Nickel Patents (Class 502/259)
  • Patent number: 7601670
    Abstract: A method of producing catalyst powder of the present invention has a step of precipitating any one of a noble metal particle (5) and a transition metal particle (10) in a reversed micelle (1); a step of precipitating, in the reversed micelle (1) in which any one of the noble metal particle (5) and the transition metal particle (10) is precipitated, a porous support material (7) which supports the noble metal particle (5) and the transition metal particle (10); and a step of precipitating the other of the noble metal particle (5) and the transition metal particle (10) in the reversed micelle (1) in which any one of the noble metal particle (5).
    Type: Grant
    Filed: February 8, 2005
    Date of Patent: October 13, 2009
    Assignee: Nissan Motor Co., Ltd.
    Inventors: Hirofumi Yasuda, Katsuo Suga, Masanori Nakamura, Hironori Wakamatsu, Kazuyuki Shiratori, Toru Sekiba
  • Patent number: 7598203
    Abstract: Provided are a hydrogenation catalyst for hydrocarbon oil, having markedly improved desulfurization activity, denitrogenation activity, and dearomatization activity; a carrier for the catalyst and its production; and a method of hydrogenation of hydrocarbon oil with the catalyst.
    Type: Grant
    Filed: January 17, 2007
    Date of Patent: October 6, 2009
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Narinobu Kagami, Ryuichiro Iwamoto
  • Publication number: 20090239739
    Abstract: A catalyst 1 has a heat-resistant support 2 selected from among Al2O3, SiO2, ZrO2, and TiO2, and a first metal 4 supported on an outer surface of the support 2, and included by an inclusion material 3 containing a component of the support 2.
    Type: Application
    Filed: December 5, 2005
    Publication date: September 24, 2009
    Inventors: Hirofumi Yasuda, Katsuo Suga, Makoto Aoyama, Toshiharu Miyamura
  • Patent number: 7592290
    Abstract: The invention relates to supported catalysts and a process for the production of these catalysts. These supported catalysts may be used in various reactions such as reforming reactions (e.g. steam methane reforming (SMR) reactions and autothermal reforming (ATR) reactions). In one aspect of the invention, the supported catalyst comprises a transition metal oxide; optionally a rare-earth metal oxide; and a transition metal aluminate.
    Type: Grant
    Filed: April 7, 2005
    Date of Patent: September 22, 2009
    Assignee: Sulzer Metco(Canada) Inc.
    Inventors: Syed Tajammul Hussain, Eugene Stelmack
  • Publication number: 20090226357
    Abstract: The invention concerns a process for preparing metallic nanoparticles with an anisotropic nature by using two different reducing agents, preferably with different reducing powers, on a source of a metal selected from columns 8, 9 or 10 of the periodic table of the elements.
    Type: Application
    Filed: November 14, 2006
    Publication date: September 10, 2009
    Inventors: Denis Uzio, Catherine Verdon, Cecile Thomazeau, Bogdan Harbuzaru, Gilles Berhault
  • Patent number: 7585812
    Abstract: A catalyst for use in the Fischer-Tropsch process, and a method to prepare the catalyst is disclosed. The catalyst of the present invention has a higher surface area, more uniform metal distribution, and smaller metal crystallite size than Fischer-Tropsch catalysts of the prior art.
    Type: Grant
    Filed: June 20, 2008
    Date of Patent: September 8, 2009
    Assignee: Sud-Chemie Inc.
    Inventors: X. D. Hu, Patrick J. Loi, Robert J. O'Brien
  • Patent number: 7585811
    Abstract: A method of producing catalyst powder of the present invention has a step of precipitating a noble metal particle (2) and a porous carrier (1) in a reversed micelle substantially simultaneously; and a step of precipitating a transition metal particle (3) in the reversed micelle. By this method, it is possible to obtain catalyst powder which restricts an aggregation of the noble metal particles even at a high temperature and is excellent in a catalytic activity.
    Type: Grant
    Filed: February 10, 2005
    Date of Patent: September 8, 2009
    Assignee: Nissan Motor Co., Ltd.
    Inventors: Masanori Nakamura, Katsuo Suga, Toru Sekiba, Hironori Wakamatsu, Kazuyuki Shiratori, Hirofumi Yasuda
  • Patent number: 7585810
    Abstract: A catalyst member formed of a substrate configured for gas flow therethrough, a base metal catalytic component disposed in a base metal catalytic layer on the substrate, and a rhodium catalytic material disposed in a rhodium layer. The base metal catalytic component is formed of a base metal; namely, nickel, cobalt, or a combination of at least one of the foregoing base metals. The catalyst member is made by depositing a base metal catalytic component on a substrate configured for gas flow therethrough, and depositing a rhodium catalytic material over the base metal catalytic component.
    Type: Grant
    Filed: September 1, 2004
    Date of Patent: September 8, 2009
    Assignee: Umicore AG & Co. KG
    Inventors: Laiyuan Chen, Jeffrey G. Weissman
  • Patent number: 7582202
    Abstract: A Composition comprising one or more metal hydroxy salts and a matrix, binder or carrier material, wherein the metal hydroxy salt is a compound comprising (a) as metal either (i) one or more divalent metals, at least one of them being selected from the group consisting of Ni, Co, Ca, Zn, Mg, Fe, and Mn, or (ii) one or more trivalent metal(s), (b) framework hydroxide, and (c) a replaceable anion. This composition has various catalytic applications.
    Type: Grant
    Filed: February 10, 2004
    Date of Patent: September 1, 2009
    Assignees: Akzo Nobel N.V., Albemarle Netherlands B.V.
    Inventors: William Jones, Paul O'Connor, Dennis Stamires
  • Publication number: 20090209412
    Abstract: A method of preparing a steam reforming catalyst characterized by improved resistance to attrition loss when used for cracking, reforming, water gas shift and gasification reactions on feedstock in a fluidized bed reactor, comprising: fabricating the ceramic support particle, coating a ceramic support by adding an aqueous solution of a precursor salt of a metal selected from the group consisting of Ni, Pt, Pd, Ru, Rh, Cr, Co, Mn, Mg, K, La and Fe and mixtures thereof to the ceramic support and calcining the coated ceramic in air to convert the metal salts to metal oxides.
    Type: Application
    Filed: October 7, 2005
    Publication date: August 20, 2009
    Applicant: ALLIANCE FOR SUSTAINABLE ENERGY, LLC
    Inventors: Yves O. Parent, Kim Magrini, Steven M. Landin, Marcus A. Ritland
  • Patent number: 7569513
    Abstract: Novel nickel and/or cobalt plated sponge based catalysts are disclosed. The catalyst have an activity and/or selectivity comparable to conventional nickel and/or cobalt sponge catalysts, e.g., Raney® nickel or Raney® cobalt catalysts, but require a reduced content of nickel and/or cobalt. Catalysts in accordance with the invention comprise nickel and/or cobalt coated on at least a portion of the surface of a sponge support. Preferably, the sponge support comprises at least one metal other than or different from the metal(s) contained in the coating. The method of preparing the plated catalysts, and the method of using the catalysts in the preparation of organic compounds are also disclosed.
    Type: Grant
    Filed: April 21, 2008
    Date of Patent: August 4, 2009
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: Stephen Raymond Schmidt
  • Patent number: 7566393
    Abstract: Compounds and methods for sorbing organosulfur compounds from fluids are provided. Generally, compounds according to the present invention comprise mesoporous, nanocrystalline metal oxides. Preferred metal oxide compounds either exhibit soft Lewis acid properties or are impregnated with a material exhibiting soft Lewis acid properties. Methods according to the invention comprise contacting a fluid containing organosulfur contaminants with a mesoporous, nanocrystalline metal oxide. In a preferred embodiment, nanocrystalline metal oxide particles are formed into pellets (14) and placed inside a fuel filter housing (12) for removing organosulfur contaminants from a hydrocarbon fuel stream.
    Type: Grant
    Filed: April 26, 2005
    Date of Patent: July 28, 2009
    Assignee: NanoScale Corporation
    Inventors: Kenneth Klabunde, Bill R. Sanford, P. Jeevanandam
  • Patent number: 7563743
    Abstract: This invention relates to doped catalysts on an aluminosilicate substrate with a low content of macropores and the hydrocracking/hydroconversion and hydrotreatment processes that use them. The catalyst comprises at least one hydro-dehydrogenating element that is selected from the group that is formed by the elements of group VIB and group VIII of the periodic table and a dopant in a controlled quantity that is selected from among phosphorus, boron, and silicon and a non-zeolitic substrate with a silica-alumina base that contains a quantity of more than 15% by weight and of less than or equal to 95% by weight of silica (SiO2).
    Type: Grant
    Filed: September 8, 2005
    Date of Patent: July 21, 2009
    Assignee: Institute Francais du Petrole
    Inventors: Patrick Euzen, Alexandra Chaumonnot, Carole Bobin, Patrick Bourges, Christophe Gueret, Hugues Dulot
  • Patent number: 7563745
    Abstract: The invention relates to a shaped catalyst or catalyst precursor containing a catalytically active component or a precursor therefore, the component selected from elements of Group VIII of the Periodic Table of the Elements, supported on a carrier, which catalyst or catalyst precursor is an elongated shaped particle having three protrusions each extending from and attached to a central position, wherein the central position is aligned along the longitudinal axis of the particle, the cross-section of the particle occupying the space encompassed by the outer edges of six circles around a central circle, each of the six circles touching two neighboring circles while three alternating circles are equidistant to the central circle and may be attached to the central circle, minus the space occupied by the three remaining outer circles and including the six interstitial regions.
    Type: Grant
    Filed: June 6, 2003
    Date of Patent: July 21, 2009
    Assignee: Shell Oil Company
    Inventors: Arend Hoek, Hans Michiel Huisman, Carolus Matthias Anna Maria Mesters
  • Patent number: 7563742
    Abstract: Supported nickel catalyst having high nickel loading and dispersion are manufactured using a dispersing agent. The dispersing agent molecules include at least one functional group that bonds with the nickel atoms and influences nanoparticle formation. The support material is loaded with at least about 5% nickel, more preferably at least about 8%, and most preferably at least about 12% by weight of the total catalyst. Catalysts manufactured using the organic dispersing agents and loaded with the foregoing amounts of nickel have metal dispersions greater than about 5% as measured by hydrogen adsorption, more preferably greater than about 10%, and most preferably greater than about 15%.
    Type: Grant
    Filed: September 22, 2006
    Date of Patent: July 21, 2009
    Assignee: Headwaters Technology Innovation, LLC
    Inventors: Clementine Reyes, Martin Fransson, Horacio Treviño, Bing Zhou
  • Patent number: 7557062
    Abstract: An unsupported catalyst composition which comprises one or more Group VIb metals, one or more Group VIII metals, and a refractory oxide material which comprises 50 wt % or more titania, on oxide basis, which is prepared by precipitation techniques, finds use in the hydroprocessing of hydrocarbonaceous feedstocks.
    Type: Grant
    Filed: February 20, 2004
    Date of Patent: July 7, 2009
    Assignee: Shell Oil Company
    Inventors: Laszlo Domokos, Hermanus Jongkind, Willem Hartman Jurriaan Stork, Johanna Maria Helena Van den Tol-Kershof
  • Patent number: 7544285
    Abstract: A bulk metal oxide catalyst composition of the general formula (X)b(M)c(Z)d(O)e??(I) wherein X represents at least one non-noble Group VIII metal; M represents at least one non-noble Group VIb metal; Z represents one or more elements selected from aluminium, silicon, magnesium, titanium, zirconium, boron, and zinc; one of b and c is the integer 1; and d and e and the other of b and c each are a number greater than 0 such that the molar ratio of b:c is in the range of from 0.5:1 to 5:1, the molar ratio of d:c is in the range of from 0.2:1 to 50:1, and the molar ratio of e:c is in the range of from 3.7:1 to 108:1; is prepared by controlled (co)precipitation of component metal compounds, refractory oxide material, and alkali compound in protic liquid. Resulting compositions find use in hydrotreatment processes involving particularly hydrodesulphurisation and hydrodenitrification.
    Type: Grant
    Filed: February 20, 2004
    Date of Patent: June 9, 2009
    Assignee: Shell Oil Company
    Inventors: Laszlo Domokos, Hermanus Jongkind, Johannes Anthonius Robert Van Veen
  • Patent number: 7541012
    Abstract: The present invention features a catalytic material which includes a metal catalyst anchored to a nano-sized crystal containing a metal oxide. Furthermore, the present invention features a method of producing the catalytic material described herein. Finally, the present invention features using the catalytic material for removing contaminants and for getting the desired products.
    Type: Grant
    Filed: July 7, 2004
    Date of Patent: June 2, 2009
    Assignee: The Hong Kong University of Science and Technology
    Inventors: King Lun Yeung, Nan Yao, Ka Yee Ho
  • Patent number: 7538066
    Abstract: This invention relates to supported multi-metallic catalysts for use in the hydroprocessing of hydrocarbon feeds, as well as a method for preparing such catalysts. The catalysts are prepared from a catalyst precursor comprised of at least one Group VIII metal and a Group VI metal and an organic agent selected from the group consisting of amino alcohols and amino acids.
    Type: Grant
    Filed: September 29, 2005
    Date of Patent: May 26, 2009
    Assignee: Exxonmobil Research and Engineering Company
    Inventors: Stuart L. Soled, Sabato Miseo, Joseph E. Baumgartner, Christine E. Kliewer, Jeffrey T. Elks
  • Publication number: 20090121613
    Abstract: A method for producing a carbon nanotube assembly, the method controlling a growth density of carbon nanotubes on a substrate, includes: a step for preparing a catalyst particle dispersed film-formed substrate including a catalyst particle dispersed film in which metal catalyst particles having a predetermined particle diameter are dispersed among barrier particles; and a thermal CVD step for growing carbon nanotubes from the metal catalyst particles serving as starting points by heat decomposition of an organic compound vapor.
    Type: Application
    Filed: September 10, 2008
    Publication date: May 14, 2009
    Applicant: NIKON CORPORATION
    Inventors: Yusuke Taki, Kiyoaki Shinohara, Makiko Kikuchi
  • Patent number: 7528092
    Abstract: The present invention relates to a catalyst nickel, silica, alumina and magnesium, wherein the nickel to magnesium atomic ratio is 5-75. In particular the present invention relates to a catalyst comprising nickel, silica, alumina and magnesium, wherein the nickel to silicium atomic ratio (Ni/Si) is 2 to 30 the nickel to aluminum atomic ratio (Ni/Al) is 9 to 40 and the nickel to magnesium atomic ratio (Ni/Mg) is 5-75. The invention further relates to a method for preparing such a catalyst. The invention further relates to a process for hydrogenating unsaturated organic compounds.
    Type: Grant
    Filed: October 17, 2003
    Date of Patent: May 5, 2009
    Assignee: BASF Catalysts LLC
    Inventors: Pieter Hildegardus Berben, Tjalling Rekker
  • Patent number: 7518023
    Abstract: The invention relates to highly active spherical metal support catalysts with a metal content of 10 to 70% by mass, and a process for their production with the use of a mixture of polysaccharides and at least one metal compound which is dropped into a metal salt solution.
    Type: Grant
    Filed: December 14, 2006
    Date of Patent: April 14, 2009
    Assignee: Shell Internationale Research Maatschappij, B.V.
    Inventors: Reinhard Geyer, Rainer Schödel, Peter Birke, Jürgen Hunold
  • Publication number: 20090088317
    Abstract: A reduction catalyst having a first metal component comprising one of Co, Os, Fe, Re, Rh and Ru. The first metal component is present in the catalyst at from 0.5 percent to 20 percent, by weight. A second metal component differing from the first metal component present in the catalyst with the second metal component being selected from the group consisting of Fe, Mn, Ru, Os, Rh, Ir, Ni, Pd, Pt, Ag, Au, Zn, Co, Re, Cu, Pb, Cr, W, Mo, Sn, Nb, Cd, Te, V, Bi, Ga and Na. A hydrogenation catalyst comprising one or both of Ni and Co and one or more elements selected from the group consisting of Mn, Fe, Ag, Au, Mo and Rh.
    Type: Application
    Filed: September 28, 2007
    Publication date: April 2, 2009
    Inventors: John G. Frye, JR., Johnathan E. Holladay, Danielle S. Muzatko, James F. White, Alan H. Zacher
  • Patent number: 7510994
    Abstract: A catalyst is provided which is low in methane selectivity in a high CO conversion region and high in chain growth probability ? in a Fischer-Tropsch synthesis and comprises a support comprising silica or alumina and an oxide of zirconium and/or titanium loaded thereon in film form in an amount ranging from 0.5 percent by mass to 10.0 percent in terms of metal, and one or more metals selected from the group consisting of cobalt, nickel and ruthenium loaded on the support.
    Type: Grant
    Filed: October 3, 2006
    Date of Patent: March 31, 2009
    Assignee: Nippon Oil Corporation
    Inventors: Masakazu Ikeda, Toshio Waku, Nobuo Aoki
  • Publication number: 20090078157
    Abstract: The invention is directed to a synthetic inorganic material, comprising inorganic compounds based on elementary particles with a sheet (phyllosilicate) structure, the elementary particles consisting of a central layer of octahedrally coordinated divalent metal ions between two layers of tetrahedrally surrounded silicon ions, which particles are substantially free of aluminum, free silica and salts and hydroxides of the divalent metal ions, the material not containing any metal ions that can be reduced to the corresponding metals at temperatures of 700° C. or less.
    Type: Application
    Filed: May 1, 2006
    Publication date: March 26, 2009
    Applicant: Eurosupport B.V.
    Inventors: John Wihelm Geus, Jacobus Berend Dirksen
  • Publication number: 20090036296
    Abstract: A catalyst for use in the Fischer-Tropsch process, and a method to prepare the catalyst is disclosed. The catalyst of the present invention has a higher surface area, more uniform metal distribution, and smaller metal crystallite size than Fischer-Tropsch catalysts of the prior art.
    Type: Application
    Filed: June 20, 2008
    Publication date: February 5, 2009
    Inventors: X.D. Hu, Patrick J. Loi, Robert J. O'Brien
  • Publication number: 20090036558
    Abstract: The present invention relates to a process for the conversion of synthesis gas to hydrocarbons in the presence of a modified supporter Fischer-Tropsch catalyst composition.
    Type: Application
    Filed: September 29, 2008
    Publication date: February 5, 2009
    Applicants: BP Exploration Operating Company Limited, Davy Process Technology Limited
    Inventors: Josephus Johannes Helena Maria Font Freide, Lawrence Trevor Hardy
  • Publication number: 20090023822
    Abstract: A system and process to activate, regenerate and use a Fischer-Tropsch catalyst at Fisher-Tropsch vessel reaction temperatures from about 100° C. to about 300° C.
    Type: Application
    Filed: July 19, 2007
    Publication date: January 22, 2009
    Inventor: Peter J. Tijm
  • Publication number: 20090011925
    Abstract: A catalytically active glass-ceramic and method for producing a catalytically active multi-phase glass-ceramic in which at least one catalyst precursor is mixed with a glass-ceramic precursor formulation to form a catalyst precursor/glass-ceramic precursor mixture. The catalyst precursor/glass-ceramic precursor mixture is then melted to form an amorphous glass material which, in turn, is devitrified to form a polycrystalline ceramic. The polycrystalline ceramic is then activated, forming a catalytically active multi-phase glass-ceramic.
    Type: Application
    Filed: July 6, 2007
    Publication date: January 8, 2009
    Inventors: Larry Gordon Felix, David Morrissey Rue, Thomas Philip Seward, III, Logan Edwin Weast
  • Patent number: 7468342
    Abstract: As catalysts for producing aromatic amines by hydrogenating aromatic nitrites, there are disclosed (1) the catalyst comprising a metal catalyst component comprising Ni and/or Co and a specific amount of zirconia as a carrier component, which is prepared by drying, calcining and forming a precipitate produced by adding an aqueous solution containing soluble salts of the metal catalyst component and the carrier component to an aqueous alkali solution; and (2) the catalyst comprising the metal catalyst component and the carrier component, which is prepared by filtering a precipitate produced by adding an aqueous solution containing soluble salts of the metal catalyst component and the carrier component to an aqueous alkali solution; forming the precipitate without drying to obtain a formed product; and subjecting the formed product to drying and then calcining.
    Type: Grant
    Filed: May 7, 2002
    Date of Patent: December 23, 2008
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Yoshinori Kanamori, Shuji Ebata, Kengo Tsukahara, Yasushi Hiramatsu
  • Patent number: 7462577
    Abstract: A method of making a catalyst. The method comprises the step of leaching a portion of the bulk of an alloy. The alloy may be a hydrogen storage alloy.
    Type: Grant
    Filed: May 12, 2006
    Date of Patent: December 9, 2008
    Assignee: Ovonic Battery Company, Inc.
    Inventors: Michael A. Fetcenko, Stanford R. Ovshinsky, Kwo Young
  • Patent number: 7452844
    Abstract: The Fischer-Tropsch catalyst of the present invention is a transition metal-based catalyst having a high surface area, a smooth, homogeneous surface morphology, an essentially uniform distribution of cobalt throughout the support, and a small metal crystallite size. In a first embodiment, the catalyst has a surface area of from about 100 m2/g to about 250 m2/g; an essentially smooth, homogeneous surface morphology; an essentially uniform distribution of metal throughout an essentially inert support; and a metal oxide crystallite size of from about 40 ? to about 200 ?. In a second embodiment, the Fischer-Tropsch catalyst is a cobalt-based catalyst with a first precious metal promoter and a second metal promoter on an aluminum oxide support, the catalyst having from about 5 wt % to about 60 wt % cobalt; from about 0.0001 wt % to about 1 wt % of the first promoter, and from about 0.01 wt % to about 5 wt % of the second promoter.
    Type: Grant
    Filed: May 8, 2001
    Date of Patent: November 18, 2008
    Assignee: Süd-Chemie Inc
    Inventors: X. D. Hu, Patrick J. Loi, Robert J. O'Brien
  • Publication number: 20080280750
    Abstract: Catalysts for treating acid gases and halogen gases and the production methods thereof. The acid and halogen gases include HCl, HF, HBr, HI, F2, Cl2, Br2, I2, ClF3, PH3, PCl3, PCl5, POCl3, P2O5, AsH3, SiH4, SiF4, SiCl4, SiHCl3, SiH2Cl2, BF3, BCl3, GeCl4, GeH4, NO, NO2, SO2, SO3 and SF6, etc. The catalysts comprise one or more carrier materials selected from activated carbon, argil, diatomite, cement, silica and ceramic materials; and one or more metal compounds selected from: alkali metal hydroxides, oxides, carbonates and bicarbonates, alkaline earth metal hydroxides, oxides, carbonates and bicarbonates, Group IIIA metal oxides, Group IVA metal oxides, and transition metal oxides, oxide hydrates, sulfates and carbonates.
    Type: Application
    Filed: May 6, 2008
    Publication date: November 13, 2008
    Inventor: Pao-Chu Liu
  • Publication number: 20080262113
    Abstract: A process for preparing a Fischer-Tropsch catalyst comprising the steps of a) providing a particle comprising a support and having a catalytically active metal homogenously distributed therein, wherein at least 50 wt % of the catalytically active metal is present as divalent oxide or divalent hydroxide; b) treating the particle with a water vapour comprising gas having a relative humidity of at least 80% or with liquid water for at least two hours; and c) drying the catalyst particle.
    Type: Application
    Filed: April 9, 2008
    Publication date: October 23, 2008
    Inventors: Hans Peter Alexander Calis, Marinus Johannes Reynhout, Guy Lode Magda Maria Verbist
  • Publication number: 20080255256
    Abstract: A catalyst composition comprising cobalt as an active catalytic element and a lesser amount of nickel as a promoter supported on a metal oxide support. The support may comprise alumina, silica, silica-alumina, zeolite, zirconia, magnesia or titania. The amount of nickel is preferably less than 50 wt %, relative to the amount of cobalt.
    Type: Application
    Filed: September 23, 2005
    Publication date: October 16, 2008
    Inventor: Erling Rytter
  • Publication number: 20080241639
    Abstract: There is provided a catalyst for a fuel cell, which simultaneously realizes excellent catalytic activity and catalytic stability. The catalyst for a fuel cell comprises a fine particle of a metal represented by formula: PtxRuySizT1u wherein T1 represents at least one element selected from the group consisting of nickel (Ni), tungsten (W), vanadium (V), and molybdenum (Mo); x=30 to 90 atomic %; y=0 to 50 atomic %; z=0.5 to 20 atomic %; and u=0.5 to 40 atomic %, or comprises a fine particle of a metal represented by formula: PtxRuySizT2u wherein T2 represents at least one element selected from the group consisting of hafnium (Hf), tin (Sn), zirconium (Zr), niobium (Nb), titanium (Ti), tantalum (Ta), chromium (Cr), and aluminum (Al); x=30 to 90 atomic %; y=0 to 50 atomic %; z=0.5 to 20 atomic %; and u=0.5 to 40 atomic %.
    Type: Application
    Filed: March 17, 2008
    Publication date: October 2, 2008
    Applicant: KABUSHIKI KAISHA TOSHIBA
    Inventors: Wu MEI, Taishi Fukazawa, Takahiro Sato, Itsuko Mizutani, Yoshihiko Nakano
  • Publication number: 20080234125
    Abstract: A catalyst and a method for selective hydrogenation of acetylene and dienes in light olefin feedstreams are provided. The catalyst retains higher activity and selectivity after regeneration than conventional selective hydrogenation catalysts. The catalyst contains a first component and a second component supported on an inorganic support. The inorganic support contains at least one salt or oxide of zirconium, a lanthanide, or an alkaline earth.
    Type: Application
    Filed: June 2, 2008
    Publication date: September 25, 2008
    Inventors: Yongqing Zhang, Stephen J. Golden
  • Patent number: 7425647
    Abstract: A process for preparing a catalyst by (a) selecting a carrier which is a silica based carrier which has been subjected to a series of washings with one or more aqueous liquids consisting of aqueous liquids which have a pH of least 3, when measured at 20° C., or which is a silica based carrier which is formed from materials one or more of which have been subjected to this series of washings, (b) precipitating a Group 8 metal compound onto the carrier, (c) converting the precipitated Group 8 metal compound into metallic species, and (d) subjecting the Group 8 metal/carrier composition to a purification treatment, before or after step (c); a catalyst which is obtainable by this process; and a process for preparing an alkenyl carboxylate by reacting a mixture comprising an olefin, a carboxylic acid and oxygen in the presence of the catalyst.
    Type: Grant
    Filed: March 28, 2002
    Date of Patent: September 16, 2008
    Assignee: Shell Oil Company
    Inventors: Michael Francis Lemanski, John Robert Lockemeyer
  • Patent number: 7422995
    Abstract: The present invention relates to a Catalyst comprising a, preferably oxidic, core material, a shell of zinc oxide around said core material, and a catalytically active material in or on the shell, based on one or more of the metals cobalt, iron, ruthenium and/or nickel, preferably a Fischer-Tropsch catalyst, to the preparation of such a catalyst and the use thereof in GTL processes.
    Type: Grant
    Filed: April 30, 2004
    Date of Patent: September 9, 2008
    Assignee: BASF Catalysts LLC
    Inventors: Cornelis Roeland Baijense, Geoffrey Johnson, Ahmad Moini
  • Publication number: 20080193370
    Abstract: Materials that are useful for absorption enhanced reforming (AER) of a fuel, including absorbent materials and catalyst materials and methods for using the materials. The materials can be fabricated by spray processing. The use of the materials in AER can produce a H2 product gas having a high H2 content and a low level of carbon oxides.
    Type: Application
    Filed: August 31, 2007
    Publication date: August 14, 2008
    Applicant: CABOT CORPORATION
    Inventors: Mark J. Hampden-Smith, Paolina Atanassova, Jian-Ping Shen, James Brewster, Paul Napolitano
  • Patent number: 7351328
    Abstract: A composition comprising a metal oxide and a promoter, wherein at least a portion of the promoter is present as a reduced valence promoter, and methods of preparing such composition are disclosed. The thus-obtained composition is employed in a desulfurization zone to remove sulfur from a hydrocarbon stream.
    Type: Grant
    Filed: July 23, 2003
    Date of Patent: April 1, 2008
    Assignee: China Petroleum & Chemical Corporation
    Inventors: Tushar V. Choudhary, Jason J. Gislason, Glenn W. Dodwell, William H. Beever
  • Publication number: 20080076660
    Abstract: Supported nickel catalyst having high nickel loading and dispersion are manufactured using a dispersing agent. The dispersing agent molecules include at least one functional group that bonds with the nickel atoms and influences nanoparticle formation. The support material is loaded with at least about 5% nickel, more preferably at least about 8%, and most preferably at least about 12% by weight of the total catalyst. Catalysts manufactured using the organic dispersing agents and loaded with the foregoing amounts of nickel have metal dispersions greater than about 5% as measured by hydrogen adsorption, more preferably greater than about 10%, and most preferably greater than about 15%.
    Type: Application
    Filed: September 22, 2006
    Publication date: March 27, 2008
    Inventors: Clementine Reyes, Martin Fransson, Horacio Trevifio, Bing Zhou
  • Patent number: 7294604
    Abstract: A process for hydrogenating unsaturations in petrochemical feedstocks, the process comprising contacting the petrochemical feedstock, including at least one component having unsaturations, and hydrogen with a catalyst comprising at least one Group Ia, Ib, IIb, VIb, VIIb or VIII metal on a support of a crystalline calcium silicate having a surface area of at least 30 m2/g, the support being in the form of substantially spherical particles having a mean diameter of from 10 to 200 microns and pores in the particles having a diameter of from 100 to 2000 Angstroms, at a temperature of from 0 to 550° C. and a pressure of from 3 to 150 barg.
    Type: Grant
    Filed: July 16, 2002
    Date of Patent: November 13, 2007
    Assignee: Total Petrochemicals Research Feluy
    Inventors: Jean-Pierre Dath, Walter Vermeiren
  • Patent number: 7270738
    Abstract: This invention relates to silico-aluminum substrates, catalysts, and the hydrocracking and hydrotreatment processes that use them. The catalyst comprises at least one hydro-dehydrogenating element that is selected from the group that is formed by elements of group VIB and group VIII of the periodic table and a non-zeolitic silica-alumina-based substrate that contains an amount of more than 5% by weight and less than or equal to 95% by weight of silica (SiO2) and has the following characteristics: A mean pore diameter, measured by mercury porosimetry, encompassed between 20 and 140 ?, a total pore volume, measured by mercury porosimetry, encompassed between 0.1 ml/g and 0.6 ml/g, a total pore volume, measured by nitrogen porosimetry, encompassed between 0.1 ml/g and 0.6 ml/g, a BET specific surface area encompassed between 100 and 550 m2/g, a pore volume, measured by mercury porosimetry, encompassed in the pores with diameters of more than 140 ?, of less than 0.
    Type: Grant
    Filed: October 30, 2003
    Date of Patent: September 18, 2007
    Assignee: Institut Francais du Petrole
    Inventors: Patrick Euzen, Carole Bobin, Magalie Roy-Auberger, Eric Benazzi, Patrick Bourges, Christophe Gueret
  • Patent number: 7268097
    Abstract: A desulfurizing agent comprising a silica-alumina carrier having an Si/Al mole ratio of 10 or less and nickel carried thereon; a desulfurizing agent for hydrocarbons derived from petroleum which comprises a carrier and a metal component carried thereon and has a specific surface area of pores having a pore diameter of 3 nm or less of 100 m2/g or more; an Ni-Cu based desulfurizing agent comprising a carrier and, carried thereon, (A) nickel, (B) copper, and (C) an alkali metal or another metal; a desulfurizing agent for hydrocarbons derived from petroleum which comprises a carrier and a metal component carried thereon and has a hydrogen adsorption capacity of 0.4 mmol/g or more; and methods for producing these nickel-based and nickel-copper-based desulfurizing agents. The above desulfurizing agents are capable of adsorbing and removing with good efficiency the sulfur contained in hydrocarbons derived from petroleum to a content of 0.2 wt. ppm or less and have a long service life.
    Type: Grant
    Filed: April 2, 2001
    Date of Patent: September 11, 2007
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Hisashi Katsuno, Satoshi Matsuda, Kazuhito Saito, Masahiro Yoshinaka
  • Patent number: 7256154
    Abstract: The present invention relates to a structured catalyst for reforming of gasoline and a method of preparing the same, more particularly to a structured catalyst for reforming of gasoline for fuel-cell powered vehicles prepared by wash-coating the transition metal based reforming catalyst on the surface of the ceramic honeycomb support wash-coated with sub-micron sized alumina or its precursor to sufficiently increase the effective surface area and the performance of the catalyst and a method of preparing the same.
    Type: Grant
    Filed: April 23, 2004
    Date of Patent: August 14, 2007
    Assignee: Korea Institute of Science and Technology
    Inventors: Dong Ju Moon, Jong Woo Ryu, Dong Min Kang, Byung Gwon Lee, Byoung Sung Ahn, Sang Deuk Lee
  • Patent number: 7220699
    Abstract: A method and device for loading a catalyst into a chamber. The catalyst loading is well suited for production of hydrogen producing microreactors. The catalyst is coated onto a strip which is mountable within the chamber.
    Type: Grant
    Filed: March 31, 2003
    Date of Patent: May 22, 2007
    Assignee: Intelligent Energy, Inc.
    Inventor: Anand Chellappa
  • Patent number: 7196034
    Abstract: The invention is directed to a catalyst suitable for the hydrogenation of hydrocarbon resins, comprising a supported nickel on silica and alumina catalyst, said catalyst having a nickel content of 45 to 85 wt. %, a silicon content, calculated as SiO2, of 14 to 45 wt. %, an aluminium content, calculated as Al2O3, of 1 to 15 wt. % an iron content, calculated as Fe, 0.25 to 4 wt. %, all percentages having been calculated on the basis of the reduced catalyst, and which catalyst has a volume of pores between 2 and 60 nm, as defined herein, of at least 0.35 ml/g of catalyst.
    Type: Grant
    Filed: November 17, 2000
    Date of Patent: March 27, 2007
    Assignee: Engelhard Corporation
    Inventor: Lucas Laurentius Kramer
  • Patent number: 7179366
    Abstract: A catalyst contains at least one group VIII element and at least molybdenum and/or tungsten, said elements being present at least in part in the catalyst in the dry state in the form of at least one heteropolyanion with formula MxAB6O24H6C(3-2x), tH2O; MxAB6O24H6C(4-2x), tH2O; MxA2B10O38H4C(6-2x), tH2O; MxA2B10O38H4C(8-2x), tH2O; or MxA2B10O38H4C(7-2x), tH2O, in which M is cobalt and/or nickel and/or iron and/or copper and/or zinc, A is one or two elements from group VIII of the periodic table, B is molybdenum and/or tungsten and C is an H+ ion and/or a (NR1R2R3R4)+ type ammonium ion, in which R1, R2, R3 and R4, which may be identical or different, correspond either to a hydrogen atom or to an alkyl group and/or caesium and/or potassium and/or sodium, t is a number between 0 and 15 and x takes a value in the range 0 to 4 depending on the formula.
    Type: Grant
    Filed: August 1, 2003
    Date of Patent: February 20, 2007
    Assignee: Institut Francais du Petrole
    Inventors: Virginie Harle, Catherine Martin, Edmond Payen, Carole Lamonier, Pascal Blanchard
  • Patent number: 7172990
    Abstract: The invention relates to highly active spherical metal support catalysts with a metal content of 10 to 70% by mass, and a process for their production with the use of a mixture of polysaccharides and at least one metal compound which is dropped into a metal salt solution.
    Type: Grant
    Filed: January 17, 2003
    Date of Patent: February 6, 2007
    Assignee: Shell Internationale Research Maatschappiji, B.V.
    Inventors: Reinhard Geyer, Rainer Schödel, Peter Birke, Jürgen Hunold