And Aluminum Patents (Class 501/59)
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Patent number: 5032548Abstract: A composition for use as a road base or levee fill. The composition comprises catalytic cracking catalyst particles in the size range of 1 to 200 microns and a binder the type and amount of which depend on the end use. Hydrated lime is employed as the binder in road base construction while hydrated lime, portland cement, fly ash or mixtures of fly ash and portland cement can be used in levee construction. The catalyst particles are present in amounts of 80% to 96% and the binder is present in amounts of 4% to 20%,both percentage ranges being determiend according to the dry weight of the composition.Type: GrantFiled: February 27, 1990Date of Patent: July 16, 1991Assignee: Marathon Oil CompanyInventor: George E. Lowe
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Patent number: 5028567Abstract: A glass-ceramic obtained by heat treating a parent glass in which specific amounts of MgO and PbO are added to the SiO.sub.2 - Al.sub.2 O.sub.3 - ZnO - TiO.sub.2 system glass has a wide range of coefficients of thermal expansion and improved fineness in diameters of crystals and also improved chemical durability or thermal expansion curve.Type: GrantFiled: May 24, 1988Date of Patent: July 2, 1991Assignee: 501 Kabushiki Kaisha OharaInventors: Naoyuki Gotoh, Makoto Hayasaka
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Patent number: 4983550Abstract: Hollow glass spheres having average densities of approximately 0.10 grams/cc to approximately 2.0 grams/cc are prepared by heating solid glass particles. The glass spheres consist essentially of the following ingredients in the following amounts state as weight percentages: SiO.sub.2 (50 to 57%); R.sub.2 O(2 to 15%); B.sub.2 O.sub.3 (0 to 20%); S(0.05 to 1.5%); RO(2 to 25%); RO.sub.2 (other than SiO.sub.2) (0 to 5%); R.sub.2 O.sub.3 (other than B.sub.2 O.sub.3) (0 to 10%); R.sub.2 O.sub.5 (0 to 5%); and F(0 to 5%). R represents a metal or an element like phosphorous which combines with oxygen in glass. The sizes of the hollow glass spheres are selected to produce a maximum average strength for a desired average density.Type: GrantFiled: August 24, 1988Date of Patent: January 8, 1991Assignee: Potters Industries, Inc.Inventors: Kenneth E. Goetz, James A. Hagarman, Joseph P. Giovene, Jr.
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Patent number: 4980318Abstract: This invention relates to photochromic glasses exhibiting refractive indices greater than 1.59, densities no higher than 3.1 g/cm.sup.3, Abbe numbers of at least 40, weight losses no greater than 0.01 mg/cm.sup.2 in the A.O. test, and which, when exposed to actinic radiation at room temperatures, darken to transmittances below 40% and fade at least 15 percentage points of transmittance after five minutes' removal from the actinic radiation.Type: GrantFiled: May 10, 1989Date of Patent: December 25, 1990Assignee: Corning IncorporatedInventor: Roger J. Araujo
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Patent number: 4973565Abstract: There are disclosed fluoroborosilicate glasses that are particularly adapted to being drawn with lead silicate core glasses to produce clad glass fibers useful in forming fiber optic bundles to be incorporated in night vision equipment. The cladding glass has a refractive index not over about 1.465 and a coefficient of thermal expansion not over about 80.times.10.sup.-7 /.degree.C. The clad fiber has a numerical aperture approximating or equal to one.Type: GrantFiled: July 17, 1989Date of Patent: November 27, 1990Assignee: Corning IncorporatedInventor: Gerald J. Fine
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Patent number: 4970178Abstract: Lead-free glass frit compositions for use in vitreous coatings consisting essentially of Na.sub.2 O--ZnO--B.sub.2 O.sub.3 --SiO.sub.2 in appropriate concentrations including molar amounts of at most 17.5 mole percent of B.sub.2 O.sub.3 and at least 40 mole percent of SiO.sub.2.Type: GrantFiled: August 14, 1989Date of Patent: November 13, 1990Assignee: Ciba-Geigy CorporationInventors: David A. Klimas, Boyd R. Frazee
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Patent number: 4950626Abstract: A process for the production of a refractory compound, e.g. a carbide or nitride, of a metallic or non-metallic element, by reacting a mixture of a compound of the metallic or non-metallic element having at least two groups reactive with hydroxyl groups and an organic compound having at least two hydroxyl groups to produce an oxygen-containing polymeric product, and pyrolysing the polymeric product, e.g. in an inert atmosphere to produce a carbide or in an atmosphere of reactive nitrogen compound to produce a nitride, in which the reaction mixture contains an aluminium compound containing at least one group reactive with hydroxyl groups.The presence of the aluminium compound in the reaction mixture leads to an increase in the proportion of carbon in the product initially produced by pyrolysis, and to a higher purity in the refractory compound which is ultimately produced.Type: GrantFiled: October 27, 1987Date of Patent: August 21, 1990Assignee: Imperial Chemical Industries PLCInventors: James D. Birchall, Mary J. Mockford, David R. Stanley
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Patent number: 4948760Abstract: An inorganic glass having high water repellence produced by irradiating and/or implanting ions upon or into a surface of the inorganic glass, the ions are those of at least one element selected from the group consisting of(a) halogen elements selected from F, Cl, and Br, group 3A, 3B, 4A and 5B elements of the International Periodic Table selected from Al, Ti, Y, In and Bi,(b) rare gas elements selected from He, Ne, Ar, Kr and Xe, group 3A, 4A, 1B, 2B, 3B, 4B and 5B elements of the International Periodic Table selected from Sc, Cu, Zn, Ag, Cd, Sn, Sb, Au, Hg, Tl and Pb, alkali metal or alkaline earth metal elements selected from Li, Na, K, Rb, Cs, Be, Mg, Ca, Sr and Ba, and(c) Ce, the dose of th (a), (b) and (c) ions being 5.times.10.sup.14 to 1.times.10.sup.20 ion/cm.sup.2, 5.times.10.sup.14 to 1.times.10.sup.17 ion/cm.sup.2 and 1.times.10.sup.17 to 1.times.10.sup.20 ion/cm.sup.2, respectively.Type: GrantFiled: September 1, 1989Date of Patent: August 14, 1990Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Takeshi Ohwaki, Yasunori Taga
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Patent number: 4940477Abstract: The present invention is directed to a method for synthesizing fluorine-containing, aluminosilicate crystals having a stoichiometry approximating that of topaz. The method comprises three basic steps:(1) vapors of a readily-oxidizable compound of silicon and of a readily-oxidizable compound of aluminum and fluorine are passed to a flame oxidation burner;(2) amorphous fluorine-containing, aluminosilicate particles resulting from the combustion of those gases are collected; and(3) the collected particles are sintered into an integral body at a temperature between about 650.degree.-925.degree. C.Type: GrantFiled: July 19, 1989Date of Patent: July 10, 1990Assignee: Corning IncorporatedInventors: Peter L. Bocko, David H. Crooker, Lina M. Echeverria
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Patent number: 4933307Abstract: Porous, silica-rich shapes have improved strength and abrasion resistance by leaching the precursor glass shape in preconditioned acid having silica ion and at least one common ion that is also present in the precursor glass shape. The precursor glass shapes have shapes such as fibers, hollow fibers, tubes, rods, beads, hollow spheres and plates and compositions having 30-75 volume percent silica and at least 10-65 volume percent nonsiliceous acid extractable components. Preconditioning of the acid solution results from a pretreatment of the acid with compounds that dissociate into the ions when added to the acid solution or with shapes, particles or fragments of glass compositions different from or similar to the glass shape to be leached so long as the glass composition has extractable material to provide the silica ion and at least one common ion.Type: GrantFiled: April 21, 1988Date of Patent: June 12, 1990Assignee: PPG Industries, Inc.Inventors: William P. Marshall, Joseph J. Hammel, Herbert W. Barch, Roy D. Hegedus, Walter J. Robertson
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Patent number: 4920082Abstract: This invention is directed to the preparation of fluoride-containing glasses wherein, when exposed to aqueous solutions, fluoride will be leached therefrom in a controlled manner over a long period of time and which can be melted and formed with little loss of fluorine through volatilization. The glasses are essentially free from alkali metal oxides and heavy toxic metals and consist essentially, in weight percent, of:SiO.sub.2 : 41.4-55.9BaO: 24.7-33.6Al.sub.2 O.sub.3 : 5.6-11B.sub.2 O.sub.3 : 6.5-10.Type: GrantFiled: October 25, 1989Date of Patent: April 24, 1990Assignee: Corning IncorporatedInventor: Paul S. Danielson
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Patent number: 4870034Abstract: The invention relates to a borosilicate glass for the manufacturing of laboratory glass, domestic glass, pharmaceutical container glass, lamp glass and X-ray tube glass. The glass has the following composition:SiO.sub.2 : 74.5 to 76.5% by weightB.sub.2 O.sub.3 : 10.0 to 12.0% by weightAl.sub.2 O.sub.3 : 3.5 to 6.0% by weightNa.sub.2 O: 6.0 to 8.0% by weightCaO: 1.0 to 2.0% by weightZrO.sub.2 : 0 to 0.50% by weightF: 0 to 1.0% by weightAs.sub.2 O.sub.3 and/or Sb.sub.2 O.sub.3 and/or NaCl are used as refining agent.Type: GrantFiled: July 5, 1988Date of Patent: September 26, 1989Assignee: Schott GlaswerkeInventor: Werner Kiefer
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Patent number: 4868141Abstract: There are disclosed fluoroborosilicate glasses that are particularly adapted to being drawn with lead silicate core glasses to produce clad glass fibers useful in forming fiber optic bundles to be incorporated in night vision equipment. The cladding glass has a refractive index not over about 1.45 and a coefficient of thermal expansion not over about 120.times.10.sup.-7 /.degree.C. The clad fiber has a numerical aperture approximating or equal to one.Type: GrantFiled: December 2, 1988Date of Patent: September 19, 1989Assignee: Corning IncorporatedInventor: Gerald J. Fine
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Patent number: 4859634Abstract: A complex oxide comprising zirconium oxide and an oxide of at least one metal selected from the group consisting of an alkali metals, alkaline earth metals, silicon and lead is mixed with pottery stone, magnesium fluoride, a compound capable of forming magnesium oxide, a compound capable of forming potassium oxide and a compound capable of forming boron oxide to obtain a composition in which the contents of elements in 100 parts by weight of the total amount exclusive of the ignition loss are 16 to 25 parts of silicon, 6 to 9 parts of aluminum, 5.5 to 12 parts of potassium, 4.7 to 15 parts of magnesium, 0.7 to 5.0 parts of zirconium, 0.7 to 3.2 parts of boron, 3.0 to 9.3 parts of fluorine, up to 7.0 parts of metals other than the foregoing elements, and the balance being oxygen. This composition is heat-melted and then cooled from a temperature higher at least 50.degree. C. than the glass transition temperature of a vitreous body to be formed to a temperature lower by at least 70.degree. C.Type: GrantFiled: September 11, 1987Date of Patent: August 22, 1989Assignee: Photon Ceramics Kabushiki KaishaInventors: Motoshige Iwamatsu, Mitsugu Kaji
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Patent number: 4859637Abstract: The present invention relates to an improved U.V. absorbing glass composition comprising from about 75 to about 98 parts by weight of a lead oxide free base glass having dissolved therein from about 2 to about 25 parts by weight of a U.V. additive selected from the group consisting of cerium oxide, manganese oxide, iron oxide, cobalt oxide, copper oxide, vanadium oxide, molybdenum oxide, and mixtures of two or more of said oxides; and to an ink composition comprising from about 15 to about 25% by weight vehicle, from about 8 to about 16% by weight a ceramic pigment, and from about 59 to about 77% by weight of said U.V. absorbing glass composition.Type: GrantFiled: December 17, 1987Date of Patent: August 22, 1989Assignee: Ferro CorporationInventor: Gordon J. Roberts
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Patent number: 4786617Abstract: This invention relates to the preparation of glass-ceramic articles in which potassium fluorrichterite and/or a related fluormica constitutes the predominant crystal phase(s). The precursor glasses can be crystallized in situ very rapidly and exhibit very little thermal deformation during the crystallization heat treatment. The base glasses are essentially free of Li.sub.2 O and consist essentially, expressed in terms of weight percent on the oxide basis, of:______________________________________ SiO.sub.2 61-70 Na.sub.2 O 0.5-3 BaO 0-3.5 Al.sub.2 O.sub.3 2.75-7 K.sub.2 O 2.5-5.5 P.sub.2 O.sub.5 0-2.5 MgO 11-16 Na.sub.2 O + K.sub.2 O <6.8 CaO 4.75-9 F 2-3.Type: GrantFiled: March 3, 1988Date of Patent: November 22, 1988Assignee: Corning Glass WorksInventors: Andre Andrieu, Marie J. M. Comte, Frederic J. M. Ferry, Jean-Pierre Mazeau
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Patent number: 4783429Abstract: A biocompatible glass ceramic comprises, by weight, 7-16% MgO, 20-45% CaO, 41-50% SiO.sub.2, 8-30% P.sub.2 O.sub.5, 0-5% B.sub.2 O.sub.3, 0-5% F.sub.2, and 0-10% Al.sub.2 O.sub.3, and has a crystal structure where a number of fine crystals of apatite, wollastonite, and diopside are densely dispersed and interlace with one another in a glass phase. The glass ceramic is non-porous and has an increased mechanical strength of 2,000 Kg f/cm.sup.2 without degradation of the chemical bonding with the bone of the living body. The glass ceramic contains no alkali and is chemically stable in the living body. The glass ceramic is useful for replacement materials of tooth roots and crowns as well as bones.Type: GrantFiled: April 2, 1987Date of Patent: November 8, 1988Assignee: Nippon Electric Glass Company, LimitedInventors: Takehiro Shibuya, Yoshinori Morita, Akira Matsui
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Patent number: 4771019Abstract: Reduced boron containing glass fibers are provided which have a refractive index similar to that of higher boron-containing glass fiber compositions. The glass fibers with a refractive index in the range of greater than 1.5495 to around 1.57 have in weight percent SiO.sub.2 - 55-56.5, CaO - 20-23, Al.sub.2 O.sub.3 14.5-15.5, B.sub.2 O.sub.3 - 5 to 5.8, R.sub.2 O - 1-1.5, wherein R is an alkali metal and F.sub.2 - 0.4 to 0.6. In addition, the glass fiber composition can have minor constituents such as TiO.sub.2 of up to around 0.6 weight percent and an MgO of up to around 0.3 weight percent and ferric oxide of up to around 0.3 weight percent. Basically, the glass fibers have a reduced content of both B.sub.2 O.sub.3 and CaO over standard glass fiber compositions such as E-glass and 621-glass and also has elevated amounts of alkali and of refractory constituents such as SiO.sub.2 and Al.sub.2 O.sub.3. The glass fibers are formed with an elevated temperature of 40.degree. to 50.degree. F. (22.degree.-28.degree.Type: GrantFiled: September 29, 1986Date of Patent: September 13, 1988Assignee: PPG Industries, Inc.Inventor: James F. Sproull
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Patent number: 4768859Abstract: A cladding glass for optical fiber comprises 60 to 80% by weight of silicon dioxide (SiO.sub.2), 0.5 to 10% by weight of aluminum oxide (Al.sub.2 O.sub.3), 9 to 17% by weight of an alkali metal oxide, 3 to 15% by weight of boron oxide (B.sub.2 O.sub.3) and more than 0 but not more than 3% by weight of fluorine (F). The cladding glass of this invention can simultaneously satisfy low refractive index and lowered viscosity, and is also excellent in water resistance and weathering resistance.Type: GrantFiled: October 22, 1987Date of Patent: September 6, 1988Assignees: Kabushiki Kaisha Toshiba, Showa Electric Wire & Cable Co., Ltd.Inventors: Mituo Kasori, Hiroshi Imagawa, Hironori Maki, Kenji Yagi, Osamu Kokubo
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Patent number: 4721690Abstract: High PbO-content glass in the optical range of flint and heavy flint glasses from the system SiO.sub.2 --PbO--M.sub.2 O wherein M.sub.2 O=alkali metal oxides, said glass having a minimum PbO content of 30 wt. % and a minimum M.sub.2 O content of 0.5 wt. %, are provided with enhanced chemical stability without loss of the desired optical position by replacing a portion of the SiO.sub.2 and PbO such that the glass contains 1.5-6 wt. % (TiO.sub.2 +ZrO.sub.2) and the ratio of TiO.sub.2 :ZrO.sub.2 is about 0.3-2.0.Type: GrantFiled: February 5, 1985Date of Patent: January 26, 1988Inventors: Ludwig Ross, Danuta Grabowski, Burkhard Speit, Volkmar Geiler
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Patent number: 4719186Abstract: An optical and ophthalmic glass with high refractive index, high Abbe number and low density, which is distinguished by good chemical stability, good crystallization behavior and capability of chemical hardening, comprises (in % by weight):______________________________________ SiO.sub.2 50-63 B.sub.2 O.sub.3 4-8 Al.sub.2 O.sub.3 1-2 Li.sub.2 O 4-8 Na.sub.2 O 4-8 K.sub.2 O 3-7 sum of M.sub.2 O 11-20 (M = Li, Na, K) MgO 0.5-2 CaO 2-5 sum of MO 0-3 (M = Mg, Ca) TiO.sub.2 8-12.5 ZrO.sub.2 1-3 F.sup.- 0-1 As.sub.2 O.sub.3 0.05-0.15 (optional refining agent) Sb.sub.2 O.sub.3 0.0-0.Type: GrantFiled: April 16, 1986Date of Patent: January 12, 1988Assignee: Schott GlaswerkeInventors: Karl Mennemann, Georg Gliemeroth, Ludwig Ross, Burkhard Speit, Volkmar Geiler, Hans-Georg Krolla, Lothar Meckel
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Patent number: 4687751Abstract: This invention relates to the production of opal glasses having a creamy-white tint which are suitable for forming culinary articles. The opacity is obtained through precipitation of fluorides, preferably NaF. The creamy-white tint results from the association of Fe.sub.2 O.sub.3 with TiO.sub.2 and/or As.sub.2 O.sub.3 and/or CeO.sub.2, with the addition of nitrates. The preferred composition of the final glass consists essentially, in weight percent, of:______________________________________ SiO.sub.2 70-73 Fe.sub.2 O.sub.3 0.1-0.25 Na.sub.2 O 10.5-13 TiO.sub.2 0.1-0.7 Fluorine 4-5.5 As.sub.2 O.sub.3 0.05-0.4 Al.sub.2 O.sub.3 6-9 CeO.sub.2 0-0.2 CaO 0.2-1.7 B.sub.2 O.sub.3 0.5-3 BaO 1-3 ______________________________________The starting composition contains NaNO.sub.3 in a proportion of 0.2-2 by weight, counted as Na.sub.2 O with regard to the glass, or an equivalent quantity of another alkali metal or alkaline earth metal nitrate.Type: GrantFiled: March 6, 1986Date of Patent: August 18, 1987Assignee: Corning Glass WorksInventors: Pernette R. M. Barlier, Jean-Pierre Mazeau
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Patent number: 4665039Abstract: A process for producing a porous glass which comprises forming a shaped product of borosilicate glass having a predetermined shape, heat-treating the shaped product for phase separation to form a silica rich insoluble phase and an alkali and boric oxide rich soluble phase, leaching out the soluble phase from the insoluble phase with an acid or an alkali to obtain a porous glass, wherein said shaped product of borosilicate glass is composed essentially of from 45 to 67% by weight of SiO.sub.2, from 0.5 to 10% by weight of Al.sub.2 O.sub.3, from 10 to 30% by weight of B.sub.2 O.sub.3, from 0.5 to 8% by weight of Na.sub.2 O, from 0.1 to 8% by weight of K.sub.2 O+Li.sub.2 O+Cs.sub.2 O, from 0.5 to 7% by weight of CaO, from 0.5 to 15% by weight of MgO+BaO+SrO, from 0 to 10% by weight of ZrO.sub.2 +TiO.sub.2 and from 0.03 to 3% by weight of F+SO.sub.3 +Cl+As.sub.2 O.sub.3 +Sb.sub.2 O.sub.3.Type: GrantFiled: October 17, 1985Date of Patent: May 12, 1987Assignee: Asahi Glass Company, Ltd.Inventors: Yoshinori Kokubu, Jiro Chiba, Kozo Saita
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Patent number: 4640900Abstract: A low expansion glass comprising, all by weight, from 55 to 65% of SiO.sub.2, from 10 to 20% of Al.sub.2 O.sub.3, from 2 to 10% of B.sub.2 O.sub.3, from 3 to 10% of MgO, from 1 to 8% of CaO, from 2 to 10% of ZnO, from 0 to 4% of R.sub.2 O where R is an alkali metal atom, and from 0 to 4% of ZrO.sub.2.Type: GrantFiled: July 27, 1984Date of Patent: February 3, 1987Assignee: Asahi Glass Company, Ltd.Inventors: Yoshinori Kokubu, Makoto Moriyasu
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Patent number: 4628038Abstract: A water resistant, devitrification resistant glass fiber consisting essentially of SiO.sub.2, Al.sub.2 O.sub.3, CaO, MgO, B.sub.2 O.sub.3, Na.sub.2 O, and F.sub.2 and/or Fe.sub.2 O.sub.3 and/or TiO.sub.2 and/or K.sub.2 O and/or SO.sub.3 in trace amounts, said glass fiber having a delta T of at least about 365.degree. F. and a durability (% fiber weight loss at 96.degree. C.) in water for 24 hours of less than about 0.9%.Type: GrantFiled: June 27, 1985Date of Patent: December 9, 1986Assignee: Owens-Corning Fiberglas CorporationInventor: Douglas A. Weirauch, Jr.
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Patent number: 4615988Abstract: Glass fibers having the following constituents in the ranges of proportions indicated: SiO.sub.2, 57-70 wt. %; Al.sub.2 O.sub.3, 2-7 wt. %; CaO, 5-10 wt. %; MgO, 0-4 wt. %; B.sub.2 O.sub.3, 0-4.5 wt. %; and F, 0.5-4 wt. %; and wherein B.sub.2 O.sub.3 and F are present in amounts according to the relationship:3.ltoreq.B.sub.2 O.sub.3 +1.5 F.ltoreq.6.5and wherein the fibers also contain the alkali oxides Na.sub.2 O and K.sub.2 O, in amounts according to the relationship:16 wt. %<Na.sub.2 O+K.sub.2 O<20 wt. %.The glass fibers are used advantageously in thermal and/or acoustic insulation.Type: GrantFiled: September 19, 1984Date of Patent: October 7, 1986Assignee: Isover Saint-GobainInventors: Simone Le Moigne, Marcel Boivent, Guy Matzen
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Patent number: 4609632Abstract: Alkali-free glasses with low dielectric losses, thermal expansion coefficients of 3.15 to 4.97.times.10.sup.-6 /.degree.C. in the temperature range from 20.degree. to 300.degree. C., adequate acid resistance, dielectric loss factors tan .delta. of 3.94 to 24.9.times.10.sup.-4 and processing temperatures (V.sub.A) of 1132.degree. to 1280.degree. C., have the following composition (in weight percent): 52.50-60.20 SiO.sub.2, 2.80-3.80 B.sub.2 O.sub.3, 8-14 Al.sub.2 O.sub.3, 6.0-20.20 PbO, 2.0-13.5 CaO, 0-3.5 MgO, 0-8 ZnO, 0-4.7 BaO, .SIGMA.PbO, CaO, MgO, ZnO, BaO 21.10-34.0, 0-1.0 F, 0.20-0.50 Sb.sub.2 O.sub.3.Type: GrantFiled: August 14, 1985Date of Patent: September 2, 1986Assignee: Schott GlaswerkeInventor: Werner Sack
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Patent number: 4608349Abstract: Photochromic glass compositions for thin refractive-index-corrected lens elements consisting essentially of about:______________________________________ SiO.sub.2 54-58% B.sub.2 O.sub.3 18-22% Al.sub.2 O.sub.3 7-8% Li.sub.2 O 3.75-4.5% Na.sub.2 O 0-1% K.sub.2 O 5.5-7.5% TiO.sub.2 0-2% ZrO.sub.2 2-4.5% Ag 0.20-0.33% Cl 0.30-0.50% Br 0.04-0.12% CuO 0.007-0.012% PbO 0-0.08% Sb.sub.2 O.sub.3 0-0.20% ______________________________________having a Li.sub.2 O:Na.sub.2 O molar ratio of at least 9:1 and exhibiting good darkening, fast fading, good chemical strengthenability and neutral dark-state coloration at thicknesses on the order of 1 mm, are described.Type: GrantFiled: November 28, 1985Date of Patent: August 26, 1986Assignee: Corning Glass WorksInventors: David J. Kerko, David W. Morgan, David L. Morse
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Patent number: 4590171Abstract: This invention relates to the production of frits especially suitable for use in contact with foods. The frits are essentially free from cadmium and lead and consist essentially, in weight percent on the oxide basis, of:Li.sub.2 O: 3-4Na.sub.2 O: 0.75-3BaO: 3.5-9.5B.sub.2 O.sub.3 : 14-17.5Al.sub.2 0.sub.3 : 6.75-8.75SiO.sub.2 : 48-55ZrO.sub.2 : 6.75-10.5F: 3-4.Type: GrantFiled: May 29, 1985Date of Patent: May 20, 1986Assignee: Corning Glass WorksInventor: Jaroslava M. Nigrin
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Patent number: 4582760Abstract: The present invention is concerned with the preparation of glazes which are especially suitable for application to glass-ceramic articles containing potassium fluorrichterite as substantially the sole crystal phase. The glazes consist essentially, expressed in terms of weight percent on the oxide basis, ofSiO.sub.2 :46-50Al.sub.2 O.sub.3 :5-8ZrO.sub.2 :0.3-1Li.sub.2 O:1-2Na.sub.2 O:2-3.5K.sub.2 O:1-2CaO:1-4ZnO:2-6SrO:2-6B.sub.2 O.sub.3 :9-11PbO:20-25.Type: GrantFiled: May 20, 1985Date of Patent: April 15, 1986Assignee: Corning Glass WorksInventors: George H. Beall, Paul S. Danielson, John E. Megles, Jr., Walter H. Tarcza
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Patent number: 4578362Abstract: Metal vaporization from precious metals is reduced by applying to the surface of the metal a flame sprayed coating comprising a refractory material and a glass.Type: GrantFiled: April 1, 1985Date of Patent: March 25, 1986Assignee: Owens-Corning Fiberglas CorporationInventor: Gary B. A. Schuster
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Patent number: 4576922Abstract: A strong white ceramic composition and method of making the same wherein said composition is characterized by an average coefficient of thermal expansion over the range of 25.degree. C. to 500.degree. C. ("Proposed American National Standards Institute/American Dental Association Specification No. 38.1 For Porcelain-Alloy Systems") of between 14 to 16.times.10.sup.-6 /.degree.C. and a transverse strength of about 18,000 psi or even greater. The ceramic composition comprises about 40 to 60% by weight crystalline magnesium oxide particles (e.g., 74 .mu.m ) dispersed in a modified silicate glass containing at least 3% by weight of dissolved ZrO.sub.2, TiO.sub.2 or mixtures thereof and is made by firing a powdered mixture of MgO.sub.2 and modified silicate glass at about 1150.degree. C. for sufficient time to produce a fine dispersion of forsterite (Mg.sub.2 SiO.sub.4) in the continuous glass matrix phase along with the crystalline magnesia particles.Type: GrantFiled: January 9, 1985Date of Patent: March 18, 1986Assignee: The Regents of the University of MichiganInventors: William J. O'Brien, Matthew T. O'Brien
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Patent number: 4562161Abstract: An optical and ophthalmic glass with high refractive index, high Abbe number and low density, which is distinguished by good chemical stability, good crystallization behavior and capability for chemical hardening, comprises (in % by weight):SiO.sub.2 --47 to 75B.sub.2 O.sub.3 --1 to 20Al.sub.2 O.sub.3 --0 to 10P.sub.2 O.sub.5 --0 to 5Li.sub.2 O--0 to 15Na.sub.2 O--0 to 10K.sub.2 O--0 to 10CaO--0 to 20MgO--0 to 15SrO--0 to 4BaO--0 to 4ZnO--0 to 5TiO.sub.2 --1 to 15ZrO.sub.2 --0 to 8Nb.sub.2 O.sub.5 --0 to 5 andF----0 to 5.Type: GrantFiled: February 18, 1983Date of Patent: December 31, 1985Assignee: Schott GlaswerkeInventors: Karl Mennemann, Georg Gliemeroth, Ludwig Ross, Burkhard Speit, Volkmar Geiler, Hans-Georg Krolla, Lothar Meckel
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Patent number: 4560666Abstract: A high strength glass-ceramic containing apatite and alkaline earth metal silicate (diopside/forsterite/akermanite) crystals having an excellent affinity for a living body and a process for producing the same are disclosed. The glass-ceramic is useful as an implant material such as an artificial dental root and an artificial bone.Type: GrantFiled: December 6, 1984Date of Patent: December 24, 1985Assignee: Hoya CorporationInventors: Masahiro Yoshida, Kenji Nakagawa
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Patent number: 4536480Abstract: This invention is drawn to spontaneous opal glasses containing an apatite-type crystal opacifying phase and exhibiting a temperature interval between the emulsion and high temperature crystallization liquidi of at least 50.degree. C. which consist essentially, in weight percent on the oxide basis, of______________________________________ Na.sub.2 O 7.5-11 B.sub.2 O.sub.3 2-4.5 K.sub.2 O 0-5 SiO.sub.2 57-65 Na.sub.2 O + K.sub.2 O .ltoreq.13 P.sub.2 O.sub.5 2-5.5 BaO 0-9.5 F 1.5-4 CaO 0-3 SrO 0-5 ZnO 0.4-5 MgO 0-2.5 Al.sub.2 O.sub.3 8-13 SrO + MgO 0-5 ______________________________________CaO and/or SrO and/or BaO at least 2.5 mole %.Type: GrantFiled: March 23, 1984Date of Patent: August 20, 1985Assignee: Corning Glass WorksInventors: James E. Flannery, John L. Stempin, Dale R. Wexell
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Patent number: 4536481Abstract: This invention is directed to spontaneous opal glasses containing an apatite opacifying phase and exhibiting a softening point of at least 740.degree. C., excellent chemical durability, and a temperature interval between the high temperature crystallization liquidus and the emulsion liquidus greater than 50.degree. C. The glasses consist essentially, in weight percent on the oxide basis, of______________________________________ SiO.sub.2 50-63 Na.sub.2 O 5.5-10 Al.sub.2 O.sub.3 10-14 K.sub.2 O 0-10 P.sub.2 O.sub.5 3.5-7 BaO 0-10 PbO 2-12 CaO 0-2.5 B.sub.2 O.sub.3 1-4 SrO 0-8 F 1.Type: GrantFiled: March 23, 1984Date of Patent: August 20, 1985Assignee: Corning Glass WorksInventors: James E. Flannery, John L. Stempin, Dale R. Wexell
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Patent number: 4532223Abstract: This invention relates to the production of sodium fluoride opal glasses tinted in a shade lying in the range from "cream-like" to "beige" by an iron-sulfur system, the analyzed quantities of sulfur (S), sulfide ions (S.sup.-2), iron (Fe), and ferric ions (Fe.sup.+3) conforming to the following expressions:S.sup.-2 /S.gtoreq.0.1570.ltoreq.Fe.ltoreq.300 ppm0.05.ltoreq.Fe.sup.+3 /Fe.sup.+2 .ltoreq.1and 3.ltoreq.S.sup.-2 .ltoreq.160 ppm when the ZnO content is below 0.1%. The glasses are especially applicable for use in culinary ware.Type: GrantFiled: March 14, 1984Date of Patent: July 30, 1985Assignee: Corning Glass WorksInventors: Pernette R. M. Barlier, Jean-Pierre Mazeau
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Patent number: 4526874Abstract: An optical glass with the familiar optical position of n.sub.d >1.70 and v.sub.d >22, which differs from the familiar optical glasses of the optical position due to its lower density and good chemical stability, and is composed of (in percent by weight): SiO.sub.2 25-42, TiO.sub.2 15-35, B.sub.2 O.sub.3 0.5-7, BaO 3-13, CaO 1-3, Nb.sub.2 O.sub.5 1-20, GeO.sub.2 0-2, Al.sub.2 O.sub.3 0-4, Na.sub.2 O 7.5-15, Li.sub.2 O 0-9, K.sub.2 O 2-10, SrO 0-6, ZnO 0-5, ZrO.sub.2 0-3, and WO.sub.3 0-3.Type: GrantFiled: April 27, 1983Date of Patent: July 2, 1985Assignee: Schott GlaswerkeInventors: Danuta Grabowski geb. Marszalek, Ludwig Ross, Volkmar Geiler, Karl Mennemann
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Patent number: 4520115Abstract: These objects have been attained by providing highly absorbent lead containing alkali metal silicate glasses for cathode ray tube image screens, having a linear absorption coefficient .mu. of >30 cm.sup.-1 (0.6 .ANG.) and with a high resistance to discoloration by X-ray and electron radiation, comprises, in weight percent:______________________________________ SiO.sub.2 20-65% P.sub.2 O.sub.5 + B.sub.2 O.sub.3 + Al.sub.2 O.sub.3 0-30% Li.sub.2 O 0-5% Na.sub.2 O 0-10% K.sub.2 O 0-15% MgO + CaO + ZnO 0-15% SrO 0-20% BaO 0-40% PbO 5-60% ZrO.sub.2 0-10% CeO.sub.2 0.1-5% Other Components 0-20%.Type: GrantFiled: August 2, 1983Date of Patent: May 28, 1985Assignee: Schott GlaswerkeInventors: Burkhard Speit, Karl Mennemann, Georg Gliemeroth
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Patent number: 4515897Abstract: Partially crystallizing glass solders, and stripping films using them as agents to be transferred, which are sintered at temperatures below 900.degree. C. from glass powder with granulation of less than <150 .mu.m, thereafter exhibiting thermal expansion coefficients of -23.5 to 34.3.sup..multidot. 10.sup.-7.multidot. K.sup.-1, whose crystallization temperature lies below 710.degree. C. and whose crystal phase consists predominantly of h-quartz mixed crystal phase exhibiting the following composition (in weight %): 23-44 SiO.sub.2, 20-37 Al.sub.2 O.sub.3, 5.5-11 Li.sub.2 O; 3-20 B.sub.2 O.sub.3 ; 0-36 PbO; 0-1 Na.sub.2 O; 0-1.5 K.sub.2 O; 0-0.1 F; 0-4 TiO.sub.2 ; 0-3.5 MgO; 0-2 CoO, provided B.sub.2 O.sub.3 +PbO+Na.sub.2 O+K.sub.2 O+F+TiO.sub.2 is 8.5-50.0.Type: GrantFiled: January 23, 1984Date of Patent: May 7, 1985Assignee: Schott GlaswerkeInventors: Werner Sack, Werner Kiefer
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Patent number: 4510252Abstract: A devitrification resistant, sulfuric acid resistant and water resistant glass fiber consisting essentially of SiO.sub.2, Al.sub.2 O.sub.3, CaO, MgO, Na.sub.2 O and/or K.sub.2 O, B.sub.2 O.sub.3, and optionally Fe.sub.2 O.sub.3, and/or TiO.sub.2 and/or F.sub.2, said glass fiber having delta T of at least about 395.degree. F. and a durability (% fiber weight loss at 96.degree. C.) in water for 24 hours of less than about 1.6% and in 10% H.sub.2 SO.sub.4 for 24 hours of less than about 1.1%.Type: GrantFiled: November 18, 1983Date of Patent: April 9, 1985Assignee: Owens-Corning Fiberglas CorporationInventor: Russell M. Potter
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Patent number: 4469799Abstract: This invention relates to easily meltable, thermally opacifiable, dense white opal glasses which exhibit satisfactory weathering resistance and consist essentially, in weight percent, of 7-12% Na.sub.2 O, 0.8-3.8% CaO, 3-7% Al.sub.2 O.sub.3, 4-8% B.sub.2 O.sub.3, 69-75% SiO.sub.2, and 3.5-4.5% F.Type: GrantFiled: April 25, 1983Date of Patent: September 4, 1984Assignee: Corning Glass WorksInventor: William H. Dumbaugh, Jr.
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Patent number: 4437192Abstract: A biologically active glass and class-ceramic composition useful for making surgical and dental implants comprising, by mol %,:______________________________________ SiO.sub.2 35.about.60 B.sub.2 O.sub.3 5.about.15 Na.sub.2 O 10.about. 30 CaO 5.about. 40 TiO.sub.2 0.5.about. 10 P.sub.2 O.sub.5 0.about. 15 K.sub.2 O 0.about. 20 Li.sub.2 O 0.about. 10 MgO 0.about. 5 Al.sub.2 O.sub.3 + ZrO.sub.2 + Nb.sub.2 O.sub.5 0.about. 8 La.sub.2 O.sub.3 + Ta.sub.2 O.sub.5 + Y.sub.2 O.sub.3 0.about.8 and F.sub.2 0.about.15.Type: GrantFiled: March 16, 1983Date of Patent: March 20, 1984Assignee: Nippon Kogaku K.K.Inventors: Takamitsu Fujiu, Makoto Ogino, Michio Kariya, Takeo Ichimura
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Patent number: 4438211Abstract: A borosilicate glass composition suitable for use as an eyeglass lens, characterized by having a refractive index nd.gtoreq.1.58, an Abbe number vd.gtoreq.45, a density .rho..ltoreq.2.75 g/cm.sup.3, and an excellent aptitude for chemical hardening, consisting essentially of the following composition, in weight percent:______________________________________ SiO.sub.2 51-65 B.sub.2 O.sub.3 2-14 Al.sub.2 O.sub.3 0-5 SiO.sub.2 + B.sub.2 O.sub.3 + Al.sub.2 O.sub.3 62-73 Li.sub.2 O 4-13 Na.sub.2 O 0-4 K.sub.2 O 0-4 Li.sub.2 O + Na.sub.2 O + K.sub.2 O 7-15 CaO 1-19 MgO 0-11 CaO + MgO 6-22 TiO.sub.2 0-8 ZrO.sub.2 0-9.Type: GrantFiled: September 30, 1982Date of Patent: March 20, 1984Assignee: Schott GlaswerkeInventors: Karl Mennemann, Georg Gliemeroth, Volkmar Geiler
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Patent number: 4433092Abstract: A lead-free green ceramic body useful after firing as an electrical resistor, and a method for producing such a resistor, are disclosed. The method preferably comprises the steps of preparing a uniform, finely-divided mixture by blending, by weight, substantially 69 percent of a glass frit with substantially 8 percent of AlPO.sub.4, substantially 3 percent of conductive carbon and substantially 20 percent of a phenyl lower alkyl silicone resin which is curable to form a temporary binder for the conductive carbon and the glass frit. One preferred frit consists essentially of substantially 43 percent SiO.sub.2, 20 percent B.sub.2 O.sub.3, 21 percent Na.sub.2 O, 3 percent CaO, 8 percent BaO and 5 percent Li.sub.2 O. A shape is then pressed from the mixture; the shape is heated to 450-550 degrees F. for about 30 minutes and cooled to ambient temperature. Silver paint is then applied to the cooled shape and the painted shape is fired to vitrify the frit of the resistor.Type: GrantFiled: September 27, 1982Date of Patent: February 21, 1984Assignee: Champion Spark Plug CompanyInventor: Joseph Nemeth
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Patent number: 4414281Abstract: This invention is directed to the production of composite articles composed of a substrate consisting of a machinable glass-ceramic and an integral, electrically-conductive surface layer consisting of metallic copper and/or silver. The inventive articles are prepared by heat treating precursor glass bodies containing copper and/or silver ions to grow fluormica crystals therein, thereby producing glass-ceramics, and to cause migration of the copper and/or silver ions to the surface thereof which are reduced to metallic copper and/or silver via heat treating in a reducing atmosphere. Where desired, holes can be bored, drilled, or punched into the glass-ceramic prior to exposure to the reducing heat treatment such that, upon heat treatment in a reducing environment, the sides of the holes will become metal plated.Type: GrantFiled: February 16, 1982Date of Patent: November 8, 1983Assignee: Corning Glass WorksInventor: Syed N. Hoda
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Patent number: 4386162Abstract: The instant invention is directed to the production of highly crystalline glass-ceramic articles demonstrating high intrinsic mechanical strength and toughness containing crystals of canasite and/or agrellite and/or fedorite as the predominant crystal phase. The articles have overall compositions consisting essentially, expressed in terms of weight percent on the oxide basis, of about______________________________________ SiO.sub.2 45-75 CaO 8-30 F 3.5-12 Na.sub.2 O 3-15 K.sub.2 O 0-20 Na.sub.2 O + K.sub.2 O 5-25 B.sub.2 O.sub.3 0-6 Al.sub.2 O.sub.3 0-7 ZrO.sub.Type: GrantFiled: October 5, 1981Date of Patent: May 31, 1983Assignee: Corning Glass WorksInventor: George H. Beall
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Patent number: 4376169Abstract: A lead-free low-melting frit is made by combining raw materials in amounts such that the product will have a specific oxide analysis, melting the raw materials at a temperature greater than 1000.degree. C. and cooling the thus-formed fused glass in a manner such that a frit is formed. The low-melting frit has the following oxide analysis:7-12.5 parts by weight alkali oxide selected from2-9 parts by weight Na.sub.2 O and 2-7 parts by weight Li.sub.2 O;23-34 parts by weight B.sub.2 O.sub.3 ;2-4 parts by weight Al.sub.2 O.sub.3 ;30-45 parts by weight SiO.sub.2 ;0.75-4 parts by weight F;2-4 parts by weight P.sub.2 O.sub.5 ;4-8 parts by weight ZnO; and2-5 parts by weight TiO.sub.2.These frits are durable, have an incipient fusion point less than about 450.degree. C. and a coefficient of thermal expansion less than 10.times.10.sup.-6 cm/cm/.degree.C. The frits of the present invention are particularly useful as components in vitrifiable glass decorating colors.Type: GrantFiled: April 28, 1982Date of Patent: March 8, 1983Assignee: Mobay Chemical CorporationInventor: Richard A. Eppler
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Patent number: 4367919Abstract: Glass microspheres and other glass elements based on B.sub.2 O.sub.3, BaO, SiO.sub.2 and TiO.sub.2 have an improved combination of crushing strength, index of refraction, and, especially in some formulations, chemical resistance. The microspheres are especially adapted for use as retroreflective elements in pavement markings.Type: GrantFiled: March 19, 1981Date of Patent: January 11, 1983Assignee: Minnesota Mining and Manufacturing CompanyInventors: Chi F. Tung, Benjamin T. Fellows
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Patent number: RE32299Abstract: This invention provides a novel glass composition having numerous uses. More particularly, the invention provides a single phase, radiopaque glass composition.Type: GrantFiled: September 21, 1984Date of Patent: December 2, 1986Assignee: Minnesota Mining and Manufacturing CompanyInventor: Ronald M. Randklev