped products include: bricks, nozzles, tubes, stoppers, plates, etc. The term unshaped products includes ones which are usually produced by the user from a corresponding composition. They include bases for furnaces which are cast from a composition but also repair compositions, etc.
    Type: Application
    Filed: August 8, 2007
    Publication date: January 7, 2010
    Applicant: Refractory Intellectual Property GmbH & Co. KG
    Inventors: Boro Djuricic, Franz Reiterer
  • Publication number: 20090142590
    Abstract: A method includes contacting a transition metal oxide, a sintering additive, and a grain growth inhibitor additive to form a mixture. The transition metal oxide include particles that have an average diameter less than about 1 micrometer and sintering the mixture to a temperature profile that is sufficiently high that a sintered mass is formed from the mixture. The sintering includes at least one of a microwave sintering or a spark plasma sintering. The thermal profile is less than about 1050 degrees Celsius.
    Type: Application
    Filed: December 22, 2008
    Publication date: June 4, 2009
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Daniel Qi Tan, Darren Michael Stohr, Wei Zhang
  • Patent number: 7510991
    Abstract: The present invention is directed to a noise suppressor for electronic signals. The noise suppressor at least includes Aluminum Oxide (Al2O3) that is sintered under high temperature, resulting in ceramic Aluminum Oxide (Al2O3) for effectively absorbing or suppressing noise, and reshaping the waveform or filtering waveform glitch of the electronic signals.
    Type: Grant
    Filed: July 17, 2006
    Date of Patent: March 31, 2009
    Assignee: Y&L Technology Inc.
    Inventors: Cheng-Cheng Wu, Chien-Lung Chen, Cheng-Fu Wu
  • Publication number: 20080274870
    Abstract: The invention relates to a refractory ceramic product which comprises: a) ?93% by weight of at least one refractory basic component and b) ?7% by weight of at least one anticorrosive component from the group including: b1) transition metals, b2) compounds of transition metals with each other, b3) non-oxidic compounds of transition metals, b4) oxidic compounds of transition metals, b5) compounds of the transition metals with Ca, Ba, Sr.
    Type: Application
    Filed: May 10, 2006
    Publication date: November 6, 2008
    Applicant: REFRACTORY INTELLECTUAL PROPERTY GMBH & CO. KG
    Inventor: Robert Treimer
  • Patent number: 6987077
    Abstract: A fired spinel complex oxide is produced by firing a mixture containing a slag by-produced in chromium refining, a reducer, and a silica-containing material, and is essentially composed of: 29 to 40 percent by weight of Fe2O3; 15 to 20 percent by weight of Al2O3; 9 to 14 percent by weight of MgO; 0 to 4 percent by weight of Na2O; 9 to 17 percent by weight of Cr2O3; 14 to 20 percent by weight of SiO2; and 2 percent by weight or less of CaO. The fired spinel complex oxide shows a Cu—K? X-ray diffraction pattern in which the ratio (b/a) of the diffraction peak intensity of the silica-containing material (b) in the vicinity of 2?=26.7° to the {113} plane diffraction peak intensity (a) in the vicinity of 2?=36° is 0.1 or less.
    Type: Grant
    Filed: June 10, 2004
    Date of Patent: January 17, 2006
    Assignee: Nippon Chemical Industrial Co., Ltd.
    Inventors: Nobuo Takagi, Masami Tadasa
  • Patent number: 6982233
    Abstract: The invention relates to a fired refractory ceramic molded piece with a spinel matrix based on (Mg)2+ (Al, Cr)23+O4, in which coarser particles based on chromium corundum and/or corundum and coarser particles based on ZrO2 are present.
    Type: Grant
    Filed: November 8, 2002
    Date of Patent: January 3, 2006
    Assignee: Refractory Intellectual Property GmbH & Co.
    Inventors: Bernd Buchberger, Markus Horn, Roland Nilica
  • Publication number: 20040254058
    Abstract: A fired spinel complex oxide is produced by firing a mixture containing a slag by-produced in chromium refining, a reducer, and a silica-containing material, and is essentially composed of: 29 to 40 percent by weight of Fe2O3; 15 to 20 percent by weight of Al2O3; 9 to 14 percent by weight of MgO; 0 to 4 percent by weight of Na2O; 9 to 17 percent by weight of Cr2O3; 14 to 20 percent by weight of SiO2; and 2 percent by weight or less of CaO. The fired spinel complex oxide shows a Cu—K&agr; X-ray diffraction pattern in which the ratio (b/a) of the diffraction peak intensity of the silica-containing material (b) in the vicinity of 2&thgr;=26.7° to the {113} plane diffraction peak intensity (a) in the vicinity of 2&thgr;=36° is 0.1 or less.
    Type: Application
    Filed: June 10, 2004
    Publication date: December 16, 2004
    Applicant: NIPPON CHEMICAL INDUSTRIAL CO., LTD.
    Inventors: Nobuo Takagi, Masami Tadasa
  • Publication number: 20040142812
    Abstract: The invention relates to a fired refractory ceramic molded piece with a spinel matrix based on (Mg)2+ (Al, Cr)23+O4, in which coarser particles based on chromium corundum and/or corundum and coarser particles based on ZrO2 are present.
    Type: Application
    Filed: November 12, 2003
    Publication date: July 22, 2004
    Inventors: Bernd Buchberger, Markus Horn, Roland Nilica
  • Patent number: 6696388
    Abstract: A gel composition substantially contained within the pores of a solid material for use as a catalyst or as a catalyst support in dehydrogenation and dehydrocyclization processes.
    Type: Grant
    Filed: January 10, 2001
    Date of Patent: February 24, 2004
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Kostantinos Kourtakis, Leo E. Manzer
  • Patent number: 6548435
    Abstract: The invention relates to free-flowing refractory castable material and castings produced therefrom. Refractory nonbasic and basic refractory castable materials have been known for a long time. The traditional refractory castable materials have thixotropic properties and must be lined sing vibration technology. In the past, free-flowing refractory castable materials were solely based on alumina raw materials. Attempts to produce an aqueous, highly concentrated basic suspension which would Coma the basis of free-flowing refractory castable materials failed to meet the requirements in terms of theological properties and a low degree of to hydration of the MgO-based materials. It is the aim of the invention to provide the above-mentioned refractory castable material for the monolithic lining or repair of high-temperature equipment and for the production of refractory castings. This is achieved by providing a fine-grained and a mixed fine and coarse-grained alternative.
    Type: Grant
    Filed: August 30, 2000
    Date of Patent: April 15, 2003
    Inventor: Jerzy Bugajski
  • Patent number: 6475950
    Abstract: A chromium catalyst is disclosed for use in dehydrogenation and dehydrocyclization processes.
    Type: Grant
    Filed: March 15, 2001
    Date of Patent: November 5, 2002
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Kostantinos Kourtakis, Leo E. Manzer
  • Patent number: 6227127
    Abstract: A sintered material includes a polycrystalline substance of MgAl2O4 and/or Al2O3; and 3 to 90 weight percent of Cr2O3 and/or CeO2. Furnace material, furnace wall block, high temperature protection tube, and high temperature protecting member are made of such sintered material, and have higher heat resistance and corrosion resistance.
    Type: Grant
    Filed: April 27, 1999
    Date of Patent: May 8, 2001
    Assignee: Kyocera Corporation
    Inventors: Shinichi Yamaguchi, Yasuhiro Tanaka
  • Patent number: 6093366
    Abstract: The present invention provides a ceramic sintered body excellent in oxidation resistance under high temperatures and markedly superior to the conventional ceramic sintered body in the mechanical strength over a wide temperature range of between room temperature and 1,500.degree. C. The ceramic sintered body of the present invention comprises at least one ceramic crystal grain selected from the group consisting essentially of a monosilicate represented by the general formula RE.sub.2 SiO.sub.5, where RE denotes a IIIa group element including yttrium, and a disilicate represented by the general formula RE.sub.2 Si.sub.2 O.sub.7, where RE denotes a IIIa group element including yttrium, and at least one additional element selected from the group consisting of Al, Cr, Hf, Nb, Zr, Ti, V, Ta, Ca and Mg which is segregated in the boundaries of the ceramic crystal grains in an amount of 0.1 to 15% by weight of the sintered body in terms of the oxide thereof.
    Type: Grant
    Filed: November 5, 1998
    Date of Patent: July 25, 2000
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Masahiro Kato, Yasuhiro Goto, Takayuki Fukasawa, Toshiaki Mizutani
  • Patent number: 5656203
    Abstract: A conductive ceramic composition is disclosed which consists essentially of alumina, chromia, and magnesia, and is suitable for use as target electrodes in electrostatic fiber charging applications. Ceramics are disclosed which have exhibit volume resistivities of 10.sup.12 ohm-cm or less at 20.degree. C., and have excellent electrical stability and superior mechanical properties; and an electrostatic charging apparatus is disclosed which employs a ceramic electronic conductor having a volume resistivity of from about 1.times.10.sup.7 to 5.times.10.sup.10 ohm-cm and a hardness of at least 5 GPa.
    Type: Grant
    Filed: July 29, 1994
    Date of Patent: August 12, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Kurt Richard Mikeska
  • Patent number: 5629251
    Abstract: A ceramic coating-forming agent of an Mg-M.sup.3+ -O based two-component oxide solid solution capable of forming a ceramic coating excellent in heat resistance, adhesion to a substrate metal, electric insulation and the properties of low thermal expansion, at a low temperature, the agent containing an Mg-M.sup.3+ -O based two-component oxide solid solution of the formula (1),(Mg.sub.1-x M.sup.2+.sub.x).sub.1-y M.sup.3+.sub.y O (1)wherein M.sup.2+ is at least one divalent metal selected from the group consisting of Ca.sup.2+, Mn.sup.2+, Fe.sup.2+, Co.sup.2+, Ni.sup.2+, Cu.sup.2+ and Zn.sup.2+, M.sup.3+ is at least one trivalent metal selected from the group consisting of Al.sup.3+, Mn.sup.3+, Fe.sup.3+, Co.sup.3+, Ni.sup.3+, Ti.sup.3+, Bi.sup.3+ and Cr.sup.3+, x is a number in the range of 0.ltoreq.x<0.5 and y is a number in the range of 0<y<0.5, or an anionic oxide-dispersed Mg-M.sup.3+ -O based two-component oxide solid solution of the formula (2),(Mg.sub.1-x M.sup.2+.sub.x).sub.1-y M.sup.3+.sub.
    Type: Grant
    Filed: May 23, 1995
    Date of Patent: May 13, 1997
    Assignee: Kabushiki Kaisha Kaisui Kagaku Kankyujo
    Inventor: Shigeo Miyata
  • Patent number: 5609961
    Abstract: The single-layer high temperature coating according to the invention, which is applied in particular on a porous substrate, comprises a high silica glaze gel frit, alumina and an emissivity agent consisting of MoSi.sub.2 or Cr.sub.2 O.sub.3, and has the following composition by weight:gel frit: 45 to 55%;MoSi.sub.2 or Cr.sub.2 O.sub.3 : 25 to 50%;Al.sub.2 O.sub.3 : 5 to 20%.
    Type: Grant
    Filed: March 5, 1996
    Date of Patent: March 11, 1997
    Assignees: Aerospatiale Societe Nationale Industrielle VIAM-, All Russian Institut of Aviation Materials
    Inventors: Galina A. Solovjeva, Vladimir M. Tjurin, Stanislav S. Solntsev
  • Patent number: 5601853
    Abstract: A conductive ceramic composition is disclosed which consists essentially of alumina, chromia, and magnesia, and is suitable for use as target electrodes in electrostatic fiber charging applications. Ceramics are disclosed which have exhibit volume resistivities of 10.sup.12 ohm-cm or less at 20.degree. C., and have excellent electrical stability and superior mechanical properties; and an electrostatic charging apparatus is disclosed which employs a ceramic electronic conductor having a volume resistivity of from about 1.times.10.sup.7 to 5.times.10.sup.10 ohm-cm and a hardness of at least 5 GPa.
    Type: Grant
    Filed: March 7, 1995
    Date of Patent: February 11, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Thomas K. Bednarz, Kurt R. Mikeska
  • Patent number: 5595948
    Abstract: A refractory is disclosed which contains integrally sintered magnesia particles forming the skeleton of the refractory and a mineral phase of magnesium orthotitanate (Mg.sub.2 TiO.sub.4) formed between the magnesia particles, thus giving an increased erosion resistance. Preferably, the refractory comprises coarse magnesia particles having an average particle diameter of at least 1 mm or a mixture of coarse magnesia particles having an average particle diameter of at least 1 mm and medium magnesia particles having an average particle diameter of 1 to 0.15 mm and 5 to 50 wt. % of magnesium orthotitanate intervening between the magnesia particles. The refractory not only has an excellent durability in a basic atmosphere, but also has a high strength because of combination of the coarse or medium magnesia particles so that it does not tend to deform and has a high durability against thermal shock.
    Type: Grant
    Filed: June 16, 1995
    Date of Patent: January 21, 1997
    Assignee: Mitsubishi Materials Corporation
    Inventors: Etsuji Kimura, Kenichi Yamaguchi, Fumihiko Ogino, Susumu Okabe
  • Patent number: 5573987
    Abstract: The present invention pertains to a refractory ceramic mass, consisting of a pure magnesia component A and a component B, which consists of granules of pure magnesia, wherein the magnesia granules of component B have a ceating consisting of a refractory material whose granule size is fine compared with that of the magnesia granules and is chemically extensively inert with respect to the magnesia granule or reacts with the magnesia granule and/or itself consists of a plurality of components that are chemically reactive with one another.
    Type: Grant
    Filed: February 7, 1995
    Date of Patent: November 12, 1996
    Assignee: Veitsch-Radex Aktiengesellschaft fur feuerfeste Erzeugnisse
    Inventors: Harald Harmuth, Roland Heindl, Josef Deutsch
  • Patent number: 5559063
    Abstract: A refractory powder includes a filler, a binder, and a metal powder. This provides improved heat transfer in the refractory material during heating, and reduces the problem of explosive cracking and spalling so the refractory material can be burned out at substantially constant temperature, thereby saving considerable amounts of time and energy.
    Type: Grant
    Filed: July 12, 1995
    Date of Patent: September 24, 1996
    Assignee: Whip Mix Corporation
    Inventor: Atul C. Sarma
  • Patent number: 5401698
    Abstract: In ceramic welding processes, oxidizing gas and a mixture of refractory and fuel powders are projected against a surface and the fuel is burnt to generate sufficient heat that the refractory powder becomes at least partially melted or softened and a cohesive refractory weld mass is progressively built up against that surface. In order to reduce any tendency for the weld mass to include a low-grade refractory phase and thus promote the refractoriness of that weld mass, the fuel powder is present in a proportion of not more than 15% by weight of the total mixture and includes at least two metals selected from aluminum, magnesium, chromium and zirconium, in that at least the major part by weight of the refractory powder consists of one or more of magnesia, alumina and chromic oxide, and in that the molar proportions of silica and calcium oxide present in the refractory powder (if any) satisfy the following expression:molar concentration of SiO.sub.2 in %.ltoreq.0.2+molar concentration of CaO in %.
    Type: Grant
    Filed: June 8, 1993
    Date of Patent: March 28, 1995
    Assignees: Glaverbel, Fosbel International Ltd.
    Inventors: Leon P. Mottet, Charles M. Zvosec, Stephen D. Cherico, Alexandre Zivkovic, Guy van Marcke de Lummen, Jean Moreau, Pierre Robyn
  • Patent number: 5322827
    Abstract: A burned chrome-containing refractory and method which provides a refractory having less than 5 ppm total soluble chromium. Such product is obtained by adding to the starting mix less than 10 wt. % (often less than 3 wt. %) zirconia, silica, zircon, or molybdic oxide either individually or in combination.
    Type: Grant
    Filed: January 22, 1993
    Date of Patent: June 21, 1994
    Assignee: Indresco, Inc.
    Inventors: David J. Michael, Albert L. Renkey, Kenneth A. McGowan
  • Patent number: 5302564
    Abstract: Abrasive material with particularly high abrasive performance is obtained in that the ceramic material contains an additive of 0.01 to 15 percent by weight, preferably 0.1 to 3 percent by weight of a chromium compound.
    Type: Grant
    Filed: February 20, 1992
    Date of Patent: April 12, 1994
    Assignee: Treibacher Chemische Werke Aktiengesellschaft
    Inventors: Herwig Winkler, Peter Janz, Georg Gottschamel
  • Patent number: 5298469
    Abstract: A lanthanum chromite ceramic powder consisting essentially of 1 mol of LaCr.sub.1-x M.sub.x O.sub.3, where M is a divalent metal selected from the group of zinc, copper and mixtures thereof and x ranges from about 0.02 to 0.2, y mols of B.sub.2 O.sub.3, where y ranges from 0.0005 to 0.04, and z mols of La.sub.2 O.sub.3, where the ratio z/y ranges from 1 to 3, the powder is sintered to high density by firing a compact thereof at a temperature of about 1400.degree. C. in air or other atmosphere, and is particularly suited for use as interconnect material for solid oxide fuel cells.
    Type: Grant
    Filed: November 25, 1992
    Date of Patent: March 29, 1994
    Assignee: AlliedSignal Inc.
    Inventors: Stephen Haig, Beili L. Wu, Jean Yamanis
  • Patent number: 5286686
    Abstract: A sinter-reactive lanthanum chromite powder is prepared from the lanthanum chromite precursor LaCr.sub.1-x M.sub.x O.sub.3 (Adsorbate). The powder is crystalline, has the formula LaCr.sub.1-x M.sub.x O.sub.3, where M is selected from the group consisting of zinc, copper and mixtures thereof and x ranges from about 0.02 to 0.2, and sinters to densities higher than about 95% of theoretical density at temperature as low as 1400.degree. C. in oxidizing atmospheres. Sintering to such high density at temperatures in the vicinity of 1400.degree. C. makes the powder particularly suited for use as interconnect material for solid oxide fuel cells.
    Type: Grant
    Filed: November 25, 1992
    Date of Patent: February 15, 1994
    Assignee: Allied-Signal Inc.
    Inventors: Stephen Haig, Beili L. Wu, Jean Yamanis
  • Patent number: 5219807
    Abstract: A burned, high-purity refractory, specifically a chrome-alumina, alumina-chrome and picrochromite composition, which contains less than 5 ppm total soluble chromium. Such products are obtained by adding to the starting mix less than 5 wt. % (often less than 3 wt. %) zircon, titania, molybdic oxide, boric acid, carbon black, or silica.
    Type: Grant
    Filed: June 27, 1991
    Date of Patent: June 15, 1993
    Assignee: Indresco Inc.
    Inventors: Stanley R. Pavlica, Dwight S. Whittemore
  • Patent number: 5206193
    Abstract: High purity fused grain and refractory compositions that contain a high purity fused grain made up of 35 to 85 wt. % chromia, 5 to 55 wt. % alumina, and 5 to 45 wt. % magnesia. Burned refractory brick having such a chemistry was found to unexpectedly possess superior resistance to AOD and electric furnace slags.
    Type: Grant
    Filed: December 19, 1991
    Date of Patent: April 27, 1993
    Assignee: Indresco, Inc.
    Inventors: Albert L. Renkey, Stanley R. Pavlica
  • Patent number: 5185301
    Abstract: A sinter-reactive lanthanum chromite powder is prepared from the lanthanum chromite precursor LaCr.sub.1-x M.sub.x O.sub.3 (Adsorbate). The powder is crystalline, has the formula LaCr.sub.1-x M.sub.x O.sub.3, where M is magnesium or calcium and x ranges from about 0.03 to 0.3, and sinters to densities higher than about 95% of theoretical density at temperature as low as 1600.degree. C. in inert or reducing atmospheres. Sintering to such high density at temperatures in the vicinity of 1600.degree. C. makes the powder particularly suited for use as interconnect material for solid oxide fuel cells.
    Type: Grant
    Filed: January 21, 1992
    Date of Patent: February 9, 1993
    Assignee: Allied-Signal Inc.
    Inventors: Beili Li, Stephen Haig, Jean Yamanis
  • Patent number: 5169811
    Abstract: A lanthanum chromite ceramic powder mixture that consists essentially of 1 mol of LaCr.sub.1-x M.sub.x O.sub.3, where M is a divalent metal selected from the group consisting of magnesium, calcium and mixtures thereof and x ranges from 0.03 to 0.3; y mols of B.sub.2 O.sub.3, where y ranges from 0.005 to 0.04; and z mols of La.sub.2 O.sub.3, where the ratio z/y ranges from 1.1 to 3. The mixture is formed into powder compacts and sintered to near full density at temperatures as low as 1400.degree. C.
    Type: Grant
    Filed: January 22, 1991
    Date of Patent: December 8, 1992
    Assignee: Allied-Signal Inc.
    Inventors: Ned E. Cipollini, Beili L. Wu, Stephen Haig, Jean Yamanis
  • Patent number: 5096642
    Abstract: A process for producing a high density ceramic of perovskite represented by the formula:ABO.sub.
    Type: Grant
    Filed: December 15, 1987
    Date of Patent: March 17, 1992
    Assignee: National Institute for Research In Inorganic Materials
    Inventor: Shin-ichi Shirasaki
  • Patent number: 5028572
    Abstract: Fused cast refractory moldings having a random microstructure, which are near in size and configuration to the desired final shape, and process and apparatus used in their manufacture are described. The process includes rapid melting of the refractory material followed by controlled rapid cooling. Laminated composite fused cast refractories may be produced.
    Type: Grant
    Filed: November 23, 1988
    Date of Patent: July 2, 1991
    Assignee: The Carborundum Company
    Inventors: Jonathan J. Kim, Thomas A. Myles
  • Patent number: 5010046
    Abstract: An improved chromia-magnesia refractory product of co-fused chromia-magnesia grains bonded by an in situ formed chromia bond is prepared by substantially avoiding the presence of grains that will pass through a screen with openings of 150 microns. The resultant product exhibits improved resistance to silicieous materials such as are present in coal slags.
    Type: Grant
    Filed: March 5, 1990
    Date of Patent: April 23, 1991
    Assignee: Norton Company
    Inventors: Anthony K. Butkus, Scott D. Martin
  • Patent number: 5001092
    Abstract: A refractory composition is disclosed which consists essentially of sized refractory aggregate including at least 10%, based on the total weight of the composition, MgO containing grain having at least 50% MgO and passing a 5 mesh screen, from about 0.1 to about 1.5%, on the dehydrated basis, of chrome sulfate or sodium sulfate, from about 0.1 to about 1.5% of an organic acid or salt thereof; and up to about 1.1% of a plasticizer.
    Type: Grant
    Filed: December 2, 1988
    Date of Patent: March 19, 1991
    Assignee: Quigley Company Inc.
    Inventors: Lawrence J. Lake, Charles R. Rumpeltin, William R. Herberger
  • Patent number: 4946806
    Abstract: Oxidizable metallic particles having a grain size of 60 microns or less of the combination of zinc and magnesium used as heat sources in the flame spraying of refractory masses wherein the zinc magnesium form 5% or less by weight of the total mixture of oxidizable particles and refractory particles, and are used with oxidizable metallic silicon in an amount between 8 and 20% by weight, wherein one or more of silica, alumina, magnesite, chromia and/or zirconia, or silicon carbide form the incombustible refractory particles.
    Type: Grant
    Filed: November 16, 1988
    Date of Patent: August 7, 1990
    Assignee: Sudamet, Ltd.
    Inventor: David C. Willard
  • Patent number: 4902654
    Abstract: Mixed lanthanide-magnesium aluminates and lasers using monocrystals of these aluminates.These lasers in particular incorporate two flash lamps for longitudinally pumping a monocrystalline rod of a magnetoplumbite-aluminate emitting visible or infrared light, amplified between a mirror, a polarizing prism being used for passing to the outside of the laser the amplified light beam. The aluminate is of formula:(La.sub.1-x Tr.sub.x).sub.1-y-v Mg.sub.1-z-t Al.sub.11-u+y+2z/3 Cr.sub.u O.sub.19-t-3v/3.in which Tr represents a) at least one single trivalent substance chosen from among lanthanides, Y.sup.3+, Sc.sup.3+, or b) at least one pair of lanthanides formed from a divalent element and a trivalent element, while retaining the electrical neutrality by adding aluminium or oxygen deficiencies, or any combination of (a) and (b); x is a number such that 0.ltoreq.x<1; y and v are numbers such that 0.ltoreq.y+v.ltoreq.0.4; z and t are numbers such that 0.ltoreq.z+t<1, provided that when z=t=0, y+v is .noteq.
    Type: Grant
    Filed: June 16, 1987
    Date of Patent: February 20, 1990
    Assignees: Commissariat a l'Energie Atomique, Centre National de la Recherche Scientifique (CNRS)
    Inventors: Jean-Jacques Aubert, Anne-Marie Lejus, Bruno Viana, Daniel Vivien
  • Patent number: 4780434
    Abstract: A refractory composition which is suitable for forming a sliding gate to be used at the bottom of a ladle or tundish is provided. The refractory composition comprises 10 to 30 parts by weight of an alumina-magnesia spinel material containing 40 to 70% by weight of Al.sub.2 O.sub.3, 25 to 60% by weight of MgO and 10% or less of impurities, and 70 to 90 parts by weight of a magnesia material containing at least 90% by weight of MgO, wherein the composition contains 10 to 25% by weight of Al.sub.2 O.sub.3 and 75 to 90% by weight of MgO. 1 to 10 parts by weight of Al.sub.2 O.sub.3 material may be further added together with the alumina-magnesia spinel material and the magnesia material, to form the refractory composition.
    Type: Grant
    Filed: December 22, 1986
    Date of Patent: October 25, 1988
    Assignee: Toshiba Ceramics, Co., Ltd.
    Inventors: Takashi Watanabe, Takumi Nishio, Yoshihisa Kato, Kazuhide Kawai, Satoshi Doro, Takafumi Nishibe, Takahiro Fukaya
  • Patent number: 4775648
    Abstract: Heavy ceramic shaped material with a content of at least one of the components magnesia, fired dolomite, chromite and spinel, characterized by a microcrack system substantially homogeneously distributed in the shaped material structure, as well as process for producing such a heavy ceramic shaped material and the use thereof.
    Type: Grant
    Filed: August 1, 1986
    Date of Patent: October 4, 1988
    Inventors: Peter Bartha, Guido Weibel
  • Patent number: 4751070
    Abstract: Ultrafine particles of ceramic or metallic material are obtained at low temperatures from a nitrate source capable of endothermic decomposition by molecularly combining under a nitrogen atmosphere the nitrate source with an inorganic reducing fuel compound, such as hydrazine, to provide a chemical precursor for the ceramic or metallic material and then exothermically decomposing the precursor in a controlled atmosphere by heating to a temperature up to about 200.degree. C. below the endothermic decomposition temperature of the nitrate source. The nitrate source is a metal nitrate or a mixture of nitrate salts. Ferrite particles are recovered when the nitrate source is a mixture of nitrate salts containing ferric nitrate in a 2:1 molar ratio with at least one additional metal nitrate.
    Type: Grant
    Filed: April 15, 1986
    Date of Patent: June 14, 1988
    Assignee: Martin Marietta Corporation
    Inventor: Vencatesh R. Pai Verneker
  • Patent number: 4657878
    Abstract: A novel method of making a refractory material is disclosed comprising the steps of providing an electrical arc metal furnace, charging that furnace with a charge of refractory oxide, and selecting voltage, amperage and electrode spacings to create novel "hum and scum" melt conditions. This hum and scum condition is maintained until said charge is substantially melted. The described technique is particularly useful for melting magnesia chrome materials to produce fusion cast refractory products which are highly reduced and quite dense. The elaboration of this product requires higher energy input per pound concurrent with an increased consumption of reducing materials compared with standard preparation conditions. The resulting product exhibits higher oxidation weight gains, higher densities, lower porosities, high cold crush strengths, more thermal shock resistance, and better corrosion-erosion resistance than similar magnesia chrome refractory products fused using prior "arc and bark" processes.
    Type: Grant
    Filed: February 8, 1985
    Date of Patent: April 14, 1987
    Assignee: Corhart Refractories
    Inventors: Thomas A. Clishem, Leonard W. Pokallus
  • Patent number: 4647547
    Abstract: A high chromia refractory composite has been developed with improved thermal shock resistance and containing about 5-30 wt. % of unstabilized ZrO.sub.2 having a temperature-dependent phase change resulting in large expansion mismatch between the ZrO.sub.2 and the chromia matrix which causes microcracks to form during cooling in the high chromia matrix. The particle size preferably is primarily between about 0.6-5 microns and particularly below about 3 microns with an average size in the order of 1.2-1.8 microns.
    Type: Grant
    Filed: December 10, 1985
    Date of Patent: March 3, 1987
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Jitendra P. Singh, Jawana J. James, John J. Picciolo
  • Patent number: 4574119
    Abstract: A refractory brick made from a size graded batch comprising 20-30 weight percent magnesite containing less than 0.8 weight percent silica, and the balance a chrome ore. The chrome ore includes oxides of chromium, aluminum and iron wherein the ratio between the oxides of chromium and the oxides of aluminum and iron is greater than 2 to 1. The silica content of the chrome ore is less than 2.7 weight percent, the iron oxide content is less than 17 weight percent, and the chrome ore to magnesite ratio is between 2.33 to 4 to 1.
    Type: Grant
    Filed: June 11, 1984
    Date of Patent: March 4, 1986
    Assignee: Dresser Industries, Inc.
    Inventors: John D. Perry, David J. Michael
  • Patent number: 4545568
    Abstract: Unfired refractory structural member in the form of a plate for the expendable lining of metallurgical vessels, especially for tundishes used in continuous steel casting, and comprising magnesia sinter and possibly olivine with a grading of 30-45% by weight under 0.09 mm, and 55-70% by weight 0.09 to 4 mm, including 20-40% by weight over 1 mm; cork or granulated ceramic fibers as a pore-forming material; an inorganic binder; and possibly other additives. This refractory structural member has good strength, a small ignition loss, a low content of volatile hydrogen-containing substances, a favorable peeling behavior, and good resistance to slag and molten steel.
    Type: Grant
    Filed: February 17, 1984
    Date of Patent: October 8, 1985
    Assignee: Didier-Werke AG
    Inventors: Hans Rothfuss, Gunter Wieland, Peter Schreiter
  • Patent number: 4522926
    Abstract: A refractory composition for use in contact with molten aluminum alloys containing a refractory aggregate, a binder and 9Al.sub.2 O.sub.3.2B.sub.2 O.sub.3. The aluminum borate may be of the type produced as a by-product in the production of ferro-boron alloys and known as aluminum boron slag.
    Type: Grant
    Filed: March 10, 1983
    Date of Patent: June 11, 1985
    Assignee: Combustion Engineering, Inc.
    Inventor: Frank T. Felice