Silicon Nitride Containing (si3n4) Patents (Class 501/97.1)
  • Patent number: 6846764
    Abstract: A silicon nitride porous body which is obtained by nitriding a molded body having metallic silicon as a main component and by performing a high temperature heating treatment at a temperature higher than the nitriding temperature, and which has a porous structure with an average pore diameter of 3 ?m or above, and contains at least one kind of element selected from the group consisting of the groups 2A, 3A, 3B inclusive of lanthanoid elements, and 4B. The silicon nitride porous body has a porous structure with a large average pore diameter, a test specimen cut out from the porous body exhibiting a high thermal conductivity and a small thermal expansion coefficient, and can be suitably used in a component for purifying gas and/or solution such as a ceramic filter.
    Type: Grant
    Filed: March 25, 2002
    Date of Patent: January 25, 2005
    Assignee: NGK Insulators, Ltd.
    Inventors: Katsuhiro Inoue, Kenji Morimoto, Masaaki Masuda, Shinji Kawasaki, Hiroaki Sakai
  • Patent number: 6811868
    Abstract: The object of the present invention is to provide a ceramic body that can support a required amount of a catalyst component, without lowering the characteristics such as strength, being manufactured without forming a coating layer and providing a high performance ceramic catalyst that is excellent in practical utility and durability. A noble metal catalyst is supported directly on the surface of the ceramic body and the second component, consisting of compound or composite compound of element having d or f orbit in the electron orbits thereof such as W, Co, Ti, Fe, Ga and Nb, is dispersed in the first component made of cordierite or the like that constitutes the substrate ceramic. The noble metal catalyst can be directly supported by bonding strength generated by sharing the d or f orbits of the second component, or through interaction with the dangling bond that is generated in the interface between the first component and the second component.
    Type: Grant
    Filed: June 6, 2003
    Date of Patent: November 2, 2004
    Assignee: Denso Corporation
    Inventors: Jun Hasegawa, Tomomi Hase, Kazuhiko Koike, Miho Ito
  • Patent number: 6784131
    Abstract: The present invention provides a silicon nitride wear resistant member composed of silicon nitride sintered body containing 1-10 mass % of rare earth element in terms of oxide thereof as sintering agent, wherein a total oxygen content of the silicon nitride sintered body is 6 mass % or less, a porosity of the silicon nitride sintered body is 0.5 vol. % or less, and a maximum size of pore existing in grain boundary phase of the silicon nitride sintered body is 0.3 &mgr;m or less. According to the above structure of the present invention, there can be provided a silicon nitride wear resistant member and a method of manufacturing the member having a high strength and a toughness property, and particularly excellent in sliding characteristics.
    Type: Grant
    Filed: January 11, 2002
    Date of Patent: August 31, 2004
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Michiyasu Komatsu, Hiroki Tonai, Hiroshi Komorita
  • Patent number: 6777361
    Abstract: A ceramic composite material, for example, a ceramic molded body or a layer obtained by pyrolysis of a starting mixture, containing at least one polymer precursor material and at least one filler, which has an average particle size of less than 200 nm. Such a composite material may be used, for example, for producing fibers, filters, catalyst support materials, ceramic sheathed-element glow plugs, metal-containing reactive composite materials, porous protective shells for sensors, ceramic or partially ceramic coatings or microstructured ceramic components.
    Type: Grant
    Filed: October 29, 2002
    Date of Patent: August 17, 2004
    Assignee: Robert Bosch GmbH
    Inventors: Wilfried Aichele, Wolfgang Dressler, Christof Rau, Volker Knoblauch, Alexander Kloncynski, Horst Boeder
  • Patent number: 6777360
    Abstract: A ceramic material suitable for use in production of paving tiles, construction tiles, flooring in offices, flooring in machinery plants and so forth is obtained by a method comprising steps of mixing defatted bran derived from rice bran with a thermosetting resin before kneading, subjecting a kneaded mixture thus obtained to a primary firing in an inert gas at a temperature in a range of 700 to 1000° C., pulverizing the kneaded mixture after the primary firing into carbonized powders, kneading the carbonized powders with which ceramic powders, a solvent, and a binder as desired are mixed into a plastic workpiece (kneaded mass), pressure-forming the plastic workpiece at pressure in a range of 10 to 100 MPa, and subjecting a formed plastic workpiece thus obtained again to firing in an inert gas atmosphere at a temperature in a range of 100 to 1400° C.
    Type: Grant
    Filed: February 11, 2002
    Date of Patent: August 17, 2004
    Assignee: Minebea Co., Ltd.
    Inventors: Kazuo Hokkirigawa, Rikuro Obara, Motoharu Akiyama
  • Patent number: 6749930
    Abstract: A corrosion-resistive member is provided, including a corrosion-resistive face that is exposed to a corrosive gas causing ion bombardmemt. At least a part of the corrosion-resistive member is composed of a sintered silicon nitride body having an open porosity of not more than 5%. The sintered silicon nitride body constitutes the corrosion-resistive face, and if two auxiliary planes are formed by cutting the corrosion-resistive member to intersect vertically with the corrosion-resistive face and to be located vertically with respect to each other, the orientation index between the two auxiliary planes is in a range of 0.8 to 1.2, and the orientation index between the corrosion-resistive face and each of the auxiliary faces is at least 1.5.
    Type: Grant
    Filed: October 18, 2001
    Date of Patent: June 15, 2004
    Assignee: NGK Insulators, Ltd.
    Inventor: Tsuneaki Ohashi
  • Patent number: 6736875
    Abstract: Composite cordierite honeycomb structures especially suitable for diesel exhaust filtration applications comprise a non-oxide polycrystalline phase constituting 10-70% by weight, with the remainder of the ceramic material constituting a cordierite phase, the non-oxide polycrystalline phase being selected from the group consisting of carbides, nitrides, and borides. Preferably the non-oxide phase is either polycrystalline silicon carbide or polycrystalline silicon nitride and has a particle aspect ratio of less than 3. Inventive ceramic bodies are porous with an open porosity of at least 30%, preferably between 40% and 60%, and a median pore size of at least 5 micrometers, more preferably greater than 8 micrometers and less than 12 micrometers.
    Type: Grant
    Filed: December 13, 2001
    Date of Patent: May 18, 2004
    Assignee: Corning Incorporated
    Inventors: Kishor P. Gadkaree, Yanxia Lu, Joseph F. Mach, Christopher J. Warren, Yuming Xie
  • Patent number: 6709999
    Abstract: A molded part of a ceramic material derived from polymers includes a composite body of a single-phase or multi-phase, amorphous, partially crystalline or crystalline matrix of silicon carbide (SiC), silicon nitride (Si3N4), silicon dioxide (SiO2) or mixtures thereof. The matrix contains graphite inclusions and the density of the ceramic material is at least 85% of the theoretical value. The molded part is produced by subjecting a mixture formed of a polymer component in an amount of 30 to 80 wt. % referred to the total weight of the mixture, fillers in an amount of 0 to 30 wt. % and graphite in an amount of 10 to 70 wt. %, to a forming process with heating to effect crosslinking of the polymer components, followed by a pyrolysis process. In particular, the molded parts are produced from polymers of the group including polysilanes, polysiloxanes, polysilazanes or polycarbosilanes. A process for producing ceramic molded parts and a sliding element having a molded part are also provided.
    Type: Grant
    Filed: June 18, 2001
    Date of Patent: March 23, 2004
    Assignee: SGL Carbon AG
    Inventors: Peter Greil, Oliver Dernovsek, Hans-Michael Güther, Ulrich Wislsperger
  • Publication number: 20040043888
    Abstract: The present invention provides methods for making a microporous ceramic material using a metal silicon powder and including a reaction sintering process of the silicon. A material for forming a microporous ceramic material used in these methods includes a metal silicon powder, a silicon nitride powder and/or a silicon carbide powder, and if desired, a yttrium oxide powder and/or an aluminum oxide powder. These methods can make a microporous ceramic material that can be used preferably as a gas or liquid filter, a catalyst carrier or a support of a gas separation membrane.
    Type: Application
    Filed: August 26, 2003
    Publication date: March 4, 2004
    Applicants: Noritake Co., Limited, Chubu Electric Power Co., Inc
    Inventors: Yasunori Ando, Seiji Yamada, Hisatomi Taguchi, Yosuke Takahashi, Shigeo Nagaya, Kiyoshi Komura
  • Publication number: 20040039217
    Abstract: The present invention concerns a process for producing silylalkylboranes containing the structural feature Si—C—B, new molecular silylalkylboranes, new molecular silyalkylborazines, new oligoborocarbosilazanes and polyborocarbosilazanes, a process for their production and their use as well as silicon boron carbide nitride ceramics and a process for their production.
    Type: Application
    Filed: March 12, 2003
    Publication date: February 26, 2004
    Inventors: Martin Jansen, Thomas Jschke
  • Patent number: 6689202
    Abstract: Blocks of material are prepared in a variety of shapes and sizes to be used in the fabrication of models for dental restorations. The material comprises a partially sintered ceramic material. The blocks are used to manufacture molds using CAD/CAM methods and equipment. The molds are useful in the manufacture of dental restorations using ceramics, metals, alloys, or powders thereof, and composite materials. The models milled from the blanks may be used to manufacture a variety of dental restorations including, but not limited to, crowns, bridges, space maintainers, tooth replacement appliances, orthodontic retainers, dentures, posts, jackets, inlays, onlays, facings, veneers, facets, implants, abutments, splints, partial crowns, teeth, cylinders, pins, and connectors.
    Type: Grant
    Filed: July 13, 2001
    Date of Patent: February 10, 2004
    Assignee: Jeneric/Pentron Incorporated
    Inventor: Carlino Panzera
  • Publication number: 20040023789
    Abstract: A silicon nitride porous body (5) obtained by nitriding a molded body having metallic silicon (3) as a main component, the porous body having a porous structure with an average pore diameter of 3 &mgr;m or above, and wherein the total content of silicon and nitrogen is 95% or above and the nitridation ratio of silicon is 90% or above. The silicon nitride porous body has a porous structure with a large average pore diameter, with a test specimen cut out from the porous body exhibiting large thermal conductivity and a small thermal expansion coefficient, and can be suitably used in a component for purifying gas and/or solution such as a ceramic filter.
    Type: Application
    Filed: December 23, 2002
    Publication date: February 5, 2004
    Inventors: Katsuhiro Inoue, Kenji Morimoto, Masaaki Masuda, Shinji Kawasaki, Hiroaki Sakai
  • Publication number: 20040009865
    Abstract: The present invention provides a method for making a microporous ceramic material and includes the steps of (a) preparing a starting material for firing comprising a nonoxide ceramic precursor containing silicon as an essential component; (b) heating the starting material for firing in an atmosphere containing at least 1 mol % of hydrogen so as to form microporous ceramic product; and (c) cooling the microporous ceramic product.
    Type: Application
    Filed: February 19, 2003
    Publication date: January 15, 2004
    Applicants: NORITAKE CO., LIMITED, CHUBU ELECTRIC POWER CO., INC.
    Inventors: Balagopal N. Nair, Yasunori Ando, Hisatomi Taguchi, Shigeo Nagaya, Kiyoshi Komura
  • Patent number: 6670294
    Abstract: Corrosion-resistive ceramic materials include a silicon based ceramic, wherein a percentage of respective metal elements other than metal elements constituting sintering agents and silicon is not more than 10 weight ppm. The corrosion-resistive ceramic materials show a high corrosion resistance with respect to corrosive substances and suppress particle generation due to an exposure to corrosive substances. Therefore, chippings and cracks do not occur easily during machining work.
    Type: Grant
    Filed: January 23, 2002
    Date of Patent: December 30, 2003
    Assignee: NGK Insulators, Ltd.
    Inventor: Hiromichi Kobayashi
  • Patent number: 6642165
    Abstract: Wear resistant member for electronic equipment comprises a silicon nitride sintered body that contains conductivity enhancing particles, and has electrical resistivity in the range from 1 to 105 &OHgr;·m. In silicon nitride sintered body, agglomeration of conductivity enhancing particles in which distance between conductivity enhancing particles is less than 1 &mgr;m exists by 30% or less by area ratio per unit area. Wear resistant member is used for a bearing ball or the like, being applied in a rotation actuator of electronic equipment such as a magnetic recorder and optical disk drive. Malfunction of electronic equipment due to static electricity may be cancelled due to electrical resistivity that silicon nitride sintered body has.
    Type: Grant
    Filed: August 13, 2001
    Date of Patent: November 4, 2003
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Kimiya Miyashita, Michiyasu Komatsu, Hisao Yabe, Minoru Takao, Yukihiro Takenami, Yoshiyuki Fukuda, Katsuhiro Shinosawa
  • Publication number: 20030186800
    Abstract: A large amount of spinel type silicon nitride powders of a high-pressure phase is produced by mixing raw powders having a particle size of 10 &mgr;m or less of &agr;-, &bgr;- or amorphous silicon nitride, each of which is a low pressure phase, with non-nitrified metal powders at a ratio of 50 weight % or more, preferably copper powders with a particle size of 100 &mgr;m or less, forming a compact with porosity of 50% or less and 10% or more, preferably around 30%, by pressing mixture powders obtained, and subjecting the compact to shock wave compression treatment at a pressure of 20GPa or more, preferably around 60GPa.
    Type: Application
    Filed: March 29, 2002
    Publication date: October 2, 2003
    Inventors: Toshimori Sekine, Hongliang He, Takamichi Kobayashi
  • Publication number: 20030186801
    Abstract: A silicon nitride porous body which is obtained by nitriding a molded body having metallic silicon as a main component and by performing a high temperature heating treatment at a temperature higher than the nitriding temperature, and which has a porous structure with an average pore diameter of 3 &mgr;m or above, and contains at least one kind of element selected from the group consisting of the groups 2A, 3A, 3B inclusive of lanthanoid elements, and 4B. The silicon nitride porous body has a porous structure with a large average pore diameter, a test specimen cut out from the porous body exhibiting a high thermal conductivity and a small thermal expansion coefficient, and can be suitably used in a component for purifying gas and/or solution such as a ceramic filter.
    Type: Application
    Filed: December 19, 2002
    Publication date: October 2, 2003
    Inventors: Katsuhiro Inoue, Kenji Morimoto, Masaaki Masuda, Shinji Kawasaki, Hiroaki Sakai
  • Publication number: 20030176270
    Abstract: A process for producing ceramic bearing components in which a material mixture is produced from an organometallic compound as a preceramic precursor and from silicon in element form or in the form of an alloy as a chemically reactive filler. The material mixture is subjected to reaction pyrolysis for conversion into a ceramic material.
    Type: Application
    Filed: January 27, 2003
    Publication date: September 18, 2003
    Applicant: AB SFK
    Inventor: Jurgen Gegner
  • Publication number: 20030176271
    Abstract: The invention concerns a new and improved method for the production of porous and formed bodies with polycrystalline structure that meets the high quality requirements of the usually excellent material characteristics of porous and formed bodies based on silicon nitride and, at the same time, at least considerably reduces known disadvantages of other state-of-the-art techniques. In this, it is provided to first precompress the silicon nitride powder mix with a modal particle distribution of coarse and fine particles to form a green body, and to subsequently bake it using a temperature-based sintering process.
    Type: Application
    Filed: February 12, 2003
    Publication date: September 18, 2003
    Inventor: Jochen Kriegesmann
  • Patent number: 6599637
    Abstract: A Si3N4 composite substrate which manifests no generation of cracking on the substrate even by mechanical shock or thermal shock, and is excellent in heat radiation property and heat-cycle-resistance property is obtained by using a Si3N4 substrate as a ceramic substrate. A Si3N4 substrate having a thermal conductivity of 90 W/m·K or more and a three-point flexural strength of 700 MPa or more is used, and the thickness tm of a metal layer connected on one major surface of the substrate and the thickness tc of the Si3N4 substrate are controlled so as to satisfy the relation formula: 2 tm≦tc≦20 tm. When metal layers are connected to both major surfaces of the Si3N4 substrate, the thickness tc and the total thickness ttm of the metal layers on both major surfaces are controlled so as to satisfy the relation formula: ttm≦tc≦10 ttm.
    Type: Grant
    Filed: April 24, 2001
    Date of Patent: July 29, 2003
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Ai Itoh, Michimasa Miyanaga, Masashi Yoshimura
  • Publication number: 20030134737
    Abstract: The invention relates to silicon nitride substances containing sintering additives and SiO2, a method for producing them and the use of the same.
    Type: Application
    Filed: April 17, 2000
    Publication date: July 17, 2003
    Inventors: GERHARD WOTTING, MATHIAS HERRMANN, GRIT MICHAEL, STEFAN SIEGEL, LUTZ FRASSEK
  • Patent number: 6593261
    Abstract: A silicon nitride porous body which is a body having a generally columnar outer shape and at least two through-holes mutually parallel to one another and which has generally perpendicularly oriented columnar crystals on the surface of the through-holes.
    Type: Grant
    Filed: April 27, 2001
    Date of Patent: July 15, 2003
    Assignee: Asahi Glass Company, Limited
    Inventors: Nobuhiro Shinohara, Naomichi Miyakawa, Kanji Arai
  • Patent number: 6589448
    Abstract: A ceramic bearing ball in which at least a portion of a constituent ceramic is formed of an electrically conductive inorganic compound phase, whereby a proper electrical conductivity is imparted to the ceramic. Thus, electrifying of a bearing ball is prevented or effectively suppressed. This prevents the problem involved in production of balls of small diameter wherein such balls adhere to an apparatus (e.g., a container) during production thereof, thus hindering smooth progress of the production process. In addition, when ceramic balls are used in precision electronic equipment, such as a hard disk drive of a computer, which is operated at high rotational speed, adhesion of foreign substance due to electrification of the balls, and resultant generation of abnormal noise or vibration can be prevented or effectively suppressed.
    Type: Grant
    Filed: April 10, 2001
    Date of Patent: July 8, 2003
    Assignee: NGK Spark Plug Co., Ltd.
    Inventors: Tomonori Niwa, Tetsuji Yogo
  • Patent number: 6573208
    Abstract: A homogeneous bulky porous ceramic material is provided, the average pore diameter D50 of which is less than 4 &mgr;m and the closed porosity of which is less than 2 &mgr;m, and having a bubble point that matches the pore diameter measured on the material. A hollow fiber based on the material and a module employing such fibers together with a paste constituting a precursor for the material and including a pore-forming agent are also provided.
    Type: Grant
    Filed: March 19, 1999
    Date of Patent: June 3, 2003
    Assignee: Societe des Ceramiques Techniques
    Inventors: Raymond Soria, Jean-Claude Foulon, Jean-Michel Cayrey
  • Publication number: 20030096695
    Abstract: Sintered silicon nitride and a silicon nitride tool. The mean major axis length, the mean minor axis length, and the aspect ratio, represented by (mean major axis length/mean minor axis length) of constituent sintered silicon nitride grains in a silicon nitride tool are controlled, and the thermal conductivity and/or fracture toughness Kc thereof are enhanced, thereby providing a tool having a cutting edge which is not prone to chipping.
    Type: Application
    Filed: November 18, 2002
    Publication date: May 22, 2003
    Applicant: NGK SPARK PLUG CO., LTD.
    Inventor: Kohei Abukawa
  • Patent number: 6562746
    Abstract: The present invention provides a cubic boron nitride-based sintered material excellent in durability and usable for a cutting tool material capable of carrying out high speed cutting of at least a high grade cast iron represented with a Ni-Resist cast iron and an austempered cast iron and having a long life. The present invention further provides a method for manufacturing the cubic boron nitride-based sintered material. The method for the production of a cubic boron nitride-based sintered material includes preparing a starting mixture by mixing particles of cubic boron nitride with a binding powders based on the system of TiCN, Si3N4, Al2O3, and CrxN, wherein x varyies from 1 to 2.7; and subjecting the starting mixture to a sintering process under pressure and at the same time at a high temperature; and recovering a sintered product.
    Type: Grant
    Filed: January 24, 2001
    Date of Patent: May 13, 2003
    Assignees: Aisin Seiki Kabushiki Kaisha, National Institute of Advanced Industrial Science and Technology, Tomei Diamong Co., Ltd.
    Inventors: Yasuhiro Enya, Shoichi Kume, Yoshinori Nishida, Tatsuya Hara
  • Patent number: 6558821
    Abstract: In ceramic sinter consisting of at least one kind selected from a group consisting of silicon nitride, zirconia, silicon carbide, cermet, SIALON, aluminum nitride and alumina, wear resistant member and electronic component member using thereof, skewness at a contact surface of the ceramic sinter is set at −2 or more and 0 or less, a depth of a micro-crack is set at 5 &mgr;m or less, and in the depth of up to 500 &mgr;m from the surface an area that pores occupy does not exceed 5%. The ceramic sinter as described above can suppress wear of the opponent member. Further, in such ceramic sinter, bonding strength with an element or a metal plate can be heightened to enable to suppress peeling. The electronic components of high reliability can be fabricated accordingly. The present wear resistant member is suitable for sliding member that is used in portions where wear is particularly remarkable.
    Type: Grant
    Filed: March 17, 2000
    Date of Patent: May 6, 2003
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Katsuhiro Shinosawa, Hiroyasu Ohta, Mineyuki Yamaga
  • Patent number: 6534428
    Abstract: The present invention relates to a titanium diboride sintered body and a method for manufacturing thereof wherein silicon nitride is added to a titanium diboride as a sintering aid. The sintered body according to the present invention has a fine structure and excellent physical characteristics such as a strength, hardness, etc. Therefore, the sintered body according to the present invention may be applicable to certain materials which requires high strength and hardness.
    Type: Grant
    Filed: May 10, 2002
    Date of Patent: March 18, 2003
    Assignee: Agency For Defense Development
    Inventors: Yong Kee Baek, Hyoun-Ee Kim, June Ho Park, Eul Son Kang
  • Publication number: 20030050178
    Abstract: The invention comprises a self-lubricating ceramic composite characterized as having a low porosity derived from a mixture of at least one ceramic powder preferably selected from the group consisting of silicon nitride, silicon carbide, zirconia, alumina, zirconium nitride, tungsten carbide, and titanium carbide; a cemetitious binder, effective amounts of at least one metal silicide, and at least one metal oxide. The ceramic powder mixture can be slurried with sufficient amounts of water and subsequently subjected to pressures of about 6.0 to 7.0 MPa in a mold at temperatures of about 125° to 175° C. to form a self-lubricating ceramic composite capable of maintaining hot-hardness temperatures above 750° C. These self-lubricating ceramic composites are particularly useful in the manufacture of high-performance turbine engines, including engine parts, bearings, gears, rotors and in other areas where high-heat lubricating properties of the ceramic composite are required.
    Type: Application
    Filed: September 7, 2001
    Publication date: March 13, 2003
    Inventors: Vinod S. Agarwala, Alfeo A. Conte
  • Publication number: 20020155940
    Abstract: Corrosion-resistive ceramic materials include a ceramic having silicon atom wherein a percentage of respective metal elements other than metal elements constituting sintering agents and silicon atom is not more than 10 weight ppm. The corrosion-resistive ceramic materials show a high corrosion resistance with respect to corrosive substances and suppress particle generation due to an exposure to corrosive substances. Therefore, chippings and cracks do not occur easily during a machining work.
    Type: Application
    Filed: January 23, 2002
    Publication date: October 24, 2002
    Applicant: NGK Insulators, Ltd.
    Inventor: Hiromichi Kobayashi
  • Patent number: 6461989
    Abstract: A process is provided for forming a material comprising an M3X1Z2 phase comprising the steps of: (a) providing a mixture of (i) at least one transition metal species, (ii) at least one co-metal species selected from the group consisting of aluminum species, germanium species and silicon species, and (iii) at least one non-metal species selected from the group consisting of boron species, carbon species and nitrogen species; (b) heating said mixture to a temperature of about 1000° C. to about 1800° C., in an atmosphere within a substantially enclosed heating zone, for a time sufficient to form said M3X1Z2 phase; wherein the atmosphere has an O2 partial pressure of no greater than about 1×10−6 atm. The process provides a substantially single phase material comprising very little MZx-phase.
    Type: Grant
    Filed: December 22, 1999
    Date of Patent: October 8, 2002
    Assignees: Drexel University, Sandvik AB
    Inventors: Tamer El-Raghy, Michel W. Barsoum, Mats Sundberg, Hans Pettersson
  • Patent number: 6458732
    Abstract: A dry refractory composition having superior insulating value. The dry refractory composition also may have excellent resistance to molten metals and slags. The composition includes filler lightweight material, which may be selected from perlite, vermiculite, expanded shale, expanded fireclay, expanded alumina silica hollow spheres, bubble alumina, sintered porous alumina, alumina spinel insulating aggregate, calcium alumina insulating aggregate, expanded mulllite, cordierite, and anorthite, and matrix material, which may be selected from calcined alumina, fused alumina, sintered magnesia, fused magnesia, silica fume, fused silica, silicon carbide, boron carbide, titanium diboride, zirconium boride, boron nitride, aluminum nitride, silicon nitride, Sialon, titanium oxide, barium sulfate, zircon, a sillimanite group mineral, pyrophyllite, fireclay, carbon, and calcium fluoride.
    Type: Grant
    Filed: June 7, 1999
    Date of Patent: October 1, 2002
    Assignee: Allied Mineral Products, Inc.
    Inventors: Douglas K. Doza, John Y. Liu
  • Patent number: 6432855
    Abstract: A ceramic material which is an orthorhombic boride of the general formula: AlMgB14:X, with X being a doping agent. The ceramic is a superabrasive, and in most instances provides a hardness of 40 GPa or greater.
    Type: Grant
    Filed: May 23, 2000
    Date of Patent: August 13, 2002
    Assignee: Iowa State University Reseach Foundation, Inc,.
    Inventors: Bruce A. Cook, Joel L. Harringa, Alan M. Russell
  • Publication number: 20020098966
    Abstract: Wear resistant member for electronic equipment comprises a silicon nitride sintered body that contains conductivity enhancing particles, and has electrical resistivity in the range from 1 to 105 &OHgr;·m. In silicon nitride sintered body, agglomeration of conductivity enhancing particles in which distance between conductivity enhancing particles is less than 1 &mgr;m exists by 30% or less by area ratio per unit area. Wear resistant member is used for a bearing ball or the like, being applied in a rotation actuator of electronic equipment such as a magnetic recorder and optical disk drive. Malfunction of electronic equipment due to static electricity may be cancelled due to electrical resistivity that silicon nitride sintered body has.
    Type: Application
    Filed: August 13, 2001
    Publication date: July 25, 2002
    Applicant: KABUSHIKI KAISHA TOSHIBA
    Inventors: Kimiya Miyashita, Michiyasu Komatsu, Hisao Yabe, Minoru Takao, Yukihiro Takenami, Yoshiyuki Fukuda, Katsuhiro Shinosawa
  • Patent number: 6420294
    Abstract: The present invention relates to a titanium diboride sintered body and a method for manufacturing thereof wherein silicon nitride is added to a titanium diboride as a sintering aid. The sintered body according to the present invention has a fine structure and excellent physical characteristics such as a strength, hardness, etc. Therefore, the sintered body according to the present invention may be applicable to certain materials which requires high strength and hardness.
    Type: Grant
    Filed: June 29, 2000
    Date of Patent: July 16, 2002
    Assignee: Agency for Defense Development
    Inventors: Yong Kee Baek, Hyoun-Ee Kim, June Ho Park, Eul Son Kang
  • Patent number: 6410468
    Abstract: A slurry Si-base composition comprising an Si powder having a thickness of a surface oxide film ranging from 1.5 to 15 nm, 50 to 90% by weight of water, 0.2 to 7.5% by weight, in terms of oxide, of a sintering aid and 0.05 to 3% by weight of a dispersant, the Si-base composition having a pH value adjusted to 8-12. This slurry Si-base composition is produced by a process which comprises subjecting Si powder to oxidation treatment at 200 to 800° C. in air, adding 50 to 90% by weight of water, 0.2 to 7.5% by weight, in terms of oxide, of a sintering aid and 0.05 to 3% by weight of a dispersant to the oxidized Si powder and performing such a pH adjustment that the resultant mixture has a pH value of 8 to 12. The slurry Si-base composition not only enables producing a ceramic of Si3N4 at a lowered cost without the need to install explosionproof facilities but also allows the obtained Si3N4 ceramic having a relative density of at least 96% and a flexural strength of at least 800 MPa can be obtained.
    Type: Grant
    Filed: July 5, 2001
    Date of Patent: June 25, 2002
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Seiji Nakahata, Akira Yamakawa
  • Patent number: 6395661
    Abstract: A sintered Si3N4 material, valves and components made with the material, and methods for making same.
    Type: Grant
    Filed: October 4, 1999
    Date of Patent: May 28, 2002
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gerhard Wötting, Ernst Gugel, Hans Andreas Lindner, Peter Woditsch
  • Patent number: 6368993
    Abstract: The present invention relates to a sintered ceramic composite implant material and a fabrication method thereof. A sintered ceramic composite implant material includes an apatite matrix phase, a ceramic secondary phase located in the apatite matrix phase, a barrier layer coating the ceramic secondary phase. The secondary phase compensates for and improves the mechanical properties of the apatite matrix phase and the barrier layer restrains an interfacial reaction between the apatite matrix phase and the secondary phase.
    Type: Grant
    Filed: December 21, 1999
    Date of Patent: April 9, 2002
    Inventors: Hyoun Ee Kim, Young Min Kong, In Seop Lee
  • Publication number: 20020037803
    Abstract: A silicon nitride sintered body, e.g., a ball, exhibiting excellent machinability is disclosed, having an X-ray diffraction profile measured on a cross section of the silicon nitride sintered body by means of a diffractometer such that X&bgr;/(X&agr;+X&bgr;) is 0.9−1, wherein X&agr; is the highest peak intensity associated with a silicon nitride phase and X&bgr; is the highest peak intensity associated with &bgr; silicon nitride phase, and silicon nitride grains of said body have an average grain size dav of 0.5-5.0 &mgr;m and a grain aspect ratio &agr; of 1-5, and are present in an average number of not less than 2×104 per square millimeter in a predominant crystalline phase observed on the cross section.
    Type: Application
    Filed: July 20, 2001
    Publication date: March 28, 2002
    Applicant: NGK SPARK PLUG CO., LTD.
    Inventors: Tomonori Niwa, Tetsuji Yogo
  • Publication number: 20020035026
    Abstract: A molded part of a ceramic material derived from polymers includes a composite body of a single-phase or multi-phase, amorphous, partially crystalline or crystalline matrix of silicon carbide (SiC), silicon nitride (Si3N4), silicon dioxide (SiO2) or mixtures thereof. The matrix contains graphite inclusions and the density of the ceramic material is at least 85% of the theoretical value. The molded part is produced by subjecting a mixture formed of a polymer component in an amount of 30 to 80 wt. % referred to the total weight of the mixture, fillers in an amount of 0 to 30 wt. % and graphite in an amount of 10 to 70 wt. %, to a forming process with heating to effect crosslinking of the polymer components, followed by a pyrolysis process. In particular, the molded parts are produced from polymers of the group including polysilanes, polysiloxanes, polysilazanes or polycarbosilanes. A process for producing ceramic molded parts and a sliding element having a molded part are also provided.
    Type: Application
    Filed: June 18, 2001
    Publication date: March 21, 2002
    Inventors: Peter Greil, Oliver Dernovsek, Hans-Michael Guther, Ulrich Wislsperger
  • Publication number: 20020006858
    Abstract: Low dielectric compounds, preferably silicon nitride precursors such as polycarbosilazanes, are mixed with a sufficient quantity of a silicon carbide additive to enhance absorption of electromagnetic energy by the mixture, thereby permitting efficient and effective curing of low dielectric compounds using electromagnetic energy.
    Type: Application
    Filed: February 2, 2001
    Publication date: January 17, 2002
    Inventors: Scott F. Timmons, Renee C. Graef, Stuart T. Schwab, Montgomery D. Grimes
  • Publication number: 20020006859
    Abstract: A sintered Si3N4 material, valves and components made with the material, and methods for making same.
    Type: Application
    Filed: October 4, 1999
    Publication date: January 17, 2002
    Inventors: GERHARD WOTTING, ERNST GUGEL, HANS ANDREAS LINDNER, PETER WODITSCH
  • Patent number: 6337295
    Abstract: A ceramic granule, obtained by granulating at least one ceramic particle into a granule together with a binder, optionally classifying the ceramic granule to remove fine particle having a particle size of not more than 10 &mgr;m, moistening the granulated ceramic granule in an agitation fluidized bed under the conditions of not aggregating said ceramic granule and regulating the water content of the moistened ceramic granule by fluidizing and drying the moistened ceramic granule in the agitation fluidized bed in such a manner that the resultant granule has a water content within the range which maintains a flowability sufficient for packing the ceramic granule in a mold in which the ceramic granule exhibits well-balanced properties of a crushing property at a low pressure and an anti-collapse property, excels in flowability, packing property into a mold, and anti-sticking property, and has a well-balanced properties of a crushing property at a low pressure and an anti-collapse property.
    Type: Grant
    Filed: May 9, 2000
    Date of Patent: January 8, 2002
    Assignee: TDK Corporation
    Inventor: Hiroshi Harada
  • Publication number: 20020002107
    Abstract: A slurry Si-base composition comprising an Si powder having a thickness of a surface oxide film ranging from 1.5 to 15 nm, 50 to 90% by weight of water, 0.2 to 7.5% by weight, in terms of oxide, of a sintering aid and 0.05 to 3% by weight of a dispersant, the Si-base composition having a pH value adjusted to 8-12. This slurry Si-base composition is produced by a process which comprises subjecting Si powder to oxidation treatment at 200 to 800° C. in air, adding 50 to 90% by weight of water, 0.2 to 7.5% by weight, in terms of oxide, of a sintering aid and 0.05 to 3% by weight of a dispersant to the oxidized Si powder and performing such a pH adjustment that the resultant mixture has a pH value of 8 to 12. The slurry Si-base composition not only enables producing a ceramic of Si3N4 at a lowered cost without the need to install explosionproof facilities but also allows the obtained Si3N4 ceramic having a relative density of at least 96% and a flexural strength of at least 800 MPa can be obtained.
    Type: Application
    Filed: July 5, 2001
    Publication date: January 3, 2002
    Applicant: Sumitomo Electric Industries, Ltd.
    Inventors: Seiji Nakahata, Akira Yamakawa
  • Patent number: 6326325
    Abstract: A method for making silicon oxynitride comprising providing a vaporous gas stream of a compound selected from the group consisting of silazanes and siloxazanes. An enclosed, heated reaction site is also provided. The vaporous gas stream is delivered to the enclosed, heated reaction site in which the levels of oxygen are strictly controlled to promote the formation of silicon oxynitride particles.
    Type: Grant
    Filed: January 18, 2000
    Date of Patent: December 4, 2001
    Assignee: Corning Incorporated
    Inventors: David F. Dawson-Elli, Carlton M. Truesdale
  • Patent number: 6313054
    Abstract: The present invention provides a silicon nitride sintered body having characteristics such as excellent wear resistance, a method for manufacturing the sintered body, and a cutting insert formed thereof. The silicon nitride sintered body is formed of a polycrystalline sintered body of predominantly &bgr;-Si3N4, wherein the oxygen content is 1.2-1.5 wt. %. The method for manufacturing the silicon nitride sintered body includes the following steps: adding an organic binder to a composition containing silicon nitride as an essential component and exhibiting a theoretical oxygen content of 2.0-3.0 wt. %; heating to remove the binder; introducing an oxygen-containing gas so as to control the carbon content to 0.10-0.60 wt. %; and sintering a resultant compact in an nitrogen atmosphere to control the oxygen content to 1.2-1.5 wt. %. The cutting insert of the present invention has excellent wear resistance.
    Type: Grant
    Filed: August 14, 2000
    Date of Patent: November 6, 2001
    Assignee: NGK Spark Plug Co., Ltd.
    Inventor: Masaru Matsubara
  • Publication number: 20010025001
    Abstract: A composite material has a quartz glass phase and a complex compound phase compounded with the quartz glass phase, which is made of one or more compounds selected from a group of silicon carbide, silicon nitride, silicon, titanium nitride and titanium carbide, as a main ingredient. The composite material can be used instead of quartz glass, and can prevent the generations of microcrack, tipping and particles after the mechanical working.
    Type: Application
    Filed: February 20, 2001
    Publication date: September 27, 2001
    Applicant: NGK Insulators, Ltd.
    Inventors: Toshio Oda, Hiromichi Kobayashi, Tsuneaki Ohashi, Shinji Kawasaki
  • Patent number: 6284690
    Abstract: A slurry Si-base composition comprising an Si powder having a thickness of a surface oxide film ranging from 1.5 to 15 nm, 50 to 90% by weight of water, 0.2 to 7.5% by weight, in terms of oxide, of a sintering aid and 0.05 to 3% by weight of a dispersant, the Si-base composition having a pH value adjusted to 8-12. This slurry Si-base composition is produced by a process which comprises subjecting Si powder to oxidation treatment at 200 to 800° C. in air, adding 50 to 90% by weight of water, 0.2 to 7.5% by weight, in terms of oxide, of a sintering aid and 0.05 to 3% by weight of a dispersant to the oxidized Si powder and performing such a pH adjustment that the resultant mixture has a pH value of 8 to 12. The slurry Si-base composition not only enables producing a ceramic of Si3N4 at a lowered cost without the need to install explosionproof facilities but also allows the obtained Si3N4 ceramic having a relative density of at least 96% and a flexural strength of at least 800 MPa can be obtained.
    Type: Grant
    Filed: September 6, 1996
    Date of Patent: September 4, 2001
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Seiji Nakahata, Akira Yamakawa
  • Patent number: 6235665
    Abstract: An improved porous ceramic article and a method for forming such porous ceramic article. A mixture of ceramic particles and pliable organic hollow spheres is prepared in a liquid, typically as a suspension. The article is formed by pressing, slip casting, extruding or injection molding the mixture. The article is dried to remove the liquid, and then is fired so that the ceramic particles are bonded such as by sintering, and the organic spheres are burned off, resulting in a strong porous ceramic article having uniformly spaced interconnected voids.
    Type: Grant
    Filed: August 11, 1999
    Date of Patent: May 22, 2001
    Assignee: Porvair Corporation
    Inventors: Gary R. Pickrell, Kenneth R. Butcher
  • Patent number: 6232252
    Abstract: Provided with a method for preparing a silicon nitride ceramic with high strength and toughness including: mixing 0.2-0.9 wt % of carbon (C) powder with silicon nitride powder containing 5.0-6.0 wt % of yttria (Y2O3) and 1.0-2.0 wt % of alumina (Al2O3) added thereto as a sintering agent, and preparing a molding; subjecting the molding to a carbothermal reduction treatment at 1400-1500° C.; and gas pressure sintering the molding at a temperature above 1850° C. after the carbothermal reduction treatment.
    Type: Grant
    Filed: October 8, 1999
    Date of Patent: May 15, 2001
    Assignee: Korea Institute of Machinery and Materials
    Inventors: Hai Doo Kim, Byung Dong Han, Dong Soo Park