Radiation Color Change Responsive Patents (Class 501/13)
  • Patent number: 11254603
    Abstract: A glass-ceramic, includes a silicate-containing glass comprising a first portion and a second portion. A plurality of crystalline precipitates comprising at least one of W and Mo. The crystalline precipitates are distributed within at least one of the first and second portions of the silicate-containing glass. The glass-ceramic comprises a difference in absorbance between the first and second portions of 0.04 optical density (OD)/mm or greater over a wavelength range of from 400 nm to 1500 nm.
    Type: Grant
    Filed: January 31, 2020
    Date of Patent: February 22, 2022
    Assignee: Corning Incorporated
    Inventors: Matthew John Dejneka, Jesse Kohl
  • Patent number: 11067828
    Abstract: The present invention relates to dichromic mirrored patterns on fashion eyewear that exhibits variable opacity on the exterior of a photochromic lens in response to changing lighting conditions wherein the pattern can go from virtually transparent to opaque. The dichromic mirror pattern(s) can be coated in multi-color pattern sections and can be coated so that some pattern sections have variable opacity and other pattern sections have a fixed high opacity. The effect can also be produced on an optical film to be applied to many optical surfaces.
    Type: Grant
    Filed: October 18, 2020
    Date of Patent: July 20, 2021
    Inventors: Jerrold Scott Pine, Brandon T Michaels
  • Patent number: 10829408
    Abstract: A glass-ceramic includes SiO2 from about 50 mol % to about 80 mol %, Al2O3 from about 0.3 mol % to about 15 mol %, B2O3 from about 5 mol % to about 40 mol %, WO3 from about 2 mol % to about 15 mol %, and R2O from about 0 mol % to about 15 mol %, wherein R2O is one or more of Li2O, Na2O, K2O, Rb2O and Cs2O. A difference in the amount of the R2O and the Al2O3 ranges from about ?12 mol % to about 2.5 mol %.
    Type: Grant
    Filed: November 14, 2018
    Date of Patent: November 10, 2020
    Assignee: Corning Incorporated
    Inventors: Matthew John Dejneka, Jesse Kohl
  • Patent number: 10336647
    Abstract: A UV-blocking glass material having precipitated cuprous halide crystals and including by weight percent, on an oxide basis: from 30 wt % to 65 wt % SiO2; from 12 wt % to 25 wt % B2O3; from 3 wt % to 10 wt % Al2O3; from 0 wt % to 7 wt % Na2O; from 0 wt % to 10 wt % K2O; from 0 wt % to 5 wt % Li2O; from 0.5 wt % to 10 wt % Ho2O3; from 0.25 wt % to 1.50 wt % CuO; and from 0.5 wt % to 5.0 wt % halogens.
    Type: Grant
    Filed: December 13, 2017
    Date of Patent: July 2, 2019
    Assignee: Corning Incorporated
    Inventor: Yves Andre Henri Brocheton
  • Patent number: 10106454
    Abstract: The present invention relates to optical glasses, in particular special short flint glasses (KZFS) and optical elements and components, which comprise these glasses, and use thereof and a method for producing such optical glasses. The optical glasses of the present invention are characterized by a pronounced short flint character and additionally by an excellent transmission and chemical resistance and workability. At that, the glasses of the invention can stand out due to lower costs of production caused by lower costs of raw materials and lower processing costs, due to their crystallization properties that can be handled also in smaller melting aggregates, and due to good environmental compatibility.
    Type: Grant
    Filed: November 18, 2016
    Date of Patent: October 23, 2018
    Assignee: SCHOTT AG
    Inventors: Simone Ritter, Bianca Schreder, Ute Woelfel, Stefanie Hansen
  • Patent number: 10093575
    Abstract: A method for continuous production of photo-sensitive glass bodies, glass bodies, and structured glass articles are provided. The glass bodies include a glass having Si4+, at least one crystal-agonist, at least one crystal-antagonist, and at least one pair of nucleating agents. The glass may be used in a method for structuring of glass. The glass bodies may be structured and/or unstructured and used in different applications such as in components or as components in micro-technology, in micro-reaction-technology, in electronic packaging, for micro-fluidic components, in or as FED spacer, for bio-technology (for example titer plates), as interposer, and in or as three-dimensional structurable antennae.
    Type: Grant
    Filed: May 18, 2016
    Date of Patent: October 9, 2018
    Assignee: SCHOTT AG
    Inventors: Lothar Niessner, Martin Feichtinger, Carsten Renz, Bianca Schreder, Sean Qian, Junming Xue
  • Patent number: 9938182
    Abstract: Disclosed herein are ultraviolet absorbing glasses. The glasses can be strengthened by a chemical tempering process and maintain good mechanical and optical properties while having a reduced thickness compared to conventional glasses. The ultraviolet absorbing glasses can include coloring agents and can be formed into ophthalmic lenses. Methods of making and using the ultraviolet absorbing glasses are also described.
    Type: Grant
    Filed: February 15, 2016
    Date of Patent: April 10, 2018
    Assignee: Corning Incorporated
    Inventor: Yves Andre Henri Brocheton
  • Publication number: 20150099130
    Abstract: Borosilicate glasses are disclosed having (in weight %) 66-76% SiO2, 0-8% Al2O3, 10-18% B2O3, 0-4% Li2O, 0-12% Na2O, 0-12% K2O, 1-1.5% Ag, 1.5-2.5% Cl? and 0.01-0.06% of a summed amount of CuO and NiO, wherein the glass composition is bleachable upon exposure to ultraviolet irradiation from a stable state color or shade to a lighter color or shade. Such reverse photochromic borosilicate glass compositions may be thermally darkenable. The borosilicate glasses may be strengthened via ion-exchange strengthening treatment. The borosilicate glasses may retain their reverse photochromic and thermally darkenable properties even after ion-exchange strengthening treatment.
    Type: Application
    Filed: October 7, 2014
    Publication date: April 9, 2015
    Inventors: John Christopher Mauro, Lynn Marie Thirion
  • Patent number: 8236716
    Abstract: The present invention relates to photochromic benzopyranobenzopyrans with additional fusion and to the use thereof in plastics of all types, in particular for ophthalmic purposes. The compounds according to the invention are photochromic benzopyran compounds which can also be regarded as derived from 9-oxa-9,10-dihydrophenanthrene.
    Type: Grant
    Filed: August 8, 2008
    Date of Patent: August 7, 2012
    Assignee: Rodenstock GmbH
    Inventors: Manfred Melzig, Yven Rohlfing, Udo Weigand
  • Patent number: 8183170
    Abstract: Disclosed are CuX-containing, Nd2O3-containing, UV-absorbing and contrast-enhancing glasses and article comprising the same. The glass has improved UV-absorption and color enhancing capabilities compared to glasses described in the prior art. The glass can be used in sunglass lenses and light filters of information displays.
    Type: Grant
    Filed: October 11, 2007
    Date of Patent: May 22, 2012
    Assignee: Corning Incorporated
    Inventor: Yves Andre Henri Brocheton
  • Publication number: 20110291436
    Abstract: A blue colored, infrared and ultraviolet absorbing glass composition uses a standard soda-lime-silica glass base composition and additionally iron, cobalt, and additional colorants selected from the group of Er2O3, Cr2O3, CuO, NiO, TiO2, Nd2O3 and combinations thereof. The glass of the present invention has a luminous transmittance of up to 60 percent, a dominant wavelength in the range of 480 to 489 nanometers and an excitation purity of at least 8 percent at a thickness of 0.160 inches (4.06 millimeters). The glass composition can form transparent glass panels that have varying limited LTA from one another as panel sets for mounting in automobiles.
    Type: Application
    Filed: May 27, 2010
    Publication date: December 1, 2011
    Applicant: PPG INDUSTRIES OHIO, INC.
    Inventors: Larry J. Shelestak, Mehran Arbab
  • Publication number: 20110201489
    Abstract: The present invention relates to photochromic benzopyranobenzopyrans with additional fusion and to the use thereof in plastics of all types, in particular for ophthalmic purposes. The compounds according to the invention are photochromic benzopyran compounds which can also be regarded as derived from 9-oxa-9,10-dihydrophenanthrene.
    Type: Application
    Filed: August 8, 2008
    Publication date: August 18, 2011
    Inventors: Manfred Melzig, Yven Rohlfing, Udo Weigand
  • Patent number: 7951733
    Abstract: The present invention provides a blue-violet light blocking glass containing copper (I) halide fine particles that satisfactorily transmits light having a wavelength of 450 nm to 600 nm and sharply blocks light having a wavelength shorter than 450 nm. Specifically, the present invention provides a blue-violet light blocking glass containing a copper (I) halide and silver; for example, 20 to 85% by weight of SiO2; 2 to 75% by weight of B2O3; not more than 10% by weight of Al2O3; 2 to 30% by weight of at least one member selected from the group consisting of Li2O, Na2O, K2O, Rb2O and Cs2O; 1 to 15% by weight of at least one member selected from the group consisting of MgO, CaO, SrO, BaO and ZnO; not more than 10% by weight of at least one member selected from the group consisting of PbO, Nb2O5, ZrO2, La2O3, Y2O3, Ta2O3 and Gd2O3; not more than 5% by weight of at least one member selected from the group consisting of Sb2O3 and As2O3; not more than 5% by weight of SnO2; 0.
    Type: Grant
    Filed: November 15, 2006
    Date of Patent: May 31, 2011
    Assignees: Isuzu Glass Co., Ltd., National Institute of Advanced Industrial Science and Technology
    Inventors: Naoto Yamashita, Kazuhisa Kimura, Tatsuya Suetsugu, Toshihiko Einishi, Kohei Kadono
  • Patent number: 7829489
    Abstract: The present invention describes a composition, method and article for a photomachinable glass having a coefficient of thermal expansion from less than 6×10?6/° C. in the temperature range of 0° C. to 300° C. The photomachinable glass composition is a low expansion glass having an amorphous glass phase and crystalline phases selected from the group consisting of spudomene and lithium disilicate.
    Type: Grant
    Filed: August 31, 2007
    Date of Patent: November 9, 2010
    Assignee: Corning Incorporated
    Inventors: Nicholas Francis Borrelli, Kathryn L Goetschius, David Lathrop Morse, Charlene Marie Smith
  • Patent number: 7799711
    Abstract: The invention is directed to photomachinable glass compositions having a controllable or tunable photosensitivity, and to a method for making such compositions. The compositions of the invention contain titania (TiO2) in an amount in the range of greater than 0.01 wt. % to 2 wt. % added to any known photomachinable glass composition. In one embodiment the TiO2 in an amount in the range of greater than 0.01 wt. % to 1 wt. %. An example of a photomachinable glass of the invention is one having a composition having, in weight percent (wt. %) of 65-80% SiO2, 15-20% Li2O, 1-4% Na2O, 1-4% K2O, 2-10% Al2O3, 0-3% ZnO, 0-0.15% Sb2O3, 0-0.015% CeO2, 0-0.001% Au, 0-0.015% Ag and >0.01% to 2% TiO2, and the sum of Au+Ag is greater than zero. In particular embodiment the TiO2 is in the range of >0.01% to 1%.
    Type: Grant
    Filed: August 31, 2007
    Date of Patent: September 21, 2010
    Assignee: Corning Incorporated
    Inventors: Nicholas Francis Borrelli, Kathryn L Goetschius, Charlene Marie Smith
  • Publication number: 20100216624
    Abstract: A glass composition for lamps includes the following by weight percent: SiO2: 60-75 wt %; CeO2+Ce2O3: 0.01-5.2 wt %; SnO+SnO2: 0.01-5.2 wt %; Al2O3: 0.5-6 wt %; B2O3: 0-5 wt %; Li2O+Na2O+K2O: 13-20 wt %; MgO: 0.5-5 wt %; CaO: 1-10 wt %; SrO: 0-10 wt %; BaO: 0-10 wt %; ZnO: 0-10 wt %; Fe2O3+FeO: 0-0.2 wt %; and TiO2: 0-1 wt %. The glass composition for lamps that contains no lead or antimony achieves high ultraviolet screening capacity, ensuring fewer occurrences of initial coloring and ultraviolet ray caused coloring of glass.
    Type: Application
    Filed: August 7, 2006
    Publication date: August 26, 2010
    Inventors: Ryousuke Sawa, Junko Abe, Tomoko Atagi, Masanobu Itou, Tomoko Akai, Masaru Yamashita
  • Publication number: 20100016141
    Abstract: The present invention relates to an apparatus and a method for dyeing glass and, more particularly, an apparatus and a method, by which both surfaces of hot sheet-like glass may be dyed simultaneously and/or the surface containing tin residues of the sheet glass may be dyed to have a different colour than the surface without tin residues. The apparatus of the invention may be used for dyeing both sheet glass and utility glass, such as glass beakers.
    Type: Application
    Filed: October 22, 2007
    Publication date: January 21, 2010
    Applicant: BENEQ OY
    Inventors: Markku Rajala, Jussi Wright, Joe Pimenoff, Kai Asikkala, Jari Sinkko
  • Patent number: 7648656
    Abstract: The invention is directed to a silver-containing polarizing boroaluminosilicate glass composition that has been doped with a noble metal selected from the group consisting of Pt, Pd, Os, Ir, Rh and Ru, including mixtures thereof, to nucleate and precipitate silver ions to silver metal without the need for a reducing atmosphere step. The invention is further directed to a method for making the glass composition of the invention. Using the composition and method of the invention, one can prepare a glass having a selected null transmission range.
    Type: Grant
    Filed: November 6, 2008
    Date of Patent: January 19, 2010
    Assignee: Corning Incorporated
    Inventors: Nicholas Francis Borrelli, George Bigelow Hares, David John McEnroe, Joseph Francis Schroeder, III
  • Patent number: 7618908
    Abstract: The invention is directed to a method for preparing visible light optical polarizers using a non-halide silver salt and any glass composition that the non-halide silver salts is soluble, provided that the glass composition, including the silver salt, was a halide content that is, on a molar basis, 10% or less than the silver content, on a molar basis, of the glass composition. The silver containing glass is hydrogen reduced prior to stretching to form an optical polarizer. The invention enables one to form a visible light polarizer having a polarizing layer thickness in the range 10-40 ?m in which the silver particles have a surround index sufficiently removed from the blue polarizer region to allow good contrast.
    Type: Grant
    Filed: December 20, 2005
    Date of Patent: November 17, 2009
    Assignee: Corning Incorporated
    Inventors: Nicholas Francis Borrelli, David John McEnroe, Joseph Francis Schroeder, III
  • Patent number: 7482296
    Abstract: The invention is directed to an aluminoborosilicate glass containing alkali metals for the production of optical components with refractive index gradients which are generated by ion exchange of monovalent metal ions in a base glass comprising at least silicon oxide, boron oxide, aluminum oxide and an alkali metal oxide, particularly for the production of gradient index lenses (GRIN lenses).
    Type: Grant
    Filed: December 17, 2004
    Date of Patent: January 27, 2009
    Assignee: Grintech GmbH
    Inventors: Bernhard Messerschmidt, Christian Ruessel, Sandra Hornschuh, Torsten Possner, Ulf Possner
  • Patent number: 7468148
    Abstract: The invention is directed to a silver-containing polarizing boroaluminosilicate glass composition that has been doped with a noble metal selected from the group consisting of Pt, Pd, Os, Ir, Rh and Ru, including mixtures thereof, to nucleate and precipitate silver ions to silver metal without the need for a reducing atmosphere step. The invention is further directed to a method for making the glass composition of the invention. Using the composition and method of the invention, one can prepare a glass having a selected null transmission range.
    Type: Grant
    Filed: October 24, 2005
    Date of Patent: December 23, 2008
    Assignee: Corning Incorporated
    Inventors: Nicholas Francis Borrelli, George Bigelow Hares, David John McEnroe, Joseph Francis Schroeder, III
  • Patent number: 7288495
    Abstract: The present invention provides an alkali alumino-silicate Na—F-containing glass material and a method of making the alkali alumino-silicate Na—F-containing glass material, with the glass material capable of being made photosensitive and thus formed into optical elements at wavelengths ranging between about 240 to 350 nm, and more particularly at the standard 248 nm wavelength of excimer lasers. Also disclosed is optical element wherein a refractive index pattern formed in the alumino-silicate Na—F containing glass material, the refractive index pattern including regions of high refractive index and regions of low refractive index, the difference between the refractive indices of the high refractive index regions and the low refractive index regions being at least 4×10?5 at a wavelength of 633 nm.
    Type: Grant
    Filed: December 20, 2004
    Date of Patent: October 30, 2007
    Assignee: Corning Incorporated
    Inventors: Joeseph F Schroeder, Nicholas F Borrelli, George B Hares
  • Patent number: 6967249
    Abstract: Specific photochromic 3H-naphtho[2,1-b]-pyran compounds useful with various types of synthetic resin materials to form photochromic articles, especially ophthalmic lenses, and photochromic articles formed with such compounds. The compounds of the invention have especially long-wave absorption maxima in the open form thereof and enable violet to blue tints to be obtained when used in photochromic articles.
    Type: Grant
    Filed: July 2, 2004
    Date of Patent: November 22, 2005
    Assignee: Rodenstock GmbH
    Inventors: Claudia Mann, Manfred Melzig, Udo Weigand
  • Patent number: 6914024
    Abstract: In one aspect, the invention provides glass beads and optical devices comprising the glass beads. In other aspects, the invention provides methods of making said glass beads and rapid glass screening methods that use glass beads. Glass beads of the invention comprise greater than 80 weight percent silica, active rare earth dopant, and modifying dopant. In another embodiment the glass beads comprise greater than 80 weight percent silica and at least 5 weight percent germania. In another embodiment, glass beads comprise and from about 20 to about 90 anion mole percent of non-oxide anion.
    Type: Grant
    Filed: April 30, 2004
    Date of Patent: July 5, 2005
    Assignee: 3M Innovative Properties Company
    Inventor: Mark T. Anderson
  • Patent number: 6887808
    Abstract: Polarized glass articles having a wavelength range that is broadened for high contrast-ratio applications. A method that imparts to a glass article a high contrast ratio of at least 40 dB for use as dichroic glass polarizers over a wavelength range of 880 nm to 1,690 nm while keeping a high transmission value. The method comprises the step of heating the glass article at a temperature ranging from 400 to 450° C. in a reducing atmosphere for a period of time ranging from 12 to 30 hours. Preferably, the reducing atmosphere is hydrogen at atmospheric pressure.
    Type: Grant
    Filed: October 3, 2003
    Date of Patent: May 3, 2005
    Assignee: Corning Incorporated
    Inventor: Kenjiro Hasui
  • Patent number: 6844277
    Abstract: The present invention relates generally to UV (ultraviolet) photosensitive bulk glass, and particularly to batch meltable alkali boro-alumino-silicate glasses. The photosensitive bulk glass of the invention exhibits photosensitivity to UV wavelengths below 300 nm. The photosensitivity of the alkali boro-alumino-silicate bulk glass to UV wavelengths below 300 nm provide for the making of refractive index patterns in the glass. With a radiation source below 300 nm, such a laser, refractive index patterns are formed in the glass. The inventive photosensitive optical refractive index pattern forming bulk glass allows for the formation of patterns in glass and devices which utilize such patterned glass.
    Type: Grant
    Filed: March 15, 2002
    Date of Patent: January 18, 2005
    Assignee: Corning Incorporated
    Inventors: Nicholas F. Borrelli, George B. Hares, Charlene M. Smith
  • Patent number: 6828262
    Abstract: The present invention relates generally to UV (ultraviolet) photosensitive bulk glass, and particularly to batch meltable alkali boro-alumino-silicate and germanosilicate glasses. The photosensitive bulk glass of the invention exhibits photosensitivity to UV wavelengths below 300 nm. The photosensitivity of the alkali boro-alumino-silicate and germanosilicate bulk glasses to UV wavelengths below 300 nm provide for the making of refractive index patterns in the glass. With a radiation source below 300 nm, such a laser, refractive index patterns are formed in the glass. The inventive photosensitive optical refractive index pattern forming bulk glass allows for the formation of patterns in glass and devices which utilize such patterned glass.
    Type: Grant
    Filed: June 28, 2002
    Date of Patent: December 7, 2004
    Assignee: Corning Incorporated
    Inventors: Nicholas F. Borrelli, George B. Hares, Charlene M. Smith
  • Patent number: 6777359
    Abstract: A polarizing glass comprising geometrically anisotropic particles dispersed in an oriented manner in at least the surface of a glass base body. The glass base body is denoted by the weight percentages of 50-65 percent SiO2, 15-22 percent B2O3, 0-4 percent Al2O3, 2-8 percent ZrO2, 6 percent <Al2O3+ZrO2<12 percent, 6-16 percent R2O (where R denotes at least one from among Li, Na, and K), 0-3 percent Li2O, 0-9 percent Na2O, 4-16 percent K2O, Li2O+Na2O<K2O, 0-7 percent BaO and/or SrO, and 0-3 percent TiO2. The glass base body comprises per 100 weight percent of essentially the above composition at least 0.15-1.0 percent Ag and at least the chemical equivalent to Ag of Cl and/or Br; and the geometrically anisotropic silver particles are metallic Ag particles. The polarizing glass is employed in optical products such as optical isolators.
    Type: Grant
    Filed: January 2, 2002
    Date of Patent: August 17, 2004
    Assignee: Hoya Corporation
    Inventors: Toshiharu Yamashita, Yoshitaka Yoneda
  • Patent number: 6762875
    Abstract: A method for creating refractive index changes in a substrate is provided by irradiating the substrate with infrared (IR) or visible light radiation. Ultra-violet (UV) radiation is generated in the substrate responsive to the IR or visible light radiation such that the change in the refractive index of the substrate is generated responsive to the UV radiation. Preferably, the substrate comprises a glass doped with rare earth ions.
    Type: Grant
    Filed: February 7, 2002
    Date of Patent: July 13, 2004
    Assignee: Corning Incorporated
    Inventor: Bryce N. Samson
  • Publication number: 20040067834
    Abstract: Polarized glass articles having a wavelength range that is broadened for high contrast-ratio applications. A method that imparts to a glass article a high contrast ratio of at least 40 dB for use as dichroic glass polarizers over a wavelength range of 880 nm to 1,690 nm while keeping a high transmission value. The method comprises the step of heating the glass article at a temperature ranging from 400 to 450° C. in a reducing atmosphere for a period of time ranging from 12 to 30 hours. Preferably, the reducing atmosphere is hydrogen at atmospheric pressure.
    Type: Application
    Filed: October 3, 2003
    Publication date: April 8, 2004
    Inventor: Kenjiro Hasui
  • Patent number: 6608215
    Abstract: Novel naphthopyrans having an oxygen-containing heterocyclic group F annelated on the f, i, j, or k side of the naphthopyran ring. These naphthopyrans may have the formula (I) presented below: These compounds (I) have interesting photochromic properties. Various organic host materials that contain such compounds are described. Articles such as ophthalmic lenses or other plastic transparencies that incorporate the novel naphthopyran compounds or combinations are enabled.
    Type: Grant
    Filed: September 20, 2001
    Date of Patent: August 19, 2003
    Assignee: Vision-Ease Lens, Inc.
    Inventor: Xuzhi Qin
  • Patent number: 6606885
    Abstract: A glass polarizer and a method of making the polarizer, the polarizer being produced from an R2O—Al2O3—B2O3—SiO2 glass containing limited amounts of ZrO2 and TiO2, and having a silver halide liquidus temperature and a rutile liquidus temperature, both temperatures being not over 995° C.
    Type: Grant
    Filed: October 9, 2001
    Date of Patent: August 19, 2003
    Assignee: Corning Incorporated
    Inventors: Michael D. Harris, Thomas G. Havens, William E. Horsfall, David J. Kerko
  • Patent number: 6562523
    Abstract: A narrowly defined range of zinc silicate glass compositions is found to produce High Energy Beam Sensitive-glass (HEBS-glass) that possesses the essential properties of a true gray level mask which is necessary for the fabrication of general three dimensional microstructures with one optical exposure in a conventional photolithographic process. The essential properties are (1) A mask pattern or image is grainiless even when observed under optical microscope at 1000× or at higher magnifications. (2) The HEBS-glass is insensitive and/or inert to photons in the spectral ranges employed in photolithographic processes, and is also insensitive and/or inert to visible spectral range of light so that a HEBS-glass mask blank and a HEBS-glass mask are permanently stable under room lighting conditions. (3) The HEBS-glass is sufficiently sensitive to electron beam exposure, so that the cost of making a mask using an e-beam writer is affordable for many applications.
    Type: Grant
    Filed: February 18, 2000
    Date of Patent: May 13, 2003
    Assignee: Canyon Materials, Inc.
    Inventors: Che-Kuang Wu, Laurie Ann Wu
  • Patent number: 6344424
    Abstract: An insulating package is provided with an insulating base having a bottom plate and frame body, electrodes led from the inside to the outside of the insulating base, and a metal cap to seal the frame body. The metal cap is adhered to the frame body by low melting point glass. This low melting point glass contains at least one selected from a group consisting of Al, Ni, Ag, BaTiO3, NiCr, TiB, and TiO2, and inside the glass, spherical particles with diameters of 10 &mgr;m or more are dispersed.
    Type: Grant
    Filed: May 15, 2000
    Date of Patent: February 5, 2002
    Assignee: NEC Corporation
    Inventors: Yoshihiro Goto, Eigo Kishi, Katuya Terai, Yoshinobu Natsuhara
  • Patent number: 6342459
    Abstract: The present invention relates to photochromic 2H-naphtho[1,2-b]pyrans as well as their use in synthetic resins of all types, especially for ophthalmic purposes. In particular, the present invention relates to photochromic naphthopyran compounds, for which a further ring system is bonded to the f side of the naphthopyran. The inventive photochromic dyes generally have the general formula (I) wherein n, R1, R2, R3, X, B and B′ are defined as in claim 1. The inventive compounds are distinguished by good darkening and decolorizing properties and a very good service life.
    Type: Grant
    Filed: May 18, 2000
    Date of Patent: January 29, 2002
    Assignee: Optische Werke G. Rodenstock
    Inventors: Manfred Melzig, Claudia Mann, Udo Weigand
  • Patent number: 6312811
    Abstract: The photochromic compounds of the invention correspond to the formula: in which Th2 represents a bithienyl group in one of the positions 5 to 10 of the naphthenic ring system system, R1 denotes a bithienyl or trithienyl group and R2 denotes a bithienyl, trithienyl, aryl, naphthyl, thienyl, furyl, pyrrolyl or N-alkylpyrrolyl group.
    Type: Grant
    Filed: July 8, 1999
    Date of Patent: November 6, 2001
    Assignee: Essilor International Compagnie Generale d'Optique
    Inventors: Michel Frigoli, Nicole Rebiere-Galy, Corinne Moustrou, Andre Samat, Robert Guglielmetti
  • Patent number: 6228787
    Abstract: This invention relates to fluorescent photosensitive glasses and a process for the production thereof. The fluorescent photosensitive glasses according to the present invention employ silicate or phosphate glass compositions including minor amounts of one or more fluorescent agents (e.g., ytterbium (Yb), samarium (Sm), europium (Eu)) and one or more photosensitive agents (e.g., erbium (Er), thulium (Tm), praseodymium (Pr), ytterbium (Yb), holmium (Ho), samarium (Sm), cerium (Ce), dysprosium (Dy), terbium (Tb), neodymium (Nd)). The inventive fluorescent photosensitive glass can be used in photographic applications, florescent displays and computer memories.
    Type: Grant
    Filed: July 27, 1998
    Date of Patent: May 8, 2001
    Inventor: Eugen Pavel
  • Patent number: 6221480
    Abstract: A polarizing glass article, and a method of making the article, that exhibits a broad band of high contrast polarizing properties in the infrared region of the radiation spectrum, that is phase-separated by precipitating silver, copper, or copper-cadmium halide crystals in the glass within a size range of 200-5000 Å, and that contains elongated silver, copper, or copper-cadmium metal particles formed on or in the halide crystals, and having an elongated aspect ratio of at least 2:1, the article having a contrast ratio of at least 100,000 over a range of at least 300 nm.
    Type: Grant
    Filed: June 2, 1999
    Date of Patent: April 24, 2001
    Assignee: Corning Incorporated
    Inventors: Nicholas F. Borrelli, Larry G. Mann, George N. Whitbred, III
  • Patent number: 6197711
    Abstract: An ophthalmic, protective, filter lens, and a method of producing such lens, the lens having a ratio of Z and Y tristimulus values between 0.25-0.40, a dominant wavelength between 570-580 nm. on a color mixture diagram, a sharp transmission drop between 450-500 nm. and a transmission not over 30% between 400-450 nm.
    Type: Grant
    Filed: April 26, 1999
    Date of Patent: March 6, 2001
    Assignee: Corning S.A.
    Inventors: Thomas G. Havens, David J. Kerko, Brent M. Wedding
  • Patent number: 6177371
    Abstract: A fixed tint, photochromic glasses and sunglass lenses produced therefrom. The glasses have R2O—Al2O3—B2O3—SiO2 base compositions, contain silver chloride and bromide contents as photochromic constituents and 0.27-0.38% and 0.035-0.060%, both by weight percent, as glass colorants, the NiO:Co3O4 ratio being at least 6:1.
    Type: Grant
    Filed: April 9, 1999
    Date of Patent: January 23, 2001
    Assignee: Corning S.A.
    Inventors: Thomas G. Havens, David J. Kerko, Brent M. Wedding
  • Patent number: 6165922
    Abstract: A fixed tint, photochromic glasses and sunglass lenses produced therefrom. The glasses have R.sub.2 O--Al.sub.2 O.sub.3 --B.sub.2 O.sub.3 --SiO.sub.2 base compositions, contain silver chloride and bromide contents as photochromic constituents and 0.22-0.38% NiO and 0.034-0.060% CoO, both by weight percent, as glass colorants, the NiO:CoO ratio being in the range of 5.5-7.2:1.
    Type: Grant
    Filed: September 8, 1999
    Date of Patent: December 26, 2000
    Assignee: Corning S.A.
    Inventors: Thomas G. Havens, David J. Kerko, Brent M. Wedding
  • Patent number: 6162749
    Abstract: The invention concerns photochromic glasses with improved properties having the following composition, in wt. %: SiO.sub.2 : 51-66, B.sub.2 O.sub.3 : 15-23, Al.sub.2 O.sub.3 : 3-10, ZrO.sub.2 : 2.5-11, TiO.sub.2 : 0-1, Li.sub.2 O: 3-7, Na.sub.2 O: 0-8, K.sub.2 O: 2-9, Ag: 0.080-0.30, CuO>0.0020-0.0130, Cl: 0.1-0.6, Br 0.040-0.3, MgO: 0-3, CaO: 0-3, SrO: 0-3, BaO: 0-3, Nb.sub.2 O.sub.5 : 0-1, La.sub.2 O.sub.3 : 0-8, Y.sub.2 O.sub.3 : 0-8, with 0.2<Ag/(Cl+Br).ltoreq.0.5, Br/(Cl+Br)>0.15, 0.5.ltoreq.La.sub.2 O.sub.3 +Y.sub.2 O.sub.3.ltoreq.8, TiO.sub.2 +Nb.sub.2 O.sub.5 .ltoreq.1.2, 10.ltoreq.Al.sub.2 O.sub.3 +ZrO.sub.2 .ltoreq.17, MgO+CaO+SrO+BaO.ltoreq.6. Use for the production of ophthalmic lenses.
    Type: Grant
    Filed: July 29, 1999
    Date of Patent: December 19, 2000
    Assignee: Corning S.A.
    Inventors: Yves Andre Henri Brocheton, Michel Prassas
  • Patent number: 6156684
    Abstract: In a light polarization control element using a stress-optical coefficient glass, the stress-optical coefficient glass is substantially composed of a phosphorous acid glass containing 20 to 60 percent by weight of P.sub.2 O.sub.5 and 40 to 73 percent by weight of BaO and PbO.
    Type: Grant
    Filed: June 16, 1998
    Date of Patent: December 5, 2000
    Assignee: Hoya Corporation
    Inventors: Kouichi Sato, Kazuo Tachiwana
  • Patent number: 6132643
    Abstract: This invention relates to fluorescent photosensitive vitroceramics and the process for the production thereof. The fluorescent photosensitive vitroceramics according to the present invention employ fluorosilicate glass compositions including various photosensitizing metals and rare earths which impart photosensitive properties and fluorescent properties to the vitroceramic. After irradiation, the photosensitive agents control the precipitation of fine fluoride crystals which also contain rare earth ions. These rare earth ions can be made to fluoresce in a controlled manner. The inventive fluorescent photosensitive vitroceramics can be used in photographic applications, florescent displays and computer memories.
    Type: Grant
    Filed: July 27, 1998
    Date of Patent: October 17, 2000
    Inventor: Eugen Pavel
  • Patent number: 6089042
    Abstract: Method of making polarizing glass having integral polarizing and non-polarizing regions disclosed. The method involves applying a protective glass/frit material capable of blocking reducing gas to the surface of the glass to form a desired pattern, exposing the glass to a reducing gas atmosphere to render unprotected glass polarizing, and removing the protective glass/frit material to reveal underlying non-polarizing regions.
    Type: Grant
    Filed: June 8, 1999
    Date of Patent: July 18, 2000
    Assignee: Corning Inc.
    Inventors: Sherry Jeanne Gill, Ahmad Sarhangi
  • Patent number: 6037283
    Abstract: A photochromic glass lens and method of producing such lens, the lens having a plus power and a composition consisting essentially of:______________________________________ SiO.sub.2 54-58% Ag 0.20-0.33% B.sub.2 O.sub.3 18-22% Cl 0.30-0.50% Al.sub.2 O.sub.3 7-8% Br 0.04-0.14% Li.sub.2 O 3.75-4.5% CuO 0.007-0.012% Na.sub.2 O 0-1% PbO 0-0.08% TiO.sub.2 0-2% Sb.sub.2 O.sub.3 0-0.20% ZrO.sub.2 2-4.5% K.sub.2 O 5.5-7.5% ______________________________________and wherein the mole ratio of Li.sub.2 O:Na.sub.2 O is =>9:1.
    Type: Grant
    Filed: August 18, 1998
    Date of Patent: March 14, 2000
    Assignee: Corning Incorporated
    Inventors: Thomas G. Havens, David J. Kerko
  • Patent number: 5958596
    Abstract: A process in which a dye film is cast, the film is peeled off from the substrate and stretched monoaxially, the stretched film is applied to a glass film, and the resultant laminate is conditioned at elevated temperature gives composite materials which are highly suitable for the production of optoelectronic instruments.
    Type: Grant
    Filed: February 18, 1997
    Date of Patent: September 28, 1999
    Assignee: Bayer Aktiengesellschaft
    Inventors: Uwe Claussen, Hanns Peter Muller, Walter Uerdingen
  • Patent number: 5932498
    Abstract: A chemically-machinable glass-magnet composition comprising a photosensitive chemically machinable glass having a magnetic material in admit therewith, wherein the photosensitive chemically machinable glass is formed of SiO.sub.2 --Li.sub.2 O--Al.sub.2 O.sub.3 containing photosensitive materials selected from silver, gold and copper and a cerium dioxide sensitizer; and the magnetic material is a Ni-Cu-Zn ferrite.
    Type: Grant
    Filed: March 24, 1997
    Date of Patent: August 3, 1999
    Assignee: International Business Machines Corporation
    Inventors: John Beeteson, Andrew Knox, Christopher Carlo Pietrzak
  • Patent number: 5698020
    Abstract: The invention relates to dental materials which contain a photochromic material such as for example a photochromic dye, a photochromic glass, a photochromic ceramic and/or a photochromic glass ceramic and which can be visually distinguished from natural tooth material after irradiating with light, but which assume their original colour again after a certain period has expired.
    Type: Grant
    Filed: May 16, 1996
    Date of Patent: December 16, 1997
    Assignee: Ivoclar AG
    Inventors: Ulrich Salz, Peter Burtscher, Volker Rheinberger, Heinz Durr
  • Patent number: 5639701
    Abstract: A photochromic glass having colorant incorporated in the glass composition to impart a permanent tint, and having its chromaticity point shifted from the blue-green side toward the red side of the white point in the CIE chromaticity coordinate system, and a method of producing such article by heating the article for a sufficient time, and at a sufficient temperature, in a dilute, hydrogen-containing atmosphere to so move the chromaticity point.
    Type: Grant
    Filed: January 9, 1996
    Date of Patent: June 17, 1997
    Assignee: Corning Incorporated
    Inventors: David J. Kerko, Brent M. Wedding