Optical Glass (e.g., Silent On Refractive Index And/or Abbe Number) Patents (Class 501/900)
  • Patent number: 5024974
    Abstract: Glass having ultrafine particles of CuCl and/or CuBr precipitated therein, which consists essentially of:from 10 to 70 mol % of SiO.sub.2,from 30 to 90 mol % of B.sub.2 O.sub.3,from 0.1 to 50 mol % of Li.sub.2 O+Na.sub.2 O+K.sub.2 O, andfrom 0.01 to 10 mol % of CuCl+CuBr.The glass may further contain from 0.01 to 40 mol % of Al.sub.2 O.sub.3.
    Type: Grant
    Filed: March 22, 1990
    Date of Patent: June 18, 1991
    Assignee: Asahi Glass Company, Ltd.
    Inventors: Arao Nakamura, Tsuneo Manabe, Naoki Sugimoto, Hiroshi Usui
  • Patent number: 5021366
    Abstract: This invention is drawn particularly to the production of glasses having essentially fluorine-free compositions consisting essentially, in mole percent, of:______________________________________ Li.sub.2 O 5-10 P.sub.2 O.sub.5 30-36 Na.sub.2 O 5-15 Al.sub.2 O.sub.3 0-5 K.sub.2 O 0-6 CeO.sub.2 0-2 Li.sub.2 O + Na.sub.2 O + K.sub.2 O 15-25 SnO 0-20 ZnO 10-33 PbO 0-20 CaO 0-20 Sb.sub.2 O.sub.3 0-12 SrO 0-20 Bi.sub.2 O.sub.3 0-6 BaO 0-20 SnO + PbO + 0-20. Sb.sub.2 O.sub.3 + Bi.sub.2 O.sub.
    Type: Grant
    Filed: October 19, 1990
    Date of Patent: June 4, 1991
    Assignee: Corning Incorporated
    Inventor: Bruce G. Aitken
  • Patent number: 4973565
    Abstract: There are disclosed fluoroborosilicate glasses that are particularly adapted to being drawn with lead silicate core glasses to produce clad glass fibers useful in forming fiber optic bundles to be incorporated in night vision equipment. The cladding glass has a refractive index not over about 1.465 and a coefficient of thermal expansion not over about 80.times.10.sup.-7 /.degree.C. The clad fiber has a numerical aperture approximating or equal to one.
    Type: Grant
    Filed: July 17, 1989
    Date of Patent: November 27, 1990
    Assignee: Corning Incorporated
    Inventor: Gerald J. Fine
  • Patent number: 4962995
    Abstract: Glass compositions for high efficiency erbium.sup.3+ -doped optical fiber lasers, amplifiers and superluminescent sources are optimized for pumping by high power solid state lasers in the vicinity of 800 nm to provide amplified signals in wavelengths between 1.5 and 1.7 microns, a principal telecommunications window. A number of suitable host glasses for doping with erbium 3+ are identified wherein the excited state absorption/ground state absorption intensity ratio calculated at 800 nm is 1.00 or less.
    Type: Grant
    Filed: June 16, 1989
    Date of Patent: October 16, 1990
    Assignee: GTE Laboratories Incorporated
    Inventors: Leonard J. Andrews, William J. Miniscalco
  • Patent number: 4902650
    Abstract: A sol-gel method for making gradient-index glass and a novel composition therefor, comprising at least a ternary system of metal alkoxides.
    Type: Grant
    Filed: July 15, 1988
    Date of Patent: February 20, 1990
    Assignee: The University of Rochester
    Inventors: J. Brian Caldwell, Duncan T. Moore
  • Patent number: 4732875
    Abstract: To tellurite optical glass comprising TeO.sub.2, high valence components are added and may be a combination of La.sub.2 O.sub.3, at least one of B.sub.2 O.sub.3 and GeO.sub.2, and at least one of Ta.sub.2 O.sub.5 and Nb.sub.2 O.sub.5. The high valence components may include Y.sub.2 O.sub.3, Gd.sub.2 O.sub.3, and Yb.sub.2 O.sub.3. Amounts of TeO.sub.2 and La.sub.2 O.sub.3 are restricted to ranges between 10% and 80% and between 5% and 35%, respectively. A sum of B.sub.2 O.sub.3 and GeO.sub.2 must fall within a range between 1% and 30%, with an amount of GeO.sub.2 restricted between 0% and 22%. A total of La.sub.2 O.sub.3, Y.sub.2 O.sub.3, Gd.sub.2 O.sub.3, and Yb.sub.2 O.sub.3 must be between 5% and 50%. A sum of Ta.sub.2 O.sub.5 and Nb.sub.2 O.sub.5 should range from 1% to 26%, with individual amounts of Ta.sub.2 O.sub.5 and Nb.sub.2 O.sub.5 kept between 0% and 20% and between 0% and 26%, respectively.
    Type: Grant
    Filed: February 21, 1986
    Date of Patent: March 22, 1988
    Assignee: Hoya Corporation
    Inventor: Koji Sagara
  • Patent number: 4699889
    Abstract: A lead phosphate glass to which has been added indium oxide or scandium oe to improve chemical durability and provide a lead phosphate glass with good optical properties.
    Type: Grant
    Filed: May 9, 1986
    Date of Patent: October 13, 1987
    Assignee: The United States of America as represented by the Department of Energy
    Inventors: Brian C. Sales, Lynn A. Boatner
  • Patent number: 4664473
    Abstract: Optical fibers comprising core and/or cladding elements composed of MgO--Al.sub.2 O.sub.3 --SiO.sub.2 glasses are described wherein control of thermal expansion mismatch among the core and cladding elements is possible. Low-stress, high numerical aperture fibers as well as prestressed polarization-relating and high strength fibers are described.
    Type: Grant
    Filed: April 1, 1985
    Date of Patent: May 12, 1987
    Assignee: Corning Glass Works
    Inventor: John R. Gannon
  • Patent number: 4652536
    Abstract: Tellurite glass is disclosed, consisting essentially of 60 to 85 mol % of TeO.sub.2, up to 25 mol % of Li.sub.2 O, up to 35 mol % of Na.sub.2 O, up to 25 mol % of K.sub.2 O, up to 25 mol % of Rb.sub.2 O, up to 15 mol % of Cs.sub.2 O, up to 10 mol % of MgO, up to 5 mol % of CaO, up to 5 mol % of SrO, 1 to 30 mol % of BaO, up to 30 mol % of ZnO, up to 30 mol % of PbO, and up to 5 mol % in total of La.sub.2 O.sub.3, ZrO.sub.2, TiO.sub.2, Nb.sub.2 O.sub.5, Ta.sub.2 O.sub.5 and WO.sub.3 with the total content of K.sub.2 O, Rb.sub.2 O and Cs.sub.2 O being from 1 to 25 mol %, and the total content of ZnO and PbO being from 1 to 30 mol %. The tellurite glass has a reduced light path difference with temperature difference and an increased figure of merit.
    Type: Grant
    Filed: June 30, 1986
    Date of Patent: March 24, 1987
    Assignee: Hoya Corporation
    Inventors: Toshitaka Nakajima, Hiroji Sagara
  • Patent number: 4495298
    Abstract: A thallium-containing optical glass composition which comprises the following oxides in the indicated proportions in mole %: SiO.sub.2 35-80, Tl.sub.2 O 1-30, Tl.sub.2 O+R.sub.2 O (R being an alkali metal) 1-35, ZnO 0-35, GeO.sub.2 0-30, BaO 0-25, TiO.sub.2 0-20, MgO 0-20, B.sub.2 O.sub.3 0-less than 10, ZrO.sub.2 0-2, Al.sub.2 O.sub.3 0-8, SnO 0-5, CaO 0-10, SrO 0-10, PbO 0-10, La.sub.2 O.sub.3 0-5, Bi.sub.2 O.sub.3 0-8, and Ta.sub.2 O.sub.5 0-2, and satisfies the following relations:5.ltoreq.ZnO+GeO.sub.2 +BaO+TiO.sub.2 +MgO+B.sub.2 O.sub.3 .ltoreq.40,0.1.ltoreq.ZrO.sub.2 +Al.sub.2 O.sub.3 +SnO.ltoreq.8,and0.ltoreq.CaO+SrO+PbO+La.sub.2 O.sub.3 +Bi.sub.2 O.sub.3 +Ta.sub.2 O.sub.5 .ltoreq.10.
    Type: Grant
    Filed: May 11, 1982
    Date of Patent: January 22, 1985
    Assignee: Nippon Sheet Glass Co., Ltd.
    Inventors: Takasi Yamagishi, Yukio Noguchi
  • Patent number: 4459510
    Abstract: The invention relates to lamps having a glass lamp vessel (1) and to a glass suitable therefor. The relevant glass is adequately resistant to attack by electrons, is resistant to atmospheric influences and is properly workable in a gas flame. This glass contains 44-60 mole % silicon oxide; 0-7.5 mole % boron oxide; 0-6 mole % zirconium oxide; 0-7.5 mole % aluminium oxide; 5-20 mole % calcium oxide; 12.5-25 mole % barium oxide; 0-15 mole % magnesium oxide; 0-10 mole % strontium oxide; 2-8 mole % sodium oxide. The sum of the alkaline earth metals is 25-42.5 mole %.No discoloration occurs in sodium vapor discharge lamps when the lamp vessel has been made of this glass.
    Type: Grant
    Filed: September 6, 1983
    Date of Patent: July 10, 1984
    Assignee: U.S. Philips Corporation
    Inventor: Hendrik J. M. Joormann
  • Patent number: 4436381
    Abstract: Glass objects, lenses in particular, can be pressed with precision from a glass which contains 45-55 mol. % P.sub.2 O.sub.5, 15-40 mol. % BaO, 5-15 mol. % Li.sub.2 O, 5-35 mol. % PbO, 0-2 mol. % Al.sub.2 O.sub.3 and 0-6 mol. % F.
    Type: Grant
    Filed: June 24, 1983
    Date of Patent: March 13, 1984
    Assignee: U.S. Philips Corporation
    Inventors: Hendrik J. M. Joormann, Hendrik Verweij, Jan Haisma
  • Patent number: 4427785
    Abstract: Optically translucent theoretically dense body of mullite is produced by pressing an amorphous mixed oxide powder composition of from about 72.5 weight % to about 76.5 weight % Al.sub.2 O.sub.3 /balance SiO.sub.2 into a compact of density of at least 1.0 g/cc, sintering the compact in oxygen or a vacuum of 0.05 torr to 1 torr producing a gas-impermeable compact, hot isostatically pressing the gas-impermeable compact to theoretical density, and with respect to compositions ranging from higher than about 74 wt % Al.sub.2 O.sub.3 /balance SiO.sub.2, annealing the theoretically dense body.
    Type: Grant
    Filed: May 25, 1982
    Date of Patent: January 24, 1984
    Assignee: General Electric Company
    Inventors: Svante Prochazka, Frederic J. Klug
  • Patent number: 4391915
    Abstract: Optical components can be pressed with such a precision that grinding and polishing of the formed components is not necessary, from glasses containing 45-55 wt. % P.sub.2 O.sub.5, 3.5-9 wt. % Al.sub.2 O.sub.3, 5-20 wt. % K.sub.2 O, 0-3 wt. % Li.sub.2 O, 8-15% BaO, 4.5-9 wt. % ZnO, 0-6 wt. % MgO, 0-18 wt. % PbO, 0-1 wt. % SiO.sub.2, 0-3 wt. % B.sub.2 O.sub.3, 0-2 wt. % TiO.sub.2.
    Type: Grant
    Filed: December 7, 1981
    Date of Patent: July 5, 1983
    Assignee: U.S. Philips Corporation
    Inventors: Gertraud A. A. Meden-Piesslinger, Johannes H. P. Van de Heuvel
  • Patent number: 4328318
    Abstract: Glasses containing fluorine. These glasses are characterized by the fact that they contain at least 25% in moles, approximately, of a fluoride or a mixture of fluorides MX(X.sub.1).sub.2, in which:X and X.sub.1 each represent a fluorine atom,and M then represents a metal chosen from among the group consisting ofgallium, iron, chromium, vanadium, indium, and the rare earths,or X represents an oxygen atom,X.sub.1 represents a fluorine atom,and M then represents a titanium atom, it being understood that the said glasses contain no hydrofluoric acid as a network former and that, in the case in which M represents a gallium or indium atom, the glasses do not contain more than 15% in moles of BaPO.sub.3 F.Application notably in obtaining glasses containing various cations conferring particular optical or magneto-optical properties.
    Type: Grant
    Filed: March 20, 1980
    Date of Patent: May 4, 1982
    Assignee: Agence Nationale de Valorisation de la Recherche (ANVAR)
    Inventors: Jean-Pierre Miranday, Charles Jacoboni, Robert de Pape
  • Patent number: 4306913
    Abstract: A microporous filler for dental composite resin restorations has been developed which gives greatly improved finishability, system non-toxicity and x-ray opacification. These fillers are prepared from frits obtained by the low temperature calcination of gelled inorganic "polymers" followed by a pulsed high-heat treatment.
    Type: Grant
    Filed: June 6, 1980
    Date of Patent: December 22, 1981
    Assignee: American Dental Association Health Foundation
    Inventors: Curtis P. Mabie, Daniel L. Menis
  • Patent number: 4302074
    Abstract: Aluminum metaphosphate optical fibers are disclosed. In a specific embodiment, aluminum metaphosphate, doped with from 10 to 30 mole percent of diboron trioxide, is found to yield an optical fiber which combines the desirable properties of both high numerical aperture and low material dispersion. The fiber is nonhygroscopic and has a high melting temperature. The index of refraction of the glass may be lowered by doping with silicon dioxide. Consequently, a graded fiber may be made by increasing the concentration of silicon oxide from the core to the cladding.
    Type: Grant
    Filed: April 2, 1979
    Date of Patent: November 24, 1981
    Assignee: Bell Telephone Laboratories, Incorporated
    Inventors: James W. Fleming, Jr., John W. Shiever