Titanium Or Zirconium Containing Patents (Class 501/38)
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Patent number: 11884575Abstract: A composition for producing a glass fiber, including the following components with corresponding percentage amounts by weight: SiO2: 57.4-60.9%; Al2O3: greater than 17% and less than or equal to 19.8%; MgO: greater than 9% and less than or equal to 12.8%; CaO: 6.4-11.8%; SrO: 0.1-1.5%; Na2O+K2O: 0.1-1.1%; Fe2O3: 0.05-1%; TiO2: lower than 0.8%; and SiO2+Al2O3: lower than or equal to 79.4%. The total weight percentage of the above components in the composition is greater than 99%. The weight percentage ratio of Al2O3+MgO to SiO2 is between 0.43 and 0.56, and the weight percentage ratio of CaO+MgO to SiO2+Al2O3 is greater than 0.205. The composition can significantly increase the glass modulus, effectively reduce the glass crystallization rate, secure a desirable temperature range (?T) for fiber formation and enhance the refinement of molten glass, thus making it particularly suitable for high performance glass fiber production with refractory-lined furnaces.Type: GrantFiled: April 15, 2022Date of Patent: January 30, 2024Assignee: JUSHI GROUP CO., LTD.Inventors: Guorong Cao, Lin Zhang, Wenzhong Xing, Xiucheng Hong, Zhonghua Yao
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Patent number: 11339085Abstract: A composition for producing a glass fiber, including the following components with corresponding percentage amounts by weight: SiO2: 57.4-60.9%; Al2O3: greater than 17% and less than or equal to 19.8%; MgO: greater than 9% and less than or equal to 12.8%; CaO: 6.4-11.8%; SrO: 0-1.6%; Na2O+K2O: 0.1-1.1%; Fe2O3: 0.05-1%; TiO2: lower than 0.8%; and SiO2+Al2O3: lower than or equal to 79.4%. The total weight percentage of the above components in the composition is greater than 99%. The weight percentage ratio of Al2O3+MgO to SiO2 is between 0.43 and 0.56, and the weight percentage ratio of CaO+MgO to SiO2+Al2O3 is greater than 0.205. The composition can significantly increase the glass modulus, effectively reduce the glass crystallization rate, secure a desirable temperature range (?T) for fiber formation and enhance the refinement of molten glass, thus making it particularly suitable for high performance glass fiber production with refractory-lined furnaces.Type: GrantFiled: November 21, 2017Date of Patent: May 24, 2022Assignee: JUSHI GROUP CO., LTD.Inventors: Guorong Cao, Lin Zhang, Wenzhong Xing, Xiucheng Hong, Zhonghua Yao
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Patent number: 11168016Abstract: A glass material with low viscosity and a low bubble content attributable to a low weight percentage of silicon dioxide includes boron trioxide (B2O3), magnesium oxide (MgO), aluminum oxide (Al2O3), and calcium oxide (CaO) in addition to silicon dioxide (SiO2); wherein Silicon dioxide (SiO2) constitutes 45%-51% by weight of the glass material, boron trioxide (B2O3) 25%-35%, magnesium oxide (MgO) 0.01%-2%, aluminum oxide (Al2O3) 10%-14.5%, and calcium oxide (CaO) 4%-10%. As the silicon dioxide (SiO2) content is lower than in the prior art, the glass material has lower viscosity, and hence a lower bubble content, than in the prior art, and this allows products made of the glass material to have a higher yield than products made of the conventional glass.Type: GrantFiled: September 17, 2019Date of Patent: November 9, 2021Assignee: TAIWAN GLASS INDUSTRY CORP.Inventor: Chia-Yu Lin
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Patent number: 11078109Abstract: A composition for producing a glass fiber, including the following components with corresponding percentage amounts by weight: 54.2-64% SiO2, 11-18% Al2O3, 20-25.5% CaO, 0.3-3.9% MgO, 0.1-2% of Na2O+K2O, 0.1-1.5% TiO2, and 0.1-1% total iron oxides including ferrous oxide (calculated as FeO). The weight percentage ratio C1=FeO/(iron oxides?FeO) is greater than or equal to 0.53. The total content of the above components in the composition is greater than 97%. The invention also provides a glass fiber produced using the composition and a composite material including the glass fiber.Type: GrantFiled: August 24, 2018Date of Patent: August 3, 2021Assignee: JUSHI GROUP CO., LTD.Inventors: Guorong Cao, Wenzhong Xing, Lin Zhang, Guijiang Gu
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Patent number: 10844222Abstract: A polymer composite includes a linear aliphatic semi-crystalline polyamide having on average 10 to 14 carbon atoms in the monomer units, or the compound thereof, an S glass fiber, and a core-shell impact modifier. The polymer composite can achieve higher stiffness and impact strength without impairing the transparency significantly. The polymer composite can be used as molding material.Type: GrantFiled: November 21, 2018Date of Patent: November 24, 2020Assignees: Evonik Operations GmbH, Evonik Specialty Chemicals (Shanghai) Co., Ltd.Inventors: Jianmin Yang, Urs Welz-Biermann, Klaus Hülsmann, Fei Teng, Juan Guo, Chenyu Ye, Zhisheng Wang, Kathrin Salwiczek
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Patent number: 10629900Abstract: A porous silicon composition, a porous alloy composition, or a porous silicon containing cermet composition, as defined herein. A method of making: the porous silicon composition; the porous alloy composition, or the porous silicon containing cermet composition, as defined herein. Also disclosed is an electrode, and an energy storage device incorporating the electrode and at least one of the disclosed compositions, as defined herein.Type: GrantFiled: November 14, 2016Date of Patent: April 21, 2020Assignee: Corning IncorporatedInventors: Indrajit Dutta, Brian Alan Kent, Patrick David Tepesch, Shawn Michael O'Malley, Randall Eugene Youngman
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Patent number: 10364178Abstract: A silicate glass that is tough and scratch resistant. The toughness is increased by minimizing the number of non-bridging oxygen atoms in the glass. In one embodiment, the silicate glass is an aluminoborosilicate glass in which ?15 mol %?(R2O+R?O?Al2O3?ZrO2)?B2O3?4 mol %, where R is one of Li, Na, K, Rb, and Cs, and R? is one of Mg, Ca, Sr, and Ba.Type: GrantFiled: September 17, 2018Date of Patent: July 30, 2019Assignee: CORNING INCORPORATEDInventors: Matthew John Dejneka, Adam James Ellison, Sinue Gomez, Robert Michael Morena
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Patent number: 10294142Abstract: A high modulus glass fiber composition, and a glass fiber and a composite material thereof. The glass fiber composition comprises the following components expressed as percentage by weight: 53-68% of SiO2, 13-24.5% of Al2O3, 0.1-8% of Y2O3+La2O3, less than 1.8% of La2O3, 10-23% of CaO+MgO+SrO, less than 2% of Li2O+Na2O+K2O, and less than 1.5% of Fe2O3, and the range of a weight percentage ratio C1 is more than 0.5, wherein C1=Y2O3/(Y2O3+La2O3). The composition significantly increases the elastic modulus of glass, significantly reduces the liquidus temperature and the forming temperature of glass, and under equal conditions, significantly reduces the crystallization rate and the bubble rate of glass. The composition effectively improves the material properties of glass, and is particularly suitable for the tank furnace production of a high modulus glass fiber having a low bubble rate.Type: GrantFiled: March 7, 2016Date of Patent: May 21, 2019Assignee: JUSHI GROUP CO., LTD.Inventors: Yuqiang Zhang, Guorong Cao, Lin Zhang, Wenzhong Xing, Guijiang Gu
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Patent number: 10287206Abstract: A composition of matter, including the following components expressed as percentage by weight: SiO2, 58-60.4%; Al2O3, 14-16.5%; CaO, 14.1-16.5%; MgO, 6-8.2%; Li2O, 0.01-0.4%; Na2O+K2O, less than 1.15%; K2O, greater than 0.5%; TiO2, less than 1.5%; and Fe2O3, less than 1%. The range of the weight percentage ratio CaO/MgO is greater than 2 and less than or equal to 2.4. A glass fiber prepared from the composition is also provided.Type: GrantFiled: December 22, 2017Date of Patent: May 14, 2019Assignee: JUSHI GROUP CO., LTD.Inventors: Guorong Cao, Lin Zhang, Wenzhong Xing, Guijiang Gu
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Patent number: 10207949Abstract: A composition for producing a glass fiber, including the following components with corresponding percentage amounts by weight: SiO2: 57.1-61.4%; Al2O3: 17.1-21%; MgO: 10.1-14.5%; Y2O3: 1.1-4.3%; CaO: <6.5%; Li2O+Na2O+K2O: ?1%; Li2O: ?0.75%; TiO2: <1.8%; and Fe2O3: 0.05-1.2%. The total weight percentage of the above components in the composition is greater than or equal to 98%. The weight percentage ratio of Al2O3 to SiO2 is greater than or equal to 0.285. The invention also provides a glass fiber produced using the composition and a composite material including the glass fiber.Type: GrantFiled: November 22, 2017Date of Patent: February 19, 2019Assignee: JUSHI GROUP CO., LTD.Inventors: Lin Zhang, Wenzhong Xing, Guorong Cao, Guijiang Gu
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Patent number: 10155686Abstract: The present invention provides a glass fiber composition, glass fiber and composite material therefrom. The glass fiber composition comprises the following components expressed as percentage by weight: 56-64% SiO2, 12-18% Al2O3, 0.1-1% Na2O, 0.1-1% K2O, 0.1-1% Fe2O3, 0.05-1% Li2O+Bi2O3, 19-25% CaO+MgO+SrO, 0.1-1.5% TiO2 and 0-1% CeO2, wherein a weight percentage ratio C1=Li2O/Bi2O3 is greater than 1, and a weight percentage ratio C2=(MgO+SrO)/CaO is 0.4-1, and a weight percentage ratio C3=MgO/(MgO+SrO) is greater than 0.7. Said composition reduces the amount of bubbles, viscosity and crystallization risk of the glass, thereby making it more suitable for large-scale production with refractory-lined furnaces.Type: GrantFiled: December 29, 2014Date of Patent: December 18, 2018Assignee: JUSHI GROUP CO., LTD.Inventors: Guorong Cao, Lin Zhang, Wenzhong Xing, Guijiang Gu
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Patent number: 10035727Abstract: The present invention relates generally to glass compositions incorporating rare earth oxides (RE2O3). In one embodiment, a glass composition suitable for fiber forming comprises 51-70 wt. % SiO2, 12.5-22 wt. % Al2O3, 0-20 wt. % CaO, 0-11 wt. % MgO, 0.2-1 wt. % Fe2O3, 0.05 or greater wt. % RE2O3, and greater than 1 wt. % MnOx. In another embodiment, a glass composition suitable for fiber forming comprises 51-70 wt. % SiO2, 12.5-22 wt. % Al2O3, 0-20 wt. % CaO, 0-11 wt. % MgO, 0.2-1 wt. % Fe2O3, 0.05 or greater wt. % RE2O3, 0-4 wt. % BaO, 0-4 wt. % SrO, and 0-5.5 wt. % ZnO, wherein the sum of BaO+SrO+ZnO is greater than about 2 wt. %. In another embodiment, a glass composition suitable for fiber forming comprises 51-70 wt. % SiO2, 12.5-22 wt. % Al2O3, 0-20 wt. % CaO, 0-11 wt. % MgO, 0.2-1 wt. % Fe2O3, 0.05 or greater wt. % RE2O3, and from greater than 0 to 2.5 wt. % Cu2O. In another embodiment, a glass composition suitable for fiber forming comprises 51-70 wt. % SiO2, 12.5-22 wt. % Al2O3, 0-20 wt. % CaO, 0-12.Type: GrantFiled: December 20, 2016Date of Patent: July 31, 2018Inventors: Hong Li, Paul A. Westbrook
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Patent number: 9944551Abstract: New glass compositions and applications thereof are disclosed. Embodiments of the present invention relate to glass compositions, to fiber glass strands, to chopped fiber glass strands, to nonwoven mats of glass fibers, and to other products and methods. A fiber glass strand comprises a plurality of glass fibers comprising the glass composition of the present invention.Type: GrantFiled: May 7, 2015Date of Patent: April 17, 2018Assignee: PPG Industries Ohio, Inc.Inventor: Hong Li
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Patent number: 9790122Abstract: The present invention relates to a glass composition which is resistant to alkalis and to acids, in particular for the preparation of reinforcing glass strands, which comprises the following constituents within the limits defined below, as percentages by weight: SiO2 ?58%, preferably ?65% ZrO2 15-20% R2O (R = Na, K or Li) ?14% K2O ?0.1%, preferably ?0.05%, RO (R = Mg, Ca or Sr) 2.5-6% MgO ?4% TiO2 >1 and ?4% the composition additionally being devoid of F, comprising less than 1% of impurities (Al2O3, Fe2O3 and Cr2O3) and satisfying the following relationships: ZrO2+TiO2?17% ZrO2/TiO2?6 It also relates to the use of the glass strands obtained in the reinforcing of inorganic materials, for example cementitious materials, or organic materials, for example plastics, and to the composites including such strands.Type: GrantFiled: October 23, 2006Date of Patent: October 17, 2017Assignee: OCV Intellectual Capital, LLCInventors: Emmanuel Lecomte, Eric Dallies, Anne Berthereau
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Patent number: 9758423Abstract: The present invention provides a glass fiber composition, a glass fiber and a composite material therefrom. The glass fiber composition comprises the following components expressed as percentage by weight: 58-64% SiO2, 14-19% Al203, ?8.8% and <11.8% CaO, 7.5-11% MgO, 0.2-2.7% SrO, 0.1-2% Na2O+K2O, 0.05-0.9% Li2O, 0.05-1% Fe2O3, 0.05-1.1% TiO2 and <0.5% F2, wherein the range of the weight percentage ratio C1=(MgO+SrO)/CaO is 0.75-1.1, and the range of the weight percentage ratio C2=CaO/MgO is less than 1.4. Said composition can effectively inhibit the crystallization tendency of glass, significantly decrease the liquidus temperature and crystallization degree of glass and also has an outstanding glass refractive index and outstanding modulus.Type: GrantFiled: January 20, 2015Date of Patent: September 12, 2017Assignee: Jushi Group Co., Ltd.Inventors: Guorong Cao, Wenzhong Xing, Lin Zhang, Guijiang Gu
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Patent number: 9586856Abstract: Glass fibers are presented having a composition of about 48-54 weight percent SiO2; about 7-14 weight percent Al2O3, about 10-16 weight percent CaO, about 7-13 weight percent TiO2, and about 9-19 weight percent ZnO. A composite material is also provided formed of a polymer matrix and glass fibers of the present invention. The fibers of the present invention have a refractive index between about 1.60 and 1.66 at 590 nm.Type: GrantFiled: December 13, 2010Date of Patent: March 7, 2017Assignee: OCV Intellectual Capital, LLCInventors: Douglas Alan Hofmann, Peter Bernard McGinnis, Rebecca Elaine Cochran
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Patent number: 9546107Abstract: Improved glass batch compositions and processes of fiberizing the compositions to form fibers are provided. The batch of the present composition can include: 40-60 wt % SiO2; 15-50 wt % Al2O3; 0-30 wt % MgO; 0-25 wt % CaO; 0-5 wt % Li2O; 0-9 wt % B2O3; and 0-5 wt % Na2O. The fibers formed of the compositions may have a Young's modulus of greater than 82.7 GPa (12 MPSI). The fibers may also have good biosolubility (kdis), of at least 100 ng/cm2/hour.Type: GrantFiled: October 18, 2013Date of Patent: January 17, 2017Assignee: OCV Intellectual Capital, LLCInventors: Peter B. McGinnis, Douglas Alan Hofmann, Michelle Lynn Korwin-Edson
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Patent number: 9522842Abstract: A vitroceramic glass composition consisting of SiO2, Al2O3, and CaO or of SiO2, Al2O3, CaO and SrO or of SiO2, Al2O3 and La2O3 is provided. In addition, a method and assembly of at least two parts using said composition is provided. Also, a gasket and assembly obtained by this method as well as a high temperature electrolyzer (HTE) or solid oxide fuel cell (SOFC) comprising this gasket or this assembly are provided.Type: GrantFiled: March 31, 2011Date of Patent: December 20, 2016Assignee: Commissariat a l'énergie atomique et aux énergies alternativesInventors: Hélène Nonnet, Andrew Connelly, Hichem Khedim
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Patent number: 9499432Abstract: The present invention concerns glass fiber composition comprising the following oxides: SiO2: 57.5-59.5 wt. % Al2O3: 17.0-20.0 wt. % CaO: 11.0-13.5 wt. % MgO: 8.5-12.5 wt. % wherein the sum of Na2O, K2O, and TiO2 is at least 0.1 wt. % and Li2O?2.0 wt. %, all amounts being expressed in weight % with respect to the total weight of the composition. It also concerns composite materials reinforced with such fibers, used in applications such as wind mill blades, pressure vessels, components in the automotive, machinery, aerospace applications and such products produced therewith, and wherein the temperature difference, ?T, defined as the difference between the temperature, T3, at which the composition has a viscosity of 103 Poise and the liquidus temperature, Tliq, is at least 50° C.Type: GrantFiled: April 16, 2013Date of Patent: November 22, 2016Assignee: 3B-FIBREGLASS SPRLInventors: Houet Yves, Laurent Dimitri
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Patent number: 9272943Abstract: A medium temperature solid oxide fuel cell glass packaging material is provided. The glass packaging material may include a glass main body made of SiO2, Al2O3, Y2O3 and ZnO, and at least one glass modifier added into the glass main body. Glass transition temperature ranges from 700 to 900 degrees Celsius. The glass modifier may be rare earth elements or transitory elements. The added glass modifier may adjust the glass transition temperature and the thermal expansion coefficient, and improve the bonding characteristics of the glass packaging material, so as to allow the manufactured glass packaging material to be applicable in SOFC application temperature range from 500 to 800 degrees Celsius.Type: GrantFiled: December 11, 2013Date of Patent: March 1, 2016Assignee: NATIONAL TAIPEI UNIVERSITY OF TECHNOLOGYInventors: Sea-Fue Wang, Yueh-Chi Hsieh, Yung-Fu Hsu
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Patent number: 9212086Abstract: The present invention relates to a chemically resistant glass composition for the production of reinforcing strands which comprises the following constituents within the limits defined below, expressed in mol %: SiO2 67-72%; ZrO2 5-9.5%, preferably ?7.5%; R2O (R=Na, K and Li) 11-17%; Li2O 0-5.5%; K2O 0-5.5%; Na2O<10%; and CaO 3-9%, the composition furthermore containing less 1% of impurities (Al2O3, Fe2O3, Cr2O3, TiO2, MgO, SrO, BaO and P2O5) and being free of F. It also relates to the glass strands obtained from this composition and to the composites based on an organic or inorganic material containing such strands.Type: GrantFiled: October 25, 2007Date of Patent: December 15, 2015Assignee: Owens Corning Intellectual Capital, LLCInventors: Anne Berthereau, Jerome Lalande
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Patent number: 9156729Abstract: A glass composition including SiO2 in an amount from 30.0 to 40.0% by weight, Al2O3 in an amount from 15.0 to 23.0% by weight, B2O3 in an amount from 0.0 to 15.0% by weight, K2O in an amount from 0.0 to 5.0% by weight, La2O3 in an amount from 0.0 to 30.0% by weight, Li2O in an amount from 0.0 to 3.0% by weight, Na2O in an amount from 0.0 to 4.0% by weight, Nb2O5 in an amount from 0.0 to 10.0% by weight, TiO2 in an amount from 0.0 to 7.5% by weight, WO3 in an amount from 0.0 to 10.0% by weight, Y2O3 in an amount from 15.0 to 35.0% by weight, and RO (one or more of MgO, CaO, SrO, and BaO) in an amount from 0.0 to 7.5% by weight is provided. Glass fibers formed from the composition have a refractive index between 1.55 and 1.69.Type: GrantFiled: October 18, 2011Date of Patent: October 13, 2015Assignee: OCV Intellectual Capital, LLCInventors: Peter B. McGinnis, Douglas Hofmann
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Patent number: 9051207Abstract: This invention discloses a kind of boron and fluorine-free fiberglass composite with its characteristic that it has the following compounds under particular mix ratio: SiO2, Al2O3, SiO2+Al2O3, CaO, MgO, TiO2, ZnO, Na2O+K2O and Fe2O3. The preferential process of this invention is: selection of mineral?grinding of mineral?compounding as per ratio?melting in furnace?outflow from platinum bushing?fiberizing?coating of infiltrating liquid?protofilament drying. Compared with the traditional E fiberglass, the composite of this invention has better mechanical performance (tensile strength increased by over 15% and elastic modulus increased by over 5%) and better corrosion resistance (resistance of acid and alkali increased by 20 times); its forming temperature (<1280° C.) and forming range (>80° C.) are proper with good fiberizing performance, which can be produced in large scale.Type: GrantFiled: July 6, 2011Date of Patent: June 9, 2015Assignee: CHONGQING POLYCOMP INTERNATIONAL CORPORATIONInventors: Lixiong Han, Xun Du, Yuan Yao, Dequan Chen
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Publication number: 20150133284Abstract: The present invention concerns glass fibre composition comprising the following oxides: Si02: 57.5-59.5 wt. % AI2O3: 17.0-20.0 wt. % CaO: 11.0-13.5 wt. % MgO: 8.5-12.5 wt. % wherein the sum of Na2O, K2O, and TiO2 is at least 0.1 wt. % and Li2O?2.0 wt. %, all amounts being expressed in weight % with respect to the total weight of the composition. It also concerns composite materials reinforced with such fibres, used in applications such as wind(a) mill blades, pressure vessels, components in the automotive, machinery, aerospace applications and such products produced therewith, and wherein the temperature difference, ?T, defined as the difference between the temperature, T3, at which the composition has a viscosity of 103 Poise and the liquidus temperature, Tliq, is at least 50° C.Type: ApplicationFiled: April 16, 2013Publication date: May 14, 2015Inventors: Houet Yves, Laurent Dimitri
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Publication number: 20150057143Abstract: Embodiments of the present invention relate to glass compositions, glass fibers formed from such compositions, and related products. In one embodiment, a glass composition comprises 58-62 weight percent SiO2, 14-17 weight percent Al2O3, 14-17.5 weight percent CaO, and 6-9 weight percent MgO, wherein the amount of Na2O is 0.09 weight percent or less.Type: ApplicationFiled: October 31, 2014Publication date: February 26, 2015Inventor: Hong Li
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Publication number: 20150018194Abstract: The present invention relates generally to glass compositions incorporating rare earth oxides. In one embodiment, a glass composition suitable for fiber forming comprises 51-65 weight percent SiO2, 12.5-19 weight percent Al2O3, 0-16 weight percent CaO, 0-12 weight percent MgO, 0-2.5 weight percent Na2O, 0-1 weight percent K2O, 0-2 weight percent Li2O, 0-3 weight percent TiO2, 0-3 weight percent ZrO2, 0-3 weight percent B2O3, 0-3 weight percent P2O5, 0-1 weight percent Fe2O3, at least one rare earth oxide in an amount not less than 0.05 weight percent, and 0-11 weight percent total other constituents. In some embodiments, the at least one rare earth oxide comprises at least one of La2O3, Y2O3, Sc2O3, and Nd2O3. The at least one rare earth oxide is present in an amount of at least 1 weight percent in some embodiments. The at least one rare earth oxide, in some embodiments, is present in an amount of at least 3 weight percent.Type: ApplicationFiled: July 8, 2014Publication date: January 15, 2015Inventors: Hong Li, Paul A. Westbrook
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Patent number: 8912107Abstract: A composition for preparing high-performance glass fiber by tank furnace production comprising in preferred percentage by weight: 57.5˜62.5% of SiO2, 14.5˜17.5% of Al2O3, 13.5˜17.5% of CaO, 6.5˜8.5% of MgO, 0.05˜0.6% of Li2O, 0.1˜2% of B2O3, 0.1˜2% of TiO2, 0.1˜2% of Na2O, 0.1˜1% of K2O and 0.1˜1% of Fe2O3 and (CaO+MgO)/MgO>3, with the content of at least one of the three components, A2O, B2O3 and TlO2 higher than 0.5%, with the composition yielding glass fiber having improved mechanical property, causing the melting and clarification of glass and forming performance of fiber close to those of boron-free E glass, and facilitating industrial mass production by tank furnace processes with manufacturing costs close to those of conventional E glass.Type: GrantFiled: May 18, 2011Date of Patent: December 16, 2014Assignee: Jushi Group Co., Ltd.Inventors: Yuqiang Zhang, Guorong Cao, Bing Zhang, Lin Zhang, Wenzhong Xing, Guijiang Gu
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Publication number: 20140235424Abstract: Glass compositions are provided that are useful in a variety of applications including, for example, electronics applications, reinforcement applications, and others. Some embodiments of glass compositions can provide desirable dielectric constants, desirable dissipation factors, and/or desirable mechanical properties while also having desirable fiber forming properties.Type: ApplicationFiled: March 27, 2014Publication date: August 21, 2014Inventor: Hong Li
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Publication number: 20140228195Abstract: The invention relates to a melt composition for the production of man-made vitreous fibres and man-made vitreous fibres comprising the following oxides, by weight of composition: SiO2 39-43 weight % Al2O3 20-23 weight % TiO2 up to 1.5 weight % Fe2O3 5-9 weight %, preferably 5-8 weight % CaO 8-18 weight % MgO 5-7 weight % Na2O up to 10 weight %, preferably 2-7 weight % K2O up to 10 weight %, preferably 3-7 weight % P2O5 up to 2% MnO up to 2% R2O up to 10 weight % wherein the proportion of Fe(2+) is greater than 80% based on total Fe and is preferably at least 90%, more preferably at least 95% and most preferably at least 97% based on total Fe.Type: ApplicationFiled: October 12, 2012Publication date: August 14, 2014Inventors: Mette Solvang, Svend Grove-Rasmussen, Mathilde Rosendahl Foldschack
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Publication number: 20140113799Abstract: This invention discloses a kind of boron and fluorine-free fiberglass composite with its characteristic that it has the following compounds under particular mix ratio: SiO2, Al2O3, SiO2+Al2O3, CaO, MgO, TiO2, ZnO, Na2O+K2O and Fe2O3. The preferential process of this invention is: selection of mineral?grinding of mineral?compounding as per ratio?melting in furnace?outflow from platinum bushing?fiberizing?coating of infiltrating liquid?protofilament drying. Compared with the traditional E fiberglass, the composite of this invention has better mechanical performance (tensile strength increased by over 15% and elastic modulus increased by over 5%) and better corrosion resistance (resistance of acid and alkali increased by 20 times); its forming temperature (<1280° C.) and forming range (>80° C.) are proper with good fiberizing performance, which can be produced in large scale.Type: ApplicationFiled: July 6, 2011Publication date: April 24, 2014Applicant: CHONGQING POLYCOMP INTERNATIONAL CORPORATIONInventor: Lixiong Han
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Patent number: 8703633Abstract: A high-intensity and high-modulus glass fiber is provided. Said fiber is produced by improving the processes, components and proportion of conventional E-glass production process and apparatus. The fiber contains 13% CaO at most, no boron and fluorine, meanwhile ZrO2 and Li2O is first added, B2O3 is first removed, and SO3 is added. The intensity and the modulus of the fiber are slightly lower than those of S-glass or T-glass, but obviously higher than those of E-glass and ECR-glass which are highly produced and widely used or other boron-free glass such as Advantex glass. Besides the intensity, modulus and fatigue resistance, said fiber has obvious advantages over E-glass in heat, acid and alkali resistance. The glass fiber roving made from said fiber has 22% higher tensile strength and 11˜15.7% higher modulus than those of E-glass, and has 16% higher tensile strength and 5˜6% higher modulus than those of ECR-glass.Type: GrantFiled: July 2, 2010Date of Patent: April 22, 2014Assignee: Chongqing Polycomp Int'l CorporationInventor: Zhiyao Tang
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Patent number: 8535438Abstract: The present invention relates to a chemically resistant glass composition for the production of reinforcing strands which comprises the following constituents within the limits defined below, expressed in mol %: SiO2 67-72%; ZrO2 5-9.5%, preferably ?7.5%; R2O (R=Na, K and Li) 11-17%; Li2O 0-5.5%; K2O 0-5.5%; Na2O<10%; and CaO 3-9%, the composition furthermore containing less 1% of impurities (Al2O3, Fe2O3, Cr2O3, TiO2, MgO, SrO, BaO and P2O5) and being free of F. It also relates to the glass strands obtained from this composition and to the composites based on an organic or inorganic material containing such strands.Type: GrantFiled: October 25, 2007Date of Patent: September 17, 2013Assignee: OCV Intellectual Capital, LLCInventors: Anne Berthereau, Jerome Lalande
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Publication number: 20130217807Abstract: A glass composition including SiO2 in an amount from 30.0 to 40.0% by weight, Al2O3 in an amount from 15.0 to 23.0% by weight, B2O3 in an amount from 0.0 to 15.0% by weight, K2O in an amount from 0.0 to 5.0% by weight, La2O3 in an amount from 0.0 to 30.0% by weight, Li2O in an amount from 0.0 to 3.0% by weight, Na2O in an amount from 0.0 to 4.0% by weight, Nb2O5 in an amount from 0.0 to 10.0% by weight, TiO2 in an amount from 0.0 to 7.5% by weight, WO3 in an amount from 0.0 to 10.0% by weight, Y2O3 in an amount from 15.0 to 35.0% by weight, and RO (one or more of MgO, CaO, SrO, and BaO) in an amount from 0.0 to 7.5% by weight is provided. Glass fibers formed from the composition have a refractive index between 1.55 and 1.69.Type: ApplicationFiled: October 18, 2011Publication date: August 22, 2013Applicant: OCV INTELLECTUAL CAPITAL, LLCInventors: Peter B. McGinnis, Douglas Hofmann
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Publication number: 20130217822Abstract: Glass batch compositions for the formation of high-modulus, and high-strength glass fibers as well as fibers suitable for use as textile and reinforcements are disclosed. Fibers formed of the composition are especially suitable for use in high-strength, low-weight applications such as windmill blades and high strength and modulus applications where strength and stiffness are required in the composite. The glass composition is up to about 70.5 weight % SiO2, about 24.5 weight % Al2O3, about 22 weight % alkaline earth oxides and may include small amounts of alkali metal oxides and ZrO2. Additionally, glass fibers formed from the inventive composition are non-corrosive or substantially non-corrosive in nature. Due to the non-corrosive nature of the glass fibers, glass fibers made with the inventive composition may be used in applications where the glass fibers or a composite formed from the glass fibers are in contact with a corrosive substance.Type: ApplicationFiled: January 30, 2007Publication date: August 22, 2013Inventors: Douglas A. Hofmann, Peter B. Mc Ginnis
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Publication number: 20130203583Abstract: A composition for preparing high-performance glass fiber by tank furnace production comprising in preferred percentage by weight: 57.5˜62.5% of SiO2, 14.5˜17.5% of Al2O3, 13.5˜17.5% of CaO, 6.5˜8.5% of MgO, 0.05˜0.6% of Li2O, 0.1˜2% of B2O3, 0.1˜2% of TiO2, 0.1˜2% of Na2O, 0.1˜1% of K2O and 0.1˜1% of Fe2O3 and (CaO+MgO)/MgO>3, with the content of at least one of the three components, A2O, B2O3 and TlO2 higher than 0.5%, with the composition yielding glass fiber having improved mechanical property, causing the melting and clarification of glass and forming performance of fiber close to those of boron-free E glass, and facilitating industrial mass production by tank furnace processes with manufacturing costs close to those of conventional E glass.Type: ApplicationFiled: May 18, 2011Publication date: August 8, 2013Applicant: Jushi Group Co., Ltd.Inventors: Yuqiang Zhang, Guorong Cao, Bing Zhang, Lin Zhang, Wenzhong Xing, Guijiang Gu
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Patent number: 8497219Abstract: A highly temperature-resistant and chemically resistant glass and a glass fibre which have an improved UV light transmission, and the use thereof in UV-curable composites are disclosed. The glass/glass fibre according to the invention has a transition temperature >920° C., a light transmission of 80-92%, and consists of 58-62% SiO2, 11.0-15.5% Al2O3, 20-25% CaO, 0.1-0.8% MgO, 0.04-1.2% Na2O, 0.1-1.2 K2O, 0.2-1.8% TiO2, 0.05-0.5% Fe2O3 and 0.002-0.085 Cr2O3.Type: GrantFiled: December 4, 2008Date of Patent: July 30, 2013Inventor: Gerhard Bürger
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Publication number: 20120322933Abstract: Glass fibers are presented having a composition of about 48-54 weight percent SiO2; about 7-14 weight percent Al2O3, about 10-16 weight percent CaO, about 7-13 weight percent TiO2, and about 9-19 weight percent ZnO. A composite material is also provided formed of a polymer matrix and glass fibers of the present invention. The fibers of the present invention have a refractive index between about 1.60 and 1.66 at 590 nm.Type: ApplicationFiled: December 13, 2010Publication date: December 20, 2012Applicant: OCV Intellectual capital, LLCInventors: Douglas Alan Hofmann, Peter Bernard McGinnis, Rebecca Elaine Cochran
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Patent number: 8334228Abstract: This invention involves a fiberglass composition containing the following components: SiO2, Al2O3, CaO, MgO, B2O3, F2, TiO2, K2O, Na2O, Fe2O3 and SO3. The weight percentage of each of the components are as follows: SiO2 58˜65%, CaO 20˜26%, Al2O3 9˜17%, MgO 0.5˜1%, B2O3 0˜5%, F2 0˜1%, TiO2 0.1˜1%, K2O+Na2O 0˜0.8%, Fe2O3 0.1˜0.5%, SO3 0˜0.6%. The ternary system, SiO2—Al2O3—CaO, is basis of the fiberglass composition in this invention, which also has low quantities of MgO and B2O3. In addition, the total amount of alkaline earth oxide and the proportional relationship between MgO and CaO are rationally designed, which helps to improve the mechanical strength, heat resistance, and chemical stability of the glass. It also has excellent manufacturing performance. Moreover, the raw materials of the fiberglass composition in this invention are low in cost, and the invention meets environmental protection requirements.Type: GrantFiled: December 14, 2009Date of Patent: December 18, 2012Assignee: Jushi Group Co. Ltd.Inventors: Yuqiang Zhang, Guorong Cao, Bing Zhang, Lin Zhang, Wenzhong Xing, Guijiang Gu
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Patent number: 8298973Abstract: A glass thread adapted for reinforcing polymeric materials includes a plurality of filaments having a chemical composition that includes the following constituents within the limits defined below in weight percent: SiO2 40 to 60 Al2O3 0 to 5 CaO 1 to 15 MgO 1 to 15 BaO 2 to 15 SrO 12 to 20 ZnO 0.5 to 10 Na2O + K2O + Li2O 0 to 5 TiO2 3 to 20 Prosthetic members including such threads are also described.Type: GrantFiled: August 28, 2008Date of Patent: October 30, 2012Assignee: Societe de Recherches Techniques Dentaires—R.T.D.Inventors: Anne Berthereau, Jerome Blaizot
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Publication number: 20120193223Abstract: Solid oxide electrolysis cell (SOEC) stack obtainable by a process comprising the use of a glass sealant with composition 50 to 70 wt % SiO2, 0 to 20 wt % Al2O3, 10 to 50 wt % CaO, 0 to 10 wt % MgO, 0 to 2 wt % (Na2o 1K2O), 0 to 10 wt % b2O3, and 0 to 5 wt % of functional elements selected from TiO2, ZrO2, ZrO2, F, P2O5, Mo03, FeO3, MnO 2, La—Sr—Mn—O perovskite (LSM) and combinations thereof. Preferably, the sealant is a sheet of E-glass fibres with a composition in wt % of 52-56 SiO2, 12-16AL2O3, 16-25 CaO, 0-6MgO, 0-2 Na2+K2O, 0-10 B2O3, 0-1.5 TiO2, O-1F.Type: ApplicationFiled: October 5, 2010Publication date: August 2, 2012Applicant: Topsoe Fuel CellInventors: Jens Ulrik Nielsen, Jørgen Gutzon Larsen
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Publication number: 20120190529Abstract: A glass composition useful in preparing fiberglass comprises 12 to 25 weight % CaO; 12 to 16 weight % Al2O3; 52 to 62 weight % SiO2; 0.05 to 0.8 Fe2O3; and greater than 2 up to about 8 weight % alkali metal oxide.Type: ApplicationFiled: March 7, 2012Publication date: July 26, 2012Inventors: Jeffrey Shock, Elam Leed, Jonathan McCann
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Publication number: 20120135849Abstract: An R-glass composition including SiO2 in an amount from 59.0 to 64.5% by weight, Al2O3 in an amount from 14.5 to 20.5% by weight, CaO in an amount from 11.0 to 16.0% by weight, MgO in an amount from 5.5 to 11.5% by weight, Na2O in N an amount from 0.0 to 4.0% by weight, TiO2 in an amount from 0.0 to 2.0% by weight, Fe2O3 in an amount from 0.0 to 1.0% by weight, B2O3 in an amount from 0.0 to about 3.0% by weight, K2O, Fe2O3, ZrO2, and Fluorine, each of which is present in an amount from 0.0 to about 1.0% by weight, and SrO and ZnO, each of which is present in an amount from 0.0 to about 2.0% by weight. In exemplary embodiments, the glass composition does not contain lithium or boron.Type: ApplicationFiled: August 4, 2010Publication date: May 31, 2012Applicant: OCV-Intellectual Capital, LLCInventors: Douglas Hoffman, Peter McGinnis, John Wingert, Anne Berthereau
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Publication number: 20120129678Abstract: A high-intensity and high-modulus glass fiber is provided. Said fiber is produced by improving the processes, components and proportion of conventional E-glass production process and apparatus. The fiber contains 13% CaO at most, no boron and fluorine, meanwhile ZrO2 and Li2O is first added, B2O3 is first removed, and SO3 is added. The intensity and the modulus of the fiber are slightly lower than those of S-glass or T-glass, but obviously higher than those of E-glass and ECR-glass which are highly produced and widely used or other boron-free glass such as Advantex glass. Besides the intensity, modulus and fatigue resistance, said fiber has obvious advantages over E-glass in heat, acid and alkali resistance. The glass fiber roving made from said fiber has 22% higher tensile strength and 11˜15.7% higher modulus than those of E-glass, and has 16% higher tensile strength and 5˜6% higher modulus than those of ECR-glass.Type: ApplicationFiled: July 2, 2010Publication date: May 24, 2012Applicant: CHONGQING POLYCOMP INTERNATIONAL CORPORATIONInventor: Zhiyao Tang
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Patent number: 8173560Abstract: The invention relates to a glass strand, the chemical composition of which is substantially free of boron oxide and comprises the following constituents, in the limits defined below expressed as percentages by weight: SiO2 55 to 65 Al2O3 ?9 to 16 CaO 15 to 26 MgO 1 to 5 BaO + SrO 0.5 to 5?? Na2O + K2O + Li2 O 0 to 2 TiO2 0 to 1 ZnO 0 to 2 ZrO2 0 to 2. It also relates to composites comprising such strands.Type: GrantFiled: December 19, 2007Date of Patent: May 8, 2012Assignee: Saint-Gobain Technical Fabrics EuropeInventors: Anne Berthereau, Emmanuel Lecomte
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Publication number: 20120064788Abstract: The present invention relates to fiber glass strands, yarns, fabrics, composites, prepregs, laminates, fiber-metal laminates, and other products incorporating glass fibers formed from glass compositions. The glass fibers, in some embodiments, are incorporated into composites that can be used in reinforcement applications. Glass fibers formed from some embodiments of the glass compositions can have certain desirable properties that can include, for example, desirable electrical properties (e.g. low Dk) or desirable mechanical properties (e.g., specific strength).Type: ApplicationFiled: September 14, 2011Publication date: March 15, 2012Inventors: James Carl Peters, Juan Camilo Serrano, Hong Li, Cheryl A. Richards, Steven Joel Parks
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Publication number: 20120058878Abstract: Glass compositions are provided that are useful in a variety of applications including, for example, electronics applications, reinforcement applications, and others. Some embodiments of glass compositions can provide desirable dielectric constants, desirable dissipation factors, and/or desirable mechanical properties while also having desirable fiber forming properties.Type: ApplicationFiled: September 9, 2011Publication date: March 8, 2012Inventors: Hong Li, Cheryl A. Richards
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Patent number: 8093164Abstract: The present invention relates to a high-temperature resistant inorganic fiber which is based on silica and has improved mechanical properties, a process for producing it and also specific uses thereof and products derived therefrom. The fiber of the invention has the following composition: 81-94% by weight of SiO2, 6-19% by weight of Al2O3, 0-12% by weight of ZrO2, 0-12% by weight of TiO2, 0-3% by weight of Na2O and not more than 1.5% by weight of further components.Type: GrantFiled: July 7, 2008Date of Patent: January 10, 2012Assignee: Belchem Fiber Materials GmbHInventors: Robin Richter, Folker Steden, Sven Lehr
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Patent number: 8042363Abstract: The invention relates to producing continuous organic fibers by stretching from molten minerals. These fibers can be used for producing heat resistant threads, rovings, cut fibers, fabrics, composite materials and products based thereon. The inventive glass has the following chemical composition in mass percentage: 15.9-18.1 Al2O3, 0.75-1.2 TiO2, 7.51-9.53 Fe2O3+FeO, 6.41-8.95 CaO, 2.5-6.4 MgO, 1.6-2.72 K2O, 3.3-4.1 Na2O, 0.23-0.5 P2O5, 0.02-0.15 SO3, 0.12-0.21 MnO, 0.05-0.19 BaO, impurities up to 1.0, the rest being SiO2. The inventive method consists in loading a ground composition in a melting furnace, in melting said composition, in homogenizing a melt, in consequently stabilizing the melt in the melting furnace feeder, in drawing and oiling the fiber and in winding it on a spool. Prior to loading, the composition is held in an alkali solution for 15-20 minutes, and is then washed with flowing water for 20-30 minutes and dried.Type: GrantFiled: December 25, 2006Date of Patent: October 25, 2011Inventors: Viktor F. Kibol, Sunao Nakanoo, Alexandr B. Biland, Roman V. Kibol
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Publication number: 20110236684Abstract: A thermally resistant fiber glass includes at least SiO2, Al2O3, and TiO2.Type: ApplicationFiled: July 29, 2008Publication date: September 29, 2011Applicant: S.D.R. BIOTEC VERFAHRENSTECHNIK GMBHInventors: Roman Teschner, Kati Richter, Hans-Peter Richter
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Patent number: RE45450Abstract: A method for producing a glass wool molded product includes the steps of processing a glass material into fibers so as to obtain a glass wool, gathering such glass wools to form a glass wool mat, and subjecting the glass wool mat to press molding, wherein the above described press molding is carried out, while supplying water so that the water content of the above described glass wool mat becomes 0.1% to 7.0% by mass, and while maintaining a temperature between 250° C. and 450° C.Type: GrantFiled: March 18, 2013Date of Patent: April 7, 2015Assignees: Mag-Isover K.K., Panasonic CorporationInventor: Toru Murakami