Plural Carbides (i.e., Carbides Of Plural Metals) Containing Patents (Class 501/93)
  • Patent number: 6617271
    Abstract: The disclosed invention describes a new high-performance binderless high purity tungsten carbide material, its manufacturing and applications as a cutting tool material.
    Type: Grant
    Filed: March 19, 2002
    Date of Patent: September 9, 2003
    Inventors: Vladimir Yurievich Kodash, Edwin Spartakovich Gevorkian
  • Patent number: 6514897
    Abstract: The present invention relates to compositions and rigid porous structures that contain nanorods having carbides and/or oxycarbides and methods of making and using such compositions and such rigid porous structures. The compositions and rigid porous structures can be used either as catalysts and/or catalyst supports in fluid phase catalytic chemical reactions. Processes for making supported catalyst for selected fluid phase catalytic reactions are also provided. The fluid phase catalytic reactions catalyzed include hydrogenation hydrodesulfuriaation, hydrodenitrogenation, hydrodemetallization, hydrodeoxygenation, hydrodearomatization, dehydrogenation, hydrogenolyis, isomerization, alkylation, dealkylation, oxidation and transalkylation.
    Type: Grant
    Filed: January 12, 2000
    Date of Patent: February 4, 2003
    Assignee: Hyperion Catalysis International, Inc.
    Inventors: David Moy, Chunming Niu, Jun Ma, James M. Willey
  • Publication number: 20030008761
    Abstract: The present invention provides a process for producing alumina matrix carbide and boride reinforced ceramic composites wherein for any particular composite, the relative density is about 97% or more of the theoretical density. The composites are prepared in a container wherein the interior surfaces of the container are graphite and have a protective coating consisting of a first layer comprising silicon carbide and boron carbide with a binder and a second layer comprising silicon carbide particles, wherein the protective coating prevents carbon bleed-through and the protective coating maintains a boride-containing equilibrium atmosphere during the process.
    Type: Application
    Filed: July 24, 2002
    Publication date: January 9, 2003
    Applicant: C-Max Technology, Inc.
    Inventor: Xi Yang
  • Patent number: 6395045
    Abstract: The present invention relates to a method for producing an abrasive grain from a hard-material alloy based on titanium carbide, with alloying contributions from the group of carbides, nitrides, and/or borides from the secondary groups IVb, Vb, and VIb of the periodic system.
    Type: Grant
    Filed: May 12, 2000
    Date of Patent: May 28, 2002
    Assignee: Treibacher Schleifmittel AG
    Inventors: Wolfgang Bucar, Hans Zeiringer
  • Patent number: 6287714
    Abstract: A method comprising incorporation of an inorganic polymer precursor of a grain growth inhibitor into nanostructured materials or intermediates useful for the production of nanostructured materials. The precursor/nanostructured material composite is optionally heat treated at a temperature below the grain growth temperature of the nanostructured material in order to more effectively disperse the precursor. The composites are then heat treated at a temperature effective to decompose the precursor and to form nanostructured materials having grain growth inhibitors uniformly distributed at the grain boundaries. Synthesis of the inorganic polymer solution comprises forming an inorganic polymer from a solution of metal salts, filtering the polymer, and drying. Alloying additives as well as grain growth inhibitors may be incorporated into the nanostructured materials.
    Type: Grant
    Filed: August 21, 1998
    Date of Patent: September 11, 2001
    Assignee: Inframat Corporation
    Inventors: Danny T. Xiao, Chris W. Strock, Donald M. Wang, Peter R. Strutt
  • Patent number: 6171989
    Abstract: A silver-colored sintered product having excellent corrosion resistance containing titanium, carbon and boron as indispensable constituent elements, and including in the sintered product composition a titanium boride phase or a boride phase which contains titanium as a chief metal element and a titanium carbide phase or a carbide phase which contains titanium as a chief metal element and a method of producing the same. The sintered product has a flexural strength of not smaller than 700 MPa, a Vickers' hardness of not smaller than 9.0 GPa and a fracture toughness of not smaller than 5.0 MPa·m½.
    Type: Grant
    Filed: June 19, 1997
    Date of Patent: January 9, 2001
    Assignee: Kyocera Corporation
    Inventor: Nobuo Yoshida
  • Patent number: 6133182
    Abstract: This invention provides an alumina base ceramic sintered body excellent in wear resistance with high hardness, also with high strength and high toughness, and particularly suitable for a cutting tool or wear resistant member. This sintered body contains 5-70 % by volume of WC and 5-70% by volume of Ti (C,N) solid solution having a C/N mole ratio ranging from 1:9 to 9:1, the WC and Ti (C,N) having particle sizes of 5 .mu.m or less, respectively.
    Type: Grant
    Filed: September 9, 1999
    Date of Patent: October 17, 2000
    Assignee: Nippon Tungsten Co., Ltd.
    Inventors: Toyoshige Sasaki, Mitsuyoshi Nagano, Eiji Okuma, Shinzou Mitomi, Tetsuo Uchiyama, Shigeo Inoue, Haruka Tamura
  • Patent number: 6069101
    Abstract: Ceramic composites of silicon carbide (SiC) grains and boron carbide (B.s4 C) grains which are uniformly coated with SiC are produced by reacting stoichiometric mixtures of silicon boride (SiB.sub.4, SiB.sub.6) and carbon (graphite or carbon black) in situ.
    Type: Grant
    Filed: December 30, 1998
    Date of Patent: May 30, 2000
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Inna G. Talmy, James A. Zaykoski
  • Patent number: 6042627
    Abstract: An aluminum-boron-carbon abrasive article is comprised of at least three phases selected from the group consisting of: B.sub.4 C; AlB.sub.2 ; AlB.sub.12 ; AlB.sub.12 C.sub.2 ; Al.sub.4 C.sub.3 ; AlB.sub.24,C.sub.4 ; Al.sub.4 B.sub.1-3 C.sub.4 ; AlB.sub.24 C.sub.4 and Al.sub.4 BC. At least a portion of the surface of the abrasive article is comprised of abrasive grains of at least one phase selected from the group consisting of AlB.sub.24 C.sub.4, Al.sub.4 BC and AlB.sub.2, where the abrasive grains have an average grain size that is at least about two times greater than the average grain size of the grains containing boron and carbon within the abrasive article. The aluminum-boron-carbon abrasive article of claim 1 is prepared by heating, under a vacuum or inert atmosphere, a body comprised of at least one boron containing phase and at least one carbon containing phase in the presence of a separate source of aluminum, such as aluminum metal or alloy thereof.
    Type: Grant
    Filed: April 29, 1998
    Date of Patent: March 28, 2000
    Assignee: The Dow Chemical Company
    Inventors: Aleksander J. Pyzik, Uday V. Deshmukh, Robert D. Krystosek
  • Patent number: 6030912
    Abstract: A sintered hard material according to the invention comprises 0.02 to 0.10 wt % of one or more metals selected from the group consisting of Fe, Co and Ni, 0.3 to 3.0 wt % of one or more compounds selected from the group consisting of carbides, nitrides and carbonitrides of transition metals of the IVa, Va and VIa groups of the periodic table and a residue of tungsten carbide component having an average particle size of 0.5 .mu.m or less, the tungsten carbide component containing WC and W.sub.2 C in a proportion W.sub.2 C/(WC+W.sub.2 C) of between 0.01 and 0.15, the W.sub.2 C in the tungsten carbide component having a lattice constant reduced by 0.3 to 1.5 %.
    Type: Grant
    Filed: January 23, 1998
    Date of Patent: February 29, 2000
    Assignee: Dijet Industrial Co., Ltd.
    Inventors: Tsutomu Yamamoto, Kazuhiro Tezuka
  • Patent number: 5942204
    Abstract: A transition metal carbide (e.g., WC) is prepared by the following steps. A carbon-precursor mixture is formed by mixing a precursor comprised of (i) a transition metal oxide (e.g., WO.sub.x) and (ii) a material selected from the group consisting of: a transition metal (e.g., W); a transition metal carbide (e.g., WC) and a substoichiometric carbide (W.sub.2 C), in the presence of a source of carbon (e.g., carbon black) in an amount sufficient to form a reduced mixture comprised of the transition metal carbide and substoichiometric transition metal carbide, wherein the amount of the transition metal oxide and transition metal is essentially zero in said reduced mixture. The carbon-precursor mixture is heated in a reducing atmosphere (e.g., 5 percent hydrogen in argon) to a reducing temperature and for a time sufficient to produce the reduced mixture.
    Type: Grant
    Filed: November 12, 1997
    Date of Patent: August 24, 1999
    Assignee: OMG Americas, Inc.
    Inventors: Stephen D. Dunmead, Hobart A. Barker, John P. Henley, Pat J. DeLuca, Tom J. Bunnelle, Joe F. Repman, Daniel F. Carroll, Stephen A. Anderson
  • Patent number: 5928976
    Abstract: In order to provide cemented carbide, provision is made about tungsten carbide powder which has a grain size not smaller than 1 .mu.m and which is mixed with carbon powder and chromium powder to form raw powder. The tungsten carbide powder is formed by fine primary crystal particles of tungsten carbide and satisfies an inequality given by:Y>0.61-0.33 log (X),where Y denotes a half-value width of (211) crystal planes in tungsten carbide (JCPDS-card 25-1047, d=0.9020) measured by a X-ray diffraction method and where X denotes a grain size measured by the FSSS method. There is also provided a method of producing the composite carbide powder having tungsten carbide powder as a main element, the method comprising the steps of preparing tungsten powder which has a mean grain size not smaller than 1 .mu.m, mixing the tungsten powder with carbon powder and chromium powder into a mixture, and processing the mixture in a predetermined atmosphere into fine primary crystal particles of tungsten carbide.
    Type: Grant
    Filed: May 19, 1997
    Date of Patent: July 27, 1999
    Assignee: Tokyo Tungsten Co., Ltd.
    Inventors: Yoshiharu Yamamoto, Nobuaki Asada, Yoshihiko Doi
  • Patent number: 5914285
    Abstract: To provide a substrate material having characteristics suitable to a magnetic head for attaining high recording density. A substrate material for a magnetic head comprising a matrix phase of a carbide of one or more of Ti, W and Ta and a dispersion phase of an oxide of one or more of Al.sub.2 O.sub.3, CrO.sub.3, and ZrO.sub.2, in which the material comprises 60 to 95 vol % of the matrix phase of the carbide. Further, a single phase in which the ingredients of carbides as the matrix phase comprise (Ti.sub.j W.sub.m Ta.sub.n)C.sub.x is preferred. Further, oxygen and/or nitrogen may be solid-solubilized in the carbide MeC of the matrix phase wherein Me is one or more of Ti, W, and Ta.
    Type: Grant
    Filed: August 25, 1997
    Date of Patent: June 22, 1999
    Assignees: Nippon Tungsten Co., Ltd., Sumitomo Special Metals Co., Ltd.
    Inventors: Toyoshige Sasaki, Shigeki Mohri, Osamu Nakano, Shin Mishima, Shigeru Kawahara, Naoyuki Okamoto
  • Patent number: 5894066
    Abstract: Ceramic composites of silicon carbide (SiC) grains and boron carbide (B.s4 C) grains which are uniformly coated with SiC are produced by reacting stoichiometric mixtures of silicon boride (SiB.sub.4, SiB.sub.6) and carbon (graphite or carbon black) in situ.
    Type: Grant
    Filed: January 12, 1998
    Date of Patent: April 13, 1999
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Inna G. Talmy, James A. Zaykoski
  • Patent number: 5888669
    Abstract: A non-oxide, transition metal based ceramic material has the general formula A.sub.y M.sub.2 Z.sub.x, wherein A is a group IA element, M is a transition metal and Z is selected from the group consisting of N, C, B, Si, and combinations thereof, and wherein x.ltoreq.2 and y.ltoreq.6-x. In these materials, the group IA element occupies interstitial sites in the metallic lattice, and may be readily inserted into or released therefrom. The materials may be used as catalysts and as electrodes. Also disclosed herein are methods for the fabrication of the materials.
    Type: Grant
    Filed: March 14, 1997
    Date of Patent: March 30, 1999
    Assignee: T/J/ Technologies
    Inventors: Levi T. Thompson, Jr., Michael R. Wixom
  • Patent number: 5880382
    Abstract: Double cemented carbide composites comprise a plurality of first regions and a second ductile phase that separate the first regions from each other. Each first region comprises a composite of grains and a first ductile phase bonding the grains. The grains are selected from the group of carbides consisting of W, Ti, Mo, Nb, V, Hf, Ta, and Cr carbides. The first ductile phase is selected from the group consisting of Co, Ni, Fe, alloys thereof, and alloys with materials selected from the group consisting of C, B, Cr, Si, and Mn. A preferred first region comprises tungsten carbide grains that are cemented with a cobalt first binder phase and which are in the form of substantially spherical pellets. The second ductile phase is selected from the group consisting of Co, Ni, Fe, W, Mo, Ti, Ta, V, Nb, alloys thereof, and alloys with materials selected from the group consisting of C, B, Cr, and Mn. A preferred second ductile phase is cobalt.
    Type: Grant
    Filed: July 31, 1997
    Date of Patent: March 9, 1999
    Assignee: Smith International, Inc.
    Inventors: Zhigang Fang, J. Albert Sue
  • Patent number: 5869019
    Abstract: In order to eliminate the oxygen sensitivity of chromium carbide and vanadium carbide particles, vanadium carbide and chromium carbide particles are formed by carburizing a precursor compound at a elevated reaction temperature of about 950.degree. C. Initially, the precursor compound is heated in an inert nitrogen-containing gas to the reaction temperature. Once the reaction temperature is achieved, hydrogen and a carbon-containing gas such as methane or ethylene are used to conduct the carbonization. After the carbonization has been completed, the carbonizing gas is then replaced with an inert nitrogen-containing gas and the product allowed to cool down. The carbonization cycle is adjusted so that the oxygen level is kept to less than 0.35%, while the nitrogen level is kept at about 2%. Powders produced from this process show minimal or no oxygen pickup when exposed to ambient air.
    Type: Grant
    Filed: October 2, 1996
    Date of Patent: February 9, 1999
    Assignee: Nanodyne Incorporated
    Inventor: Purnesh Seegopaul
  • Patent number: 5856251
    Abstract: Castable refractory for a slide gate plate is mainly formed of alumina raw material and amorphous carbon raw material of 2 to 15 wt %, and contains silicon carbide and/or boron carbide, the total content thereof being equal to 0.5 to 10 wt % (the content of boron carbide is equal to or less than 3 wt %, and when the content of boron carbide is less than 0.5 wt %, silicon carbide is set to 3 wt % or more), 2 to 10 wt % magnesia of 1 mm or less in particle size, 0.2 to 3 wt % silica fine powder of 5 micrometers or less in particle size, and 0.1 to 5 wt % salt of condensate of formalin and aromatic sulfonate.
    Type: Grant
    Filed: June 9, 1997
    Date of Patent: January 5, 1999
    Assignee: Toshiba Ceramics Co., Ltd.
    Inventors: Hisahiro Teranishi, Isao Imai, Toshihiro Indou
  • Patent number: 5852088
    Abstract: The present invention provides for amorphous, nanoporous, catalytic metal-containing ceramic material having a surface area in excess of 70 m.sup.2 /gm and characterized by a high content of open microporous cell structure wherein the micropores have a mean width of less than 20 Angstroms and wherein said microporous structure comprises a volume of greater than about 0.03 cm.sup.3 /gm of the ceramic. The invention also provides for a preceramic composite intermediate composition comprising a mixture of a ceramic precursor and from about 0.5 up to about 65 wt % of an organometallic compound containing a metal of Group IB, II, III, IV, IV, V, VIB, VIIA or VIII of the Periodic Table, including rare earth metals, whose pyrolysis product in ammonia or an inert atmosphere at temperatures of up to less than about 1100.degree. C. gives rise to the nanoporous catalytic ceramics of the invention.
    Type: Grant
    Filed: December 27, 1995
    Date of Patent: December 22, 1998
    Assignee: Exxon Research and Engineering Company
    Inventors: John P. Dismukes, Jack Wayne Johnson, John Stewart Bradley
  • Patent number: 5844153
    Abstract: A mixed metal powder for hard metal alloys comprising cobalt, 1 to 10 parts per weight tungsten and 1 to 10 parts by weight of aluminum and a hard metal alloy containing the mixed metal powder binder in an amount of from 2 to 12 parts by weight per about 100 parts by weight of a metal carbide for corrosion resistant hard metal tools.
    Type: Grant
    Filed: July 12, 1996
    Date of Patent: December 1, 1998
    Assignee: EMTEC Magnetics GmbH
    Inventors: Manfred Schlatter, Jurgen Koppe, Volker Eichhorst
  • Patent number: 5820789
    Abstract: A method of heating, comprising the step of providing a line voltage of between 120V and 230 V across a ceramic igniter having a hot zone composition comprising:(a) between 50 and 80 v/o of an electrically insulating ceramic having a resistivity of at least about 10.sup.10 ohm-cm;(b) between 10 and 45 v/o of a semiconductive material having a resistivity of between about 1 and about 10.sup.8 ohm-cm;(c) between 5 and 25 v/o of a metallic conductor having a resistivity of less than about 10.sup.-2 ohm-cm; and(d) between 2.0 and 20 v/o of a resistivity-enhancing compound selected from the group consisting of metallic oxides, metallic oxynitrides, rare earth oxides, rare earth oxynitrides, and mixtures thereof.
    Type: Grant
    Filed: April 3, 1997
    Date of Patent: October 13, 1998
    Assignee: Saint Gobain/Norton Industrail Ceramics Corp.
    Inventors: Craig A. Willkens, Linda S. Batemen
  • Patent number: 5780164
    Abstract: A hard drive disk substrate is formed of a multi-phase ceramic-based material having at least two phases with amorphous phases being present in an amount less than about 1 volume percent based on the volume of the ceramic-based material or at least one phase being free metal. A process for producing the ceramic-based disk substrate is produced by forming a flat disk of a porous ceramic and then infiltrating the porous ceramic with a metal whereby a multi-phase ceramic-based computer hard drive disk is produced. Additionally, a step of passivating the porous ceramic by elevating it to a temperature of about 1300.degree. to about 1800.degree. C. before the infiltrating step may be performed, such that the surfaces are passivated and the reaction kinetics can be controlled during the infiltrating step. A preferred composite material is made of a multi-phase boron carbide composite material including grains having peaks with an average roughness value, Ra, of between about 1 to about 200 .ANG.
    Type: Grant
    Filed: June 29, 1995
    Date of Patent: July 14, 1998
    Assignee: The Dow Chemical Company
    Inventors: Aleksander J. Pyzik, Uday V. Deshmukh, Chan Han, Kevin J. Nilsen, Donald J. Perettie, Arthur R. Prunier, Jr.
  • Patent number: 5756409
    Abstract: Abrasive grain with significantly improved toughness is obtained by pressureless sintering of .alpha.-silicon carbide powder with oxidic sinter additives, especially aluminum oxide/yttrium oxide, which is also suitable for those applications where an ordinary silicon carbide abrasive grain is too brittle.
    Type: Grant
    Filed: October 21, 1996
    Date of Patent: May 26, 1998
    Assignee: Korund Laufenburg, GmbH
    Inventors: Franciscus van Dijen, Edgar Mayer
  • Patent number: 5756410
    Abstract: A submicrometer transition metal carbonitride is produced having the formula:M.sub.a M'.sub.b M".sub.(1-a-b) (C.sub.1-x) N.sub.x).sub.zwherein M is Ti, Zr or Hf; M' is V, Nb or Ta; M" is Cr, Mo or W; a ranges from 0 to 1; b ranges from 0 to 1 with the proviso that (a +b) is less than or equal to 1; x ranges from about 0.02 to about 0.95 and z ranges from about 0.9 to about 2. The transition metal carbonitride is produced by mixing (a) a transition metal oxide source of a transition metal in the above formula and (b) a carbon source such as carbon black.
    Type: Grant
    Filed: February 27, 1997
    Date of Patent: May 26, 1998
    Assignee: The Dow Chemical Company
    Inventors: Stephen D. Dunmead, Alan W. Weimer
  • Patent number: 5750449
    Abstract: A ceramic porous body composed principally of silicon carbide or silicon nitride which has higher strength, higher heat resistance and higher thermal shock resistance and has a large number of fine pores, and a method of producing the same. The ceramic porous body, comprised principally of silicon carbide or silicon nitride, has a pore diameter of not more than 1 .mu.m, with a porosity of not less than 35%, and has a flexural strength of not less than 100 MPa. The ceramic porous body is produced by using a silicon oligomer which is capable of producing silicon carbide or silicon nitride when calcined, mixing the silicon oligomer with a silicon carbide powder or silicon nitride powder, and/or other ceramic powder which has a mean particle diameter of not more than 1.0 .mu.m, molding the mixture into shape, then sintering the molding in a suitable atmosphere at temperatures of not less than 1200.degree. C.
    Type: Grant
    Filed: December 20, 1996
    Date of Patent: May 12, 1998
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Koichi Niihara, Akira Yamakawa
  • Patent number: 5733649
    Abstract: A matrix powder for formation along with an infiltrant into a matrix for use as a wear element or for use in retaining at least one discrete hard element. The matrix powder including macrocrystalline tungsten carbide particles, crushed sintered cemented macrocrystalline tungsten carbide particles, tungsten carbide, and an iron-based component.
    Type: Grant
    Filed: September 23, 1996
    Date of Patent: March 31, 1998
    Assignee: Kennametal Inc.
    Inventors: Harold E. Kelley, William E. Silvis, Charles J. Terry
  • Patent number: 5733664
    Abstract: A matrix powder for formation along with an infiltrant into a matrix for use as a wear element or for use in retaining at least one discrete hard element. The matrix powder includes crushed sintered cemented tungsten carbide particles. The composition of the crushed sintered cemented tungsten carbide comprises between about 6 weight percent and about 13 weight percent binder metal and between about 87 weight percent and about 94 weight percent tungsten carbide.
    Type: Grant
    Filed: December 18, 1995
    Date of Patent: March 31, 1998
    Assignee: Kennametal Inc.
    Inventors: Harold E. Kelley, William E. Silvis, Charles J. Terry, Gary R. Peterson
  • Patent number: 5672435
    Abstract: Hard disk drive components, such as, sliders, load beams, support arms, actuators, actuator bearings, spacers, clamps, spindles, ball bearings, thrust bearings, journal bearings, base plates, housings, and covers, formed of a multi-phase ceramic-based material. One method of making the hard disk drive components includes (a) forming a porous body of ceramic; (b) infiltrating a liquid into the pores of the ceramic body; (c) solidifying the infiltrated liquid; and (d) machining the metal-infiltrated ceramic body to form the hard disk drive component.
    Type: Grant
    Filed: June 29, 1995
    Date of Patent: September 30, 1997
    Assignee: The Dow Chemical Company
    Inventors: David W. Born, Uday V. Deshmukh, Timothy G. Fawcett, Richard T. Fox, Kevin J. Nilsen, Aleksander J. Pyzik
  • Patent number: 5670253
    Abstract: A composite ceramic wafer including a beta silicon carbide layer. The composite ceramic wafer is useful for making thin film magnetic heads.
    Type: Grant
    Filed: December 20, 1995
    Date of Patent: September 23, 1997
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Raymond C. Chiu, Robert G. Smith, Billy Lee Weaver
  • Patent number: 5665661
    Abstract: A silicon carbide ceramic having crystalline grain boundary phases is prepared by heating a composition comprising silicon carbide, a silicate glass and a high metal content transition metal silicide, to a temperature of 1300.degree. C. to 2100.degree. C. under vacuum until oxygen is removed from the glass as SiO gas, and the glass that remains within the silicon carbide ceramic crystallizes.
    Type: Grant
    Filed: June 20, 1995
    Date of Patent: September 9, 1997
    Assignee: Lanxide Technology Company, LP
    Inventor: Roger Lee Ken Matsumoto
  • Patent number: 5637266
    Abstract: A composite ceramic block gauge is formed from a tungsten carbide (WC) reinforced phase and a chromium carbide (Cr.sub.3 C.sub.2) matrix. The finished block gauge possesses excellent properties such as hardness and corrosion resistance and high reflectivity. The block gauges made from Cr.sub.3 C.sub.2 /WC composites can be calibrated using the traditional optical interferometry techniques.
    Type: Grant
    Filed: June 20, 1995
    Date of Patent: June 10, 1997
    Assignee: Industrial Technology Research Institute
    Inventors: Chung-Ping Lai, Cheng-Tsu Fu, Jia-Ruey Duann, Ai-Kang Li, Kai-Li Ko
  • Patent number: 5612264
    Abstract: A method of forming a low level carbon high-density tungsten carbide-containing material includes sintering a preform which contains tungsten carbide powder and has a composition such that the resulting sintered material has at most 6.05 weight percent tungsten-bound carbon based on the total weight of tungsten and tungsten-bound carbon. This low level of carbon may be achieved by, prior to the sintering step, oxidizing the tungsten carbide powder sufficiently to achieve the desired substoichiometric carbon level in the sintered product or by adding a carbon-lowering material selected from the group consisting of tungsten, ditungsten carbide, and tungsten oxide. Optionally, other materials can be present in the preform such as carbon-getter metals and compounds thereof. The carbon-getter metals are those metals of which the carbides thereof are more thermodynamically stable than monotungsten carbide.
    Type: Grant
    Filed: November 13, 1995
    Date of Patent: March 18, 1997
    Assignee: The Dow Chemical Company
    Inventors: Robert T. Nilsson, Richard T. Fox, Stephen D. Dunmead
  • Patent number: 5580833
    Abstract: A high performance ceramic composite containing tungsten carbide reinforced chromium carbide matrix in which 5.about.35 vol % of tungsten carbide particles are uniformly dispersed in 65.about.95 vol % of chromium carbide matrix. The diameters of the tungsten carbide and chromium carbide particles are preferably in the rage between 0.1.about.10 .mu.m, and their average diameters are preferably at about 2.0 and 1.5 .mu.m, respectively. The tungsten carbide/chromium carbide composite is prepared from a sintering process by applying heat and pressure to a green compact containing tungsten carbide and chromium carbide particles, without using a metallic sintering aid.
    Type: Grant
    Filed: October 11, 1994
    Date of Patent: December 3, 1996
    Assignee: Industrial Technology Research Institute
    Inventors: Cheng-Tsu Fu, Ai-Kang Li, Chung-Ping Lai, Jia-Ruey Duann
  • Patent number: 5545248
    Abstract: A titanium-base sintered alloy which comprises a TiC and/or TiN or Ti(C,N) solid solution accounting for 5 to 70 vol %, with the remainder being composed of two components. The first component is at least one species selected from the group consisting of Groups Va and VIa metallic elements, except Cr, or at least one species selected from the group consisting of carbides, nitrides, and carbonitrides of Groups Va and VIa metallic elements, except Cr. The second component is titanium. The first component accounts for 1 to 30 vol % and the second component accounts for 70 to 99 vol % of the total amount of the first and second components. The alloy produces a preferred result when the content of TiC or TiN is 35 to 70 vol % and the first component accounts for 1 to 15 vol % of the remainder. It is desirable that the TiC, TiN, and the first component of the remainder be in the form of a solid solution.
    Type: Grant
    Filed: February 14, 1995
    Date of Patent: August 13, 1996
    Assignee: Nippon Tungsten Co., Ltd.
    Inventors: Kei Tokumoto, Tetsunori Kitada, Hironobu Shinoaki, Shigeya Sakaguchi
  • Patent number: 5543369
    Abstract: A block copolymer is prepared by reacting an aluminum-nitrogen polymer and a silazane polymer at a temperature not greater than 400.degree. C. Block copolymers containing alkenyl or alkynyl groups can be crosslinked by supplying energy to generate free radicals. An AlN/SiC-containing ceramic is formed by pyrolyzing the crosslinked block copolymer in a nonoxidizing atmosphere.
    Type: Grant
    Filed: January 15, 1993
    Date of Patent: August 6, 1996
    Inventor: James A. Jensen
  • Patent number: 5525555
    Abstract: Disclosed are high density, sintered titanium carbide bodies comprising 2-10 wt % silicon carbide, up to 2 wt % free carbon and 88 to 98 wt % titanium carbide.
    Type: Grant
    Filed: February 10, 1995
    Date of Patent: June 11, 1996
    Assignee: Dow Corning Corporation
    Inventor: Gregg A. Zank
  • Patent number: 5523269
    Abstract: A method of making a compound selected from metal and silicon carbides and nitrides includes the steps of providing a solution of a coal-derived material in a solvent, the coal-derived material having a composition, free of solvent, of 70 to 91 percent by mass of carbon, 2 to 6 percent by mass of hydrogen and 3 to 20 percent by mass of oxygen, and a source of an oxide of silicon or the metal, causing the coal-derived material in solution and the source of the oxide to interact, removing the solvent to form a precursor and heat treating the precursor to produce the compound.
    Type: Grant
    Filed: September 14, 1994
    Date of Patent: June 4, 1996
    Assignee: Enerkom (Proprietary) Limited
    Inventors: David L. Morgan, Vladimir Cukan
  • Patent number: 5516595
    Abstract: The invention comprises a method of making self-supporting ceramic and ceramic composite structures by the oxidation reaction of a body of molten parent metal precursor with a vapor-phase oxidant to form an oxidation reaction product. This reaction or growth is continued to form a thick, self-supporting ceramic or ceramic composite body. The body is recovered and in a separate subsequent operation, at least a portion of a surface is coated with one or more materials in order to effect desired changes in the properties of the surface, e.g., hardness, corrosion resistance.
    Type: Grant
    Filed: November 16, 1994
    Date of Patent: May 14, 1996
    Assignee: Lanxide Technology Company, LP
    Inventors: Marc S. Newkirk, Adam J. Gesing, Michael A. Rocazella, Christopher R. Kennedy, Daniel J. Frydrych, Robert A. Wolffe, Paul V. Kelsey, Alvin P. Gerk
  • Patent number: 5514630
    Abstract: A ceramic material comprising:(a) between about 50 and about 80 v/o of an electrically insulating ceramic having a resistivity of at least about 10 E+10 ohm-cm;(b) between about 10 and about 45 v/o of a semiconductive material having a resistivity of between about 1 and about 10 E+8 ohm-cm;(c) between about 5 and about 25 v/o of a metallic conductor having a resistivity of less than about 10 E-2 ohm-cm; and(d) between about 0.5 and about 20 v/o of a resistivity-enhancing compound selected from the group consisting of metallic oxides, metallic oxynitrides, rare earth oxides, rare earth oxynitrides, and mixtures thereof.
    Type: Grant
    Filed: October 6, 1994
    Date of Patent: May 7, 1996
    Assignee: Saint Gobain/Norton Industrial Ceramics Corp.
    Inventors: Craig A. Willkens, Linda S. Bateman
  • Patent number: 5500394
    Abstract: The invention provides a ceramic composite material which includes 60-85% silicon carbide, 4-15% titanium carbide, 4-20% titanium boride, 4-13% aluminum oxide, and 1-8% titanium oxide. All constituents are in powder form, and have a particle size of between 1 and 40 microns, and a purity of at least 97%. The powdered constituents are blended and consolidated by sintering, although either hot isostatic pressing (HIPing) or by hot pressing can be used to improve certain properties such as impact resistance.
    Type: Grant
    Filed: December 22, 1994
    Date of Patent: March 19, 1996
    Assignee: Composite Materials, Inc.
    Inventor: Stanislav F. Kondakov
  • Patent number: 5482670
    Abstract: This invention consists of two parts: "Cemented Carbide with Minimal Amount of Binder Metal", and "Nonmagnetic cemented Carbide".The "Cemented Carbide with Minimal Amount of Binder Metal" is for cemented carbide bodies which are made from less than 2% binder metal powder and more than two kinds of metal carbide powder. Neither kind of carbide powder exceeds 98% of all the carbide powder used as raw material. The raw powder is to be prepared following a conventional powder metallurgy method--especially the conventional method of making cemented carbide--milling, cold pressing and non-high-pressure sintering. During the sintering process, metal carbide powder forms complicated solid solution carbides, and the small amount of binder which initially helped sintering is lost for the most part, if not entirely, during sintering.The "Non-magnetic Cemented Carbide" is cemented carbides which have nickel-tungsten alloy as a binder metal. The process of manufacturing uses said conventional powder metallurgy.
    Type: Grant
    Filed: May 20, 1994
    Date of Patent: January 9, 1996
    Inventor: Joonpyo Hong
  • Patent number: 5470807
    Abstract: A composite ceramic block gauge and its preparing method is disclosed. The ceramic block gauge comprises a tungsten carbide (WC) reinforced phase and a chromium carbide (Cr.sub.3 C.sub.2) matrix. The finished block gauge possesses excellent properties such as hardness and corrosion resistance and high reflectivity. The block gauges made from Cr.sub.3 C.sub.2 /WC composites can be calibrated using the traditional optical interferometry techniques.
    Type: Grant
    Filed: March 17, 1995
    Date of Patent: November 28, 1995
    Assignee: Industrial Technology Research Institute
    Inventors: Chung-Ping Lai, Cheng-Tsu Fu, Jia-Ruey Duann, Ai-Kang Li, Kai-Li Ko
  • Patent number: 5470806
    Abstract: Pressureless sintering is used to densify silicon carbide based ceramics using a compound comprising transition metal oxides and aluminum oxide at temperatures in excess of 1850.degree. C. The resulting sintered body has a density greater than 95% of its theoretical density, flexural strength in excess of 560 MPa and fracture toughness of 7.2 MPa.m.sup.1/2. The method consists of sintering and conversion of transition metal oxides into carbides in one step operation. Practically any transition metal oxide can be used. The sintered ceramic bodies made by the present invention consist of silicon carbide matrix phase and Al.sub.2 O.sub.3 and transition metal carbide phases.
    Type: Grant
    Filed: September 20, 1993
    Date of Patent: November 28, 1995
    Inventors: Vladimir D. Krstic, Milan Vlajic
  • Patent number: 5468690
    Abstract: A slurry for joining metallic or ceramic surfaces or for coating metallic or ceramic and refractory surfaces, comprising a liquid suspending medium and at least two constituents in particulate form suspended in the medium, the constituents being so selected and proportioned as to undergo combustion synthesis when ignited. A method for coating or joining metallic or ceramic surfaces comprises applying such a slurry to a surface to be coated or to surfaces to be joined, and igniting the slurry to cause combustion synthesis.
    Type: Grant
    Filed: February 15, 1994
    Date of Patent: November 21, 1995
    Assignee: University of Cincinnati
    Inventors: Jainagesh A. Sekhar, V. Subramanian, Necip S. Canarslan
  • Patent number: 5401694
    Abstract: A method for manufacture of Group IVB metal carbide comprising a carbide of a metal selected from the group consisting of titanium, hafnium and zirconium ceramic composites is provided wherein a permeable mass of filler and carbon is contacted with a molten Group IVB metal. The molten metal is maintained in contact with the permeable mass for a sufficient period to infiltrate the permeable mass and to react the molten metal with the carbon source to form a Group IVB metal carbide composite. The permeable mass may comprise a Group IVB metal carbide, or other inert filler, or a combination of filler materials.
    Type: Grant
    Filed: October 18, 1993
    Date of Patent: March 28, 1995
    Assignee: Lanxide Technology Company, LP
    Inventors: Adam J. Gesing, Edward S. Luce, Narashima S. Raghavan, Danny R. White
  • Patent number: 5380688
    Abstract: A method for making submicrometer metallic carbides and submicrometer solid solution metallic carbides from sources of at least one metallic oxide and carbon involves the rapid heating of a reactive particulate mixture of at least one metallic oxide and carbon in order to achieve a resulting particulate size of less than 1 micrometer. Submicrometer sized metallic carbides and solid solution metallic carbides have found great use in commercial ceramic applications. It has been found that the smaller sized particles produce a product having superior toughness and hardness. In addition, the submicrometer sized solid solution metallic carbide resulting from this method is also disclosed.
    Type: Grant
    Filed: August 9, 1993
    Date of Patent: January 10, 1995
    Assignee: The Dow Chemical Company
    Inventors: Stephen D. Dunmead, William G. Moore, Alan W. Weimer, Glenn A. Eisman, John P. Henley
  • Patent number: 5376466
    Abstract: A cermet blade member including a cermet substrate is provided which consists essentially of: 0.2% by weight to 8% by weight of a binder phase of at least one binder metal of cobalt and nickel; 5% by weight to 30% by weight of a first hard dispersed phase of at least one material of zirconia and a stabilized zirconia; and the remainder of a second hard dispersed phase of at least one metal carbo-nitride. The metal of the above-mentioned metal carbo-nitride is selected from metals in Group IVA in a periodic table. In addition, a cermet blade member including the cermet substrate and a hard coating layer formed on the surface of the cermet substrate is provided. The hard coating layer consists of at least one layer of a compound selected from a titanium carbide, a titanium nitride, a titanium carbo-nitride, titanium carbo-oxide represented by TiCO, titanium carbo-oxi-nitride represented by TiCNO and an aluminum oxide.
    Type: Grant
    Filed: October 14, 1992
    Date of Patent: December 27, 1994
    Assignee: Mitsubishi Materials Corporation
    Inventors: Takashi Koyama, Susumu Uchida, Ken Yanai
  • Patent number: 5372978
    Abstract: A new silicon carbide material is made following a procedure including hot pressing to provide a finished product having a microstructure with an optimal grain size of less than 7 micrometers. The material exhibits a dominant failure mode of intergranular fracture requiring significant energy for crack propagation. The method of manufacturing is cost-effective by allowing the use of "dirty" raw materials since the process causes impurities to segregate at multi-grain boundary junctions to form isolated pockets of impurities which do not affect the structural integrity of the material. End uses include use as protective projectile-resistant armor.
    Type: Grant
    Filed: March 11, 1993
    Date of Patent: December 13, 1994
    Assignee: Cercom Inc.
    Inventor: Andre Ezis
  • Patent number: 5348917
    Abstract: Ceramics that are formed from high temperature oxidatively stable thermosetting polymers which, in turn, are formed from linear polymeric materials having repeat units that contain at least one alkynyl group for cross-linking purposes and at least one bis(silyl or siloxanyl)carboranyl group.
    Type: Grant
    Filed: February 8, 1993
    Date of Patent: September 20, 1994
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Teddy M. Keller, Leslie J. Henderson, Jr.
  • Patent number: RE35538
    Abstract: The present invention relates to a sintered body for chip forming machining containing at least one hard constituent comprising a carbide, nitride and/or carbonitride of a metal of group IVB, VB or VIB in the periodical system and a binder metal based upon Co, No and/or Fe, in which the body comprises a core containing eta-phase or an intermediate phase, substantially free of carbon and/or nitrogen surrounded by a hard constituent- and binder phase-containing surface zone, free of said eta-phase or intermediate phase.
    Type: Grant
    Filed: October 16, 1995
    Date of Patent: June 17, 1997
    Assignee: Santrade Limited
    Inventors: Leif A. E. .ANG.kesson, Marian Mikus