Chromium Compound Containing Patents (Class 501/132)
  • Patent number: 8658552
    Abstract: A high-chromia refractory, comprised of: about 60% to about 99% by weight of refractory grain, wherein the refractory grain is comprised of grains having about 20% to 100% by weight chromia; 0% to about 35% by weight of a fine particulate, the fine particulate selected from chromic oxide, alumina, ceria, yttria, lanthanum oxide, or combinations thereof; and about 1% to about 8% of a liquid resin or pitch.
    Type: Grant
    Filed: December 23, 2009
    Date of Patent: February 25, 2014
    Assignee: Harbison-Walker Refractories Company
    Inventors: H. David Prior, Glenn H. McIntyre, III
  • Patent number: 8609563
    Abstract: A sintered product presenting a mean chemical composition such that, in percentages by weight based on the oxides: Cr2O3: 72.0%-98.9% 2%<Al2O3?20% 0.1%?TiO2?6.0% ZrO2<4.0% SiO2?0.9%.
    Type: Grant
    Filed: April 15, 2010
    Date of Patent: December 17, 2013
    Assignee: Saint-Gobain Centre de Recherches et d'Etudes Europeen
    Inventors: Olivier Citti, Julien Fourcade
  • Publication number: 20130183531
    Abstract: An article which includes a structure of a ceramic material that has a composition SiOxMzCy, where Si is silicon, O is oxygen, M is at least one metal and C is carbon and wherein x<2, y>0 and z<1 and x and z are non-zero.
    Type: Application
    Filed: January 18, 2012
    Publication date: July 18, 2013
    Inventors: Wayde R. Schmidt, Paul Sheedy, Tania Bhatia Kashyap, Daniel G. Goberman, Xia Tang
  • Patent number: 8481152
    Abstract: A treated refractory material includes a porous refractory material having one or more protective materials disposed within pores of the refractory material. Methods of preparing the treated refractory material are also provided. The treated refractory material provides protection from the penetration of slag and extends the service life of the refractory material.
    Type: Grant
    Filed: August 14, 2008
    Date of Patent: July 9, 2013
    Assignee: General Electric Company
    Inventors: Roman Shuba, Wei Chen, Anthony Mark Thompson
  • Patent number: 8362869
    Abstract: A thermistor based on a composition having the general formula (I): Re2-x-yCraMnbMcEyOz wherein Re is a rare earth metal or a mixture of two or more rare earth metals, M is a metal selected from the group consisting of nickel, cobalt, copper, magnesium and mixtures thereof, E is a metal selected from the group consisting of calcium, strontium, barium and mixtures thereof, x is the sum of a+b+c and is a number between 0.1 and 1, and the relative ratio of the molar fractions a, b and c is in an area bounded by points A, B, C and D in a ternary diagram, wherein point A is, if y<0.006, at (Cr=0.00, Mn=0.93+10?y, M=0.07?10?y), and, if y?0.006, at (Cr=0?00, Mn=0.99, M=0.01), point B is, if y<0.006, at (Cr=0.83, Mn=0.10+10?y, M=0.07?10?y), and, if y?0.006, at (Cr=0.83, Mn=0.16, M=0.01), point C is at (Cr=0.50, Mn=0.10, M=0.40) and point D is at (Cr=0.00, Mn=0.51, M=0.49), y is a number between 0 and 0.5?x, and z is a number between 2.5 and 3.5.
    Type: Grant
    Filed: December 19, 2008
    Date of Patent: January 29, 2013
    Assignee: Vishay Resistors Belgium BVBA
    Inventors: Véronique Poulain, Sophie Schuurman, André Lannoo, Frans F. Westendorp
  • Patent number: 8263514
    Abstract: The invention provides a sintered product presenting an apparent density greater than 4.00 g/cm3 and having the following mean chemical composition, as a percentage by weight based on the oxides and for a total of 100%: Al2O2: complement to 100% 16%?Cr2O3?29.5% TiO2 in a quantity such that the Cr2O3/TiO2 weight ratio is greater than 16 and less than 35, other species: ?1% Application as an electrode bushing block.
    Type: Grant
    Filed: July 10, 2008
    Date of Patent: September 11, 2012
    Assignee: D'Etudes Europeen
    Inventors: Olivier Citti, Julien Fourcade
  • Patent number: 8173564
    Abstract: A gasifier comprising an interior wall on which a layer is applied or an interior wall protected by an assembly of blocks, said layer or said blocks having at least one region of a sintered material containing: i) at least 25% by weight of chromium oxide Cr2O3; and ii) at least 1% by weight of zirconium oxide, wherein at least 20% by weight of said zirconium oxide ZrO2 is stabilized in the cubic and/or quadratic form.
    Type: Grant
    Filed: July 2, 2008
    Date of Patent: May 8, 2012
    Assignee: Saint-Gobain Centre de Recherches et d'Etudes Europeen
    Inventors: Thibault Pierre Paul Champion, Christian Claude His, Franceline Marguerite Louise Villermaux
  • Patent number: 8034469
    Abstract: There is described a two-Level Layer System with Pyrochlore Phase and Oxides. Besides a good thermal insulation property, thermal insulation layer systems must also have a long lifetime of the thermal insulation layer. The layer system has a layer sequence of a metallic bonding layer, an inner ceramic layer and an outer ceramic layer, which are specially matched to one another.
    Type: Grant
    Filed: May 6, 2008
    Date of Patent: October 11, 2011
    Assignee: Siemens Aktiengesellschaft
    Inventor: Ramesh Subramanian
  • Publication number: 20110152059
    Abstract: A high-chromia refractory, comprised of: about 60% to about 99% by weight of refractory grain, wherein the refractory grain is comprised of grains having about 20% to 100% by weight chromia; 0% to about 35% by weight of a fine particulate, the fine particulate selected from chromic oxide, alumina, ceria, yttria, lanthanum oxide, or combinations thereof; and about 1% to about 8% of a liquid resin or pitch.
    Type: Application
    Filed: December 23, 2009
    Publication date: June 23, 2011
    Inventors: H. David Prior, Glenn H. McIntyre, III
  • Patent number: 7754633
    Abstract: A refractory composition comprising at least 50 weight percent chromic oxide (Cr2O3), as measured by chemical analysis. The composition includes fused chromia-containing grain, powdered chromic oxide and sintered chromia-containing grain. The fused chromia-containing grain and the sintered chromia-containing grain comprise at least 50 weight percent chromia oxide, as measured by chemical analysis.
    Type: Grant
    Filed: July 22, 2008
    Date of Patent: July 13, 2010
    Assignee: Harbison-Walker Reeractories Company
    Inventors: H. David Prior, Howard Winkelbauer, Viktor Fischer
  • Publication number: 20100040778
    Abstract: A treated refractory material includes a porous refractory material having one or more protective materials disposed within pores of the refractory material. Methods of preparing the treated refractory material are also provided. The treated refractory material provides protection from the penetration of slag and extends the service life of the refractory material.
    Type: Application
    Filed: August 14, 2008
    Publication date: February 18, 2010
    Applicant: General Electric Company
    Inventors: Roman Shuba, Wei Chen, Anthony Mark Thompson
  • Publication number: 20100019419
    Abstract: A refractory composition comprising at least 50 weight percent chromic oxide (Cr2O3), as measured by chemical analysis. The composition includes fused chromia-containing grain, powdered chromic oxide and sintered chromia-containing grain. The fused chromia-containing grain and the sintered chromia-containing grain comprise at least 50 weight percent chromia oxide, as measured by chemical analysis.
    Type: Application
    Filed: July 22, 2008
    Publication date: January 28, 2010
    Inventors: H. David Prior, Howard Winkelbauer, Viktor Fischer
  • Publication number: 20100004114
    Abstract: The invention relates to a fired refractory ceramic product. According to the invention, this generic term encompasses both shaped and unshaped products. Shaped products are ones which have a defined shape so that they can be manufactured in finished form on the premises of the manufacturer. Shaped products include: bricks, nozzles, tubes, stoppers, plates, etc. The term unshaped products includes ones which are usually produced by the user from a corresponding composition. They include bases for furnaces which are cast from a composition but also repair compositions, etc.
    Type: Application
    Filed: August 8, 2007
    Publication date: January 7, 2010
    Applicant: Refractory Intellectual Property GmbH & Co. KG
    Inventors: Boro Djuricic, Franz Reiterer
  • Publication number: 20090253570
    Abstract: A composition includes particles of an inorganic component A and particles of an inorganic component B which together can form a eutectic system and react at least partly with one another at a sintering temperature, resulting in formation of at least one ternary chemical compound of the spinel type. The composition can be applied to high-temperature-stable ceramic layers, coatings and shaped bodies and also their production, their uses and compositions for producing them.
    Type: Application
    Filed: August 22, 2006
    Publication date: October 8, 2009
    Inventors: Martin Jost, Ralph Nonninger
  • Publication number: 20090142590
    Abstract: A method includes contacting a transition metal oxide, a sintering additive, and a grain growth inhibitor additive to form a mixture. The transition metal oxide include particles that have an average diameter less than about 1 micrometer and sintering the mixture to a temperature profile that is sufficiently high that a sintered mass is formed from the mixture. The sintering includes at least one of a microwave sintering or a spark plasma sintering. The thermal profile is less than about 1050 degrees Celsius.
    Type: Application
    Filed: December 22, 2008
    Publication date: June 4, 2009
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Daniel Qi Tan, Darren Michael Stohr, Wei Zhang
  • Patent number: 7510991
    Abstract: The present invention is directed to a noise suppressor for electronic signals. The noise suppressor at least includes Aluminum Oxide (Al2O3) that is sintered under high temperature, resulting in ceramic Aluminum Oxide (Al2O3) for effectively absorbing or suppressing noise, and reshaping the waveform or filtering waveform glitch of the electronic signals.
    Type: Grant
    Filed: July 17, 2006
    Date of Patent: March 31, 2009
    Assignee: Y&L Technology Inc.
    Inventors: Cheng-Cheng Wu, Chien-Lung Chen, Cheng-Fu Wu
  • Publication number: 20080293559
    Abstract: The instant invention relates to a process and plant for the transformation of dangerous wastes containing chromium six as contaminant into non dangerous wastes that can be stored without special care and will be degraded in the environment without time limit. The process basically consists of milling, extracting chromium six in liquid phase and under controlled conditions of stirring, time and temperature, proceeding then, through reduction, to transform the chromium six in chromium three and then precipitating as chromium trioxide, through gasification. The solid resulting from the transformation process can be used as raw material for the manufacturing of firebricks or eventually for the manufacturing of bricks used in the building industry through a process not included in the instant description.
    Type: Application
    Filed: February 7, 2006
    Publication date: November 27, 2008
    Applicant: CROMOTECNICA MEXICO
    Inventor: Francisco Garcia Fernandez
  • Publication number: 20080260952
    Abstract: The present invention relates to a green ceramic coating composition, the composition comprises nano-sized particles dispersed within a carrier medium together with preformed particles. The composition optionally comprises an infiltration medium.
    Type: Application
    Filed: January 21, 2005
    Publication date: October 23, 2008
    Applicant: THE UNIVERSITY OF MANCHESTER
    Inventors: Ping Xiao, Xin Wang
  • Patent number: 7151067
    Abstract: A porous catalyst layer containing mixed conducting oxide having substantially a perovskite structure and containing a first element selected from Co and Fe, and a second element selected from In, Sn and Y arranged in the B site in the perovskite structure is contiguous to a second surface (1a) of a selective oxygen-permeable dense continuous layer (1) containing mixed conducting oxide. A porous intermediate catalyst layer (3) containing mixed conducting oxide and at least one of Co, Fe, Mn and Pd is contiguous to a first layer (1b) of the dense continuous layer (1). A porous reactive catalyst layer (4) provided with a metal catalyst selected from at least one of Ni, Co, Ru, Rh, Pt, Pd, Ir and Re and a support is continguous to the porous intermediate catalyst layer (3) in a manner to sandwich between the dense continuous layer (1) and the porous reactive catalyst layer (4).
    Type: Grant
    Filed: October 11, 2002
    Date of Patent: December 19, 2006
    Assignees: Nippon Steel Corporation, Teikoku Oil Co., Ltd.
    Inventors: Tadashi Sakon, Wataru Ito, Hitoshi Dohnomae, Toru Nagai, Hideki Kurimura, Shouichi Kaganoi, Youhei Suzuki, Takashi Ito
  • Patent number: 7012037
    Abstract: Particles particularly useful for thermal spraying a wear resistant coating on to a substrate comprise an essentially single phase crystalline structure comprising from 45 to 99% by weight of chromia and 55 to 1% by weight of alpha alumina.
    Type: Grant
    Filed: April 8, 2002
    Date of Patent: March 14, 2006
    Assignee: Saint-Gobain Ceramics and Plastics, Inc.
    Inventors: Sung H. Yu, Howard Wallar
  • Patent number: 6987077
    Abstract: A fired spinel complex oxide is produced by firing a mixture containing a slag by-produced in chromium refining, a reducer, and a silica-containing material, and is essentially composed of: 29 to 40 percent by weight of Fe2O3; 15 to 20 percent by weight of Al2O3; 9 to 14 percent by weight of MgO; 0 to 4 percent by weight of Na2O; 9 to 17 percent by weight of Cr2O3; 14 to 20 percent by weight of SiO2; and 2 percent by weight or less of CaO. The fired spinel complex oxide shows a Cu—K? X-ray diffraction pattern in which the ratio (b/a) of the diffraction peak intensity of the silica-containing material (b) in the vicinity of 2?=26.7° to the {113} plane diffraction peak intensity (a) in the vicinity of 2?=36° is 0.1 or less.
    Type: Grant
    Filed: June 10, 2004
    Date of Patent: January 17, 2006
    Assignee: Nippon Chemical Industrial Co., Ltd.
    Inventors: Nobuo Takagi, Masami Tadasa
  • Patent number: 6846763
    Abstract: A refractory repair batch material includes a refractory, in particular a basic resistor component in granule form and a binder system. The binder system contains at least one hard bitumen component in granule form, at least one ignitable metal powder and at least one combustible mineral oil.
    Type: Grant
    Filed: November 18, 2003
    Date of Patent: January 25, 2005
    Assignee: Refratechnik Holding GmbH
    Inventors: Helge Jansen, Heinrich Grosse Daldrup
  • Patent number: 6774076
    Abstract: Particles particularly useful for thermal spraying a wear resistant coating on to a substrate comprise an essentially single phase crystalline structure comprising from 45 to 100% by weight of chromia and from 0 to 55% by weight of alpha alumina.
    Type: Grant
    Filed: September 3, 2002
    Date of Patent: August 10, 2004
    Assignee: Saint-Gobain Ceramics & Plastics, Inc.
    Inventors: Sung H. Yu, Howard Wallar
  • Patent number: 6723674
    Abstract: A microstructured or nanostructured multi-component ceramic comprises (a) a major ceramic phase comprising a ceramic oxide composite; (b) a ceramic oxide additive; and (c) a rare earth ceramic oxide additive, wherein the total of the additives (b) and (c) comprise from about 0.1 weight percent to less than 50 weight percent based on the total weight the multi-component ceramic composite. In another embodiment, a microstructured or nanostructured multi-component ceramic comprises (a) a major ceramic oxide phase comprising a ceramic oxide composite; and either (b) a ceramic oxide additive or (c) a rare earth ceramic oxide additive, wherein amount of the additive (b) or (c) comprises from about 0.1 weight percent to less than 50 weight percent based on the total weight the multi-component ceramic composite. Such ceramics are useful as bulk materials or as feedstocks for thermal spray.
    Type: Grant
    Filed: September 21, 2001
    Date of Patent: April 20, 2004
    Assignee: Inframat Corporation
    Inventors: Donald M. Wang, You Wang, Tongsan D. Xiao
  • Patent number: 6548435
    Abstract: The invention relates to free-flowing refractory castable material and castings produced therefrom. Refractory nonbasic and basic refractory castable materials have been known for a long time. The traditional refractory castable materials have thixotropic properties and must be lined sing vibration technology. In the past, free-flowing refractory castable materials were solely based on alumina raw materials. Attempts to produce an aqueous, highly concentrated basic suspension which would Coma the basis of free-flowing refractory castable materials failed to meet the requirements in terms of theological properties and a low degree of to hydration of the MgO-based materials. It is the aim of the invention to provide the above-mentioned refractory castable material for the monolithic lining or repair of high-temperature equipment and for the production of refractory castings. This is achieved by providing a fine-grained and a mixed fine and coarse-grained alternative.
    Type: Grant
    Filed: August 30, 2000
    Date of Patent: April 15, 2003
    Inventor: Jerzy Bugajski
  • Publication number: 20030008764
    Abstract: A microstructured or nanostructured multi-component ceramic comprises (a) a major ceramic phase comprising a ceramic oxide composite; (b) a ceramic oxide additive; and (c) a rare earth ceramic oxide additive, wherein the total of the additives (b) and (c) comprise from about 0.1 weight percent to less than 50 weight percent based on the total weight the multi-component ceramic composite. In another embodiment, a microstructured or nanostructured multi-component ceramic comprises (a) a major ceramic oxide phase comprising a ceramic oxide composite; and either (b) a ceramic oxide additive or (c) a rare earth ceramic oxide additive, wherein amount of the additive (b) or (c) comprises from about 0.1 weight percent to less than 50 weight percent based on the total weight the multi-component ceramic composite. Such ceramics are useful as bulk materials or as feedstocks for thermal spray.
    Type: Application
    Filed: September 21, 2001
    Publication date: January 9, 2003
    Inventors: You Wang, Tongsan D. Xiao, Donald M. Wang
  • Patent number: 6475950
    Abstract: A chromium catalyst is disclosed for use in dehydrogenation and dehydrocyclization processes.
    Type: Grant
    Filed: March 15, 2001
    Date of Patent: November 5, 2002
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Kostantinos Kourtakis, Leo E. Manzer
  • Patent number: 6372679
    Abstract: This invention relates to processes for the production of a sintered body consisting of an intimate solid solution of Cr2O3 and Al2O3 by using inexpensive materials, as well as sintered bodies produced thereby. More specifically, it relates to processes for the production of a sintered body which comprises the steps of providing a powder mixture consisting essentially of Cr2O3 powder and Al2O3 powder each having an average particle diameter of not greater than 0.5 &mgr;m, or a powder mixture obtained by mixing the aforesaid powder mixture with 1.5 to 15% by weight of TiO2 powder having an average particle diameter of not greater than 0.5 &mgr;m, and sintering the powder mixture at a temperature of 1,350 to 1,600° C. in a vacuum atmosphere of 10−20 to 10−5 atm. to yield a sintered body consisting of an intimate solid solution of Cr2O3 and Al2O3 and having a relative density of not less than 95%, as well as sintered bodies produced thereby.
    Type: Grant
    Filed: December 20, 1999
    Date of Patent: April 16, 2002
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Takehiko Hirata, Hirokazu Yamamoto
  • Patent number: 6352951
    Abstract: The invention concerns a refractory material based on chromium corundum, a chromium corundum brick made of said material as well as the use thereof.
    Type: Grant
    Filed: March 12, 2000
    Date of Patent: March 5, 2002
    Assignee: Didier-Werke AG
    Inventors: Karl-Heinz Mossal, Selim Yesiltas, Albert Kleinevoss, Thomas Weichert
  • Patent number: 6316106
    Abstract: A filler sand for a ladle tap hole valve contains 70 to 90 wt % of chromite sand and 10 to 30 wt % of silica sand and is blended externally with 0.05 to 5 wt % of carbon black calculated based on the total amount of the chromite sand and the silica sand; or contains 70 to 90 wt % of chromite sand and 10 to 30 wt % of silica sand, wherein the chromite sand has a particle diameter distribution such that 99% or more of the chromite sand consists of particles having diameters ranging from 150 to 850 &mgr;m and that 95% or more of the chromite sand consists of particles having diameters ranging from 200 to 600 &mgr;m, and the silica sand has a particle diameter distribution such that 95% or more of the silica sand consists of particles having diameters ranging from 150 to 850 &mgr;m and that 80% or more of the silica sand consists of particles having diameters ranging from 200 to 600 &mgr;m.
    Type: Grant
    Filed: January 19, 1999
    Date of Patent: November 13, 2001
    Assignees: NKK Corporation, Nippon Rotary Nozzle Co., Ltd.
    Inventors: Hideto Takasugi, Manabu Tano, Takeshi Ishii, Shinichi Akai, Akira Shirayama, Hirohisa Nakashima
  • Patent number: 6254657
    Abstract: Disclosed is a molding method for powder particles, which is excellent in molding performance, and which makes it possible to obtain a preliminary molded product excellent in strength by enhancing mutual bonding between particles in the preliminary molded product. A molding apparatus for powder particles includes an outer frame die having a mold space with a lower punch and an upper punch to be slidably fitted thereto. Slight clearances exist between the outer frame die and the lower and upper punches. A mixture is prepared by mixing a powdery raw material with a liquid additive to cause an exothermic reaction therewith.
    Type: Grant
    Filed: August 17, 1999
    Date of Patent: July 3, 2001
    Assignee: Honda Giken Kogyo Kabushiki Kaisha
    Inventor: Mitsuo Kuwabara
  • Patent number: 6200248
    Abstract: A roll for use in the manufacture of paper and board, a press roll, in particular a center roll in a press, a backup roll for an extended-nip press roll, a hot press roll, or equivalent, which is in direct contact with a wet paper web, or a calender roll, a method for manufacturing the same and a coating composition therefor including an adhesion layer arranged on the frame part of the roll and a ceramic layer arranged on the adhesion layer. The ceramic layer has a thickness of from about 100 &mgr;m to about 2000 &mgr;m and includes from about 50% to about 95% by weight of Cr2O3 and from about 3% to about 50% by weight of TiO2, or from about 50% to about 80% by weight of Al2O3 and from about 20% to about 50% by weight of ZrO2, or exclusively Al2TiO5. The outer face of the ceramic layer is finished until the roughness Ra is from about 0.2 &mgr;m to about 2.0 &mgr;m and/or the porosity of the outer face of the roll is from about 1% to about 20%.
    Type: Grant
    Filed: April 9, 1998
    Date of Patent: March 13, 2001
    Assignee: Valmet Corporation
    Inventors: Juhani Vestola, Kari Niemi
  • Patent number: 6187157
    Abstract: A multi-phase solid electrolyte ion transport membrane comprising at least two phases wherein one of the phases comprises an oxygen ion single conductive material, or a mixed conductor. The other phase comprises an electronically-conductive metal or metal oxide that is incorporated into the membrane by deposition of the metal or metal oxide from a polymer made by polymerizing a chelated metal dispersion in a polymerizable organic monomer or prepolymer. The multi-phase composition advantageously comprises a first phase of a ceramic material and a second phase of a metal or metal oxide bound to a surface of the ceramic material. The multi-phase composition is advantageously prepared in an in-situ fashion before fabricating the membrane matrix. As another alternative, a preformed ceramic matrix is surface-coated with a metal or metal oxide.
    Type: Grant
    Filed: February 2, 1999
    Date of Patent: February 13, 2001
    Assignee: Praxair Technology, Inc.
    Inventors: Chieh-Cheng Chen, Ravi Prasad
  • Patent number: 6136231
    Abstract: The present invention relates to rare earth elemental thermistors and compositions useful for making such thermistors. In particular, it relates to yttrium and chromium oxide based thermistor systems having at least two phases: YCrO.sub.3 and Cr.sub.2 O.sub.3 and their use for measuring temperature.
    Type: Grant
    Filed: November 20, 1998
    Date of Patent: October 24, 2000
    Assignee: Keystone Thermometrics, Inc.
    Inventor: David J. Sorg
  • Patent number: 6093366
    Abstract: The present invention provides a ceramic sintered body excellent in oxidation resistance under high temperatures and markedly superior to the conventional ceramic sintered body in the mechanical strength over a wide temperature range of between room temperature and 1,500.degree. C. The ceramic sintered body of the present invention comprises at least one ceramic crystal grain selected from the group consisting essentially of a monosilicate represented by the general formula RE.sub.2 SiO.sub.5, where RE denotes a IIIa group element including yttrium, and a disilicate represented by the general formula RE.sub.2 Si.sub.2 O.sub.7, where RE denotes a IIIa group element including yttrium, and at least one additional element selected from the group consisting of Al, Cr, Hf, Nb, Zr, Ti, V, Ta, Ca and Mg which is segregated in the boundaries of the ceramic crystal grains in an amount of 0.1 to 15% by weight of the sintered body in terms of the oxide thereof.
    Type: Grant
    Filed: November 5, 1998
    Date of Patent: July 25, 2000
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Masahiro Kato, Yasuhiro Goto, Takayuki Fukasawa, Toshiaki Mizutani
  • Patent number: 6066584
    Abstract: The invention relates to the field of ceramics and concerns sintered Al.s2 O.sub.3 compositions produced from corundum powder and also methods for the use of the invented compositions as medical implants or tool material. To produce such materials, an initially unsintered precursor having a relative density of .rho..gtoreq.55% is produced from .alpha.-Al.sub.2 O.sub.3 powder having defined properties using at least two different dispersing methods, this precursor is subsequently subjected to heat treatment and sintering.
    Type: Grant
    Filed: January 31, 1997
    Date of Patent: May 23, 2000
    Assignee: Fraunhofer-Gesellschaft zur Forderung der Angewandten Forschung e.V.
    Inventors: Andreas Krell, Paul Blank
  • Patent number: 6060182
    Abstract: A hard film is covered on the outer circumferential surface of a piston ring by means of an arc ion plating. The hard film has a mixture of crystal structure of CrN and crystal structure of Mo.sub.2 N containing oxygen in a solid solution state, and comprises chromium at 40 to 78 percent by weight, molybdenum at 3 to 35 percent by weight, oxygen at 3 to 20 percent by weight and the remainder of nitrogen. The crystal particle size is less than 1 .mu.m. The Vickers hardness is within a range from 1600 to 2500. The film thickness is preferably 1 to 60 .mu.m. Carbon in a solid solution state at 0.5 to 8 percent by weight may be substituted for the oxygen. Alternatively, both oxygen and carbon may be contained in a solid solution state with oxygen at 3 to 20 percent by weight, carbon at 0.5 to 8 percent by weight with the total content of carbon and oxygen within 25 percent by weight.
    Type: Grant
    Filed: June 5, 1998
    Date of Patent: May 9, 2000
    Assignee: Teikoku Piston Ring Co., Ltd.
    Inventors: Shoji Tanaka, Nobuyuki Yamashita, Naoki Ito
  • Patent number: 6051514
    Abstract: A filler for a sliding gate containing 70 to 90 wt % of chromite sand and 10 to 30 wt % of silica sand in which the particle size distribution of the chromite sand is substantially from 500 to 1,000 .mu.m, which is not melted, sintered or penetrated by molten metal (molten steel) poured in a ladle in a steel works, and therefore is easily discharged to let the gate through.
    Type: Grant
    Filed: April 7, 1998
    Date of Patent: April 18, 2000
    Assignees: Yamakawa Sangyo Co., Ltd., NKK Corporation, Nippon Rotary Nozzle Co., Ltd.
    Inventors: Jun Ayama, Akira Ohashi, Manabu Tano, Hideto Takasugi, Akira Shirayama, Hirohisa Nakashima
  • Patent number: 5830816
    Abstract: Zirconium dioxide containing 2 to 40 vol. % of stabilizing oxides is embedded in the matrix material of a sintered molding consisting of an aluminum oxide/chromium oxide mixed crystal. The quantity of stabilizing oxides added is chosen so that the zirconium dioxide is predominantly tetragonal. The molar ratio of the zirconium dioxide containing the stabilizing oxides to the chromium oxide is between 1000:1 and 20:1 and the zirconium dioxide has a maximum particle size of 2 .mu.m.
    Type: Grant
    Filed: July 2, 1996
    Date of Patent: November 3, 1998
    Assignee: Cerasiv GmbH Innovatives Keramik-Engineering
    Inventors: Wolfgang Burger, Stefan Gernsheimer, Hans Andersch, Kilian Friederich, Siegbert Lehmann, Johannes Schneider, Michael Fripan
  • Patent number: 5811071
    Abstract: A precursor, in gel form, of an oxide having the formula (I), BaO.n(Al.sub.2x Cr.sub.2y O.sub.3), where 1.ltoreq.n.ltoreq.6.6, (x+y)=1, and 0.ltoreq.y.ltoreq.0.5, said oxide being derivable from the precursor gel by the application of heat, is prepared by mixing a solution of a barium salt with a solution of an aluminium salt or a solution of an aluminium salt and a solution of a chromium salt, and polymerising the mixture to produce said precursor gel. A mixture suitable for firing to an oxide of the formula (II), BaO.m(Al.sub.2x Cr.sub.2y O.sub.3), where 4.6.ltoreq.m.ltoreq.6.6; (x+y)=1; and 0.ltoreq.y.ltoreq.0.5, comprises at least one of:(a) barium oxide;(b) a clean thermal precursor of barium oxide; and(c) barium mono-aluminate, BaO.Al.sub.2 O.sub.3 ; with at least one of:(A) alumina, Al.sub.2 O.sub.3 ;(B) hydrated forms of alumina, such as boehmite, Al.sub.2 O.sub.3.H.sub.2 O; and(C) a clean thermal precursor of aluminium oxide; and, where y is not zero, with at least one of(D) chromium(III) oxide, Cr.
    Type: Grant
    Filed: December 14, 1995
    Date of Patent: September 22, 1998
    Assignee: Alcan International Limited
    Inventors: Harold Garton Emblem, Thomas James Davies
  • Patent number: 5749932
    Abstract: A certain group of electrically conductive refractory materials presently known for use in high temperature applications as throat constructions, melter sidewalls, forehearth, stacks, port sills, hot face lining for slagging coal gasifiers, slag runners, and linings for nuclear waste encapsulation furnaces may be used as electrodes permitting joule heating at temperatures in excess of 1200 C. in excess of about 4400 hours even in the presence of transition group element(s). More specifically, the invention is an electrode for melting earthen materials, wherein the electrode is made from an electrically conductive refractory material, specifically at least one metal oxide wherein the metal is selected from the group consisting of chrome, ruthenium, rhodium, tin and combinations thereof.
    Type: Grant
    Filed: March 29, 1996
    Date of Patent: May 12, 1998
    Assignee: Battelle Memorial Institute
    Inventors: David A. Lamar, Chris C. Chapman, Michael L. Elliott
  • Patent number: 5707911
    Abstract: The disclosed invention is directed to novel ceramic compositions, and to stabilizer compositions for use with those ceramic compositions. The ceramic materials are formed of rare earth chromium oxides that include a novel combination of stabilizing compounds. Also, dryer or sterilizer devices which incorporate these ceramic compositions for generating infrared radiation for drying or sterilizing various articles.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: January 13, 1998
    Assignee: Mitech Scientific Corp.
    Inventors: Roustam Khakimovich Rakhimov, Elena Vasilievna Kim
  • Patent number: 5703000
    Abstract: Provided is a semiconductive ceramic composition comprising a lanthanum cobalt oxide and having a negative resistance-temperature characteristic, which contains, as the side component, a chromium oxide in an amount of from about 0.005 to 30 mol % in terms of chromium, and also a semiconductive ceramic device comprising the composition. The device is usable for rush current inhibition, for motor start-up retardation and for halogen lamp protection, and is also usable in temperature-compensated crystal oscillators.
    Type: Grant
    Filed: February 6, 1997
    Date of Patent: December 30, 1997
    Assignee: Murata Manufacturing Co., Ltd.
    Inventors: Akinori Nakayama, Terunobi Ishikawa, Hiroshi Takagi, Yukio Sakabe
  • Patent number: 5624542
    Abstract: Enhancement of mechanical properties of ceramic membranes by introduction of a uniformly distributed high-temperature oxidation-resistant metal phase into the brittle ceramic phase to achieve mechanically strong ceramic/metal composites operable in an oxidation atmosphere and at elevated temperatures.
    Type: Grant
    Filed: June 12, 1995
    Date of Patent: April 29, 1997
    Assignee: Gas Research Institute
    Inventors: Yousheng Shen, Ashok V. Joshi, Dale M. Taylor, Michael J. Boettcher, Kevin Krist, Anil V. Virkar
  • Patent number: 5484750
    Abstract: Transparent, polycrystalline garnet bodies having desirable properties for use as laser material, luminescent x-ray scintillator materials and other uses are produced by mixing a chloride source solution of the desired cations with a basic ammonium solution to produce a precipitate having a substantially uniform composition which can be further processed to provide the desired transparent body. This precipitate is separated from the solution, dried, thermally decomposed at a temperature in the range from 700.degree. to 1,000.degree. C., pressed to form a compact, isostatically pressed at up to 60,000 psi to provide a green, unsintered compact having a density in the vicinity of 55% of theoretic density. That green compact is then sintered in oxygen at a temperature between 1,400.degree. and 1,700.degree. C. to produce the desired transparent body. Alternatively, the compact may be sintered in oxygen at temperatures in the range from about 1,400.degree. to about 1,600.degree. C.
    Type: Grant
    Filed: August 10, 1994
    Date of Patent: January 16, 1996
    Assignee: General Electric Company
    Inventors: Charles D. Greskovich, William P. Minnear, Chester R. O'Clair, Erdogan O. Gurmen, Robert J. Riedner
  • Patent number: 5482907
    Abstract: A ceramic composite contains one spinel phase and one or more than one oxides phases. The composite is derived from the mixtures of two oxides, A.sub.2 O.sub.3 and BO, with different molar ratio, in which A and B are metallic ions of three and two valences respectively. The oxides are heated at a high temperature to form a composite containing a spinel and residual oxides. The formed spinel and residual oxides also undergo densification under high temperature. After the treatment at high temperature, not only the spinel is formed but also the composite is densified. The performance of the composite is superior in its strength, toughness and high-temperature stability.
    Type: Grant
    Filed: May 26, 1994
    Date of Patent: January 9, 1996
    Assignee: National Science Council
    Inventors: Wei-Hsing Tuan, Ming-Cherng Lin
  • Patent number: 5470494
    Abstract: An oxide type solid lubricant is formed of a powder of a fired composite ceramic material resulting from heating a mixture of BaZrO.sub.3 and Cr.sub.2 O.sub.3 powders in which the Cr.sub.2 O.sub.3 content is up to 80% by weight.
    Type: Grant
    Filed: September 7, 1994
    Date of Patent: November 28, 1995
    Assignees: Agency of Industrial Science & Technology, Ministry of International Trade & Industry
    Inventor: Kazunori Umeda
  • Patent number: 5413871
    Abstract: An article of manufacture has as its basic structure a piece of a titanium aluminide, such as gamma (TiAl) or alpha-2 (Ti3Al), desirably in the shape of an aircraft gas turbine component. A thermal barrier coating system overlies at least a portion of the surface of the piece of titanium aluminide. The thermal barrier coating system includes a metallic bond coat layer, preferably in the form of a layer of a nickel-based alloy no more than about 0.005 inches thick, that contacts the piece of titanium aluminide, and a ceramic thermal barrier coating layer, preferably a stabilized zirconia such as yttria-stabilized zirconia, overlying the bond coat.
    Type: Grant
    Filed: February 25, 1993
    Date of Patent: May 9, 1995
    Assignee: General Electric Company
    Inventors: Warren A. Nelson, Jon C. Schaeffer, Srinivasan Raghuraman
  • Patent number: 5401698
    Abstract: In ceramic welding processes, oxidizing gas and a mixture of refractory and fuel powders are projected against a surface and the fuel is burnt to generate sufficient heat that the refractory powder becomes at least partially melted or softened and a cohesive refractory weld mass is progressively built up against that surface. In order to reduce any tendency for the weld mass to include a low-grade refractory phase and thus promote the refractoriness of that weld mass, the fuel powder is present in a proportion of not more than 15% by weight of the total mixture and includes at least two metals selected from aluminum, magnesium, chromium and zirconium, in that at least the major part by weight of the refractory powder consists of one or more of magnesia, alumina and chromic oxide, and in that the molar proportions of silica and calcium oxide present in the refractory powder (if any) satisfy the following expression:molar concentration of SiO.sub.2 in %.ltoreq.0.2+molar concentration of CaO in %.
    Type: Grant
    Filed: June 8, 1993
    Date of Patent: March 28, 1995
    Assignees: Glaverbel, Fosbel International Ltd.
    Inventors: Leon P. Mottet, Charles M. Zvosec, Stephen D. Cherico, Alexandre Zivkovic, Guy van Marcke de Lummen, Jean Moreau, Pierre Robyn
  • Patent number: 5362692
    Abstract: The present invention pertains to a refractory casting slip consisting of a refractory matrix material and a finely divided reactive component, as well as a hydraulic binder and various additives, which can be discharged as a free-flowing mass upon addition of water.
    Type: Grant
    Filed: July 31, 1992
    Date of Patent: November 8, 1994
    Assignee: Radex-Heraklith Industriebeteiligungs Aktiengesellschaft
    Inventors: Matgorzata Bugajski, Margit Hosler, Gunther Mortl