Abstract: The invention relates to a filtration structure, for filtering a gas coming from a diesel engine, which is laden with gaseous pollutants of the nitrogen oxide NOx type and with solid particles, of the particulate filter type, said filtration structure being characterized in that it includes a catalytic system comprising at least one noble metal or transition metal suitable for reducing the NOx and a support material, in which said support material comprises or is made of a zirconium oxide partially substituted with a trivalent cation M3+ or with a divalent cation M?2+, said zirconium oxide being in a reduced, oxygen-sub-stoichiometric, state.

Abstract: An improved process to make a slurry catalyst for the upgrade of heavy oil feedstock is provided. The sulfiding of the metal precursor/catalyst precursor is carried out at least twice (“enhanced sulfiding”) in the improved process to form a slurry catalyst with improved surface area and porosity value. The slurry catalyst under an enhanced sulfiding scheme is characterized as having increased catalytic activities over a slurry catalyst without an enhanced sulfidation step.

Abstract: The present invention provides an electrocatalytic material and a method for making an electrocatalytic material. There is also provided an electrocatalytic material comprising amorphous metal or mixed metal oxides. There is also provided methods of forming an electrocatalyst, comprising an amorphous metal oxide film.

Abstract: The present invention provides a catalyst for generating hydrogen, containing a composite metal of iron and nickel, the catalyst used in a decomposition reaction of at least one compound selected from the group consisting of hydrazine and hydrates thereof; and a method for generating hydrogen, including contacting the catalyst for generating hydrogen with at least one compound selected from the group consisting of hydrazine and hydrates thereof. According to the invention, hydrogen can be efficiently generated with improved selectivity in the method for generating hydrogen that utilizes the decomposition reaction of hydrogen.

Abstract: Olefins are oligomerized by bringing at least one C2 to C8-olefin into contact with a nickel-containing heterogeneous catalyst. The catalyst is conditioned before contact with the olefin by passing an inert gas flow over the same, until the inert gas flow has a water content of less than 1000 ppm. Selectivity for the production of higher oligomers, in particular trimers relative to the formation of dimers is increased by the pretreatment.

Abstract: A process for preparing a slurry catalyst for the upgrade of heavy oil feedstock is provided. The process employs a pressure leach solution obtained from a metal recovery process as part of the metal precursor feed. In one embodiment, the process comprises: sulfiding a pressure leach solution having at least a Group VIB metal precursor compound in solution forming a catalyst precursor, and mixing the sulfided catalyst precursor with a hydrocarbon diluent to form the slurry catalyst. In another embodiment, the pressure leach solution is mixed with a hydrocarbon diluent under high shear mixing conditions to form an emulsion, which emulsion can be sulfided in-situ upon contact with a heavy oil feedstock in the heavy oil upgrade process.

Abstract: Electrooxidative materials and various method for preparing electrooxidative materials formed from an alloy of oxophilic and electrooxidative metals. The alloy may be formed using methods such as spray pyrolysis or mechanosynthesis and may or may not include a supporting material which may or may not be sacrificial as well as the materials.

Abstract: The performance of an ABx type metal hydride alloy is improved by adding an element to the alloy which element is operative to enhance the surface area morphology of the alloy. The alloy may include surface regions of differing morphologies.

Abstract: The performance of an ABx type metal hydride alloy is improved by adding an element to the alloy which element is operative to enhance the surface area morphology of the alloy. The alloy may include surface regions of differing morphologies.

Abstract: A method for the production of nanocrystalline nickel oxides as well as the nickel oxides produced by the method according to the invention and the use thereof as catalyst following reduction to nickel metal, in particular for hydrogenation reactions.

Abstract: The present invention is directed to catalyst particles comprising a layered core-shell-shell structure and to a method of their manufacture. The catalyst particles have the general formula BM/IL/PM in which BM is a base metal core (selected from Co, Ni or Cu), PM is a precious metal outer shell (selected from Pt, Ir or Pd) and IL is an intermediate layer comprising a base metal/precious metal alloy with a concentration gradient of base metal to the outside PM layer. The particles of the present invention comprise a core-shell-shell structure and a substantially continuous precious metal shell layer. They find use in various catalytic applications, for example in gas-phase catalysis, in electrocatalysts for fuel cells, in catalytic converters for automobiles and in electronic or medical applications.

Abstract: A hydroprocessing co-catalyst composition may comprise in an embodiment a first component comprising co-catalyst particles and a liquid carrier, and a second component comprising a dispersant and a dispersant diluent. The co-catalyst particles may be in the micron size range, and the dispersant may promote dispersion of the co-catalyst particles in materials such as the liquid carrier, the dispersant diluent, and combinations thereof. Methods of introducing a hydroprocessing co-catalyst composition into a hydroprocessing system are also disclosed.

Abstract: Core-shell nanoparticles and techniques for their synthesis are described herein. Generally, the nanoparticles comprise a core that includes iron and at least one shell disposed about the core that includes nickel. In certain versions, the nanoparticles are free of precious metals.

Abstract: Platinum (Pt)-based alloys are effective catalysts for oxygen reduction reaction (ORR) or fuel oxidation in proton exchange membrane fuel cells (PEMFCs). A wet-chemical approach for preparing monodisperse Pt3Ni, Pt3Co and Pt3Fe nanocubes and Pt3Ni nanoctahedra which are terminated with {100} and {111} facets, respectively, were developed. Such nanoscaled electrocatalysts supported on carbon black with controlled shape, e.g., octahedral configuration, is provided. ORR activity on the Pt3Ni nanoctahedra is ˜5.1 fold higher than that of nanocubes with a similar size, and their C-supported samples are highly active with respect to commercial Pt/C.

Abstract: Described is a nitrogen oxide storage catalyst comprising: a substrate; a first washcoat layer provided on the substrate, the first washcoat layer comprising a nitrogen oxide storage material, a second washcoat layer provided on the first washcoat layer, the second washcoat layer comprising a hydrocarbon trap material, wherein the hydrocarbon trap material comprises substantially no element or compound in a state in which it is capable of catalyzing selective catalytic reduction, preferably wherein the hydrocarbon trap material comprises substantially no element or compound in a state in which it is capable of catalyzing a reaction wherein nitrogen oxide is reduced to N2, said catalyst further comprising a nitrogen oxide conversion material which is either comprised in the second washcoat layer and/or in a washcoat layer provided between the first washcoat layer and the second washcoat layer.

Abstract: The present invention provides methods and designs of enclosed-channel reactor system for manufacturing catalysts or supports. Both of the configuration designs force the gaseous precursors and purge gas flow through the channel surface of reactor. The precursors will transform to thin film or particle catalysts or supports under adequate reaction temperature, working pressure and gas concentration. The reactor body is either sealed or enclosed for isolation from atmosphere. Another method using super ALD cycles is also proposed to grow alloy catalysts or supports with controllable concentration. The catalysts prepared by the method and system in the present invention are noble metals, such as platinum, palladium, rhodium, ruthenium, iridium and osmium, or transition metals such as iron, silver, cobalt, nickel and tin, while supports are silicon oxide, aluminum oxide, zirconium oxide, cerium oxide or magnesium oxide, or refractory metals, which can be chromium, molybdenum, tungsten or tantalum.

Abstract: A method of steam reforming where a reaction occurs in which an oxygenated feed contacts a catalyst to produce hydrogen. The catalyst of the reaction comprises a metal/metal promoter on a nickel/transition metal blend catalyst supported on a high-energy lattice metal oxide.

Abstract: The present invention a catalyst that includes a metallic or ceramic foam catalyst support having surfaces within the foam for the placement of a catalytic material, and an active catalyst material which is applied by washcoating or dipping.

Abstract: A method for providing a catalyst on a substrate is disclosed comprising providing a first washcoat comprising a soluble washcoat salt species, a polar organic solvent, and an insoluble particulate material, contacting the first washcoat with a substrate to form a coated substrate, and then contacting the coated substrate with a second washcoat comprising an oxide or an oxide-supported catalyst to physisorb, chemisorb, bond, or otherwise adhere the oxide or the oxide-supported catalyst to the coated substrate. Also disclosed is a catalyst on a substrate comprising: a substrate; an anchor layer comprising a soluble washcoat salt species, a polar organic solvent, and an insoluble particulate material; and a second layer comprises an oxide or an oxide-supported catalyst. The catalyst on a substrate can be in either green or fired form.

Abstract: A method for synthesizing carbon nanotubes having a narrow distribution of diameter and/or chirality is presented. The method comprises providing catalyst particles to a reactor for synthesizing the carbon nanotubes, wherein the catalyst particles are characterized by a narrow distribution of catalyst-particle diameters and a narrow distribution of catalyst-particle compositions. Preferably, the catalyst particles are characterized by a mean catalyst-particle diameter of 2.6 nm or less and a composition of NixFe1-x, wherein x is less than or equal to 0.5.

Abstract: A catalyst composition that is especially useful in the hydroconversion of pitch, micro carbon residue and sulfur contents of a heavy hydrocarbon feedstock without the excessive formation of sediment. The catalyst composition is a reasonably high surface area composition containing alumina and a low molybdenum content with a high ratio of nickel-to-molybdenum. The catalyst composition further has a unique pore distribution that in combination with the special metals loading provide for good conversion of pitch and micro carbon residue without an excessive yield of sediment.

Abstract: An improved process to make a slurry catalyst for the upgrade of heavy oil feedstock is provided. In the process, at least a metal precursor feedstock is portioned and fed in any of the stages: the promotion stage; the sulfidation stage; or the transformation stage of a water-based catalyst precursor to a slurry catalyst. In one embodiment, the promoter metal precursor feedstock is split into portions, the first portion is for the sulfiding step, the second portion is for the promotion step; and optionally the third portion is to be added to the transformation step in the mixing of the sulfided promoted catalyst precursor with a hydrocarbon diluent to form the slurry catalyst. In another embodiment, the Primary metal precursor feedstock is split into portions.

Abstract: A single metal slurry catalyst for the upgrade of heavy oil feedstock is provided. The slurry catalyst is prepared by sulfiding a Primary metal precursor, then mixing the sulfided metal precursor with a hydrocarbon diluent to form the slurry catalyst. The single-metal slurry catalyst has the formula (Mt)a(Sv)d(Cw)e(Hx)f(Oy)g(Nz)h, wherein M is at least one of a non-noble Group VIII metal, a Group VIB metal, a Group IVB metal, and a Group IIB metal; 0.5a<=d<=4a; 0<=e<=11a; 0<=f<=18a; 0<=g<=2a; 0<=h<=3a; t, v, w, x, y, z, each representing total charge for each of: M, S, C, H, O, and N; and ta+vd+we+xf+yg+zh=0. The slurry catalyst has a particle size ranging from 1 to 300 ?m.

Abstract: A method and system for the reduction of pollutant NOx gases from automobile exhaust, as well as a method of reforming hydrocarbons, using a self-sustaining catalyst comprising an ion conductive support, a dispersed cathodic phase, a dispersed anodic phase, and a dispersed sacrificial phase, and a method of forming the self-sustaining catalyst.

Abstract: An exhaust gas purifying catalyst (1) of the present invention includes anchor/promoter simultaneous enclosure particles (5) including catalyst units (13) which contain: noble metal particles (8); and anchor particles (9) as an anchor material of the noble metal particles (8) supporting the noble metal particles (8); promoter units (14) which are provided not in contact with the noble metal particles (8) and contain first promoter particles (11) having an oxygen storage and release capacity; and an enclosure material (12) which encloses both the catalyst units (13) and the promoter units (14), and separates the noble metal particles (8) and the anchor particles (9) in the catalyst units (13) from the first promoter particles (11) in the promoter units (14). The exhaust gas purifying catalyst (1) further includes second promoter particles (6) which have the oxygen storage and release capacity, and are not enclosed in the anchor/promoter simultaneous enclosure particles (5) by the enclosure material (12).

Abstract: A catalyst particle for use in growth of elongated nanostructures, such as e.g. nanowires, is provided. The catalyst particle comprises a catalyst compound for catalyzing growth of an elongated nanostructure comprising a nanostructure material without substantially dissolving in the nanostructure material and at least one dopant element for doping the elongated nanostructure during growth by substantially completely dissolving in the nanostructure material. A method for forming an elongated nanostructure, e.g. nanowire, on a substrate using the catalyst particle is also provided. The method allows controlling dopant concentration in the elongated nanostructures, e.g. nanowires, and allows elongated nanostructures with a low dopant concentration of lower than 1017 atoms/cm3 to be obtained.

Abstract: A catalytic article for decomposition of a volatile organic compound includes a porous support body, a plurality of active centers formed on the support body and adapted for catalytic decomposition of the volatile organic compound, and a plurality of capture centers bound to the support body. Each of the active centers is composed of one of a noble metal, a transition metal oxide, and the combination thereof. Each of the capture centers includes at least one functional group that is adapted for attracting or binding the volatile organic compound. A method for preparing the catalytic article is also disclosed.

Abstract: A metal oxide-supported nickel catalyst includes a matrix containing a metal oxide and catalytic sites distributed throughout the matrix and having an intricate interface with the matrix, in which the catalytic sites are selected from the group consisting of nano-nickel(0) domains and nano-nickel(0)-A(0) alloy domains. Also disclosed are a method for preparing this catalyst and a method for using it to produce carbon monoxide and hydrogen by partial oxidation of a C1-C5 hydrocarbon.

Abstract: A bulk metal oxide catalyst composition of the general formula (X)b(M)c(Z)d(O)e??(I) wherein X represents at least one non-noble Group VIII metal; M represents at least one non-noble Group VIb metal; Z represents one or more elements selected from aluminum, silicon, magnesium, titanium, zirconium, boron, and zinc; one of b and c is the integer 1; and d and e and the other of b and c each are a number greater than 0 such that the molar ratio of b:c is in the range of from 0.5:1 to 5:1, the molar ratio of d:c is in the range of from 0.2:1 to 50:1, and the molar ratio of e:c is in the range of from 3.7:1 to 108:1; is prepared by controlled (co)precipitation of component metal compounds, refractory oxide material, and alkali compound in protic liquid. Resulting compositions find use in hydrotreatment processes involving particularly hydrodesulphurization and hydrodenitrification.

Abstract: A metal oxide-supported nickel catalyst includes a matrix containing a metal oxide and catalytic sites distributed throughout the matrix and having an intricate interface with the matrix, in which the catalytic sites are selected from the group consisting of nano-nickel(0) domains and nano-nickel(0)-A(0) alloy domains. Also disclosed are a method for preparing this catalyst and a method for using it to produce carbon monoxide and hydrogen by partial oxidation of a C1-C5 hydrocarbon.

Abstract: Disclosed are methods for producing carbon, metal and/or metal oxide porous materials that have precisely controlled structures on the nanometer and micrometer scales. The methods involve the single or repeated infiltration of porous templates with metal salts at controlled temperatures, the controlled drying and decomposition of the metal salts under reducing conditions, and optionally the removal of the template. The carbon porous materials are involve the infiltration of a carbon precursor into a porous template, followed by polymerization and pyrolysis. These porous materials have utility in separations, catalysis, among others.

Abstract: The invention relates to a method for producing a N-substituted amine compound by catalyzed alkylation. The method uses amine and alcohol or two kinds of amines as the reaction materials, employs composite metal oxides catalyst at a reaction temperature of 80-180° C. to catalyze the reaction for 6-36 hours, so as to produce the N-substituted amine compound. The reaction condition of the method of the invention is relatively moderate, using a catalyst made of cheap non-noble metals, which is non-caustic and easy to be separated and reused. The reaction does not need any medium and has relatively high conversion rate and selectivity.

Abstract: The present invention relates to a method for forming a catalyst comprising catalytic nanoparticles and a catalyst support, wherein the catalytic nanoparticles are embedded in the catalyst support, comprising forming the catalytic nanoparticles on carbon particle, dispersing the carbon particle in a solution comprising precursors of the catalyst support to form a suspension, heating the suspension to form a gel, subjecting the gel to incineration to form a powder, and sintering the powder to form the catalyst.

Abstract: A CO2 reforming catalyst may include at least one catalyst metal supported in a porous carrier. The at least one catalyst metal may include a transition metal (e.g., Ni, Co, Cr, Mn, Mo, Ag, Cu, Zn, and/or Pd). Each particle of the at least one catalyst metal may be bound with the porous carrier in a form of an alloy. The porous carrier may form a rod-shaped protruding portion around the catalyst metal particle.

Abstract: A process is described for preparing a catalyst comprising at least one porous support and at least one metallic phase containing nickel and tin in a proportion such that the Sn/Ni molar ratio is in the range 0.01 to 0.2, said process comprising at least the following steps in succession: a) depositing nickel on at least said support in order to obtain a supported nickel-based monometallic catalyst; b) reducing said monometallic catalyst in the presence of at least one reducing gas; c) depositing, in the gas phase and in the presence of at least one reducing gas, at least one organometallic tin compound onto said reduced monometallic catalyst; and d) activating the solid derived from said step c) in the presence of at least one reducing gas.

Abstract: Ethylene is oligomerized with a catalyst in which nickel is supported on a support containing silica and alumina. The catalyst has little deterioration over long periods and affords oligomers with high productivity. The ethylene oligomerization catalyst includes a support and a nickel compound supported on the support, the support including silica and alumina, and the amount of nickel supported is in the range of 0.0001 to 1 wt % based on the weight of the support, and the molar ratio of silica to alumina in the support (SiO2/Al2O3) is in the range of 100 to 2000. In a process of the invention, ethylene is oligomerized with use of the catalyst.

Abstract: A mesoporous oxide-catalyst complex including: a mesoporous metal oxide; and a catalyst metal supported on the mesoporous metal oxide, wherein the catalyst on the mesoporous metal oxide has a degree of dispersion of about 30 to about 90 percent.

Abstract: A method is described for preparing a catalyst suitable for use in a steam reforming process, including the steps of: (i) spraying a slurry containing a particulate catalyst compound, including one or more catalytic metals selected from the group consisting of Ni, Cu, Pt, Pd, Rh, Ru and Au, on to the surface of a shaped support in a pan coater to form a coated shaped support material having the catalytic metal in a surface layer, (ii) drying and optionally calcining the coated shaped support material to form a catalyst precursor, and (iii) optionally reducing the metal or metals in the catalyst precursor to a lower oxidation state to form the catalyst. The egg-shell catalyst is useful for performing a steam reforming reaction.

Abstract: A Raney-type metal porous material of which at least the inner surface of the pores constituting the porous structure is an alloy of the skeletal metal constituting it and a metal differing from the skeletal metal. The invention has made it possible to alloy a Raney-type metal with a porous structure, to realize a novel method of enabling remarkable enhancement of the function and the activity of the alloy based on the porous structure thereof, and to use the alloy as catalysts, etc.

Abstract: A CO2 reforming catalyst composition includes a hydroxyl group-containing porous oxide, and a composite porous catalyst supported by a porous supporter. The composite porous catalyst includes a catalyst metal.

Abstract: An exhaust gas purifying catalyst is constituted by: noble metal particles (1); first compounds (2) which support the noble metal particles (1); second compounds (3) different in type from the first compounds (2); and oxides (4) which surround the noble metal particles (1), the first compounds (2) and the second compounds (3). A median diameter of the first compounds (2) and a median diameter of the second compounds (3) satisfy a relationship of a following inequality: median diameter of first compounds<median diameter of second compounds.

Abstract: A series of binary and ternary Pt-alloys, that promote the important reactions for catalysis at an alloy surface; oxygen reduction, hydrogen oxidation, and hydrogen and oxygen evolution. The first two of these reactions are essential when applying the alloy for use in a PEMFC.

Abstract: The present invention provides catalyst compositions useful for transamination reactions. The catalyst compositions have a catalyst support that includes transitional alumina, use a low metal loading (for example, less than 25 wt. %), and do not require the presence of rhenium. The catalyst compositions are able to advantageously promote transamination of a reactant product (such as the transamination of EDA to DETA) with excellent activity and selectivity, and similar to transaminations promoted using a precious metal-containing catalyst.

Abstract: Provided are a metal structure catalyst and a method of preparing the same. Particularly, the method includes forming a metal precipitate on a metal support by contact of a mixed solution including a precursor of a metal catalyst and a precipitating agent with the metal support, and forming metal particles by thermally treating and reducing the metal precipitate formed on the metal support. The metal structure catalyst includes a metal support, a metal oxide layer formed on the metal support, and metal nanoparticles formed on the metal oxide layer. In addition, the metal nanoparticles are uniform and have enhanced binding strength.

Abstract: According to various embodiments, a catalyst composition includes a catalytic metal secured to a porous substrate. The substrate has pores that are templated. The substrate is a product of adding a substrate precursor to a water-in-oil microemulsion including a catalytic metal salt, a solvent, a templating agent, and water.

Abstract: A support of metal oxyfluoride or metal halide for a metal-based hydrogenation catalyst useful in hydrogenating fluoroolefins is provided.

Abstract: A fuel reforming catalyst is fabricated. The catalyst is used in solid oxide fuel cell. By using the catalyst, the hydrogen generation is enhanced with a great reforming ratio. In addition, the catalyst is coking-resistant and will not be broken into powder after a long time of use.

Abstract: The present invention relates unique pore structures in nickel supported on alumina with the negligible formation of macropores. Incorporation of additional elements stabilizes the pore structure of the nickel supported on alumina. Additional element(s) were then further added into the nickel-supported materials. These additional element(s) further stabilize the pore structures under heating conditions. The improvements of pore structure stability under heating conditions and negligible presence of macropores limit the sintering of nickel metal to a mechanism of impeded diffusion. The negligible presence of macropores also limits the deposition of alkali metal hydroxide(s)/carbonate(s) on the outer shell of the catalyst pellet in the molten carbonate fuel cells. Both the negligible presence of macropores and improvement in pore structure stability allow for prolonging the catalyst life of these nickel supported on alumina catalysts of the present invention for reforming hydrocarbons.

Abstract: Catalyst comprising: a) a catalytic ceramic support comprising an arrangement of crystallites of the same size, same isodiametric morphology and same chemical composition or substantially of the same size, same isodiametric morphology and same chemical composition in which each crystallite is in point contact or virtually point contact with crystallites that surround it, and b) at least one active phase comprising metallic particles mechanically anchored into said catalytic support so that the coalescence and the mobility of each particle are limited to a volume corresponding to that of a crystallite of said catalytic ceramic support.

Abstract: A catalyst structure 1 used for hydrogenation reaction or dehydrogenation reaction is characterized by the inclusion of a first coiled catalytic wire body 4 formed by coiling a catalytic wire in which a catalytic material is supported on the surface of a metallic core material, and a second catalytic member 5 disposed on the inner surface side and/or outer surface side of the coiled catalytic wire body 4.