Vanadium Containing Patents (Class 502/312)
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Patent number: 8569200Abstract: A catalyst for hydrocarbon steam cracking for the production of light olefin, a preparation method of the catalyst and a preparation method of olefin by using the same. More precisely, the present invention relates to a composite catalyst prepared by mixing the oxide catalyst powder represented by CrZrjAkOx (0.5?j?120, 0?k?50, A is a transition metal, x is the number satisfying the condition according to valences of Cr, Zr and A, and values of j and k) and carrier powder and sintering thereof, a composite catalyst wherein the oxide catalyst is impregnated on a carrier, and a method of preparing light olefin such as ethylene and propylene by hydrocarbon steam cracking in the presence of the composite catalyst. The composite catalyst of the present invention has excellent thermal/mechanical stability in the cracking process, and has less inactivation rate by coke and significantly increases light olefin yield.Type: GrantFiled: December 1, 2011Date of Patent: October 29, 2013Assignee: LG Chem, Ltd.Inventors: Jun-han Kang, Jong-hun Song, Jun-seon Choi, Byoung-gi Park, Chang-hoon Kang, Si-hyun Noh
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Publication number: 20130253216Abstract: An apparatus for producing a catalyst comprising a tank configured to prepare an aqueous mixed solution containing a Mo compound, a V compound and a Nb compound, a dryer configured to spray-dry the aqueous mixed solution, and a pipe for connecting the tank with the dryer so that the aqueous mixed solution can be supplied from the tank to the dryer, wherein a heater configured to heat the aqueous mixed solution is provided in the tank and/or the pipe, and a filter configured to filtrate the aqueous mixed solution is provided in the pipe.Type: ApplicationFiled: December 13, 2011Publication date: September 26, 2013Applicant: ASAHI KASEI CHEMICALS CORPORATIONInventors: Takaaki Kato, Satoshi Endo, Minoru Kadowaki
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Publication number: 20130253223Abstract: Provided is a catalyst for producing unsaturated carboxylic acid, which excels in mechanical strength and attrition loss and is capable of producing the object product at a high yield. This catalyst is formed of a catalytically active component comprising molybdenum and vanadium as the essential ingredients and inorganic fibers, which are supported on an inert carrier, said catalyst being characterized in that said inorganic fibers comprise at least an inorganic fiber having an average diameter less than 1.0 ?m and another inorganic fiber having an average diameter ranging from 1.5 to 7 ?m.Type: ApplicationFiled: September 26, 2011Publication date: September 26, 2013Applicant: NIPPON SHOKUBAI CO., LTD.Inventor: Toshiya Nishiguchi
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Publication number: 20130253217Abstract: A method for producing a complex oxide catalyst containing a complex oxide represented by the formula: Mo1VaSbbNbcWdZeOn (wherein a component Z represents an element such as La, Ce, Pr, Yb, Y, Sc, Sr, and Ba; a, b, c, d, e, and n each represent an atomic ratio of an element to one Mo atom; 0.1?a?0.4, 0.1?b?0.4, 0.01?c?0.3, 0?d?0.2, and 0?e?0.1; an atomic ratio a/b is 0.85?a/b<1.0, and an atomic ratio a/c is 1.4<a/c<2.3.Type: ApplicationFiled: December 27, 2011Publication date: September 26, 2013Applicant: ASAHI KASEI CHEMICALS CORPORATIONInventors: Yusuke Ishii, Takaaki Kato
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Publication number: 20130225862Abstract: Disclosed is a process for producing an oxide catalyst for use in the gas-phase catalytic oxidation reaction or the like of propane or the like, the process comprising the steps of: (I) obtaining a preparation containing compounds of Mo, V, Nb, and Sb or Te at the predetermined atomic ratios; (II) drying the preparation to obtain a dry powder; and (III) calcining the dry powder, wherein the step (III) comprises the step of calcining the dry powder in the presence of a compound containing W in the form of a solid to obtain a pre-stage calcined powder or a mainly calcined powder, or the step of calcining the dry powder and calcining the obtained pre-stage calcined powder in the presence of the solid to obtain a mainly calcined powder, the solid satisfies the predetermined conditions, and the oxide catalyst comprises a catalytic component having the predetermined composition.Type: ApplicationFiled: October 3, 2011Publication date: August 29, 2013Applicant: ASAHI KASEI CHEMICALS CORPORATIONInventors: Eri Tateno, Takeo Ichihara, Takaaki Kato
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Patent number: 8507403Abstract: A process is described for producing a powder batch comprises a plurality of particles, wherein the particles include (a) a first catalytically active component comprising at least one transition metal or a compound thereof; (b) a second component different from said first component and capable of removing oxygen from, or releasing oxygen to, an exhaust gas stream; and (c) a third component different from said first and second components and comprising a refractory support. The process comprises providing a precursor medium comprising a liquid vehicle and a precursor to al least one of said components (a) to (c) and heating droplets of said precursor medium carried in a gas stream to remove at least part of the liquid vehicle and chemically convert said precursor to said at least one component.Type: GrantFiled: June 27, 2008Date of Patent: August 13, 2013Assignee: Cabot CorporationInventors: Miodrag Oljaca, Toivo T. Kodas, Ranko P. Bontchev, Klaus Kunze, Kenneth C. Koehlert
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Patent number: 8507626Abstract: The invention provides a catalyst for producing acrylic acid at high yield for a long time, in a method for producing acrylic acid by catalytic gas phase oxidation of propane and/or acrolein in the presence of molecular oxygen or a molecular oxygen-containing gas. This catalyst comprises a complex oxide containing molybdenum, vanadium and X component (here the X component is at least one element selected from antimony, niobium and tin) as the essential components, and is characterized in that its main peak as measured by X-ray diffractiometry using K? ray of Cu, d=4.00±0.1 angstrom, and in that the particle size of the X component in the catalyst does not exceed 20 ?m.Type: GrantFiled: May 28, 2008Date of Patent: August 13, 2013Assignee: Nippon Shokubai Co., Ltd.Inventors: Naohiro Fukumoto, Toshiya Nishiguchi
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Patent number: 8492305Abstract: The present invention relates to a catalyst for hydrocarbon steam cracking for the production of light olefin, a preparation method of the catalyst and a preparation method of olefin by using the same. More precisely, the present invention relates to a composite catalyst prepared by mixing the oxide catalyst powder represented by CrZrjAkOx (0.5?j?120, 0?k?50, A is a transition metal, x is the number satisfying the condition according to valences of Cr, Zr and A, and values of j and k) and carrier powder and sintering thereof, a composite catalyst wherein the oxide catalyst is impregnated on a carrier, and a method of preparing light olefin such as ethylene and propylene by hydrocarbon steam cracking in the presence of the composite catalyst. The composite catalyst of the present invention has excellent thermal/mechanical stability in the cracking process, and has less inactivation rate by coke and significantly increases light olefin yield.Type: GrantFiled: December 1, 2011Date of Patent: July 23, 2013Assignee: LG Chem, Ltd.Inventors: Jun-han Kang, Jong-hun Song, Jun-seon Choi, Byoung-gi Park, Chang-hoon Kang, Si-hyun Noh
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Publication number: 20130178670Abstract: The present invention relates to catalysts, to processes for making catalysts and to chemical processes employing such catalysts. The catalysts are preferably used for converting acetic acid and ethyl acetate to ethanol. The catalyst comprises an extruded modified support, and a precious metal. The processes for making the catalysts comprises modifying the catalyst, extruding the catalyst, and impregnating the precious metal onto the catalyst.Type: ApplicationFiled: January 4, 2013Publication date: July 11, 2013Applicant: Celanese International CorporationInventor: Celanese International Corporation
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Patent number: 8481451Abstract: The present invention relates to a catalyst for hydrocarbon steam cracking, a method of preparing the same, and a method of preparing olefin by the hydrocarbon steam cracking by using the catalyst, and more specifically, to a catalyst for hydrocarbon steam cracking for preparing light olefin including an oxide catalyst (0.5?j?120, 1?k?50, A is transition metal, and x is a number corresponding to the atomic values of Cr, Zr, and A and values of j and k) represented by CrZrjAkOx, wherein the composite catalyst is a type that has an outer radius r2 of 0.5R to 0.96R (where R is a radius of a cracking reaction tube), a thickness (t; r2?r1) of 2 to 6 mm, and a length h of 0.5r2 to 10r2, a method of preparing the same, and a method of preparing light olefins by using the same.Type: GrantFiled: June 4, 2010Date of Patent: July 9, 2013Assignee: LG Chem, Ltd.Inventors: Jun-Han Kang, Jonghun Song, Junseon Choi
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Patent number: 8481448Abstract: The invention is a heteropoly acid compound catalyst composition, a method of making the catalyst composition and a process for the oxidation of saturated and/or unsaturated aldehydes to unsaturated carboxylic acids using the catalyst composition. The catalyst composition is a heteropoly acid compound containing molybdenum, vanadium, phosphorus, cesium, bismuth, copper and antimony. Thermal stability is achieved with higher cesium content (up to less than 3.0) but antimony, copper and bismuth must be present to maintain good activity. The catalyst is made by dissolving compounds of the components of each of the heteropoly acid compounds in a solution, precipitating the heteropoly acid compounds, obtaining a catalyst precursor and calcining the catalyst precursor to form a heteropoly acid compound catalyst. Unsaturated aldehydes, such as methacrolein, may be oxidized in the presence of the heteropoly acid compound catalyst to produce an unsaturated carboxylic acid, such as methacrylic acid.Type: GrantFiled: July 19, 2010Date of Patent: July 9, 2013Assignee: Saudi Basic Industries CorporationInventors: Wugeng Liang, David Sullivan, James W. Kauffman, Clark Rea, Joe Linzer, Shahid Shaikh
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Patent number: 8475921Abstract: A composite material includes an aggregate which contains a first metal particle constituting a core and second metal oxide particulates surrounding the first metal particle and having an average primary particle diameter ranging from 1 to 100 nm.Type: GrantFiled: July 20, 2006Date of Patent: July 2, 2013Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Tomoyuki Kayama, Kouzi Banno, Kiyoshi Yamazaki, Koji Yokota
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Patent number: 8465713Abstract: A catalyst composition represented by the general formula XVO4/S wherein XVO4 stands for TransitionMetal-Vanadate, or a mixed TransitionMetal-/RareEarth-Vanadate, and S is a support comprising TiO2.Type: GrantFiled: April 16, 2010Date of Patent: June 18, 2013Assignee: Treibacher Industrie AGInventors: Karl Schermanz, Amod Sagar, Alessandro Trovarelli, Marzia Casanova
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Publication number: 20130144085Abstract: Catalyst compositions including a compound of the following general formula (I): MoVaNbbPtcMdZeOx??(I) a is a number having a value between about 0.15 and about 0.50, b is a number having a value between about 0.05 and about 0.30, c is a number having a value between about 0.0001 and about 0.10, d is a number having a value between about 0.0 and about 0.35, e is a number having a value between about 0 and about 0.10, x is a number depending on the relative amount and valence of the elements different from oxygen in formula (I), M is one or more elements selected from the group consisting of Ag, Te, and Sb, and Z is one or more element selected from Ru, Mn, Sc, Ti, Cr, Fe, Co, Ni, Cu, Zn, Ga, Y, Zr, Rh, Pd, In, Ce, Pr, Nd, Sm, Tb, Ta, W, Re, Ir, Au, Pb, B, and mixtures thereof, where the compositions are capable of simultaneously oxidizing an alkane to a desired product and by-product carbon monoxide to carbon dioxide, with only a minor change in catalyst activity and selectivity.Type: ApplicationFiled: December 2, 2011Publication date: June 6, 2013Inventors: Paulette Hazin, Reginald L. Tennyson, Michael E. Huckman
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Patent number: 8449762Abstract: A sulfur reduction catalyst useful to reduce the levels of sulfur in a cracked gasoline product comprises a metal vanadate compound. The metal vanadate compound can be supported on a molecular sieve such as a zeolite in which the metal vanadate compound is primarily located on the exterior surface of the pore structure of the zeolite and on the surface of any matrix material used to bind or support the zeolite.Type: GrantFiled: February 23, 2011Date of Patent: May 28, 2013Assignee: BASF CorporationInventors: Xingtao Gao, James Fu
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Patent number: 8426335Abstract: An object of the present invention is to provide: a catalyst for production of acrylic acid which is a catalyst usable for production of acrylic acid and is excellent in the catalytic performances such as catalytic activity and in the physical properties such as physical strength of the catalyst itself; and a process for production of acrylic acid using this catalyst. As a means of achieving this object, a catalyst for production of acrylic acid according to the present invention is a catalyst obtained by drying a mixed liquid of starting materials including molybdenum and vanadium as essential components to give a dried material, molding the dried material with a liquid binder, and calcining the resultant molding, with the catalyst being characterized in that an ignition loss ratio of the dried material is from 5 to 40% by mass.Type: GrantFiled: October 6, 2008Date of Patent: April 23, 2013Assignee: Nippon Shokubai Co., Ltd.Inventors: Hiromi Yunoki, Michio Tanimoto, Daisuke Nakamura
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Patent number: 8415268Abstract: A process for producing a ringlike oxidic shaped body by mechanically compacting a pulverulent aggregate introduced into the fill chamber of a die, wherein the outer face of the resulting compact corresponds to that of a frustocone.Type: GrantFiled: June 30, 2009Date of Patent: April 9, 2013Assignee: BASF SEInventors: Knut Eger, Jens Uwe Faust, Holger Borchert, Ralf Streibert, Klaus Joachim Mueller-Engel, Andreas Raichle
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Publication number: 20130053596Abstract: It is an object of the present invention to provide a mixed catalyst for a vapor-phase catalytic oxidation or a vapor-phase catalytic ammoxidation reaction of propane or isobutane, capable of providing a corresponding unsaturated acid or unsaturated nitrile at high yield from propane or isobutane. A mixed catalyst for a vapor-phase catalytic oxidation reaction or a vapor-phase catalytic ammoxidation reaction of propane or isobutane comprises: (a) a composite oxide represented by the following composition formula (1): Mo1VaNbbSbcWdZeOn??(1) wherein Z represents at least one element selected from the group consisting of La, Ce, Pr, Yb, Y, Sc, Sr, and Ba; each of a, b, c, d, e, and n represents an atomic ratio of each element based on Mo atom; a is in a range of 0.01?a?1; b is in a range of 0.01?b?1; c is in a range of 0.01?c?1; d is in a range of 0.Type: ApplicationFiled: March 23, 2011Publication date: February 28, 2013Applicant: ASAHI KASEI CHEMICALS CORPORATIONInventors: Takaaki Kato, Minoru Kadowaki
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Publication number: 20130029841Abstract: Catalyst compositions for producing mixed alcohols from a synthesis gas feed. The catalyst composition comprises a catalytic metal combination on a catalyst support, a first optional promoter and a second optional promoter, where the catalytic metal combination consists essentially of iridium, vanadium, and molybdenum.Type: ApplicationFiled: March 30, 2011Publication date: January 31, 2013Applicant: DOW GLOBAL TECHNOLOGIES LLCInventors: Daniela Ferrari, Neelesh J. Rane, Adam Chojecki, Gerolamo Budroni, David G. Barton, Mark H. McAdon, Robert J. Gulotty, JR., Dean M. Millar, Palanichamy Manikandan
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Patent number: 8361923Abstract: A process is provided for producing a complex oxide catalyst which exhibits superior catalytic activity in a vapor phase catalytic oxidation reaction, particularly in production of unsaturated aldehyde and unsaturated carboxylic acid. The process is characterized by the steps of preparing an aqueous slurry by mixing a complex oxide containing molybdenum and cobalt with an acid and water; drying the aqueous slurry; and calcining the resulting dried solid. Preferably, the complex oxide is obtained as follows: a molybdenum- and cobalt-containing complex oxide catalyst which has been used in a vapor phase catalytic oxidation reaction is mixed with an aqueous extracting solution obtained by dissolving at least one of ammonia and an organic base in water, to thereby extract molybdenum and cobalt into the aqueous phase; and the aqueous phase is dried and is then calcined under an atmosphere of an oxidizing gas.Type: GrantFiled: September 29, 2010Date of Patent: January 29, 2013Assignee: Sumitomo Chemical Company, LimitedInventors: Hirotsugu Kano, Eiichi Shiraishi
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Patent number: 8357625Abstract: An object of the present invention is to provide a catalyst exhibiting excellent performance particularly in partial oxidation reaction. Another object is to provide a method for efficiently producing carboxylic acid or carboxylic anhydride through vapor-phase partial oxidation of an organic compound by use of an oxygen-containing gas in the presence of the catalyst. The catalyst contains (1) diamond; (2) at least one species selected from among Group 5 transition element oxides, collectively called oxide A; and (3) at least one species selected from among Group 4 transition element oxides, collectively called oxide B. The method for producing a carboxylic acid or a carboxylic anhydride includes subjecting an organic compound to vapor phase partial oxidation by use of an oxygen-containing gas in the presence of the catalyst, wherein the organic compound is an aromatic compound having one or more substituents in a molecule thereof, the substituents each including a carbon atom bonded to an aromatic ring.Type: GrantFiled: June 18, 2009Date of Patent: January 22, 2013Assignee: Mitsubishi Gas Chemical Company, Inc.Inventor: Atsushi Okamoto
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Publication number: 20130006030Abstract: The oxidative dehydrogenation of propane provides a highly selective catalyst for the oxidative dehydrogenation of propane to propylene, and a process for preparing the catalyst. The catalyst is a mixed metal oxides catalyst of the general formula MoaVbOx, where the molar ratio of molybdenum to vanadium is between 1:1 and 9:1 (a:b is between 0.5:0.5 and 0.9:0.1) and x is determined according to the oxidation state of the cations present. The catalyst is prepared by mixing the metals by sol-gel technique, heating the gel to dry the mixed oxides, further heating the dried product to induce auto-combustion, washing the product with isopropyl alcohol, and drying with a supercritical CO2 dryer. Oxidative dehydrogenation is carried out by contacting a stream of propane gas with the bulk mixed metal oxides catalyst at a temperature between 350° C. and 550° C. Propylene selectivity of 100% is reached at conversion rates between 1.9% and 4.8%.Type: ApplicationFiled: June 28, 2011Publication date: January 3, 2013Applicant: KING FAHD UNIVERSITY OF PETROLEUM AND MINERALSInventors: SHAKEEL AHMED, HASSAN S. ALASIRI, FAIZUR RAHMAN, ADNAN M.J. AL-AMER
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Publication number: 20130006019Abstract: The present invention refers to a catalyst for aldehyde production, in particular formaldehyde or acetaldehyde production, through selective oxidation of alkanol, especially methanol or ethanol, with oxygen, said catalyst having a spinel structure. The catalyst typically comprises a Feaq+Vb+Moc+y+?zO4 spinel structure wherein ? is an optional cation vacancy and wherein wherein z=3?q?x?y and q×a+x×b+y×c=8 in concentrations corresponding to 0.6<q<3, 0<x<1.5, 0<y<1 and 0<z<1.3 and 2<a<3, 3<b<5 and 3<c<6. The present invention further refers to a process for producing said catalyst and to the use of said catalyst for selective oxidation of alkanol, preferably methanol or ethanol, with oxygen to aldehyde, preferably formaldehyde or acetaldehyde.Type: ApplicationFiled: January 19, 2011Publication date: January 3, 2013Inventors: Arne Andersson, Robert Haggblad
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Patent number: 8318631Abstract: A process for preparing a coated catalyst in which a finely divided mixture of a multielement oxide comprising the elements Mo and V and a molybdenum oxide or a molybdenum oxide former is applied to the surface of a support body as an active composition.Type: GrantFiled: February 28, 2008Date of Patent: November 27, 2012Assignee: BASF SEInventors: Ulrich Cremer, Andreas Raichle, Frank Rosowski, Ulrich Hammon, Klaus Joachim Mueller-Engel
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Patent number: 8318384Abstract: The present disclosure relates to an ion conductive material useful as an anode catalyst comprising LaCrO3, a vanadium oxide (VOx) and a solid electrolyte, and methods of making the same. The catalysts are useful in solid oxide fuels cells and, in particular, using impure hydrogen.Type: GrantFiled: April 30, 2008Date of Patent: November 27, 2012Assignee: The Governors of the University of AlbertaInventors: Jing-Li Luo, Karl Tze-tang Chuang, Zhengrong Xu, Alan Sanger
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Patent number: 8299203Abstract: A melt phase process for making a polyester polymer melt phase product by adding an antimony containing catalyst to the melt phase, polycondensing the melt containing said catalyst in the melt phase until the It.V. of the melt reaches at least 0.75 dL/g. Polyester polymer melt phase pellets containing antimony residues and having an It.V. of at least 0.75 dL/g are obtained without solid state polymerization. The polyester polymer pellets containing antimony residues and having an It.V. of at least 0.70 dL/g obtained without increasing the molecular weight of the melt phase product by solid state polymerization are fed to an extruder, melted to produce a molten polyester polymer, and extruded through a die to form shaped articles. The melt phase products and articles made thereby have low b* color and/or high L* brightness, and the reaction time to make the melt phase products is short.Type: GrantFiled: December 22, 2011Date of Patent: October 30, 2012Assignee: Grupo Petrotemex, S.A. DE C.V.Inventors: Mary Therese Jernigan, Michael Paul Ekart, Richard Gill Bonner
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Patent number: 8288306Abstract: The present invention provides a preparation process of complex oxides catalyst containing Mo, Bi, Fe and Co, which comprising steps as following: dissolving precursor compounds of the components for catalyst and complexing agent in water to obtain a solution, and then drying, molding and calcining the solution to obtain catalyst. The catalyst is used for gas phase oxidation of light alkenes to unsaturated aldehydes. The catalyst has high activity, selectivity and stability. The reaction condition is mild. The preparation process of the catalyst is easy to operate and can be used for mass production.Type: GrantFiled: January 20, 2010Date of Patent: October 16, 2012Assignee: Shanghai Huayi Acrylic Acid Co., Ltd.Inventors: Ge Luo, Xin Wen, Xiaoqi Zhao, Xuemei Li, Yan Zhuang, Jianxue Ma, Jingming Shao
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Patent number: 8288309Abstract: A highly durable mercury oxidation catalyst contains V2O5 and MoO3 as active components, and is capable of preventing volatilization of MoO3 in the mercury oxidation catalyst. A method of producing the mercury oxidation catalyst is provided. A mercury oxidation catalyst oxidizing mercury in an exhaust gas into mercury oxide includes: TiO2 as a carrier, V2O5 and MoO3 supported on the carrier as active components, and at least one kind of element or compound selected from the group consisting of W, Cu, Co, Ni, and Zn or the compounds thereof supported on the carrier as a MoO3 volatilization preventing component.Type: GrantFiled: September 30, 2010Date of Patent: October 16, 2012Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Katsumi Nochi, Masanao Yonemura, Masashi Kiyosawa
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Publication number: 20120252659Abstract: Structural catalyst bodies are described herein which, in some embodiments, can be used in the treatment of nitrogen oxides present in exhaust or flue gases from stationary or mobile combustion sources. In some embodiments, a structural catalyst body described herein comprises an outer peripheral wall and a plurality of inner partition walls having an average thickness less than about 0.5 mm, the outer peripheral wall and the inner partition walls having dispersed throughout a chemical composition comprising 50-99.9% by weight an inorganic oxide composition, less than 3% by weight an inorganic extrusion aid and at least 0.1% by weight a catalytically active metal functional group comprising vanadium, the structural catalyst body having a crystalline vanadium pentoxide content less than 0.1 weight percent.Type: ApplicationFiled: March 28, 2012Publication date: October 4, 2012Applicant: Cormetech, Inc.Inventor: Chris E. DiFrancesco
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Patent number: 8247344Abstract: The present invention provides a Mo—Bi—Nb based composite metal oxide (with the proviso that Te is not included); a method for producing (meth)acrylic acid from at least one reactant selected from the group consisting of propylene, propane, isobutylene, t-butyl alcohol and methyl-t-butyl ether, in which a Mo—Bi—Nb based composite metal oxide (with the proviso that Te is not included) is used as a catalyst; and a reactor used for producing (meth)acrylic acid from at least one reactant selected from the group consisting of propylene, propane, isobutylene, t-butyl alcohol and methyl-t-butyl ether, in which a Mo—Bi—Nb based composite metal oxide (with the proviso that Te is not included) is used as a catalyst. Further, the present invention provides a method for producing the (meth)acrylic acid without any additional process of converting (meth)acrolein into (meth)acrylic acid.Type: GrantFiled: April 7, 2011Date of Patent: August 21, 2012Assignee: LG Chem, Ltd.Inventors: Hyun-Jong Shin, Byung-Yul Choi, Yeon-Shick Yoo, Young-Jin Cho
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Publication number: 20120208695Abstract: A supported catalyst composition suitable for use in converting synthesis gas to alcohols comprises a catalytic metal, a catalyst promoter and a catalyst support.Type: ApplicationFiled: November 2, 2010Publication date: August 16, 2012Applicant: Dow Global Technologies LLCInventors: Billy B. Bardin, David G. Barton, Adam Chojecki, Howard W. Clark, Daniela Ferrari, Robert J. Gulotty, JR., Yu Liu, Mark H. McAdon, Dean M. Millar, Neelesh Rane, Hendrik E. Tuinstra
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Patent number: 8242048Abstract: Process for the selective oxidation of ethane to ethylene and/or acetic acid, and/or the selective oxidation of ethylene to acetic acid, by contacting ethane and/or ethylene with a molecular oxygen-containing gas at elevated temperature in the presence of a spray-dried supported catalyst composition. The supported catalyst composition includes molybdenum, vanadium and niobium metal components, supported on a support comprising alpha-alumina. The supported catalyst is prepared by forming a slurry of the metal components and alpha-alumina support particles or an alpha-alumina support precursor, and spray-drying the slurry.Type: GrantFiled: September 30, 2009Date of Patent: August 14, 2012Assignee: BP Chemicals LimitedInventor: Bruce I. Rosen
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Patent number: 8202818Abstract: The present invention relates to a catalyst composition for preparing carbon nanotube and a process for preparing carbon nanotube using the same. More particularly, this invention relates to a process for preparing carbon nanotube by the chemical vapor deposition method through the decomposition of lower saturated or unsaturated hydrocarbons using a multi-component metal catalyst composition containing active metal catalyst from Co, V, Al and inactive porous support. Further, the present invention affords the carbon nanotube having 5˜30 nm of diameter and 100˜10,000 of aspect ratio in a high catalytic yield.Type: GrantFiled: May 26, 2009Date of Patent: June 19, 2012Assignee: Korea Kumho Petrochemical Co., Ltd.Inventors: Hyun-Kyung Sung, Wan Sung Lee, Namsun Choi, Dong Hwan Kim, Youngchan Jang
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Patent number: 8178718Abstract: The invention is a supported or bound heteropoly acid catalyst composition, a method of making the catalyst composition and a process for the oxidation of saturated and/or unsaturated aldehydes to unsaturated carboxylic acids using the catalyst composition. The catalyst composition has a heteropoly acid component containing molybdenum, vanadium, phosphorus and cesium and support/binder having a surface area of about 0.1 m2/g to about 1.0 m2/g. The catalyst is made by dissolving compounds of the components of each of the heteropoly acid compounds in a solution, precipitating the heteropoly acid compounds, contacting the heteropoly acid compounds to form a catalyst precursor and calcining the catalyst precursor to form a heteropoly acid compound catalyst. Unsaturated aldehydes, such as methacrolein, may be oxidized in the presence of the heteropoly acid compound catalyst to produce an unsaturated carboxylic acid, such as methacrylic acid.Type: GrantFiled: February 5, 2007Date of Patent: May 15, 2012Assignee: Saudi Basic Industries CorporationInventors: Wugeng Liang, Paul E. Ellis, Joseph R. Linzer
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Publication number: 20120115713Abstract: Exemplary embodiments of the present invention relate to the processing of hydrocarbon-containing feedstreams in the presence of an active catalyst component comprising a surface, and a metal oxide film coated on the surface of the active catalyst component. The catalysts and processes of the present invention can improve overall hydrogenation, product conversion, as well as improved resistance to catalytic deactivation due to sulfur and nitrogen compounds present in the hydrocarbon feedstreams.Type: ApplicationFiled: November 9, 2010Publication date: May 10, 2012Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Chuansheng Bai, Adrienne J. Thornburg, Heather A. Elsen, William G. Borghard, Cody R. Cole
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Patent number: 8173306Abstract: A catalyst is provided and includes fine catalyst particles of a composition represented by formula (1): PtuRuxTayTz, in which T is at least one element selected from the group consisting of Hf, W, Ni, and V; u, x, y, and z are 10 to 98.9 atm %, 0.1 to 50 atm %, 0.5 to 35 atm %, and 0.5 to 35 atm %, respectively, or formula (2): PtuRuxTayTz, in which T is at least one element selected from the group consisting of Ct, Mo, Nb, Zr, and T; u, x, y, and z are 40 to 70 atm %, 0.1 to 50 atm %, 0.5 to 15 atm %, and 0.5 to 15 atm %, respectively.Type: GrantFiled: March 18, 2008Date of Patent: May 8, 2012Assignee: Kabushiki Kaisha ToshibaInventors: Itsuko Mizutani, Wu Mei, Taishi Fukazawa, Takahiro Sato, Yoshihiko Nakano
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Publication number: 20120071671Abstract: The invention relates to a catalyst for partially oxidizing hydrocarbons in the gas phase, containing a multi-metal oxide of the general formula (I), AgaMObVcMdOe.f H2O (I), wherein M stands for at least one element selected from among Li, Na, K, Rb, Cs, Be, Mg, Ca, Sr, Ba, B, Al, Ga, In, Si, Sn, Pb, P, Sb, Bi, Y, Ti, Zr, Hf, V, Nb, Ta, Cr, W, Mn, Re, Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt, Cu, Au, Zn, Cd, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and U, a has a value of 0.5 to 1.5, b has a value of 0.5 to 1.5, c has a value of 0.5 to 1.5, a+b+c has the value 3, d has a value of less than 1, e means a number that is determined by the valence and frequency of the elements other than oxygen in the formula (I), f has a value of 0 to 20, which multi-metal oxide exists in a crystal structure, the X-ray powder diffractogram of which is characterized by diffraction reflections at a minimum of 5 lattice distances selected from among d=4.53, 3.38, 3.32, 3.23, 2.88, 2.57, 2.39, 2.26, 1.83, 1.77 AA (+?0.Type: ApplicationFiled: May 28, 2010Publication date: March 22, 2012Applicant: BASF SEInventors: Andrey Karpov, Hartmut Hibst, Christine Deißler, Cornelia Katharina Dobner, Frank Rosowski, Nadine Brem, Stephan Schunk
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Patent number: 8105972Abstract: A catalyst for the oxidative dehydrogenation of a paraffin to form an olefin, the catalyst having a general formula MoaVbXcYdOn wherein: X=at least one of Nb and Ta; Y=at least one of Te, Sb, Ga, Pd, W, Bi and Al; a=1.0; b=0.05 to 1.0; c=0.001 to 1.0; d=0.001 to 1.0; and n is determined by the oxidation states of the other elements. The catalyst may have a selectivity to the olefin of at least 90 mole % at a paraffin conversion of at least 65%.Type: GrantFiled: April 2, 2009Date of Patent: January 31, 2012Assignee: Lummus Technology Inc.Inventors: Anne Mae Gaffney, Ruma Ghosh, Ruozhi Song, Chuen Yuan Yeh, Tadeusz Langner
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Patent number: 8105971Abstract: A process for forming a catalyst useful for the production of an olefin from a hydrocarbon is disclosed. The process may include: admixing at least one of elemental metals and compounds to form a multi-metal composition comprising Mo, V, Nb, Te and at least one of Ni and Sb; adjusting the pH of the multi-metal composition by adding nitric acid; drying the acidified multi-metal composition; calcining the dried multi-metal composition; and grinding the calcined multi-metal composition. The ground multi-metal composition may then be sized or shaped to form a mixed metal oxide catalyst. Alternatively, the ground multi-metal composition may be treated with an acid, optionally annealed, and sized or shaped to form a mixed metal oxide catalyst.Type: GrantFiled: April 2, 2009Date of Patent: January 31, 2012Assignee: Lummus Technology Inc.Inventors: Anne Mae Gaffney, Ruma Ghosh, Ruozhi Song, Chuen Yuan Yeh, Tadeusz Langner
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Patent number: 8088707Abstract: A supported catalyst with a solid sphere structure of the present invention includes an oxide supporting body and a metal such as Ni, Co, Fe, or a combination thereof distributed on the surface and inside of the supporting body. The supported catalyst with a solid sphere structure can maintain a spherical shape during heat treatment and can be used with a floating bed reactor due to the solid sphere structure thereof.Type: GrantFiled: December 17, 2009Date of Patent: January 3, 2012Assignee: Cheil Industries Inc.Inventors: Byeong Yeol Kim, Yun Tack Lee, Seung Yong Bae, Young Sil Lee
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Patent number: 8057763Abstract: The invention relates to a process for recovering Group VIB metals from a catalyst, in particular a spent bulk catalyst, comprising one or more Group VIB metals and one or more Group VIII metals. Further, the invention relates to a solid Group VIB metal compound obtainable by the process according to the invention having the general formula H2XO4, wherein X=W1-yMoy, wherein y is between 0 and 1 and to its use in a process for the manufacture of a fresh catalyst.Type: GrantFiled: September 14, 2007Date of Patent: November 15, 2011Assignee: Albemarle Netherlands B.V.Inventors: Bob Gerardus Oogjen, Harmannus Willem Homan Free, Johannes Cornelis Sitters
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Publication number: 20110275856Abstract: An eggshell catalyst consisting of a hollow cylindrical support body of length 2 to 10 mm, external diameter 4 to 10 mm and wall thickness 1 to 4 mm, and an eggshell, applied to the outer surface of the support body, of catalytically active oxide material of the general formula I, Mo12V2 to 4W0 to 3Cu0.8 to 1.5X10 to 4X20 to 40On??(I) in which the variables are each defined as follows: X1=one or more elements of the alkali metals and alkaline earth metals; X2=one or more elements from the group of Si, Al, Ti and Zr; and n=the stoichiometric coefficient of the element oxygen, which is determined by the stoichiometric coefficients of the elements other than oxygen and the charges thereof in I.Type: ApplicationFiled: April 25, 2011Publication date: November 10, 2011Applicant: BASF SEInventors: Andrey KARPOV, Catharina Horstmann, Cornelia Katharina Dobner, Josef Macht, Frank Rosowski, Klaus Joachim Müller-Engel
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Patent number: 8053386Abstract: The present invention relates to a heteropoly acid catalyst which is used for the production of methacrylic acid by gas phase oxidation of methacrolein and a preparing method thereof. The present invention, thereby, provides a novel heteropoly acid catalyst having excellent methacrolein conversion rate, methacrylic acid selectivity and yield.Type: GrantFiled: November 29, 2007Date of Patent: November 8, 2011Assignee: LG Chem, Ltd.Inventors: Gyo-hyun Hwang, Min-ho Kil, Hyun-kuk Noh, Won-ho Lee, Min-suk Kim
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Patent number: 7985830Abstract: Methods for synthesizing dimeric or polymeric reaction products of nitrogen aromatics comprise contacting a composition comprising the nitrogen aromatic with a catalyst composition. The catalyst comprises a first metal substrate having a second reduced metal coated on the substrate.Type: GrantFiled: December 30, 2009Date of Patent: July 26, 2011Assignee: GM Global Technology Operations LLCInventors: Andrew M. Mance, Tao Xie, Belabbes Merzougui, Charlene A. Hayden
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Publication number: 20110166384Abstract: A catalyst for producing acrylic acid from propane and/or acrolein by gas-phase catalytic oxidation with molecular oxygen-containing gas, comprising a catalytic active component containing molybdenum and vanadium as essential elements, and having a crystallinity T of 5% or more and 20% or less in the 20 range of 5° to 90°, measured by an X-ray diffraction analysis with Cu-K? radiation; and a process for producing acrylic acid by gas-phase catalytic oxidation of propane and/or acrolein with molecular oxygen, comprising the step of conducting the gas-phase catalytic oxidation in the presence of the catalyst. According to the catalyst and the process for producing acrylic acid of the present invention, it is possible to stably produce acrylic acid at a high yield for a long period.Type: ApplicationFiled: September 25, 2009Publication date: July 7, 2011Inventors: Michio Tanimoto, Nobuyuki Hakozaki
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Patent number: 7972569Abstract: A catalyst includes a carrier body and a catalytic portion carried by the carrier body. The catalytic portion includes a plurality of distinct layers of catalytic material, which layers may be deposited through atomic layer deposition techniques. The catalyst may have a selectivity for the conversion of alkanes to alkenes of over 50%. The catalyst may be incorporated in a reactor such as a fluidized bed reactor or a single pass reactor.Type: GrantFiled: January 28, 2009Date of Patent: July 5, 2011Assignee: UChicago Argonne, LLCInventors: Jeffrey W. Elam, Michael J. Pellin, Joseph A. Libera, Peter C. Stair, Gerry Zajac, Steven A. Cohen
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Publication number: 20110105790Abstract: A method for the production of a nanocrystalline molybdenum mixed oxide, the use of the molybdenum mixed oxide as catalyst for chemical conversions, in particular for a conversion of acrolein to acrylic acid as well as a catalyst that contains the molybdenum mixed oxide.Type: ApplicationFiled: April 3, 2009Publication date: May 5, 2011Applicant: SUD-CHEMIE AGInventors: Alfred Hagemeyer, Gerhard Mestl, Silvia Neumann, Hans-Jörg Wölk
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Publication number: 20110101265Abstract: A catalyst for producing a carbon nanofiber is obtained by dissolving or dispersing [I] a compound containing Fe element; [II] a compound containing Co element; [III] a compound containing at least one element selected from the group consisting of Ti, V, Cr, and Mn; and [IV] a compound containing at least one element selected from the group consisting of W and Mo in a solvent to obtain a solution or the fluid dispersion, and then impregnating a particulate carrier with the solution or the fluid dispersion. A carbon nanofiber is obtained by bringing a carbon element-containing compound into contact with the catalyst in a vapor phase at a temperature of 300 degrees C. to 500 degrees C.Type: ApplicationFiled: June 16, 2009Publication date: May 5, 2011Applicant: SHOWA DENKO K.K.Inventors: Eiji Kambara, Akihiro Kitazaki
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Publication number: 20110104490Abstract: A catalyst for production of a carbon fiber is obtained by dissolving or dispersing [I] a compound containing Fe element; [II] a compound containing Co element; [III] a compound containing at least one element selected from the group consisting of Ti, V, Cr, and Mn; and [IV] a compound containing at least one element selected from the group consisting of W and Mo in a solvent to obtain a solution or a fluid dispersion, and then by impregnating a particulate carrier with the solution or the fluid dispersion. By means of a step of bringing a carbon source into contact with the catalyst in a vapor phase, the carbon fiber is obtained which is tubular and in which a graphite layer is approximately parallel with the carbon fiber axis, and a shell is in a multi-walled structure.Type: ApplicationFiled: June 16, 2009Publication date: May 5, 2011Inventors: Eiji Kambara, Akihiro Kitazaki
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Patent number: 7927551Abstract: There is disclosed a catalytic body with purifying efficiency and smaller pressure loss and its manufacturing method. Provided is a catalytic body wherein a porous honeycomb structure including partition walls defining a plurality of cells acting as fluid passages which extend through the honeycomb structure from one end surface to the other end surface thereof is formed of at least one type of (a) a catalytic substance and (b) a substance including an oxide and at least one type of noble metal carried on the oxide. The catalytic converter is characterized in that (c) 10% or more of a plurality of cells are plugged by plugging parts formed at one ends or in the middles of passages, that (d) the average pore diameter of the honeycomb structure is 10 ?m or more, or that (e) the porosity is 40% or more.Type: GrantFiled: March 27, 2007Date of Patent: April 19, 2011Assignee: NGK Insulators, Ltd.Inventors: Yukio Miyairi, Naomi Noda, Mikio Makino, Shinichi Miwa